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CN113997543B - Production process of ultra-micro glass fiber cotton reinforced HDPE double-wall corrugated pipe - Google Patents

Production process of ultra-micro glass fiber cotton reinforced HDPE double-wall corrugated pipe Download PDF

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Publication number
CN113997543B
CN113997543B CN202111315714.8A CN202111315714A CN113997543B CN 113997543 B CN113997543 B CN 113997543B CN 202111315714 A CN202111315714 A CN 202111315714A CN 113997543 B CN113997543 B CN 113997543B
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fixedly connected
glass fiber
pipe
wall
water
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CN113997543A (en
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侯祥锐
刘俊峰
潘学东
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Anhui Glant New Material Co Ltd
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Anhui Glant New Material Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/885External treatment, e.g. by using air rings for cooling tubular films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto
    • B08B9/02Cleaning pipes or tubes or systems of pipes or tubes
    • B08B9/023Cleaning the external surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911Cooling
    • B29C48/9115Cooling of hollow articles
    • B29C48/912Cooling of hollow articles of tubular films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Drying Of Solid Materials (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

本发明公开了超微玻纤棉增强HDPE双壁波纹管的生产工艺,包括以下步骤:步骤一:按如下重量份数称取HDPE树脂、改性玻璃纤维棉和加工助剂,然后将以上物料送入搅拌机内进行混合均匀,然后通入螺杆挤出机内,通过在制备时加入改性玻璃纤维棉,并且将玻璃纤维棉放入乙烯基三乙氧基硅烷和20%‑35%的乙醇溶液中进行浸泡,能够有效的将玻璃纤维棉进行活化,利用该种方法所制得的HDPE双壁波纹管材具有尺寸收缩率小、硬度高、韧性好的优点,并且加入具有功能性的加工助剂,能够使得制备的HDPE双壁波纹管的具有更好的耐用性。

The invention discloses a production process for ultra-micro glass fiber cotton reinforced HDPE double-wall corrugated pipes, which includes the following steps: Step 1: Weigh HDPE resin, modified glass fiber cotton and processing aids according to the following weight parts, and then add the above materials Send it into the mixer to mix evenly, and then pass it into the screw extruder. Add modified glass fiber wool during preparation, and put the glass fiber wool into vinyl triethoxysilane and 20%-35% ethanol. Soaking in the solution can effectively activate the glass fiber wool. The HDPE double-wall corrugated pipe produced by this method has the advantages of small dimensional shrinkage, high hardness and good toughness, and functional processing aids are added. The agent can make the prepared HDPE double-wall corrugated pipe have better durability.

Description

超微玻纤棉增强HDPE双壁波纹管的生产工艺Production process of ultra-micro glass fiber wool reinforced HDPE double-wall corrugated pipe

技术领域Technical field

本发明涉及双壁波纹管生产技术领域,具体涉及超微玻纤棉增强HDPE双壁波纹管的生产工艺。The invention relates to the technical field of double-wall corrugated pipe production, and specifically to the production technology of ultra-fine glass fiber cotton reinforced HDPE double-wall corrugated pipes.

背景技术Background technique

HDPE是世界5大常用塑料之一,鉴于其良好的韧性及加工性,得到广泛使用,在市政给排水管道中也得以大量运用,常规HDPE双壁波纹管材一般采用滑石粉和碳酸钙作为增强材料。HDPE is one of the top five commonly used plastics in the world. Due to its good toughness and processability, it is widely used and is also widely used in municipal water supply and drainage pipelines. Conventional HDPE double-wall corrugated pipes generally use talcum powder and calcium carbonate as reinforcing materials. .

但是现有的HDPE双壁波纹管材在制造时的成型效果较差,而且制备的HDPE双壁波纹管在硬度、韧性和抗冲击性能方面效果往往较差,并且在制造时需要对管材进行冷却降温,而目前在冷却降温时不仅降温速度较慢,而且管道的表面还会粘附有冷却液,不仅导致冷却液的浪费,而且会粘连有大量的灰尘。However, the existing HDPE double-wall corrugated pipes have poor molding effects during manufacturing, and the prepared HDPE double-wall corrugated pipes are often poor in hardness, toughness and impact resistance, and the pipes need to be cooled during manufacturing. , and at present, not only the cooling speed is slow during cooling, but also the coolant will adhere to the surface of the pipe, which not only leads to the waste of coolant, but also causes a large amount of dust to adhere.

发明内容Contents of the invention

本发明的目的在于提供超微玻纤棉增强HDPE双壁波纹管的生产工艺,通过在制备时加入改性玻璃纤维棉,并且将玻璃纤维棉放入乙烯基三乙氧基硅烷和20%-35%的乙醇溶液中进行浸泡,能够有效的将玻璃纤维棉进行活化,利用该种方法所制得的HDPE双壁波纹管材具有尺寸收缩率小、硬度高、韧性好的优点,并且加入具有功能性的加工助剂,能够使得制备的HDPE双壁波纹管的具有更好的耐用性点。The object of the present invention is to provide a production process for ultra-fine glass fiber wool reinforced HDPE double-wall corrugated pipes by adding modified glass fiber wool during preparation, and adding the glass fiber cotton into vinyl triethoxysilane and 20%- Soaking in 35% ethanol solution can effectively activate the glass fiber wool. The HDPE double-wall corrugated pipe made by this method has the advantages of small dimensional shrinkage, high hardness and good toughness, and is added with functional Special processing aids can make the prepared HDPE double-wall corrugated pipes have better durability.

本发明的目的可以通过以下技术方案实现:The object of the present invention can be achieved through the following technical solutions:

超微玻纤棉增强HDPE双壁波纹管的生产工艺,包括以下步骤:The production process of ultra-fine glass fiber wool reinforced HDPE double-wall corrugated pipes includes the following steps:

步骤一:按如下重量份数称取HDPE树脂50-55份、改性玻璃纤维棉20-30份和加工助剂3-5份,然后将以上物料送入搅拌机内进行混合均匀,然后通入螺杆挤出机内;Step 1: Weigh 50-55 parts of HDPE resin, 20-30 parts of modified glass fiber cotton and 3-5 parts of processing aids according to the following weight parts, then put the above materials into the mixer to mix evenly, and then pass through Inside the screw extruder;

步骤二:通过螺杆挤出机以包覆共挤的方式挤出外壁和内壁,然后通过牵引将外壁和内壁送入成型机内通过压合的方式将外壁和内壁进行粘接,并通过负压吸附的方式在外壁的表面形成波纹;Step 2: Use the screw extruder to extrude the outer wall and the inner wall in a coating and co-extrusion manner, and then feed the outer wall and the inner wall into the molding machine through traction, bond the outer wall and the inner wall through pressure, and use negative pressure The adsorption method forms ripples on the surface of the outer wall;

步骤三:将成型的管道送入冷却水箱的内部进行冷却,从而得到成品管材,然后通过烘干箱对管材的表面进行烘干,再利用牵引切割机对管材进行光电定位切割,从而得到管件;Step 3: Send the formed pipe into the cooling water tank for cooling to obtain the finished pipe, then dry the surface of the pipe through a drying box, and then use a traction cutting machine to photoelectrically position and cut the pipe to obtain pipe fittings;

其中冷却水箱由清洗箱和位于清洗箱底部的蓄水箱组成,所述清洗箱的底部开设有出水口,所述蓄水箱的顶部开设有进水口,所述蓄水箱内腔的底部固定连接有抽水泵,所述抽水泵的出水端连通有出水管,所述出水管的一端依次贯穿蓄水箱和清洗箱并延伸至清洗箱的内部,所述清洗箱的外表面固定连接有支撑板,所述支撑板的底部与清洗箱内腔的底部固定连接,所述出水管的外表面固定连接有环形管,所述环形管的外表面固定连接有三个固定套,所述固定套的一侧与清洗箱的内表面固定连接,所述环形管的外表面贯穿有四个喷头,所述清洗箱的两侧均设置有推管口,所述清洗箱的内表面通过驱动组件连接有擦拭组件,所述蓄水箱内腔顶部的两侧均固定连接有限位板,两个所述限位板相对的一侧之间设置有过滤板,所述蓄水箱的一侧连接贯穿有水管,所述水管的外表面固定连接有控制阀。The cooling water tank is composed of a cleaning tank and a water storage tank located at the bottom of the cleaning tank. The bottom of the cleaning tank is provided with a water outlet, the top of the water storage tank is provided with a water inlet, and the bottom of the inner cavity of the water storage tank is fixed. A water pump is connected to the water pump. The water outlet end of the water pump is connected to a water outlet pipe. One end of the water outlet pipe passes through the water storage tank and the cleaning tank in sequence and extends to the inside of the cleaning tank. The outer surface of the cleaning tank is fixedly connected with a support. The bottom of the support plate is fixedly connected to the bottom of the inner cavity of the cleaning box. The outer surface of the water outlet pipe is fixedly connected to an annular tube. The outer surface of the annular tube is fixedly connected to three fixed sleeves. The fixed sleeves are One side is fixedly connected to the inner surface of the cleaning box. The outer surface of the annular tube is penetrated by four nozzles. Both sides of the cleaning box are provided with push pipe openings. The inner surface of the cleaning box is connected with a drive assembly. Wiping assembly, both sides of the top of the inner cavity of the water storage tank are fixedly connected with limit plates, a filter plate is provided between the opposite sides of the two limit plates, and one side of the water storage tank is connected with a Water pipe, the outer surface of the water pipe is fixedly connected with a control valve.

所述擦拭组件包括支撑环,所述支撑环内表面的上方和下方均通过连接套固定连接有电动伸缩杆,两个所述电动伸缩杆相对的一端之间固定连接有推板,所述推板的内部设置有转动环,所述转动环表面的两侧均转动连接有转动页,两个所述转动页的一侧均固定连接有连接板,所述连接板的一侧固定连接有擦洗棉,所述擦洗棉的一侧开设有若干个适配槽,两个所述推板相对远离的一侧均固定连接有固定套,所述固定套的内表面滑动连接有连接杆,所述连接杆的一端贯穿推板并延伸至推板的外部,所述转动页的外表面固定连接有转动块,所述转动块的内表面与连接杆的一端转动连接,所述连接杆的另一端固定连接有滑动板,所述滑动板的一侧固定连接有弹簧,所述弹簧的一端与固定套内腔的一侧固定连接。The wiping assembly includes a support ring. An electric telescopic rod is fixedly connected above and below the inner surface of the support ring through a connecting sleeve. A push plate is fixedly connected between the opposite ends of the two electric telescopic rods. There is a rotating ring inside the plate. Both sides of the surface of the rotating ring are connected with rotating pages. One side of the two rotating pages is fixedly connected with a connecting plate. One side of the connecting plate is fixedly connected with a wiping plate. Cotton, one side of the scouring cotton is provided with several adapting grooves, and the sides of the two push plates that are relatively far away are fixedly connected with fixed sleeves, and the inner surface of the fixed sleeve is slidably connected with a connecting rod. One end of the connecting rod penetrates the push plate and extends to the outside of the push plate. The outer surface of the rotating leaf is fixedly connected with a rotating block. The inner surface of the rotating block is rotationally connected to one end of the connecting rod. The other end of the connecting rod A sliding plate is fixedly connected, one side of the sliding plate is fixedly connected with a spring, and one end of the spring is fixedly connected to one side of the inner cavity of the fixed sleeve.

所述驱动组件包括位于清洗箱顶部的驱动电机,所述驱动电机的输出端固定连接有驱动齿轮,所述推板的外表面固定连接有齿圈,所述齿圈的外表面与驱动齿轮的外表面相啮合,所述推板的外表面且位于齿圈的两侧均固定连接有限位环,所述限位环的内表面滚动连接有钢珠,所述清洗箱的内表面在钢珠的对应位置开设有滚动槽,所述钢珠的外表面与滚动槽的外表面滚动连接。The drive assembly includes a drive motor located on the top of the cleaning box. The output end of the drive motor is fixedly connected to a drive gear. The outer surface of the push plate is fixedly connected to a ring gear. The outer surface of the ring gear is in contact with the drive gear. The outer surfaces of the push plate are meshed with each other. The outer surface of the push plate and both sides of the ring gear are fixedly connected with limit rings. The inner surface of the limit ring is rollingly connected with steel balls. The inner surface of the cleaning box is at the corresponding position of the steel balls. A rolling groove is provided, and the outer surface of the steel ball is rollingly connected to the outer surface of the rolling groove.

作为本发明进一步的方案:所述改性玻璃纤维棉的制备方法为:将玻璃纤维棉放置在容器内,并向容器内注入乙烯基三乙氧基硅烷和浓度为20%-35%的乙醇溶液中进行浸泡1-3min,同时对其进行搅拌,然后将玻璃纤维棉取出,并通过烘干机进行烘干,从而得到改性玻璃纤维棉。As a further solution of the present invention: the preparation method of the modified glass fiber wool is: placing the glass fiber wool in a container, and injecting vinyl triethoxysilane and ethanol with a concentration of 20%-35% into the container Soak in the solution for 1-3 minutes while stirring, then take out the glass fiber wool and dry it in a dryer to obtain modified glass fiber wool.

作为本发明进一步的方案:所述玻璃纤维棉的直径为10-13微米。As a further solution of the present invention: the diameter of the glass fiber wool is 10-13 microns.

作为本发明进一步的方案:所述步骤一中搅拌机的搅拌速度为120-180r/min,搅拌时间为3-5min。As a further solution of the present invention: in the step one, the stirring speed of the mixer is 120-180r/min, and the stirring time is 3-5min.

作为本发明进一步的方案:所述步骤二中螺杆挤出机的挤出温度为200-220℃,螺杆挤出机的模具温度设置为220-235℃。As a further solution of the present invention: in step two, the extrusion temperature of the screw extruder is 200-220°C, and the die temperature of the screw extruder is set to 220-235°C.

作为本发明进一步的方案:所述步骤三中烘干箱内部温度设置为70-90℃,烘干箱内烘干的时间为30-50s。As a further solution of the present invention: in step three, the internal temperature of the drying box is set to 70-90°C, and the drying time in the drying box is 30-50s.

本发明的有益效果:Beneficial effects of the present invention:

(1)本发明中,通过在制备时加入改性玻璃纤维棉,并且将玻璃纤维棉放入乙烯基三乙氧基硅烷和20%-35%的乙醇溶液中进行浸泡,能够有效的将玻璃纤维棉进行活化,利用该种方法所制得的HDPE双壁波纹管材具有尺寸收缩率小、硬度高、韧性好的优点,并且加入具有功能性的加工助剂,能够使得制备的HDPE双壁波纹管的具有更好的耐用性。(1) In the present invention, by adding modified glass fiber wool during preparation, and soaking the glass fiber wool in vinyl triethoxysilane and 20%-35% ethanol solution, the glass can be effectively Fiber cotton is activated. The HDPE double-wall corrugated pipe produced by this method has the advantages of small dimensional shrinkage, high hardness and good toughness, and adding functional processing aids can make the prepared HDPE double-wall corrugated pipe Tubes have better durability.

(2)本发明中,用过在冷却水箱的内部设置多个环形管,并在环形管的表面设置四个等距离的喷头,从而能够实现对双壁波纹管进行全面的冷却,而且在清洗箱中设置擦拭组件,能够将双壁波纹管表面粘附的冷却液擦下,而且通过电动伸缩杆的收缩,使得两个转动页转动,从而将擦拭棉中的冷却液挤出,而冷却液会再次通过出水口和进水口留至蓄水箱内以达到循环使用的目的,此结构不仅能够快速的对管道进行降温,而且能够实现冷却液的循环使用,易于推广。(2) In the present invention, multiple annular tubes are arranged inside the cooling water tank, and four equidistant nozzles are arranged on the surface of the annular tubes, so that the double-wall corrugated pipe can be fully cooled and cleaned during cleaning. A wiping component is installed in the box, which can wipe off the coolant adhered to the surface of the double-walled corrugated pipe, and through the contraction of the electric telescopic rod, the two rotating pages rotate, thereby squeezing out the coolant in the wiping cotton, and the coolant It will be left in the water storage tank through the water outlet and water inlet again to achieve the purpose of recycling. This structure can not only quickly cool down the pipeline, but also realize the recycling of coolant, which is easy to promote.

附图说明Description of drawings

下面结合附图对本发明作进一步的说明。The present invention will be further described below in conjunction with the accompanying drawings.

图1是本发明的工艺流程示意图;Figure 1 is a schematic diagram of the process flow of the present invention;

图2是本发明冷却水箱的内部结构示意图;Figure 2 is a schematic diagram of the internal structure of the cooling water tank of the present invention;

图3是本发明清洗箱的局部结构侧剖图;Figure 3 is a partial structural side cross-sectional view of the cleaning box of the present invention;

图4是本发明擦拭组件的外部结构侧视图;Figure 4 is a side view of the external structure of the wiping assembly of the present invention;

图5是本发明转动页的局部结构剖视图;Figure 5 is a partial structural cross-sectional view of the rotating page of the present invention;

图6是本发明图2中A处的局部结构放大图;Figure 6 is an enlarged view of the partial structure of position A in Figure 2 of the present invention;

图7是本发明图2中B处的局部结构放大图。Figure 7 is an enlarged view of the partial structure at B in Figure 2 of the present invention.

图中:1、清洗箱;2、蓄水箱;3、抽水泵;4、出水管;5、出水口;6、进水口;7、环形管;8、固定套;9、喷头;10、支撑板;11、推管口;12、驱动组件;121、驱动电机;122、驱动齿轮;123、齿圈;124、限位环;125、滚动槽;126、钢珠;13、擦拭组件;131、支撑环;132、适配槽;133、电动伸缩杆;134、推板;135、连接套;136、转动环;137、转动页;138、擦洗棉;139、连接板;1310、滑动板;1311、弹簧;1312、连接杆;1313、转动块;14、过滤板;15、水管;16、控制阀;17、限位板。In the picture: 1. Cleaning tank; 2. Water storage tank; 3. Water pump; 4. Water outlet pipe; 5. Water outlet; 6. Water inlet; 7. Ring pipe; 8. Fixed sleeve; 9. Nozzle; 10. Support plate; 11. Push tube opening; 12. Driving assembly; 121. Driving motor; 122. Driving gear; 123. Ring gear; 124. Limit ring; 125. Rolling groove; 126. Steel balls; 13. Wiping assembly; 131 , Support ring; 132. Adapting groove; 133. Electric telescopic rod; 134. Push plate; 135. Connecting sleeve; 136. Rotating ring; 137. Rotating page; 138. Scrubbing cotton; 139. Connecting plate; 1310. Sliding plate ; 1311. Spring; 1312. Connecting rod; 1313. Rotating block; 14. Filter plate; 15. Water pipe; 16. Control valve; 17. Limit plate.

具体实施方式Detailed ways

下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其它实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts fall within the scope of protection of the present invention.

请参阅图1-7所示,本发明为超微玻纤棉增强HDPE双壁波纹管的生产工艺,包括以下步骤:Please refer to Figures 1-7. The present invention is a production process for ultra-fine glass fiber cotton reinforced HDPE double-wall corrugated pipes, which includes the following steps:

步骤一:按如下重量份数称取HDPE树脂55份、改性玻璃纤维棉30份、加工助剂3份,该加工助剂包括无毒润滑剂、抗氧化剂、光稳定剂、偶联剂、活化剂等,用于提供的管道的使用性能,然后将以上物料送入搅拌机内进行混合均匀,然后通入螺杆挤出机内;Step 1: Weigh 55 parts of HDPE resin, 30 parts of modified glass fiber cotton, and 3 parts of processing aids according to the following parts by weight. The processing aids include non-toxic lubricants, antioxidants, light stabilizers, coupling agents, Activator, etc., are used to improve the performance of the pipeline, and then the above materials are fed into the mixer to mix evenly, and then passed into the screw extruder;

步骤二:通过螺杆挤出机以包覆共挤的方式挤出外壁和内壁,然后通过牵引将外壁和内壁送入成型机内通过压合的方式将外壁和内壁进行粘接,并通过负压吸附的方式在外壁的表面形成波纹;Step 2: Use the screw extruder to extrude the outer wall and the inner wall in a coating and co-extrusion manner, and then feed the outer wall and the inner wall into the molding machine through traction, bond the outer wall and the inner wall through pressure, and use negative pressure The adsorption method forms ripples on the surface of the outer wall;

步骤三:将成型的管道送入冷却水箱的内部进行冷却,从而得到成品管材,然后通过烘干箱对管材的表面进行烘干,再利用牵引切割机对管材进行光电定位切割,从而得到管件。Step 3: Send the formed pipe into the interior of the cooling water tank for cooling to obtain the finished pipe, then dry the surface of the pipe through a drying box, and then use a traction cutting machine to photoelectrically position and cut the pipe to obtain pipe fittings.

其中冷却水箱由清洗箱1和位于清洗箱1底部的蓄水箱2组成,清洗箱1的底部开设有出水口5,蓄水箱2的顶部开设有进水口6,蓄水箱2内腔的底部固定连接有抽水泵3,抽水泵3的出水端连通有出水管4,出水管4的一端依次贯穿蓄水箱2和清洗箱1并延伸至清洗箱1的内部,清洗箱1的外表面固定连接有支撑板10,支撑板10的底部与清洗箱1内腔的底部固定连接,出水管4的外表面固定连接有环形管7,环形管7的外表面固定连接有三个固定套8,固定套8的一侧与清洗箱1的内表面固定连接,环形管7的外表面贯穿有四个喷头9,四个喷头9之间的间距相等,从而能够对管道的底部进行冷却,清洗箱1的两侧均设置有推管口11,推管口11用于推动波纹管为现有技术,清洗箱1的内表面通过驱动组件12连接有擦拭组件13,擦拭组件13能够将波纹管表面粘覆的冷却液进行擦拭,蓄水箱2内腔顶部的两侧均固定连接有限位板17,两个限位板17相对的一侧之间设置有过滤板14,过滤板14能够将冷却液中的杂质过滤,而蓄水箱2的正面设置有密封门用于将过滤板14取出,从而对过滤板14进行清洗,蓄水箱2的一侧连接贯穿有水管15,水管15的外表面固定连接有控制阀16,通过控制阀16向蓄水箱2的内部注入冷却液或排出冷却液。The cooling water tank consists of a cleaning tank 1 and a water storage tank 2 located at the bottom of the cleaning tank 1. The bottom of the cleaning tank 1 is provided with a water outlet 5, and the top of the water storage tank 2 is provided with a water inlet 6. The inner cavity of the water storage tank 2 is A water pump 3 is fixedly connected to the bottom, and the outlet end of the water pump 3 is connected to an outlet pipe 4. One end of the outlet pipe 4 passes through the water storage tank 2 and the cleaning tank 1 in sequence and extends to the inside of the cleaning tank 1. The outer surface of the cleaning tank 1 There is a support plate 10 fixedly connected. The bottom of the support plate 10 is fixedly connected with the bottom of the inner cavity of the cleaning box 1. The outer surface of the outlet pipe 4 is fixedly connected with an annular pipe 7. The outer surface of the annular pipe 7 is fixedly connected with three fixing sleeves 8. One side of the fixed sleeve 8 is fixedly connected to the inner surface of the cleaning box 1. The outer surface of the annular pipe 7 is penetrated by four nozzles 9. The spacing between the four nozzles 9 is equal, so that the bottom of the pipe can be cooled and the cleaning box Both sides of 1 are provided with push tube openings 11. The push tube openings 11 are used to push the bellows, which is an existing technology. The inner surface of the cleaning box 1 is connected to a wiping assembly 13 through a driving assembly 12. The wiping assembly 13 can wipe the surface of the bellows. The stuck coolant is wiped, and limit plates 17 are fixedly connected to both sides of the top of the inner cavity of the water storage tank 2. A filter plate 14 is provided between the opposite sides of the two limit plates 17. The filter plate 14 can cool the The impurities in the liquid are filtered, and a sealed door is provided on the front of the water storage tank 2 for taking out the filter plate 14 so as to clean the filter plate 14. One side of the water storage tank 2 is connected with a water pipe 15, and the outside of the water pipe 15 A control valve 16 is fixedly connected to the surface, through which cooling liquid is injected into or discharged from the inside of the water storage tank 2 .

擦拭组件13包括支撑环131,支撑环131内表面的上方和下方均通过安装套固定连接有电动伸缩杆133,两个电动伸缩杆133相对的一端之间固定连接有推板134,推板134的内部设置有转动环136,转动环136表面的两侧均转动连接有转动页137,两个转动页137的一侧均固定连接有连接板139,连接板139的一侧固定连接有擦洗棉138,擦洗棉138的一侧开设有若干个适配槽132,两个推板134相对远离的一侧均固定连接有连接套135,连接套135的内表面滑动连接有连接杆1312,连接杆1312的一端贯穿推板134并延伸至推板134的外部,转动页137的外表面固定连接有转动块1313,转动块1313的内表面与连接杆1312的一端转动连接,连接杆1312的另一端固定连接有滑动板1310,滑动板1310的一侧固定连接有弹簧1311,弹簧1311的一端与连接套135内腔的一侧固定连接。The wiping assembly 13 includes a support ring 131. The upper and lower sides of the inner surface of the support ring 131 are fixedly connected to an electric telescopic rod 133 through a mounting sleeve. A push plate 134 is fixedly connected between the opposite ends of the two electric telescopic rods 133. The push plate 134 There is a rotating ring 136 inside. Both sides of the surface of the rotating ring 136 are connected with rotating pages 137. One side of the two rotating pages 137 is fixedly connected with a connecting plate 139. One side of the connecting plate 139 is fixedly connected with a scrubbing cotton. 138. A number of adapting slots 132 are provided on one side of the scrubbing cotton 138. The opposite sides of the two push plates 134 are fixedly connected with connecting sleeves 135. The inner surfaces of the connecting sleeves 135 are slidingly connected with connecting rods 1312. The connecting rods One end of 1312 penetrates the push plate 134 and extends to the outside of the push plate 134. The outer surface of the rotating page 137 is fixedly connected with the rotating block 1313. The inner surface of the rotating block 1313 is rotationally connected with one end of the connecting rod 1312, and the other end of the connecting rod 1312 A sliding plate 1310 is fixedly connected, a spring 1311 is fixedly connected to one side of the sliding plate 1310, and one end of the spring 1311 is fixedly connected to one side of the inner cavity of the connecting sleeve 135.

驱动组件12包括位于清洗箱1顶部的驱动电机121,驱动电机121的输出端固定连接有驱动齿轮122,推板134的外表面固定连接有齿圈123,齿圈123的外表面与驱动齿轮122的外表面相啮合,推板134的外表面且位于齿圈123的两侧均固定连接有限位环124,限位环124的内表面滚动连接有钢珠126,钢珠126起到支撑和限位的作用,清洗箱1的内表面在钢珠126的对应位置开设有滚动槽125,钢珠126的外表面与滚动槽125的外表面滚动连接。The driving assembly 12 includes a driving motor 121 located on the top of the cleaning box 1. The output end of the driving motor 121 is fixedly connected to a driving gear 122. The outer surface of the push plate 134 is fixedly connected to a ring gear 123. The outer surface of the ring gear 123 is connected to the driving gear 122. The outer surface of the push plate 134 is engaged with the outer surface of the push plate 134 and is fixedly connected to the limit ring 124 on both sides of the ring gear 123. The inner surface of the limit ring 124 is rollingly connected with steel balls 126. The steel balls 126 play the role of support and limit. , the inner surface of the cleaning box 1 is provided with a rolling groove 125 at a corresponding position of the steel ball 126, and the outer surface of the steel ball 126 is rollingly connected with the outer surface of the rolling groove 125.

本发明的工作原理:首先将水管15与外部的管道进行连接,并打开控制阀16,使得降温液输送至蓄水箱2的内部,然后关闭控制阀16,此时可将双壁波纹管从推管口11送入清洗箱1的内部,然后启动抽水泵3,并将蓄水箱2内的降温液通过出水管4送至环形管7的内部,并经喷头9将降温液喷在双壁波纹管的外表面,从而吸收波纹管表面的热量,此时启动驱动电机121,从而带动驱动齿轮122进行转动,通过驱动齿轮122和齿圈123的啮合关系,使得推板134进行转动,此时钢珠126在限位环124和滚动槽125的内表面进行滚动,同时通过连接套135内的连接杆1312,带动转动页137进行转动,此时的擦洗棉138上的适配槽132对双壁波纹管外表面的降温液进行擦拭,并将降温液进行吸收,当双壁波纹管清洗完成后,此时通过电动伸缩杆133推动两个推板134向相对靠近的一侧进行运动,连接杆1312和转动块1313之间发生转动,从而使得推板134挤压两个转动页137在转动环136的外表面进行转动,此时的弹簧1311被拉长而两个转动页137上的擦洗棉138被挤压,从而使得擦洗棉138内吸附的降温液被挤出,而落下的降温液从出水口5和进水口6落在过滤板14上,将杂质进行过滤,并落至蓄水箱2的内部待冷却后再次使用。The working principle of the present invention: first connect the water pipe 15 to the external pipeline, open the control valve 16, so that the cooling liquid is transported to the inside of the water storage tank 2, and then close the control valve 16. At this time, the double-wall corrugated pipe can be removed from Push the pipe opening 11 into the inside of the cleaning tank 1, then start the water pump 3, and send the cooling liquid in the water storage tank 2 to the inside of the annular pipe 7 through the water outlet pipe 4, and spray the cooling liquid on both sides through the nozzle 9 The outer surface of the wall bellows absorbs the heat on the surface of the bellows. At this time, the driving motor 121 is started to drive the driving gear 122 to rotate. Through the meshing relationship between the driving gear 122 and the ring gear 123, the push plate 134 is rotated. This When the steel ball 126 rolls on the inner surface of the limit ring 124 and the rolling groove 125, it drives the rotating page 137 to rotate through the connecting rod 1312 in the connecting sleeve 135. At this time, the adapter groove 132 on the scrubbing cotton 138 has a double pair. Wipe the cooling liquid on the outer surface of the wall corrugated pipe and absorb the cooling liquid. When the cleaning of the double-walled corrugated pipe is completed, the electric telescopic rod 133 is used to push the two push plates 134 to move to the relatively close side, and the connection Rotation occurs between the rod 1312 and the rotating block 1313, so that the push plate 134 squeezes the two rotating leaves 137 to rotate on the outer surface of the rotating ring 136. At this time, the spring 1311 is elongated and the two rotating leaves 137 are wiped. The cotton 138 is squeezed, so that the cooling liquid adsorbed in the scrubbing cotton 138 is squeezed out, and the falling cooling liquid falls on the filter plate 14 from the water outlet 5 and the water inlet 6, and the impurities are filtered and fall to the water storage The inside of box 2 is allowed to cool before use again.

所述改性玻璃纤维棉的制备方法为:将玻璃纤维棉放置在容器内,并向容器内注入浓度为35%的乙醇溶液和乙烯基三乙氧基硅烷中进行浸泡3min,同时对其进行搅拌,然后将玻璃纤维棉取出,并通过烘干机进行烘干,从而得到改性玻璃纤维棉,所述玻璃纤维棉的直径为13微米。The preparation method of the modified glass fiber wool is as follows: place the glass fiber wool in a container, inject an ethanol solution with a concentration of 35% and vinyl triethoxysilane into the container, soak it for 3 minutes, and simultaneously perform Stir, then take out the glass fiber wool and dry it in a dryer to obtain modified glass fiber wool, the diameter of the glass fiber wool is 13 microns.

所述步骤一中搅拌机的搅拌速度为180r/min,搅拌时间为5min,所述步骤二中螺杆挤出机的挤出温度为220℃,螺杆挤出机的模具温度设置为235℃,所述步骤三中烘干箱内部温度设置为90℃,烘干箱内烘干的时间为50s。In step one, the stirring speed of the mixer is 180r/min, and the stirring time is 5 minutes. In step two, the extrusion temperature of the screw extruder is 220°C, and the mold temperature of the screw extruder is set to 235°C. In step three, the internal temperature of the drying box is set to 90°C, and the drying time in the drying box is 50 seconds.

在本发明的描述中,需要理解的是,术语“上”、“下”、“左”、“右”等指示方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以及特定的方位构造和操作,因此,不能理解为对本发明的限制。此外,“第一”、“第二”仅由于描述目的,且不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。因此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者多个该特征。本发明的描述中,除非另有说明,“多个”的含义是两个或两个以上。In the description of the present invention, it should be understood that the terms "upper", "lower", "left", "right", etc. indicating the orientation or positional relationship are based on the orientation or positional relationship shown in the drawings, and are only for convenience. By describing the present invention and simplifying the description, it is not intended to indicate or imply that the device or element referred to must have a specific orientation, and be constructed and operated in a specific orientation, and therefore, is not to be construed as a limitation of the present invention. In addition, the terms "first" and "second" are for descriptive purposes only and cannot be understood as indicating or implying relative importance or implicitly indicating the number of indicated technical features. Therefore, features defined by “first” and “second” may explicitly or implicitly include one or more of these features. In the description of the present invention, unless otherwise stated, the meaning of "plurality" is two or more.

在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”“相连”“连接”等应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接连接,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that, unless otherwise clearly stated and limited, the terms "installation", "connection", "connection", etc. should be understood in a broad sense. For example, it can be a fixed connection or a detachable connection. , or integrally connected; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium; it can be an internal connection between two components. For those of ordinary skill in the art, the specific meanings of the above terms in the present invention can be understood on a case-by-case basis.

以上对本发明的一个实施例进行了详细说明,但所述内容仅为本发明的较佳实施例,不能被认为用于限定本发明的实施范围。凡依本发明申请范围所作的均等变化与改进等,均应仍归属于本发明的专利涵盖范围之内。An embodiment of the present invention has been described in detail above, but the content is only a preferred embodiment of the present invention and cannot be considered to limit the implementation scope of the present invention. All equivalent changes and improvements made within the scope of the present invention shall still fall within the scope of the patent of the present invention.

Claims (6)

1.超微玻纤棉增强HDPE双壁波纹管的生产工艺,其特征在于,包括以下步骤:1. The production process of ultra-micro glass fiber cotton reinforced HDPE double-wall corrugated pipe is characterized by including the following steps: 步骤一:按如下重量份数称取HDPE树脂50-55份、改性玻璃纤维棉20-30份和加工助剂3-5份,然后将以上物料送入搅拌机内进行混合均匀,然后通入螺杆挤出机内;Step 1: Weigh 50-55 parts of HDPE resin, 20-30 parts of modified glass fiber cotton and 3-5 parts of processing aids according to the following weight parts, then put the above materials into the mixer to mix evenly, and then pass through Inside the screw extruder; 步骤二:通过螺杆挤出机以包覆共挤的方式挤出外壁和内壁,然后通过牵引将外壁和内壁送入成型机内通过压合的方式将外壁和内壁进行粘接,并通过负压吸附的方式在外壁的表面形成波纹;Step 2: Use the screw extruder to extrude the outer wall and the inner wall in a coating and co-extrusion manner, and then feed the outer wall and the inner wall into the molding machine through traction, bond the outer wall and the inner wall through pressure, and use negative pressure The adsorption method forms ripples on the surface of the outer wall; 步骤三:将成型的管道送入冷却水箱的内部进行冷却,从而得到成品管材,然后通过烘干箱对管材的表面进行烘干,再利用牵引切割机对管材进行光电定位切割,从而得到管件;Step 3: Send the formed pipe into the cooling water tank for cooling to obtain the finished pipe, then dry the surface of the pipe through a drying box, and then use a traction cutting machine to photoelectrically position and cut the pipe to obtain pipe fittings; 其中冷却水箱由清洗箱(1)和位于清洗箱(1)底部的蓄水箱(2)组成,清洗箱(1)的底部开设有出水口(5),蓄水箱(2)的顶部开设有进水口(6),蓄水箱(2)内腔的底部固定连接有抽水泵(3),抽水泵(3)的出水端连通有出水管(4),出水管(4)的一端依次贯穿蓄水箱(2)和清洗箱(1)并延伸至清洗箱(1)的内部,清洗箱(1)的外表面固定连接有支撑板(10),支撑板(10)的底部与清洗箱(1)内腔的底部固定连接,出水管(4)的外表面固定连接有环形管(7),环形管(7)的外表面固定连接有三个固定套(8),固定套(8)的一侧与清洗箱(1)的内表面固定连接,环形管(7)的外表面贯穿有四个喷头(9),四个喷头(9)之间的间距相等,从而能够对管道的底部进行冷却,清洗箱(1)的两侧均设置有推管口(11),清洗箱(1)的内表面通过驱动组件(12)连接有擦拭组件(13),擦拭组件(13)能够将波纹管表面粘覆的冷却液进行擦拭,蓄水箱(2)内腔顶部的两侧均固定连接有限位板(17),两个限位板(17)相对的一侧之间设置有过滤板(14),过滤板(14)能够将冷却液中的杂质过滤,而蓄水箱(2)的正面设置有密封门用于将过滤板(14)取出,蓄水箱(2)的一侧连接贯穿有水管(15),水管(15)的外表面固定连接有控制阀(16);The cooling water tank consists of a cleaning tank (1) and a water storage tank (2) located at the bottom of the cleaning tank (1). A water outlet (5) is provided at the bottom of the cleaning tank (1), and a water outlet (5) is provided at the top of the water storage tank (2). There is a water inlet (6), and a water pump (3) is fixedly connected to the bottom of the inner cavity of the water storage tank (2). The water outlet of the water pump (3) is connected with a water outlet pipe (4), and one end of the water outlet pipe (4) is in sequence. It penetrates the water storage tank (2) and the cleaning tank (1) and extends to the inside of the cleaning tank (1). The outer surface of the cleaning tank (1) is fixedly connected with a support plate (10), and the bottom of the support plate (10) is in contact with the cleaning tank (1). The bottom of the inner cavity of the box (1) is fixedly connected, and the outer surface of the outlet pipe (4) is fixedly connected with an annular pipe (7). The outer surface of the annular pipe (7) is fixedly connected with three fixing sleeves (8). The fixing sleeves (8) ) is fixedly connected to the inner surface of the cleaning box (1). The outer surface of the annular pipe (7) is penetrated by four nozzles (9). The spacing between the four nozzles (9) is equal, so that the pipe can be cleaned. The bottom is cooled, and push tube openings (11) are provided on both sides of the cleaning box (1). The inner surface of the cleaning box (1) is connected to a wiping assembly (13) through the driving assembly (12). The wiping assembly (13) can Wipe the coolant adhered to the surface of the bellows, and limit plates (17) are fixedly connected to both sides of the top of the inner cavity of the water storage tank (2). There is a gap between the opposite sides of the two limit plates (17). The filter plate (14) can filter impurities in the coolant, and a sealing door is provided on the front of the water tank (2) for taking out the filter plate (14). A water pipe (15) is connected and penetrated on one side, and a control valve (16) is fixedly connected to the outer surface of the water pipe (15); 擦拭组件(13)包括支撑环(131),支撑环(131)内表面的上方和下方均通过安装套固定连接有电动伸缩杆(133),两个电动伸缩杆(133)相对的一端之间固定连接有推板(134),推板(134)的内部设置有转动环(136),转动环(136)表面的两侧均转动连接有转动页(137),两个转动页(137)的一侧均固定连接有连接板(139),连接板(139)的一侧固定连接有擦洗棉(138),擦洗棉(138)的一侧开设有若干个适配槽(132),两个推板(134)相对远离的一侧均固定连接有连接套(135),连接套(135)的内表面滑动连接有连接杆(1312),连接杆(1312)的一端贯穿推板(134)并延伸至推板(134)的外部,转动页(137)的外表面固定连接有转动块(1313),转动块(1313)的内表面与连接杆(1312)的一端转动连接,连接杆(1312)的另一端固定连接有滑动板(1310),滑动板(1310)的一侧固定连接有弹簧(1311),弹簧(1311)的一端与连接套(135)内腔的一侧固定连接;The wiping assembly (13) includes a support ring (131). The upper and lower parts of the inner surface of the support ring (131) are fixedly connected to an electric telescopic rod (133) through a mounting sleeve. A push plate (134) is fixedly connected, and a rotating ring (136) is provided inside the pushing plate (134). Both sides of the surface of the rotating ring (136) are connected with rotating pages (137), and the two rotating pages (137) A connecting plate (139) is fixedly connected to one side of the connecting plate (139), a scouring cotton (138) is fixedly connected to one side of the connecting plate (139), and several adapter slots (132) are provided on one side of the scouring cotton (138). The relatively distant sides of each push plate (134) are fixedly connected with a connecting sleeve (135). The inner surface of the connecting sleeve (135) is slidingly connected with a connecting rod (1312). One end of the connecting rod (1312) penetrates the push plate (134). ) and extends to the outside of the push plate (134). The outer surface of the rotating page (137) is fixedly connected with the rotating block (1313). The inner surface of the rotating block (1313) is rotationally connected with one end of the connecting rod (1312). The connecting rod The other end of (1312) is fixedly connected with a sliding plate (1310), one side of the sliding plate (1310) is fixedly connected with a spring (1311), and one end of the spring (1311) is fixedly connected with one side of the inner cavity of the connecting sleeve (135) ; 驱动组件(12)包括位于清洗箱(1)顶部的驱动电机(121),驱动电机(121)的输出端固定连接有驱动齿轮(122),推板(134)的外表面固定连接有齿圈(123),齿圈(123)的外表面与驱动齿轮(122)的外表面相啮合,推板(134)的外表面且位于齿圈(123)的两侧均固定连接有限位环(124),限位环(124)的内表面滚动连接有钢珠(126),钢珠(126)起到支撑和限位的作用,清洗箱(1)的内表面在钢珠(126)的对应位置开设有滚动槽(125),钢珠(126)的外表面与滚动槽(125)的外表面滚动连接。The driving assembly (12) includes a driving motor (121) located on the top of the cleaning box (1). The output end of the driving motor (121) is fixedly connected with a driving gear (122), and the outer surface of the push plate (134) is fixedly connected with a ring gear. (123), the outer surface of the ring gear (123) meshes with the outer surface of the driving gear (122), and the outer surface of the push plate (134) located on both sides of the ring gear (123) is fixedly connected to the limiting ring (124) , the inner surface of the limit ring (124) is rollingly connected with steel balls (126), and the steel balls (126) play the role of support and limit. The inner surface of the cleaning box (1) is provided with rolling steel balls (126) at the corresponding positions. groove (125), the outer surface of the steel ball (126) is rollingly connected with the outer surface of the rolling groove (125). 2.根据权利要求1所述的超微玻纤棉增强HDPE双壁波纹管的生产工艺,其特征在于,所述改性玻璃纤维棉的制备方法为:将玻璃纤维棉放置在容器内,并向容器内注入乙烯基三乙氧基硅烷和浓度为20%-35%的乙醇溶液进行浸泡1-3min,同时对其进行搅拌,然后将玻璃纤维棉取出,并通过烘干机进行烘干,从而得到改性玻璃纤维棉。2. The production process of ultra-micro glass fiber wool reinforced HDPE double-wall corrugated pipe according to claim 1, characterized in that the preparation method of the modified glass fiber wool is: placing the glass fiber wool in a container, and Inject vinyltriethoxysilane and ethanol solution with a concentration of 20%-35% into the container and soak it for 1-3 minutes while stirring, then take out the glass fiber wool and dry it in a dryer. Thus modified glass fiber wool is obtained. 3.根据权利要求2所述的超微玻纤棉增强HDPE双壁波纹管的生产工艺,其特征在于,所述玻璃纤维棉的直径为10-13微米。3. The production process of ultra-fine glass fiber wool reinforced HDPE double-wall corrugated pipe according to claim 2, characterized in that the diameter of the glass fiber wool is 10-13 microns. 4.根据权利要求3所述的超微玻纤棉增强HDPE双壁波纹管的生产工艺,其特征在于,所述步骤一中搅拌机的搅拌速度为120-180r/min,搅拌时间为3-5min。4. The production process of ultra-micro glass fiber wool reinforced HDPE double-wall corrugated pipe according to claim 3, characterized in that in the step one, the stirring speed of the mixer is 120-180r/min, and the stirring time is 3-5min . 5.根据权利要求4所述的超微玻纤棉增强HDPE双壁波纹管的生产工艺,其特征在于,所述步骤二中螺杆挤出机的挤出温度为200-220℃,螺杆挤出机的模具温度设置为220-235℃。5. The production process of ultra-micro glass fiber wool reinforced HDPE double-wall corrugated pipe according to claim 4, characterized in that the extrusion temperature of the screw extruder in step two is 200-220°C, and the screw extrusion The mold temperature of the machine is set to 220-235°C. 6.根据权利要求5所述的超微玻纤棉增强HDPE双壁波纹管的生产工艺,其特征在于,所述步骤三中烘干箱内部温度设置为70-90℃,烘干箱内烘干的时间为30-50s。6. The production process of ultra-fine glass fiber cotton reinforced HDPE double-wall corrugated pipe according to claim 5, characterized in that in step three, the internal temperature of the drying box is set to 70-90°C, and the drying box is dried in the drying box. The drying time is 30-50s.
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CN107216527A (en) * 2017-07-20 2017-09-29 安徽杰蓝特新材料有限公司 A kind of ultra micro glass cotton applied to HDPE double-wall corrugated pipes strengthens master batch
CN107286433A (en) * 2017-07-20 2017-10-24 安徽杰蓝特新材料有限公司 A kind of ultra micro glass cotton strengthens HDPE double-wall corrugated pipe forming methods
CN107312226A (en) * 2017-07-20 2017-11-03 安徽杰蓝特新材料有限公司 Strengthen the process of surface treatment of master batch applied to HDPE double-wall corrugated pipe ultra micro glasses cotton
CN107337838A (en) * 2017-07-20 2017-11-10 安徽杰蓝特新材料有限公司 A kind of ultra micro glass fiber cotton strengthens HDPE double-wall corrugated pipes

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EP2061663B1 (en) * 2006-08-31 2016-11-30 Compagnie Générale des Etablissements Michelin Elastomer composition having glass micro fibers

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CN107216527A (en) * 2017-07-20 2017-09-29 安徽杰蓝特新材料有限公司 A kind of ultra micro glass cotton applied to HDPE double-wall corrugated pipes strengthens master batch
CN107286433A (en) * 2017-07-20 2017-10-24 安徽杰蓝特新材料有限公司 A kind of ultra micro glass cotton strengthens HDPE double-wall corrugated pipe forming methods
CN107312226A (en) * 2017-07-20 2017-11-03 安徽杰蓝特新材料有限公司 Strengthen the process of surface treatment of master batch applied to HDPE double-wall corrugated pipe ultra micro glasses cotton
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