CN114016017B - Method for laser cladding copper alloy on cast iron surface and surface structure of explosion-proof impeller - Google Patents
Method for laser cladding copper alloy on cast iron surface and surface structure of explosion-proof impeller Download PDFInfo
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- 238000004372 laser cladding Methods 0.000 title claims abstract description 98
- 238000000034 method Methods 0.000 title claims abstract description 84
- 229910001018 Cast iron Inorganic materials 0.000 title claims abstract description 68
- 229910000881 Cu alloy Inorganic materials 0.000 title claims abstract description 58
- 239000010410 layer Substances 0.000 claims abstract description 55
- 230000007704 transition Effects 0.000 claims abstract description 36
- 239000002346 layers by function Substances 0.000 claims abstract description 27
- 229910000640 Fe alloy Inorganic materials 0.000 claims abstract description 14
- BIJOYKCOMBZXAE-UHFFFAOYSA-N chromium iron nickel Chemical compound [Cr].[Fe].[Ni] BIJOYKCOMBZXAE-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims description 49
- 229910000816 inconels 718 Inorganic materials 0.000 claims description 25
- 229910001141 Ductile iron Inorganic materials 0.000 claims description 19
- 238000010583 slow cooling Methods 0.000 claims description 17
- 229910001060 Gray iron Inorganic materials 0.000 claims description 14
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000000956 alloy Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 229910001120 nichrome Inorganic materials 0.000 claims description 6
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical class [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000000788 chromium alloy Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910000599 Cr alloy Inorganic materials 0.000 claims description 2
- 229910000570 Cupronickel Inorganic materials 0.000 claims description 2
- 229910001037 White iron Inorganic materials 0.000 claims description 2
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 2
- GXDVEXJTVGRLNW-UHFFFAOYSA-N [Cr].[Cu] Chemical compound [Cr].[Cu] GXDVEXJTVGRLNW-UHFFFAOYSA-N 0.000 claims description 2
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 claims description 2
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000005266 casting Methods 0.000 abstract description 3
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 18
- 239000000463 material Substances 0.000 description 11
- 238000005336 cracking Methods 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 238000005253 cladding Methods 0.000 description 7
- 230000007547 defect Effects 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 7
- 125000004122 cyclic group Chemical group 0.000 description 6
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 238000002310 reflectometry Methods 0.000 description 5
- 238000012876 topography Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229910019589 Cr—Fe Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- -1 NiCrBSi Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000009689 gas atomisation Methods 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
- C23C24/10—Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
- C23C24/103—Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
- C23C24/106—Coating with metal alloys or metal elements only
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/02—Selection of particular materials
- F04D29/023—Selection of particular materials especially adapted for elastic fluid pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/26—Rotors specially for elastic fluids
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
Description
技术领域technical field
本发明属于激光熔覆表面改性技术领域,具体涉及一种铸铁表面激光熔覆铜合金的方法及防爆叶轮表面结构。The invention belongs to the technical field of laser cladding surface modification, in particular to a method for laser cladding copper alloy on the surface of cast iron and a surface structure of an explosion-proof impeller.
背景技术Background technique
公开该背景技术部分的信息仅仅旨在增加对本发明的总体背景的理解,而不必然被视为承认或以任何形式暗示该信息构成已经成为本领域一般技术人员所公知的现有技术。The information disclosed in this Background section is only for enhancement of understanding of the general background of the invention and should not necessarily be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person of ordinary skill in the art.
要实现鼓风机在复杂环境中安全高效运转,叶轮是关键,而当风机内部叶轮与其他相对运动部件之间发生动或静摩擦以及相互碰撞后所产生的炙热颗粒,会导致机械火花或高温表面等现象时,极易引起爆炸等安全事故。To realize the safe and efficient operation of the blower in a complex environment, the impeller is the key, and when dynamic or static friction occurs between the impeller and other relatively moving parts inside the blower, as well as the hot particles generated after the collision with each other, it will lead to mechanical sparks or high temperature surfaces and other phenomena It is very easy to cause safety accidents such as explosions.
目前鼓风机非防爆叶轮一般采用铸铁制造,而防爆叶轮多采用铜合金整体制造以避免碰撞导致的火花的出现,导致防爆风机价格昂贵,资源消耗巨大。而铸铁表面激光熔覆铜合金层存在成型困难的问题,导致成型后存在较多缺陷,使用质量下降。At present, the non-explosion-proof impeller of the blower is generally made of cast iron, while the explosion-proof impeller is mostly made of copper alloy as a whole to avoid the occurrence of sparks caused by collision, which makes the explosion-proof fan expensive and consumes huge resources. However, the laser cladding copper alloy layer on the surface of cast iron has the problem of difficulty in forming, which leads to many defects after forming, and the quality of use is reduced.
发明内容SUMMARY OF THE INVENTION
针对上述现有技术中存在的问题,本发明的目的是提供一种铸铁表面激光熔覆铜合金的方法及防爆叶轮表面结构。In view of the above problems in the prior art, the purpose of the present invention is to provide a method for laser cladding copper alloy on the surface of cast iron and the surface structure of the explosion-proof impeller.
为了解决以上技术问题,本发明的技术方案为:In order to solve the above technical problems, the technical scheme of the present invention is:
第一方面,一种铸铁表面激光熔覆铜合金的方法,所述方法为:A first aspect, a method for laser cladding copper alloy on cast iron surface, the method is:
在铸铁表面进行镍铬铁合金过渡层的激光熔覆,在铸铁表面形成镍铬铁合金过渡层;Carry out laser cladding of Nichrome transition layer on the surface of cast iron, and form Nichrome transition layer on the surface of cast iron;
然后在镍铬铁合金过渡层上进行铜合金功能层的激光熔覆。Laser cladding of the copper alloy functional layer is then performed on the Nichrome transition layer.
在铸铁表面与铜合金层之间,通过激光熔覆的工艺形成镍铬铁合金过渡层,镍铬铁合金起到连接铸铁与铜合金的作用,相比于直接在铸铁表面激光熔覆形成铜合金层,能够使各层的界面处的冶金结合性大大增强,界面结合强度大于铸铁本身强度。Between the cast iron surface and the copper alloy layer, a Ni-Cr-Fe alloy transition layer is formed by the laser cladding process. The Ni-Cr-Fe alloy plays the role of connecting the cast iron and the copper alloy, compared to the direct laser cladding on the cast iron surface to form the copper alloy layer , which can greatly enhance the metallurgical bonding at the interface of each layer, and the bonding strength of the interface is greater than the strength of the cast iron itself.
由于铸铁与铜合金之间结晶过程中二者原子极强的排斥作用以及铜合金对激光的高反射率,激光熔覆技术存在对高反射铜材料难成型、高含碳量铸铁类材料易开裂、结合界面处有气孔裂纹缺陷等问题。通过激光熔覆方法,形成的表层结构铸铁与镍铬铁合金界面以及镍铬铁合金与铜合金界面处组织均匀致密,无气孔、裂纹缺陷。Due to the strong repulsion between the atoms of the cast iron and the copper alloy during the crystallization process and the high reflectivity of the copper alloy to the laser, the laser cladding technology is difficult to form the high-reflection copper material, and the high-carbon content cast iron material is easy to crack. , There are problems such as porosity and crack defects at the bonding interface. Through the laser cladding method, the surface structure at the interface of cast iron and nickel-chromium-iron alloy and at the interface of nickel-chromium-iron alloy and copper alloy are uniform and dense, and have no pores and crack defects.
在本发明的一些实施方式中,所述铜合金为铜镍合金、铜锌合金、铜锡合金、铜铬合金中的一种。所述铜合金具有较强的耐磨性能,能够提高叶轮表面的耐高温性能,所述铜锡合金的耐火花的性能更好。进一步为铜锡合金;CuSn15、CuSn10、CuSn12、CuSn20、CuSn30等;优选为CuSn15、CuSn10、CuSn12。In some embodiments of the present invention, the copper alloy is one of a copper-nickel alloy, a copper-zinc alloy, a copper-tin alloy, and a copper-chromium alloy. The copper alloy has strong wear resistance and can improve the high temperature resistance of the surface of the impeller, and the copper-tin alloy has better spark resistance. Further, it is copper-tin alloy; CuSn15, CuSn10, CuSn12, CuSn20, CuSn30, etc.; preferably CuSn15, CuSn10, CuSn12.
在本发明的一些实施方式中,所述铸铁包括灰口铸铁、白口铸铁、球磨铸铁、蠕墨铸铁、合金铸铁中的一种。所述铸铁为鼓风机中常用的叶轮材质,所述鼓风机还可以为引风机、送风机等。In some embodiments of the present invention, the cast iron includes one of gray cast iron, white cast iron, ductile cast iron, vermicular graphite cast iron, and alloy cast iron. The cast iron is a commonly used impeller material in a blower, and the blower can also be an induced draft fan, a blower or the like.
在本发明的一些实施方式中,所述镍铬铁合金为Inconel 718。所述镍铬铁合金与叶轮的铸铁具有较好的匹配性。选择Inconel718作为过渡层的原因为:与NiCrBSi等镍基合金相比,Inconel718与基体及铜合金之间的润湿性更好,热膨胀系数位于二者之间,显微硬度与二者均相差不大,从而使得界面平整光滑,无裂纹、孔洞等缺陷,界面结合强度也较高。这解决了铜合金与铸铁结合性差导致的翘曲、脱落等问题,同时与铜合金直接沉积在铸铁上相比使得铜合金更易成型,降低由于铜合金的高反射率造成的材料难成型性。In some embodiments of the invention, the Inconel 718 is Inconel. The nickel-chromium-iron alloy has good matching with the cast iron of the impeller. The reason for choosing Inconel718 as the transition layer is: Compared with Ni-based alloys such as NiCrBSi, Inconel718 has better wettability with the matrix and copper alloy, the thermal expansion coefficient is between the two, and the microhardness is similar to the two. Therefore, the interface is smooth and smooth, without defects such as cracks and holes, and the interface bonding strength is also high. This solves the problems of warping and shedding caused by poor bonding between copper alloy and cast iron, and at the same time, compared with the direct deposition of copper alloy on cast iron, it makes copper alloy easier to form, and reduces the difficulty of forming the material due to the high reflectivity of copper alloy.
在本发明之前,并没有防爆叶轮采用铸铁表面制备铜合金这种设计方法,均为采用铜合金整体铸造的方式进行生产。在铸铁上制备铜合金的研究也较少,因为铸铁本身的硬脆性和铜合金的高反射率使得其很难成形,本发明通过预热缓冷、Inconel 718过渡层添加及参数优化成功制备Before the present invention, there is no design method in which the explosion-proof impeller adopts the cast iron surface to prepare the copper alloy, all of which are produced by the method of integral casting of the copper alloy. There is also less research on the preparation of copper alloys on cast iron, because the hard and brittle cast iron itself and the high reflectivity of copper alloys make it difficult to form.
在本发明的一些实施方式中,所述镍铬铁合金粉末粒径介于50~150μm。In some embodiments of the present invention, the particle size of the nickel-chromium-iron alloy powder ranges from 50 to 150 μm.
在本发明的一些实施方式中,所述铜合金功能层的激光熔覆是利用铜合金粉末进行的,所述铜合金粉末的粒径介于75~150μm。In some embodiments of the present invention, the laser cladding of the copper alloy functional layer is performed using copper alloy powder, and the particle size of the copper alloy powder is between 75 and 150 μm.
在本发明的一些实施方式中,铸铁表面进行激光熔覆前对铸铁进行预热,并在激光熔覆的过程中保持铸铁的预热温度。进一步,所述预热的温度为250-350℃。In some embodiments of the present invention, the cast iron is preheated before laser cladding is performed on the surface of the cast iron, and the preheating temperature of the cast iron is maintained during the laser cladding process. Further, the temperature of the preheating is 250-350°C.
在本发明的一些实施方式中,激光熔覆的条件为:激光功率1300-1600W、扫描速度600~1000mm/min、送粉速率14-18g/min、光斑直径2-3mm、搭接率35-40%;进一步为:激光功率1400-1600W、扫描速度600~1000mm/min、送粉速率15-17g/min、光斑直径2-3mm、搭接率36-38%;更进一步为:激光功率1500W、扫描速度600~1000mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。激光扫描路径根据工件尺寸结合运动关系计算得到,同时生成对应数控机床所需程式。In some embodiments of the present invention, the conditions for laser cladding are: laser power 1300-1600W, scanning speed 600-1000mm/min, powder feeding rate 14-18g/min, spot diameter 2-3mm, lap rate 35- 40%; further: laser power 1400-1600W, scanning speed 600-1000mm/min, powder feeding rate 15-17g/min, spot diameter 2-3mm, lap rate 36-38%; further: laser power 1500W , The scanning speed is 600~1000mm/min, the powder feeding rate is 16.36g/min, the spot diameter is 2.4mm, and the overlap rate is 37.5%. The laser scanning path is calculated according to the size of the workpiece and the motion relationship, and the program required by the corresponding CNC machine tool is generated at the same time.
激光熔覆的过程中,合金粉末沉积形成熔覆层,针对不同的基质和不同的沉积结果,所涉及的激光熔覆工艺参数是不同的,而且本申请中还涉及到高反射率的铜合金,所以激光的功率和送粉速率、扫描速度的选择决定了各熔覆层的成型质量,合适的工艺参数选择有助于解决铜合金高反射率带来的难成型问题,实现其在镍铬铁表面的顺利成型。In the process of laser cladding, alloy powder is deposited to form a cladding layer. For different substrates and different deposition results, the involved laser cladding process parameters are different, and this application also involves high reflectivity copper alloys Therefore, the selection of laser power, powder feeding rate and scanning speed determines the forming quality of each cladding layer. The selection of appropriate process parameters will help to solve the difficult forming problem caused by the high reflectivity of copper alloys, and realize its high performance in nickel-chromium alloys. Smooth forming of iron surfaces.
在本发明的一些实施方式中,激光熔覆后进行缓冷处理,首先保温50-150min,之后每隔20min将温度降低10~30℃直至室温。缓冷处理能够有效解决熔覆过程中的基体材料开裂的问题。In some embodiments of the present invention, slow cooling treatment is performed after laser cladding, the temperature is first kept for 50-150 minutes, and then the temperature is lowered by 10-30° C. every 20 minutes until room temperature. Slow cooling treatment can effectively solve the problem of matrix material cracking during the cladding process.
第二方面,上述铸铁表面激光熔覆铜合金的方法得到的防爆叶轮表面结构,所述表面结构由内至外依次为铸铁层、镍铬铁合金过渡层、铜合金功能层。In the second aspect, the surface structure of the explosion-proof impeller obtained by the above-mentioned method of laser cladding copper alloy on the surface of cast iron is the cast iron layer, the transition layer of nickel-chromium-iron alloy, and the functional layer of copper alloy from the inside to the outside.
在本发明的一些实施方式中,镍铬铁合金过渡层的厚度为0.5-1mm。In some embodiments of the present invention, the thickness of the Nichrome transition layer is 0.5-1 mm.
在本发明的一些实施方式中,铜合金功能层的厚度为大于2mm;进一步为2.5-10mm。In some embodiments of the present invention, the thickness of the copper alloy functional layer is greater than 2 mm; further, it is 2.5-10 mm.
本发明一个或多个技术方案具有以下有益效果:One or more technical solutions of the present invention have the following beneficial effects:
本发明相比于现有的铸铁表面进行铜合金改性的制备方法,采用了激光熔覆的方法,所述激光熔覆的方法能够促使铸铁-过渡层-功能层更好的融合形成防爆叶轮表面结构,从而成功制造出仅表面使用铜合金的防爆叶轮。Compared with the existing preparation method for copper alloy modification on the surface of cast iron, the present invention adopts the method of laser cladding, and the method of laser cladding can promote better fusion of cast iron, transition layer and functional layer to form an explosion-proof impeller surface structure, so as to successfully manufacture an explosion-proof impeller using only copper alloy on the surface.
本发明相比于现有的铸铁表面进行铜合金改性的制备方法,先在铸铁的表面形成镍铬铁合金过渡层,然后再形成铜合金功能层,工件界面处的冶金结合性大大增强,界面结合强度大于铸铁本身强度。Compared with the existing preparation method for copper alloy modification on the surface of cast iron, the present invention first forms a transition layer of nickel-chromium-iron alloy on the surface of cast iron, and then forms a functional layer of copper alloy, so that the metallurgical bonding at the interface of the workpiece is greatly enhanced, and the interface is greatly enhanced. The bonding strength is greater than the strength of cast iron itself.
本发明的激光熔覆工艺,在激光熔覆过程中及完成后铸铁基体不发生开裂、熔覆层不发生翘曲脱落现象。In the laser cladding process of the invention, the cast iron matrix does not crack during and after the laser cladding process, and the cladding layer does not warp and fall off.
本发明的方法为防爆叶轮的生产提供了新的工艺方式,与原有整体铜合金铸造的生产方式相比大大降低了成本,提高了生产的灵活性。The method of the invention provides a new technological method for the production of explosion-proof impeller, greatly reduces the cost and improves the flexibility of production compared with the original production method of integral copper alloy casting.
附图说明Description of drawings
构成本发明的一部分的说明书附图用来提供对本申请的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。The accompanying drawings forming a part of the present invention are used to provide further understanding of the present application, and the exemplary embodiments of the present invention and their descriptions are used to explain the present invention and do not constitute an improper limitation of the present invention.
图1为对比例1CuSn15功能层与基体球墨铸铁QT400界面微观形貌光学显微镜照片图,图中球形区域为界面处产生的气孔缺陷。Figure 1 is an optical microscope photo of the microscopic morphology of the interface between the CuSn15 functional layer and the base ductile iron QT400 in Comparative Example 1. The spherical area in the figure is the pore defect generated at the interface.
图2为实施例1中制备的CuSn15功能层与Inconel 718过渡层界面微观形貌光学显微镜照片图。2 is an optical microscope photograph of the microscopic topography of the interface between the CuSn15 functional layer and the Inconel 718 transition layer prepared in Example 1.
图3为实施例1中制备的Inconel 718过渡层与基体球墨铸铁QT400界面微观形貌光学显微镜照片图。3 is an optical microscope photograph of the microscopic topography of the interface between the transition layer of Inconel 718 and the base ductile iron QT400 prepared in Example 1.
图4为对比例2的CuSn15功能层与基体灰铸铁HT250界面微观形貌光学显微镜照片图。4 is an optical microscope photo of the microscopic morphology of the interface between the CuSn15 functional layer and the base gray cast iron HT250 in Comparative Example 2.
图5为实施例2中制备的Inconel 718过渡层与基体灰铸铁HT250界面微观形貌光学显微镜照片图。FIG. 5 is an optical microscope photograph of the microscopic topography of the interface between the transition layer of Inconel 718 prepared in Example 2 and the base gray cast iron HT250.
图6为实施例2中制备的Inconel 718过渡层与CuSn15功能层界面微观形貌光学显微镜照片图。6 is an optical microscope photograph of the microscopic topography of the interface between the Inconel 718 transition layer and the CuSn15 functional layer prepared in Example 2.
图7为不采取预热缓冷工艺下的工件样貌及实施例2中制备的采取预热缓冷工艺后的工件样貌对比图;其中A图为不进行缓冷工艺制备得到的工件,B图为进行缓冷工艺制备得到的工件。Figure 7 is a comparison diagram of the appearance of the workpiece without the preheating and slow cooling process and the workpiece appearance after the preheating and slow cooling process prepared in Example 2; wherein Figure A is the workpiece prepared without the slow cooling process, Picture B is the workpiece prepared by slow cooling process.
图8为对比例3中制备的NiCrBSi过渡层与基体球墨铸铁QT400及CuSn15功能层界面微观形貌显微镜照片图。8 is a micrograph of the microscopic topography of the interface between the NiCrBSi transition layer and the base ductile iron QT400 and the CuSn15 functional layer prepared in Comparative Example 3.
图9为对比例1、实施例1及对比例3中制备的拉伸件在拉伸实验中测得的界面结合强度对比图。FIG. 9 is a comparison diagram of the interfacial bonding strength measured in the tensile test of the tensile members prepared in Comparative Example 1, Example 1 and Comparative Example 3. FIG.
图10为对比例1、实施例1及对比例3中制备的镶嵌块在显微硬度计下测得的结合界面处显微硬度分布对比图。10 is a comparison diagram of the microhardness distribution at the bonding interface measured by the microhardness tester for the mosaic blocks prepared in Comparative Example 1, Example 1 and Comparative Example 3.
图11为实施例3中叶轮几何尺寸图。FIG. 11 is a geometrical dimension drawing of the impeller in Embodiment 3. FIG.
图12为实施例3中制备的鼓风机叶轮激光熔覆前后形貌对比图,其中A为激光熔覆前的图片,B、C、D分别为激光熔覆后的不同角度的图。12 is a comparison diagram of the blower impeller before and after laser cladding prepared in Example 3, wherein A is a picture before laser cladding, and B, C, and D are pictures at different angles after laser cladding, respectively.
具体实施方式Detailed ways
应该指出,以下详细说明都是例示性的,旨在对本发明提供进一步的说明。除非另有指明,本文使用的所有技术和科学术语具有与本发明所属技术领域的普通技术人员通常理解的相同含义。It should be noted that the following detailed description is exemplary and intended to provide further explanation of the invention. Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
需要注意的是,这里所使用的术语仅是为了描述具体实施方式,而非意图限制根据本申请的示例性实施方式。如在这里所使用的,除非上下文另外明确指出,否则单数形式也意图包括复数形式,此外,还应当理解的是,当在本说明书中使用术语“包含”和/或“包括”时,其指明存在特征、步骤、操作、器件、组件和/或它们的组合。It should be noted that the terminology used herein is for the purpose of describing specific embodiments only, and is not intended to limit the exemplary embodiments according to the present application. As used herein, unless the context clearly dictates otherwise, the singular is intended to include the plural as well, furthermore, it is to be understood that when the terms "comprising" and/or "including" are used in this specification, it indicates that There are features, steps, operations, devices, components and/or combinations thereof.
下面结合实施例对本发明进一步说明Below in conjunction with embodiment, the present invention is further described
本发明实施例中采用的Inconel 718粉末及CuSn15粉末均为采用气雾化方式生产的粉末。The
本发明实施例中烘干粉末所采用的设备为真空干燥机。The equipment used for drying the powder in the embodiment of the present invention is a vacuum dryer.
本发明实施例中观察界面形貌采用的光学显微镜型号为SOIF-6XB。The model of the optical microscope used to observe the interface morphology in the embodiment of the present invention is SOIF-6XB.
实施例1Example 1
1、选用球墨铸铁QT400作为基体材料,使用角磨机及砂纸打磨表面去除氧化层,选用无水乙醇清洗基体表面油污。1. Use ductile iron QT400 as the base material, use an angle grinder and sandpaper to polish the surface to remove the oxide layer, and use anhydrous ethanol to clean the oil on the surface of the base.
2、球形Inconel 718粉末在120℃真空环境中烘干120min备用,球形CuSn15粉末在100℃真空环境中烘干60min备用,Inconel 718粉末粒径介于50~150μm,CuSn15粉末粒径介于75~150μm。2. The
3、将球墨铸铁基体加热至300℃并在激光熔覆过程中保持该温度,以防止铸铁基体在激光熔覆过程中出现裂纹。3. Heat the ductile iron base to 300°C and keep the temperature during the laser cladding process to prevent the cast iron base from cracking during the laser cladding process.
4、在球墨铸铁基体表面进行Inconel 718过渡层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度600mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。激光扫描路径为直线循环扫描。4. Laser cladding of
5、在Inconel 718过渡层上继续进行CuSn15功能层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度800mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。5. Continue the laser cladding of the CuSn15 functional layer on the
6、激光熔覆完成后采取缓冷工艺,首先保持300℃温度60min,随后每隔20min将温度降低30℃直至室温。6. After the laser cladding is completed, a slow cooling process is adopted. First, the temperature is kept at 300 °C for 60 minutes, and then the temperature is lowered by 30 °C every 20 minutes until it reaches room temperature.
对比例1Comparative Example 1
1、选用球墨铸铁QT400作为基体材料,使用角磨机及砂纸打磨表面去除氧化层,选用无水乙醇清洗基体表面油污。1. Use ductile iron QT400 as the base material, use an angle grinder and sandpaper to polish the surface to remove the oxide layer, and use anhydrous ethanol to clean the oil on the surface of the base.
2、球形CuSn15粉末在100℃真空环境中烘干60min备用CuSn15粉末粒径介于75~150μm。2. The spherical CuSn15 powder is dried in a vacuum environment at 100℃ for 60min. The particle size of the standby CuSn15 powder is between 75 and 150μm.
3、将球墨铸铁基体加热至300℃并在激光熔覆过程中保持该温度,以防止铸铁基体在激光熔覆过程中出现裂纹。3. Heat the ductile iron base to 300°C and keep the temperature during the laser cladding process to prevent the cast iron base from cracking during the laser cladding process.
4、在球墨铸铁上进行CuSn15功能层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度800mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。4. Laser cladding of CuSn15 functional layer on ductile iron. The laser cladding process parameters are laser power 1500W, scanning speed 800mm/min, powder feeding rate 16.36g/min, spot diameter 2.4mm, and lap rate 37.5%.
5、激光熔覆完成后采取缓冷工艺,首先保持300℃温度60min,随后每隔20min将温度降低30℃直至室温。5. After the laser cladding is completed, a slow cooling process is adopted. First, the temperature is kept at 300 °C for 60 minutes, and then the temperature is lowered by 30 °C every 20 minutes until it reaches room temperature.
将结合界面处截面制成镶嵌块在光镜下观察界面形貌,实施例1得到的形貌照片如图2图3所示,图1中的结合界面处放大后可发现孔洞,与图1对比可发现,实施例1的界面处放大后可见整个界面处平整光滑,无明显裂纹及孔洞产生。The cross section of the bonding interface is made into a mosaic block, and the interface morphology is observed under a light microscope. The morphology photos obtained in Example 1 are shown in Figure 2 and Figure 3. After magnifying the bonding interface in Figure 1, holes can be found, which is the same as Figure 1. By comparison, it can be found that after the interface of Example 1 is enlarged, it can be seen that the entire interface is smooth and smooth, and no obvious cracks and holes are generated.
图3中的球墨铸铁QT400中能够看到圆形石墨。Circular graphite can be seen in the ductile iron QT400 in Figure 3.
实施例2Example 2
1、选用灰铸铁HT250作为基体材料,使用角磨机及砂纸打磨表面去除氧化层,选用无水乙醇清洗基体表面油污。1. Use gray cast iron HT250 as the base material, use an angle grinder and sandpaper to polish the surface to remove the oxide layer, and use anhydrous ethanol to clean the oil on the surface of the base.
2、球形Inconel 718粉末在120℃真空环境中烘干120min备用,球形CuSn15粉末在100℃真空环境中烘干60min备用,Inconel 718粉末粒径介于50~150μm,CuSn15粉末粒径介于75~150μm。2. The
3、将灰铸铁基体加热至300℃并在激光熔覆过程中保持该温度,以防止铸铁基体在激光熔覆过程中出现裂纹。3. Heat the gray cast iron base to 300°C and maintain the temperature during the laser cladding process to prevent the cast iron base from cracking during the laser cladding process.
4、在灰铸铁基体表面进行Inconel 718过渡层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度600mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。4. Laser cladding of
5、在Inconel 718过渡层上继续进行CuSn15功能层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度600mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。激光扫描路径为直线循环扫描。5. Continue the laser cladding of the CuSn15 functional layer on the
6、激光熔覆完成后采取缓冷工艺,首先保持300℃温度60min,随后每隔20min将温度降低20℃直至室温。6. After the laser cladding is completed, a slow cooling process is adopted. First, the temperature is maintained at 300 °C for 60 minutes, and then the temperature is lowered by 20 °C every 20 minutes until room temperature.
对比例2Comparative Example 2
1、选用灰铸铁HT250作为基体材料,使用角磨机及砂纸打磨表面去除氧化层,选用无水乙醇清洗基体表面油污。1. Use gray cast iron HT250 as the base material, use an angle grinder and sandpaper to polish the surface to remove the oxide layer, and use anhydrous ethanol to clean the oil on the surface of the base.
2、形CuSn15粉末在100℃真空环境中烘干60min备用,CuSn15粉末粒径介于75~150μm。2. The CuSn15 powder is dried in a vacuum environment of 100℃ for 60min for use. The particle size of the CuSn15 powder is between 75 and 150μm.
3、将灰铸铁基体加热至300℃并在激光熔覆过程中保持该温度,以防止铸铁基体在激光熔覆过程中出现裂纹。3. Heat the gray cast iron base to 300°C and maintain the temperature during the laser cladding process to prevent the cast iron base from cracking during the laser cladding process.
4、在灰铸铁基体上进行CuSn15功能层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度600mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。激光扫描路径为直线循环扫描。4. Laser cladding of CuSn15 functional layer on gray cast iron substrate. The laser cladding process parameters are laser power 1500W, scanning speed 600mm/min, powder feeding rate 16.36g/min, spot diameter 2.4mm, and lap rate 37.5%. The laser scanning path is linear cyclic scanning.
5、激光熔覆完成后采取缓冷工艺,首先保持300℃温度60min,随后每隔20min将温度降低20℃直至室温。5. After the laser cladding is completed, a slow cooling process is adopted. First, the temperature is maintained at 300 °C for 60 minutes, and then the temperature is lowered by 20 °C every 20 minutes until it reaches room temperature.
将结合界面处截面制成镶嵌块在光镜下观察界面形貌,实施例2得到的形貌照片如图5图6所示,图4的界面处虽不经放大,仍然可见较大的裂纹,与图4对比可发现,实施例2的界面处即使放大后仍然能够看到平整光滑的界面,无明显裂纹及孔洞产生。The cross section of the bonding interface is made into a mosaic block, and the interface morphology is observed under a light microscope. The morphology photos obtained in Example 2 are shown in Figures 5 and 6. Although the interface in Figure 4 is not enlarged, large cracks are still visible. , compared with Figure 4, it can be found that the interface of Example 2 can still see a flat and smooth interface even after magnification, and no obvious cracks and holes are generated.
同时,如图7中的A图和B图所示,将采取预热缓冷工艺下制备的工件同不采取此工艺下制备的工件形貌进行对比,可看出预热缓冷工艺有效解决了熔覆过程中的基体材料开裂的问题。At the same time, as shown in Figures A and B in Figure 7, the morphology of the workpiece prepared under the preheating and slow cooling process is compared with that of the workpiece prepared without this process, and it can be seen that the preheating and slow cooling process effectively solves the problem. The problem of matrix material cracking during the cladding process is solved.
对比例3Comparative Example 3
1、选用球墨铸铁QT400作为基体材料,使用角磨机及砂纸打磨表面去除氧化层,选用无水乙醇清洗基体表面油污。1. Use ductile iron QT400 as the base material, use an angle grinder and sandpaper to polish the surface to remove the oxide layer, and use anhydrous ethanol to clean the oil on the surface of the base.
2、球形NiCrBSi粉末在120℃真空环境中烘干120min备用,球形CuSn15粉末在100℃真空环境中烘干60min备用,NiCrBSi粉末粒径介于50~150μm,CuSn15粉末粒径介于75~150μm。2. The spherical NiCrBSi powder was dried in a vacuum environment at 120°C for 120 minutes for standby use, and the spherical CuSn15 powder was dried in a vacuum environment at 100°C for 60 minutes for standby use.
3、将球墨铸铁基体加热至300℃并在激光熔覆过程中保持该温度,以防止铸铁基体在激光熔覆过程中出现裂纹。3. Heat the ductile iron base to 300°C and keep the temperature during the laser cladding process to prevent the cast iron base from cracking during the laser cladding process.
4、在球墨铸铁基体表面进行NiCrBSi过渡层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度600mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。激光扫描路径为直线循环扫描。4. Laser cladding of NiCrBSi transition layer on the surface of ductile iron substrate. The laser cladding process parameters are laser power 1500W, scanning speed 600mm/min, powder feeding rate 16.36g/min, spot diameter 2.4mm, and lap rate 37.5%. The laser scanning path is linear cyclic scanning.
5、在NiCrBSi过渡层上继续进行CuSn15功能层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度800mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。5. Continue the laser cladding of the CuSn15 functional layer on the NiCrBSi transition layer. The laser cladding process parameters are laser power 1500W, scanning speed 800mm/min, powder feeding rate 16.36g/min, spot diameter 2.4mm, and lap rate 37.5%.
6、激光熔覆完成后采取缓冷工艺,首先保持300℃温度60min,随后每隔20min将温度降低30℃直至室温。6. After the laser cladding is completed, a slow cooling process is adopted. First, the temperature is kept at 300 °C for 60 minutes, and then the temperature is lowered by 30 °C every 20 minutes until it reaches room temperature.
将结合界面处截面制成镶嵌块在光镜下观察界面形貌,对比例3得到的形貌照片如图8所示,可发现过渡层出现裂纹与孔洞,其中裂纹一直延伸至界面附近。The cross-section of the bonding interface was made into a mosaic block, and the interface morphology was observed under a light microscope. The morphology photo obtained in Comparative Example 3 is shown in Figure 8. It can be found that cracks and holes appear in the transition layer, and the cracks extend to the vicinity of the interface.
同时,如图9所示,对比例3得到的界面结合强度稍弱于对比例1得到的界面结合强度,远远低于实施例1得到的界面结合强度;如图10所示,对比例3得到的结合界面处硬度分布曲线起伏较大,而实施例1得到的结合界面处硬度分布曲线则较为平缓,说明采用Inconel 718作为过渡层能够与铸铁及铜合金均有更好的冶金结合。At the same time, as shown in Figure 9, the interface bonding strength obtained in Comparative Example 3 is slightly weaker than that obtained in Comparative Example 1, and far lower than the interface bonding strength obtained in Example 1; as shown in Figure 10, Comparative Example 3 The obtained hardness distribution curve at the bonding interface fluctuates greatly, while the hardness distribution curve at the bonding interface obtained in Example 1 is relatively flat, indicating that using
实施例3Example 3
1、选用灰铸铁HT250鼓风机叶轮作为基体,使用角磨机及砂纸打磨表面去除氧化层,选用无水乙醇清洗基体表面油污。1. Use gray cast iron HT250 blower impeller as the base, use an angle grinder and sandpaper to polish the surface to remove the oxide layer, and use anhydrous ethanol to clean the oil on the surface of the base.
2、球形Inconel 718粉末在120℃真空环境中烘干120min备用,球形CuSn15粉末在100℃真空环境中烘干90min备用,Inconel 718粉末粒径介于50~150μm,CuSn15粉末粒径介于75~150μm。2. The
3、将铸铁基体加热至300℃并在激光熔覆过程中保持该温度,以防止铸铁基体在激光熔覆过程中出现裂纹。3. Heat the cast iron base to 300°C and maintain the temperature during the laser cladding process to prevent the cast iron base from cracking during the laser cladding process.
4、在球墨铸铁基体表面进行Inconel 718过渡层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度600mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。激光扫描路径通过图11所示的叶轮几何尺寸对应运动关系计算得到,同时由此生成对应程式。4. Laser cladding of
5、在Inconel 718过渡层上继续进行CuSn15功能层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度600mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。熔覆路径通过图11所示的叶轮几何尺寸对应运动关系计算得到,同时由此生成对应程式。5. Continue the laser cladding of the CuSn15 functional layer on the
6、激光熔覆完成后采取缓冷工艺,首先保持300℃温度90min,随后每隔20min将温度降低15℃直至室温。6. After the laser cladding is completed, a slow cooling process is adopted. First, the temperature is kept at 300 °C for 90 minutes, and then the temperature is lowered by 15 °C every 20 minutes until room temperature.
如图12所示,鼓风机叶轮熔覆后有着良好的外貌,表面光滑,无明显缺陷。As shown in Figure 12, the blower impeller has a good appearance after cladding, the surface is smooth, and there are no obvious defects.
实施例4Example 4
1、选用灰铸铁HT250作为基体材料,使用角磨机及砂纸打磨表面去除氧化层,选用无水乙醇清洗基体表面油污。1. Use gray cast iron HT250 as the base material, use an angle grinder and sandpaper to polish the surface to remove the oxide layer, and use anhydrous ethanol to clean the oil on the surface of the base.
2、球形Inconel 718粉末在120℃真空环境中烘干120min备用,球形CuSn10粉末在100℃真空环境中烘干60min备用,Inconel 718粉末粒径介于50~150μm,CuSn10粉末粒径介于75~150μm。2. The
3、将灰铸铁基体加热至300℃并在激光熔覆过程中保持该温度,以防止铸铁基体在激光熔覆过程中出现裂纹。3. Heat the gray cast iron base to 300°C and maintain the temperature during the laser cladding process to prevent the cast iron base from cracking during the laser cladding process.
4、在灰铸铁基体表面进行Inconel 718过渡层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度600mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。4. Laser cladding of
5、在Inconel 718过渡层上继续进行CuSn10功能层的激光熔覆。激光熔覆工艺参数为激光功率1500W、扫描速度600mm/min、送粉速率16.36g/min、光斑直径2.4mm、搭接率37.5%。激光扫描路径为直线循环扫描。5. Continue the laser cladding of the CuSn10 functional layer on the
6、激光熔覆完成后采取缓冷工艺,首先保持300℃温度60min,随后每隔20min将温度降低20℃直至室温。6. After the laser cladding is completed, a slow cooling process is adopted. First, the temperature is maintained at 300 °C for 60 minutes, and then the temperature is lowered by 20 °C every 20 minutes until room temperature.
实施例4得到叶轮表面结构,在结合界面处无明显缺陷,但功能层表面存在少许气孔。The impeller surface structure obtained in Example 4 has no obvious defects at the bonding interface, but there are some pores on the surface of the functional layer.
对比例4Comparative Example 4
1、选用球墨铸铁QT400作为基体材料,使用角磨机及砂纸打磨表面去除氧化层,选用无水乙醇清洗基体表面油污。1. Use ductile iron QT400 as the base material, use an angle grinder and sandpaper to polish the surface to remove the oxide layer, and use anhydrous ethanol to clean the oil on the surface of the base.
2、球形Inconel 718粉末在120℃真空环境中烘干120min备用,球形CuSn15粉末在100℃真空环境中烘干60min备用,Inconel 718粉末粒径介于50~150μm,CuSn15粉末粒径介于75~150μm。2. The
3、将球墨铸铁基体加热至300℃并在激光熔覆过程中保持该温度,以防止铸铁基体在激光熔覆过程中出现裂纹。3. Heat the ductile iron base to 300°C and keep the temperature during the laser cladding process to prevent the cast iron base from cracking during the laser cladding process.
4、在球墨铸铁基体表面进行Inconel 718过渡层的激光熔覆。激光熔覆工艺参数为激光功率1300W、扫描速度600mm/min、送粉速率15g/min、光斑直径2.4mm、搭接率37.5%。激光扫描路径为直线循环扫描。4. Laser cladding of
5、在Inconel 718过渡层上继续进行CuSn15功能层的激光熔覆。激光熔覆工艺参数为激光功率1300W、扫描速度800mm/min、送粉速率15g/min、光斑直径2.4mm、搭接率37.5%。5. Continue the laser cladding of the CuSn15 functional layer on the
6、激光熔覆完成后采取缓冷工艺,首先保持300℃温度60min,随后每隔20min将温度降低30℃直至室温。6. After the laser cladding is completed, a slow cooling process is adopted. First, the temperature is kept at 300 °C for 60 minutes, and then the temperature is lowered by 30 °C every 20 minutes until it reaches room temperature.
对比例4得到叶轮表面结构,在结合界面处存在细小孔洞,CuSn15功能层表面较为粗糙,存在许多气孔,且层厚较小。The surface structure of the impeller obtained in Comparative Example 4 shows that there are small pores at the bonding interface, and the surface of the CuSn15 functional layer is relatively rough, with many pores and a small layer thickness.
对比例5Comparative Example 5
相比于实施例1,送粉速率为19g/min,其它条件相同。Compared with Example 1, the powder feeding rate was 19 g/min, and other conditions were the same.
对比例5得到叶轮表面结构,不同层之间的冶金结合变差,结合强度降低,且粉末利用率降低。The surface structure of the impeller obtained in Comparative Example 5, the metallurgical bonding between the different layers deteriorated, the bonding strength decreased, and the powder utilization rate decreased.
以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.
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