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CN113856454B - A kind of regeneration tower for gas-liquid phase catalytic oxidation process for removing hydrogen sulfide - Google Patents

A kind of regeneration tower for gas-liquid phase catalytic oxidation process for removing hydrogen sulfide Download PDF

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CN113856454B
CN113856454B CN202110933251.5A CN202110933251A CN113856454B CN 113856454 B CN113856454 B CN 113856454B CN 202110933251 A CN202110933251 A CN 202110933251A CN 113856454 B CN113856454 B CN 113856454B
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fixedly connected
sleeve
liquid
wall
gas
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CN113856454A (en
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姚瑞清
马政生
刘驰宇
马博锐
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NORTHWEST UNIVERSITY
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • B01D53/8612Hydrogen sulfide

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Abstract

The invention relates to the technical field of gas-liquid reactors and discloses a regeneration tower for a hydrogen sulfide removal process by a gas-liquid phase catalytic oxidation method, which comprises a cylinder body, a skirt seat and a cover plate, wherein the skirt seat is fixedly connected with the side wall of the cylinder body, the upper end of the cylinder body is provided with an opening, the opening is fixedly connected with the cover plate through a lock catch, the right end of the cylinder body is fixedly connected with a liquid inlet pipe, one end of the liquid inlet pipe extends into the cylinder body, the upper end of the cover plate is symmetrically and fixedly connected with two exhaust pipes, the center of the lower end of the cylinder body is fixedly connected with a liquid discharge pipe, the upper end of the cover plate is fixedly connected with a shell through a round hole, the shell is internally connected with a transmission mechanism, and a plurality of uniformly distributed cross rods are fixedly connected in the cylinder body. The regeneration tower for the hydrogen sulfide removal process by the gas-liquid phase catalytic oxidation method can improve the air oxidation efficiency, avoid scaling and blockage caused by sulfur foam and avoid complex operation of flow equipment caused by sulfur foam treatment, and is simple to maintain.

Description

一种用于气液相催化氧化法脱硫化氢工艺的再生塔A kind of regeneration tower for gas-liquid phase catalytic oxidation process for removing hydrogen sulfide

技术领域technical field

本发明涉及气液反应器技术领域,具体为一种用于气液相催化氧化法脱硫化氢工艺的再生塔。The invention relates to the technical field of gas-liquid reactors, in particular to a regeneration tower used for a gas-liquid phase catalytic oxidation method for removing hydrogen sulfide.

背景技术Background technique

硫化氢是一种毒害性极大的化合物,广泛存在于多种工业生产和民用生活所涉及的气体当中,硫化氢属于酸性气体,毒性高,腐蚀性强,脱除气体中的硫化氢是工业生产中常见的过程,脱除硫化氢常用的技术包括固相化学吸收法、气固相催化氧化法、气液相催化氧化法,其中,气液相催化氧化法技术工艺简单,操作弹性大,脱硫效率高且能耗低,该技术工艺中,液体吸收催化剂的再生过程通常是在再生塔中,塔身设置硫泡沫溢流管,利用泡沫带出硫磺,硫泡沫经加热熔融脱水,分离硫磺和水相,或者硫泡沫在储罐中存储后用过滤机固液分离,脱除硫磺,此外在液体催化剂体系中加入化学消泡剂,抑制和消除泡沫层,让硫磺颗粒沉入设备底部,通过泵送,进行过滤脱除硫磺。Hydrogen sulfide is a very toxic compound, widely present in a variety of gases involved in industrial production and civil life. Hydrogen sulfide is an acid gas with high toxicity and strong corrosiveness. The removal of hydrogen sulfide in the gas is an industrial Common processes in production, commonly used technologies for removing hydrogen sulfide include solid-phase chemical absorption method, gas-solid phase catalytic oxidation method, and gas-liquid phase catalytic oxidation method. The desulfurization efficiency is high and the energy consumption is low. In this technical process, the regeneration process of the liquid absorption catalyst is usually in the regeneration tower. The tower body is equipped with a sulfur foam overflow pipe, and the sulfur is carried out by the foam. The sulfur foam is heated and melted and dehydrated to separate the sulfur. and water phase, or sulfur foam after storage in storage tank, use filter to separate solid and liquid to remove sulfur, in addition, chemical defoamer is added to liquid catalyst system to suppress and eliminate foam layer, so that sulfur particles sink to the bottom of equipment, By pumping, filtering is performed to remove sulfur.

目前,往塔内鼓入空气时,液面会产生大量含硫磺颗粒的泡沫,硫泡沫极易在再生塔内产生结垢、堵塞以及处理硫泡沫导致的流程设备运行较为复杂,而且设备维护也比较困难。At present, when air is blown into the tower, a large amount of foam containing sulfur particles will be produced on the liquid level. tougher.

发明内容SUMMARY OF THE INVENTION

(一)解决的技术问题(1) Technical problems solved

针对现有技术的不足,本发明提供了一种用于气液相催化氧化法脱硫化氢工艺的再生塔,可以提高空气氧化效率,避免硫泡沫导致的结垢、堵塞以及处理硫泡沫导致的流程设备运行复杂,而且维护也简单,解决了再生塔鼓入空气时,液面会产生大量含硫磺颗粒的泡沫,硫泡沫极易在再生塔内产生结垢、堵塞以及处理硫泡沫导致的流程设备运行较为复杂,而且设备维护也比较困难的问题。In view of the deficiencies of the prior art, the present invention provides a regeneration tower for a gas-liquid phase catalytic oxidation process for removing hydrogen sulfide, which can improve the air oxidation efficiency, avoid scaling and blockage caused by sulfur foam, and treat the problems caused by sulfur foam. The operation of the process equipment is complicated and the maintenance is also simple, which solves the problem that when the regeneration tower is blown into the air, a large amount of foam containing sulfur particles will be generated on the liquid surface. Equipment operation is more complicated, and equipment maintenance is also more difficult.

(二)技术方案(2) Technical solutions

为实现上述的目的,本发明提供如下技术方案:一种用于气液相催化氧化法脱硫化氢工艺的再生塔,包括筒体、裙座和盖板,所述裙座与筒体的侧壁固定固定连接,所述筒体的上端设有开口,且开口处通过锁扣与盖板紧固连接,所述筒体的右端固定连接有进液管,所述进液管的一端延伸至筒体内,所述盖板的上端对称固定连接有两个排气管,所述筒体的下端中心处固定连接有排液管,所述盖板的上端通过圆孔固定连接有壳体,且壳体内连接有传动机构,所述筒体内固定连接有多个均匀分布的横杆,多个所述横杆相对的一端共同固定连接有定位环,所述定位环内滑动套接有套筒,且套筒的侧壁连接有发泡机构,所述筒体的左端下侧固定连接有进气管,所述进气管的一端延伸至筒体内并固定连接有曝气头,所述套筒内固定连接有进液头,所述定位环的一侧通过通孔与进液管的管口处固定连接。In order to achieve the above-mentioned purpose, the present invention provides the following technical solutions: a regeneration tower for the gas-liquid phase catalytic oxidation process for removing hydrogen sulfide, comprising a cylinder, a skirt and a cover plate, the skirt and the side of the cylinder are The wall is fixed and connected, the upper end of the cylinder is provided with an opening, and the opening is fastened to the cover plate through a lock, the right end of the cylinder is fixedly connected with a liquid inlet pipe, and one end of the liquid inlet pipe extends to In the cylinder, two exhaust pipes are symmetrically and fixedly connected to the upper end of the cover plate, a drain pipe is fixedly connected to the center of the lower end of the cylinder body, and the upper end of the cover plate is fixedly connected to a casing through a circular hole, and A transmission mechanism is connected in the casing, a plurality of evenly distributed transverse rods are fixedly connected in the cylinder, a positioning ring is fixedly connected with the opposite ends of the plurality of transverse rods, and a sleeve is slidably sleeved in the positioning ring, And the side wall of the sleeve is connected with a foaming mechanism, the lower side of the left end of the cylinder is fixedly connected with an air inlet pipe, one end of the air inlet pipe extends into the cylinder and is fixedly connected with an aeration head, and the sleeve is fixed inside. A liquid inlet head is connected, and one side of the positioning ring is fixedly connected with the nozzle of the liquid inlet pipe through a through hole.

优选的,所述传动机构包括套管,所述套管的管壁通过第一密封轴承与壳体的下端中心处转动连接,所述套管内通过第二密封轴承转动连接有转轴,所述转轴的轴壁上固定连接有多个均匀分布的传动杆,多个所述传动杆远离转轴的一端均倾斜固定连接有刮板,多个所述刮板的下端共同滑动连接有喇叭状结构的导管,且导管的下端与套筒的上端固定连接,所述壳体内固定连接有电机,所述电机的输出端与转轴的上端固定连接。Preferably, the transmission mechanism includes a sleeve, the pipe wall of the sleeve is rotatably connected to the center of the lower end of the casing through a first sealing bearing, and a rotating shaft is rotatably connected in the sleeve through a second sealing bearing, and the rotating shaft A plurality of evenly distributed transmission rods are fixedly connected to the shaft wall of the shaft, and one end of the plurality of transmission rods away from the rotating shaft is obliquely and fixedly connected with a scraper, and the lower ends of the plurality of scrapers are jointly slidably connected with a pipe with a horn-shaped structure. , and the lower end of the conduit is fixedly connected with the upper end of the sleeve, a motor is fixedly connected in the casing, and the output end of the motor is fixedly connected with the upper end of the rotating shaft.

优选的,所述套管的管壁上固定连接有多个均匀分布的支撑杆,多个所述支撑杆远离套管的一端均固定连接有斜板,所述套管的管壁上固定连接有齿圈,所述转轴的轴壁上固定连接有第一带轮,所述壳体的下端内壁通过滚珠轴承转动连接有传动轴,所述传动轴的轴壁上固定连接有第二带轮和齿轮,所述第一带轮与第二带轮之间共同绕接有皮带,所述齿轮与齿圈啮合。Preferably, a plurality of evenly distributed support rods are fixedly connected to the pipe wall of the casing, and inclined plates are fixedly connected to one end of the plurality of support rods away from the casing, and the pipe wall of the casing is fixedly connected There is a ring gear, a first pulley is fixedly connected to the shaft wall of the rotating shaft, a transmission shaft is rotatably connected to the inner wall of the lower end of the casing through a ball bearing, and a second pulley is fixedly connected to the shaft wall of the transmission shaft and a gear, a belt is jointly wound between the first pulley and the second pulley, and the gear meshes with the ring gear.

优选的,所述套筒内套接有叶轮,所述转轴的下端延伸至套筒内并与叶轮的中心处固定连接,所述套筒内固定连接有网孔板,所述网孔板的中心处通过圆口与转轴的轴壁套接。Preferably, an impeller is sleeved in the sleeve, the lower end of the rotating shaft extends into the sleeve and is fixedly connected with the center of the impeller, and a mesh plate is fixedly connected in the sleeve, and the mesh plate is The center is sleeved with the shaft wall of the rotating shaft through a round mouth.

优选的,所述发泡机构包括圆管,所述圆管的上端固定连接有橡胶圈,所述圆管的侧壁固定连接有环形板,且环形板的侧壁开设有过液通道,所述环形板的边缘处与筒体的内壁固定连接,所述圆管的管壁上固定连接有多个L形管,多个所述L形管的竖直部上端均固定连接有弧形管,所述套筒的下端固定连接有限位环,所述限位环与圆管的管壁滑动套接,所述套筒的侧壁通过斜孔固定连接有多个倾斜设置的引流管。Preferably, the foaming mechanism comprises a circular tube, the upper end of the circular tube is fixedly connected with a rubber ring, the side wall of the circular tube is fixedly connected with an annular plate, and the side wall of the annular plate is provided with a liquid passage, so The edge of the annular plate is fixedly connected with the inner wall of the cylinder, the pipe wall of the circular pipe is fixedly connected with a plurality of L-shaped pipes, and the upper ends of the vertical parts of the plurality of L-shaped pipes are fixedly connected with arc-shaped pipes. The lower end of the sleeve is fixedly connected with a limit ring, the limit ring is slidably sleeved with the pipe wall of the round pipe, and the side wall of the sleeve is fixedly connected with a plurality of inclined drainage pipes through inclined holes.

优选的,所述圆管的下端管口处内沿固定连接有隔板,所述隔板的中心处通过安装孔与进液管的管壁固定连接,所述隔板的侧壁固定连接有两个对称分布的稳压管。Preferably, a partition plate is fixedly connected to the inner edge of the mouth of the lower end of the round pipe, the center of the partition plate is fixedly connected to the pipe wall of the liquid inlet pipe through a mounting hole, and the side wall of the partition plate is fixedly connected with a Two symmetrically distributed Zener tubes.

(三)有益效果(3) Beneficial effects

与现有技术相比,本发明提供了一种用于气液相催化氧化法脱硫化氢工艺的再生塔,具备以下有益效果:Compared with the prior art, the present invention provides a regeneration tower for the gas-liquid phase catalytic oxidation process for removing hydrogen sulfide, which has the following beneficial effects:

1、本发明在使用的时候,将进气管与外部的气源装置,将含有硫化氢的富液灌注在筒体内,将泵送设备的输出端与进液管进行连接,用于泵送富液,在气体从进气管中经过曝气头进入到套筒内,经过曝气头排出的气泡在套筒内上浮时形成空气泡,空气泡上升到液面时会出现含有硫磺颗粒的泡沫,此时启动传动机构工作,传动机构工作时消除上升的气泡层,进而避免气泡结垢和堵塞,在气泡破碎时,硫磺颗粒在传动机构的作用下集中在筒体内壁并下落,进而能够在筒体与套筒之间的夹缝之间下落,硫磺颗粒逐渐沉淀在筒体底部,从而能够便于从排液管中抽出筒体进行进行过滤。1. When the present invention is in use, the air inlet pipe is connected to the external air source device, the rich liquid containing hydrogen sulfide is poured into the cylinder, and the output end of the pumping equipment is connected with the liquid inlet pipe for pumping rich liquid. When the gas enters the sleeve from the air inlet pipe through the aeration head, the air bubbles discharged through the aeration head form air bubbles when they float in the sleeve. When the air bubbles rise to the liquid surface, foam containing sulfur particles will appear. At this time, the transmission mechanism is started to work. When the transmission mechanism is working, the rising bubble layer is eliminated, thereby avoiding the fouling and clogging of the bubbles. When the bubbles are broken, the sulfur particles are concentrated on the inner wall of the cylinder under the action of the transmission mechanism and fall down, which can then be trapped in the cylinder. The sulphur particles are gradually precipitated at the bottom of the cylinder body and fall between the gap between the body and the sleeve, so that the cylinder body can be easily drawn out from the drain pipe for filtration.

2、本发明设置有的传动机构,在使用时,启动电机带动转轴旋转,转轴旋转带动传动杆使刮板做圆周运动,刮板运动时能够对导管内的空气泡产生离心力,进而使空气泡快速排出套筒,在转轴旋转时带动第一带轮使第二带轮旋转,第二带轮旋转带动传动轴使齿轮旋转,齿轮旋转带动齿圈使套管旋转,套管旋转时带动支撑杆使斜板做圆周运动,由于第一带轮和第二带轮的转向相同,而齿轮与齿圈相反,由于第二带轮与齿轮的转向相同,因此可知转轴与套管的转向相反,因此由刮板刮离的空气泡在被反向旋转的斜板撞击改变运动方向,进而能够使空气泡中的硫磺颗粒具备落入富液的初速度,有利于硫磺颗粒沉淀,且含有的硫磺颗粒的空气泡也不易结垢和堵塞,并且转轴旋转时带动叶轮在套筒内旋转,叶轮旋转时能够在套筒内对富液产生上升的推力,有利于富液筒体内流动。2. The transmission mechanism provided in the present invention, when in use, starts the motor to drive the rotating shaft to rotate, and the rotating shaft rotates to drive the transmission rod to make the scraper make a circular motion. Quickly discharge the sleeve, drive the first pulley to rotate the second pulley when the shaft rotates, the second pulley rotates to drive the transmission shaft to rotate the gear, the gear rotates to drive the ring gear to rotate the casing, and the casing rotates to drive the support rod Make the swash plate make a circular motion. Since the steering of the first pulley and the second pulley is the same, and the gear is opposite to the ring gear, since the second pulley and the gear have the same steering, it can be seen that the rotation of the shaft and the casing is opposite, so The air bubbles scraped off by the scraper are impacted by the counter-rotating inclined plate to change the direction of movement, so that the sulfur particles in the air bubbles can have the initial velocity of falling into the rich liquid, which is conducive to the precipitation of the sulfur particles, and the sulfur particles contained in the air bubbles. The air bubbles are not easy to scale and block, and when the rotating shaft rotates, the impeller rotates in the sleeve, and when the impeller rotates, it can generate a rising thrust to the rich liquid in the sleeve, which is conducive to the flow of the rich liquid cylinder.

3、本发明设置有的发泡机构,传动机构带动套筒内的富液流动时,液体经过环形板上的过液通道进入到筒体下端,筒体底部的液体经过稳压管上升至圆管内,圆管内的液体上升经过引流管排至筒体内,进而形成循环流动,由于稳压管的通过量较小,因此在筒体内的液体经过弧形管进入到L形管内,L形管内的富液大量进入到圆管内,进而保证筒体内富液循环流动的顺畅,并且由于弧形管的特殊结构,且硫磺颗粒进入到筒体内液面处的速度较快,因此弧形管内不易随富液进入大量的硫磺颗粒,且富液经过环形板上的过液通道时能够带走硫磺颗粒进入到筒体底部,由于筒体底部的富液流速较慢,因此有利于硫磺颗粒沉淀,便于抽出硫磺颗粒,也方便对再生塔进行维护。3. The present invention is provided with a foaming mechanism. When the transmission mechanism drives the rich liquid in the sleeve to flow, the liquid enters the lower end of the cylinder through the liquid passage on the annular plate, and the liquid at the bottom of the cylinder rises to the circular cylinder through the voltage stabilizer tube. In the tube, the liquid in the round tube rises through the drainage tube and is discharged into the cylinder, thereby forming a circulating flow. Because the throughput of the voltage stabilizer tube is small, the liquid in the cylinder enters the L-shaped tube through the arc tube, and the liquid in the L-shaped tube A large amount of rich liquid enters the circular tube, thereby ensuring the smooth circulation of rich liquid in the cylinder, and due to the special structure of the arc-shaped tube, and the speed of the sulfur particles entering the liquid surface in the cylinder is relatively fast, so the arc-shaped tube is not easy to follow the rich liquid. The liquid enters a large number of sulfur particles, and when the rich liquid passes through the liquid passage on the annular plate, it can take away the sulfur particles and enter the bottom of the cylinder. Because the flow rate of the rich liquid at the bottom of the cylinder is slow, it is conducive to the precipitation of the sulfur particles and facilitates extraction. Sulphur pellets also facilitate maintenance of the regeneration tower.

附图说明Description of drawings

图1为本发明提出的一种用于气液相催化氧化法脱硫化氢工艺的再生塔结构示意图;Fig. 1 is a kind of regenerating tower structure schematic diagram for gas-liquid phase catalytic oxidation dehydrogen sulfide technology proposed by the present invention;

图2为本发明提出的一种用于气液相催化氧化法脱硫化氢工艺的再生塔图1中筒体的内部结构示意图;Fig. 2 is a kind of regenerating tower that the present invention proposes and is used for the gas-liquid phase catalytic oxidation method to remove hydrogen sulfide technology The internal structure schematic diagram of the cylinder in Fig. 1;

图3为本发明提出的一种用于气液相催化氧化法脱硫化氢工艺的再生塔图1中筒体和套筒的剖视图;Fig. 3 is a kind of sectional view of the cylinder and the sleeve in Fig. 1 of the regeneration tower proposed by the present invention for the gas-liquid phase catalytic oxidation process for removing hydrogen sulfide;

图4为本发明提出的一种用于气液相催化氧化法脱硫化氢工艺的再生塔图2中的传动机构的结构示意图;Fig. 4 is a kind of structural representation of the transmission mechanism in Fig. 2 of the regeneration tower proposed by the present invention for the gas-liquid phase catalytic oxidation process for removing hydrogen sulfide;

图5为本发明提出的一种用于气液相催化氧化法脱硫化氢工艺的再生塔图2中圆管和L形管的结构示意图;Fig. 5 is a kind of regenerating tower that the present invention proposes for the gas-liquid phase catalytic oxidation method to remove hydrogen sulfide technology The structural representation of round pipe and L-shaped pipe in Fig. 2;

图6为本发明提出的一种用于气液相催化氧化法脱硫化氢工艺的再生塔图2中发泡机构的结构示意图。FIG. 6 is a schematic structural diagram of the foaming mechanism in FIG. 2 of a regeneration tower for a gas-liquid phase catalytic oxidation process for removing hydrogen sulfide proposed by the present invention.

图中:1、筒体;2、排气管;3、壳体;4、盖板;5、进气管;6、裙座;7、排液管;8、进液管;9、电机;10、导管;11、套筒;12、横杆;13、弧形管;14、L形管;15、限位环;16、定位环;17、引流管;18、圆管;19、环形板;20、斜板;21、刮板;22、网孔板;23、叶轮;24、隔板;25、曝气头;26、传动杆;27、支撑杆;28、第一带轮;29、齿圈;30、第二带轮;31、齿轮;32、转轴;33、套管;34、橡胶圈;35、稳压管;36、进液头。In the figure: 1. Cylinder body; 2. Exhaust pipe; 3. Shell; 4. Cover plate; 5. Intake pipe; 6. Skirt; 7. Discharge pipe; 8. Liquid inlet pipe; 9. Motor; 10, catheter; 11, sleeve; 12, cross bar; 13, arc tube; 14, L-shaped tube; 15, limit ring; 16, positioning ring; 17, drainage tube; 18, round tube; 19, annular Plate; 20, inclined plate; 21, scraper; 22, mesh plate; 23, impeller; 24, partition plate; 25, aeration head; 26, transmission rod; 27, support rod; 28, first pulley; 29, ring gear; 30, second pulley; 31, gear; 32, shaft; 33, casing; 34, rubber ring; 35, stabilizer tube; 36, liquid inlet.

具体实施方式Detailed ways

下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

实施例1:Example 1:

参照附图1-6,一种用于气液相催化氧化法脱硫化氢工艺的再生塔,包括筒体1、裙座6和盖板4,裙座6与筒体1的侧壁固定固定连接,筒体1的上端设有开口,且开口处通过锁扣与盖板4紧固连接,筒体1的右端固定连接有进液管8,进液管8的一端延伸至筒体1内,盖板4的上端对称固定连接有两个排气管2,筒体1的下端中心处固定连接有排液管7,盖板4的上端通过圆孔固定连接有壳体3,且壳体3内连接有传动机构,筒体1内固定连接有多个均匀分布的横杆12,多个横杆12相对的一端共同固定连接有定位环16,定位环16内滑动套接有套筒11,且套筒11的侧壁连接有发泡机构,筒体1的左端下侧固定连接有进气管5,进气管5的一端延伸至筒体1内并固定连接有曝气头25,套筒11内固定连接有进液头36,定位环16的一侧通过通孔与进液管8的管口处固定连接。With reference to accompanying drawing 1-6, a kind of regeneration tower that is used for gas-liquid phase catalytic oxidation process for removing hydrogen sulfide technology, comprises cylinder 1, skirt 6 and cover plate 4, and the side wall of skirt 6 and cylinder 1 is fixed and fixed The upper end of the cylinder body 1 is provided with an opening, and the opening is tightly connected with the cover plate 4 through a lock; , the upper end of the cover plate 4 is symmetrically and fixedly connected with two exhaust pipes 2, the center of the lower end of the cylinder body 1 is fixedly connected with a drain pipe 7, and the upper end of the cover plate 4 is fixedly connected with a casing 3 through a circular hole, and the casing 3. A transmission mechanism is connected inside, and a plurality of evenly distributed transverse rods 12 are fixedly connected in the cylinder body 1. The opposite ends of the plurality of transverse rods 12 are fixedly connected with a positioning ring 16. The positioning ring 16 is slidably sleeved with a sleeve 11. , and the side wall of the sleeve 11 is connected with a foaming mechanism, the lower side of the left end of the cylinder body 1 is fixedly connected with an air inlet pipe 5, one end of the air inlet pipe 5 extends into the cylinder body 1 and is fixedly connected with an aeration head 25, the sleeve A liquid inlet head 36 is fixedly connected inside 11 , and one side of the positioning ring 16 is fixedly connected to the nozzle of the liquid inlet pipe 8 through a through hole.

本发明在使用的时候,将进气管与外部的气源装置(图中未示出),将含有硫化氢的富液(充分吸收硫化氢后的液体吸收催化剂)灌注在筒体1内,将泵送设备(图中未示出)的输出端与进液管8进行连接,用于泵送富液,在气体从进气管5中经过曝气头25进入到套筒11内,经过曝气头25排出的气泡在套筒11内上浮时形成空气泡,空气泡上升到液面时会出现含有硫磺颗粒的泡沫,此时启动传动机构工作,传动机构工作时消除上升的气泡层,进而避免气泡结垢和堵塞,在气泡破碎时,硫磺颗粒在传动机构的作用下集中在筒体1内壁并下落,进而能够在筒体1与套筒11之间的夹缝之间下落,硫磺颗粒逐渐沉淀在筒体1底部,从而能够便于从排液管7中抽出筒体1进行进行过滤。When the present invention is in use, the intake pipe and the external air source device (not shown in the figure) are poured into the cylinder 1 with the rich liquid containing hydrogen sulfide (liquid absorption catalyst after fully absorbing hydrogen sulfide), and the The output end of the pumping device (not shown in the figure) is connected to the liquid inlet pipe 8 for pumping the rich liquid. The gas enters the sleeve 11 from the gas inlet pipe 5 through the aeration head 25 and passes through the aeration head. The air bubbles discharged from the head 25 form air bubbles when they float up in the sleeve 11. When the air bubbles rise to the liquid surface, foam containing sulfur particles will appear. At this time, the transmission mechanism is started to work, and the rising bubble layer is eliminated when the transmission mechanism works, thereby avoiding Bubble scaling and clogging, when the bubbles are broken, the sulfur particles are concentrated on the inner wall of the cylinder 1 and fall under the action of the transmission mechanism, and then can fall between the gap between the cylinder 1 and the sleeve 11, and the sulfur particles gradually precipitate. At the bottom of the cylindrical body 1, it is convenient to extract the cylindrical body 1 from the drain pipe 7 for filtering.

实施例2:基于实施例1有所不同的是;Embodiment 2: What is different based on Embodiment 1 is;

参照附图2-4,传动机构包括套管33,套管33的管壁通过第一密封轴承与壳体3的下端中心处转动连接,套管33内通过第二密封轴承转动连接有转轴32,转轴32的轴壁上固定连接有多个均匀分布的传动杆26,多个传动杆26远离转轴32的一端均倾斜固定连接有刮板21,多个刮板21的下端共同滑动连接有喇叭状结构的导管10,且导管10的下端与套筒11的上端固定连接,壳体3内固定连接有电机9,电机9的输出端与转轴32的上端固定连接,套管33的管壁上固定连接有多个均匀分布的支撑杆27,多个支撑杆27远离套管33的一端均固定连接有斜板20,套管33的管壁上固定连接有齿圈29,转轴32的轴壁上固定连接有第一带轮28,壳体3的下端内壁通过滚珠轴承转动连接有传动轴,传动轴的轴壁上固定连接有第二带轮30和齿轮31,第一带轮28与第二带轮30之间共同绕接有皮带,齿轮31与齿圈29啮合,套筒11内套接有叶轮23,转轴32的下端延伸至套筒11内并与叶轮23的中心处固定连接,套筒11内固定连接有网孔板22,网孔板22的中心处通过圆口与转轴32的轴壁套接。2-4, the transmission mechanism includes a casing 33, the wall of the casing 33 is rotatably connected to the center of the lower end of the casing 3 through a first sealed bearing, and a rotating shaft 32 is rotatably connected in the casing 33 through a second sealed bearing , the shaft wall of the rotating shaft 32 is fixedly connected with a plurality of evenly distributed transmission rods 26, the ends of the plurality of transmission rods 26 away from the rotating shaft 32 are all inclined and fixedly connected with the scraper 21, and the lower ends of the plurality of scrapers 21 are slidably connected with a horn The lower end of the catheter 10 is fixedly connected with the upper end of the sleeve 11, the motor 9 is fixedly connected in the housing 3, the output end of the motor 9 is fixedly connected with the upper end of the rotating shaft 32, and the tube wall of the sleeve 33 is fixedly connected. A plurality of evenly distributed support rods 27 are fixedly connected, and one end of the plurality of support rods 27 away from the sleeve 33 is fixedly connected with a swash plate 20 . A first pulley 28 is fixedly connected to the top, a transmission shaft is rotatably connected to the inner wall of the lower end of the housing 3 through a ball bearing, and a second pulley 30 and a gear 31 are fixedly connected to the shaft wall of the transmission shaft. A belt is commonly wound between the two pulleys 30, the gear 31 meshes with the ring gear 29, the sleeve 11 is sleeved with the impeller 23, the lower end of the rotating shaft 32 extends into the sleeve 11 and is fixedly connected to the center of the impeller 23, A mesh plate 22 is fixedly connected in the sleeve 11 , and the center of the mesh plate 22 is sleeved with the shaft wall of the rotating shaft 32 through a circular opening.

本发明设置有的传动机构,在使用时,启动电机9带动转轴32旋转,转轴32旋转带动传动杆26使刮板21做圆周运动,刮板21运动时能够对导管10内的空气泡产生离心力,进而使空气泡快速排出套筒11,在转轴32旋转时带动第一带轮28使皮带驱动第二带轮30旋转,第二带轮30旋转带动传动轴使齿轮31旋转,齿轮31旋转带动齿圈29使套管33旋转,套管33旋转时带动支撑杆27使斜板20做圆周运动,由于第一带轮28和第二带轮30的转向相同,而齿轮31与齿圈29相反,由于第二带轮30与齿轮31的转向相同,因此可知转轴32与套管33的转向相反,因此由刮板21刮离的空气泡在被反向旋转的斜板20撞击改变运动方向,进而能够使空气泡中的硫磺颗粒具备落入富液的初速度,有利于硫磺颗粒沉淀,且含有的硫磺颗粒的空气泡也不易结垢和堵塞,并且转轴32旋转时带动叶轮23在套筒11内旋转,叶轮23旋转时能够在套筒11内对富液产生上升的推力,有利于富液筒体1内流动。The transmission mechanism provided in the present invention, when in use, starts the motor 9 to drive the rotating shaft 32 to rotate, and the rotating shaft 32 rotates to drive the transmission rod 26 to make the scraper 21 make a circular motion. When the scraper 21 moves, it can generate centrifugal force on the air bubbles in the conduit 10 Then, the air bubbles are quickly discharged from the sleeve 11, and when the rotating shaft 32 rotates, the first pulley 28 is driven to make the belt drive the second pulley 30 to rotate, the second pulley 30 rotates to drive the transmission shaft to rotate the gear 31, and the rotation of the gear 31 drives The ring gear 29 makes the sleeve 33 rotate. When the sleeve 33 rotates, it drives the support rod 27 to make the swash plate 20 make a circular motion. Since the first pulley 28 and the second pulley 30 have the same steering, the gear 31 is opposite to the ring gear 29 , since the steering of the second pulley 30 and the gear 31 is the same, it can be seen that the steering of the rotating shaft 32 and the sleeve 33 is opposite, so the air bubbles scraped off by the scraper 21 are hit by the counter-rotating swash plate 20 to change the direction of movement, Furthermore, the sulfur particles in the air bubbles can have the initial velocity of falling into the rich liquid, which is conducive to the precipitation of the sulfur particles, and the air bubbles containing the sulfur particles are not easy to be scaled and blocked, and when the rotating shaft 32 rotates, the impeller 23 is driven in the sleeve. 11 , when the impeller 23 rotates, it can generate a rising thrust to the rich liquid in the sleeve 11 , which is beneficial to the flow in the rich liquid cylinder 1 .

实施例3:基于实施例1有所不同的是;Embodiment 3: The difference based on Embodiment 1 is;

参照附图5-6,发泡机构包括圆管18,圆管18的上端固定连接有橡胶圈34,圆管18的侧壁固定连接有环形板19,且环形板19的侧壁开设有过液通道,环形板19的边缘处与筒体1的内壁固定连接,圆管18的管壁上固定连接有多个L形管14,多个L形管14的竖直部上端均固定连接有弧形管13,套筒11的下端固定连接有限位环15,限位环15与圆管18的管壁滑动套接,套筒11的侧壁通过斜孔固定连接有多个倾斜设置的引流管17,圆管18的下端管口处内沿固定连接有隔板24,隔板24的中心处通过安装孔与进液管8的管壁固定连接,隔板24的侧壁固定连接有两个对称分布的稳压管35。5-6, the foaming mechanism includes a circular tube 18, the upper end of the circular tube 18 is fixedly connected with a rubber ring 34, the side wall of the circular tube 18 is fixedly connected with an annular plate 19, and the side wall of the annular plate 19 is provided with a Liquid channel, the edge of the annular plate 19 is fixedly connected with the inner wall of the cylinder body 1, the pipe wall of the circular pipe 18 is fixedly connected with a plurality of L-shaped pipes 14, and the upper ends of the vertical parts of the plurality of L-shaped pipes 14 are fixedly connected with The arc-shaped tube 13, the lower end of the sleeve 11 is fixedly connected with a limit ring 15, the limit ring 15 is slidably sleeved with the tube wall of the round tube 18, and the side wall of the sleeve 11 is fixedly connected with a plurality of inclined drainage through the inclined holes Pipe 17, the inner edge of the lower end of the round pipe 18 is fixedly connected with a partition 24, the center of the partition 24 is fixedly connected with the pipe wall of the liquid inlet pipe 8 through the mounting hole, and the side wall of the partition 24 is fixedly connected with two. There are symmetrically distributed voltage regulator tubes 35 .

本发明设置有的发泡机构,传动机构带动套筒11内的富液流动时,液体经过环形板19上的过液通道进入到筒体1下端,筒体1底部的液体经过稳压管35上升至圆管18内,圆管18内的液体上升经过引流管17排至筒体1内,进而形成循环流动,由于稳压管35的通过量较小,因此在筒体1内的液体经过弧形管13进入到L形管14内,L形管14内的富液大量进入到圆管18内,进而保证筒体1内富液循环流动的顺畅,并且由于弧形管13的特殊结构,且硫磺颗粒进入到筒体1内液面处的速度较快,因此弧形管13内不易随富液进入大量的硫磺颗粒,且富液经过环形板19上的过液通道时能够带走硫磺颗粒进入到筒体1底部,由于筒体1底部的富液流速较慢,因此有利于硫磺颗粒沉淀,而且也方便对再生塔进行维护。The present invention is provided with a foaming mechanism. When the transmission mechanism drives the rich liquid in the sleeve 11 to flow, the liquid enters the lower end of the cylinder 1 through the liquid passage on the annular plate 19, and the liquid at the bottom of the cylinder 1 passes through the pressure-stabilizing tube 35. Rising into the circular tube 18, the liquid in the circular tube 18 rises up through the drainage tube 17 and is discharged into the cylinder body 1, thereby forming a circulating flow. The arc-shaped pipe 13 enters the L-shaped pipe 14, and the rich liquid in the L-shaped pipe 14 enters the circular pipe 18 in large quantities, thereby ensuring the smooth circulation of the rich liquid in the cylinder 1, and due to the special structure of the arc-shaped pipe 13 , and the speed of the sulfur particles entering the liquid level in the cylinder body 1 is relatively fast, so it is difficult for the arc-shaped pipe 13 to enter a large number of sulfur particles with the rich liquid, and the rich liquid can be taken away when it passes through the liquid passage on the annular plate 19. The sulfur particles enter the bottom of the cylinder body 1. Since the flow rate of the rich liquid at the bottom of the cylinder body 1 is relatively slow, it is conducive to the precipitation of the sulfur particles, and also facilitates the maintenance of the regeneration tower.

需要说明的是,术语“包括”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。在没有更多限制的情况下,由语句“包括一个……”限定的要素,并不排除在包括所述要素的过程、方法、物品或者设备中还存在另外的相同要素。It should be noted that the term "comprising" or any other variation thereof is intended to encompass a non-exclusive inclusion such that a process, method, article or device comprising a series of elements includes not only those elements, but also not expressly listed Other elements, or elements that are inherent to such a process, method, article or apparatus. Without further limitation, an element qualified by the phrase "comprising a..." does not preclude the presence of additional identical elements in a process, method, article or apparatus that includes the element.

尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, and substitutions can be made in these embodiments without departing from the principle and spirit of the invention and modifications, the scope of the present invention is defined by the appended claims and their equivalents.

Claims (5)

1.一种用于气液相催化氧化法脱硫化氢工艺的再生塔,包括筒体(1)、裙座(6)和盖板(4),所述裙座(6)与筒体(1)的侧壁固定连接,所述筒体(1)的上端设有开口,且开口处通过锁扣与盖板(4)紧固连接,所述筒体(1)的右端固定连接有进液管(8),所述进液管(8)的一端延伸至筒体(1)内,所述盖板(4)的上端对称固定连接有两个排气管(2),所述筒体(1)的下端中心处固定连接有排液管(7),其特征在于:所述盖板(4)的上端通过圆孔固定连接有壳体(3),且壳体(3)内连接有传动机构,所述筒体(1)内固定连接有多个均匀分布的横杆(12),多个所述横杆(12)相对的一端共同固定连接有定位环(16),所述定位环(16)内滑动套接有套筒(11),且套筒(11)的侧壁连接有发泡机构,所述发泡机构包括圆管(18),所述圆管(18)的上端固定连接有橡胶圈(34),所述圆管(18)的侧壁固定连接有环形板(19),且环形板(19)的侧壁开设有过液通道,所述环形板(19)的边缘处与筒体(1)的内壁固定连接,所述圆管(18)的管壁上固定连接有多个L形管(14),多个所述L形管(14)的竖直部上端均固定连接有弧形管(13),所述套筒(11)的下端固定连接有限位环(15),所述限位环(15)与圆管(18)的管壁滑动套接,所述套筒(11)的侧壁通过斜孔固定连接有多个倾斜设置的引流管(17),所述筒体(1)的左端下侧固定连接有进气管(5),所述进气管(5)的一端延伸至筒体(1)内并固定连接有曝气头(25),所述套筒(11)内固定连接有进液头(36),所述定位环(16)的一侧通过通孔与进液管(8)的管口处固定连接。1. A regeneration tower for a gas-liquid phase catalytic oxidation process for removing hydrogen sulfide, comprising a cylindrical body (1), a skirt seat (6) and a cover plate (4), the skirt seat (6) and the cylindrical body ( 1) is fixedly connected to the side wall, the upper end of the cylinder (1) is provided with an opening, and the opening is fastened to the cover plate (4) through a lock, and the right end of the cylinder (1) is fixedly connected with an inlet. A liquid pipe (8), one end of the liquid inlet pipe (8) extends into the cylinder (1), and two exhaust pipes (2) are symmetrically and fixedly connected to the upper end of the cover plate (4). A drain pipe (7) is fixedly connected to the center of the lower end of the body (1). A transmission mechanism is connected, a plurality of evenly distributed transverse rods (12) are fixedly connected in the cylinder body (1), and a positioning ring (16) is fixedly connected with the opposite ends of the plurality of transverse rods (12). A sleeve (11) is slidably sleeved in the positioning ring (16), and a foaming mechanism is connected to the side wall of the sleeve (11). A rubber ring (34) is fixedly connected to the upper end of the circular tube (18), an annular plate (19) is fixedly connected to the side wall of the circular tube (18), and a liquid passage is opened on the side wall of the annular plate (19). The edge of (19) is fixedly connected to the inner wall of the cylinder (1), and the pipe wall of the circular pipe (18) is fixedly connected with a plurality of L-shaped pipes (14), and a plurality of the L-shaped pipes (14) An arc-shaped tube (13) is fixedly connected to the upper end of the vertical part of the sleeve (11), and a limit ring (15) is fixedly connected to the lower end of the sleeve (11), and the limit ring (15) is connected to the tube of the round tube (18). Wall sliding sleeve connection, the side wall of the sleeve (11) is fixedly connected with a plurality of inclined drainage pipes (17) through the inclined holes, and the lower side of the left end of the cylinder body (1) is fixedly connected with the air inlet pipe (5). ), one end of the air inlet pipe (5) extends into the cylinder (1) and is fixedly connected with an aeration head (25), and a liquid inlet head (36) is fixedly connected in the sleeve (11), and the One side of the positioning ring (16) is fixedly connected with the nozzle of the liquid inlet pipe (8) through the through hole. 2.根据权利要求1所述的一种用于气液相催化氧化法脱硫化氢工艺的再生塔,其特征在于:所述传动机构包括套管(33),所述套管(33)的管壁通过第一密封轴承与壳体(3)的下端中心处转动连接,所述套管(33)内通过第二密封轴承转动连接有转轴(32),所述转轴(32)的轴壁上固定连接有多个均匀分布的传动杆(26),多个所述传动杆(26)远离转轴(32)的一端均倾斜固定连接有刮板(21),多个所述刮板(21)的下端共同滑动连接有喇叭状结构的导管(10),且导管(10)的下端与套筒(11)的上端固定连接,所述壳体(3)内固定连接有电机(9),所述电机(9)的输出端与转轴(32)的上端固定连接。2. A regeneration tower for a gas-liquid phase catalytic oxidation process for removing hydrogen sulfide according to claim 1, characterized in that: the transmission mechanism comprises a casing (33), and the casing (33) has a The tube wall is rotatably connected to the center of the lower end of the casing (3) through a first sealed bearing, and a rotating shaft (32) is rotatably connected in the sleeve (33) through a second sealed bearing, and the shaft wall of the rotating shaft (32) A plurality of evenly distributed transmission rods (26) are fixedly connected to the upper part, and scrapers (21) are fixedly connected at one end of the plurality of transmission rods (26) away from the rotating shaft (32). ) are jointly slidably connected with a conduit (10) of a trumpet-shaped structure, and the lower end of the conduit (10) is fixedly connected with the upper end of the sleeve (11), and a motor (9) is fixedly connected in the housing (3), The output end of the motor (9) is fixedly connected with the upper end of the rotating shaft (32). 3.根据权利要求2所述的一种用于气液相催化氧化法脱硫化氢工艺的再生塔,其特征在于:所述套管(33)的管壁上固定连接有多个均匀分布的支撑杆(27),多个所述支撑杆(27)远离套管(33)的一端均固定连接有斜板(20),所述套管(33)的管壁上固定连接有齿圈(29),所述转轴(32)的轴壁上固定连接有第一带轮(28),所述壳体(3)的下端内壁通过滚珠轴承转动连接有传动轴,所述传动轴的轴壁上固定连接有第二带轮(30)和齿轮(31),所述第一带轮(28)与第二带轮(30)之间共同绕接有皮带,所述齿轮(31)与齿圈(29)啮合。3 . The regeneration tower for a gas-liquid phase catalytic oxidation process for removing hydrogen sulfide according to claim 2 , characterized in that: a plurality of uniformly distributed uniformly distributed Support rods (27), one end of the plurality of support rods (27) away from the sleeve (33) is fixedly connected with a swash plate (20), and a ring gear ( 29), a first pulley (28) is fixedly connected to the shaft wall of the rotating shaft (32), and a transmission shaft is rotatably connected to the inner wall of the lower end of the casing (3) through a ball bearing. A second pulley (30) and a gear (31) are fixedly connected to the upper, and a belt is commonly wound between the first pulley (28) and the second pulley (30). Ring (29) engages. 4.根据权利要求2所述的一种用于气液相催化氧化法脱硫化氢工艺的再生塔,其特征在于:所述套筒(11)内套接有叶轮(23),所述转轴(32)的下端延伸至套筒(11)内并与叶轮(23)的中心处固定连接,所述套筒(11)内固定连接有网孔板(22),所述网孔板(22)的中心处通过圆口与转轴(32)的轴壁套接。4. A regeneration tower for a gas-liquid phase catalytic oxidation process for removing hydrogen sulfide according to claim 2, characterized in that: the sleeve (11) is sleeved with an impeller (23), and the rotating shaft The lower end of (32) extends into the sleeve (11) and is fixedly connected to the center of the impeller (23). ) is sleeved with the shaft wall of the rotating shaft (32) through the round opening. 5.根据权利要求1所述的一种用于气液相催化氧化法脱硫化氢工艺的再生塔,其特征在于:所述圆管(18)的下端管口处内沿固定连接有隔板(24),所述隔板(24)的中心处通过安装孔与进液管(8)的管壁固定连接,所述隔板(24)的侧壁固定连接有两个对称分布的稳压管(35)。5 . The regeneration tower for a gas-liquid phase catalytic oxidation process for removing hydrogen sulfide according to claim 1 , wherein a clapboard is fixedly connected along the inner edge of the lower end of the circular pipe (18). 6 . (24), the center of the partition plate (24) is fixedly connected with the pipe wall of the liquid inlet pipe (8) through the installation hole, and the side wall of the partition plate (24) is fixedly connected with two symmetrically distributed voltage stabilizers. Tube (35).
CN202110933251.5A 2021-08-14 2021-08-14 A kind of regeneration tower for gas-liquid phase catalytic oxidation process for removing hydrogen sulfide Expired - Fee Related CN113856454B (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4111864A (en) * 1974-10-18 1978-09-05 Chevron Research Company Sulfur foam
US4909945A (en) * 1988-07-29 1990-03-20 Union Oil Company Of California Method for increasing the size of elemental sulfur particles produced by a hydrogen sulfide removal process
CN101058078A (en) * 2006-04-18 2007-10-24 向松 Addend preparation method and process for wet oxidation-desulfurizing catalyst
CN111676068A (en) * 2020-07-02 2020-09-18 宁波科新化工工程技术有限公司大连分公司 A desulfurization regeneration tower or top sulfur foam extraction device and process of regeneration tank
CN112138522A (en) * 2020-09-29 2020-12-29 中冶焦耐(大连)工程技术有限公司 Desulfurizing liquid regeneration tank with horizontal jet flow at bottom
CN213286367U (en) * 2020-07-17 2021-05-28 山东红枫环境能源有限公司 Self-suction air type desulfurization solution regeneration tank adopting chemical desulfurization method
CN112958289A (en) * 2021-02-05 2021-06-15 北京中科润宇环保科技股份有限公司 Wet desulfurization sulfur flotation device and method

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5928892B2 (en) * 2012-07-30 2016-06-01 株式会社リコー Foam removing apparatus and foam removing method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4111864A (en) * 1974-10-18 1978-09-05 Chevron Research Company Sulfur foam
US4909945A (en) * 1988-07-29 1990-03-20 Union Oil Company Of California Method for increasing the size of elemental sulfur particles produced by a hydrogen sulfide removal process
CN101058078A (en) * 2006-04-18 2007-10-24 向松 Addend preparation method and process for wet oxidation-desulfurizing catalyst
CN111676068A (en) * 2020-07-02 2020-09-18 宁波科新化工工程技术有限公司大连分公司 A desulfurization regeneration tower or top sulfur foam extraction device and process of regeneration tank
CN213286367U (en) * 2020-07-17 2021-05-28 山东红枫环境能源有限公司 Self-suction air type desulfurization solution regeneration tank adopting chemical desulfurization method
CN112138522A (en) * 2020-09-29 2020-12-29 中冶焦耐(大连)工程技术有限公司 Desulfurizing liquid regeneration tank with horizontal jet flow at bottom
CN112958289A (en) * 2021-02-05 2021-06-15 北京中科润宇环保科技股份有限公司 Wet desulfurization sulfur flotation device and method

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