CN113896912A - Liquid color master batch and application thereof - Google Patents
Liquid color master batch and application thereof Download PDFInfo
- Publication number
- CN113896912A CN113896912A CN202111350167.7A CN202111350167A CN113896912A CN 113896912 A CN113896912 A CN 113896912A CN 202111350167 A CN202111350167 A CN 202111350167A CN 113896912 A CN113896912 A CN 113896912A
- Authority
- CN
- China
- Prior art keywords
- liquid color
- liquid
- fatty acid
- color concentrate
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007788 liquid Substances 0.000 title claims abstract 20
- 239000004595 color masterbatch Substances 0.000 title claims abstract 5
- 239000012141 concentrate Substances 0.000 claims abstract 13
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract 10
- 239000000194 fatty acid Substances 0.000 claims abstract 10
- 229930195729 fatty acid Natural products 0.000 claims abstract 10
- -1 fatty acid ester Chemical class 0.000 claims abstract 9
- 229920000728 polyester Polymers 0.000 claims abstract 7
- 239000004094 surface-active agent Substances 0.000 claims abstract 6
- 239000000049 pigment Substances 0.000 claims abstract 5
- 238000005886 esterification reaction Methods 0.000 claims abstract 2
- 239000002736 nonionic surfactant Substances 0.000 claims abstract 2
- 229920005862 polyol Polymers 0.000 claims abstract 2
- 150000003077 polyols Chemical class 0.000 claims abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000004185 ester group Chemical group 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 239000013538 functional additive Substances 0.000 claims 1
- 239000001023 inorganic pigment Substances 0.000 claims 1
- 239000012860 organic pigment Substances 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 150000005846 sugar alcohols Polymers 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000000969 carrier Substances 0.000 abstract 1
- 238000004040 coloring Methods 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/223—Packed additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
- C08J2471/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a liquid color masterbatch and application thereof, wherein the liquid color masterbatch comprises: liquid carriers, pigments and surfactants; the liquid carrier is modified fatty acid ester, and the modified fatty acid ester is prepared by esterification reaction of monocarboxylic acid fatty acid and polyol; the surfactant is a nonionic surfactant. The liquid color concentrate is used to form a colored polyester article with polyester. The liquid color master batch has excellent storage stability and good compatibility with polyester, is particularly suitable for coloring polyester fibers, can avoid the phenomenon of uneven dispersion of pigment in the polyester fiber forming process, and solves the problems of screw slippage, color point and the like generated in the extrusion process.
Description
Technical Field
The invention belongs to the technical field of fine chemical engineering, and particularly relates to a liquid color master batch and application thereof in coloring polyester products.
Background
The coloring of products such as polyester, polyamide plastic, fiber and the like by using color master batches is a mature technology; the technology mixes color master batch with chips of polyester, polyamide and the like, and then feeds the mixed material into an extruder or a forming machine, so that resin and colorant are plasticized, and the colorant is mixed into molten plastic or fiber to obtain a colored product.
The color master batch is a solid colorant prepared by mixing and dispersing a high proportion of pigment or additive and thermoplastic resin, and the selected resin has good wetting and dispersing effects on the colorant and has good compatibility with a material to be colored. The color master batch is used for coloring plastics or fibers, and besides the high inventory cost, the resin of the color master batch needs to be subjected to two heating processes, which may have adverse effects on the resin per se, increase the energy consumption in the plastic or fiber processing process, and lead to the troublesome cleaning of a screw extruder in the color changing process.
The liquid color masterbatch can avoid the process that the resin is heated twice, and can be directly added at the rear end of the screw extruder for processing, thereby reducing the difficulty of screw cleaning and being a plastic and fiber colorant with good development prospect.
Liquid color concentrates are dispersions containing pigments and/or functional additives, a liquid medium (non-aqueous) for thermoplastic polymers. The liquid medium is mainly used as a liquid carrier, such as a liquid polymer carrier, a biological oil and a derivative carrier thereof and the like. For example, chinese patent CN101421348B discloses a liquid color concentrate comprising an acrylic liquid polymer carrier, at least one colorant and optionally other functional additives; chinese patent CN101522840B discloses a liquid color or additive concentrate using a bio-derived oil, comprising a grape seed oil liquid carrier (bio-derived oil), at least one colorant or functional additive, optionally a surfactant, a viscosity modifier and other functional or specialty colorants; chinese patent CN111040458A discloses a universal modified rosin liquid color masterbatch composition and a preparation method thereof, wherein the universal modified rosin liquid color masterbatch composition comprises a modified rosin thickening liquid carrier and a plastic additive.
At present, liquid carriers for the preparation of liquid colorants suitable for polymers, plastics, films and fibers have been disclosed at home and abroad. For example, U.S. patent US4167503 discloses liquid carriers comprising alkylated phenoxypoly (ethyleneoxy) ethanol and teaches the use of liquid color concentrates formed using such carriers for the coloration of polyester fibers. The surfactant-based carrier of these colorants provides an excellent pigment dispersion medium and allows for relatively high pigment loadings. However, the surfactants used in these colorants are polar in nature and are incompatible with many plastics.
Liquid color concentrates have many advantages over other colorants, particularly in terms of pigment dispersibility. In general, liquid color concentrates have better pigment dispersion than color concentrates. However, the liquid color concentrates at the present stage also have some undesirable phenomena, such as pigment particles in the liquid color concentrates may precipitate and agglomerate with time. Such phenomena of pigment settling, particle agglomeration and the like can lead to the formation of difficult to redisperse solids at the bottom of the container, resulting in color point problems during the coloring of plastics and fibers due to poor dispersion of the pigment.
Furthermore, color point problems during coloring of colored oils can also occur due to mechanical mixing irregularities, improper selection and use of surfactants, and the like. Furthermore, some liquid carriers have high lubricity, which causes severe screw slippage in the twin-screw extruder during processing and causes colored streaks. In order to overcome the problems of color points, streaking, etc. of liquid color concentrate coloring, various technical solutions have been reported abroad, for example, U.S. Pat. No. 4,4624983 discloses a polyolefin compatible liquid colorant/additive concentrate comprising a low molecular weight addition polymer and a compatible, substantially non-volatile solvent (diluent) mixture carrier, colorant and/or additive, dispersing aid. The product prepared by the liquid color masterbatch can not generate stripes or color points, and also eliminates the phenomenon of screw slippage. For another example, U.S. Pat. No. 5,300,8395 discloses a storage stable liquid color concentrate for incorporation into a polymeric resin comprising a carrier and at least one colorant or additive, the carrier being composed of at least one organic rosin resin and at least one surfactant. The liquid color masterbatch is compatible with various plastics, overcomes the problem of screw slippage, and reduces other processing defects, such as uneven flow at the pump inlet. However, the liquid color concentrates are mainly used for coloring plastics, and how to prepare the liquid color concentrates with high coloring effect and good stability in fibers at low cost is still a very challenging subject.
Disclosure of Invention
In order to solve the technical problems, the invention aims to provide a liquid color master batch and application thereof; the liquid color master batch has excellent storage stability and good compatibility with polyester, is particularly suitable for coloring polyester fibers, can avoid the phenomenon of uneven dispersion of pigment in the polyester fiber forming process, and simultaneously solves the problems of screw slippage, color points and the like generated in the extrusion process.
In order to achieve the technical purpose and achieve the technical effect, the invention is realized by the following technical scheme:
a liquid color masterbatch, comprising:
the liquid carrier is modified fatty acid ester, and the modified fatty acid ester is prepared by esterification reaction of monocarboxylic acid fatty acid and polyol;
a pigment;
a surfactant, wherein the surfactant is a nonionic surfactant.
Further, the color masterbatch comprises: 25-85 parts of liquid carrier, 15-50 parts of pigment and 0.5-2 parts of surfactant.
Further, the color concentrate may further comprise functional additives such as uv absorbers, antioxidants, and the like.
Further, the monocarboxylic fatty acid used for preparing the modified fatty acid ester has a structural general formula shown in formula (I):
R1CH2COOH(I)
wherein R is1Is represented by C10-C20A long carbon chain containing unsaturated double bonds or saturated alkyl containing sulfonic substituent groups; preferably, R1Is represented by C14-C20A long carbon chain containing an unsaturated double bond or a saturated alkyl group containing a sulfonic substituent; more preferably, R1Is represented by C14-C20A long carbon chain containing unsaturated double bonds; c containing unsaturated double bond in monocarboxylic fatty acid14-C20Representative material structures for long carbon chains, comprising one or more of: CH (CH)3(CH2)5CH＝CH(CH2)6、CH3(CH2)7CH＝CH(CH2)6、CH3(CH2)4CH＝CHCH2CH＝CH(CH2)6。
Further, the polyhydric alcohol used for preparing the modified fatty acid ester is dihydric alcohol, and the dihydric alcohol is at least one of ethylene glycol, propylene glycol and polyethylene glycol. Further preferably, the diol is polyethylene glycol, such as polyethylene glycol 200, polyethylene glycol 264, polyethylene glycol 400, and polyethylene glycol 600.
Further, the modified fatty acid ester has a molar mass of 500 to 2000 g/mol; based thereon, the modified fatty acid ester liquid carrier is preferably polyethylene glycol oleate. Such as polyethylene glycol 400 oleate, polyethylene glycol 600 oleate; the modified fatty acid ester liquid carrier may also be a mixture of polyethylene glycol oleates of different molecular weights, such as a mixture of polyethylene glycol 400 oleate and polyethylene glycol 600 oleate.
Further, the pigment is an organic pigment or an inorganic pigment; wherein the types of inorganic pigments include: titanium dioxide, carbon black, iron oxide, and the like; types of organic pigments include: azo pigments (monoazo, disazo), phthalocyanines, quinacridone pigments, perylene pigments, isoindolones, anthraquinones, and the like; the selection of the pigment in the liquid color master batch can refer to a pigment selection method commonly used in the color master batch industry, and the temperature resistance, the weather resistance and other properties of the pigment are comprehensively considered; the different color requirements of the polyester article can be achieved by toning according to methods well known in the art.
Further, the surfactant is an ester substance containing a hydroxyl functional group; more preferably, the ester substance containing hydroxyl functional groups has a molar mass of 800-1000 g/mol, and the structural general formula of the ester substance is shown as a formula (II), such as that of Pasteur
HS 15；
CH3(CH2)4CH2CH(OH)CH2(CH2)8CH2CO(OCH2CH2)nOH (Ⅱ)。
The preparation process of the liquid color masterbatch is generally at ambient temperature, and specifically comprises the following steps: and dissolving the surfactant in the liquid carrier, then adding the pigment, and mixing and dispersing by using mixing and dispersing equipment to obtain the liquid color master batch. The mixing and dispersing apparatus may be one of a conventional dispersing machine which performs dispersion with a stirring paddle, a three-roll machine, a sand mill, a ball mill, and the like, and a three-roll machine is generally preferred as the mixing and dispersing apparatus.
The invention further provides the application of the liquid color masterbatch, namely, the liquid color masterbatch is mixed with resin or pumped into polymer melt flow prepared by a screw extruder and other equipment, and finally a colored polyester product is formed; preferably, the liquid color concentrate is used to prepare colored polyester fibers.
The invention has the beneficial effects that:
in the liquid color masterbatch, the nonionic surfactant with hydroxyl groups and the modified fatty acid ester liquid carrier are combined and interact with each other, so that the pigment can be stably dispersed in the liquid carrier, the storage stability of the liquid color masterbatch is improved, the pigment is uniformly dispersed in the molding process of a polyester product, the problems of screw slippage, color points and the like generated in the molding process are solved, and the complexity of procedures such as color changing of polyester fiber coloring is reduced. The liquid color masterbatch disclosed by the invention has good compatibility with polyester, and is particularly suitable for coloring polyester fibers.
Detailed Description
The technical solutions in the present invention will be described clearly and completely with reference to specific embodiments, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
81 parts of polyethylene glycol 400 monooleate (prepared by esterification of oleic acid and polyethylene glycol 400), 17.5 parts of C.I. pigment black 7 and 1.5 parts of
HS15 was dispersed using a disperser with a common paddle and milled using a laboratory scale three roll mill to produce a liquid color masterbatch 1.
Example 2
69.5 parts of polyethylene glycol 400 monooleate, 29.3 parts of C.I. pigment red 254 and 1.2 parts of
HS15 was dispersed using a disperser with a common paddle and milled using a laboratory scale three roll mill to obtain liquid color masterbatch 2.
Example 3
66 parts of polyethylene glycol 600 monooleate (prepared by esterification of oleic acid and polyethylene glycol 600), 33 parts of C.I. pigment blue 15:3 and 1 part of
HS15 was dispersed using a disperser with a common paddle and milled using a laboratory scale three roll mill to produce a liquid color masterbatch 3.
Example 4
54 parts of polyethylene glycol 600 dioleate, 45 parts of C.I. pigment red 101 and 1 part of
HS15 was dispersed using a disperser with a common paddle and milled using a laboratory scale three roll mill to produce liquid color concentrate 4.
Example 5
29.5 parts of polyethylene glycol 400 monooleate, 39.2 parts of polyethylene glycol 600 dioleate, 30 parts of C.I. pigment yellow 150 and 1.3 parts of
HS15 was dispersed using a disperser with a common paddle and milled using a laboratory scale three roll mill to produce a liquid color masterbatch 5.
Comparative example
The polyethylene glycol 400 monooleate in example 1 was replaced with sorbitan monooleate, and the other raw materials were kept unchanged, and the raw materials were dispersed in a dispersion machine equipped with a common stirring paddle, and then milled using a laboratory scale three-roll mill to obtain a liquid color masterbatch 6.
Storage stability test
The liquid color concentrates of the above examples and comparative examples were stored in 500ml sealed bottles at 50 ℃ for 30 days, and visually examined for storage stability, and the liquid color concentrate was represented by "√" where no pigment bottom or liquid color concentrate delamination occurred, and the liquid color concentrate was represented by "×" where pigment bottom or liquid color concentrate delamination occurred. The storage stability test results are shown in table 1 below.
TABLE 1 storage stability test results
Preparation of colored polyester fibers
And transferring the liquid color masterbatch into a pressure container, feeding the liquid color masterbatch into an inlet of a metering pump, and controlling the rotating speed of the metering pump and the feeding speed of a screw of an extruder so as to keep a stable mass ratio of the polyester melt to the liquid color masterbatch. The proportion of pigment content in the fibres in the total amount was chosen to be 0.1 wt.% in this experiment. The liquid color master batch containing the pigment and the fiber-grade polymer enter a double-screw extruder together, and the colored polyester master batch is prepared by extruding and granulating through the double-screw extruder. Then, the colored polyester master batch is used as a raw material, a multifunctional spinning machine is used for spinning, and polyester fiber is extruded downwards from a spinneret plate of the multifunctional spinning machine and is wound on a bobbin rotating at the peripheral speed of 300 m/min.
And (3) coloring effect test: visually observing the coloring effect of the colored polyester master batches and the polyester fibers, wherein color points or stripes do not appear in the colored polyester master batches and the polyester fibers, and the color points or stripes are represented by the square root; any one of the colored polyester master batch and the polyester fiber is colored or striped and is indicated by an "x". The results of the coloring effect test are shown in table 2 below.
Table 2 coloring effect test results
As can be seen from tables 1 and 2, the liquid color masterbatch of the embodiment of the invention has excellent storage stability, and the colored polyester masterbatch and the polyester fiber prepared by using the liquid color masterbatch have good coloring effect, thereby eliminating the problem of color spots or stripes.
The above description is only an embodiment of the present invention, and not intended to limit the scope of the present invention, and all modifications of equivalent structures and equivalent processes, which are made by the present specification, or directly or indirectly applied to other related technical fields, are included in the scope of the present invention.
Claims (10)
1. A liquid color concentrate, comprising:
the liquid carrier is modified fatty acid ester, and the modified fatty acid ester is prepared by esterification reaction of monocarboxylic acid fatty acid and polyol;
a pigment;
a surfactant, wherein the surfactant is a nonionic surfactant.
2. The liquid color concentrate of claim 1, wherein: the color masterbatch comprises: 25-85 parts of liquid carrier, 15-50 parts of pigment and 0.5-2 parts of surfactant.
3. The liquid color concentrate of claim 1, wherein: the color concentrate also contains functional additives.
4. The liquid color concentrate according to claim 1 or 2, characterized in that: the monocarboxylic fatty acid used for preparing the modified fatty acid ester has a structural general formula shown in a formula (I):
R1CH2COOH (I)
wherein R is1Is represented by C10-C20Long carbon chains containing unsaturated double bonds or saturated alkyl groups containing sulfonic substituents.
5. The liquid color concentrate according to claim 1 or 2, characterized in that: the polyhydric alcohol used for preparing the modified fatty acid ester is dihydric alcohol, and the dihydric alcohol is at least one of ethylene glycol, propylene glycol and polyethylene glycol.
6. The liquid color concentrate according to claim 1 or 2, characterized in that: the modified fatty acid ester has a molar mass of 500-2000 g/mol.
7. The liquid color concentrate according to claim 1 or 2, characterized in that: the pigment is an organic pigment or an inorganic pigment.
8. The liquid color concentrate according to claim 1 or 2, characterized in that: the surfactant is an ester substance containing a hydroxyl functional group.
9. The liquid color concentrate of claim 8, wherein: the ester substance containing the hydroxyl functional group has the molar mass of 800-1000 g/mol, and the structural general formula is shown as the formula (II):
CH3(CH2)4CH2CH(OH)CH2(CH2)8CH2CO(OCH2CH2)nOH (Ⅱ)。
10. use of a liquid color concentrate according to any of claims 1-9, characterized in that: the liquid color concentrate is used to form a colored polyester article with polyester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111350167.7A CN113896912A (en) | 2021-11-15 | 2021-11-15 | Liquid color master batch and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111350167.7A CN113896912A (en) | 2021-11-15 | 2021-11-15 | Liquid color master batch and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113896912A true CN113896912A (en) | 2022-01-07 |
Family
ID=79194405
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111350167.7A Pending CN113896912A (en) | 2021-11-15 | 2021-11-15 | Liquid color master batch and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113896912A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115678252A (en) * | 2022-11-14 | 2023-02-03 | 安踏（中国）有限公司 | High-light-transmittance color sole material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101421348A (en) * | 2006-04-14 | 2009-04-29 | 普立万公司 | Liquid color concentrate |
| CN101802051A (en) * | 2007-09-24 | 2010-08-11 | 普立万公司 | Liquid color concentrate for polyester articles |
| CN102585450A (en) * | 2012-02-13 | 2012-07-18 | 广州市波斯塑胶颜料有限公司 | Coloring master batch used for polyester |
| CN106978639A (en) * | 2017-04-01 | 2017-07-25 | 苏州世名科技股份有限公司 | A kind of polyester fiber original liquid coloring liquid coloring agent and preparation method thereof |
-
2021
- 2021-11-15 CN CN202111350167.7A patent/CN113896912A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101421348A (en) * | 2006-04-14 | 2009-04-29 | 普立万公司 | Liquid color concentrate |
| CN101802051A (en) * | 2007-09-24 | 2010-08-11 | 普立万公司 | Liquid color concentrate for polyester articles |
| CN102585450A (en) * | 2012-02-13 | 2012-07-18 | 广州市波斯塑胶颜料有限公司 | Coloring master batch used for polyester |
| CN106978639A (en) * | 2017-04-01 | 2017-07-25 | 苏州世名科技股份有限公司 | A kind of polyester fiber original liquid coloring liquid coloring agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115678252A (en) * | 2022-11-14 | 2023-02-03 | 安踏（中国）有限公司 | High-light-transmittance color sole material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5308395A (en) | Liquid colorant/additive concentrate for incorporation into plastics | |
| US5604279A (en) | Colorant preparation for producing masterbatches | |
| JP3103072B2 (en) | Colored polyester thermoplastic material composed of a poly (oxyalkylenated) compound as a colorant and a specific surfactant as a diluent | |
| CN104059273A (en) | Special polyethylene coloring masterbatch for white thin film and preparation method of masterbatch | |
| CN106496740A (en) | A kind of antistatic PET color master batch | |
| CN113896912A (en) | Liquid color master batch and application thereof | |
| CN110903617A (en) | PET color master batch for water-based superfine fiber and preparation method thereof | |
| CN106633701A (en) | Special color masterbatch for spinning filament polyester, and preparation method and application thereof | |
| US3668172A (en) | Pigmented polyester compositions | |
| CN114561031B (en) | High-pigment-content color master batch and preparation method and application thereof | |
| CN112176447A (en) | Colored polyester fiber and preparation method thereof | |
| CN101679764B (en) | Low Dust Additive and Pigment Blends with Improved Color | |
| CN110922575A (en) | Colored conductive polyester fiber and preparation method thereof | |
| CA1056080A (en) | Pigment concentrates | |
| CN113402736A (en) | Antibacterial color master batch and preparation method thereof | |
| CN111849142A (en) | Semiconductive PC black master batch and preparation method thereof | |
| TWI656150B (en) | Method for producing nanodispersion composition and color matching system applying nanodispersion composition | |
| CN118459986B (en) | High-performance pigment master batch and preparation method thereof | |
| CN107236175A (en) | A kind of bloom black agglomerate applied to HDPE plumbing tubing | |
| CN113956568A (en) | High-quality injection molding color master batch for injection molding | |
| CN1997710A (en) | Bridged bisanthraquinone dye derivatives | |
| CN114958030A (en) | Preparation method of superfine pigment preparation for coloring polyester | |
| CN111286798A (en) | Preparation method of auxiliary agent bag applied to ultra-black technology | |
| CN116876101A (en) | Preparation method of degradable high polymer colored fiber | |
| JPS59230029A (en) | Production of masterbatch coloring polymer pellet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220107 |