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CN113724756B - Nonvolatile decimal photoelectric memory based on waveguide grating structure - Google Patents

Nonvolatile decimal photoelectric memory based on waveguide grating structure Download PDF

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CN113724756B
CN113724756B CN202110997579.3A CN202110997579A CN113724756B CN 113724756 B CN113724756 B CN 113724756B CN 202110997579 A CN202110997579 A CN 202110997579A CN 113724756 B CN113724756 B CN 113724756B
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change material
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crystalline
amorphous
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CN113724756A (en
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刘富荣
张露露
张永志
陈清远
谢轩轩
连阳波
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Beijing University of Technology
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    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C13/00Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/0002Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
    • G11C13/0004Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements comprising amorphous/crystalline phase transition cells
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C13/00Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/04Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using optical elements ; using other beam accessed elements, e.g. electron or ion beam
    • G11C13/047Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using optical elements ; using other beam accessed elements, e.g. electron or ion beam using electro-optical elements
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N70/00Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
    • H10N70/20Multistable switching devices, e.g. memristors
    • H10N70/231Multistable switching devices, e.g. memristors based on solid-state phase change, e.g. between amorphous and crystalline phases, Ovshinsky effect
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N70/00Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
    • H10N70/801Constructional details of multistable switching devices
    • H10N70/881Switching materials
    • H10N70/882Compounds of sulfur, selenium or tellurium, e.g. chalcogenides
    • H10N70/8828Tellurides, e.g. GeSbTe

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Abstract

A non-volatile decimal photoelectric memory based on a waveguide grating structure belongs to the technical field of information. The memory comprises a layer bottom, an optical waveguide, a conductive electrode material and a phase change material film. The phase change material film is deposited on the waveguide in an array grating structure, the state of the phase change material film can be changed through an electric signal, and the number of crystalline states and amorphous states can be programmed and controlled, so that data can be written into/erased from the grating array. The phase change material film has great difference in optical constants between crystalline and amorphous states, and can change the light propagation behavior in the optical waveguide. Thus, the written data can be read out by utilizing the difference in transmittance of the optical signal. The nonvolatile ultrafast phase change material of the invention combines the universality of electric drive and the ultrafast property of optical reading, realizes low loss and large capacity of the memory, has simple design structure and convenient integration, and lays a foundation for the development of future photoelectric devices.

Description

一种基于波导光栅结构的非易失性十进制光电存储器A non-volatile decimal optical memory based on waveguide grating structure

技术领域Technical field

本发明涉及一种光电混合器件,属于信息技术领域,具体涉及一种基于波导光栅结构的非易失性十进制光电存储器。The invention relates to an optoelectronic hybrid device, which belongs to the field of information technology, and specifically relates to a non-volatile decimal optoelectronic memory based on a waveguide grating structure.

背景技术Background technique

近几十年来,由于互联网技术的快速发展,记录信息和存储数据的半导体存储器具有不可替代的重要地位。目前,市面上的存储器主要分为易失性存储器和非易失性存储器两种。动态随机存储器(DRAM)存储单元的内容可随意写入和读取,并且写入速度与位置无关,但这种存储器易失性的,在断电时会丢失数据。闪存(FLASH)是则一种非易失性的存储器,在断电情况下仍能保存数据的完整性;但该结构擦除数据时以固定区域为单位,而不是以单个字节为单位擦除。In recent decades, due to the rapid development of Internet technology, semiconductor memories for recording information and storing data have played an irreplaceable and important role. Currently, memories on the market are mainly divided into two types: volatile memory and non-volatile memory. The contents of dynamic random access memory (DRAM) memory cells can be written and read at will, and the writing speed is independent of position, but this kind of memory is volatile and data will be lost when power is turned off. Flash memory (FLASH) is a non-volatile memory that can still preserve the integrity of data even when the power is off; however, this structure erases data in units of fixed areas rather than in units of single bytes. remove.

相变存储器(PCRAM)被认为是最具有潜力的非易失性存储器,其关键材料包括硅衬底、相变材料记录薄膜、加热电极材料、绝缘材料和引出电极材料。其原理是利用相变材料薄膜在晶态和非晶态之间转变进行写入、读取和擦除操作。目前来说,主要是利用晶态和非晶态之间的电阻差异或者光学常数的差别。当相变材料薄膜处于非晶态时,变现为高电阻值;利用电信号的热效应,可以将相变材料非晶态转变为晶态;当相变材料薄膜处于非晶态时,变现为低电阻值。利用这种电阻差异就可以实现二进制的数据存储。利用擦除电信号可以将相变材料薄膜从晶态转变为非晶态,从而达到擦除的操作。而相变光盘就是利用相变材料薄膜在晶态和非晶态之间的光学差异实现写入、读取和擦除操作。Phase change memory (PCRAM) is considered to be the most potential non-volatile memory. Its key materials include silicon substrate, phase change material recording film, heating electrode material, insulating material and extraction electrode material. The principle is to use a phase-change material film to transition between crystalline and amorphous states for writing, reading and erasing operations. At present, the difference in resistance or optical constants between crystalline and amorphous states is mainly used. When the phase change material film is in the amorphous state, it exhibits a high resistance value; using the thermal effect of the electrical signal, the amorphous state of the phase change material can be converted into a crystalline state; when the phase change material film is in the amorphous state, it exhibits a low resistance value. resistance. Binary data storage can be achieved using this resistance difference. The erasing electrical signal can be used to change the phase change material film from the crystalline state to the amorphous state, thereby achieving the erasing operation. The phase-change optical disc uses the optical difference between the crystalline and amorphous states of the phase-change material film to achieve writing, reading and erasing operations.

但是,目前相变存储器主要基于二进制数据进行写入和读出,在一个单元区域只能存储一个数据点,这大大降低了数据的容量。而且随着光子芯片的发展,实现光波导存储器也势在必行。相变材料薄膜可以波导中的传输光进行调控,并且在晶态和非晶态下表现出不同的特性。结合以上特性提出一种基于相变材料阵列波导光栅的非易失性十进制光电存储器。利用电信号进行写入和擦除,利用光信号进行读取,有利于信号传输,促进未来电光网络信息技术的发展。However, current phase change memory is mainly based on binary data for writing and reading, and can only store one data point in a unit area, which greatly reduces the data capacity. And with the development of photonic chips, it is also imperative to realize optical waveguide memory. Thin films of phase change materials can regulate the transmitted light in waveguides and exhibit different properties in the crystalline and amorphous states. Combining the above characteristics, a non-volatile decimal optoelectronic memory based on phase-change material array waveguide grating is proposed. Using electrical signals for writing and erasing and using optical signals for reading is beneficial to signal transmission and promotes the development of future electro-optical network information technology.

发明内容Contents of the invention

针对现有存储器的缺陷和改进需求,本发明提出一种基于相变材料阵列波导光栅的非易失性十进制光电存储器,目的在于提升存储容量,减小损耗。为了解决上述技术问题,本发明主要提供了如下技术方案。In view of the defects and improvement needs of existing memories, the present invention proposes a non-volatile decimal photoelectric memory based on phase-change material array waveguide gratings, with the purpose of increasing storage capacity and reducing losses. In order to solve the above technical problems, the present invention mainly provides the following technical solutions.

本发明首先提供了一种用于光电存储器的相变材料。如所述的相变材料薄膜包括不限于:Ge2Sb2Te5、GeTe、Sb2Te3此类硫系相变材料。The present invention first provides a phase change material for optoelectronic memory. The phase change material films described above include, but are not limited to, chalcogenide phase change materials such as Ge 2 Sb 2 Te 5 , GeTe, and Sb 2 Te 3 .

采用磁控溅射的方法制备所述的相变材料薄膜。The phase change material film is prepared by magnetron sputtering.

一种基于相变材料阵列波导光栅的非易失性十进制光电存储器,其特征在于,利用相变材料薄膜阵列光栅进行存储十进制数据;A non-volatile decimal photoelectric memory based on phase change material array waveguide grating, which is characterized in that the phase change material thin film array grating is used to store decimal data;

具体的结构包括如下:光波导位于衬底上,将相变材料薄膜光栅阵列沉淀在波导上表面上,利用光波导中的光进行读取数据;在每个相变材料薄膜光栅结构中即两侧面引入电极材料,对相变材料薄膜进行通电加热,改变相变材料薄膜的相态,从而实现数据的写入和擦除。The specific structure includes the following: the optical waveguide is located on the substrate, the phase change material thin film grating array is deposited on the upper surface of the waveguide, and the light in the optical waveguide is used to read data; in each phase change material thin film grating structure, there are two Electrode materials are introduced on the side to energize and heat the phase change material film, changing the phase state of the phase change material film, thereby realizing data writing and erasing.

相变材料薄膜光栅阵列沿光波导的长度方向进行并列排列,优选为9个光栅结构。The phase change material thin film grating arrays are arranged side by side along the length direction of the optical waveguide, preferably with nine grating structures.

当全是晶态时,表示写入“0”;有几个非晶态代表写入的是几,所述的非晶态是从阵列的一端开始并连续的的;当1个非晶态,8个晶态时,表示写入“1”。当2个非晶态,7个晶态时,表示写入“2”。以此类推,当全是非晶态时,表示写入“9”。When they are all crystalline, it means writing "0"; there are several amorphous states, which means how many are written, and the amorphous state starts from one end of the array and is continuous; when 1 amorphous state , when there are 8 crystal states, it means writing "1". When there are 2 amorphous states and 7 crystalline states, it means writing "2". By analogy, when it is all amorphous, it means writing "9".

作为优选,每个相变材料薄膜光栅结构的宽即光波导的宽相等,优选为500nm,每个相变材料薄膜光栅结构的长即沿光波导的长度方法的长优选为250nm;光栅周期1000nm。Preferably, the width of each phase change material film grating structure is equal to the width of the optical waveguide, preferably 500 nm. The length of each phase change material film grating structure, that is, the length along the length of the optical waveguide, is preferably 250 nm; the grating period is 1000 nm. .

作为优选,相变材料薄膜的厚度从左到右依次选择为2个10nm、4个20nm、3个30nm。Preferably, the thickness of the phase change material film is selected from left to right as two 10nm thicknesses, four 20nm thicknesses, and three 30nm thicknesses.

作为优选,光波导的厚度选择为220nm,宽度选择为500nm。Preferably, the thickness of the optical waveguide is selected to be 220nm, and the width is selected to be 500nm.

作为优选,所述导电极材料选择金、铝、铜和钨等。Preferably, the conductive electrode material is gold, aluminum, copper, tungsten, etc.

与现有技术相比,本发明的有益效果Compared with the existing technology, the beneficial effects of the present invention

本发明提出了一种基于相变材料阵列波导光栅的非易失性十进制光电存储器,相变材料薄膜阵列光栅在电极的作用下,可以在晶态和非晶态之间转变。通过编程处理,控制相变材料薄膜阵列光栅的晶态和非晶态数,可以实现数据的写入和擦除。相变材料薄膜可以对光场的调控,利用光的传输就可以读出存储的数据。从而实现了电存储,光读取的过程。十进制的存储可以提升数据的存储容量,光读取后传递信号不需要转变成光进行传递,降低了能耗。对未来大规模的集成光电网络有重要的应用价值。The invention proposes a non-volatile decimal photoelectric memory based on phase change material array waveguide grating. The phase change material thin film array grating can transform between crystalline and amorphous states under the action of electrodes. Through programming processing, the number of crystalline and amorphous states of the phase change material thin film array grating can be controlled, so that data can be written and erased. The phase change material film can control the light field, and the stored data can be read out using the transmission of light. Thus realizing the process of electrical storage and optical reading. Decimal storage can increase the storage capacity of data. After optical reading, the signal does not need to be converted into light for transmission, which reduces energy consumption. It has important application value for future large-scale integrated photoelectric networks.

附图说明Description of the drawings

图1是一种基于波导光栅结构的非易失性十进制光电存储器结构示意图。Figure 1 is a schematic structural diagram of a non-volatile decimal optical memory based on a waveguide grating structure.

图2是所设计的十进制光电存储器读取“0”示意图。Figure 2 is a schematic diagram of the designed decimal photoelectric memory for reading "0".

图3是所设计的十进制光电存储器读取“1”示意图。Figure 3 is a schematic diagram of the designed decimal photoelectric memory reading "1".

图4是所设计的十进制光电存储器读取“2”示意图。Figure 4 is a schematic diagram of the designed decimal photoelectric memory reading "2".

图5是所设计的十进制光电存储器读取“3”示意图。Figure 5 is a schematic diagram of the designed decimal photoelectric memory reading "3".

图6是所设计的十进制光电存储器读取“4”示意图。Figure 6 is a schematic diagram of the designed decimal photoelectric memory for reading "4".

图7是所设计的十进制光电存储器读取“5”示意图。Figure 7 is a schematic diagram of the designed decimal photoelectric memory for reading "5".

图8是所设计的十进制光电存储器读取“6”示意图。Figure 8 is a schematic diagram of the designed decimal photoelectric memory for reading "6".

图9是所设计的十进制光电存储器读取“7”示意图。Figure 9 is a schematic diagram of the designed decimal photoelectric memory for reading "7".

图10是所设计的十进制光电存储器读取“8”示意图。Figure 10 is a schematic diagram of the designed decimal photoelectric memory for reading "8".

图11是所设计的十进制光电存储器读取“9”示意图。Figure 11 is a schematic diagram of the designed decimal photoelectric memory for reading "9".

图12是所设计的十进制光电存储器十进制阶次示意图。Figure 12 is a schematic diagram of the decimal order of the designed decimal photoelectric memory.

其中:1为衬底、2为光波导、3为电极材料、4为相变材料薄膜覆盖层。Among them: 1 is the substrate, 2 is the optical waveguide, 3 is the electrode material, and 4 is the phase change material film covering layer.

具体实施方式Detailed ways

为了更加清晰的解释本发明的目的,原理以及技术方案,下面结合附图和实例对本发明进行进一步的说明。应当理解,本实例只适用于对本发明进行进一步的详细说明,并不用于限定本发明,不能理解为对本发明保护范围的限制。In order to explain the purpose, principle and technical solution of the present invention more clearly, the present invention will be further described below in conjunction with the accompanying drawings and examples. It should be understood that this example is only suitable for further describing the present invention in detail and is not used to limit the present invention and cannot be understood as limiting the scope of protection of the present invention.

需要说明的是,本实例所提供的图示仅说明本发明的基本构象,组件数目、形状及尺寸可随意的改变,且组件布局形态也可能更复杂。It should be noted that the diagrams provided in this example only illustrate the basic configuration of the present invention. The number, shape and size of components can be changed at will, and the component layout may also be more complex.

本发明利用电信号将信息写入或擦除在相变材料薄膜中,利用相变材料薄膜在晶态和非晶态对波导中的光不同调控特性,实现信息的读取。The invention uses electrical signals to write or erase information in the phase change material film, and utilizes the different control characteristics of the phase change material film in the crystalline and amorphous states of light in the waveguide to realize the reading of information.

如图1所述,一种基于相变材料阵列波导光栅的非易失性十进制光电存储器结构示意图,包括衬底1、光波导2、电极材料3、相变材料薄膜覆盖层4。其中,光波导的厚度选择为220nm,宽度选择为500nm。相变材料薄膜宽500nm,长250nm。光栅周期1000nm。相变材料薄膜的厚度选择为10nm、20nm和30nm不同厚度。所述导电极材料选择金、铝、铜和钨等。As shown in Figure 1, a schematic structural diagram of a non-volatile decimal optoelectronic memory based on phase change material array waveguide grating, including substrate 1, optical waveguide 2, electrode material 3, and phase change material film covering layer 4. Among them, the thickness of the optical waveguide is selected as 220nm, and the width is selected as 500nm. The phase change material film is 500nm wide and 250nm long. The grating period is 1000nm. The thickness of the phase change material film is selected as different thicknesses of 10nm, 20nm and 30nm. The conductive electrode material may be gold, aluminum, copper, tungsten, etc.

实施例1Example 1

(1)利用电子束曝光和反应离子刻蚀制备所述的光波导结构;通过磁控溅射和溅射窗口的方法沉积相变材料薄膜阵列光栅,并沉积导电材料。(1) Use electron beam exposure and reactive ion etching to prepare the optical waveguide structure; deposit phase change material thin film array gratings through magnetron sputtering and sputtering windows, and deposit conductive materials.

(2)通过编程,分别对9个相变材料薄膜光场进行通电,光相变材料薄膜晶态和非晶态个数不同的时候,代表写入的数据不同。当全是晶态时,表示写入“0”。当1个非晶态,8个晶态时,表示写入“1”。当2个非晶态,7个晶态时,表示写入“2”。以此类推,当全是非晶态时,表示写入“9”。(2) Through programming, 9 phase change material film light fields are energized respectively. When the number of crystalline and amorphous states of the optical phase change material film is different, it means that the written data is different. When it is all crystalline, it means writing "0". When there is 1 amorphous state and 8 crystalline states, it means writing "1". When there are 2 amorphous states and 7 crystalline states, it means writing "2". By analogy, when it is all amorphous, it means writing "9".

(3)由于相变材料薄膜在晶态和非晶态时,对光场的调控特性不同,可以利于光的传输进行数据的读取。如图2所示,其中,1表示非晶态,0表示晶态。写入时,全是晶态,读取时光的透过率为0.095182,表示为“0”。如图3所示,当写入1个非晶态,8个晶态时,读取时光的透过率为0.15545,表示为“1”。以此类推,图4到图11分别为其他数据的读取结果。(3) Since the phase change material film has different control characteristics of the light field in the crystalline and amorphous states, it can facilitate the transmission of light and data reading. As shown in Figure 2, where 1 represents the amorphous state and 0 represents the crystalline state. When writing, it is all crystalline. When reading, the light transmittance is 0.095182, which is expressed as "0". As shown in Figure 3, when writing 1 amorphous state and 8 crystalline states, the transmittance of reading light is 0.15545, expressed as "1". By analogy, Figures 4 to 11 respectively show the reading results of other data.

(4)基于以上实现了十进制的写入和读取,如图12所示读取数据分别为0.095182,表示为“0”、0.15545,表示为“1”、0.25729表示为“2”、0.38368表示为“3”、0.47276表示为“4”、0.57160表示为“5”、0.65589表示为“6”、0.74844表示为“7”、0.80859表示为“8”、0.97451表示为“9”。(4) Based on the above, decimal writing and reading are implemented. As shown in Figure 12, the read data are 0.095182, represented as "0", 0.15545, represented as "1", 0.25729 represented as "2", and 0.38368 represented is "3", 0.47276 is represented as "4", 0.57160 is represented as "5", 0.65589 is represented as "6", 0.74844 is represented as "7", 0.80859 is represented as "8", and 0.97451 is represented as "9".

以上所述的具体描述,对本发明的目的、技术方案和有益效果进行了进一步的说明,以上所述只是本发明的具体实施案例,并不限定于本发明的保护范围。凡是本发明的精神和原则之内,所做的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above-mentioned specific description further explains the purpose, technical solution and beneficial effects of the present invention. The above-mentioned are only specific implementation examples of the present invention and do not limit the scope of protection of the present invention. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present invention shall be included in the protection scope of the present invention.

Claims (5)

1. The non-volatile decimal photoelectric memory based on the phase-change material array waveguide grating is characterized in that decimal data are stored by utilizing the phase-change material thin film array grating;
the specific structure comprises the following steps: the optical waveguide is positioned on the substrate, the phase change material film grating array is deposited on the upper surface of the waveguide, and data is read by utilizing light in the optical waveguide; electrode materials are introduced into two side surfaces of each phase change material film grating structure, and the phase change material films are electrified and heated to change the phase states of the phase change material films, so that data writing and erasing are realized;
the phase change material film grating arrays are arranged in parallel along the length direction of the optical waveguide and have 9 grating structures;
when all crystalline, it means that a "0" is written; written to are several amorphous representations, the amorphous states beginning at one end of the array and continuing; when 1 amorphous, 8 crystalline states, this indicates writing of "1"; when 2 amorphous states, 7 crystalline states, this indicates writing "2"; when 3 amorphous, 6 crystalline, represent write 3; when 4 amorphous, 5 crystalline, represent write 4; when 5 amorphous, 4 crystalline, represent write 5; when 6 amorphous, 3 crystalline, represent write 6; when 7 amorphous, 2 crystalline, represent write 7; when 8 amorphous, 1 crystalline, represent write 8; when all amorphous, it means writing "9";
(3) The phase change material film has different regulation and control characteristics on the light field when in a crystalline state and an amorphous state, so that the transmission of light is facilitated, and data is read; the crystalline state is all crystalline, and the transmittance of light during reading is 0.095182, which is denoted as "0"; when 1 amorphous state and 8 crystalline states are written, the transmittance of light at the time of reading is 0.15545, which is expressed as "1".
2. A phase change material arrayed waveguide grating-based nonvolatile decimal optoelectronic memory according to claim 1 wherein the width of each phase change material thin film grating structure is equal to the width of the optical waveguide and is 500nm, and the length of each phase change material thin film grating structure, namely the length along the length direction of the optical waveguide, is 250nm; the grating period is 1000nm.
3. A phase change material arrayed waveguide grating based non-volatile decimal optoelectronic memory in accordance with claim 1 wherein the thickness of the thin film of phase change material is selected to be 2 10nm, 4 20nm and 3 30nm in sequence from left to right.
4. A phase change material arrayed waveguide grating based non-volatile decimal optoelectronic memory in accordance with claim 1 wherein the optical waveguide is selected to have a thickness of 220nm and a width of 500nm.
5. A phase change material arrayed waveguide grating based non-volatile decimal optoelectronic memory in accordance with claim 1 wherein the electrode material is selected from the group consisting of gold, aluminum, copper and tungsten.
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