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CN114143949B - A flexible hydrophobic barrier medium plasma anti-icing device and anti-icing method - Google Patents

A flexible hydrophobic barrier medium plasma anti-icing device and anti-icing method Download PDF

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CN114143949B
CN114143949B CN202111462899.5A CN202111462899A CN114143949B CN 114143949 B CN114143949 B CN 114143949B CN 202111462899 A CN202111462899 A CN 202111462899A CN 114143949 B CN114143949 B CN 114143949B
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insulating medium
flexible insulating
plasma
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CN114143949A (en
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吴云
卞栋梁
梁华
宗豪华
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Air Force Engineering University of PLA
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/2406Generating plasma using dielectric barrier discharges, i.e. with a dielectric interposed between the electrodes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B64AIRCRAFT; AVIATION; COSMONAUTICS
    • B64DEQUIPMENT FOR FITTING IN OR TO AIRCRAFT; FLIGHT SUITS; PARACHUTES; ARRANGEMENT OR MOUNTING OF POWER PLANTS OR PROPULSION TRANSMISSIONS IN AIRCRAFT
    • B64D15/00De-icing or preventing icing on exterior surfaces of aircraft

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  • Plasma & Fusion (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Aviation & Aerospace Engineering (AREA)
  • Plasma Technology (AREA)

Abstract

The flexible hydrophobic barrier medium plasma anti-icing device comprises a bare electrode (1), a hydrophobic coating (4), a middle flexible insulating medium (3), a buried electrode (2) and a lower flexible insulating medium (5) from top to bottom. The plasma surface treatment equipment for the flexible insulating medium in the preparation process comprises a sine wave power supply (6), a switch (11), an upper electrode plate (7), a lower electrode plate (9), an upper insulating plate (8) and a lower insulating plate (10). In addition, a preparation method of the flexible hydrophobic anti-icing plasma anti-icing device is also provided. Under the condition of the same power supply excitation parameters, the invention can obviously reduce the discharge power consumption of the plasma anti-icing device; the plasma discharge is more uniform, the surface temperature distribution is more uniform, and the temperature distortion can not occur; can effectively prevent ice accumulation on the surface of the aircraft body.

Description

一种柔性疏水阻挡介质等离子体防冰装置及防冰方法A flexible hydrophobic barrier medium plasma anti-icing device and anti-icing method

技术领域technical field

本发明涉及等离子技术领域,具体涉及一种柔性疏水阻挡介质等离子体防冰装置及防冰方法。The invention relates to the field of plasma technology, in particular to a flexible hydrophobic barrier medium plasma anti-icing device and an anti-icing method.

背景技术Background technique

无人机防除冰技术密切关乎飞行安全,当无人机在结冰气象条件下飞行时,冷水滴或降水中的过冷雨碰到飞机机体,或水汽直接在机体表面凝华,都会形成积冰。无人机一旦积冰,轻则影响气动外形、电子传感等,重则造成飞行事故甚至坠毁。大型飞机可采用热空气、电加热、化学防冻、机械等传统方式防除冰,而对于中小型无人机,没有涡轮式发动机可提供除冰的气热,机械除冰又会改变机身外形、负重,因此,迫切需要发展负载小、能耗低的防冰方法。基于快速加热效应,放电等离子体在防冰方面具有显著的技术优势,但是目前采用的表面介质阻挡放电形式防冰作用区域小,无法实现高效的防冰需求。UAV anti-icing technology is closely related to flight safety. When UAVs fly in icy weather conditions, cold water droplets or supercooled rain in precipitation hit the aircraft body, or water vapor directly condenses on the body surface, which will form ice accumulation. Once the UAV accumulates ice, it will affect the aerodynamic shape and electronic sensing at the least, and cause flight accidents or even crashes at the worst. Large-scale aircraft can be deiced by traditional methods such as hot air, electric heating, chemical antifreeze, and machinery. For small and medium-sized UAVs, there is no turbine engine to provide air heat for deicing, and mechanical deicing will change the shape and load of the fuselage. Therefore, it is urgent to develop anti-icing methods with small loads and low energy consumption. Based on the rapid heating effect, discharge plasma has significant technical advantages in anti-icing, but the anti-icing effect area of the surface dielectric barrier discharge currently used is small, and cannot meet the high-efficiency anti-icing requirements.

发明内容Contents of the invention

为克服现有技术的不足,本发明提供一种柔性疏水阻挡介质等离子体防冰装置,该装置自上而下包括裸露电极1、疏水涂层4、中层柔性绝缘介质3、掩埋电极2、下层柔性绝缘介质5;其中In order to overcome the deficiencies in the prior art, the present invention provides a flexible hydrophobic barrier medium plasma anti-icing device, which includes a bare electrode 1, a hydrophobic coating 4, a middle flexible insulating medium 3, a buried electrode 2, and a lower flexible insulating medium 5 from top to bottom;

中层柔性绝缘介质3为薄片状;The middle flexible insulating medium 3 is in the shape of a sheet;

疏水涂层4位于中层柔性绝缘介质3之上,疏水涂层4在水平面上的投影形状与中层柔性绝缘介质3的相同;The hydrophobic coating 4 is located on the middle flexible insulating medium 3, and the projection shape of the hydrophobic coating 4 on the horizontal plane is the same as that of the middle flexible insulating medium 3;

薄片状裸露电极1布置在疏水涂层4上表面上,裸露电极1在水平面上的投影为矩形;裸露电极1位于疏水涂层4上表面的左侧或右侧,裸露电极1的左右边缘均与疏水涂层4的左右边缘平行,裸露电极1的各边缘与疏水涂层4的相应边缘均保持一定间距;The flake-shaped exposed electrode 1 is arranged on the upper surface of the hydrophobic coating 4, and the projection of the exposed electrode 1 on the horizontal plane is a rectangle; the exposed electrode 1 is located on the left or right side of the upper surface of the hydrophobic coating 4, and the left and right edges of the exposed electrode 1 are parallel to the left and right edges of the hydrophobic coating 4, and each edge of the exposed electrode 1 is kept at a certain distance from the corresponding edge of the hydrophobic coating 4;

掩埋电极2布置在中层柔性绝缘介质3的下表面,掩埋电极2总体位于中层柔性绝缘介质3下表面的大致中间位置,掩埋电极2在水平面上的投影为矩形;当裸露电极1靠近中层柔性绝缘介质3左侧时,掩埋电极2左边缘在水平面上的投影与裸露电极1右边缘在水平面上的投影重合,或者保持较小间距;当裸露电极1靠近中层柔性绝缘介质3右侧时,掩埋电极2右边缘在水平面上的投影与裸露电极1左边缘在水平面上的投影重合,或者保持较小间距;掩埋电极2的各边缘与中层柔性绝缘介质3的相应边缘均保持一定间距;The buried electrode 2 is arranged on the lower surface of the middle layer flexible insulating medium 3, and the buried electrode 2 is generally located in the approximate middle of the lower surface of the middle layer flexible insulating medium 3, and the projection of the buried electrode 2 on the horizontal plane is rectangular; when the exposed electrode 1 is close to the left side of the middle layer flexible insulating medium 3, the projection of the left edge of the buried electrode 2 on the horizontal plane coincides with the projection of the right edge of the exposed electrode 1 on the horizontal plane, or keeps a small distance; The projections of the left edge of the exposed electrode 1 on the horizontal plane coincide, or keep a small distance; each edge of the buried electrode 2 and the corresponding edge of the middle flexible insulating medium 3 maintain a certain distance;

下层柔性绝缘介质5布置于柔性疏水阻挡介质等离子体防冰装置的最下层,其上下两面具有粘性通常情况下,其在水平面上的投影形状与疏水涂层4、中层柔性绝缘介质3的相同;下层柔性绝缘介质5完全覆盖掩埋电极2;通过下层柔性绝缘介质5将所述装置粘接到飞机容易结冰的位置;The lower layer of flexible insulating medium 5 is arranged at the bottom of the flexible hydrophobic barrier medium plasma anti-icing device, and its upper and lower sides are viscous. Normally, its projected shape on the horizontal plane is the same as that of the hydrophobic coating 4 and the middle layer of flexible insulating medium 3; the lower layer of flexible insulating medium 5 completely covers the buried electrode 2; the device is bonded to the position where the aircraft is easy to freeze through the lower layer of flexible insulating medium 5;

裸露电极1与疏水涂层4之间、疏水涂层4与中层柔性绝缘介质3之间、掩埋电极2与中层柔性绝缘介质3之间均通过粘性物质粘结。The exposed electrode 1 and the hydrophobic coating 4 , the hydrophobic coating 4 and the middle flexible insulating medium 3 , and the buried electrode 2 and the middle flexible insulating medium 3 are bonded by adhesive substances.

在本发明的一个实施例中,中层柔性绝缘介质3为矩形薄片,厚度为0.1-0.3mm。In one embodiment of the present invention, the middle flexible insulating medium 3 is a rectangular sheet with a thickness of 0.1-0.3 mm.

在本发明的另一个实施例中,掩埋电极2与裸露电极1在水平面上的投影保持1-2mm间距。In another embodiment of the present invention, a distance of 1-2 mm is maintained between the buried electrode 2 and the projection of the exposed electrode 1 on the horizontal plane.

在本发明的一个具体实施例中,In a specific embodiment of the present invention,

中层柔性绝缘介质3为矩形薄片,厚度为0.2mm;下层柔性绝缘介质5选自硅橡胶、环氧树脂、双面聚酰亚胺胶带、双面聚四氟乙烯胶带,优选双面聚酰亚胺胶带;The middle flexible insulating medium 3 is a rectangular sheet with a thickness of 0.2 mm; the lower flexible insulating medium 5 is selected from silicone rubber, epoxy resin, double-sided polyimide tape, double-sided polytetrafluoroethylene tape, preferably double-sided polyimide tape;

裸露电极1、掩埋电极2采用铜胶带粘接的方法制备,或通过离子束溅射、丝网印刷工艺,将铜、银、铂或金直接制备于中层柔性绝缘介质3的下表面、疏水涂层4的上表面。The exposed electrode 1 and the buried electrode 2 are prepared by bonding copper tape, or by ion beam sputtering and screen printing, copper, silver, platinum or gold are directly prepared on the lower surface of the middle flexible insulating medium 3 and the upper surface of the hydrophobic coating 4 .

还提供一种柔性疏水阻挡介质等离子体防冰装置在制备过程中,柔性绝缘介质需要用到的等离子体表面处理设备,采用上述的柔性疏水阻挡介质等离子体防冰装置,其特征在于,该设备包括正弦波电源6,开关11,上电极板7,下电极板9,上绝缘板8和下绝缘板10;其中There is also provided a flexible hydrophobic barrier medium plasma anti-icing device in the preparation process, plasma surface treatment equipment required for flexible insulating media, using the above-mentioned flexible hydrophobic barrier medium plasma anti-icing device, characterized in that the equipment includes a sine wave power supply 6, a switch 11, an upper electrode plate 7, a lower electrode plate 9, an upper insulating plate 8 and a lower insulating plate 10;

上电极板7位于上绝缘板8上表面上,与上绝缘板8固定连接,与高压电源6高压端相连,二者之间插入开关11,用于控制等离子体的产生于切断;The upper electrode plate 7 is located on the upper surface of the upper insulating plate 8, is fixedly connected to the upper insulating plate 8, and is connected to the high-voltage end of the high-voltage power supply 6, and a switch 11 is inserted between the two to control the generation and cutting of the plasma;

下电极板9位于下绝缘板10下表面上,与下绝缘板10固定连接,下电极板9接地;下电极板9与上电极板7在水平面上的投影基本重合;上绝缘板8与下绝缘板10位置相对,相互平行地放置,二者在水平面上的投影基本重合,上绝缘板8与下绝缘板10之间的垂直间距为2-4mm;The lower electrode plate 9 is located on the lower surface of the lower insulating plate 10, fixedly connected with the lower insulating plate 10, and the lower electrode plate 9 is grounded; the projections of the lower electrode plate 9 and the upper electrode plate 7 on the horizontal plane are basically coincident; the upper insulating plate 8 is opposite to the lower insulating plate 10 and placed parallel to each other, and the projections of the two on the horizontal plane are basically coincident. The vertical distance between the upper insulating plate 8 and the lower insulating plate 10 is 2-4mm;

将所述柔性疏水阻挡介质等离子体防冰装置放置于下绝缘板10上方的中间位置;The plasma anti-icing device of the flexible hydrophobic barrier medium is placed in the middle position above the lower insulating plate 10;

高压电源6的负端接地。The negative end of the high voltage power supply 6 is grounded.

在本发明的一个实施例中,上绝缘板8与下绝缘板10位置相对,相互平行地放置,二者在水平面上的投影基本重合,上绝缘板8与下绝缘板10之间的垂直间距为2-4mm。In one embodiment of the present invention, the upper insulating plate 8 and the lower insulating plate 10 are positioned opposite to each other and placed parallel to each other. The projections of the two on the horizontal plane basically overlap, and the vertical distance between the upper insulating plate 8 and the lower insulating plate 10 is 2-4mm.

在本发明的一个具体实施例中,上绝缘板8与下绝缘板10之间的垂直间距为3mm;高压电源6输出电压为10-15kV,放电频率10-15kHz。In a specific embodiment of the present invention, the vertical distance between the upper insulating plate 8 and the lower insulating plate 10 is 3mm; the output voltage of the high voltage power supply 6 is 10-15kV, and the discharge frequency is 10-15kHz.

此外,还提供一种柔性疏水防冰等离子体防冰装置制备方法,具体如下:In addition, a method for preparing a flexible hydrophobic anti-icing plasma anti-icing device is provided, specifically as follows:

第一步,中层柔性绝缘材料3表面处理The first step, middle flexible insulating material 3 surface treatment

首先,将绝缘材料用酒精冲洗;然后,在去离子水中清洗10min-20min,在烘箱中烘干10min-20min;进一步,通过等离子体对中层柔性绝缘材料3进行表面处理;First, rinse the insulating material with alcohol; then, wash it in deionized water for 10min-20min, and dry it in an oven for 10min-20min; further, perform surface treatment on the middle flexible insulating material 3 by plasma;

使用等离子体表面处理设备,将前述处理过的中层柔性绝缘介质3置于下绝缘板10上方,调节正弦波电源6输出电压为10-15kV,放电频率10-15kHz,接通开关11后,在上绝缘板8与下绝缘板10间隙之间产生等离子体,该等离子体对中层柔性绝缘介质3的上表面进行表面处理,处理时间为30-60s,获得表面处理后的中层柔性绝缘介质3;Using plasma surface treatment equipment, place the above-mentioned treated middle layer flexible insulating medium 3 above the lower insulating plate 10, adjust the output voltage of the sine wave power supply 6 to 10-15kV, and discharge the frequency to 10-15kHz. After switching on the switch 11, plasma is generated between the gap between the upper insulating plate 8 and the lower insulating plate 10, and the plasma is surface-treated on the upper surface of the middle layer flexible insulating medium 3. The treatment time is 30-60s, and the surface-treated middle layer flexible insulating medium 3 is obtained;

第二步,制备疏水涂层The second step is to prepare a hydrophobic coating

将SiC颗粒与树脂基体混合,SiC颗粒质量分数30%-40%之间,在常温下转速磁力搅拌1h-2h,再用超声细胞破碎机在常温下超声分散30min-60min;待充分混合均匀,将涂料均匀涂覆于玻璃基底上,待涂料自然流平,形成一定厚度的涂层;放入高温烘箱中固化2-3h;即可制备得到疏水涂层;Mix the SiC particles with the resin matrix, the mass fraction of SiC particles is between 30%-40%, stir magnetically at room temperature for 1h-2h, and then use an ultrasonic cell crusher to ultrasonically disperse at room temperature for 30min-60min; after fully mixing and uniform coating, the coating is evenly coated on the glass substrate.

第三步,制备电极The third step is to prepare the electrodes

在柔性介质两面制备电极;Prepare electrodes on both sides of the flexible medium;

第四步,铺覆下层柔性绝缘介质5The fourth step is to pave the lower layer of flexible insulating medium 5

下层柔性绝缘介质5铺覆范围与中层柔性绝缘介质3大小一致,一面粘贴于柔性介质的背面,用于阻隔防冰装置背部的放电,另一面粘结于飞机机体易于结冰之处。The covering range of the lower flexible insulating medium 5 is the same as that of the middle flexible insulating medium 3. One side is pasted on the back of the flexible medium to block the discharge on the back of the anti-icing device, and the other side is glued to the place where the aircraft body is prone to icing.

在本发明的一个具体实施例中,上述柔性疏水防冰等离子体防冰装置制备方法具体如下:In a specific embodiment of the present invention, the preparation method of the above-mentioned flexible hydrophobic anti-icing plasma anti-icing device is as follows:

第一步,中层柔性绝缘材料3表面处理The first step, middle flexible insulating material 3 surface treatment

绝缘材料选自聚酰亚胺、硅橡胶、聚四氟乙烯或聚乙烯;在去离子水中清洗15min,在50℃环境烘箱中烘干15min;The insulating material is selected from polyimide, silicone rubber, polytetrafluoroethylene or polyethylene; wash in deionized water for 15 minutes, and dry in an ambient oven at 50°C for 15 minutes;

使用等离子体表面处理设备,将前述处理过的中层柔性绝缘介质3置于下绝缘板10上方,调节正弦波电源6输出电压为12kV,放电频率13kHz,接通开关11后,在上绝缘板8与下绝缘板10间隙之间产生等离子体,该等离子体对中层柔性绝缘介质3的上表面进行表面处理,处理时间为45s,获得表面处理后的中层柔性绝缘介质3;Using plasma surface treatment equipment, the above-mentioned treated middle layer flexible insulating medium 3 is placed above the lower insulating plate 10, the output voltage of the sine wave power supply 6 is adjusted to 12kV, and the discharge frequency is 13kHz. After the switch 11 is turned on, plasma is generated between the gap between the upper insulating plate 8 and the lower insulating plate 10, and the plasma is surface-treated on the upper surface of the middle layer flexible insulating medium 3. The treatment time is 45s, and the surface-treated middle layer flexible insulating medium 3 is obtained;

第二步,制备疏水涂层The second step is to prepare a hydrophobic coating

将SiC颗粒与树脂基体混合,SiC颗粒质量分数35%,在25℃下以300r/min的转速磁力搅拌1.5h,再用超声细胞破碎机以100W的功率,在25℃下超声分散45min;待充分混合均匀,将涂料均匀涂覆于玻璃基底上,待涂料自然流平,形成0.05-0.3mm厚度的涂层;放入100℃烘箱中,固化2.5h;即可制备得到疏水涂层;Mix the SiC particles with the resin matrix, the mass fraction of SiC particles is 35%, magnetically stir at 25°C at a speed of 300r/min for 1.5h, and then use an ultrasonic cell breaker with a power of 100W to ultrasonically disperse at 25°C for 45min; after fully mixing and uniform coating, the coating is evenly coated on the glass substrate, and the coating is naturally leveled to form a coating with a thickness of 0.05-0.3mm; put it in an oven at 100°C and cure for 2.5h; coating;

第三步,制备电极The third step is to prepare the electrodes

直接选用铜胶带粘贴于柔性介质两面,或者用丝网印刷、离子束溅射工艺制备,丝网印刷工艺所用的金属材料为导电银浆,离子束溅射工艺选用的金属材料为铜钯、银钯、铂钯、金钯或钨钯;Directly use copper tape to paste on both sides of the flexible medium, or prepare by screen printing or ion beam sputtering process. The metal material used in the screen printing process is conductive silver paste, and the metal material used in the ion beam sputtering process is copper palladium, silver palladium, platinum palladium, gold palladium or tungsten palladium;

第四步,铺覆下层柔性绝缘介质5The fourth step is to pave the lower layer of flexible insulating medium 5

下层柔性绝缘介质5铺覆范围与中层柔性绝缘介质3大小一致,一面粘贴于柔性介质的背面,用于阻隔防冰装置背部的放电,另一面粘结于飞机机体易于结冰之处。The covering range of the lower flexible insulating medium 5 is the same as that of the middle flexible insulating medium 3. One side is pasted on the back of the flexible medium to block the discharge on the back of the anti-icing device, and the other side is glued to the place where the aircraft body is prone to icing.

本发明通过对常规柔性绝缘介质进行等离子体表面改性,然后在改性后的绝缘介质表面制备疏水涂层,作为等离子体防冰装置的绝缘阻挡介质,相比没有涂层的阻挡介质,其优势在于:在相同电源激励参数条件下,该装置能够显著降低等离子体防冰装置的放电功耗;等离子体放电更为均匀,表面温度分布也更为均匀,不会出现温度畸变;疏水涂层内含无机填料,能够有效阻隔等离子体放电产生的活性粒子对柔性绝缘介质的轰击破坏,从而有效延长该装置的使用寿命;疏水表面能够改变过冷来流积冰形态,减小与等离子体防冰装置表面的接触面积;疏水涂层配合等离子体放电的快速加热,能够高效防止飞机机体表面积冰。The present invention carries out plasma surface modification on the conventional flexible insulating medium, and then prepares a hydrophobic coating on the surface of the modified insulating medium, as the insulating barrier medium of the plasma anti-icing device, compared with the blocking medium without coating, its advantages are: under the same power excitation parameter conditions, the device can significantly reduce the discharge power consumption of the plasma anti-icing device; the plasma discharge is more uniform, the surface temperature distribution is also more uniform, and there will be no temperature distortion; the hydrophobic coating contains inorganic fillers, which can effectively block active particles generated by plasma discharge from bombarding and destroying the flexible insulating medium, thereby effectively prolonging the service life of the device; The hydrophobic surface can change the form of supercooled incoming ice accumulation and reduce the contact area with the surface of the plasma anti-icing device; the hydrophobic coating can effectively prevent ice accumulation on the surface of the aircraft body in combination with the rapid heating of the plasma discharge.

附图说明Description of drawings

图1示出柔性疏水阻挡介质等离子体防冰装置结构示意图;Fig. 1 shows a schematic structural diagram of a flexible hydrophobic barrier medium plasma anti-icing device;

图2示出柔性疏水阻挡介质等离子体防冰装置制备过程示意图;Figure 2 shows a schematic diagram of the preparation process of a flexible hydrophobic barrier medium plasma anti-icing device;

图3示出绝缘介质等离子体表面处理示意图;Fig. 3 shows the schematic diagram of insulating medium plasma surface treatment;

图4示出柔性疏水阻挡介质等离子体防冰装置工作过程产生的等离子体区域;Fig. 4 shows the plasma region generated during the working process of the flexible hydrophobic barrier medium plasma anti-icing device;

图5示出高压电源输出的两种波形,其中图5(a)示出正弦波形,图5(b)示出尖脉冲波形。Fig. 5 shows two waveforms output by the high-voltage power supply, wherein Fig. 5(a) shows a sinusoidal waveform, and Fig. 5(b) shows a sharp pulse waveform.

具体实施方式Detailed ways

下面结合附图和实施例对本发明进一步说明,本发明包括但不仅限于下述实施例。The present invention will be further described below in conjunction with the accompanying drawings and embodiments, and the present invention includes but not limited to the following embodiments.

图1(a)和(b)分别示出了柔性疏水阻挡介质等离子体防冰装置结构主视图和俯视图。如图1(a)所示,柔性疏水阻挡介质等离子体防冰装置自上而下包括裸露电极1、疏水涂层4、中层柔性绝缘介质3、掩埋电极2、下层柔性绝缘介质5。Figure 1(a) and (b) show the front view and top view of the structure of the flexible hydrophobic barrier dielectric plasma anti-icing device, respectively. As shown in Fig. 1(a), the flexible hydrophobic barrier dielectric plasma anti-icing device includes a bare electrode 1, a hydrophobic coating 4, a middle flexible insulating medium 3, a buried electrode 2, and a lower flexible insulating medium 5 from top to bottom.

中层柔性绝缘介质3通常为矩形薄片,厚度为0.1-0.3mm,优选厚度0.2mm。The middle flexible insulating medium 3 is generally a rectangular sheet with a thickness of 0.1-0.3mm, preferably 0.2mm.

在疏水涂层4上表面上布置薄片状裸露电极1,裸露电极1在水平面上的投影通常为矩形。在本发明的一个具体实施例中,如图1(a)所示,裸露电极1位于疏水涂层4左侧或右侧,裸露电极1的左右边缘均与疏水涂层4的左右边缘平行,裸露电极1的各边缘与疏水涂层4的相应边缘均保持一定间距。A flake-shaped exposed electrode 1 is arranged on the upper surface of the hydrophobic coating 4 , and the projection of the exposed electrode 1 on the horizontal plane is generally rectangular. In a specific embodiment of the present invention, as shown in Figure 1 (a), the exposed electrode 1 is located on the left or right side of the hydrophobic coating 4, the left and right edges of the exposed electrode 1 are parallel to the left and right edges of the hydrophobic coating 4, and each edge of the exposed electrode 1 is kept at a certain distance from the corresponding edge of the hydrophobic coating 4.

疏水涂层4在水平面上的投影形状与中层柔性绝缘介质3的相同。在本发明的一个具体实施例中,疏水涂层4通过喷涂工艺制备于中层柔性绝缘介质3上表面,涂层厚度约0.1mm。The projection shape of the hydrophobic coating 4 on the horizontal plane is the same as that of the middle flexible insulating medium 3 . In a specific embodiment of the present invention, the hydrophobic coating 4 is prepared on the upper surface of the middle flexible insulating medium 3 by a spraying process, and the thickness of the coating is about 0.1 mm.

在中层柔性绝缘介质3的下表面布置掩埋电极2,掩埋电极2总体位于中层柔性绝缘介质3下表面的大致中间位置,掩埋电极2在水平面上的投影通常为矩形,掩埋电极2左边缘在水平面上的投影与裸露电极1在水平面上的投影重合,也可以保持1-2mm间距,掩埋电极2的各边缘与中层柔性绝缘介质3的相应边缘均保持一定间距。The buried electrode 2 is arranged on the lower surface of the middle layer flexible insulating medium 3, and the buried electrode 2 is generally located in the approximate middle of the lower surface of the middle layer flexible insulating medium 3. The projection of the buried electrode 2 on the horizontal plane is usually rectangular, and the projection of the left edge of the buried electrode 2 on the horizontal plane coincides with the projection of the exposed electrode 1 on the horizontal plane, and a distance of 1-2 mm can also be maintained.

下层柔性绝缘介质5布置于柔性疏水阻挡介质等离子体防冰装置的最下层,其在具备绝缘功能的基础上,还需具备上下两面粘性的功能,可选的材料有硅橡胶、环氧树脂、双面聚酰亚胺胶带、双面聚四氟乙烯胶带等,优选双面聚酰亚胺胶带。通常情况下,其在水平面上的投影形状与疏水涂层4、中层柔性绝缘介质3的相同;下层柔性绝缘介质5必须完全覆盖掩埋电极2,下层柔性绝缘介质5一方面用来阻挡掩埋电极2一侧的放电,另一方面用于将本发明的柔性疏水阻挡介质等离子体防冰装置粘接到机翼、尾翼等飞机容易结冰的位置处。The lower layer of flexible insulating medium 5 is arranged on the bottom layer of the plasma anti-icing device with flexible hydrophobic barrier medium. In addition to its insulating function, it also needs to have the function of stickiness on the upper and lower sides. The optional materials include silicone rubber, epoxy resin, double-sided polyimide tape, double-sided polytetrafluoroethylene tape, etc., preferably double-sided polyimide tape. Normally, its projected shape on the horizontal plane is the same as that of the hydrophobic coating 4 and the middle flexible insulating medium 3; the lower flexible insulating medium 5 must completely cover the buried electrode 2, and the lower flexible insulating medium 5 is used on the one hand to block the discharge on one side of the buried electrode 2, and on the other hand, it is used to bond the plasma anti-icing device of the flexible hydrophobic barrier medium of the present invention to the positions where aircraft such as wings and empennages are prone to icing.

在本发明的一个具体实施例中,裸露电极1与疏水涂层4之间、疏水涂层4与中层柔性绝缘介质3之间、掩埋电极2与中层柔性绝缘介质3之间均通过胶层粘结。裸露电极1、掩埋电极2除了采用铜胶带粘接的方法制备,还可以通过离子束溅射、丝网印刷工艺,将铜、银、铂、金等金属直接制备于中层柔性绝缘介质3的下表面、疏水涂层4的上表面。In a specific embodiment of the present invention, the exposed electrode 1 and the hydrophobic coating 4 , the hydrophobic coating 4 and the middle flexible insulating medium 3 , and the buried electrode 2 and the middle flexible insulating medium 3 are all bonded by an adhesive layer. The exposed electrode 1 and the buried electrode 2 are not only prepared by bonding copper tape, but also copper, silver, platinum, gold and other metals can be directly prepared on the lower surface of the middle flexible insulating medium 3 and the upper surface of the hydrophobic coating 4 by ion beam sputtering and screen printing processes.

图2示出柔性疏水阻挡介质等离子体防冰装置的制备过程,分为四个步骤,分别为柔性绝缘材料表面处理,制备疏水涂层,制备电极,铺覆双面绝缘胶带。具体如下:Figure 2 shows the preparation process of the flexible hydrophobic barrier dielectric plasma anti-icing device, which is divided into four steps, namely surface treatment of flexible insulating materials, preparation of hydrophobic coating, preparation of electrodes, and laying double-sided insulating tape. details as follows:

第一步,中层柔性绝缘材料表面处理The first step, the surface treatment of the middle flexible insulating material

中层柔性绝缘材料可选用聚酰亚胺、硅橡胶、聚四氟乙烯、聚乙烯等。首先,将中层柔性绝缘材料用酒精冲洗;然后,在去离子水中清洗10min-20min,优选15min,在50℃环境烘箱中烘干10min-20min,优选15min;进一步,为了后续增强中层柔性绝缘介质3与疏水涂层4之间的结合力,避免因长期放电、复杂环境等因素出现涂层脱落的情况,需要通过等离子体对中层柔性绝缘材料进行表面处理。The flexible insulating material of the middle layer can be polyimide, silicone rubber, polytetrafluoroethylene, polyethylene, etc. First, rinse the flexible insulating material in the middle layer with alcohol; then, wash it in deionized water for 10 minutes to 20 minutes, preferably 15 minutes, and dry it in an oven at 50°C for 10 minutes to 20 minutes, preferably 15 minutes; further, in order to subsequently enhance the bonding force between the flexible insulating medium 3 in the middle layer and the hydrophobic coating 4, and avoid coating peeling off due to factors such as long-term discharge and complex environments, the surface of the flexible insulating material in the middle layer needs to be treated by plasma.

等离子体表面处理装置如图3所示,装置包括正弦波电源6,开关11,上电极板7,下电极板9,上绝缘板8和下绝缘板10。上电极板7与正弦波电源6高压端相连,二者之间插入开关11,用于控制等离子体的产生于切断。正弦波电源6的负端接地。下电极板9的形状与上电极板7相同,二者相互平行地水平放置,且二者在水平面上的投影完全重叠;下电极板9接地。上绝缘板8的上表面与上电极板7的下表面紧密接触,上电极板7大致位于上绝缘板8的中心位置,上绝缘板8水平放置。下绝缘板10的下表面与下电极板9的上表面紧密接触,下电极板9大致位于下绝缘板10的中心位置,下绝缘板10水平放置,且下绝缘板10与上绝缘板8在水平面上的投影完全重叠。上绝缘板8与下绝缘板10之间的垂直间距为2-4mm,优选3mm。将前述处理过的中层柔性绝缘介质3置于下绝缘板上方,调节正弦波电源6输出电压为10-15kV,优选12kV,放电频率10-15kHz,优选13kHz,接通开关11后,在上绝缘板8与下绝缘板10间隙之间产生等离子体,该等离子体对中层柔性绝缘介质3的上表面进行表面处理,处理时间为30-60s,优选45s,获得表面处理后的中层柔性绝缘介质3。The plasma surface treatment device is shown in FIG. 3 . The device includes a sine wave power source 6 , a switch 11 , an upper electrode plate 7 , a lower electrode plate 9 , an upper insulating plate 8 and a lower insulating plate 10 . The upper electrode plate 7 is connected to the high-voltage end of the sine wave power supply 6, and a switch 11 is inserted between the two to control the generation and cut-off of the plasma. The negative end of the sine wave power supply 6 is grounded. The shape of the lower electrode plate 9 is the same as that of the upper electrode plate 7, and they are placed parallel to each other horizontally, and their projections on the horizontal plane completely overlap; the lower electrode plate 9 is grounded. The upper surface of the upper insulating plate 8 is in close contact with the lower surface of the upper electrode plate 7 , the upper electrode plate 7 is roughly located at the center of the upper insulating plate 8 , and the upper insulating plate 8 is placed horizontally. The lower surface of the lower insulating plate 10 is in close contact with the upper surface of the lower electrode plate 9, the lower electrode plate 9 is roughly located at the center of the lower insulating plate 10, the lower insulating plate 10 is placed horizontally, and the projections of the lower insulating plate 10 and the upper insulating plate 8 on the horizontal plane completely overlap. The vertical distance between the upper insulating plate 8 and the lower insulating plate 10 is 2-4 mm, preferably 3 mm. Put the aforementioned mid-layer flexible insulation medium 3 on the lower insulation board, adjust the sine wave power supply 6 output voltage is 10-15kV, preferably 12kV, the discharge frequency is 10-15kHz, preferably 13kHz, after connecting the switch 11, a plasma is generated between the upper insulation board 8 and the lower insulation board. Surface treatment, the processing time is 30-60s, preferably 45s, and obtain the surface processing mid-layer flexible insulation medium 3.

第二步,制备疏水涂层4The second step is to prepare a hydrophobic coating 4

将SiC颗粒与树脂基体混合,SiC颗粒质量分数30%-40%之间,优选35%,在25℃下以300r/min的转速磁力搅拌1h-2h,优选1.5h,再用超声细胞破碎机以100W的功率,在25℃下超声分散30min-60min,优选45min。待充分混合均匀,用尼龙刷蘸取涂料,均匀涂覆于中层柔性绝缘介质3表面,待涂料自然流平,形成0.05-0.3mm厚度的涂层,优选0.1mm厚度。放入100℃烘箱中,固化2-3h,优选2.5h。即可制备获得疏水涂层4。Mix the SiC particles with the resin matrix, the mass fraction of SiC particles is between 30%-40%, preferably 35%, magnetically stir at 25°C at a speed of 300r/min for 1h-2h, preferably 1.5h, and then use an ultrasonic cell breaker with a power of 100W to ultrasonically disperse at 25°C for 30min-60min, preferably 45min. After being fully mixed and uniform, dip the paint with a nylon brush, and evenly coat it on the surface of the middle flexible insulating medium 3, and wait for the paint to level off naturally to form a coating with a thickness of 0.05-0.3 mm, preferably 0.1 mm. Put it in an oven at 100°C, and cure for 2-3 hours, preferably 2.5 hours. The hydrophobic coating 4 can be prepared.

第三步,制备电极The third step is to prepare the electrodes

可直接选用铜胶带作为裸露电极1和掩埋电极2,将裸露电极1制备于疏水涂层4的一侧(疏水涂层4的另一侧与中层柔性绝缘介质3粘合,且二者形状相同、相互覆盖),将掩埋电极2制备在中层柔性绝缘介质3的一侧(如上所述,中层柔性绝缘介质3的另一侧与疏水涂层4粘合)。此外,裸露电极1和掩埋电极2也可用丝网印刷、离子束溅射工艺制备,丝网印刷工艺所用的金属材料为导电银浆,离子束溅射工艺可选用的金属材料为铜钯、银钯、铂钯、金钯、钨钯等。Copper tape can be directly selected as the exposed electrode 1 and the buried electrode 2, and the exposed electrode 1 is prepared on one side of the hydrophobic coating 4 (the other side of the hydrophobic coating 4 is bonded to the middle flexible insulating medium 3, and both have the same shape and covers each other), and the buried electrode 2 is prepared on one side of the middle flexible insulating medium 3 (as mentioned above, the other side of the middle flexible insulating medium 3 is bonded to the hydrophobic coating 4). In addition, the exposed electrode 1 and the buried electrode 2 can also be prepared by screen printing and ion beam sputtering. The metal material used in the screen printing process is conductive silver paste, and the metal materials that can be used in the ion beam sputtering process are copper palladium, silver palladium, platinum palladium, gold palladium, tungsten palladium, etc.

第四步,铺覆下层柔性绝缘介质5The fourth step is to pave the lower layer of flexible insulating medium 5

下层柔性绝缘介质5采用双面绝缘胶带,双面绝缘胶带铺覆范围与中层柔性绝缘介质3大小一致,一面粘贴于中层柔性绝缘介质3的背面,完全覆盖掩埋电极2,用于阻隔防冰装置背部的放电,另一面粘结于飞机机体。The lower flexible insulating medium 5 adopts double-sided insulating tape. The double-sided insulating tape covers the same size as the middle flexible insulating medium 3. One side is pasted on the back of the middle flexible insulating medium 3 to completely cover the buried electrode 2, which is used to block the discharge on the back of the anti-icing device, and the other side is bonded to the aircraft body.

本发明中柔性疏水防冰等离子体防冰装置,其防冰方法为:In the present invention, the flexible hydrophobic anti-icing plasma anti-icing device, its anti-icing method is:

柔性疏水防冰等离子体防冰装置的裸露电极1连接高压电源13的高压端,高压电源13负端接地。掩埋电极2接地(例如在下层柔性绝缘介质5上打孔,用导线自外及内连接掩埋电极2并接地)。高压电源13可以选用图3中示出的正弦波电源6,也可采用脉冲电源(未示出),其主要作用是在裸露电极1和掩埋电极2之间产生一个强电场,并在裸露电极1右侧、疏水涂层4上表面之上形成等离子体放电区域12,如图4所示。高压电源的电压波形可以是正弦式的、脉冲式的也可以是其他类型,图5(a)、(b)分别示出高压电源输出的正弦波形、尖脉冲波形。The exposed electrode 1 of the flexible hydrophobic anti-icing plasma anti-icing device is connected to the high-voltage end of the high-voltage power supply 13, and the negative end of the high-voltage power supply 13 is grounded. The buried electrode 2 is grounded (for example, a hole is drilled in the lower flexible insulating medium 5, and the buried electrode 2 is connected to the ground with a wire from outside and inside). The high-voltage power supply 13 can be the sine wave power supply 6 shown in FIG. 3 , or a pulse power supply (not shown). Its main function is to generate a strong electric field between the exposed electrode 1 and the buried electrode 2, and form a plasma discharge region 12 on the right side of the exposed electrode 1 and on the upper surface of the hydrophobic coating 4, as shown in FIG. 4 . The voltage waveform of the high-voltage power supply can be sinusoidal, pulsed, or other types. Figure 5(a) and (b) show the sinusoidal waveform and spike waveform output by the high-voltage power supply respectively.

本发明的柔性疏水防冰等离子体防冰装置,不仅能够降低等离子体放电功耗,而且具备以下优点:The flexible hydrophobic anti-icing plasma anti-icing device of the present invention can not only reduce the power consumption of plasma discharge, but also has the following advantages:

在相同电源激励参数条件下,该装置能够扩大等离子体防冰面积;等离子体放电更为均匀,表面温度分布也更为均匀,不会出现温度畸变;疏水涂层内含无机填料,能够有效阻隔等离子体放电产生的活性粒子对柔性绝缘介质的轰击破坏,从而有效延长该装置的使用寿命;疏水表面能够改变过冷来流积冰形态,减小与等离子体防冰装置表面的接触面积;疏水涂层配合等离子体放电的快速加热,能够高效防止飞机机体表面积冰。Under the same power supply excitation parameters, the device can expand the plasma anti-icing area; the plasma discharge is more uniform, the surface temperature distribution is also more uniform, and there will be no temperature distortion; the hydrophobic coating contains inorganic fillers, which can effectively block the active particles generated by the plasma discharge from bombarding and destroying the flexible insulating medium, thereby effectively prolonging the service life of the device; the hydrophobic surface can change the form of supercooled ice accretion and reduce the contact area with the surface of the plasma anti-icing device;

Claims (9)

1.一种柔性疏水阻挡介质等离子体防冰装置,其特征在于,该装置自上而下包括裸露电极(1)、疏水涂层(4)、中层柔性绝缘介质(3)、掩埋电极(2)、下层柔性绝缘介质(5);其中1. A flexible hydrophobic barrier medium plasma anti-icing device is characterized in that, the device comprises an exposed electrode (1), a hydrophobic coating (4), a middle flexible insulating medium (3), a buried electrode (2), and a lower flexible insulating medium (5) from top to bottom; 中层柔性绝缘介质(3)为薄片状;The middle flexible insulating medium (3) is in the shape of a sheet; 疏水涂层(4)位于中层柔性绝缘介质(3)之上,疏水涂层(4)在水平面上的投影形状与中层柔性绝缘介质(3)的相同;The hydrophobic coating (4) is located on the middle flexible insulating medium (3), and the projection shape of the hydrophobic coating (4) on the horizontal plane is the same as that of the middle flexible insulating medium (3); 薄片状裸露电极(1)布置在疏水涂层(4)上表面上,裸露电极(1)在水平面上的投影为矩形;裸露电极(1)位于疏水涂层(4)上表面的左侧或右侧,裸露电极(1)的左右边缘均与疏水涂层(4)的左右边缘平行,裸露电极(1)的各边缘与疏水涂层(4)的相应边缘均保持一定间距;The flake-shaped exposed electrode (1) is arranged on the upper surface of the hydrophobic coating (4), and the projection of the exposed electrode (1) on the horizontal plane is a rectangle; the exposed electrode (1) is located on the left or right side of the upper surface of the hydrophobic coating (4), the left and right edges of the exposed electrode (1) are parallel to the left and right edges of the hydrophobic coating (4), and a certain distance is maintained between each edge of the exposed electrode (1) and the corresponding edge of the hydrophobic coating (4); 掩埋电极(2)布置在中层柔性绝缘介质(3)的下表面,掩埋电极(2)总体位于中层柔性绝缘介质(3)下表面的中间位置,掩埋电极(2)在水平面上的投影为矩形;当裸露电极(1)靠近中层柔性绝缘介质(3)左侧时,掩埋电极(2)左边缘在水平面上的投影与裸露电极(1)右边缘在水平面上的投影重合,或者保持较小间距;当裸露电极(1)靠近柔性绝缘介质(3)右侧时,掩埋电极(2)右边缘在水平面上的投影与裸露电极(1)左边缘在水平面上的投影重合,或者保持较小间距;掩埋电极(2)的各边缘与中层柔性绝缘介质(3)的相应边缘均保持一定间距;The buried electrode (2) is arranged on the lower surface of the middle layer flexible insulating medium (3), and the buried electrode (2) is generally located in the middle of the lower surface of the middle layer flexible insulating medium (3), and the projection of the buried electrode (2) on the horizontal plane is rectangular; when the exposed electrode (1) is close to the left side of the middle layer flexible insulating medium (3), the projection of the left edge of the buried electrode (2) on the horizontal plane coincides with the projection of the right edge of the exposed electrode (1) on the horizontal plane, or a small distance is kept; when the exposed electrode (1) is close to the flexible insulating medium (3) On the right side, the projection of the right edge of the buried electrode (2) on the horizontal plane coincides with the projection of the left edge of the exposed electrode (1) on the horizontal plane, or keep a small distance; each edge of the buried electrode (2) maintains a certain distance from the corresponding edge of the middle flexible insulating medium (3); 下层柔性绝缘介质(5)布置于柔性疏水阻挡介质等离子体防冰装置的最下层,其上下两面具有粘性通常情况下,其在水平面上的投影形状与疏水涂层(4)、中层柔性绝缘介质(3)的相同;下层柔性绝缘介质(5)完全覆盖掩埋电极(2);通过下层柔性绝缘介质(5)将所述装置粘接到飞机容易结冰的位置;The lower layer of flexible insulating medium (5) is arranged at the bottom of the flexible hydrophobic barrier medium plasma anti-icing device, and its upper and lower sides are viscous. Under normal circumstances, its projected shape on the horizontal plane is the same as that of the hydrophobic coating (4) and the middle layer of flexible insulating medium (3); the lower layer of flexible insulating medium (5) completely covers the buried electrode (2); through the lower layer of flexible insulating medium (5), the device is bonded to the position where the aircraft is prone to icing; 裸露电极(1)与疏水涂层(4)之间、疏水涂层(4)与中层柔性绝缘介质(3)之间、掩埋电极(2)与中层柔性绝缘介质(3)之间均通过粘性物质粘结。The exposed electrodes (1) and the hydrophobic coating (4), the hydrophobic coating (4) and the middle flexible insulating medium (3), and the buried electrodes (2) and the middle flexible insulating medium (3) are bonded by viscous substances. 2.如权利要求1所述的柔性疏水阻挡介质等离子体防冰装置,其特征在于,中层柔性绝缘介质(3)为矩形薄片,厚度为0.1-0.3mm。2. The plasma anti-icing device with flexible hydrophobic barrier medium according to claim 1, characterized in that, the middle flexible insulating medium (3) is a rectangular sheet with a thickness of 0.1-0.3 mm. 3.如权利要求1所述的柔性疏水阻挡介质等离子体防冰装置,其特征在于,掩埋电极(2)与裸露电极(1)在水平面上的投影保持1-2mm间距。3. The plasma anti-icing device of flexible hydrophobic barrier medium according to claim 1, characterized in that the buried electrode (2) and the projection of the exposed electrode (1) on the horizontal plane maintain a distance of 1-2mm. 4.如权利要求1所述的柔性疏水阻挡介质等离子体防冰装置,其特征在于,4. flexible hydrophobic barrier medium plasma anti-icing device as claimed in claim 1, is characterized in that, 中层柔性绝缘介质(3)为矩形薄片,厚度为0.2mm;下层柔性绝缘介质(5)选自硅橡胶、环氧树脂、双面聚酰亚胺胶带、双面聚四氟乙烯胶带;The middle flexible insulating medium (3) is a rectangular sheet with a thickness of 0.2 mm; the lower flexible insulating medium (5) is selected from silicone rubber, epoxy resin, double-sided polyimide tape, and double-sided polytetrafluoroethylene tape; 裸露电极(1)、掩埋电极(2)采用铜胶带粘接的方法制备,或通过离子束溅射、丝网印刷工艺,将铜、银、铂或金直接制备于中层柔性绝缘介质(3)的下表面、疏水涂层(4)的上表面。The exposed electrodes (1) and buried electrodes (2) are prepared by bonding copper tape, or by ion beam sputtering and screen printing processes, directly preparing copper, silver, platinum or gold on the lower surface of the middle flexible insulating medium (3) and the upper surface of the hydrophobic coating (4). 5.一种柔性疏水阻挡介质等离子体防冰装置在制备过程中,柔性绝缘介质需要用到的等离子体表面处理设备,采用如权利要求1至4的任何一项所述的柔性疏水阻挡介质等离子体防冰装置,其特征在于,该设备包括正弦波电源(6),开关(11),上电极板(7),下电极板(9),上绝缘板(8)和下绝缘板(10);其中5. A flexible hydrophobic barrier medium plasma anti-icing device in the preparation process, the plasma surface treatment equipment that flexible insulating medium needs to use, adopts the flexible hydrophobic barrier medium plasma anti-icing device as described in any one of claims 1 to 4, it is characterized in that the equipment includes a sine wave power supply (6), a switch (11), an upper electrode plate (7), a lower electrode plate (9), an upper insulating plate (8) and a lower insulating plate (10); wherein 上电极板(7)位于上绝缘板(8)上表面上,与上绝缘板(8)固定连接,与正弦波电源(6)高压端相连,二者之间插入开关(11),用于控制等离子体的产生于切断;The upper electrode plate (7) is located on the upper surface of the upper insulating plate (8), fixedly connected to the upper insulating plate (8), connected to the high-voltage end of the sine wave power supply (6), and a switch (11) is inserted between the two to control the generation and cut-off of plasma; 下电极板(9)位于下绝缘板(10)下表面上,与下绝缘板(10)固定连接,下电极板(9)接地;下电极板(9)与上电极板(7)在水平面上的投影基本重合;上绝缘板(8)与下绝缘板(10)位置相对,相互平行地放置,二者在水平面上的投影基本重合,上绝缘板(8)与下绝缘板(10)之间的垂直间距为2-4mm;The lower electrode plate (9) is located on the lower surface of the lower insulating plate (10), fixedly connected with the lower insulating plate (10), and the lower electrode plate (9) is grounded; the projections of the lower electrode plate (9) and the upper electrode plate (7) on the horizontal plane basically overlap; the upper insulating plate (8) is opposite to the lower insulating plate (10), and are placed parallel to each other. 将所述柔性疏水阻挡介质等离子体防冰装置放置于下绝缘板(10)上方的中间位置;placing the flexible hydrophobic barrier medium plasma anti-icing device in the middle above the lower insulating plate (10); 正弦波电源(6)的负端接地。The negative end of the sine wave power supply (6) is grounded. 6.如权利要求5所述的等离子体表面处理设备,其特征在于,上绝缘板(8)与下绝缘板(10)位置相对,相互平行地放置,二者在水平面上的投影基本重合,上绝缘板(8)与下绝缘板(10)之间的垂直间距为2-4mm。6. plasma surface treatment equipment as claimed in claim 5, is characterized in that, upper insulating plate (8) and lower insulating plate (10) position are relative, are placed parallel to each other, the projection of the two on the horizontal plane coincides substantially, and the vertical distance between upper insulating plate (8) and lower insulating plate (10) is 2-4mm. 7.如权利要求6所述的等离子体表面处理设备,其特征在于,上绝缘板(8)与下绝缘板(10)之间的垂直间距为3mm;正弦波电源(6)输出电压为10-15kV,放电频率10-15kHz。7. plasma surface treatment equipment as claimed in claim 6, is characterized in that, the vertical spacing between upper insulating plate (8) and lower insulating plate (10) is 3mm; Sine wave power supply (6) output voltage is 10-15kV, discharge frequency 10-15kHz. 8.一种柔性疏水防冰等离子体防冰装置制备方法,其特征在于,具体如下:8. A method for preparing a flexible hydrophobic anti-icing plasma anti-icing device, characterized in that, the details are as follows: 第一步,中层柔性绝缘介质(3)表面处理The first step, middle layer flexible insulating medium (3) surface treatment 首先,将中层柔性绝缘介质(3)用酒精冲洗;然后,在去离子水中清洗10min-20min,在烘箱中烘干10min-20min;进一步,通过等离子体对中层柔性绝缘介质(3)进行表面处理;First, rinse the middle layer flexible insulating medium (3) with alcohol; then, wash it in deionized water for 10min-20min, and dry it in an oven for 10min-20min; further, perform surface treatment on the middle layer flexible insulating medium (3) by plasma; 使用等离子体表面处理设备,将前述处理过的中层柔性绝缘介质(3)置于下绝缘板(10)上方,调节正弦波电源(6)输出电压为10-15kV,放电频率10-15kHz,接通开关(11)后,在上绝缘板(8)与下绝缘板(10)间隙之间产生等离子体,该等离子体对中层柔性绝缘介质(3)的上表面进行表面处理,处理时间为30-60s,获得表面处理后的中层柔性绝缘介质(3);Using plasma surface treatment equipment, place the above-mentioned treated middle layer flexible insulating medium (3) above the lower insulating plate (10), adjust the output voltage of the sine wave power supply (6) to 10-15kV, and the discharge frequency to 10-15kHz. After the switch (11) is turned on, plasma is generated between the upper insulating plate (8) and the lower insulating plate (10), and the plasma is surface treated on the upper surface of the middle layer flexible insulating medium (3). insulating medium (3); 第二步,制备疏水涂层The second step is to prepare a hydrophobic coating 将SiC颗粒与树脂基体混合,SiC颗粒质量分数30%-40%之间,在常温下转速磁力搅拌1h-2h,再用超声细胞破碎机在常温下超声分散30min-60min;待充分混合均匀,将涂料均匀涂覆于玻璃基底上,待涂料自然流平,形成一定厚度的涂层;放入高温烘箱中固化2-3h;即可制备得到疏水涂层;Mix the SiC particles with the resin matrix, the mass fraction of SiC particles is between 30%-40%, stir magnetically at room temperature for 1h-2h, and then use an ultrasonic cell crusher to ultrasonically disperse at room temperature for 30min-60min; after fully mixing and uniform coating, the coating is evenly coated on the glass substrate. 第三步,制备电极The third step is to prepare the electrodes 在柔性介质两面制备电极;Prepare electrodes on both sides of the flexible medium; 第四步,铺覆下层柔性绝缘介质(5)The fourth step is to pave the lower layer of flexible insulating medium (5) 下层柔性绝缘介质(5)铺覆范围与中层柔性绝缘介质(3)大小一致,一面粘贴于柔性介质的背面,用于阻隔防冰装置背部的放电,另一面粘结于飞机机体易于结冰之处。The covering range of the lower flexible insulating medium (5) is the same as that of the middle flexible insulating medium (3). One side is pasted on the back of the flexible medium to block the discharge on the back of the anti-icing device, and the other side is glued to the place where the aircraft body is prone to icing. 9.如权利要求8所述的柔性疏水防冰等离子体防冰装置制备方法,其特征在于,具体如下:9. The method for preparing a flexible hydrophobic anti-icing plasma anti-icing device according to claim 8, characterized in that, it is as follows: 第一步,中层柔性绝缘材料3表面处理The first step, middle flexible insulating material 3 surface treatment 绝缘材料选自聚酰亚胺、硅橡胶、聚四氟乙烯或聚乙烯;在去离子水中清洗15min,在50℃环境烘箱中烘干15min;The insulating material is selected from polyimide, silicone rubber, polytetrafluoroethylene or polyethylene; wash in deionized water for 15 minutes, and dry in an ambient oven at 50°C for 15 minutes; 使用等离子体表面处理设备,将前述处理过的中层柔性绝缘介质(3)置于下绝缘板(10)上方,调节正弦波电源(6)输出电压为12kV,放电频率13kHz,接通开关(11)后,在上绝缘板(8)与下绝缘板(10)间隙之间产生等离子体,该等离子体对中层柔性绝缘介质(3)的上表面进行表面处理,处理时间为45s,获得表面处理后的中层柔性绝缘介质(3);Using plasma surface treatment equipment, placing the above-mentioned treated middle layer flexible insulating medium (3) above the lower insulating plate (10), adjusting the output voltage of the sine wave power supply (6) to 12kV, and the discharge frequency to 13kHz, after switching on the switch (11), plasma is generated between the upper insulating plate (8) and the lower insulating plate (10), and the plasma is surface-treated on the upper surface of the middle layer flexible insulating medium (3), and the treatment time is 45s, and the surface-treated middle layer flexible insulating medium (3) is obtained; 第二步,制备疏水涂层The second step is to prepare a hydrophobic coating 将SiC颗粒与树脂基体混合,SiC颗粒质量分数35%,在25℃下以300r/min的转速磁力搅拌1.5h,再用超声细胞破碎机以100W的功率,在25℃下超声分散45min;待充分混合均匀,将涂料均匀涂覆于玻璃基底上,待涂料自然流平,形成0.05-0.3mm厚度的涂层;放入100℃烘箱中,固化2.5h;即可制备得到疏水涂层;Mix the SiC particles with the resin matrix, the mass fraction of SiC particles is 35%, magnetically stir at 25°C at a speed of 300r/min for 1.5h, and then use an ultrasonic cell breaker with a power of 100W to ultrasonically disperse at 25°C for 45min; after fully mixing and uniform coating, the coating is evenly coated on the glass substrate, and the coating is naturally leveled to form a coating with a thickness of 0.05-0.3mm; put it in an oven at 100°C and cure for 2.5h; coating; 第三步,制备电极The third step is to prepare the electrodes 直接选用铜胶带粘贴于柔性介质两面,或者用丝网印刷、离子束溅射工艺制备,丝网印刷工艺所用的金属材料为导电银浆,离子束溅射工艺选用的金属材料为铜钯、银钯、铂钯、金钯或钨钯;Directly use copper tape to paste on both sides of the flexible medium, or prepare by screen printing or ion beam sputtering process. The metal material used in the screen printing process is conductive silver paste, and the metal material used in the ion beam sputtering process is copper palladium, silver palladium, platinum palladium, gold palladium or tungsten palladium; 第四步,铺覆下层柔性绝缘介质(5)The fourth step is to pave the lower layer of flexible insulating medium (5) 下层柔性绝缘介质(5)铺覆范围与中层柔性绝缘介质(3)大小一致,一面粘贴于柔性介质的背面,用于阻隔防冰装置背部的放电,另一面粘结于飞机机体易于结冰之处。The covering range of the lower flexible insulating medium (5) is the same as that of the middle flexible insulating medium (3). One side is pasted on the back of the flexible medium to block the discharge on the back of the anti-icing device, and the other side is glued to the place where the aircraft body is prone to icing.
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