[go: up one dir, main page]

CN113725244A - Image sensor and method for manufacturing the same - Google Patents

Image sensor and method for manufacturing the same Download PDF

Info

Publication number
CN113725244A
CN113725244A CN202111005082.5A CN202111005082A CN113725244A CN 113725244 A CN113725244 A CN 113725244A CN 202111005082 A CN202111005082 A CN 202111005082A CN 113725244 A CN113725244 A CN 113725244A
Authority
CN
China
Prior art keywords
layer
image sensor
semiconductor substrate
region
material layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111005082.5A
Other languages
Chinese (zh)
Inventor
王奇伟
张磊
詹曜宇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Huali Microelectronics Corp
Original Assignee
Shanghai Huali Microelectronics Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Huali Microelectronics Corp filed Critical Shanghai Huali Microelectronics Corp
Priority to CN202111005082.5A priority Critical patent/CN113725244A/en
Publication of CN113725244A publication Critical patent/CN113725244A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F39/00Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
    • H10F39/011Manufacture or treatment of image sensors covered by group H10F39/12
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F39/00Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
    • H10F39/011Manufacture or treatment of image sensors covered by group H10F39/12
    • H10F39/014Manufacture or treatment of image sensors covered by group H10F39/12 of CMOS image sensors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F39/00Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
    • H10F39/80Constructional details of image sensors
    • H10F39/803Pixels having integrated switching, control, storage or amplification elements
    • H10F39/8037Pixels having integrated switching, control, storage or amplification elements the integrated elements comprising a transistor

Landscapes

  • Solid State Image Pick-Up Elements (AREA)

Abstract

The invention provides a manufacturing method of an image sensor, which is applied to the technical field of semiconductors. Specifically, a patterned photoresist layer is formed on the semiconductor substrate before a sidewall etching process (forming a first sidewall structure and a second sidewall structure), so that the patterned photoresist layer covers the surface of the semiconductor substrate corresponding to the photodiode region, and then a subsequent etching process is performed, so that the semiconductor substrate corresponding to the photodiode region is prevented from being completely exposed in a plasma environment in the etching process, the surface of the semiconductor substrate corresponding to the photodiode region is prevented from being damaged, and further, dark current caused by surface damage is avoided, and meanwhile, the normal functions of a pixel device region and a logic device region are ensured, and finally, the performance of the image sensor is improved.

Description

Image sensor and method for manufacturing the same
Technical Field
The present invention relates to CMOS image sensors in the field of semiconductor technologies, and in particular, to an image sensor and a method for manufacturing the same.
Background
With the rapid development of the new fields such as artificial intelligence, internet of things, industry 4.0 and the like, the demand of the market for a CMOS Image sensor (CMOS Image sensor) is increasing day by day, the performance requirement of the CMOS Image sensor is higher and higher, and an important index of the Image sensing performance is the dark current level. Dark current means that a photodiode (Photo Diode) can still generate charges under the condition of no light at all, and current signals are formed to be read out, and the current signals are reflected as 'white' pixels in image imaging, so that the picture quality is reduced.
For some special application scenes, indexes of application dark current such as monitoring and the like are particularly important, main sources of the dark current include surface damage, silicon body stress, ion implantation damage, lattice defects and the like caused by plasma, for application fields such as monitoring, industrial monitoring, unmanned aerial vehicle shooting and the like with high requirements on picture quality, a large pixel structure is adopted in design, namely the area of a photodiode region is particularly large to obtain enough light entering quantity, the pixel size of the product is usually more than 5 micrometers, even more, the size can be more than ten micrometers, in order to prevent tailing effect, the ion implantation of the photodiode region (PD region) is not too deep, and the dark current caused by the surface damage is particularly obvious under the condition that the product has an overlarge surface area and is shallow.
In the existing image sensor manufacturing process, referring to fig. 1-2, fig. 1-2 are schematic device diagrams in the existing image sensor manufacturing process, in the sidewall etching process, the image sensor undergoes the change process from fig. 1 to fig. 2, and the silicon nitride layer, the oxide layer and the high-temperature thermal oxide layer on the substrate are removed by dry etching, however, the etched photodiode region surface only has a gate oxide layer with the thickness of 10nm, and plasma acting on the surface in the etching process is easy to cause damage, so that dark current is caused, and for products with the pixel size larger than 5 micrometers, the dark current caused by surface damage of the photodiode region is more obvious.
Disclosure of Invention
The invention aims to provide an image sensor and a manufacturing method thereof, which are used for preventing the surface of a photodiode region from being damaged in the manufacturing process of the image sensor, thereby effectively reducing dark current and further improving the image performance of a product.
In a first aspect, to achieve the above object, the present invention provides a method for manufacturing an image sensor, including the following steps:
s1, providing a semiconductor substrate, wherein a pixel device area is defined in the semiconductor substrate and comprises a photodiode area and a transfer transistor area, a first gate structure and a side wall material layer which covers the surface of the first gate structure and extends to cover the surface of the semiconductor substrate corresponding to the photodiode area are sequentially formed on the surface of the semiconductor substrate corresponding to the transfer transistor area, and the surface of the side wall material layer is a nitride layer;
s2, performing an oxygen treatment process on the surface layer of the side wall material layer, which faces away from the first gate structure, so that the surface layer of the side wall material layer, which faces away from the first gate structure, is converted into an oxynitride layer;
s3, forming a patterned photoresist layer, wherein the patterned photoresist layer covers the photodiode region and the surface of the side wall material layer corresponding to a part of the transfer transistor region to expose a part of the side wall material layer corresponding to the transfer transistor region;
s4, etching the exposed side wall material layer by taking the patterned photoresist layer as a mask so as to form a first side wall structure on one side of the first grid structure;
and S5, removing the patterned photoresist layer, and performing subsequent processes on the semiconductor substrate including the side wall material layer covering the photodiode region and part of the transfer transistor region to form the electrical structure of the image sensor.
Further, a device isolation structure and a logic device region separated from the pixel device region by the device isolation structure may be further formed in the semiconductor substrate provided in step S1, and a second gate structure may be formed on a surface of the semiconductor substrate corresponding to the logic device region; the spacer material layer in step S1 may further extend to cover the surfaces of the device isolation structure and the second gate structure.
Furthermore, the side wall material layer can be of a single-layer structure or a double-layer structure.
Further, when the side wall material layer is of a single-layer structure, the material of the side wall material layer may include nitride; when the side wall material layer is of a multilayer structure, the material of the side wall material layer may include an oxide and a nitride which are stacked in sequence.
Further, the process conditions of the oxygen treatment process in the step S2 may include: the temperature range can be 200-300 ℃, the reaction gas can be a mixed gas of oxygen and nitrogen, and the process duration can be 20-90 s.
Further, the process of removing the patterned photoresist layer in step S5 may be a dry etching process; the process conditions of the dry etching process may include: the temperature range is 200-300 ℃, the reaction gas can be plasma gas of oxygen and nitrogen, and the process duration can be 30-90 s.
Further, the step of performing subsequent processes on the semiconductor substrate in the step S5 may include:
s5.1, sequentially depositing an oxide layer, a nitride layer, an interlayer dielectric layer and a patterned hard mask layer on the surface of the semiconductor substrate including the side wall material layer which covers the photodiode region and part of the transfer transistor region;
s5.2, with the hard mask layer as a mask, etching the interlayer dielectric layer and the nitride layer to form corresponding contact holes in the transfer transistor area and the logic device area, wherein the bottoms of the contact holes are exposed out of the tops of the first grid structure or the second grid structure;
and S5.3, forming a conductive plug filled in the contact hole.
Further, the boundary of the patterned photoresist layer formed in the step S3 along a side close to the logic device region may be horizontally spaced from the conductive plug formed in the transfer transistor region by 1/5 to 1/3L, where L may be a width of the conductive plug formed in the transfer transistor region in a direction parallel to the surface of the semiconductor substrate.
Further, in step S4, while forming the first sidewall structure of the first gate structure, second sidewall structures may be formed on two sides of the second gate structure.
In a second aspect, the present invention also provides an image sensor based on the manufacturing method of the image sensor, and in particular, the image sensor can be manufactured by the manufacturing method of the image sensor.
Compared with the prior art, the technical scheme of the invention has the following beneficial effects:
according to the manufacturing method of the image sensor, the patterned photoresist layer is formed on the semiconductor substrate before the side wall etching process (forming the first side wall structure and the second side wall structure) so as to cover the surface of the semiconductor substrate corresponding to the photodiode region, and then the subsequent etching process is performed, so that the semiconductor substrate corresponding to the photodiode region is prevented from being completely exposed in a plasma environment in the etching process, the damage to the surface of the semiconductor substrate corresponding to the photodiode region is avoided, the dark current caused by the surface damage is further avoided, the normal functions of the pixel device region and the logic device region are ensured, and the performance of the image sensor is finally improved.
The image sensor provided by the invention is manufactured by adopting the manufacturing method of the image sensor provided by the invention, the photoresist covers the photodiode area, so that the surface damage of plasma gas in an etching process to the photodiode area is avoided, the dark current caused by the surface damage is avoided, and the performance of the image sensor is improved.
Drawings
FIG. 1 is a schematic diagram of a device in a prior art image sensor manufacturing process;
FIG. 2 is a schematic diagram of a device in a prior art image sensor manufacturing process;
fig. 3 is a schematic flow chart of a method for manufacturing an image sensor according to an embodiment of the present invention;
fig. 4a to 4f are schematic structural diagrams of a method for manufacturing an image sensor according to an embodiment of the present invention during a manufacturing process thereof.
Wherein the reference numerals are as follows:
01-a nitride layer; 02-an oxide layer; 03-high temperature thermal oxidation layer; 04-gate oxide layer; 05-photodiode region; 11-photodiode region; 12-pixel device region; 13-logic device area; 14 a-a first gate structure; 14 b-a second gate structure; a-a first sidewall structure; 15-device isolation structures; 16-a semiconductor substrate; 17-a gate oxide layer; 18-high temperature thermal oxidation layer; 19-an oxide layer; a 20-nitride layer; 20' -an oxynitride layer; 21-a patterned photoresist layer; 22-an oxide layer; 23-a nitride layer; 24-interlayer dielectric layer; 25-conductive plug.
Detailed Description
As described in the background art, at present, for some special application scenarios, such as monitoring, etc., the index of applying dark current is particularly important, the main sources of dark current include surface damage caused by plasma, silicon bulk stress, ion implantation damage, lattice defects, etc., for application fields with high requirements on picture quality, such as monitoring, industrial monitoring, unmanned aerial vehicle shooting, etc., a large pixel structure is adopted in design, that is, the area of a photodiode region is particularly large to obtain sufficient light input, the pixel size of such products is usually above 5 micrometers, even more, tens of micrometers can be achieved, in order to prevent "tailing effect", the ion implantation of the photodiode region (PD region) is generally not too deep, and the dark current caused by surface damage is particularly significant under the condition that such products have an ultra-large surface area and the ion implantation is shallow.
In the existing image sensor manufacturing process, referring to fig. 1-2, fig. 1-2 are schematic device diagrams in the existing image sensor manufacturing process, in the sidewall etching process, the image sensor undergoes the change process from fig. 1 to fig. 2, a silicon nitride layer, an oxide layer and a high-temperature thermal oxide layer on a substrate are removed by dry etching, however, the surface of an etched photodiode region is only a gate oxide layer with the thickness of 10nm, and plasma in the etching process acts on the surface to easily cause damage, so that dark current is caused, and for products with the pixel size larger than 5 micrometers, the dark current caused by the surface damage of the photodiode region is more obvious, wherein, the 01-nitride layer; 02-an oxide layer; 03-high temperature thermal oxidation layer; 04-gate oxide layer; 05-photodiode region.
Therefore, the invention provides an image sensor and a manufacturing method thereof, which are used for preventing the surface of a photodiode region from being damaged in the manufacturing process of the image sensor, thereby effectively reducing dark current and further improving the image performance of a product. Referring to fig. 3 in detail, fig. 3 is a schematic flow chart of a manufacturing method of an image sensor according to an embodiment of the present invention, and as can be seen from fig. 3, the manufacturing method of the image sensor may specifically include the following steps:
s1, providing a semiconductor substrate, wherein a pixel device area is defined in the semiconductor substrate and comprises a photodiode area and a transfer transistor area, a first gate structure and a side wall material layer which covers the surface of the first gate structure and extends to cover the surface of the semiconductor substrate corresponding to the photodiode area are sequentially formed on the surface of the semiconductor substrate corresponding to the transfer transistor area, and the surface of the side wall material layer is a nitride layer;
s2, performing an oxygen treatment process on the surface layer of the side wall material layer, which faces away from the first gate structure, so that the surface layer of the side wall material layer, which faces away from the first gate structure, is converted into an oxynitride layer;
s3, forming a patterned photoresist layer, wherein the patterned photoresist layer covers the photodiode region and the surface of the side wall material layer corresponding to a part of the transfer transistor region to expose a part of the side wall material layer corresponding to the transfer transistor region;
s4, etching the exposed side wall material layer by taking the patterned photoresist layer as a mask so as to form a first side wall structure on one side of the first grid structure;
and S5, removing the patterned photoresist layer, and performing subsequent processes on the semiconductor substrate including the side wall material layer covering the photodiode region and part of the transfer transistor region to form the electrical structure of the image sensor.
That is, in the method for manufacturing an image sensor provided by the present invention, a patterned photoresist layer is formed on a semiconductor substrate before a sidewall etching process (forming a first sidewall structure and a second sidewall structure) to cover the photoresist layer on the surface of the semiconductor substrate corresponding to a photodiode region, and then a subsequent etching process is performed to prevent the semiconductor substrate corresponding to the photodiode region from being completely exposed to a plasma environment in the etching process, thereby avoiding damage to the surface of the semiconductor substrate corresponding to the photodiode region, further avoiding dark current caused by surface damage, ensuring normal functions of a pixel device region and a logic device region, and finally improving the performance of the image sensor.
The image sensor and the method for manufacturing the same according to the present invention will be described in further detail with reference to the accompanying drawings and specific embodiments. The advantages and features of the present invention will become more apparent from the following description. It is to be noted that the drawings are in a very simplified form and are not to precise scale, which is merely for the purpose of facilitating and distinctly claiming the embodiments of the present invention.
Fig. 4a to 4f are schematic structural diagrams illustrating a manufacturing method of an image sensor in an embodiment of the invention during a manufacturing process thereof.
In step S1, and with particular reference to fig. 4a, a semiconductor substrate 16 is provided, the semiconductor substrate 16 being used to provide a platform for operation of the subsequent process for producing an image sensor device. The material of the semiconductor substrate 16 is selected from monocrystalline silicon, polycrystalline silicon or amorphous silicon; the semiconductor substrate 16 may also be selected from compounds such as silicon, germanium, gallium arsenide, or silicon germanium; the semiconductor substrate 16 may also be other semiconductor materials. Illustratively, in the embodiment of the present invention, the semiconductor substrate 16 is a silicon substrate. In the embodiment of the present invention, a pixel device region is defined in the semiconductor substrate 16, the pixel device region includes a photodiode region 11 and a transfer transistor region 12, a first gate structure 14a and a sidewall material layer covering the surface of the first gate structure 14a and extending to cover the surface of the semiconductor substrate 16 corresponding to the photodiode region 12 are sequentially formed on the surface of the semiconductor substrate 16 corresponding to the transfer transistor region 12, where the sidewall material layer may be a multilayer structure, and specifically, the sidewall material layer in the embodiment of the present invention may be a multilayer structure composed of a high temperature oxide layer 18, an oxide layer 19, and a nitride layer 20, which are sequentially stacked in a direction away from the surface of the semiconductor substrate 16. Also, the photodiode region 11 may be a PD region having a certain junction depth obtained by an ion implantation process into the semiconductor substrate 16. The first gate structure 14a includes a gate oxide layer 17, and the gate oxide layer 17 further extends to cover the surface of the semiconductor substrate 16 corresponding to the photodiode region 12.
Further, as shown in fig. 4a, a device isolation structure 15 and a logic device region 13 separated from the pixel device regions (11 and 12) by the device isolation structure 15 are further formed in the semiconductor substrate 16, and a second gate structure 14b is formed on a surface of the semiconductor substrate 16 corresponding to the logic device region 13; the side wall material layer in step S1 further extends to cover the surfaces of the device isolation structure 15 and the second gate structure 14 b. Illustratively, the device isolation structure 15 may be a shallow trench isolation structure.
Furthermore, the side wall material layer may also be a single-layer structure made of nitride, such as silicon nitride, or a double-layer structure made of oxide and nitride, such as a stacked structure of silicon dioxide and silicon nitride, and the silicon nitride is located on the surface of the silicon dioxide.
In step S2, referring to fig. 4b, an oxygen treatment process is performed on a surface of the sidewall material layer facing away from the first gate structure 14a (and the second gate structure 14b), so that a surface of the sidewall material layer 110 facing away from the first gate structure 14a (and the second gate structure 14b) is converted into an oxynitride layer 20'.
In this embodiment, since the photoresist (photoresist) is "poisoned" due to the direct contact between the photoresist (photoresist) and the nitride layer 20 in the sidewall material layer in practical applications, and the subsequent process cannot clean the "poisoned" photoresist, thereby forming contaminants on the semiconductor substrate 16, in order to solve the problem, the method for manufacturing an image sensor according to the present invention needs to perform an oxidation process on the sidewall material layer before forming the patterned photoresist layer 21 (photoresist layer) in step S3, so as to convert the surface of the sidewall material layer from the nitride layer 20 to the oxynitride layer 20'. Specifically, the semiconductor substrate 16 may be placed in a reaction chamber containing a mixed gas of oxygen and nitrogen at a temperature of 200 ℃ to 300 ℃ for 20 seconds to 90 seconds, so that the nitride layer 20 included in the sidewall material layer is converted into plasma in the chamber to prepare for forming the patterned photoresist layer 21 by subsequent coating.
In step S3, referring to fig. 4c, a patterned photoresist layer 21 is formed, and the patterned photoresist layer 21 covers the photodiode region 11 and a portion of the surface of the oxynitride layer 20 'of the sidewall material layer corresponding to the transfer transistor region 12 to expose a portion of the surface of the oxynitride layer 20' of the sidewall material layer corresponding to the transfer transistor region 12.
In this embodiment, a photoresist layer (not shown) may be formed on the surface of the oxynitride layer 20' of the sidewall material layer, then, the semiconductor substrate 16 is exposed through a preset mask, and a pattern on the mask is copied onto the photoresist layer, so that the photoresist coated on the logic device region 12 and the pixel device region 13 is exposed by the mask, and the exposed photoresist is developed, so that the photoresist on the photodiode region 11 is retained, that is, a patterned photoresist layer 21 is formed, and the retained patterned photoresist layer 21 protects the photodiode region 11.
It should be noted that, in consideration of a slight offset in an actual photolithography process, the boundary position of the reserved area of the patterned photoresist layer 21 should be disposed on the first gate structure 14a of the pixel device area 12 to ensure that the photodiode area 11 is completely protected, and further, in consideration of that the formation position of the subsequent conductive plug 25 must be located in the photoresist developing area, the boundary position of the reserved area of the patterned photoresist layer 21 cannot exceed the edge of the first gate structure 14a of the pixel device area 12 by too much, and an optimal boundary position of the reserved area of the patterned photoresist layer 21 needs to be defined according to actual conditions. Specifically, the horizontal distance between the boundary of the patterned photoresist layer 21 formed in the step S3 along the side close to the logic device region 13 and the conductive plug 25 formed in the transfer transistor region 12 is 1/5-1/3L, where L is the width of the conductive plug 25 formed in the transfer transistor region 12 along the direction parallel to the surface of the semiconductor substrate 16. Preferably, as shown in fig. 4c and 4f, the distance from the conductive plug 25 of the pixel device region 12 to the edge of the first gate structure 14a of the pixel device region 12 close to the photodiode region 11 is L, and the distance from the boundary position of the remaining region of the patterned photoresist layer 21 to the edge of the first gate structure 14a of the pixel device region 12 close to the photodiode region 11 may be 1/3L-1/5L.
In step S4, referring to fig. 4d and referring to fig. 4c, the exposed spacer material layer is etched using the patterned photoresist layer 21 as a mask, so as to form a first spacer structure a on one side of the first gate structure 14 a.
In this embodiment, when the exposed sidewall material layer including the high temperature thermal oxide layer 18, the oxide layer 19 and the oxynitride layer 20' is etched in step S4, the patterned photoresist layer 21 is formed on the surfaces of the sidewall material layer in the photodiode region 11 and the partial transfer transistor region 12, so that the surface of the photodiode region 11 is not damaged by plasma in the sidewall etching process, thereby reducing dark current caused by surface damage, improving device performance, and ensuring normal operation of the pixel device region 12 and the logic device region 13. Further, for an image sensor with a large pixel size, i.e. an image sensor with a pixel unit size larger than 5 μm, the technical solution of the present embodiment can significantly reduce the dark current caused by the surface damage caused by the plasma due to the shallow ion implantation of the photodiode region 11 of the image sensor with a large pixel size.
In step S5, referring to fig. 4e and 4f, the patterned photoresist layer 21 is removed, and a subsequent process is performed on the semiconductor substrate 16 including the sidewall material layer covering the photodiode region 11 and a portion of the transfer transistor region 12, so as to form an electrical structure of the image sensor.
In this embodiment, the step of performing subsequent processes on the semiconductor substrate 16 in the step S5 includes: s5.1, sequentially depositing an oxide layer 22, a nitride layer 23, an interlayer dielectric layer 24 and a patterned hard mask layer (not shown) on the surface of the semiconductor substrate 16 including the side wall material layer covering the photodiode region 11 and part of the transfer transistor region 12; s5.2, with the hard mask layer as a mask, etching the interlayer dielectric layer 24 and the nitride layer 23 to form corresponding contact holes (not shown) in the transfer transistor region 12 and the logic device region 13, wherein the bottoms of the contact holes expose the tops of the first gate structures 14a or the second gate structures 14 b; and S5.3, forming a conductive plug 25 filled in the contact hole.
In this embodiment, the step of removing the patterned photoresist layer 21 on the semiconductor substrate 16, i.e. removing the photoresist layer 21 remained in the photodiode region 11, includes: the plasma gas of oxygen and nitrogen lasts for 30-90 seconds in the cavity at 200-300 ℃, so that the photoresist layer 21 is completely removed.
Further, after removing the photoresist layer 21, an oxide layer, such as silicon dioxide, may be formed on the semiconductor substrate 16, and then, the oxide layer covering the top surfaces of the first gate structure 14a and the second gate structure 14b is removed by photolithography and etching processes to form an oxide layer 22 shown in fig. 4e, so that the remaining oxide layer 22 covers all the surfaces of the semiconductor substrate 16 except the top surfaces of the first gate structure 14a and the second gate structure 14 b. Finally, a nitride layer 23 and an interlayer dielectric layer 24 are formed on the structure shown in fig. 4e, and a conductive plug 25 for electrically connecting the first gate structure 14a and the second gate structure 14b is formed in the interlayer dielectric layer 24 and the nitride layer 23, respectively, by an etching process.
In summary, in the manufacturing method of the image sensor provided by the present invention, the patterned photoresist layer is formed on the semiconductor substrate before the sidewall etching process (forming the first sidewall structure and the second sidewall structure) to cover the surface of the semiconductor substrate corresponding to the photodiode region, and then the subsequent etching process is performed to prevent the semiconductor substrate corresponding to the photodiode region from being completely exposed to the plasma environment in the etching process, so as to avoid damage to the surface of the semiconductor substrate corresponding to the photodiode region, thereby avoiding dark current caused by surface damage, ensuring normal functions of the pixel device region and the logic device region, and finally improving the performance of the image sensor.
The image sensor provided by the invention is manufactured by adopting the manufacturing method of the image sensor provided by the invention, the photoresist covers the photodiode area, so that the surface damage of plasma gas in an etching process to the photodiode area is avoided, the dark current caused by the surface damage is avoided, and the performance of the image sensor is improved.
It should be noted that, although the present invention has been described with reference to the preferred embodiments, the present invention is not limited to the embodiments. It will be apparent to those skilled in the art from this disclosure that many changes and modifications can be made, or equivalents modified, in the embodiments of the invention without departing from the scope of the invention. Therefore, any simple modification, equivalent change and modification made to the above embodiments according to the technical essence of the present invention are still within the protection scope of the technical solution of the present invention, unless the content of the technical solution of the present invention is departed from.
It should be further understood that the terms "first," "second," "third," and the like in the description are used for distinguishing between various components, elements, steps, and the like, and are not intended to imply a logical or sequential relationship between various components, elements, steps, or the like, unless otherwise indicated or indicated.
It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to limit the scope of the present invention. It must be noted that, as used herein and in the appended claims, the singular forms "a," "an," and "the" include plural referents unless the context clearly dictates otherwise. For example, reference to "a step" or "an apparatus" means a reference to one or more steps or apparatuses and may include sub-steps as well as sub-apparatuses. All conjunctions used should be understood in the broadest sense. And, the word "or" should be understood to have the definition of a logical "or" rather than the definition of a logical "exclusive or" unless the context clearly dictates otherwise. Further, implementation of the methods and/or apparatus of embodiments of the present invention may include performing the selected task manually, automatically, or in combination.

Claims (10)

1.一种图像传感器的制造方法,其特征在于,包括:1. A method of manufacturing an image sensor, comprising: S1、提供一半导体衬底,所述半导体衬底内定义有像素器件区,所述像素器件区包括光电二极管区和转移晶体管区,在所述转移晶体管区对应的半导体衬底的表面上依次形成有第一栅极结构和覆盖在所述第一栅极结构表面上,并延伸覆盖在所述光电二极管区对应的半导体衬底表面上的侧墙材料层,所述侧墙材料层的表面为氮化物层;S1. Provide a semiconductor substrate, wherein a pixel device region is defined in the semiconductor substrate, and the pixel device region includes a photodiode region and a transfer transistor region, which are sequentially formed on the surface of the semiconductor substrate corresponding to the transfer transistor region There is a first gate structure and a spacer material layer covering the surface of the first gate structure and extending and covering the surface of the semiconductor substrate corresponding to the photodiode region, and the surface of the spacer material layer is nitride layer; S2、对所述侧墙材料层背向所述第一栅极结构的表层进行氧气处理工艺,以使得所述侧墙材料层背向所述第一栅极结构的表层转换为氮氧化物层;S2, performing an oxygen treatment process on the surface layer of the spacer material layer facing away from the first gate structure, so that the surface layer of the spacer material layer facing away from the first gate structure is converted into an oxynitride layer ; S3、形成图案化的光阻层,所述图案化的光阻层覆盖在所述光电二极管区和部分所述转移晶体管区对应的侧墙材料层的表面上,以暴露出部分所述转移晶体管区对应的侧墙材料层;S3. Forming a patterned photoresist layer, the patterned photoresist layer covers the surface of the spacer material layer corresponding to the photodiode region and part of the transfer transistor region, so as to expose part of the transfer transistor The corresponding side wall material layer of the zone; S4、以所述图案化的光阻层为掩膜,刻蚀所述暴露出的侧墙材料层,以在所述第一栅极结构的一侧形成第一侧墙结构;S4, using the patterned photoresist layer as a mask, etching the exposed spacer material layer to form a first spacer structure on one side of the first gate structure; S5、去除所述图案化的光阻层,并对包含所述覆盖在所述光电二极管区和部分所述转移晶体管区对应的侧墙材料层的所述半导体衬底进行后续工艺,以形成所述图像传感器的电学结构。S5. Remove the patterned photoresist layer, and perform a subsequent process on the semiconductor substrate including the spacer material layer corresponding to the photodiode region and part of the transfer transistor region to form the patterned photoresist layer. Describe the electrical structure of the image sensor. 2.如权利要求1所述的图像传感器的制造方法,其特征在于,所述步骤S1中提供的半导体衬底内还形成有器件隔离结构和通过所述器件隔离结构与所述像素器件区分离开的逻辑器件区,且所述逻辑器件区对应的半导体衬底的表面上形成有第二栅极结构;所述步骤S1中的侧墙材料层还延伸覆盖在所述器件隔离结构和所述第二栅极结构的表面上。2 . The method for manufacturing an image sensor according to claim 1 , wherein a device isolation structure is further formed in the semiconductor substrate provided in the step S1 and is separated from the pixel device by the device isolation structure. 3 . the logic device region, and a second gate structure is formed on the surface of the semiconductor substrate corresponding to the logic device region; the spacer material layer in the step S1 also extends and covers the device isolation structure and the first gate structure. on the surface of the two gate structures. 3.如权利要求2所述的图像传感器的制造方法,其特征在于,所述侧墙材料层为单层结构或双层结构。3 . The method for manufacturing an image sensor according to claim 2 , wherein the sidewall material layer has a single-layer structure or a double-layer structure. 4 . 4.如权利要求3所述的图像传感器的制造方法,其特征在于,当所述侧墙材料层为单层结构时,所述侧墙材料层的材料包括氮化物;当所述侧墙材料层为多层结构时,所述侧墙材料层的材料包括依次堆叠的氧化物和氮化物。4 . The method for manufacturing an image sensor according to claim 3 , wherein when the spacer material layer is a single-layer structure, the material of the spacer material layer comprises nitride; When the layer is a multi-layer structure, the material of the spacer material layer includes oxides and nitrides stacked in sequence. 5.如权利要求1所述的图像传感器的制造方法,其特征在于,所述步骤S2中的氧气处理工艺的工艺条件包括:温度范围为200℃~300℃,反应气体为氧气与氮气的混合气体,工艺持续时间为20s~90s。5 . The manufacturing method of an image sensor according to claim 1 , wherein the process conditions of the oxygen treatment process in the step S2 include: a temperature range of 200° C. to 300° C., and the reaction gas is a mixture of oxygen and nitrogen. 6 . gas, and the process duration is 20s to 90s. 6.如权利要求1所述的图像传感器的制造方法,其特征在于,所述步骤S5中去除所述图案化的光阻层的工艺为干法刻蚀工艺;所述干法刻蚀工艺的工艺条件包括:温度范围为200℃~300℃,反应气体为氧气与氮气的等离子气体,工艺持续时间为30s~90s。6 . The method for manufacturing an image sensor according to claim 1 , wherein the process of removing the patterned photoresist layer in the step S5 is a dry etching process; The process conditions include: the temperature range is 200°C to 300°C, the reaction gas is a plasma gas of oxygen and nitrogen, and the process duration is 30s to 90s. 7.如权利要求2所述的图像传感器的制造方法,其特征在于,所述步骤S5中对所述半导体衬底进行后续工艺的步骤包括:7. The method for manufacturing an image sensor according to claim 2, wherein the step of performing a subsequent process on the semiconductor substrate in the step S5 comprises: S5.1、在包含所述覆盖在所述光电二极管区和部分所述转移晶体管区对应的侧墙材料层的所述半导体衬底的表面上依次沉积氧化物层、氮化物层、层间介质层和图案化的硬掩膜层;S5.1. On the surface of the semiconductor substrate including the spacer material layer corresponding to the photodiode region and part of the transfer transistor region, sequentially deposit an oxide layer, a nitride layer, and an interlayer dielectric layers and patterned hardmask layers; S5.2、以所述硬掩膜层为掩膜,刻蚀所述层间介质层和氮化物层,以在所述转移晶体管区和逻辑器件区中形成相应的接触孔,所述接触孔的底部暴露出所述第一栅极结构或所述第二栅极结构的顶部;S5.2. Using the hard mask layer as a mask, etch the interlayer dielectric layer and the nitride layer to form corresponding contact holes in the transfer transistor region and the logic device region, and the contact holes The bottom of the first gate structure or the top of the second gate structure is exposed; S5.3、形成填充于所述接触孔中的导电插塞。S5.3, forming a conductive plug filled in the contact hole. 8.如权利要求7所述的图像传感器的制造方法,其特征在于,所述步骤S3中形成的所述图案化的光阻层沿靠近所述逻辑器件区一侧的边界与形成在所述转移晶体管区中的导电插塞的水平间距为1/5~1/3L,其中L为所述转移晶体管区中形成的导电插塞沿平行于所述半导体衬底表面方向的宽度。8 . The manufacturing method of an image sensor according to claim 7 , wherein the patterned photoresist layer formed in the step S3 is formed on the border of the side close to the logic device region and formed on the The horizontal spacing of the conductive plugs in the transfer transistor region is 1/5˜1/3L, where L is the width of the conductive plugs formed in the transfer transistor region along a direction parallel to the surface of the semiconductor substrate. 9.如权利要求2所述的图像传感器的制造方法,其特征在于,所述步骤S4中在形成第一栅极结构的第一侧墙结构的同时,在所述第二栅极结构的两侧形成第二侧墙结构。9 . The manufacturing method of the image sensor according to claim 2 , wherein in the step S4 , while forming the first spacer structure of the first gate structure, two parts of the second gate structure are formed at the same time. 10 . The sides form a second sidewall structure. 10.一种图像传感器,其特征在于,采用权利要求1~9中任一项所述的图像传感器的制造方法制成。10. An image sensor produced by the method of manufacturing an image sensor according to any one of claims 1 to 9.
CN202111005082.5A 2021-08-30 2021-08-30 Image sensor and method for manufacturing the same Pending CN113725244A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111005082.5A CN113725244A (en) 2021-08-30 2021-08-30 Image sensor and method for manufacturing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111005082.5A CN113725244A (en) 2021-08-30 2021-08-30 Image sensor and method for manufacturing the same

Publications (1)

Publication Number Publication Date
CN113725244A true CN113725244A (en) 2021-11-30

Family

ID=78679304

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111005082.5A Pending CN113725244A (en) 2021-08-30 2021-08-30 Image sensor and method for manufacturing the same

Country Status (1)

Country Link
CN (1) CN113725244A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115020324A (en) * 2022-05-07 2022-09-06 上海华力集成电路制造有限公司 Double-pattern process method
CN115132771A (en) * 2022-09-01 2022-09-30 合肥晶合集成电路股份有限公司 Image sensor and manufacturing method thereof
CN120018604A (en) * 2025-04-18 2025-05-16 荣芯半导体(宁波)有限公司 Semiconductor device and manufacturing method thereof, and electronic device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060003519A1 (en) * 2004-07-01 2006-01-05 Dongbuanam Semiconductor Inc. Method for fabricating CMOS image sensor
KR20090025933A (en) * 2007-09-07 2009-03-11 삼성전자주식회사 Image sensor and its manufacturing method
CN105374835A (en) * 2014-08-06 2016-03-02 瑞萨电子株式会社 Semiconductor device and manufacturing method thereof
US10062584B1 (en) * 2017-06-05 2018-08-28 United Microelectronics Corp. Method for forming semiconductor structure
CN108630713A (en) * 2017-03-17 2018-10-09 中芯国际集成电路制造(上海)有限公司 Semiconductor structure and forming method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060003519A1 (en) * 2004-07-01 2006-01-05 Dongbuanam Semiconductor Inc. Method for fabricating CMOS image sensor
KR20090025933A (en) * 2007-09-07 2009-03-11 삼성전자주식회사 Image sensor and its manufacturing method
CN105374835A (en) * 2014-08-06 2016-03-02 瑞萨电子株式会社 Semiconductor device and manufacturing method thereof
CN108630713A (en) * 2017-03-17 2018-10-09 中芯国际集成电路制造(上海)有限公司 Semiconductor structure and forming method thereof
US10062584B1 (en) * 2017-06-05 2018-08-28 United Microelectronics Corp. Method for forming semiconductor structure

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115020324A (en) * 2022-05-07 2022-09-06 上海华力集成电路制造有限公司 Double-pattern process method
CN115132771A (en) * 2022-09-01 2022-09-30 合肥晶合集成电路股份有限公司 Image sensor and manufacturing method thereof
CN120018604A (en) * 2025-04-18 2025-05-16 荣芯半导体(宁波)有限公司 Semiconductor device and manufacturing method thereof, and electronic device

Similar Documents

Publication Publication Date Title
CN113725244A (en) Image sensor and method for manufacturing the same
US7652331B2 (en) Semiconductor device and method for fabricating the same
US7294524B2 (en) Method for fabricating image sensor without LTO-based passivation layer
JP2970158B2 (en) Method for manufacturing solid-state imaging device
CN102637706A (en) Semiconductor device manufacturing method
CN115295570A (en) Method for manufacturing CMOS image sensor
CN109841503A (en) The production method of self-alignment duplex pattern semiconductor structure
CN114725145A (en) A kind of semiconductor structure and its manufacturing method
US8513037B2 (en) Method of integrating slotted waveguide into CMOS process
CN105529274B (en) Production method, array substrate and the display device of thin film transistor (TFT)
TWI567785B (en) Method for fabricating patterned structure of semiconductor device
CN114005846A (en) Manufacturing method of image sensor
JP2007180475A (en) Method for manufacturing semiconductor device using amorphous carbon
JP2003229551A (en) Method for manufacturing solid-state imaging apparatus
JP2002373935A (en) Trench element isolation method
CN106158890B (en) Image sensor
CN107919367B (en) A method of manufacturing a semiconductor device
CN112331686A (en) Pixel structure of CMOS image sensor and method for forming the pixel structure
TWI703714B (en) Method of forming polysilicon gate structure in image sensor device, polysilicon gate structure and method of protecting pixel in image sensor device
JP6486137B2 (en) Manufacturing method of semiconductor device
JP6362373B2 (en) Method for manufacturing photoelectric conversion device
JP2007311391A (en) Solid-state imaging device and manufacturing method thereof
JPH0778956A (en) Fabrication of solid state image sensing element
TWI566297B (en) Semiconductor device and fabrication method of the same
KR100231847B1 (en) Method of fabricating semiconductor device

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20211130