CN113828109B - Flue gas purification system and its moving bed adsorption tower with distributor - Google Patents
Flue gas purification system and its moving bed adsorption tower with distributor Download PDFInfo
- Publication number
- CN113828109B CN113828109B CN202111081488.1A CN202111081488A CN113828109B CN 113828109 B CN113828109 B CN 113828109B CN 202111081488 A CN202111081488 A CN 202111081488A CN 113828109 B CN113828109 B CN 113828109B
- Authority
- CN
- China
- Prior art keywords
- blanking
- flue gas
- section
- inlets
- moving bed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 96
- 239000003546 flue gas Substances 0.000 title claims abstract description 96
- 238000001179 sorption measurement Methods 0.000 title claims abstract description 76
- 238000000746 purification Methods 0.000 title claims abstract description 14
- 239000000779 smoke Substances 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 14
- 238000011049 filling Methods 0.000 claims abstract description 4
- 239000003463 adsorbent Substances 0.000 claims description 45
- 238000012856 packing Methods 0.000 claims description 19
- 239000004744 fabric Substances 0.000 claims description 13
- 238000001816 cooling Methods 0.000 claims description 12
- 230000002093 peripheral effect Effects 0.000 claims description 10
- 230000000694 effects Effects 0.000 abstract description 9
- 239000000945 filler Substances 0.000 abstract description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- 239000003344 environmental pollutant Substances 0.000 description 5
- 231100000719 pollutant Toxicity 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
- B01D53/08—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds according to the "moving bed" method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
Description
技术领域technical field
本申请涉及烟气处理技术领域,尤其是涉及一种烟气净化系统及其具有分布器的移动床吸附塔。The present application relates to the technical field of flue gas treatment, in particular to a flue gas purification system and a moving bed adsorption tower with a distributor.
背景技术Background technique
燃煤烟气产生大量的污染物是危害大气环境和人类健康的重要因素之一。烟气净化领域通常采用固定床吸附塔对烟气中的污染物进行吸附以实现净化烟气的目的,但是相关技术中的固定床吸附塔在应用时普遍存在填料层压力与密度不均匀、吸附不均匀、吸附效果差、吸附能力随使用时间延长而降低的问题,而且在需要更换吸附剂时需要停止工作,严重影响吸附效率,提高了操作难度。相关技术采用移动床吸附塔通过使吸附剂在塔内流动,克服了固定床吸附塔吸附能力随使用时间延长而降低的问题,但是移动床吸附塔中仍然存在烟气分布不均匀、净化效果不理想的问题。The large amount of pollutants produced by coal combustion flue gas is one of the important factors that endanger the atmospheric environment and human health. In the field of flue gas purification, fixed bed adsorption towers are usually used to adsorb pollutants in flue gas to achieve the purpose of purifying flue gas. The problem of unevenness, poor adsorption effect, and the decrease of adsorption capacity with the extension of use time, and the need to stop working when the adsorbent needs to be replaced, seriously affects the adsorption efficiency and increases the difficulty of operation. The related technology adopts the moving bed adsorption tower to make the adsorbent flow in the tower, so as to overcome the problem that the adsorption capacity of the fixed bed adsorption tower decreases with the prolongation of use time, but there are still uneven distribution of flue gas and poor purification effect in the moving bed adsorption tower. Ideal question.
发明内容Contents of the invention
本发明旨在至少在一定程度上解决相关技术中的技术问题之一。为此,本发明的实施例提出一种移动床吸附塔,具有吸附均匀、吸附效果好的优点。The present invention aims to solve one of the technical problems in the related art at least to a certain extent. For this reason, the embodiment of the present invention proposes a moving bed adsorption tower, which has the advantages of uniform adsorption and good adsorption effect.
本发明的实施例还提出一种包括上述移动床吸附塔的烟气净化系统。Embodiments of the present invention also provide a flue gas purification system comprising the above-mentioned moving bed adsorption tower.
根据本发明实施例的移动床吸附塔,包括塔体,所述塔体内具有空腔,所述塔体设有与所述空腔连通的加料口、出料口、烟气进口和烟气出口,所述空腔在烟气的流通方向上具有进气段、填料段和布料段,所述填料段用于填充吸附剂;分布器,所述分布器设在所述塔体内,所述分布器包括多个落料入口和多个与所述落料入口对应的落料出口,所述分布器位于所述填料段的下方以便所述填料段中的吸附剂通过所述落料入口和对应的所述落料出口流出,其中所述落料入口为方形;多个落料管,多个所述落料管与多个所述落料出口一一对应,所述落料出口位于所述落料管内,所述落料管与所述分布器之间具有间隙以便烟气通过,所述烟气进口位于所述落料入口的下方,所述落料管位于所述出料口的上方。The moving bed adsorption tower according to the embodiment of the present invention includes a tower body, the tower body has a cavity, and the tower body is provided with a feeding port, a material outlet, a flue gas inlet and a flue gas outlet communicating with the cavity , the cavity has an inlet section, a packing section and a cloth section in the flow direction of the flue gas, and the packing section is used to fill the adsorbent; the distributor, the distributor is arranged in the tower body, the distribution The device includes a plurality of blanking inlets and a plurality of blanking outlets corresponding to the blanking inlets, and the distributor is located below the packing section so that the adsorbent in the packing section passes through the blanking inlets and corresponding The blanking outlets flow out, wherein the blanking inlets are square; multiple blanking tubes correspond to multiple blanking outlets one by one, and the blanking outlets are located at the In the drop pipe, there is a gap between the drop pipe and the distributor for flue gas to pass through, the flue gas inlet is located below the drop inlet, and the drop pipe is located above the discharge port .
根据本发明实施例的移动床吸附塔具有吸附均匀、吸附效果好的优点。The moving bed adsorption tower according to the embodiment of the present invention has the advantages of uniform adsorption and good adsorption effect.
在一些实施例中,所述分布器包括分布板和多个分布管,所述落料入口设在所述分布板上,所述分布管与所述分布板的下端面相连并从所述分布板向下延伸,所述分布管为方管,多个所述分布管与多个所述落料入口一一对应,所述分布管的下端设有所述落料出口,多个所述落料管与多个所述分布管一一对应,所述分布管的下端部伸入对应的所述落料管的上端部内,所述落料管的顶端与所述分布板的下端面之间具有缝隙,所述分布管与对应的所述落料管之间具有间隔,所述烟气进口位于所述分布板的下方。In some embodiments, the distributor includes a distribution plate and a plurality of distribution pipes, the blanking inlet is set on the distribution plate, the distribution pipe is connected to the lower end surface of the distribution plate and passes from the distribution plate The plate extends downwards, the distribution pipe is a square pipe, and a plurality of the distribution pipes correspond to a plurality of the blanking inlets, the lower end of the distribution pipe is provided with the blanking outlet, and the plurality of the falling The feeding pipe corresponds to a plurality of the distribution pipes one by one, the lower end of the distribution pipe extends into the upper end of the corresponding feeding pipe, and the top end of the feeding pipe and the lower end surface of the distribution plate There is a gap, there is a space between the distribution pipe and the corresponding drop pipe, and the smoke inlet is located below the distribution plate.
在一些实施例中,所述落料管的顶端与所述分布板的下端面之间的缝隙在竖直方向上的尺寸为20mm-100mm。In some embodiments, the vertical dimension of the gap between the top end of the drop tube and the lower end surface of the distribution plate is 20mm-100mm.
在一些实施例中,所述分布管的外周壁与对应的所述落料管的内周壁之间在水平方向上间隔5mm-40mm。In some embodiments, the distance between the outer peripheral wall of the distribution pipe and the corresponding inner peripheral wall of the drop pipe is 5mm-40mm in the horizontal direction.
在一些实施例中,所述分布管的伸入所述落料管内的部分的长度为5mm-40mmIn some embodiments, the length of the part of the distribution pipe protruding into the discharge pipe is 5mm-40mm
在一些实施例中,多个所述落料入口排列为多排,每排落料入口包括若干所述落料入口,每排落料入口中的若干落料入口沿第一方向间隔排布,多排落料入口在第二方向上间隔排布,所述第一方向和所述第二方向相互垂直,相邻两排落料入口在第二方向上对齐。In some embodiments, the multiple blanking inlets are arranged in multiple rows, each row of blanking inlets includes several blanking inlets, and several blanking inlets in each row of blanking inlets are arranged at intervals along the first direction, Multiple rows of blanking inlets are arranged at intervals in the second direction, the first direction and the second direction are perpendicular to each other, and two adjacent rows of blanking inlets are aligned in the second direction.
在一些实施例中,所述落料入口的边缘为正方形,所述落料入口的边长为150mm-300mm。In some embodiments, the edge of the blanking inlet is square, and the side length of the blanking inlet is 150mm-300mm.
在一些实施例中,在所述第一方向上相邻的两个落料入口之间的间隔为20mm-100mm,在所述第二方向上相邻的两个落料入口之间的间隔为20mm-100mm。In some embodiments, the interval between two adjacent blanking inlets in the first direction is 20mm-100mm, and the interval between two adjacent blanking inlets in the second direction is 20mm-100mm.
在一些实施例中,所述落料管为圆管,所述落料管包括第一段和第二段,所述第一段的直径大于所述第二段的直径,所述第一段的下端与所述第二段的上端相连,所述分布管的下端部伸入对应的所述落料管的所述第一段内。In some embodiments, the feeding tube is a circular tube, and the feeding tube includes a first section and a second section, the diameter of the first section is larger than the diameter of the second section, and the first section The lower end of the distribution pipe is connected to the upper end of the second section, and the lower end of the distribution pipe extends into the corresponding first section of the drop pipe.
根据本发明实施例的烟气净化系统,包括:烟气冷却装置,所述烟气冷却装置具有进烟口和出烟口,所述烟气冷却装置用于将从所述进烟口进入的烟气冷却至室温及以下;移动床吸附塔,所述移动床吸附塔为上述任一项实施例所述的移动床吸附塔,所述烟气冷却装置的出烟口与所述移动床吸附塔的所述烟气出口连通,所述移动床吸附塔用于对所述烟气进行吸附。The flue gas purification system according to the embodiment of the present invention includes: a flue gas cooling device, the flue gas cooling device has a smoke inlet and a smoke outlet, and the flue gas cooling device is used to The flue gas is cooled to room temperature and below; a moving bed adsorption tower, the moving bed adsorption tower is the moving bed adsorption tower described in any one of the above embodiments, and the smoke outlet of the flue gas cooling device is adsorbed with the moving bed The flue gas outlet of the tower is connected, and the moving bed adsorption tower is used for adsorbing the flue gas.
附图说明Description of drawings
图1是根据本发明实施例的移动床吸附塔的正视图。Fig. 1 is a front view of a moving bed adsorption tower according to an embodiment of the present invention.
图2是根据本发明实施例的移动床吸附塔的俯视图。Fig. 2 is a top view of a moving bed adsorption tower according to an embodiment of the present invention.
图3是图2中A-A处的剖视图。Fig. 3 is a cross-sectional view at A-A in Fig. 2 .
图4是图3中B-B处的剖视图。Fig. 4 is a cross-sectional view at B-B in Fig. 3 .
图5是图3中分布器的正视图。Fig. 5 is a front view of the distributor of Fig. 3 .
图6是图3中多个落料管的剖视示意图。FIG. 6 is a schematic cross-sectional view of a plurality of drop tubes in FIG. 3 .
图7是另一个实施例中多个落料管的剖视示意图。Fig. 7 is a schematic cross-sectional view of a plurality of drop tubes in another embodiment.
附图标记:Reference signs:
塔体1;布料段11;加料口111;填料段12;烟气出口121;进气段13;烟气进口131;出料段14;出料口141;
分布器2;分布板21;分布管22;落料入口23;落料出口24;Distributor 2;
落料管3;第一段31;第二段32。Falling tube 3;
具体实施方式Detailed ways
下面详细描述本发明的实施例,所述实施例的示例在附图中示出。下面通过参考附图描述的实施例是示例性的,旨在用于解释本发明,而不能理解为对本发明的限制。Embodiments of the invention are described in detail below, examples of which are illustrated in the accompanying drawings. The embodiments described below by referring to the figures are exemplary and are intended to explain the present invention and should not be construed as limiting the present invention.
如图1至图3所示,根据本发明实施例的移动床吸附塔,包括塔体1,分布器2和多个落料管3。As shown in FIGS. 1 to 3 , a moving bed adsorption tower according to an embodiment of the present invention includes a
塔体1内具有空腔,塔体1设有与空腔连通的加料口111、出料口141、烟气进口131和烟气出口121,空腔在烟气的流通方向上具有进气段13、填料段12和布料段11,填料段12用于填充吸附剂;There is a cavity in the
具体地,烟气进口131与进气段13连通,烟气出口121与布料段11连通,加料口111与布料段11连通,加料口111和烟气出口121位于填料段12的上方,出料口141和烟气进口131位于填料段12的下方。需要说明的是,烟气流通方向是从烟气进口131到烟气出口121,布料段11、填料段12和进气段13沿着从上至下的方向依次排布。由此,烟气从塔体1的下半部进入塔体1的内部并从塔体1的上侧流出,吸附剂从塔体1的上侧进入塔体1并从塔体1的下端流出,烟气的流向与吸附剂的流向相反,烟气中氮和硫的浓度随着烟气上升逐渐降低,吸附剂的吸附效果随着与烟气接触的时间逐渐降低,较低氮和硫浓度的烟气较好吸附效果的吸附剂接触,能够有效降低从烟气出口121排出气体中氮和硫的浓度,提高吸附效率。Specifically, the
分布器2设在塔体1内,分布器2包括多个落料入口23和多个与落料入口23对应的落料出口24,分布器2位于填料段12的下方以便填料段12中的吸附剂通过落料入口23和对应的落料出口24流出,其中落料入口23为方形;Distributor 2 is arranged in
具体地,落料出口24与落料入口23一一对应,落料出口24位于落料入口23的下方,落料入口23平行间隔布置且间距相等。由此,吸附剂穿过落料入口23和落料出口24进入落料管3中,吸附剂通过均匀布置的落料入口23的流量大致相同,一方面延缓了吸附剂向下流动的速度,增加了吸附剂颗粒与烟气接触的时间,另一方面避免吸附剂集中从一个或多个分布管22流出、在流动中产生死角,提高了吸附剂流动的效率,从而提高了吸附效果。Specifically, the
多个落料管3与多个落料出口24一一对应,落料出口24位于落料管3内,落料管3与分布器2之间具有间隙以便烟气通过,烟气进口131位于落料入口23的下方,落料管3位于出料口141的上方。Multiple blanking tubes 3 correspond to multiple
具体地,落料出口24的下端伸入落料管3的内部,落料管3与分布器2之间的间隙即为落料管3内壁的上端与落料出口24外壁的下端之间的空隙。由此,吸附剂在穿过落料出口24落入落料管3时,能够完全落入落料管3中,避免吸附剂从落料出口24和落料管3之间的间隙溅出,从而避免吸附剂从烟气进口131流出塔体1。Specifically, the lower end of the
在一些实施例中,分布器2包括分布板21和多个分布管22,落料入口23设在分布板21上,分布管22与分布板21的下端面相连并从分布板21向下延伸,分布管22为方管,多个分布管22与多个落料入口23一一对应,分布管22的下端设有落料出口24,多个落料管3与多个分布管22一一对应,分布管22的下端部伸入对应的落料管3的上端部内,落料管3的顶端与分布板21的下端面之间具有缝隙,分布管22与对应的落料管3之间具有间隔,烟气进口131位于分布板21的下方。In some embodiments, the distributor 2 includes a
具体地,如图5所示,分布板21上设置有与分布管22形状相同的通孔,通孔平行等间距排列,分布管22的截面呈方形,分布管22沿着竖直方向延伸。需要说明的是,落料入口23和落料出口24的形状都是方形。由此,吸附剂能够从分布器2中均匀的流出,避免在流动中产生死角,提高了吸附效率。分布管22在水平方向上的几何中心与落料管3在水平方向上的几何中心重合。由此,分布管222中流出的吸附剂能够直接落入落料管3中,避免了吸附剂从分布器2进入落料管3中流动不畅造成堆积,提高了吸附剂在内腔中流动的流畅程度。Specifically, as shown in FIG. 5 , the
在一些实施例中,落料管3的顶端与分布板21的下端面之间的缝隙在竖直方向上的尺寸为20mm-100mm。具体地,上述尺寸可以为20mm至100mm之间的任意数值,例如,落料管3的顶端与分布板21的下端面之间的缝隙在竖直方向上的尺寸可以为33mm、40mm、60.5mm、88m等。In some embodiments, the vertical dimension of the gap between the top end of the drop tube 3 and the lower end surface of the
优选的,落料管3的顶端与分布板21的下端面之间的缝隙在竖直方向上的尺寸为35mm,这样设置设置一方面减少了烟气从分布管22和落料管3之间经过的路径长度,使烟气流动更顺畅,另一方面便于分布管22伸入落料管3的内部,防止吸附剂颗粒经过分布管22和落料管3之间的空隙溅出塔体1,减少了吸附剂的损耗。Preferably, the vertical dimension of the gap between the top of the discharge pipe 3 and the lower end surface of the
在一些实施例中,分布管22的外周壁与对应的落料管3的内周壁之间在水平方向上间隔5mm-40mm。具体地,该尺寸可以为50mm至100mm之间的任意数值,例如,分布管22的外周壁与对应的落料管3的内周壁之间在水平方向上间隔可以为9mm、15.5mm、26mm、40mm等。In some embodiments, the distance between the outer peripheral wall of the
优选的,分布管22的外周壁与对应的落料管3的内周壁之间在水平方向上间隔为25mm,这样设置一方面减少了烟气从分布管22和落料管3之间经过的路径长度,使烟气流动更顺畅,另一方面便于分布管22伸入落料管3的内部,防止吸附剂颗粒经过分布管22和落料管3之间的空隙溅出塔体1,减少了吸附剂的损耗。Preferably, the distance between the outer peripheral wall of the
在一些实施例中,分布管22的伸入落料管3内的部分的长度为5mm-40mm。具体地,分布管22的伸入落料管3内的部分的长度即为落料出口24的底端与落料管3的上端在竖直方向上的距离,分布管22的伸入落料管3内的部分的长度可以为5mm至40mm之间的任意数值,例如,分布管22的伸入落料管3内的部分的长度可以为9mm、15.5mm、26mm、40mm等。In some embodiments, the length of the part of the
优选的,分布管22的伸入落料管3内的部分的长度为25mm,这样设置一方面减少了烟气从分布管22和落料管3之间经过的路径长度,使烟气流动更顺畅,另一方面分布管22的伸入落料管3内部能够有效的防止吸附剂颗粒经过分布管22和落料管3之间的空隙溅出塔体1,减少了吸附剂的损耗。Preferably, the length of the part of the
在一些实施例中,多个落料入口23排列为多排,每排落料入口23包括若干落料入口23,每排落料入口23中的若干落料入口23沿第一方向间隔排布,多排落料入口23在第二方向上间隔排布,第一方向和第二方向相互垂直,相邻两排落料入口23在第二方向上对齐。In some embodiments, a plurality of blanking
具体地,分布板21为矩形,分布板21的长度为1000mm-3000mm,分布板21的宽度为500mm-1500mm,第一方向为分布板21的长度方向,第二方向为分布板21的宽度方向。需要说明的是,如图4所示,第一方向即为左右方向,第二方向即为前后方向。Specifically, the
优选的,分布板21的长度为2000mm,分布板21的宽度为1000mm,这样设置如此设置便于将布料板21固定在塔体1上。Preferably, the length of the
在其他一些实施例中,分布板21可以为圆形、椭圆形、三角形等。In some other embodiments, the
在一些实施例中,落料入口23的边缘为正方形,落料入口23的边长为150mm-300mm。具体地,落料入口23的边长可以为150mm至300mm之间的任意数值,例如,落料入口23的边长可以为160mm、199.5mm、266mm、299mm等。In some embodiments, the edges of the blanking
优选的,落料入口23的边长为200mm,这样设置能够在分布板21上布置更多的落料入口23。Preferably, the side length of the blanking
在一些实施例中,在第一方向上相邻的两个落料入口23之间的间隔为20mm-100mm,在第二方向上相邻的两个落料入口23之间的间隔为20mm-100mm。In some embodiments, the interval between two
具体地,相邻的两个落料入口23之间的间隔即为相邻的两个落料入口23最近两点之间的距离。需要说明的是,第一方向上相邻的两个落料入口23之间的间隔与第二方向上相邻的两个落料入口23之间的间隔可以相同也可以不同。Specifically, the distance between two
优选的,在第一方向上相邻的两个落料入口23之间的间隔为50mm,在第二方向上相邻的两个落料入口23之间的间隔为50mm.如此设置能够布置更多的落料入口23。Preferably, the interval between two
在一些实施例中,落料管3为圆管,落料管3包括第一段31和第二段32,第一段31的直径大于第二段32的直径,第一段31的下端与第二段32的上端相连,分布管22的下端部伸入对应的落料管3的第一段31内。In some embodiments, the feeding tube 3 is a circular tube, and the feeding tube 3 includes a
具体地,第一段31和第二段32的宽度是第一段31和第二段32沿着第一方向的尺寸,第一段31和第二段32的长度是第一段31和第二段32沿着第二方向的尺寸,第二段32的长度可以与第一段31相等,第二段32的长度也可以小于第一段31的长度。第一段31的宽度大于第二段32的宽度。如图6所示,落料管3是圆管便于加工。Specifically, the width of the
在其它一些实施例中,如图7所示,落料管3也可以是方管。In some other embodiments, as shown in FIG. 7 , the drop tube 3 can also be a square tube.
在一些实施例中,落料管3沿竖直方向延伸,落料管3的长度为500mm-800mm。具体地,落料管3的长度为可以为500mm至800mm之间的任意数值,例如,落料管3的长度为可以为505mm、620.7mm、700mm、786.85m等。In some embodiments, the drop tube 3 extends vertically, and the length of the drop tube 3 is 500mm-800mm. Specifically, the length of the drop tube 3 can be any value between 500mm and 800mm, for example, the length of the drop tube 3 can be 505mm, 620.7mm, 700mm, 786.85m, etc.
优选的,落料管3的长度为为740mm,这样设置使料向下流动顺畅Preferably, the length of the drop tube 3 is 740mm, so that the material flows down smoothly
在一些实施例中,烟气进口131位于落料出口24的上方。In some embodiments, the
具体地,烟气进口131的最下端的高度高于落料出口24的高度。由此,烟气进口131完全位于落料出口24的上方,保证吸附剂从落料管3中落下时,不会经过烟气进口131溅出塔体1,提高了吸附剂收集的效率。Specifically, the height of the lowermost end of the
在一些实施例中,空腔还包括位于布料段11下方的出料段14,出料段14呈倒锥型,出料口141与出料段14的底部连通。In some embodiments, the cavity further includes a
具体地,空腔是指塔体1内部的空间,出料段14是倒四棱锥形,出料段14的顶部与进气段13连接,出料段14是中空结构,出料段14内部的空间与空腔相连,出料段14的截面积沿着从上向下的方向逐渐减小,出料口141设置在出料段14的下端。由此,吸附剂在完成对烟气中有害成分的吸附后,经过落料管3落入出料段14,并在出料段14中进行收集,在收集一定数量的吸附剂后,从出料口141排出,对回收的吸附剂进行下一步的处理,在出料口141封闭时,吸附剂中逸出的有害成分与烟气进口131中进入的烟气一起向上流动,不会挥散到大气中。Specifically, the cavity refers to the space inside the
在一些实施例中,出料段14的高度为1.0m-3.0m。具体地,出料段14的高度即为出料段14顶部与出料段14的底部在竖直方向上的距离。出料段14的高度可以为1.0m至3.0m之间的任意数值,例如,出料段14的高度可以为1.1m、2.0m、2.1m、2.85m等。In some embodiments, the height of the
优选的,出料段14的高度为1.8m,这样设置使料向下流动顺畅。Preferably, the height of the
在一些实施例中,移动床吸附塔的高度为4.0m-8.0m。具体地,移动床吸附塔的高度即为加料口111和出料口141在竖直方向上的距离。移动床吸附塔的高度可以为4.0m至8.0m之间的任意数值,例如,移动床吸附塔的高度可以为4.1m、5.02m、6.15m、7.8m等。In some embodiments, the height of the moving bed adsorption tower is 4.0m-8.0m. Specifically, the height of the moving bed adsorption tower is the vertical distance between the
优选的,移动床吸附塔的高度为6.02m,这样设置设置充分考虑了料层高度以及空间占地。Preferably, the height of the moving bed adsorption tower is 6.02m, and the setting in this way fully considers the height of the material layer and the space occupied.
在一些实施例中,进气段13的高度为1.0m-2.0m,填料段12的高度为2.0m-3.0m,布料段11的高度为0.5m-1m。In some embodiments, the height of the
具体地,填料段12的高度大于进气段13与布料段11的和,例如进气段13的高度为1.5m,布料段11的高度为0.6m,填料段12的高度为2.5m,由此,由于述填料段12的高度大于进气段13与布料段11的和,吸附剂在填料段12存留的时间大于在进气段13中与在布料段11中存留时间的和,增加了吸附剂对烟气进行吸附的时间,从而提高吸附效率。Specifically, the height of the
优选的,进气段13的高度为1.45m,填料段12的高度为2.05m,布料段11的高度为0.7m,这样设置使料能布满布料板21。Preferably, the height of the
在一些实施例中,移动床吸附塔的空速为600h-1-1500h-1。具体地,空速指的是移动床吸附塔的烟气流量与移动床吸附塔中吸附剂的装填体积之比。由此,移动床吸附塔的空速较高,在相同的烟气流量下移动床吸附塔的装填体积可以小于现有移动床吸附塔的装填体积,如此设置可以减小移动床吸附塔的体积,还可以减少塔内吸附剂的装填量。In some embodiments, the space velocity of the moving bed adsorption tower is 600h -1 -1500h -1 . Specifically, the space velocity refers to the ratio of the flue gas flow rate of the moving bed adsorption tower to the packing volume of the adsorbent in the moving bed adsorption tower. As a result, the space velocity of the moving bed adsorption tower is high, and the filling volume of the moving bed adsorption tower can be smaller than that of the existing moving bed adsorption tower under the same flue gas flow rate, so that the volume of the moving bed adsorption tower can be reduced , It can also reduce the loading amount of adsorbent in the tower.
优选地,移动床吸附塔的空速为1200h-1-1500h-1,使移动床吸附塔具有优选的吸附效果。Preferably, the space velocity of the moving bed adsorption tower is 1200h -1 -1500h -1 , so that the moving bed adsorption tower has an optimal adsorption effect.
根据本发明实施例的烟气净化系统,包括:烟气冷却装置,烟气冷却装置具有进烟口和出烟口,烟气冷却装置用于将从进烟口进入的烟气冷却至室温及以下;移动床吸附塔,移动床吸附塔为根据上述任一实施例的移动床吸附塔,烟气冷却装置的出烟口与移动床吸附塔的烟气出口121连通,移动床吸附塔用于对烟气进行吸附。The flue gas purification system according to the embodiment of the present invention includes: a flue gas cooling device, the flue gas cooling device has a smoke inlet and a smoke outlet, and the flue gas cooling device is used to cool the flue gas entering from the smoke inlet to room temperature and Below: moving bed adsorption tower, the moving bed adsorption tower is the moving bed adsorption tower according to any of the above-mentioned embodiments, the smoke outlet of the flue gas cooling device is communicated with the
可选地,烟气进口131进入的烟气的温度为-100℃-室温(例如室温为25℃)。可选地,吸附剂为活性焦(碳)。Optionally, the temperature of the flue gas entering the
本实施例提供的烟气净化系统在对烟气进行吸附时采用低温吸附的方式,利用烟气中污染物组分在低温下的溶解特性和吸附特性进行污染物的脱出,能够同时实现脱硫脱硝。其中,烟气中的二氧化硫以物理吸附为主,解析温度低,吸附剂损耗低,吸附剂补充量低,降低了运行成本。并且,在低温下进行吸附的烟气净化系统对污染物的吸附量大,吸附剂装填量少,移动床吸附塔等设备的占地面积小。The flue gas purification system provided in this example adopts the low-temperature adsorption method when adsorbing the flue gas, and utilizes the dissolution characteristics and adsorption characteristics of the pollutant components in the flue gas at low temperatures to remove pollutants, and can simultaneously realize desulfurization and denitrification . Among them, the sulfur dioxide in the flue gas is mainly physically adsorbed, the desorption temperature is low, the loss of the adsorbent is low, and the replenishment of the adsorbent is low, which reduces the operating cost. Moreover, the flue gas purification system that adsorbs at low temperature has a large adsorption capacity for pollutants, a small amount of adsorbent loading, and a small footprint for equipment such as moving bed adsorption towers.
需要说明的是,本实施例提供的烟气净化系统在对烟气进行吸附净化时,烟气中难以脱除的NOx组分用过低温氧化吸附机理,氧化成NO2吸附脱除,不需要喷入NH3进行催化还原,运行成本低。本实施例提供的烟气净化系统对烟气中NOx的吸附比例大于99%,脱硝效率明显优于现有技术中70~80%的脱硝效率。It should be noted that when the flue gas purification system provided in this example performs adsorption and purification of the flue gas, the NO x components that are difficult to remove in the flue gas are oxidized to NO by adsorption and removal at a low temperature through the mechanism of oxidation adsorption. It needs to inject NH3 for catalytic reduction, and the operation cost is low. The flue gas purification system provided in this embodiment can absorb more than 99% of NOx in the flue gas, and the denitrification efficiency is obviously better than the 70-80% denitrification efficiency in the prior art.
在本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”、“顺时针”、“逆时针”、“轴向”、“径向”、“周向”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In describing the present invention, it should be understood that the terms "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", " Back", "Left", "Right", "Vertical", "Horizontal", "Top", "Bottom", "Inner", "Outer", "Clockwise", "Counterclockwise", "Axial", The orientation or positional relationship indicated by "radial", "circumferential", etc. is based on the orientation or positional relationship shown in the drawings, and is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying the referred device or element Must be in a particular orientation, be constructed in a particular orientation, and operate in a particular orientation, and therefore should not be construed as limiting the invention.
此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括至少一个该特征。在本发明的描述中,“多个”的含义是至少两个,例如两个,三个等,除非另有明确具体的限定。In addition, the terms "first" and "second" are used for descriptive purposes only, and cannot be interpreted as indicating or implying relative importance or implicitly specifying the quantity of indicated technical features. Thus, the features defined as "first" and "second" may explicitly or implicitly include at least one of these features. In the description of the present invention, "plurality" means at least two, such as two, three, etc., unless otherwise specifically defined.
在本发明中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接或彼此可通讯;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系,除非另有明确的限定。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。In the present invention, unless otherwise clearly specified and limited, terms such as "installation", "connection", "connection" and "fixation" should be understood in a broad sense, for example, it can be a fixed connection or a detachable connection , or integrated; can be mechanically connected, can also be electrically connected or can communicate with each other; can be directly connected, can also be indirectly connected through an intermediary, can be the internal communication of two components or the interaction relationship between two components, Unless expressly defined otherwise. Those of ordinary skill in the art can understand the specific meanings of the above terms in the present invention according to specific situations.
在本发明中,除非另有明确的规定和限定,第一特征在第二特征“上”或“下”可以是第一和第二特征直接接触,或第一和第二特征通过中间媒介间接接触。而且,第一特征在第二特征“之上”、“上方”和“上面”可是第一特征在第二特征正上方或斜上方,或仅仅表示第一特征水平高度高于第二特征。第一特征在第二特征“之下”、“下方”和“下面”可以是第一特征在第二特征正下方或斜下方,或仅仅表示第一特征水平高度小于第二特征。In the present invention, unless otherwise clearly specified and limited, the first feature may be in direct contact with the first feature or the first and second feature may be in direct contact with the second feature through an intermediary. touch. Moreover, "above", "above" and "above" the first feature on the second feature may mean that the first feature is directly above or obliquely above the second feature, or simply means that the first feature is higher in level than the second feature. "Below", "beneath" and "beneath" the first feature may mean that the first feature is directly below or obliquely below the second feature, or simply means that the first feature is less horizontally than the second feature.
在本发明中,术语“一个实施例”、“一些实施例”、“示例”、“具体示例”、或“一些示例”等意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不必须针对的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任一个或多个实施例或示例中以合适的方式结合。此外,在不相互矛盾的情况下,本领域的技术人员可以将本说明书中描述的不同实施例或示例以及不同实施例或示例的特征进行结合和组合。As used herein, the terms "one embodiment," "some embodiments," "example," "specific examples," or "some examples" mean specific features, structures, materials, or features described in connection with the embodiment or example. A feature is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the above terms are not necessarily directed to the same embodiment or example. Furthermore, the described specific features, structures, materials or characteristics may be combined in any suitable manner in any one or more embodiments or examples. In addition, those skilled in the art can combine and combine different embodiments or examples and features of different embodiments or examples described in this specification without conflicting with each other.
尽管上面已经示出和描述了本发明的实施例,可以理解的是,上述实施例是示例性的,不能理解为对本发明的限制,本领域的普通技术人员在本发明的范围内可以对上述实施例进行变化、修改、替换和变型。Although the embodiments of the present invention have been shown and described above, it can be understood that the above embodiments are exemplary and should not be construed as limiting the present invention, those skilled in the art can make the above-mentioned The embodiments are subject to changes, modifications, substitutions and variations.
Claims (8)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111027093 | 2021-09-02 | ||
CN2021110270933 | 2021-09-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113828109A CN113828109A (en) | 2021-12-24 |
CN113828109B true CN113828109B (en) | 2023-03-07 |
Family
ID=78959497
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111081488.1A Active CN113828109B (en) | 2021-09-02 | 2021-09-15 | Flue gas purification system and its moving bed adsorption tower with distributor |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113828109B (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113828111B (en) * | 2021-09-02 | 2023-02-24 | 中国华能集团有限公司 | Moving bed adsorption tower and flue gas cleaning system with sparger |
CN116351197B (en) * | 2023-06-01 | 2023-08-29 | 中国华能集团清洁能源技术研究院有限公司 | Flue gas distributor, adsorption tower and low-temperature flue gas adsorption system |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1988008746A1 (en) * | 1987-05-07 | 1988-11-17 | Horst Grochowski | Feed inlet floor for mobile bed reactors |
CN203002168U (en) * | 2012-12-13 | 2013-06-19 | 成都源创环保工程有限公司 | Moving bed adsorption tower for exhaust gas purification |
CN207614615U (en) * | 2017-12-07 | 2018-07-17 | 国电科学技术研究院 | A kind of activated coke smoke eliminator of sulphur nitre integration removing |
-
2021
- 2021-09-15 CN CN202111081488.1A patent/CN113828109B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1988008746A1 (en) * | 1987-05-07 | 1988-11-17 | Horst Grochowski | Feed inlet floor for mobile bed reactors |
CN203002168U (en) * | 2012-12-13 | 2013-06-19 | 成都源创环保工程有限公司 | Moving bed adsorption tower for exhaust gas purification |
CN207614615U (en) * | 2017-12-07 | 2018-07-17 | 国电科学技术研究院 | A kind of activated coke smoke eliminator of sulphur nitre integration removing |
Also Published As
Publication number | Publication date |
---|---|
CN113828109A (en) | 2021-12-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN113828110B (en) | Moving bed adsorption tower and flue gas purification system with same | |
CN113828112B (en) | Moving bed adsorption tower and flue gas purification system | |
CN116351207B (en) | Low-temperature flue gas adsorption tower with flue gas cooling function and adsorption method | |
CN116351197B (en) | Flue gas distributor, adsorption tower and low-temperature flue gas adsorption system | |
CN113828109B (en) | Flue gas purification system and its moving bed adsorption tower with distributor | |
CN103349892B (en) | A kind of cross-current type twin-stage moving-bed active coke waste gas integrated purification tower | |
CN101310827B (en) | Activated charcoal gas cleaning method and device thereof | |
CN113797711B (en) | Moving bed adsorption tower and flue gas purification system | |
CN216149387U (en) | Moving bed adsorption tower and flue gas purification system with same | |
CN113828111B (en) | Moving bed adsorption tower and flue gas cleaning system with sparger | |
CN117282228B (en) | Low-temperature flue gas adsorption tower and low-temperature flue gas adsorption system with flue gas diversion function | |
CN113797710B (en) | Flue gas purification system and moving bed adsorption tower thereof | |
WO2025077909A1 (en) | Multi-layer series cross-flow low-temperature flue gas purification tower and low-temperature flue gas treatment system | |
WO2025108170A1 (en) | Low-temperature flue gas adsorption tower with flue gas mixing function, and low-temperature flue gas adsorption system | |
CN111888925B (en) | Dry desulfurization assembly, desulfurization dust removal unit, integrated equipment and system | |
CN113797712B (en) | Flue gas purification system and moving bed adsorption tower | |
CN113828108B (en) | Flue gas purification system and moving bed adsorption tower | |
WO2023029411A1 (en) | Moving bed adsorption tower and flue gas purification system having same | |
CN105561723A (en) | Lead smoke purifying apparatus of high performance storage battery | |
CN216537701U (en) | Flue gas purification system and moving bed adsorption tower thereof | |
CN203315990U (en) | Cross flow type twin-stage moving bed active coke exhaust gas integration purifying tower | |
CN212819071U (en) | Desulfurization dust removal unit | |
CN216537702U (en) | Flue gas purification system and moving bed adsorption tower with distributor thereof | |
CN216537699U (en) | A moving bed adsorption tower and flue gas purification system | |
CN215876797U (en) | A moving bed adsorption tower and flue gas purification system with moving bed adsorption tower |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |