CN113732058A - Preparation method of ultra-wide and ultra-thin metal lithium and alloy strip thereof - Google Patents
Preparation method of ultra-wide and ultra-thin metal lithium and alloy strip thereof Download PDFInfo
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- CN113732058A CN113732058A CN202110930329.8A CN202110930329A CN113732058A CN 113732058 A CN113732058 A CN 113732058A CN 202110930329 A CN202110930329 A CN 202110930329A CN 113732058 A CN113732058 A CN 113732058A
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- ultra
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- winding
- wide
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- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 41
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 38
- 239000000956 alloy Substances 0.000 title claims abstract description 38
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 37
- 239000002184 metal Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000004804 winding Methods 0.000 claims abstract description 69
- 238000005096 rolling process Methods 0.000 claims abstract description 47
- 230000001681 protective effect Effects 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000000853 adhesive Substances 0.000 claims abstract description 10
- 230000001070 adhesive effect Effects 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims description 21
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- -1 polyethylene terephthalate Polymers 0.000 claims description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 238000009825 accumulation Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/24—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C47/00—Winding-up, coiling or winding-off metal wire, metal band or other flexible metal material characterised by features relevant to metal processing only
- B21C47/02—Winding-up or coiling
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metal Rolling (AREA)
Abstract
The invention discloses a preparation method of ultra-wide and ultra-thin metal lithium and an alloy strip thereof. The preparation method of the ultra-wide and ultra-thin metal lithium and the alloy strip thereof comprises the following steps: step A: selecting a blank with the specification of 0.15mm x 80-110 mm; and B: placing the protective film on an unreeling device of a rolling mill, drawing the protective film through a roller, and finally winding the protective film on a reeling device; and C: and placing the blank on the other unwinding device of the rolling mill. According to the preparation method of the ultra-wide and ultra-thin metal lithium and the alloy strip thereof, the double-film-covering finish rolling and film-pasting winding methods are adopted, and the two films with different adhesive forces are used, so that the influence of winding tension on the strip is reduced, the direct contact with a roller is avoided, the uniform consistency of the thickness and the width of the strip is ensured while the thickness of the strip is reduced and the width of the strip is increased, the phenomena of accumulation, folding and the like of the strip at a rolling opening are avoided, the undesirable phenomena of splitting, fracture, edge wave and the like of the strip are reduced, and the quality stability of the strip is improved.
Description
Technical Field
The invention belongs to the field of metal lithium and alloy deep processing production, and particularly relates to a preparation method of ultra-wide and ultra-thin metal lithium and an alloy strip thereof.
Background
With the rapid development of industries such as portable electronic equipment, unmanned aerial vehicles, electric vehicles and the like, the requirement on the specific capacity of the lithium ion secondary battery is higher and higher. The theoretical specific capacity of the metal lithium is high, the oxidation-reduction potential is low, and the metal lithium has obvious advantages when used as the negative electrode of the lithium ion battery. Research shows that when the metal lithium and the alloy strip thereof are used as the negative electrode, the wider and thinner the metal lithium and the alloy strip thereof are, the production cost of the battery can be reduced, the discharge current of the battery can be increased, the power and the capacity of the battery can be improved, the heat dissipation area can be increased, the discharge temperature can be reduced, the discharge current can be increased, and the safety performance can be improved.
At present, in some fields, particularly the field of electric automobiles, the requirements on the width and the thickness of metal lithium and alloy strips thereof are high, and particularly, the thickness of the metal lithium and the alloy strips thereof used in an all-solid-state lithium battery is generally required to be less than 50 μm.
The existing process usually adopts a mode of combining extrusion and rolling to prepare ultra-wide and ultra-thin metal lithium and alloy strips thereof, but in the actual operation process, the metal lithium and the alloy strips thereof are thin and have high viscosity and are easy to adhere to a roller, so that the problems of folds, fractures, accumulation, edge waves and the like are caused to be accumulated at a rolling feeding port, and the rolling process cannot be smoothly carried out.
Disclosure of Invention
Based on the above, the invention is completed for solving the defects in the prior art, and the invention aims to provide a preparation method of ultra-wide and ultra-thin metal lithium and alloy strips thereof.
In order to achieve the purpose, the invention provides the following technical scheme:
a preparation method of ultra-wide and ultra-thin metal lithium and alloy strips thereof comprises the following steps:
step A: selecting a blank with the specification of 0.15mm x 80-110 mm;
and B: placing the protective film on an unreeling device of a rolling mill, drawing the protective film through a roller, and finally winding the protective film on a reeling device;
and C: placing the blank on another unwinding device of the rolling mill, and preparing ultra-wide and ultra-thin metal lithium and alloy strips thereof with the thickness of 0.01-0.05mm and the width of 110-;
step D: placing the reel on the other winding device of the rolling mill, and arranging a winding film unwinding device below the reel;
step E: firstly, winding the winding film on a reel, then winding a strip material on the winding film, starting continuous finish rolling to form a layer of winding film and a layer of strip material, and winding the layer of winding film and the layer of strip material on the reel;
step F: and (5) operating the step A to the step E to continuously produce the ultra-wide and ultra-thin metal lithium and the alloy strip thereof.
Further, the protective film of the step B comprises a first film layer and a second film layer, wherein the first film layer and the second film layer are both provided with an organic silicon adhesive, and the adhesive force of the first film layer is greater than that of the second film layer.
Further, the first film layer and the second film layer are both made of a polyethylene terephthalate material.
Further, the rolling film of the step D is an OPP protective film.
According to the preparation method of the ultra-wide and ultra-thin metal lithium and the alloy strip thereof, two films with different adhesive forces are used by adopting a double-film-covering finish rolling and film-pasting winding method, so that the influence of winding tension on the strip is reduced, the direct contact with a roller is avoided, the uniform consistency of the thickness and the width of the strip is ensured while the thickness of the strip is reduced and the width of the strip is increased, the phenomena of accumulation, folding and the like of the strip at a rolling port are avoided, the adverse phenomena of splitting, fracture, edge wave and the like of the strip are reduced, the quality stability of the strip is improved, the ultra-wide and ultra-thin metal lithium and the alloy strip thereof with the thickness of 0.01-0.05mm and the width of 110-plus-210 mm are successfully rolled industrially, the requirements of customers on products of the type are met, the productivity of the company is liberated, the production cost is reduced, the market competitiveness is improved, and the economic benefit of the company is improved.
Detailed Description
The invention provides a preparation method of ultra-wide and ultra-thin metal lithium and alloy strips thereof, which is characterized by comprising the following steps:
step A: selecting a blank with the specification of 0.15mm x 80-110 mm;
and B: placing the protective film on an unreeling device of a rolling mill, drawing the protective film through a roller, and finally winding the protective film on a reeling device;
and C: placing the blank on another unwinding device of the rolling mill, and preparing ultra-wide and ultra-thin metal lithium and alloy strips thereof with the thickness of 0.01-0.05mm and the width of 110-;
step D: placing the reel on the other winding device of the rolling mill, and arranging a winding film unwinding device below the reel;
step E: firstly, winding the winding film on a reel, then winding a strip material on the winding film, starting continuous finish rolling to form a layer of winding film and a layer of strip material, and winding the layer of winding film and the layer of strip material on the reel; preferably, because the strips are thin and soft, the rolling film is adopted to protect rolling, so that the phenomenon that subsequent use is influenced by adhesion among the strips is avoided, the problems of collapse, inward rolling and the like caused by excessive accumulation of the strips are also prevented by utilizing the stability of the rolling film, and a complete strip is obtained when a client uses the rolling film;
step F: and (5) operating the step A to the step E to continuously produce the ultra-wide and ultra-thin metal lithium and the alloy strip thereof.
Further, the protective film of the step B comprises a first film layer and a second film layer, wherein the first film layer and the second film layer are both provided with an organic silicon adhesive, and the adhesive force of the first film layer is greater than that of the second film layer.
Further, the first film layer and the second film layer are both made of a polyethylene terephthalate material. Therefore, the strip can be ensured to be only covered on the first film layer when being separated from the protective film, the phenomena of accumulation, folding and the like of the strip at a rolling opening are avoided, and the bad phenomena of breakage, edge waves, splitting and the like caused by the simultaneous pulling of the double films of the strip are avoided.
Furthermore, the rolling film in the step D is an OPP protective film, so that the rolling film is good in sticking performance and easy to peel.
According to the preparation method of the ultra-wide and ultra-thin metal lithium and the alloy strip thereof, two films with different adhesive forces are used by adopting a double-film-covering finish rolling and film-pasting winding method, so that the influence of winding tension on the strip is reduced, the direct contact with a roller is avoided, the uniform consistency of the thickness and the width of the strip is ensured while the thickness of the strip is reduced and the width of the strip is increased, the phenomena of accumulation, folding and the like of the strip at a rolling port are avoided, the adverse phenomena of splitting, fracture, edge wave and the like of the strip are reduced, the quality stability of the strip is improved, the ultra-wide and ultra-thin metal lithium and the alloy strip thereof with the thickness of 0.01-0.05mm and the width of 110-plus-210 mm are successfully rolled industrially, the requirements of customers on products of the type are met, the productivity of the company is liberated, the production cost is reduced, the market competitiveness is improved, and the economic benefit of the company is improved.
Example 1
Step A: selecting a blank with the specification of 0.15mm x 80 mm;
and B: placing the protective film on an unreeling device of a rolling mill, drawing the protective film through a roller, and finally winding the protective film on a reeling device;
and C: placing the blank on the other unwinding device of the rolling mill, and preparing an ultra-wide and ultra-thin metal lithium and alloy strip thereof with the thickness of 0.01mm and the width of 110mm by the aid of the roller;
step D: placing the reel on the other winding device of the rolling mill, and arranging a winding film unwinding device below the reel;
step E: firstly, winding the winding film on a reel, then winding a strip material on the winding film, starting continuous finish rolling to form a layer of winding film and a layer of strip material, and winding the layer of winding film and the layer of strip material on the reel;
step F: and (5) operating the step A to the step E to continuously produce the ultra-wide and ultra-thin metal lithium and the alloy strip thereof.
Example 2
Step A: selecting a blank with the specification of 0.15mm x 110 mm;
and B: placing the protective film on an unreeling device of a rolling mill, drawing the protective film through a roller, and finally winding the protective film on a reeling device;
and C: placing the blank on the other unwinding device of the rolling mill, and preparing an ultra-wide and ultra-thin metal lithium and alloy strip thereof with the thickness of 0.05mm and the width of 210mm by the aid of the roller;
step D: placing the reel on the other winding device of the rolling mill, and arranging a winding film unwinding device below the reel;
step E: firstly, winding the winding film on a reel, then winding a strip material on the winding film, starting continuous finish rolling to form a layer of winding film and a layer of strip material, and winding the layer of winding film and the layer of strip material on the reel;
step F: and (5) operating the step A to the step E to continuously produce the ultra-wide and ultra-thin metal lithium and the alloy strip thereof.
Example 3
Step A: selecting a blank with the specification of 0.15mm x 100 mm;
and B: placing the protective film on an unreeling device of a rolling mill, drawing the protective film through a roller, and finally winding the protective film on a reeling device;
and C: placing the blank on the other unwinding device of the rolling mill, and preparing an ultra-wide and ultra-thin metal lithium and alloy strip thereof with the thickness of 0.04mm and the width of 180mm by the aid of the roller;
step D: placing the reel on the other winding device of the rolling mill, and arranging a winding film unwinding device below the reel;
step E: firstly, winding the winding film on a reel, then winding a strip material on the winding film, starting continuous finish rolling to form a layer of winding film and a layer of strip material, and winding the layer of winding film and the layer of strip material on the reel;
step F: and (5) operating the step A to the step E to continuously produce the ultra-wide and ultra-thin metal lithium and the alloy strip thereof.
According to the preparation method of the ultra-wide and ultra-thin metal lithium and the alloy strip thereof, two films with different adhesive forces are used by adopting a double-film-covering finish rolling and film-pasting winding method, so that the influence of winding tension on the strip is reduced, the direct contact with a roller is avoided, the uniform consistency of the thickness and the width of the strip is ensured while the thickness of the strip is reduced and the width of the strip is increased, the phenomena of accumulation, folding and the like of the strip at a rolling port are avoided, the adverse phenomena of splitting, fracture, edge wave and the like of the strip are reduced, the quality stability of the strip is improved, the ultra-wide and ultra-thin metal lithium and the alloy strip thereof with the thickness of 0.01-0.05mm and the width of 110-plus-210 mm are successfully rolled industrially, the requirements of customers on products of the type are met, the productivity of the company is liberated, the production cost is reduced, the market competitiveness is improved, and the economic benefit of the company is improved.
The above description is only for the purpose of illustrating specific embodiments of the present invention, and should not be construed as limiting the scope of the present invention, and all equivalent changes and modifications made in accordance with the spirit of the present invention should be considered as falling within the scope of the present invention.
Claims (4)
1. A preparation method of ultra-wide and ultra-thin metal lithium and alloy strips thereof is characterized in that: the method comprises the following steps:
step A: selecting a blank with the specification of 0.15mm x 80-110 mm;
and B: placing the protective film on an unreeling device of a rolling mill, drawing the protective film through a roller, and finally winding the protective film on a reeling device;
and C: placing the blank on another unwinding device of the rolling mill, and preparing ultra-wide and ultra-thin metal lithium and alloy strips thereof with the thickness of 0.01-0.05mm and the width of 110-;
step D: placing the reel on the other winding device of the rolling mill, and arranging a winding film unwinding device below the reel;
step E: firstly, winding the winding film on a reel, then winding a strip material on the winding film, starting continuous finish rolling to form a layer of winding film and a layer of strip material, and winding the layer of winding film and the layer of strip material on the reel;
step F: and (5) operating the step A to the step E to continuously produce the ultra-wide and ultra-thin metal lithium and the alloy strip thereof.
2. The method for preparing ultra-wide and ultra-thin lithium metal and the alloy strip thereof according to claim 1, wherein the method comprises the following steps: the protective film in the step B comprises a first film layer and a second film layer, wherein the first film layer and the second film layer are both provided with organic silicon adhesives, and the adhesive force of the first film layer is greater than that of the second film layer.
3. The method for preparing ultra-wide and ultra-thin lithium metal and the alloy strip thereof according to claim 2, wherein the method comprises the following steps: the first film layer and the second film layer are both made of a polyethylene terephthalate material.
4. The method for preparing ultra-wide and ultra-thin lithium metal and the alloy strip thereof according to claim 1, wherein the method comprises the following steps: and D, the rolling film in the step D is an OPP protective film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110930329.8A CN113732058A (en) | 2021-08-13 | 2021-08-13 | Preparation method of ultra-wide and ultra-thin metal lithium and alloy strip thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110930329.8A CN113732058A (en) | 2021-08-13 | 2021-08-13 | Preparation method of ultra-wide and ultra-thin metal lithium and alloy strip thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113732058A true CN113732058A (en) | 2021-12-03 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202110930329.8A Pending CN113732058A (en) | 2021-08-13 | 2021-08-13 | Preparation method of ultra-wide and ultra-thin metal lithium and alloy strip thereof |
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| CN109301161A (en) * | 2018-11-02 | 2019-02-01 | 山东玉皇新能源科技有限公司 | Electrodes of lithium-ion batteries and its winding method coated with dielectric film |
| CN109802098A (en) * | 2019-03-19 | 2019-05-24 | 天津中能锂业有限公司 | A kind of super thin metal lithium foil process units and method |
| CN209822779U (en) * | 2019-03-18 | 2019-12-20 | 天津中能锂业有限公司 | Ultrathin lithium foil and device for preparing ultrathin lithium foil |
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| CN111957744A (en) * | 2020-07-27 | 2020-11-20 | 上海神火铝箔有限公司 | Rolling method of ultra-wide and ultra-thin aluminum foil |
| CN112151758A (en) * | 2019-06-28 | 2020-12-29 | 天津中能锂业有限公司 | Ultrathin lithium film prefabricated member and preparation method thereof |
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| CN212434665U (en) * | 2020-07-23 | 2021-01-29 | 天津中能锂业有限公司 | Wide-width ultrathin lithium foil and equipment for preparing wide-width ultrathin lithium foil |
-
2021
- 2021-08-13 CN CN202110930329.8A patent/CN113732058A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104842626A (en) * | 2015-04-29 | 2015-08-19 | 宁德时代新能源科技有限公司 | Lithium strip production method |
| CN106981625A (en) * | 2017-05-27 | 2017-07-25 | 天津中能锂业有限公司 | A kind of production method of complex lithium band |
| CN109301161A (en) * | 2018-11-02 | 2019-02-01 | 山东玉皇新能源科技有限公司 | Electrodes of lithium-ion batteries and its winding method coated with dielectric film |
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Application publication date: 20211203 |
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