Disclosure of Invention
In order to overcome the above-mentioned technical problems, the present invention aims to provide a method for efficiently processing a heterogeneous material by using a composite laser, which uses a multi-wavelength laser with photothermal and photochemical effects, and realizes high-speed processing of the heterogeneous material by using laser irradiation with specific parameters and combining real-time monitoring of spectral parameters and laser parameter regulation and control. The method solves the problems that the laser processing heterogeneous material is easy to damage the low threshold phase or part, the optimization parameter matching of each phase or each part aiming at specific processing is difficult to realize, the processing effect is difficult to regulate and control in real time, and the processing process is difficult to carry out at high speed.
In order to achieve the purpose, the invention adopts the following technical scheme:
a method for efficiently processing a heterogeneous material by composite laser comprises the following specific steps:
(1) determining the phase P of the most abundant heterogeneous material to be processed M Phase P with highest lasing threshold FM Phase P with lowest lasing threshold Fm ;
(2) According to the most abundant phase P M Phase P with highest lasing threshold FM And minimum threshold of laser actionPhase P of Fm The absorption rate of ultraviolet light-infrared light is selected, and an ultraviolet light wavelength L1 with the highest relative absorption rate and an infrared light wavelength L2 with the highest relative absorption rate are selected;
(3) determination of the most abundant phase P M Respectively corresponding to ultraviolet light wavelength L1 and infrared light wavelength L2 at different irradiation densities, such as phase P with the highest content M Damage threshold value F of th (P M )、1.5*F th (P M )、2*F th (P M ) Depth of irradiation D at constant M Width of irradiation B M Width E of the region affected by irradiation M Until reaching a certain multiple a, using a damage threshold (a +0.5) × F th (P M ) Depth of action of applied radiation D M Width of irradiation B M Width E of the region affected by irradiation M The processing requirements are not met, and the phase P with the maximum content of the processing heterogeneous material with the ultraviolet light wavelength L1 and the infrared light wavelength L2 is obtained M Respectively corresponding to the highest laser irradiation density a 1F th (P M ,L1)、a2*F th (P M ,L2);
(4) Determining the phase P with the highest lasing threshold FM Corresponding to the ultraviolet light wavelength L1 and the infrared light wavelength L2 in different irradiation densities, such as the phase P with the highest laser action threshold FM Damage threshold value F of th (P FM )、1.5*F th (P FM )、 2*F th (P FM ) Depth of irradiation D under the like FM Width of irradiation B FM Width E of the region affected by irradiation FM Until a certain multiple b is reached, a damage threshold (b +0.5) × F is used th (P FM ) Depth of action of applied radiation D FM Width of irradiation B FM Width E of the region affected by irradiation FM The processing requirements are not met, and the phase P with the highest laser action threshold of the heterogeneous material processed by the ultraviolet light wavelength L1 and the infrared light wavelength L2 is obtained FM Respective highest laser irradiation density b 1F th (P FM ,L1),b2*F th (P FM ,L2);
(5) Determining the phase P with the lowest lasing threshold Fm Corresponding to ultraviolet wavelength L1, redThe external light wavelength L2 is in different irradiation densities, such as the phase P with the lowest laser action threshold Fm Damage threshold value F of th (P Fm )、1.5*F th (P Fm )、 2*F th (P Fm ) Depth of irradiation D under the like Fm Width of irradiation B Fm Width E of region affected by irradiation Fm Until reaching a certain multiple c, a damage threshold (c +0.5) × F is used th Depth of action of applied radiation D Fm Width of irradiation B Fm Width E of region affected by irradiation Fm The processing requirements are not met, and the phase P with the lowest laser action threshold of the heterogeneous material processed by the ultraviolet light wavelength L1 and the infrared light wavelength L2 is obtained Fm Respective highest laser irradiation density c 1F th (P Fm ,L1)、c2*F th (P Fm ,L2);
(6) When the most abundant phase P is present in the heterogeneous material to be processed M Phase P with lowest lasing threshold Fm When the laser with infrared wavelength L2 is used, c 2F is adopted th (P Fm L2) laser irradiation density to process the heterogeneous material to be processed, and realizing the phase P with the lowest laser action threshold value in the processing area Fm Monitoring the peak position and the peak value of the laser induced spectrum in real time by adopting a spectrum device, and entering the step (7); phase P in maximum content in the heterogeneous material to be processed M Phase P not having the lowest lasing threshold Fm Then, entering the step (11);
(7) when the peak position of the monitored laser-induced spectrum changes or the peak value is reduced by 10% or more, recording the position corresponding to the change; using the wavelength L2 of infrared light and the laser irradiation density c 2F th (P Fm L2) irradiating the heterogeneous material with the laser beam until all surfaces to be processed have been processed;
(8) calculating the recorded position, calculating the average width K of the recorded position, and finding out the laser irradiation density x F under the action of the corresponding ultraviolet light wavelength L1 th (P FM L1), irradiation width D under the action of the laser irradiation density M Width E of region affected by irradiation M When the sum is close to and not higher than the average width K, processing an area with the recording position size larger than K, and monitoring the peak position and the peak value of the laser-induced spectrum in real time by adopting a spectrum device;
(9) when the peak position of the monitored laser induced spectrum changes, or the peak value changes by 10% or more, recording the position corresponding to the change; using ultraviolet light wavelength L1 and laser irradiation density x F th (P FM L1) until all recorded surfaces have been machined;
(10) adopting ultraviolet light wavelength L1 and laser irradiation density F th (P FM L1), setting the light spot to the minimum state with a diaphragm, and implementing the minimum light spot scanning processing on the recording position until the change of the laser-induced spectrum peak value no longer occurs;
(11) when the most abundant phase P is present in the heterogeneous material to be processed M Phase P with highest threshold for lasing FM Comparison c 2F th (P Fm L2) and F th (P FM L2), if c 2F th (P Fm ,L2)>F th (P M L2), using the infrared light wavelength L2, laser irradiation density c2 x F th (P Fm L2) processing the heterogeneous material to be processed, monitoring the peak position and peak value of the laser induced spectrum in real time by adopting a spectrum device, and entering the step (12); if c 2F th (P Fm ,L2)<F th (P FM L2), go to step (15); phase P in maximum content in the heterogeneous material to be processed M Not of the phase P with the highest lasing threshold FM If yes, entering step (20);
(12) when the peak position of the monitored laser induced spectrum changes or the peak value is reduced by 10 percent or more, recording the position corresponding to the change; using the wavelength L2 of infrared light and the laser irradiation density c 2F th (P Fm L2) irradiating the heterogeneous material with the laser beam until all surfaces to be processed have been processed;
(13) the recorded position is calculated by using the wavelength L2 of infrared light and the irradiation density F of laser th (P FM L2) processing the recorded area; using the wavelength L2 of infrared light and the laser irradiation density F th (P FM L2), until all surfaces to be processed have been processed, monitoring the peak position and peak value of its laser-induced spectrum in real time by using a spectroscopic device;
(14) when the peak position of the monitored laser induced spectrum changes, or the peak value changes by 10% or more, recording the position corresponding to the change; using ultraviolet light wavelength L1 and laser irradiation density a 1F th (P FM L1) until no change in the peak value of the laser-induced spectrum occurs;
(15) if c 2F th (P Fm ,L2)<F th (P FM L2), using uv light wavelength L1, laser irradiation density c1 x F th (P Fm L1) processing the heterogeneous material to be processed, and monitoring the peak position and peak value of the laser-induced spectrum in real time by using a spectrum device;
(16) when the peak position of the monitored laser-induced spectrum changes or the peak value is reduced by 10% or more, recording the position corresponding to the change; using ultraviolet light wavelength L1 and laser irradiation density c 1F th (P Fm L1) irradiating the heterogeneous material with laser light until all surfaces to be machined have been machined;
(17) calculating the recorded position, calculating the average width K of the recorded position, and finding out the laser irradiation density y x F under the action of the corresponding ultraviolet wavelength L1 th (P FM L1), irradiation width D under the irradiation density of the laser light M Width E of region affected by irradiation M When the sum is close to and not higher than the average width K, processing an area with the recording position size larger than K, and monitoring the peak position and the peak value of the laser-induced spectrum in real time by adopting a spectrum device;
(18) when the peak position of the monitored laser induced spectrum changes, or the peak value changes by 10% or more, recording the position corresponding to the change; using ultraviolet wavelength L1 and laser irradiation density y F th (P FM L1) until all marks are reachedThe recorded surfaces are processed;
(19) adopting ultraviolet light wavelength L1 and laser irradiation density F th (P FM L1) the processing of the recording position is effected until no change in the peak value of the laser-induced spectrum occurs anymore;
(20) when the maximum content of phase P in the heterogeneous material to be processed is reached M Phase P not having the highest lasing threshold FM Or not the phase P with the lowest lasing threshold Fm Selecting the wavelength L2 of infrared light and the laser irradiation density c 2F th (P Fm L2) nearest x F th (P M L2) processing the heterogeneous material to be processed, and monitoring the peak position and peak value of the laser induced spectrum in real time by using a spectrum device;
(21) when the peak position of the monitored laser-induced spectrum changes or the peak value is reduced by 10% or more, recording the position corresponding to the change; using the wavelength L2 of infrared light and the laser irradiation density x F th (P M L2) irradiating the heterogeneous material with the laser beam until all surfaces to be processed have been processed;
(22) calculating the recorded position, calculating the average width K of the recorded position, and finding out the laser irradiation density z x F under the action of the corresponding ultraviolet light wavelength L1 th (P M L1), irradiation width D under the action of the laser irradiation density M Width E of region affected by irradiation M When the sum is close to and not higher than the average width K, processing an area with the recording position size larger than K, and monitoring the peak position and the peak value of the laser-induced spectrum in real time by adopting a spectrum device;
(23) when the peak position of the monitored laser induced spectrum changes, or the peak value changes by 10% or more, recording the position corresponding to the change; adopting ultraviolet light wavelength L1 and laser irradiation density z x F th (P M L1) until all recorded surfaces have been machined;
(24) adopting ultraviolet light wavelength L1 and laser irradiation density F th (P FM L1), the diaphragm is used to set the light spot to the minimum state, and the maximum to the recording position is achievedAnd scanning and processing the small light spot until the change of the laser-induced spectrum peak value does not occur.
Compared with the prior art, the invention has the following beneficial effects:
(1) the laser processing method has the advantages that the multi-wavelength laser with photo-thermal and photochemical effects is adopted as the laser source, laser parameters suitable for processing various heterogeneous materials including ceramics, metals, composite materials, porous materials, organic matters and the like can be reasonably matched, the advantages of high-speed repetition frequency of thermal effect laser megahertz or continuous irradiation and the advantages of high-resolution and low-influence area of photochemical effect laser are fully utilized, and the laser processing method can be suitable for various processing requirements such as punching, cutting, polishing and the like;
(2) by adopting laser irradiation with specific parameters and through differential classification and removal of parameters of each phase or each part, optimal parameter setting of each phase or each part can be realized, the loss of low-melting-point, volatile and other low-laser irradiation damage threshold materials in the processing process is reduced, and the high-quality processing quality is ensured;
(3) the consumption condition of a processed phase or part of the processing process is monitored through real-time laser-induced breakdown spectroscopy measurement of the processing process, laser parameters (energy, defocusing amount and the like) are regulated and controlled in real time according to information such as spectral peak positions, peak values and the like, and the processing effect is improved through real-time regulation and control of the processing process;
(4) the technical scheme provided by the invention can be suitable for processing various heterogeneous materials, has high efficiency and good processing quality, and is easy to realize automation and batch production.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail below with reference to the accompanying drawings in conjunction with specific examples of composite laser surface polishing of SiC fiber reinforced resin matrix composites.
(1) Determining the phase P of the most abundant heterogeneous material to be processed M The resin phase and the phase P with the highest laser action threshold FM Phase P with lowest threshold for SiC fibre and laser action Fm Is a resin phase;
(2) selecting the two phases to have a relative highest absorbance ultraviolet wavelength L1 of 193nm and a relative highest absorbance infrared wavelength L2 of 1064 nm;
(3) the resin phase with the most content is respectively corresponding to the irradiation action depth D of the ultraviolet light wavelength L1 and the infrared light wavelength L2 under different irradiation densities M Width of irradiation B M Width E of the region affected by irradiation M The parameters are as follows, wherein the processing depth, action width and influence area width of the process requirement are respectively 1 μm, unlimited and 10 μm, thereby obtaining the highest energy density of 6.0J/cm respectively corresponding to the ultraviolet light wavelength L1 and the infrared light wavelength L2 for processing the heterogeneous material 2 (P M ,L1)、750KW/cm2(P M ,L2);
(4) Determining irradiation depth D of the phase SiC fibers with the highest laser action threshold under different irradiation densities corresponding to the ultraviolet light wavelength L1 and the infrared light wavelength L2 FM Width of irradiation B FM Width E of the region affected by irradiation FM The parameters are as follows, wherein the processing depth, action width and influence area width of the process requirement are respectively 1 μm, and are not limited to 10 μm, thereby obtaining the highest energy density of 7.0J/cm respectively corresponding to the composite laser wavelength L1 and L2 for processing the heterogeneous material 2 (P FM ,L1),1400KW/cm 2 (P FM ,L2);
(5) The phase P with the maximum content in the SiC fiber reinforced composite material to be processed M Phase P with lowest lasing threshold Fm Directly using a laser with a wavelength of 1064nm and adopting 750W/cm 2 (P Fm L2) laser irradiation density to process the heterogeneous material to realize the laser irradiation densityPhase P with lowest laser action threshold in machining region Fm The processing of (3) and monitoring the peak position and peak value of the laser induced spectrum in real time by adopting a spectrum device;
(7) when the peak position of the monitored laser-induced spectrum changes or the peak value is reduced by 10% or more, recording the position corresponding to the change; using 1064nm laser with 750W/cm wavelength 2 (P Fm L2) irradiating the heterogeneous material with laser of the laser irradiation parameters until all surfaces to be processed have been processed;
(8) calculating the recorded position, calculating the average width K of the recorded position to be 32 μm, and searching corresponding x F th (P FM ,L1)=1.0J/cm 2 Processing an area with the recording area size larger than K, and monitoring the peak position and the peak value of the laser-induced spectrum in real time by adopting a spectrum device;
(9) when the peak position of the monitored laser induced spectrum changes, or the peak value changes by 10% or more, recording the position corresponding to the change; adopting 1064nm laser, 750W/cm 2 (P Fm L2) irradiating the heterogeneous material with laser light of the laser irradiation parameters until all recorded surfaces have been processed;
(10) using a 193nm wavelength of 0.4J/cm 2 (P FM L1) laser irradiation density, setting the spot to the minimum state with a diaphragm, and realizing minimum spot scanning processing for the recording position until no change in the laser-induced spectral peak value occurs any more.
As shown in fig. 1, it can be seen from the figure that the surface processing of the SiC fiber reinforced resin matrix composite material can be realized without damaging the fiber by adopting the laser irradiation with specific parameters, combining the real-time monitoring of the spectral parameters and the laser parameter regulation and control, and the advantages of the invention can be embodied.