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CN114047154B - A device and method for online measurement of burnout degree of pulverized coal boilers based on spectral analysis - Google Patents

A device and method for online measurement of burnout degree of pulverized coal boilers based on spectral analysis Download PDF

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CN114047154B
CN114047154B CN202111589371.4A CN202111589371A CN114047154B CN 114047154 B CN114047154 B CN 114047154B CN 202111589371 A CN202111589371 A CN 202111589371A CN 114047154 B CN114047154 B CN 114047154B
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pulverized coal
burnout degree
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CN114047154A (en
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闫伟杰
弓慧芳
李框宇
胡智超
邢小玉
周怀春
陈玉民
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Jiangsu Hanguang Intelligent Technology Co ltd
Jiangsu Shenhuo Environmental Protection Technology Co ltd
China University of Mining and Technology CUMT
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Jiangsu Shenhuo Environmental Protection Technology Co ltd
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    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
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    • GPHYSICS
    • G01MEASURING; TESTING
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Abstract

本发明公开一种基于光谱分析在线测量煤粉锅炉燃尽度的装置及方法,该装置包括探测装置和装有控制软件的计算机;探测装置包括前、后两个腔体,在前腔体远离后腔体的侧面上设有开孔,在前腔体内设有沿其长度方向延伸的铠装光纤,铠装光纤远离后腔体的一端与开孔对应的位置设有准直透镜,铠装光纤的另一端与后腔体内的光谱仪相连,光谱仪与计算机间通过串行总线连接通讯。本申请公开的装置的结构简单,可与计算机配合原位检测靠近炉膛中心的煤焦的燃尽度,获得实时燃烧速率和表观动力学参数。

The invention discloses a device and a method for online measuring the burnout degree of a pulverized coal boiler based on spectral analysis. The device includes a detection device and a computer equipped with control software; the detection device includes two front and rear cavities. When the front cavity is far away from the rear An opening is provided on the side of the cavity, and an armored optical fiber extending along its length is provided in the front cavity. A collimating lens is provided at an end of the armored optical fiber away from the rear cavity and corresponding to the opening. The armored optical fiber The other end is connected to the spectrometer in the rear cavity, and the spectrometer and the computer communicate through a serial bus connection. The device disclosed in this application has a simple structure and can be used with a computer to detect the burnout degree of coal near the center of the furnace in situ and obtain real-time combustion rate and apparent kinetic parameters.

Description

一种基于光谱分析在线测量煤粉锅炉燃尽度的装置及方法A device and method for online measurement of burnout degree of pulverized coal boilers based on spectral analysis

技术领域Technical field

本发明属于燃煤分析研究技术领域,具体涉及一种基于光谱分析在线测量煤粉锅炉燃尽度的装置及方法。The invention belongs to the technical field of coal combustion analysis research, and specifically relates to a device and method for online measuring the burnout degree of a pulverized coal boiler based on spectral analysis.

背景技术Background technique

煤炭一直以来都是支持我国经济和社会发展的重要一次性能源,煤炭的高效和清洁利用对经济和生态的可持续发展具有深远意义。煤炭资源在我国的总能源中占据非常关键的位置,起到有效支撑国民经济的快速发展的作用。电站锅炉的正常运行,是电站安全运行的基础,煤炭的燃烧状态关乎锅炉的运行,因此快速、及时和准确的判断出电站锅炉炉膛内的燃烧状态是极为重要的。Coal has always been an important primary energy source supporting my country's economic and social development. The efficient and clean utilization of coal has far-reaching significance for the sustainable development of the economy and ecology. Coal resources occupy a very critical position in my country's total energy and play an effective role in supporting the rapid development of the national economy. The normal operation of the power station boiler is the basis for the safe operation of the power station. The combustion state of coal is related to the operation of the boiler. Therefore, it is extremely important to quickly, timely and accurately judge the combustion state in the furnace of the power station boiler.

对于燃煤发电机组,煤焦发热值可占到煤总发热值的95%,煤焦燃尽时间约占全部燃烧所需时间的90%以上,因此煤的燃烧效率和燃尽时间主要由煤焦决定,炉内煤焦的燃尽度很大程度上决定了煤粉的利用程度,煤焦的燃尽度是衡量煤粉利用程度的一个重要指标,这就要求在实际燃烧过程中煤焦要在较短的时间内尽可能完全燃烧。根据炉内不同高度的燃尽度检测结果,可以更好地组织炉内煤焦的燃烧,提高煤粉燃烧效率,减少煤炭的使用量,降低CO2减排压力。For coal-fired power generating units, the calorific value of coal coke can account for 95% of the total calorific value of coal, and the burnout time of coal coke accounts for more than 90% of the total combustion time. Therefore, the combustion efficiency and burnout time of coal are mainly determined by the coal. Determined by coke, the degree of burnout of coal coke in the furnace largely determines the degree of utilization of pulverized coal. The degree of burnout of coal coke is an important indicator to measure the degree of utilization of pulverized coal. This requires that the degree of coal coke burnout in the actual combustion process Burn as completely as possible in the shortest possible time. According to the burnout detection results at different heights in the furnace, the combustion of coal char in the furnace can be better organized, the efficiency of pulverized coal combustion can be improved, the usage of coal can be reduced, and the pressure of CO2 emission reduction can be reduced.

目前调查煤粉炉燃尽度的研究方法主要为沿程取样法,该方法根据不同高度采集的煤焦的组分变化计算对应的燃尽度,中国专利CN 105527255 A公开一种入炉煤煤质特性在线监测系统,包括取样单元、等离子体光谱分析单元、储样单元、三通式颗粒流测量单元和样品回送单元,该系统可对煤质特性进行有效分析,但是该种方法的取样管路比较复杂,在实验中存在诸多不便,并且缺少对锅炉燃尽度的检测与分析,无法实现在线实时检测,也无法得到实时燃烧速率和表观动力学参数。The current research method for investigating the burnout degree of pulverized coal furnaces is mainly the along-process sampling method. This method calculates the corresponding burnout degree based on the component changes of coal char collected at different heights. Chinese patent CN 105527255 A discloses a method of coal feeding into the furnace. The quality characteristics online monitoring system includes a sampling unit, a plasma spectrum analysis unit, a sample storage unit, a three-way particle flow measurement unit and a sample return unit. This system can effectively analyze the coal quality characteristics, but the sampling tube of this method The road is relatively complicated, there are many inconveniences in the experiment, and there is a lack of detection and analysis of the boiler burnout degree. It is impossible to achieve online real-time detection, and it is impossible to obtain real-time combustion rate and apparent kinetic parameters.

常用的燃尽度计算方法主要为灰示踪法,该方法假设煤样中灰分在燃烧前后保持不变,根据燃烧前后灰分质量分数的变化计算煤中可燃物的析出比例,即燃尽度。这种检测方法只能采集靠近采样点(观火孔)附近的煤焦的燃尽度,无法检测靠近炉膛中心的煤焦的燃尽度,检测结果无法代表检测高度处燃尽度的整体水平,且无法实时原位检测,获得实时燃烧速率和表观动力学参数。The commonly used calculation method for burnout degree is mainly the ash tracer method. This method assumes that the ash content in the coal sample remains unchanged before and after combustion, and calculates the precipitation ratio of combustibles in coal based on the change in ash mass fraction before and after combustion, that is, the burnout degree. This detection method can only collect the burnout degree of coal char near the sampling point (fire observation hole), and cannot detect the burnout degree of coal char near the center of the furnace. The detection results cannot represent the overall level of burnout degree at the detection height. , and it is impossible to detect in situ in real time to obtain real-time combustion rate and apparent kinetic parameters.

发明内容Contents of the invention

本发明的目的在于提供一种基于光谱分析在线测量煤粉锅炉燃尽度的装置及方法,装置结构简单,可与计算机配合原位检测靠近炉膛中心的煤焦的燃尽度,获得实时燃烧速率和表观动力学参数。The object of the present invention is to provide a device and method for online measurement of the burnout degree of a pulverized coal boiler based on spectral analysis. The device has a simple structure and can be used with a computer to detect the burnout degree of coal near the center of the furnace in situ and obtain the real-time combustion rate. and apparent kinetic parameters.

本发明的技术方案为:一种基于光谱分析在线测量煤粉锅炉燃尽度的装置,包括探测装置和装有控制软件的计算机;探测装置包括前、后两个腔体,前腔体远离后腔体的侧面上设有开孔,在前腔体内设有沿其长度方向延伸的铠装光纤,铠装光纤远离后腔体的一端与开孔对应的位置设有准直透镜,铠装光纤的另一端与后腔体内的光谱仪相连,光谱仪与计算机间通过串行总线连接通讯。The technical solution of the present invention is: a device for online measuring the burnout degree of pulverized coal boilers based on spectral analysis, including a detection device and a computer equipped with control software; the detection device includes two front and rear cavities, and the front cavity is far away from the rear cavity. There is an opening on the side of the body, and an armored optical fiber extending along its length is provided in the front cavity. A collimating lens is provided at the end of the armored optical fiber away from the rear cavity and corresponding to the opening. The armored optical fiber is The other end is connected to the spectrometer in the rear cavity, and the spectrometer and the computer communicate through a serial bus connection.

进一步地,开孔处装有石英镜片。Further, a quartz lens is installed at the opening.

进一步地,铠装光纤通过支撑架固定在前腔体内,前腔体和后腔体的腔体外壳材质为304不锈钢;在后腔体下端设有握柄、上端装有提把。Further, the armored optical fiber is fixed in the front cavity through a support frame. The cavity shells of the front cavity and the rear cavity are made of 304 stainless steel; there is a handle at the lower end of the rear cavity and a handle at the upper end.

利用上述基于光谱分析在线测量煤粉锅炉燃尽度的装置测量煤粉锅炉燃尽度的方法,主要包括如下步骤:The method of measuring the burnout degree of a pulverized coal boiler using the above-mentioned device for online measurement of the burnout degree of a pulverized coal boiler based on spectral analysis mainly includes the following steps:

S1:装配探测装置、使用串行总线连接计算机,将探测装置的前腔体插入观火孔;S1: Assemble the detection device, connect the computer using the serial bus, and insert the front cavity of the detection device into the fire observation hole;

S2:炉膛内部光线通过铠装光纤传到光谱仪,光谱仪采集电站煤粉炉燃烧状况的光谱图像,采集过程中调整合适的积分时间,图像数据采集完成后,图像信息传输至计算机,计算机上的程序通过算法进行数据处理;S2: The light inside the furnace is transmitted to the spectrometer through the armored optical fiber. The spectrometer collects spectral images of the combustion conditions of the pulverized coal furnace in the power station. The appropriate integration time is adjusted during the acquisition process. After the image data acquisition is completed, the image information is transmitted to the computer, and the program on the computer Data processing through algorithms;

S3:利用采集到的煤粉炉各层的光谱分布图,根据光谱辐射强度计算出炉膛横截面的温度和发射率分布图像,通过光谱发射率与温度、燃尽度的函数模型计算得到煤焦颗粒在不同温度、不同光谱发射率情况下的煤粉燃尽度;S3: Using the collected spectral distribution diagram of each layer of the pulverized coal furnace, calculate the temperature and emissivity distribution image of the furnace cross-section according to the spectral radiation intensity, and use the function model of spectral emissivity, temperature, and burnout degree Calculate the pulverized coal burnout degree of coal char particles at different temperatures and different spectral emissivities;

S4:改变探测装置的探头位置,重复上述步骤S1、S2、S3,得到不同工况下煤粉炉的温度以及发射率分布图,计算出煤粉燃尽度。S4: Change the probe position of the detection device, repeat the above steps S1, S2, and S3 to obtain the temperature and emissivity distribution diagram of the pulverized coal furnace under different working conditions, and calculate the burnout degree of the pulverized coal.

进一步地,步骤S3中提及函数模型是在如下步骤的基础上建立的:Further, in step S3, the function model is mentioned It is established based on the following steps:

1)根据热辐射定理,获取单颗粒煤焦的光谱辐射强度的表达式;1) According to the thermal radiation theorem, obtain the expression of the spectral radiation intensity of single particle coal char;

2)利用光谱仪采集煤焦颗粒200-1100nm波段范围内的辐射光谱;2) Use a spectrometer to collect the radiation spectrum of coal char particles in the 200-1100nm band;

3)将光谱响应带划分多个窄谱带,得到每个窄谱带中的光谱辐射强度并进行归一化处理;3) Divide the spectral response band into multiple narrow spectral bands, obtain the spectral radiation intensity in each narrow spectral band and perform normalization processing;

4)根据划分的可见光窄谱带,得到每个窄谱带中的黑体辐射强度并进行归一化处理;4) According to the divided narrow spectral bands of visible light, obtain the blackbody radiation intensity in each narrow spectral band and perform normalization processing;

5)归一化后的测量光谱辐射强度与归一化的相同温度下黑体辐射强度具有相似的分布特性,在不同温度下比较,并根据最小二乘法计算实际物体的光谱辐射强度和Planck黑体辐射强度之间的差异,较小的系数给出了更强的相关性;获取窄带光谱窗口中光谱强度曲线与普朗克黑体辐射曲线在不同温度下的最小距离,此时对应的温度即为当前光谱窗口中对应的测量温度;5) The normalized measured spectral radiation intensity and the normalized black body radiation intensity at the same temperature have similar distribution characteristics. Compare them at different temperatures and calculate the spectral radiation intensity and Planck black body radiation of the actual object according to the least squares method. The difference between intensities, a smaller coefficient gives a stronger correlation; obtain the minimum distance between the spectral intensity curve in the narrow-band spectral window and the Planck blackbody radiation curve at different temperatures, and the corresponding temperature at this time is the current The corresponding measured temperature in the spectral window;

6)将处理后的光谱辐射强度和黑体辐射强度相除,得到热辐射波段内的光谱发射率;6) Divide the processed spectral radiation intensity and blackbody radiation intensity to obtain the spectral emissivity in the thermal radiation band;

7)根据沿程取样法得到煤粉的燃尽度,根据已经得到的温度、发射率以及燃尽度,建立三者之间的关系,获得光谱发射率与温度、燃尽度的函数模型 7) Obtain the burnout degree of pulverized coal according to the along-process sampling method. Based on the obtained temperature, emissivity and burnout degree, establish the relationship between the three and obtain the function model of spectral emissivity, temperature and burnout degree.

进一步地,步骤1)中,根据热辐射定理,获取单颗粒煤焦的光谱辐射强度表示为:Further, in step 1), according to the thermal radiation theorem, the spectral radiation intensity of single particle coal char is obtained and expressed as:

式(1)中,Ibi,T)为黑体辐射强度,W/m-3;I(λi,T)为光谱辐射强度,W/m-3;ε(λi)为煤焦颗粒的光谱发射率;T为煤焦颗粒的温度,℃;C1为Planck第一辐射常数,1.1910×108W·μm4·m-2·sr-1;λi为波长,m;n为波长数目;C2为Planck第二辐射常数,1.4388×10- 2m·K。In formula (1), I bi , T) is the blackbody radiation intensity, W/m -3 ; I (λ i , T) is the spectral radiation intensity, W/m -3 ; ε (λ i ) is the coal Spectral emissivity of char particles; T is the temperature of char particles, ℃; C 1 is Planck’s first radiation constant, 1.1910×10 8 W·μm 4 ·m -2 ·sr -1 ; λ i is the wavelength, m; n is the number of wavelengths; C 2 is Planck’s second radiation constant, 1.4388×10 - 2 m·K.

进一步地,步骤3)中,将光谱响应带划分为M个窄带光谱窗口,每个窄谱带内有i个波长,对于第m个窄谱有Further, in step 3), the spectral response band is divided into M narrow-band spectral windows. There are i wavelengths in each narrow-band spectrum. For the m-th narrow spectrum, there are

Im=[I(λ1,Tm),I(λ2,Tm),…I(λi,Tm)],m=1,2,…M (2)I m =[I (λ 1 , T m ), I (λ 2 , T m ),...I (λ i , T m )], m=1, 2,...M (2)

式(2)中,Im为第m个窄谱带内的光谱辐射强度,W/m3,将窄谱带内的光谱辐射强度作归一化处理为:In formula (2), I m is the spectral radiation intensity in the m-th narrow spectrum band, W/m 3 . The spectral radiation intensity in the narrow spectrum band is normalized as:

式(3)中,I′(λi,Tm)为窄谱带区间内归一化后的光谱辐射强度分布;In formula (3), I′(λ i , T m ) is the normalized spectral radiation intensity distribution within the narrow band interval;

步骤4)中,标准Planck黑体辐射强度矩阵I′bi,Tm)在窄谱带内归一化处理为:In step 4), the standard Planck blackbody radiation intensity matrix I′ bi , T m ) is normalized in the narrow band as:

式(4)中,b表示黑体,T1,T2,…Tm表示煤焦颗粒可能的温度范围。In formula (4), b represents a black body, T 1 , T 2 ,...T m represents the possible temperature range of coal char particles.

进一步地,步骤5)中,根据最小二乘法计算得出最小值,具体计算如下所示:Further, in step 5), the minimum value is calculated according to the least squares method. The specific calculation is as follows:

对于任意元素n=1,2,…,N;最小距离对应的温度Tm的计算方法如下:For any element n=1, 2,...,N; the temperature T m corresponding to the minimum distance is calculated as follows:

T1,T2,…TN表示煤焦颗粒可能的温度范围。T 1 , T 2 ,...T N represent the possible temperature range of coal char particles.

进一步地,步骤6)中,热辐射波段内的光谱发射率为Further, in step 6), the spectral emissivity in the thermal radiation band is

进一步地,步骤7)中,根据沿程取样法得到煤粉的燃尽度具体公式如下:Further, in step 7), the specific formula for the burnout degree of pulverized coal is obtained according to the along-process sampling method as follows:

B为燃尽度,A为煤粉燃烧过程中的灰分质量分数,A0为煤粉初始的灰分质量分数,根据已经得到的温度、发射率以及燃尽度,建立三者之间的关系:B is the burnout degree, A is the ash mass fraction during the combustion process of pulverized coal, and A 0 is the initial ash mass fraction of pulverized coal. Based on the obtained temperature, emissivity and burnout degree, the relationship between the three is established:

设待定系数矩阵为Let the undetermined coefficient matrix be

则煤粉颗粒的燃尽度B可以表示为200~1100nm波段内的平均表面发射率和温度T的函数:Then the burnout degree B of pulverized coal particles can be expressed as the average surface emissivity in the 200-1100nm band and a function of temperature T:

其中,通过式(7)可以得到不同燃尽度Bm=[B1 B2 B3 … Bm]和燃烧温度Tm=[T1 T2 T3 … Tm]对应的煤粉颗粒在200~1100nm波段内的平均表面发射率通过二元非线性回归可以求得待定系数矩阵A,在检测锅炉煤粉燃尽度时,将通过式(6)和(7)测得的煤粉火焰燃烧温度和200~1100nm波段内的平均表面发射率带入式(9),即可求得炉膛内煤粉火焰燃尽度。in, Through formula (7), it can be obtained that the pulverized coal particles corresponding to different burnout degrees B m = [B 1 B 2 B 3 ... B m ] and combustion temperatures T m = [T 1 T 2 T 3 ... T m ] are in the range of 200 ~ Average surface emissivity in the 1100nm band The undetermined coefficient matrix A can be obtained through binary nonlinear regression. When detecting the burnout degree of boiler pulverized coal, the pulverized coal flame combustion temperature measured through equations (6) and (7) and the average value in the 200-1100nm band By bringing the surface emissivity into equation (9), the burnout degree of the pulverized coal flame in the furnace can be obtained.

相比于现有技术,本发明具有如下优点:Compared with the existing technology, the present invention has the following advantages:

1.本申请提出的基于光谱分析的煤粉锅炉燃尽度检测装置可以实现煤粉锅炉燃尽度的在线检测,根据煤焦在可见光波段(200nm-1100nm)的辐射光谱,通过光谱分析计算得到煤焦颗粒表面温度和发射率,获取煤焦颗粒在热辐射波段的光谱发射率分布,在已知温度和发射率的情况下,计算出煤焦燃尽度,并可在此基础上建立煤粉炉中不同高度、不同燃尽度之间的关系;1. The pulverized coal boiler burnout degree detection device proposed in this application based on spectral analysis can realize online detection of the pulverized coal boiler burnout degree. According to the radiation spectrum of coal char in the visible light band (200nm-1100nm), it is calculated through spectral analysis The surface temperature and emissivity of coal char particles are used to obtain the spectral emissivity distribution of coal char particles in the thermal radiation band. Under the condition of known temperature and emissivity, the coal char burnout degree can be calculated, and on this basis, the coal char burnout degree can be calculated. The relationship between different heights and different burnout degrees in the powder furnace;

2.与现有技术相比本申请公开方案可以实现在线实时检测,得到实时燃烧速率和表观动力学参数;2. Compared with the existing technology, the disclosed solution of this application can realize online real-time detection and obtain real-time combustion rate and apparent kinetic parameters;

3.本申请公开的探测装置可以深入锅炉观火孔内,获得较好的视野并保持后腔体内的光谱仪远离高温,通过计算机控制探测器后腔体内的光谱仪,即可采集光谱数据并计算煤粉燃尽度,使用便捷性有显著提升。3. The detection device disclosed in this application can go deep into the fire observation hole of the boiler to obtain a better field of view and keep the spectrometer in the rear cavity away from high temperatures. By controlling the spectrometer in the rear cavity of the detector through a computer, spectral data can be collected and calculated. The powder burns completely and the convenience of use is significantly improved.

附图说明Description of the drawings

图1是一种基于光谱分析在线测量煤粉锅炉燃尽度的装置的结构示意图;Figure 1 is a schematic structural diagram of a device for online measurement of burnout degree of pulverized coal boilers based on spectral analysis;

图2是在滴管炉上检测煤焦颗粒光谱信号实验装置示意图;Figure 2 is a schematic diagram of the experimental device for detecting spectral signals of coal char particles on a drop tube furnace;

图3为利用图1所示装置进行测量的现场测试简图;Figure 3 is a schematic diagram of a field test using the device shown in Figure 1 for measurement;

图4是现场实际测量图;Figure 4 is the actual measurement diagram on site;

图5是相同负荷下光谱响应曲线及发射率;Figure 5 shows the spectral response curve and emissivity under the same load;

图6是现场采集的火焰图像。Figure 6 is a flame image collected on site.

其中,1-探测装置,2-计算机;Among them, 1-detection device, 2-computer;

11-前腔体,12-后腔体,13-开孔,14-铠装光纤,15-支撑架,16-准直透镜,17-光谱仪,18-握柄,19-提把;11-front cavity, 12-rear cavity, 13-opening, 14-armored optical fiber, 15-support frame, 16-collimating lens, 17-spectrometer, 18-grip, 19-handle;

具体实施方式Detailed ways

下面结合附图对本发明的技术方案作进一步的说明,但并不局限于此,凡是对本发明技术方案进行修改或者等同替换,而不脱离本发明技术方案的精神和范围,均应涵盖在本发明的保护范围中。The technical solution of the present invention will be further described below in conjunction with the accompanying drawings, but it is not limited thereto. Any modification or equivalent replacement of the technical solution of the present invention without departing from the spirit and scope of the technical solution of the present invention shall be covered by the present invention. within the scope of protection.

为能成功可靠地检测到靠近炉膛中心的煤焦的燃尽度,本实施方式中公开一种基于光谱分析在线测量煤粉锅炉燃尽度的装置,其结构如图1所示,其主要由探测装置1和装有控制软件的计算机2组成。In order to successfully and reliably detect the burnout degree of coal coke near the center of the furnace, this embodiment discloses a device for online measurement of the burnout degree of pulverized coal boilers based on spectral analysis. Its structure is shown in Figure 1. It mainly consists of It consists of a detection device 1 and a computer 2 equipped with control software.

探测装置1包括前、后两个腔体,前腔体11和后腔体12一体成型制备,腔体外壳材质为304不锈钢,可以耐受高温。The detection device 1 includes two front and rear cavities. The front cavity 11 and the rear cavity 12 are integrally formed. The cavity shell is made of 304 stainless steel and can withstand high temperatures.

前腔体11为长条柱状结构以保证可以深入锅炉炉膛的中心位置,前腔体11远离后腔体12的侧面上设有开孔13,开孔13处装有保护镜头的石英镜片,在前腔体11内设有沿其长度方向延伸的铠装光纤14,铠装光纤14通过支撑架15固定在前腔体11内,铠装光纤14远离后腔体12的一端设有准直透镜16,准直透镜16的设置位置与开孔13位置对应,可以保证进入铠装光纤14的是探头正视方向的平行光。铠装光纤14的另一端与后腔体12内的光谱仪17相连。The front cavity 11 is a long columnar structure to ensure that it can penetrate into the center of the boiler furnace. There is an opening 13 on the side of the front cavity 11 away from the rear cavity 12. The opening 13 is equipped with a quartz lens to protect the lens. The front cavity 11 is provided with an armored optical fiber 14 extending along its length direction. The armored optical fiber 14 is fixed in the front cavity 11 through a support frame 15 . An end of the armored optical fiber 14 away from the rear cavity 12 is provided with a collimating lens. 16. The setting position of the collimating lens 16 corresponds to the position of the opening 13, which can ensure that the parallel light entering the armored optical fiber 14 is the parallel light in the direction in which the probe is facing. The other end of the armored optical fiber 14 is connected to the spectrometer 17 in the rear cavity 12 .

前腔体11伸入锅炉观火孔内,对准需要检测燃尽度的炉膛区域,可获得较好的视野并保证后腔体12内的光谱仪17能远离高温。光谱仪17通过串行总线与计算机2连接,光谱响应范围为200-1100nm,采集的光谱数据由计算机2记录并处理,计算煤粉燃尽度。The front cavity 11 extends into the boiler's flame viewing hole and is aligned with the furnace area where the burnout degree needs to be detected, thereby obtaining a better view and ensuring that the spectrometer 17 in the rear cavity 12 can stay away from high temperatures. The spectrometer 17 is connected to the computer 2 through a serial bus, and the spectral response range is 200-1100nm. The collected spectral data are recorded and processed by the computer 2 to calculate the burnout degree of the pulverized coal.

此外,为方便操作,在后腔体12下端设有握柄18、上端装有提把19,便于携带和检测。In addition, for the convenience of operation, a handle 18 is provided at the lower end of the rear cavity 12 and a handle 19 is provided at the upper end for easy carrying and inspection.

基于光谱分析计算煤粉燃尽度的原理如下:The principle of calculating the burnout degree of pulverized coal based on spectral analysis is as follows:

探测装置1采集到的光谱信号主要由炉膛内煤焦热辐射产生的连续光谱和碱金属特征光谱组成,计算光谱发射率时首先应进行光谱分析,先剔除碱金属特征光谱后,再利用多项式拟合的光谱分离算法,排除非煤焦热辐射的影响,得到煤焦热辐射产生的连续光谱。The spectral signal collected by the detection device 1 is mainly composed of the continuous spectrum generated by the thermal radiation of coal char in the furnace and the characteristic spectrum of alkali metals. When calculating the spectral emissivity, spectral analysis should first be performed. After eliminating the characteristic spectra of alkali metals, polynomials can be used to simulate The combined spectral separation algorithm eliminates the influence of non-coal thermal radiation and obtains the continuous spectrum produced by coal thermal radiation.

根据热辐射定理,单颗粒煤焦的光谱辐射强度可表示为:According to the thermal radiation theorem, the spectral radiation intensity of single particle coal char can be expressed as:

式(1)中,Ibi,T)为黑体辐射强度,W/m-3;I(λi,T)为光谱辐射强度,W/m-3;ε(λi)为煤焦颗粒的光谱发射率;T为煤焦颗粒的温度,℃;C1为Planck第一辐射常数,1.1910×108W·μm4·m-2·sr-1;λi为波长,m;n为波长数目;C2为Planck第二辐射常数,1.4388×10-2m·K。In formula (1), I bi , T) is the blackbody radiation intensity, W/m -3 ; I (λ i , T) is the spectral radiation intensity, W/m -3 ; ε (λ i ) is the coal Spectral emissivity of char particles; T is the temperature of char particles, ℃; C 1 is Planck’s first radiation constant, 1.1910×10 8 W·μm 4 ·m -2 ·sr -1 ; λ i is the wavelength, m; n is the number of wavelengths; C 2 is Planck’s second radiation constant, 1.4388×10- 2 m·K.

将光谱响应带划分为M个窄带光谱窗口,每个窄谱带内有i个波长,对于第m个窄谱有The spectral response band is divided into M narrow-band spectral windows. There are i wavelengths in each narrow spectral band. For the m-th narrow spectrum, there are

Im=[I(λ1,Tm),I(λ2,Tm),…I(λi,Tm)],m=1,2,…M (2)I m =[I (λ 1 , T m ), I (λ 2 , T m ),...I (λ i , T m )], m=1, 2,...M (2)

式(2)中,Im为第m个窄谱带内的光谱辐射强度,W/m3,将窄谱带内的光谱辐射强度作归一化处理为:In formula (2), I m is the spectral radiation intensity in the m-th narrow spectrum band, W/m 3 . The spectral radiation intensity in the narrow spectrum band is normalized as:

式(3)中,I′(λi,Tm)为窄谱带区间内归一化后的辐射强度分布,同理,在第m个窄谱带内归一化处理标准Planck黑体辐射强度矩阵为:In formula (3), I′(λ i , T m ) is the normalized radiation intensity distribution within the narrow spectrum band. In the same way, the standard Planck blackbody radiation intensity is normalized within the mth narrow spectrum band. The matrix is:

式(4)中,b表示黑体,T1,T2,…Tm表示煤焦颗粒可能的温度范围,在不同温度下比较,并根据最小二乘法计算得出最小值,具体计算如下所示:In formula (4), b represents a black body, T 1 , T 2 ,...T m represents the possible temperature range of coal char particles. Compare at different temperatures and calculate the minimum value according to the least squares method. The specific calculation is as follows :

对于任意元素n=1,2,…,N,使用最小二乘法来计算实际物体的光谱辐射强度和Planck黑体辐射强度之间的差异,曲线之间的误差越大,光谱仪测量的光谱辐射强度曲线与标准普朗克辐射强度曲线之间的相关性越弱。相反,较小的系数给出了更强的相关性。For any element n=1, 2,...,N, use the least squares method to calculate the difference between the spectral radiation intensity of the actual object and the Planck blackbody radiation intensity. The greater the error between the curves, the greater the spectral radiation intensity curve measured by the spectrometer. The correlation with the standard Planck radiation intensity curve is weaker. On the contrary, smaller coefficients give stronger correlations.

光谱窗口中的距离差在最小化时,对应的温度TN为当前光谱窗口中对应的测量温度,等式(6)中T1,T2,…,TN表示煤焦颗粒可能的温度范围,这N个元素表示窄带光谱窗口中测量光谱强度曲线与普朗克黑体辐射曲线在不同温度下的距离,即最小距离对应的温度就为所求温度:When the distance difference in the spectrum window is minimized, the corresponding temperature T N is the corresponding measured temperature in the current spectrum window. In equation (6), T 1 , T 2 ,..., T N represent the possible temperature range of the coal char particles. , these N elements represent the distance between the measured spectral intensity curve in the narrow-band spectral window and the Planck blackbody radiation curve at different temperatures, that is, the temperature corresponding to the minimum distance is the desired temperature:

方程(4)中矩阵的每一行,表示不同波长下的归一化标准普朗克辐射强度,而每一列表示同一波长下不同温度下的标准普朗克辐射强度,则热辐射波段内的光谱发射率为Each row of the matrix in equation (4) represents the normalized standard Planck radiation intensity at different wavelengths, and each column represents the standard Planck radiation intensity at the same wavelength at different temperatures, then the spectrum in the thermal radiation band Emissivity

该实施方式需要通过上述算法得到不同温度、不同燃尽度下煤焦颗粒的光谱发射率,通过在滴管炉上实验采集到所需的数据,实验将在图2所示的装置上展开,具体的实验步骤如下:This implementation requires obtaining the spectral emissivity of coal particles at different temperatures and different burnout degrees through the above algorithm. The required data are collected experimentally on a dropper furnace. The experiment will be carried out on the device shown in Figure 2. The specific experimental steps are as follows:

1.选用国内常用的五种动力烟煤:神东煤(不粘煤、长焰煤)、大同煤(弱粘煤)、准格尔煤(长焰煤)、铁法煤(长焰煤)、靖远煤(不粘煤),利用管式炉制备不同燃尽度的煤焦颗粒,将制备好的煤焦筛分成单颗粒;1. Select five commonly used domestic bituminous coals: Shendong coal (non-caking coal, long-flame coal), Datong coal (weak-caking coal), Zhungeer coal (long-flame coal), Tiefa coal (long-flame coal) , Jingyuan coal (non-sticking coal), uses a tube furnace to prepare coal coke particles with different burnout degrees, and sieves the prepared coal coke into single particles;

2.利用滴管炉生成高温环境,将炉子设定为N2气氛,设定炉温为1400K,利用铂铑细丝热电偶测量N2气氛下炉内反应段温度分布;2. Use a dropper furnace to generate a high-temperature environment, set the furnace to N2 atmosphere, set the furnace temperature to 1400K, and use a platinum-rhodium filament thermocouple to measure the temperature distribution of the reaction section in the furnace under N2 atmosphere;

3.利用注射器向单颗粒注入孔注入单颗粒煤焦,使用光纤光谱仪从滴管炉的可视化窗口采集光谱数据;3. Use a syringe to inject single particle coal char into the single particle injection hole, and use a fiber spectrometer to collect spectral data from the visualization window of the dropper furnace;

4.调整空气的比例,实现对温度的调控,每个工况下滴管炉的可视化窗口位置的温度由铂铑细丝热电偶进行测量,用于验证光谱测温的准确性;4. Adjust the proportion of air to achieve temperature control. The temperature at the visual window position of the dropper furnace under each working condition is measured by a platinum-rhodium filament thermocouple to verify the accuracy of spectral temperature measurement;

5.测量得到不同温度下的光谱数据,利用上文所述的算法得到各个工况下的光谱发射率分布。根据沿程取样法得到煤粉的燃尽度具体公式如下:5. Measure the spectral data at different temperatures, and use the algorithm described above to obtain the spectral emissivity distribution under each working condition. The specific formula for the burnout degree of pulverized coal based on the along-process sampling method is as follows:

B为燃尽度,A为煤粉燃烧过程中的灰分质量分数,A0为煤粉初始的灰分质量分数。B is the burnout degree, A is the ash mass fraction during the combustion process of pulverized coal, and A 0 is the initial ash mass fraction of pulverized coal.

根据已经得到的温度、发射率以及燃尽度,建立三者之间的关系:Based on the obtained temperature, emissivity and burnout degree, establish the relationship between the three:

设待定系数矩阵为Let the undetermined coefficient matrix be

则煤粉颗粒的燃尽度B可以表示为200~1100nm波段内的平均表面发射率和温度T的函数:Then the burnout degree B of pulverized coal particles can be expressed as the average surface emissivity in the 200-1100nm band and a function of temperature T:

其中,通过式(7)可以得到不同燃尽度Bm=[B1 B2 B3…Bm]和燃烧温度Tm=[T1 T2 T3…Tm]对应的煤粉颗粒在200~1100nm波段内的平均表面发射率通过二元非线性回归可以求得待定系数矩阵A,在检测锅炉煤粉燃尽度时,将通过式(6)和(7)测得的煤粉火焰燃烧温度和200~1100nm波段内的平均表面发射率带入式(9),可以求得炉膛内煤粉火焰燃尽度。in, Through formula (7), it can be obtained that the pulverized coal particles corresponding to different burnout degrees B m =[B 1 B 2 B 3 ...B m ] and combustion temperatures T m =[T 1 T 2 T 3 ...T m ] are in the range of 200~ Average surface emissivity in the 1100nm band The undetermined coefficient matrix A can be obtained through binary nonlinear regression. When detecting the burnout degree of boiler pulverized coal, the pulverized coal flame combustion temperature measured through equations (6) and (7) and the average value in the 200-1100nm band The surface emissivity is brought into equation (9), and the burnout degree of the pulverized coal flame in the furnace can be obtained.

6.重复不同的煤种实验,可以直接求解不同煤粉的燃尽度。6. By repeating experiments with different coal types, the burnout degree of different pulverized coals can be directly calculated.

上述燃尽度测量方法在现场测量时可包括以下步骤(可参考图3):The above burnout degree measurement method may include the following steps during on-site measurement (refer to Figure 3):

S1:在安装好煤粉炉测量装置、使用串行总线连接计算机后,整个系统开始运行,将测量装置装有铠装光纤的前腔体的前端插入观火孔,为防止观火孔喷出的高温气体或煤粉灼伤操作人员,可在观火孔处安装阻火板;S1: After installing the pulverized coal furnace measuring device and connecting to the computer using the serial bus, the entire system starts to run. Insert the front end of the front cavity of the measuring device equipped with armored optical fiber into the fire observation hole. In order to prevent the fire observation hole from erupting If the operator is burned by high-temperature gas or pulverized coal, a fire-retardant plate can be installed at the fire observation hole;

S2:炉膛内部光线通过铠装光纤传到光谱仪,光谱仪采集电站煤粉炉燃烧状况的光谱图像,采集过程中可调整合适的积分时间,以便保证光谱仪采集到的光谱图像数据非饱和,并且具有高的信噪比,图像数据采集完成后,通过串行总线传输功能把图像信息传输至计算机,计算机上的程序通过算法进行数据处理;S2: The light inside the furnace is transmitted to the spectrometer through the armored optical fiber. The spectrometer collects the spectral image of the combustion status of the pulverized coal furnace in the power station. The appropriate integration time can be adjusted during the acquisition process to ensure that the spectral image data collected by the spectrometer is not saturated and has high performance. After the image data collection is completed, the image information is transmitted to the computer through the serial bus transmission function, and the program on the computer performs data processing through algorithms;

S3:利用采集到的煤粉炉各层的光谱分布图,根据光谱辐射强度计算出炉膛横截面的温度和发射率分布图像,利用上述实验得到的光谱发射率与温度、燃尽度的函数模型计算得到煤焦颗粒在不同温度、不同光谱发射率情况下的煤粉燃尽度。S3: Use the collected spectral distribution diagram of each layer of the pulverized coal furnace to calculate the temperature and emissivity distribution image of the furnace cross-section based on the spectral radiation intensity. Use the function model of spectral emissivity, temperature, and burnout degree obtained from the above experiments. The pulverized coal burnout degree of coal char particles under different temperatures and different spectral emissivities was calculated.

S4:改变检测装置探头位置,重复上述步骤1、2、3,得到不同工况下煤粉炉的温度以及发射率分布图,计算出煤粉燃尽度。S4: Change the probe position of the detection device and repeat the above steps 1, 2, and 3 to obtain the temperature and emissivity distribution diagrams of the pulverized coal furnace under different working conditions, and calculate the burnout degree of the pulverized coal.

图4位为现场测量图,根据光谱仪采集的现场数据,将电信号转化为辐射强度,然后经过黑体炉的标定,转化为绝对辐射强度,利用上述算法,计算火焰温度和发射率,图5为从现场采集的光谱数据中挑选的相同负荷下六条典型的光谱曲线以及经过计算所得的不同波长下火焰的光谱发射率。Figure 4 shows the on-site measurement chart. Based on the on-site data collected by the spectrometer, the electrical signal is converted into radiation intensity, and then converted into absolute radiation intensity through the calibration of the blackbody furnace. The above algorithm is used to calculate the flame temperature and emissivity. Figure 5 is Six typical spectral curves under the same load were selected from the spectral data collected on site and the calculated spectral emissivity of the flame at different wavelengths.

从图5中可以看出,光谱曲线上有几个光谱凸起,这些凸起被分布在光谱曲线的窄波段范围内。根据光谱数据库查询,可以获知凸起位置的辐射光谱为碱金属元素受热激发出的原子发射谱线,其中590nm处的特征谱线来自碱金属Na,在766.5nm和769.9nm处的特征谱线来自碱金属K。As can be seen from Figure 5, there are several spectral bumps on the spectral curve, and these bumps are distributed within the narrow band range of the spectral curve. According to the query of the spectral database, it can be known that the radiation spectrum at the convex position is the atomic emission spectrum line excited by the heat of the alkali metal element. The characteristic spectral line at 590nm comes from the alkali metal Na, and the characteristic spectral lines at 766.5nm and 769.9nm come from Alkali metal K.

图6所示火焰图像为不同积分时间下的图像,从中可以看出,根据积分时间的不同,火焰的明亮程度也不同,根据算法得出温度及平均发射率如下:The flame images shown in Figure 6 are images under different integration times. It can be seen that the brightness of the flame is different depending on the integration time. According to the algorithm, the temperature and average emissivity are as follows:

以上为一层火焰的光谱数据计算结果,根据实验建立的煤焦颗粒200nm-1100nm波段内光谱发射率与温度、燃尽度的函数模型计算燃尽度。根据本发明提出的检测装置跟方法可以实现炉膛内不同高度和区域燃尽度的在线检测,并按照不同工况建立不同高度对应的燃尽度分布图象,经过计算机处理后可以进一步得到炉内燃尽度与高度的关系。The above are the calculation results of the spectral data of a layer of flame. Based on the experimentally established functional model of spectral emissivity, temperature and burnout degree of coal char particles in the 200nm-1100nm band Calculate burndown. According to the detection device and method proposed by the present invention, online detection of burnout degrees at different heights and regions in the furnace can be achieved, and burnout degree distribution images corresponding to different heights can be established according to different working conditions. After computer processing, the burnout degree in the furnace can be further obtained. The relationship between degree and height.

以上所述仅为本发明的实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书及附图内容所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本发明的专利保护范围内。The above are only examples of the present invention, and do not limit the patent scope of the present invention. Any equivalent structure or equivalent process transformation made by using the description and drawings of the present invention, or directly or indirectly applied to other related technologies fields are equally included in the scope of patent protection of the present invention.

Claims (3)

1.一种基于光谱分析在线测量煤粉锅炉燃尽度的装置测量煤粉锅炉燃尽度的方法,其特征在于,装置包括探测装置和装有控制软件的计算机;1. A method for measuring the burnout degree of a pulverized coal boiler using a device for online measuring the burnout degree of a pulverized coal boiler based on spectral analysis, characterized in that the device includes a detection device and a computer equipped with control software; 探测装置包括前、后两个腔体,在前腔体远离后腔体的侧面上设有开孔,在前腔体内设有沿其长度方向延伸的铠装光纤,铠装光纤远离后腔体的一端与开孔对应的位置设有准直透镜,铠装光纤的另一端与后腔体内的光谱仪相连,光谱仪与计算机间通过串行总线连接通讯;The detection device includes two front and rear cavities. An opening is provided on the side of the front cavity away from the rear cavity. An armored optical fiber extending along its length direction is provided in the front cavity. The armored optical fiber is located away from the rear cavity. One end of the optical fiber is equipped with a collimating lens at the position corresponding to the opening, and the other end of the armored optical fiber is connected to the spectrometer in the rear cavity. The spectrometer and the computer communicate through a serial bus connection; 测量过程包括如下步骤:The measurement process includes the following steps: S1:装配探测装置、使用串行总线连接计算机,将探测装置的前腔体插入观火孔;S1: Assemble the detection device, connect the computer using the serial bus, and insert the front cavity of the detection device into the fire observation hole; S2:炉膛内部光线通过铠装光纤传到光谱仪,光谱仪采集电站煤粉炉燃烧状况的光谱图像,采集过程中调整合适的积分时间,图像数据采集完成后,图像信息传输至计算机,计算机上的程序通过算法进行数据处理;S2: The light inside the furnace is transmitted to the spectrometer through the armored optical fiber. The spectrometer collects spectral images of the combustion conditions of the pulverized coal furnace in the power station. The appropriate integration time is adjusted during the acquisition process. After the image data acquisition is completed, the image information is transmitted to the computer, and the program on the computer Data processing through algorithms; S3:利用采集到的煤粉炉各层的光谱分布图,根据光谱辐射强度计算出炉膛横截面的温度和发射率分布图像,通过光谱发射率与温度、燃尽度的函数模型计算得到煤焦颗粒在不同温度、不同光谱发射率情况下的煤粉燃尽度;S3: Using the collected spectral distribution diagram of each layer of the pulverized coal furnace, calculate the temperature and emissivity distribution image of the furnace cross-section according to the spectral radiation intensity, and use the function model of spectral emissivity, temperature, and burnout degree Calculate the pulverized coal burnout degree of coal char particles at different temperatures and different spectral emissivities; S4:改变探测装置的探头位置,重复上述步骤S1、S2、S3,得到不同工况下煤粉炉的温度以及发射率分布图,计算出煤粉燃尽度;S4: Change the probe position of the detection device, repeat the above steps S1, S2, and S3 to obtain the temperature and emissivity distribution diagram of the pulverized coal furnace under different working conditions, and calculate the burnout degree of the pulverized coal; 步骤S3中提及函数模型是在如下步骤的基础上建立的:Function model mentioned in step S3 It is established based on the following steps: 1)根据热辐射定理,获取单颗粒煤焦的光谱辐射强度的表达式;1) According to the thermal radiation theorem, obtain the expression of the spectral radiation intensity of single particle coal char; 2)利用光谱仪采集煤焦颗粒200-1100nm波段范围内的辐射光谱;2) Use a spectrometer to collect the radiation spectrum of coal char particles in the 200-1100nm band; 3)将光谱响应带划分多个窄谱带,得到每个窄谱带中的光谱辐射强度并进行归一化处理;3) Divide the spectral response band into multiple narrow spectral bands, obtain the spectral radiation intensity in each narrow spectral band and perform normalization processing; 4)根据划分的可见光窄谱带,得到每个窄谱带中的黑体辐射强度并进行归一化处理;4) According to the divided narrow spectral bands of visible light, obtain the blackbody radiation intensity in each narrow spectral band and perform normalization processing; 5)归一化后的测量光谱辐射强度与归一化的相同温度下黑体辐射强度具有相似的分布特性,在不同温度下比较,并根据最小二乘法计算实际物体的光谱辐射强度和Planck黑体辐射强度之间的差异,较小的系数给出了更强的相关性;获取窄带光谱窗口中光谱强度曲线与普朗克黑体辐射曲线在不同温度下的最小距离,此时对应的温度即为当前光谱窗口中对应的测量温度;5) The normalized measured spectral radiation intensity and the normalized black body radiation intensity at the same temperature have similar distribution characteristics. Compare them at different temperatures and calculate the spectral radiation intensity and Planck black body radiation of the actual object according to the least squares method. The difference between intensities, a smaller coefficient gives a stronger correlation; obtain the minimum distance between the spectral intensity curve in the narrow-band spectral window and the Planck blackbody radiation curve at different temperatures, and the corresponding temperature at this time is the current The corresponding measured temperature in the spectral window; 6)将处理后的光谱辐射强度和黑体辐射强度相除,得到热辐射波段内的光谱发射率;6) Divide the processed spectral radiation intensity and blackbody radiation intensity to obtain the spectral emissivity in the thermal radiation band; 7)根据沿程取样法得到煤粉的燃尽度,根据已经得到的温度、发射率以及燃尽度,建立三者之间的关系,获得光谱发射率与温度、燃尽度的函数模型 7) Obtain the burnout degree of pulverized coal according to the along-process sampling method. Based on the obtained temperature, emissivity and burnout degree, establish the relationship between the three and obtain the function model of spectral emissivity, temperature and burnout degree. 步骤1)中,根据热辐射定理,获取单颗粒煤焦的光谱辐射强度表示为:In step 1), according to the thermal radiation theorem, the spectral radiation intensity of single particle coal char is obtained as: 式(1)中,Ibi,T)为黑体辐射强度,W/m-3;I(λi,T)为光谱辐射强度,W/m-3;ε(λi)为煤焦颗粒的光谱发射率;T为煤焦颗粒的温度,℃;C1为Planck第一辐射常数,1.1910×108W·μm4·m-2·sr-1;λi为波长,m;n为波长数目;C2为Planck第二辐射常数,1.4388×10-2m·K;In formula (1), I bi , T) is the blackbody radiation intensity, W/m -3 ; I (λ i , T) is the spectral radiation intensity, W/m -3 ; ε (λ i ) is the coal Spectral emissivity of char particles; T is the temperature of char particles, ℃; C 1 is Planck’s first radiation constant, 1.1910×10 8 W·μm 4 ·m -2 ·sr -1 ; λ i is the wavelength, m; n is the number of wavelengths; C 2 is Planck’s second radiation constant, 1.4388×10 -2 m·K; 步骤3)中,将光谱响应带划分为M个窄带光谱窗口,每个窄谱带内有i个波长,对于第m个窄谱有In step 3), the spectral response band is divided into M narrow-band spectral windows. There are i wavelengths in each narrow-band spectrum. For the m-th narrow spectrum, there are Im=[I(λ1,Tm),I(λ2,Tm),…I(λi,Tm)],m=1,2,…M (2)I m =[I (λ 1 , T m ), I (λ 2 , T m ),...I (λ i , T m )], m=1, 2,...M (2) 式(2)中,Im为第m个窄谱带内的光谱辐射强度,W/m3,将窄谱带内的光谱辐射强度作归一化处理为:In formula (2), I m is the spectral radiation intensity in the m-th narrow spectrum band, W/m 3 . The spectral radiation intensity in the narrow spectrum band is normalized as: 式(3)中,I′(λi,Tm)为窄谱带区间内归一化后的光谱辐射强度分布;In formula (3), I′(λ i , T m ) is the normalized spectral radiation intensity distribution within the narrow band interval; 步骤4)中,标准Planck黑体辐射强度矩阵I′bi,Tm)在窄谱带内归一化处理为:In step 4), the standard Planck blackbody radiation intensity matrix I′ bi , T m ) is normalized in the narrow band as: 式(4)中,b表示黑体,T1,T2,…Tm表示煤焦颗粒可能的温度范围;In formula (4), b represents a black body, T 1 , T 2 ,...T m represents the possible temperature range of coal char particles; 步骤5)中,根据最小二乘法计算得出最小值,具体计算如下所示:In step 5), the minimum value is calculated according to the least squares method. The specific calculation is as follows: 对于任意元素n=1,2,…,N;最小距离对应的温度Tm的计算方法如下:For any element n=1, 2,...,N; the temperature T m corresponding to the minimum distance is calculated as follows: T1,T2,…TN表示煤焦颗粒可能的温度范围;T 1 , T 2 ,...T N represent the possible temperature range of coal char particles; 步骤6)中,热辐射波段内的光谱发射率为In step 6), the spectral emissivity in the thermal radiation band is 步骤7)中,根据沿程取样法得到煤粉的燃尽度具体公式如下:In step 7), the specific formula for the burnout degree of pulverized coal is obtained according to the along-process sampling method as follows: B为燃尽度,A为煤粉燃烧过程中的灰分质量分数,A0为煤粉初始的灰分质量分数,根据已经得到的温度、发射率以及燃尽度,建立三者之间的关系:B is the burnout degree, A is the ash mass fraction during the combustion process of pulverized coal, and A 0 is the initial ash mass fraction of pulverized coal. Based on the obtained temperature, emissivity and burnout degree, the relationship between the three is established: 设待定系数矩阵为Let the undetermined coefficient matrix be 则煤粉颗粒的燃尽度B可以表示为200~1100nm波段内的平均表面发射率和温度T的函数:Then the burnout degree B of pulverized coal particles can be expressed as the average surface emissivity in the 200-1100nm band and a function of temperature T: 其中, in, 通过式(7)可以得到不同燃尽度Bm=[B1 B2 B3 … Bm]和燃烧温度Tm[=T1 T2 T3 … Tm]对应的煤粉颗粒在200~1100nm波段内的平均表面发射率通过二元非线性回归可以求得待定系数矩阵A,在检测锅炉煤粉燃尽度时,将通过式(6)和(7)测得的煤粉火焰燃烧温度和200~1100nm波段内的平均表面发射率带入式(9),即可求得炉膛内煤粉火焰燃尽度。Through formula (7), it can be obtained that the pulverized coal particles corresponding to different burnout degrees B m =[B 1 B 2 B 3 ... B m ] and combustion temperatures T m [=T 1 T 2 T 3 ... T m ] are in the range of 200~ Average surface emissivity in the 1100nm band The undetermined coefficient matrix A can be obtained through binary nonlinear regression. When detecting the burnout degree of boiler pulverized coal, the pulverized coal flame combustion temperature measured through equations (6) and (7) and the average value in the 200-1100nm band By bringing the surface emissivity into equation (9), the burnout degree of the pulverized coal flame in the furnace can be obtained. 2.如权利要求1所述的一种基于光谱分析在线测量煤粉锅炉燃尽度的装置测量煤粉锅炉燃尽度的方法,其特征在于,开孔处装有石英镜片。2. A method for measuring the burnout degree of a pulverized coal boiler using a device for online measuring the burnout degree of a pulverized coal boiler based on spectral analysis as claimed in claim 1, characterized in that a quartz lens is installed at the opening. 3.如权利要求1所述的一种基于光谱分析在线测量煤粉锅炉燃尽度的装置测量煤粉锅炉燃尽度的方法,其特征在于,铠装光纤通过支撑架固定在前腔体内,前腔体和后腔体的腔体外壳材质为304不锈钢;在后腔体下端设有握柄、上端装有提把。3. A method for measuring the burnout degree of a pulverized coal boiler based on a device for online measuring the burnout degree of a pulverized coal boiler based on spectral analysis as claimed in claim 1, characterized in that the armored optical fiber is fixed in the front cavity through a support frame, The cavity shells of the front cavity and the rear cavity are made of 304 stainless steel; there is a handle at the lower end of the rear cavity and a carrying handle at the upper end.
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