CN113710093A - Granular pesticide composition and method for spreading the same - Google Patents

Abstract

The present invention provides a granular pesticide composition characterized by containing 0.1 to 70 parts by mass of an agricultural chemical active ingredient, 0.3 to 15 parts by mass of an organic hollow body, and 0.01 to 9.99 parts by mass of an inorganic hollow body per 100 parts by mass, which has high hardness and is not easily pulverized, and thus does not cause drift when it is dispersed in the air by a power disperser.

Description

Granular pesticide composition and method for dispersing the same

technical field

The present invention relates to a granular agricultural chemical composition and a method for dispersing the agricultural chemical in which the granular agricultural chemical composition is applied to farmland using a power spreader mounted on an aircraft such as an unmanned aerial vehicle.

Background technique

Conventionally, pesticide compositions used in paddy fields and the like are generally granules, powders, emulsions, wettable powders, suspensions, and the like. In these pesticide compositions, granules and powders are usually dispersed directly without dilution in water in an amount of 1 to 4 kg relative to a 10a paddy field.

In recent years, labor saving for pesticide spraying has been proposed, and a granular pesticide composition with a large particle size and a granular pesticide composition with a high content of agrochemical active ingredients can reduce the spraying amount, and can be injected from the bank without entering the paddy field (Patent Document 1). , Non-patent literature 1). In addition, in recent years, as further labor saving, dispersal using aircraft such as unmanned helicopters and unmanned aerial vehicles has been studied.

However, when spreading (spraying) by means of an aircraft, a power spreader is required because it is necessary to fly the granular pesticide composition over a long distance. There is an impeller with blades in the power spreader. When the granular pesticide composition collides with the blades of the impeller, the granular pesticide composition is hit hard, resulting in the granular pesticide composition with low strength being pulverized, and the pulverized pesticide is in the air. Drift will cause the operator to come into contact with pesticides and cause phytotoxicity to crops in adjacent areas, causing so-called drift. In addition, when the granular agrochemical composition is a water-surface diffusible granular agrochemical composition, the disintegration of the granular agrochemical composition which has been broken and reduced in size is immediately completed when it falls on the water surface, so that the desired self-diffusing property may not be exhibited.

In view of such a situation, in the granular agricultural chemical composition to be dispersed in the air by a power sprayer, it is an important subject to increase the hardness of the granular agricultural chemical composition and to make the granular agricultural chemical composition less likely to be pulverized.

prior art literature

Patent Literature

Patent Document 1: Japanese Patent Laid-Open No. 2000-302602

Non-patent literature

Non-Patent Document 1: "The Science of New Pesticide", Asakura Shoten, p175, 2019

SUMMARY OF THE INVENTION

The problem to be solved by the invention

Therefore, an object of the present invention is to provide a granular agrochemical composition which does not cause drift during aerial spraying with a power sprayer by increasing the hardness of the granular pesticide composition so as to make it less likely to be pulverized.

means of solving problems

The inventors of the present invention have conducted intensive studies in order to solve the above-mentioned problems, and as a result, they have found that the above-mentioned problems can be solved by including an organic hollow body and an inorganic hollow body in a specific amount in a granular agrochemical composition containing an agrochemical active ingredient, thereby completing the present invention. invention.

That is, the present invention is a granular agrochemical composition characterized by containing 0.1 to 70 parts by mass of agrochemical active ingredients, 0.3 to 15 parts by mass of an organic hollow body, and 0.01 to 9.99 parts by mass of an inorganic hollow body per 100 parts by mass. body.

In addition, the present invention is a method of spreading an agricultural chemical, characterized in that the above-mentioned granular agricultural chemical composition is applied to a farmland using a power spreader.

Furthermore, the present invention is a method for producing a granular agricultural chemical composition, characterized in that 0.1 to 70 parts by mass of the agrochemical active ingredient, 0.3 to 15 parts by mass of the organic hollow body, and 0.01 to 9.99 parts by mass per 100 parts by mass The mixture of inorganic hollow bodies is kneaded, granulated, granulated, and then dried.

In addition, the present invention is a method for suppressing pulverization of a granular agrochemical composition, characterized in that 0.3 to 15 parts by mass of the agrochemical active ingredient is contained in 100 parts by mass of the granular agrochemical composition containing 0.1 to 70 parts by mass of the active ingredient. Organic hollow bodies and 0.01 to 9.99 parts by mass of inorganic hollow bodies.

Invention effect

The granular agricultural chemical composition of the present invention has high hardness and is not easily pulverized. Therefore, the granular agricultural chemical composition of the present invention is suitably applied to farmland using a power spreader mounted on an aircraft such as an unmanned aerial vehicle in addition to normal spreading.

Detailed ways

The granular pesticide composition of the present invention (hereinafter referred to as "the composition of the present invention") contains, per 100 parts by mass: 0.1 to 70 parts by mass of the pesticide active ingredient, 0.3 to 15 parts by mass of the organic hollow body, and 0.01 to 9.99 parts by mass of inorganic hollow bodies.

The pesticidal active ingredient used in the composition of the present invention is not particularly limited, for example, it can be mentioned:

隆(isouron)、异

氯草酮(isoxachlortole)、异

唑草酮(isoxaflutole)、异

酰草胺(isoxaben)、异丙隆(isoproturon)、三唑酰草胺(ipfencarbazone)、咪唑喹啉酸(imazaquin)、甲咪唑烟酸(imazapic)(包括与胺等的盐)、咪唑烟酸(imazapyr)(包括与异丙胺等的盐)、咪草酸(imazamethabenz-methyl)、甲氧咪草烟(imazamox)、咪唑乙烟酸(imazethapyr)、唑吡嘧磺隆(imazosulfuron)、茚嗪氟草胺(indaziflam)、茚草酮(indanofan)、甘草津(eglinazine-ethyl)、戊草丹(esprocarb)、胺苯磺隆(ethametsulfuron-methyl)、乙丁烯氟灵(ethalfluralin)、磺噻隆(ethidimuron)、乙氧磺隆(ethoxysulfuron)、氯氟草醚乙酯(ethoxyfen-ethyl)、乙氧呋草黄(ethofumesate)、乙氧苯草胺(etobenzanid)、内氧草索钠盐(endothal-disodium)、

草酮(oxadiazon)、丙炔

草酮(oxadiargyl)、

嗪草酮(oxaziclomefone)、环氧嘧磺隆(oxasulfuron)、乙氧氟草醚(oxyfluorfen)、氨磺乐灵(oryzalin)、嘧苯胺磺隆(orthosulfamuron)、坪草丹(orbencarb)、油酸(oleic acid)、唑草胺(cafenstrole)、唑酮草酯(carfentrazone-ethyl)、特胺灵(karbutilate)、双酰草胺(carbetamide)、喹禾灵(quizalofop-ethyl)、精喹禾灵(quizalofop-P-ethyl)、喹禾糠酯(quizalofop-P-tefuryl)、灭藻醌(quinoclamine)、二氯喹啉酸(quinclorac)、氯甲喹啉酸(quinmerac)、苄草隆(cumyluron)、氯酰草膦(clacyfos)、草甘膦(glyphosate)(包括与钠、钾、铵、胺、丙胺、异丙胺、二甲胺或三甲基锍(trimesium)等的盐)、草铵膦(glufosinate)(包括与胺或钠等的盐)、精草铵膦钠盐(glufosinate-P-sodium)、烯草酮(clethodim)、炔草酸(clodinafop-propargyl)、二氯吡啶酸(clopyralid)、异

草松(clomazone)、甲氧除草醚(chlomethoxyfen)、氯甲酰草胺(clomeprop)、氯酯磺草胺(cloransulam-methyl)、草灭畏(chloramben)、氯草敏(chloridazon)、氯嘧磺隆(chlorimuron-ethyl)、氯磺隆(chlorsulfuron)、氯酞酸甲酯(chlorthal-dimethyl)、氯硫酰草胺(chlorthiamid)、氯酞亚胺(chlorphthalim)、整形醇(chlorflurenol-methyl)、氯苯胺灵(chlorpropham)、氯溴隆(chlorbromuron)、枯草隆(chloroxuron)、绿麦隆(chlorotoluron)、Ketospiradox(包括与钠、钙或氨等的盐)、苯嘧磺草胺(saflufenacil)、假蒟亭碱(sarmentine)、氰草津(cyanazine)、氰胺(cyanamide)、敌草隆(diuron)、乙酰甲草胺(diethatyl-ethyl)、麦草畏(dicamba)(包括与胺、二乙胺、异丙胺、二甘醇胺、钠或锂等的盐)、环草敌(cycloate)、噻草酮(cycloxydim)、双氯磺草胺(diclosulam)、环丙嘧磺隆(cyclosulfamuron)、Cyclopyranil、Cyclopyrimorate、敌草腈(dichlobenil)、精禾草灵(diclofop-P-methyl)、禾草灵(diclofop-methyl)、2,4-滴丙酸(dichlorprop)、精2,4-滴丙酸(dichlorprop-P)、敌草快(diquat)、氟硫草定(dithiopyr)、环草隆(siduron)、氨氟灵(dinitramine)、吲哚酮草酯(cinidon-ethyl)、醚磺隆(cinosulfuron)、地乐酚(dinoseb)、特乐酚(dinoterb)、氰氟草酯(cyhalofop-butyl)、双苯酰草胺(diphenamid)、野燕枯(difenzoquat)、吡氟酰草胺(diflufenican)、氟吡草腙(diflufenzopyr)、西玛津(simazine)、二甲草胺(dimethachlor)、异戊净(dimethametryn)、二甲吩草胺(dimethenamid)、精二甲吩草胺(dimethenamid-P)、西草净(simetryn)、哌草丹(dimepiperate)、

唑隆(dimefuron)、环庚草醚(cinmethylin)、灭草灵(swep)、磺草酮(sulcotrione)、甲磺草胺(sulfentrazone)、草硫膦(sulfosate)、磺酰磺隆(sulfosulfuron)、甲嘧磺隆(sulfometuron-methyl)、烯禾定(sethoxydim)、特草定(terbacil)、杀草隆(daimuron)、Thaxtomin A、茅草枯(dalapon)、噻唑烟酸(thiazopyr)、Tiafenacil、噻酮磺隆(thiencarbazone)(包括钠盐、甲酯等)、仲草丹(tiocarbazil)、禾草丹(thiobencarb)、噻二唑草胺(thidiazimin)、噻吩磺隆(thifensulfuron-methyl)、甜菜安(desmedipham)、敌草净(desmetryne)、噻吩草胺(thenylchlor)、牧草胺(tebutam)、丁噻隆(tebuthiuron)、吡喃草酮(tepraloxydim)、特糠酯酮(tefuryltrione)、环磺酮(tembotrione)、特丁津(terbuthylazine)、特丁净(terbutryn)、特丁通(terbumeton)、苯唑草酮(topramezone)、三甲苯草酮(tralkoxydim)、三嗪氟草胺(triaziflam)、醚苯磺隆(triasulfuron)、氟酮磺草胺(triafamone)、野麦畏(tri-allate)、草达津(trietazine)、三氯吡氧乙酸(triclopyr)、三氯吡氧乙酸丁氧基乙酯(triclopyr-butotyl)、Trifludimoxazin、三氟甲磺隆(tritosulfuron)、氟胺磺隆(triflusulfuron-methyl)、氟乐灵(trifluralin)、三氟啶磺隆(trifloxysulfuron-sodium)、苯磺隆(tribenuron-methyl)、Tolpyralate、萘草胺(naptalam)(包括与钠等的盐)、萘丙胺(naproanilide)、敌草胺(napropamide)、敌草胺-M(napropamide-M)、烟嘧磺隆(nicosulfuron)、草不隆(neburon)、哒草伏(norflurazon)、灭草敌(vernolate)、百草枯(paraquat)、氯氟吡啶酯(halauxifen-benzyl)、氟氯吡啶酯(halauxifen-methyl)、氟吡禾灵(haloxyfop)、高效氟吡甲禾灵(haloxyfop-P)、氟吡乙禾灵(haloxyfop-etotyl)、氟硝磺酰胺(halosafen)、氯吡嘧磺隆(halosulfuron-methyl)、氨氯吡啶酸(picloram)、氟吡酰草胺(picolinafen)、氟吡草酮(bicyclopyrone)、双草醚(bispyribac-sodium)、唑啉草酯(pinoxaden)、甲羧除草醚(bifenox)、哌草磷(piperophos)、双唑草腈(pyraclonil)、磺酰草吡唑(pyrasulfotole)、苄草唑(pyrazoxyfen)、吡嘧磺隆(pyrazosulfuron-ethyl)、吡唑特(pyrazolynate)、双丙氨膦(bilanafos)、吡草醚(pyraflufen-ethyl)、氯苯哒醇(pyridafol)、嘧草硫醚(pyrithiobac-sodium)、哒草特(pyridate)、环酯草醚(pyriftalid)、稗草丹(pyributicarb)、嘧啶肟草醚(pyribenzoxim)、嘧氟磺草胺(pyrimisulfan)、嘧草醚(pyriminobac-methyl)、砜吡草唑(pyroxasulfone)、甲氧磺草胺(pyroxsulam)、棉胺宁(phenisopham)、非草隆(fenuron)、Fenoxasulfone、

唑禾草灵(fenoxaprop)(包括甲酯、乙酯、异丙酯)、精

唑禾草灵(fenoxaprop-P)(包括甲酯、乙酯、异丙酯)、Fenquinotrione、噻唑禾草灵(fenthiaprop-ethyl)、四唑酰草胺(fentrazamide)、甜菜宁(phenmedipham)、丁草胺(butachlor)、氟丙嘧草酯(butafenacil)、抑草磷(butamifos)、丁草敌(butylate)、丁烯草胺(butenachlor)、仲丁灵(butralin)、丁苯草酮(butroxydim)、啶嘧磺隆(flazasulfuron)、麦草氟(flamprop)(包括甲酯、乙酯、异丙酯)、氟燕灵(flamprop-M)(包括甲酯、乙酯、异丙酯)、氟嘧磺隆(primisulfuron-methyl)、吡氟禾草灵(fluazifop-butyl)、精吡氟禾草灵(fluazifop-P-butyl)、异丙吡草酯(fluazolate)、氟草隆(fluometuron)、乙羧氟草醚(fluoroglycofen-ethyl)、氟唑磺隆(flucarbazone-sodium)、氯乙氟灵(fluchloralin)、氟吡磺隆(flucetosulfuron)、嗪草酸甲酯(fluthiacet-methyl)、氟啶嘧磺隆(flupyrsulfuron-methyl-sodium)、氟噻草胺(flufenacet)、氟哒嗪草酯(flufenpyr-ethyl)、四氟丙酸(flupropanate)、氟胺草唑(flupoxame)、丙炔氟草胺(flumioxazin)、氟烯草酸(flumiclorac-pentyl)、唑嘧磺草胺(flumetsulam)、氟啶草酮(fluridone)、呋草酮(flurtamone)、氯氟吡氧乙酸(fluroxypyr)、氟咯草酮(flurochloridone)、丙草胺(pretilachlor)、丙苯磺隆钠(procarbazone-sodium)、氨氟乐灵(prodiamine)、氟磺隆(prosulfuron)、苄草丹(prosulfocarb)、喔草酸(propaquizafop)、毒草胺(propachlor)、扑灭津(propazine)、敌稗(propanil)、炔苯酰草胺(propyzamide)、异丙草胺(propisochlor)、丙嗪嘧磺隆(propyrisulfuron)、苯胺灵(propham)、氟唑草胺(profluazol)、丙苯磺隆(propoxycarbazone-sodium)、环苯草酮(profoxydim)、除草定(bromacil)、溴草敏(brompyrazon)、扑草净(prometryn)、扑灭通(prometon)、溴苯腈(bromoxynil)(包括与丁酸、辛酸或庚酸等的酯)、溴酚肟(bromofenoxim)、溴丁酰草胺(bromobutide)、双氟磺草胺(florasulam)、Florpyrauxifen、环嗪酮(hexazinone)、烯草胺(pethoxamid)、草除灵(benazolin)、五氟磺草胺(penoxsulam)、胺苯吡菌酮(heptamaloxyloglucan)、氟丁酰草胺(beflubutamid)、克草敌(pebulate)、壬酸(pelargonic acid)、苯唑磺隆(bencarbazone)、二甲戊灵(pendimethalin)、双苯嘧草酮(benzfendizone)、地散磷(bensulide)、苄嘧磺隆(bensulfuron-methyl)、双环磺草酮(benzobicyclon)、吡草酮(benzofenap)、灭草松(bentazone)、甲氯酰草胺(pentanochlor)、环戊

草酮(pentoxazone)、乙丁氟灵(benfluralin)、呋草黄(benfuresate)、蔓草磷(fosamine)、氟磺胺草醚(fomesafen)、甲酰氨基嘧磺隆(foramsulfuron)、2甲4氯丙酸(mecoprop)(包括与钠、钾、异丙胺、三乙醇胺、二甲胺等的盐)、精2甲4氯丙酸(mecoprop-P-potassium)、甲基二磺隆(mesosulfuron-methyl)、甲基磺草酮(mesotrione)、吡草胺(metazachlor)、嗪吡嘧磺隆(metazosulfuron)、甲基苯噻隆(methabenzthiazuron)、苯嗪草酮(metamitron)、

唑酰草胺(metamifop)、DSMA(甲胂酸二钠)、Methiozolin、甲基杀草隆(methyldymuron)、甲氧隆(metoxuron)、磺草唑胺(metosulam)、甲磺隆(metsulfuron-methyl)、溴谷隆(metobromuron)、吡喃隆(metobenzuron)、异丙甲草胺(metolachlor)、嗪草酮(metribuzin)、苯噻酰草胺(mefenacet)、单嘧磺隆(monosulfuron)(包括甲酯、乙酯、异丙酯)、绿谷隆(monolinuron)、禾草敌(molinate)、碘甲磺隆(iodosulfuron)、甲基碘磺隆钠盐(iodosulfulon-methyl-sodium)、Iofensulfuron、Iofensulfuron-sodium、乳氟禾草灵(lactofen)、lancotrione、利谷隆(linuron)、砜嘧磺隆(rimsulfuron)、环草定(lenacil)、TCA(2,2,2-三氯乙酸)(包括与钠、钙或氨等的盐)、草芽畏(2,3,6-TBA)、2,4,5-三氯苯氧乙酸(2,4,5-T)、2,4-二氯苯氧乙酸(2,4-D)(包括与胺、二乙胺、三乙醇胺、异丙胺、钠或锂等的盐)、ACN(2-氨基-3-氯-1,4-萘醌)、2甲4氯(MCPA)、2甲4氯丁酸(MCPB)(包括钠盐、乙酯等)、2,4-滴丁酸(2,4-DB)、二硝酚(DNOC)(包括与胺或钠等的盐)、AE-F-150944(代号)、HW-02(代号)、IR-6396(代号)、2甲4氯硫代乙酯(MCPA-thioethyl)、SYP-298(代号)、NC-653(代号)、SYP-300(代号)、茵草敌(EPTC)、精异丙甲草胺(S-metolachlor)等除草活性成分；ioxynil (ioxynil), aclonifen (aclonifen), acrolein (acrolein), azafenidin (azafenidin), acifluorfen (including salts with sodium etc.), tetrazolium azimsulfuron, asulam, acetochlor, atrazine, anilofos, amicarbazone, amidosulfuron, chlorfenuron Amitrole, aminocyclopyrachlor, aminopyralid, amiprofos-methyl, ametryn, alachlor, alloxydim), iso

isouron, different

Isoxachlortole, isoxachlortole

Isoxaflutole, isoxaflutole

Isoxaben, isoproturon, ipfencarbazone, imazaquin, imazapic (including salts with amines, etc.), imazaquin (imazapyr) (including salts with isopropylamine, etc.), imazamethabenz-methyl, imazamox, imazethapyr, imazosulfuron, indazine ( indaziflam), indanofan, eglinazine-ethyl, esprocarb, ethametsulfuron-methyl, ethalfluralin, ethidimuron , ethoxysulfuron, ethoxyfen-ethyl, ethofumesate, etobenzanid, endothal-disodium ,

oxadiazon, propyne

oxadiargyl,

oxaziclomefone, oxasulfuron, oxyfluorfen, oryzalin, orthosulfamuron, orbencarb, oleic acid (oleic acid), cafenstrole, carfentrazone-ethyl, karbutilate, carbetamide, quizalofop-ethyl, quizalofop-ethyl (quizalofop-P-ethyl), quizalofop-P-tefuryl, quinoclamine, quinclorac, quinmerac, cumyluron , clacyfos, glyphosate (including salts with sodium, potassium, ammonium, amine, propylamine, isopropylamine, dimethylamine or trimesium, etc.), glufosinate (glufosinate) (including salts with amine or sodium), glufosinate-P-sodium, clethodim, clodinafop-propargyl, clopyralid ,different

Clomazone, chlomethoxyfen, clomeprop, cloransulam-methyl, chloramben, chloridazon, chloropyrimidine Chlorimuron-ethyl, chlorsulfuron, chlorthal-dimethyl, chlorthiamid, chlorphthalim, chlorflurenol-methyl , chlorpropham, chlorbromuron, chloroxuron, chlorotoluron, Ketospiradox (including salts with sodium, calcium or ammonia, etc.), saflufenacil , sarmentine (sarmentine), cyanazine (cyanazine), cyanamide (cyanamide), diuron (diuron), acetochlor (diethatyl-ethyl), dicamba (dicamba) (including with amine, diethyl amine, isopropylamine, diethylene glycol amine, salts of sodium or lithium, etc.), cycloate, cycloxydim, diclosulam, cyclosulfamuron, Cyclopyranil, Cyclopyrimorate, dichlobenil, diclofop-P-methyl, diclofop-methyl, dichlorprop, dichlorprop Acid (dichlorprop-P), diquat (diquat), dithiopyr, siduron (siduron), dinitramine, cinidon-ethyl, ethersulfuron (cinosulfuron), dinoseb, dinoterb, cyhalofop-butyl, diphenamid, difenzoquat, difenzoquat ( diflufenican, diflufenzopyr, simazine, dimethachlor, dimethametryn, dimethenamid, dimethachlor enamid-P), simetryn, dimepiperate,

Dimefuron, cinmethylin, swep, sulcotrione, sulfentrazone, sulfosate, sulfosulfuron , sulfometuron-methyl, sethoxydim, terbacil, daimuron, Thaxtomin A, dalapon, thiazopyr, Tiafenacil, Thiencarbazone (including sodium salt, methyl ester, etc.), tiocarbazil, thiobencarb, thidiazimin, thifensulfuron-methyl, sugar beet Desmedipham, desmetryne, thenylchlor, tebutam, tebuthiuron, tepraloxydim, tefuryltrione, cyclosulfonone ( tembotrione), terbuthylazine, terbutryn, terbumeton, topramezone, tralkoxydim, triaziflam, ether Triasulfuron, triafamone, tri-allate, trietazine, triclopyr, butoxyethyl triclopyr (triclopyr-butotyl), Trifludimoxazin, tritosulfuron, triflusulfuron-methyl, trifluralin, trifloxysulfuron-sodium, tribenuron -methyl), Tolpyralate, naptalam (including salts with sodium, etc.), naproanilide, napropamide, napropamide-M (napropamide-M), nicosulfuron ( nicosulfuron), neburon, norflurazon, vernolate, Paraquat, halauxifen-benzyl, halauxifen-methyl, haloxyfop, haloxyfop-P, haloxyfop-P haloxyfop-etotyl, halosafen, halosulfuron-methyl, picloram, picolinafen, bicyclopyrone , bispyribac-sodium, pinoxaden, bifenox, piperophos, pyraclonil, pyrasulfotole, pyrazoxyfen, pyrazosulfuron-ethyl, pyrazolynate, bilanafos, pyraflufen-ethyl, pyridafol, pyrimidine pyrithiobac-sodium, pyridate, pyriftalid, pyributicarb, pyribenzoxim, pyrimisulfan, pyrimox Ether (pyriminobac-methyl), pyroxasulfone, pyroxsulam, phenisopham, fenuron, Fenoxasulfone,

fenoxaprop (including methyl ester, ethyl ester, isopropyl ester), essence

Fenoxaprop-P (including methyl, ethyl, isopropyl), Fenquinotrione, fenthiaprop-ethyl, fentrazamide, phenmedipham, Butachlor, butafenacil, butamifos, butylate, butenachlor, butralin, butroxydim ), flazasulfuron, flamprop (including methyl ester, ethyl ester, isopropyl ester), flamprop-M (including methyl ester, ethyl ester, isopropyl ester), fluorine Primisulfuron-methyl, fluazifop-butyl, fluazifop-P-butyl, fluazolate, fluometuron, Fluoroglycofen-ethyl, flucarbazone-sodium, fluchloralin, flucetosulfuron, fluthiacet-methyl, fluoropyrimidine Flupyrsulfuron-methyl-sodium, flufenacet, flufenpyr-ethyl, flupropanate, flupoxame, flufenazone (flumioxazin), flumiclorac-pentyl, flumetsulam, fluridone, flurtamone, fluroxypyr, flurotrione (flurochloridone), pretilachlor, procarbazone-sodium, prodiamine, prosulfuron, prosulfocarb, propaquizafop, propachlor, propazine, propanil, propyzamide, propisochlor, propyrisulfuron, aniline (propham), profluazol, propoxycarbazone-sodium, profoxydim, bromacil, brompyrazon, prometryn, Prometon, bromoxynil (including esters with butyric, caprylic, or heptanoic acid, etc.), bromofenoxim, bromobutide, florasulam ), Florpyrauxifen, hexazinone, pethoxamid, benazolin, penoxsulam, heptamaloxyloglucan, beflubutamid ), pebulate, pelargonic acid, bencarbazone, pendimethalin, benzfendizone, bensulide, benzyl pyrimidine Bensulfuron-methyl, benzobicyclon, benzofenap, bentazone, pentanochlor, cyclopenta

pentoxazone, benfluralin, benfuresate, fosamine, fomesafen, foramsulfuron, 2 methyl 4 chloropropane Acid (mecoprop) (including salts with sodium, potassium, isopropylamine, triethanolamine, dimethylamine, etc.), mecoprop-P-potassium, mesosulfuron-methyl , Mesotrione, Metazachlor, Metazosulfuron, Methabenzthiazuron, Metamitron,

Metamifop, DSMA (disodium formate), Methiozolin, methyldymuron, metoxuron, metosulam, metsulfuron-methyl ), metobromuron, metobenzuron, metolachlor, metribuzin, mefenacet, monosulfuron (including methyl ester, ethyl ester, isopropyl ester), monolinuron, molinate, iodosulfuron, iodosulfulon-methyl-sodium, Iofensulfuron, Iofensulfuron-sodium, lactofen, lancotrione, linuron, rimsulfuron, lenacil, TCA (2,2,2-trichloroacetic acid) ( Including salts with sodium, calcium or ammonia, etc.), dicamba (2,3,6-TBA), 2,4,5-trichlorophenoxyacetic acid (2,4,5-T), 2,4- Dichlorophenoxyacetic acid (2,4-D) (including salts with amine, diethylamine, triethanolamine, isopropylamine, sodium or lithium, etc.), ACN (2-amino-3-chloro-1,4-naphthalene) quinone), 2-methyl-4-chlorobutyric acid (MCPA), 2-methyl-4-chlorobutyric acid (MCPB) (including sodium salt, ethyl ester, etc.), 2,4-D butyric acid (2,4-DB), dinitrophenol (DNOC) ) (including salts with amine or sodium, etc.), AE-F-150944 (code), HW-02 (code), IR-6396 (code), 2 methyl 4 chlorothioethyl ester (MCPA-thioethyl), SYP -298 (code), NC-653 (code), SYP-300 (code), EPTC, S-metolachlor and other herbicidal active ingredients;

磷(azamethiphos)、Acynonapyr、益棉磷(azinphos-ethyl)、保棉磷(azinphos-methyl)、灭螨醌(acequinocyl)、啶虫脒(acetamiprid)、乙酰虫腈(acetoprole)、乙酰甲胺磷(acephate)、三唑锡(azocyclotin)、阿维菌素(abamectin)、Afidopyropen、阿福拉纳(afoxolaner)、磺胺螨酯(amidoflumet)、双甲脒(amitraz)、棉铃威(alanycarb)、涕灭威(aldicarb)、涕灭砜威(aldoxycarb)、烯丙菊酯(allethrin)[包括d-顺式-反式-型、d-反式-型]、氯唑磷(isazophos)、Isamidofos、水胺硫磷(isocarbophos)、

唑磷(isoxathion)、甲基异柳磷(isofenphos-methyl)、异丙威(isoprocarb)、伊维菌素(ivermectin)、新烟磷(imicyafos)、吡虫啉(imidacloprid)、炔咪菊酯(imiprothrin)、茚虫威(indoxacarb)、S-氰戊菊酯(esfenvalerate)、乙硫苯威(ethiofencarb)、乙硫磷(ethion)、乙虫腈(ethiprole)、二溴乙烷(ethylene dibromide)、乙螨唑(etoxazole)、醚菊酯(etofenprox)、灭线磷(ethoprophos)、乙嘧硫磷(etrimfos)、甲氨基阿维菌素苯甲酸盐(emamectin benzoate)、硫丹(endosulfan)、右旋烯炔菊酯(empenthrin)、Oxazosulfyl、杀线威(oxamyl)、亚砜磷(oxydemeton-methyl)、异砜磷(oxydeprofos)、氧乐果(omethoate)、硫线磷(cadusafos)、七氟菊酯(Kappa-tefluthrin)、联苯菊酯(Kappa-bifenthrin)、噻吩菊酯(Kadethrin)、辛酸甘油酯(glyceryl caprylate)、水黄皮素(karanjin)、杀螟丹(cartap)、甲萘威(carbaryl)、丁硫克百威(carbosulfan)、克百威(carbofuran)、林丹(gamma-BHC)、灭杀威(xylylcarb)、喹硫磷(quinalphos)、烯虫炔酯(kinoprene)、灭螨猛(chinomethionat)、蝇毒磷(coumaphos)、冰晶石(cryolite)、甘油柠檬酸脂肪酸酯(glyceryl monooleate citrate)、噻虫胺(clothianidin)、四螨嗪(clofentezine)、环虫酰肼(chromafenozide)、氯虫苯甲酰胺(chlorantraniliprole)、氯氧磷(chlorethoxyfos)、氯丹(chlordane)、氯化苦(chloropicrin)、毒死蜱(chlorpyrifos)、甲基毒死蜱(chlorpyrifos-methyl)、虫螨腈(chlorfenapyr)、毒虫畏(chlorfenvinphos)、氟啶脲(chlorfluazuron)、氯甲硫磷(chlormephos)、右旋反式氯丙炔菊酯(chloroprallethrin)、杀螟腈(cyanophos)、丁醚脲(diafenthiuron)、除线特(diamidafos)、氰虫酰胺(cyantraniliprole)、遍地克(dienochlor)、腈吡螨酯(cyenopyrafen)、蔬果磷(dioxabenzofos)、苯虫醚(diofenolan)、环溴虫酰胺(cyclaniliprole)、百治磷(dicrotophos)、除线磷(dichlofenthion)、乙氰菊酯(cycloprothrin)、敌敌畏(dichlorvos)、Dicloromezotiaz、1,3-滴·滴混剂(1,3-dichloropropene)、三氯杀螨醇(dicofol)、环虫腈(dicyclanil)、乙拌磷(disulfoton)、呋虫胺(dinotefuran)、消螨通(dinobuton)、氯氟氰虫酰胺(cyhalodiamide)、氯氟氰菊酯(cyhalothrin)[包括γ-型，λ-型]、苯醚氰菊酯(cyphenothrin)[包括(1R)-反式-型]、氟氯氰菊酯(cyfluthrin)[包括β-型]、除虫脲(diflubenzuron)、丁氟螨酯(cyflumetofen)、氟螨嗪(diflovidazin)、三环锡(cyhexatin)、氯氰菊酯(cypermethrin)[包括α-型、β-型、θ-型、ζ-型]、甲基毒虫畏(dimethylvinphos)、四氟甲醚菊酯(dimefluthrin)、乐果(dimethoate)、氟硅菊酯(silafluofen)、灭蝇胺(cyromazine)、乙基多杀菌素(spinetoram)、多杀霉素(spinosad)、螺螨酯(spirodiclofen)、螺虫乙酯(spirotetramat)、螺甲螨酯(spiromesifen)、磺苯醚隆钠(sulcofuron-sodium)、氟虫胺(sulfluramid)、氟啶虫胺腈(sulfoxaflor)、治螟磷(sulfotep)、二嗪磷(diazinon)、噻虫啉(thiacloprid)、噻虫嗪(thiamethoxam)、Tioxazafen、硫双威(thiodicarb)、杀虫环(thiocyclam)、杀虫双(thiosultap)、虫线磷(thionazin)、久效威(thiofanox)、甲基乙拌磷(thiometon)、杀虫畏(tetrachlorvinphos)、三氯杀螨砜(tetradifon)、氟氰虫酰胺(tetraniliprole)、四氟醚菊酯(tetramethylfluthrin)、胺菊酯(tetramethrin)、丁基嘧啶磷(tebupirimfos)、虫酰肼(tebufenozide)、吡螨胺(tebufenpyrad)、七氟菊酯(tefluthrin)、氟苯脲(teflubenzuron)、甲基内吸磷(demeton-S-methyl)、双硫磷(temephos)、溴氰菊酯(deltamethrin)、特丁硫磷(terbufos)、四溴菊酯(tralomethrin)、四氟苯菊酯(transfluthrin)、唑蚜威(triazamate)、三唑磷(triazophos)、敌百虫(trichlorfon)、杀铃脲(triflumuron)、三氟苯嘧啶(triflumezopyrim)、混杀威(trimethacarb)、唑虫酰胺(tolfenpyrad)、二溴磷(naled)、烯啶虫胺(nitenpyram)、氟酰脲(novaluron)、多氟脲(noviflumuron)、蜡蚧轮枝菌(Verticillium lecanii)、烯虫乙酯(hydroprene)、穿刺芽孢杆菌(Pasteuriapenetrans)、蚜灭磷(vamidothion)、对硫磷(parathion)、甲基对硫磷(parathion-methyl)、苄螨醚(halfenprox)、氯虫酰肼(halofenozide)、生物烯丙菊酯(bioallethrin)、2-环戊烯基生物烯丙菊酯(bioallethrinS-cyclopentenyl)、生物苄呋菊酯(bioresmethrin)、双二氟虫脲(bistrifluron)、氟蚁腙(hydramethylnon)、联苯肼酯(bifenazate)、联苯菊酯(bifenthrin)、Pyflubumide、增效醚(piperonyl butoxide)、吡蚜酮(pymetrozine)、吡唑硫磷(pyraclofos)、吡嗪氟虫腈(pyrafluprole)、哒嗪硫磷(pyridaphenthion)、哒螨灵(pyridaben)、啶虫醚(pyridalyl)、Pyrifluquinazon、Pyriprole、吡丙醚(pyriproxyfen)、抗蚜威(pirimicarb)、嘧螨醚(pyrimidifen)、嘧螨胺(pyriminostrobin)、甲基嘧啶磷(pirimiphos-methyl)、除虫菊素(pyrethrine)、伐灭磷(famphur)、氟虫腈(fipronil)、喹螨醚(fenazaquin)、苯线磷(fenamiphos)、杀螟硫磷(fenitrothion)、苯氧威(fenoxycarb)、苯硫威(fenothiocarb)、苯醚菊酯(phenothrin)[包括(1R)-反式-型]、仲丁威(fenobucarb)、倍硫磷(fenthion)、稻丰散(phenthoate)、氰戊菊酯(fenvalerate)、唑螨酯(fenpyroximate)、苯丁锡(fenbutatin oxide)、甲氰菊酯(fenpropathrin)、地虫硫磷(fonofos)、硫酰氟(sulfurylfluoride)、丁酮威(butocarboxim)、丁酮砜威(butoxycarboxim)、噻嗪酮(buprofezin)、呋线威(furathiocarb)、右旋炔丙菊酯(prallethrin)、嘧螨酯(fluacrypyrim)、三氟咪啶酰胺(fluazaindolizine)、啶蜱脲(fluazuron)、联氟砜(fluensulfone)、氟乙酸钠(sodiumfluoroacetate)、氟

唑酰胺(fluxametamide)、氟环脲(flucycloxuron)、氟氰戊菊酯(flucythrinate)、磺菌胺(flusulfamide)、氟胺氰菊酯(fluvalinate)[包括tau-型]、氟吡呋喃酮(flupyradifurone)、吡氟硫磷(flupyrazofos)、Flupyrimin、丁虫腈(flufiprole)、嘧虫胺(flufenerim)、氟菌螨酯(flufenoxystrobin)、氟虫脲(flufenoxuron)、Fluhexafon、氟虫酰胺(flubendiamide)、氟氯苯菊酯(flumethrin)、氟雷拉纳(fluralaner)、丙硫磷(prothiofos)、丙苯烃菊酯(protrifenbute)、氟啶虫酰胺(flonicamid)、丙虫磷(propaphos)、炔螨特(propargite)、丙溴磷(profenofos)、Broflanilide、溴氟菊酯(brofluthrinate)、丙氟菊酯(profluthrin)、胺丙畏(propetamphos)、残杀威(propoxur)、Flometoquin、溴螨酯(bromopropylate)、噻螨酮(hexythiazox)、氟铃脲(hexaflumuron)、细脚拟青霉(Paecilomyces tenuipes)、玫烟色拟青霉(Paecilomyces fumosoroceus)、Heptafluthrin、庚烯磷(heptenophos)、氯菊酯(permethrin)、Benclothiaz、Benzpyrimoxan、杀虫磺(bensultap)、苯螨特(benzoximate)、

虫威(bendiocarb)、丙硫克百威(benfuracarb)、纤细白僵菌(Beauveria tenella)、蚕白僵菌(Beauveria bassiana)、布氏白僵菌(Beauveria brongniartii)、辛硫磷(phoxim)、伏杀硫磷(phosalone)、噻唑磷(fosthiazate)、丁硫环磷(fosthietan)、磷胺(phosphamidon)、亚胺硫磷(phosmet)、浏阳霉素(polynactins)、伐虫脒(formetanate)、甲拌磷(phorate)、马拉硫磷(malathion)、弥拜菌素(milbemectin)、灭蚜磷(mecarbam)、甲亚砜磷(mesulfenfos)、烯虫酯(methoprene)、灭多威(methomyl)、氰氟虫腙(metaflumizone)、甲胺磷(methamidophos)、威百亩(metham)、甲硫威(methiocarb)、杀扑磷(methidathion)、敌线酯(methyl isothiocyanate)、溴甲烷(methyl bromide)、甲氧滴滴涕(methoxychlor)、甲氧虫酰肼(methoxyfenozide)、甲醚菊酯(methothrin)、甲氧苄氟菊酯(metofluthrin)、ε-甲氧苄氟菊酯(epsilon-metofluthrin)、速灭威(metolcarb)、速灭磷(mevinphos)、氯氟醚菊酯(meperfluthrin)、Monacrosporium phymatophagum、久效磷(monocrotophos)、Momfluorothrin、Epsilon-momfluorothrin(一种甲氧苄氟菊酯单体)、litlure-A、litlure-B、磷化铝(aluminium phosphide)、磷化锌(zinc phosphide)、磷化氢(phosphine)、虱螨脲(lufenuron)、Rescalure、苄呋菊酯(resmethrin)、雷皮菌素(lepimectin)、鱼藤酮(rotenone)、苯丁锡(fenbutatin oxide)、氰化钙(calciumcyanide)、硫酸烟碱(nicotine sulfate)、(Z)-11-十四碳烯＝乙酸酯、(Z)-11-十六碳烯醛、(Z)-11-十六碳烯＝乙酸酯、(Z)-9,12-十四碳二烯＝乙酸酯、(Z)-9-十四碳烯-1-醇、(Z,E)-9,11-十四碳二烯＝乙酸酯、(Z,E)-9,12-十四碳二烯＝乙酸酯、日本甲虫芽孢杆菌(Bacillus popilliae)、枯草芽孢杆菌(Bacillus subtillis)、球形芽孢杆菌(Bacillussphaericus)、苏云金芽孢杆菌鲇泽亚种菌株(Bacillus thuringiensis subsp.Aizawai)、苏云金芽孢杆菌以色列亚种菌株(Bacillus thuringiensis subsp.Israelensis)、苏云金芽孢杆菌塔克亚种菌株(Bacillus thuringiensis subsp.Kurstaki)、苏云金芽孢杆菌拟步行甲亚种菌株(Bacillus thuringiensis subsp.Tenebrionis)、Bt蛋白质(Cry1Ab、Cry1Ac、Cry1Fa、Cry2Ab、mCry3A、Cry3Ab、Cry3Bb、Cry34/35Ab1)、CL900167(代号)、二氯异丙醚(DCIP)、滴滴涕(DDT)、二甲基-2,2,2-三氯-1-羟乙基膦酸酯(DEP)、二硝酚(DNOC)、O,O-二乙基-O-[4-(二甲基氨磺酰基)苯基]-硫代磷酸酯(DSP)、苯硫膦(EPN)、核型多角体病毒包埋体、NA-85(代号)、NA-89(代号)、NC-515(代号)、RU15525(代号)、XMC、Z-13-二十碳烯-10-酮、ZXI8901(代号)、(RS)-2-氯-4-氟-5-[5-(三氟甲硫基)戊氧基]苯基、2,2,2-三氟乙基亚砜(化学名，CAS登录号：1472050-04-6)等杀虫活性成分；Acrinathrin, azadirachtin, methylpyridine

Phosphorus (azamethiphos), Acynonapyr, azinphos-ethyl, azinphos-methyl, acequinocyl, acetamiprid, acetoprole, acephate (acephate), azocyclotin, abamectin, Afidopyropen, afoxolaner, amidoflumet, amitraz, alanycarb, rhizoma aldicarb, aldoxycarb, allethrin [including d-cis-trans-form, d-trans-form], isazophos, Isamidofos, Isocarbophos,

Isoxathion, isofenphos-methyl, isoprocarb, ivermectin, imicyafos, imidacloprid, imiprothrin ), indoxacarb, S-fenvalerate, ethiofencarb, ethion, ethiprole, ethylene dibromide, etoxazole, etofenprox, ethopropos, etrimfos, emamectin benzoate, endosulfan, Dexenthrin, Oxazosulfyl, oxamyl, oxydemeton-methyl, oxydeprofos, omethoate, cadusafos, seven Kappa-tefluthrin, Kappa-bifenthrin, Kadethrin, Glyceryl caprylate, karanjin, cartap, Amethyst Carbaryl, Carbosulfan, Carbofuran, Lindane, Gamma-BHC, Xylylcarb, Quinalphos, Kinoprene , chinomethionat, coumaphos, cryolite, glyceryl monooleate citrate, clothianidin, clofentezine, cyclophosphine Hydrazine (chromafenozide), chlorantraniliprole, chlorethoxyfos (chlorethoxyfos), chlordane (chlordane), chloropicrin (chloropicrin), chlorpyrifos (chlorpyrifos), chlorpyrifos-methyl (chlorpyrifos-methyl), mites Nitrile (chlorfenapyr), chlorfenvinphos (chlorfenvinphos), chlorfenapyr luazuron, chlormephos, chloroprallethrin, cyanophos, diafenthiuron, diamidafos, cyantraniliprole ), dienochlor, cyenopyrafen, dioxabenzofos, diofenolan, cyclaniliprole, dicrotophos, dichlofenthion , cycloprothrin, dichlorvos, Dicloromezotiaz, 1,3-dichloropropene, dicofol, dicyclanil, disulfoton ), dinotefuran, dinobuton, cyhalodiamide, cyhalothrin [including γ-type, λ-type], cyhalothrin ( cyphenothrin) [including (1R)-trans-form], cyfluthrin [including beta-form], diflubenzuron, cyflumetofen, diflovidazin, tricyclic Tin (cyhexatin), cypermethrin (including α-type, β-type, θ-type, ζ-type), dimethylvinphos, dimefluthrin, dimethoate ), silafluofen, cyromazine, spinetoram, spinosad, spirodiclofen, spirotetramat, spirotetramat Spiromesifen, sulcofuron-sodium, sulfluramid, sulfoxaflor, sulfotep, diazinon, thiamethoxam thiacloprid, thiamethoxam, Tioxazafen, thiodicarb, thiocyclam, thio sultap), thionazin, thiofanox, thiometon, tetrachlorvinphos, tetradifon, tetraniliprole, tetramethylfluthrin, tetramethrin, tebupirimfos, tebufenozide, tebufenpyrad, tefluthrin, fenflunomuron ( teflubenzuron, demeton-S-methyl, temephos, deltamethrin, terbufos, tralomethrin, tetrafluorobenzene transfluthrin, triazamate, triazophos, trichlorfon, triflumuron, triflumezopyrim, trimethacarb, azole Tolfenpyrad, naled, nitenpyram, novaluron, novoflumuron, Verticillium lecanii, methoprene ( hydroprene), Bacillus piercing (Pasteuria penetrans), aphid phosphatidic (vamidothion), parathion (parathion), methyl parathion-methyl (parathion-methyl), benzyl fenprox (halfenprox), halofenozide (halofenozide), Bioallethrin, 2-cyclopentenyl bioallethrin (bioallethrinS-cyclopentenyl), bioresmethrin, bistrifluron, hydramethylnon , bifenazate, bifenthrin, Pyflubumide, piperonyl butoxide, pymetrozine, pyraclofos, pyrafluprole , pyridaphenthion, pyridaben ), pyridalyl, Pyrifluquinazon, Pyriprole, pyriproxyfen, pirimicarb, pyrimidifen, pyriminostrobin, pirimiphos-methyl , pyrethrine, famphur, fipronil, fenazaquin, fenamiphos, fenitrothion, fenoxycarb, Fenothiocarb, phenothrin [including (1R)-trans-form], fenobucarb, fenthion, phenthoate, fenvalerate Fenvalerate, fenpyroximate, fenbutatin oxide, fenpropathrin, fonofos, sulfurylfluoride, butocarboxim, Butoxycarboxim, buprofezin, furathiocarb, prallethrin, fluacrypyrim, fluazaindolizine, pyridoxine Urea (fluazuron), bifluorosulfone (fluensulfone), sodium fluoroacetate (sodiumfluoroacetate), fluorine

Fluxametamide, flucycloxuron, flucythrinate, flusulfamide, fluvalinate [including tau-form], flupyradifurone ), flupyrazofos, Flupyrimin, flufiprole, flufenerim, flufenoxystrobin, flufenoxuron, Fluhexafon, flubendiamide, Flumethrin, fluralaner, prothiofos, protrifenbute, flonicamid, propaphos, propargyl mites Propargite, profenofos, Broflanilide, brofluthrinate, profluthrin, propetamphos, propoxur, Flometoquin, bromopropylate ), hexythiazox, hexaflumuron, Paecilomyces tenuipes, Paecilomyces fumosoroceus, Heptafluthrin, heptenophos, permethrin ( permethrin), Benclothiaz, Benzpyrimoxan, bensultap, benzoximate,

Bendiocarb, Benfuracarb, Beauveria tenella, Beauveria bassiana, Beauveria brongniartii, phoxim, Phosalone, fosthiazate, fosthietan, phosphamidon, phosmet, polynactins, formetanate, Phorate, malathion, milbemectin, mecarbam, mesulfenfos, methoprene, methomyl ), metaflumizone, methamidophos, metham, methiocarb, methidathion, methyl isothiocyanate, methyl bromide ), methoxychlor, methoxyfenozide, methothrin, metofluthrin, epsilon-metofluthrin, Metolcarb, mevinphos, meperfluthrin, Monacrosporium phymatophagum, monocrotophos, Momfluorothrin, Epsilon-momfluorothrin (a monomer of methotrexate) , litlure-A, litlure-B, aluminum phosphide, zinc phosphide, phosphine, lufenuron, Rescalure, resmethrin, thunder Lepimectin, rotenone, fenbutatin oxide, calcium cyanide, nicotine sulfate, (Z)-11-tetradecene=acetate, (Z)-11-hexadecenal, (Z)-11-hexadecene Carbene=acetate, (Z)-9,12-tetradecadiene=acetate, (Z)-9-tetradecen-1-ol, (Z,E)-9,11- Tetradecadiene=acetate, (Z,E)-9,12-tetradecadiene=acetate, Bacillus popilliae, Bacillus subtillis, Bacillus sphaericus (Bacillussphaericus), Bacillus thuringiensis subsp.Aizawai, Bacillus thuringiensis subsp.Israelensis, Bacillus thuringiensis subsp.Kurstaki , Bacillus thuringiensis subsp.Tenebrionis, Bt proteins (Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34/35Ab1), CL900167 (code), dichloroisopropyl ether (DCIP), DDT (DDT), Dimethyl-2,2,2-trichloro-1-hydroxyethylphosphonate (DEP), Dinitrophenol (DNOC), O,O-diethyl-O -[4-(Dimethylsulfamoyl)phenyl]-phosphorothioate (DSP), phenylphosphine (EPN), nuclear polyhedrosis virus embedding, NA-85 (code), NA-89 (code), NC-515 (code), RU15525 (code), XMC, Z-13-eicosen-10-one, ZXI8901 (code), (RS)-2-chloro-4-fluoro-5- Insecticidal active ingredients such as [5-(trifluoromethylthio)pentyloxy]phenyl, 2,2,2-trifluoroethyl sulfoxide (chemical name, CAS accession number: 1472050-04-6);

霜灵(oxadixyl)、Oxazinylazole、氟噻唑吡乙酮(oxathiapiprolin)、氧化萎锈灵(oxycarboxin)、喹啉铜(oxine-copper)、土霉素(oxytetracycline)、

咪唑(oxpoconazole-fumarate)、喹菌酮(oxolinic acid)、辛酸铜(copper dioctanoate)、辛噻酮(octhilinone)、呋酰胺(ofurace)、肟醚菌胺(orysastrobin)、邻苯基苯酚(o-phenylphenol)、春雷霉素(kasugamycin)、敌菌丹(captafol)、环丙酰菌胺(carpropamid)、多菌灵(carbendazim)、萎锈灵(carboxin)、香芹酮(carvone)、苯氧喹啉(quinoxyfen)、Quinofumelin、灭螨猛(chinomethionat)、克菌丹(captan)、Quinconazole、五氯硝基苯(quintozene)、双辛胍胺(guazatine)、硫杂灵(cufraneb)、丁香菌酯(coumoxystrobin)、醚菌酯(kresoxim-methyl)、Clozylacon、乙菌利(chlozolinate)、百菌清(chlorothalonil)、地茂散(chloroneb)、氰霜唑(cyazofamid)、乙霉威(diethofencarb)、双氯氰菌胺(diclocymet)、苯氟磺胺(dichlofluanid)、Dichlobenthiazox、哒菌酮(diclomezine)、氯硝胺(dicloran)、双氯酚(dichlorophen)、二氰蒽醌(dithianon)、烯唑醇(diniconazole)、R-烯唑醇(diniconazole-M)、代森锌(zineb)、二硝巴豆酸酯(dinocap)、Dipymetitrone、二苯胺(diphenylamine)、苯醚甲环唑(difenoconazole)、环氟苄酰胺(cyflufenamid)、氟嘧菌胺(diflumetorim)、环菌唑(cyproconazole)、嘧菌环胺(cyprodinil)、硅氟唑(simeconazole)、二甲嘧酚(dimethirimol)、二甲基二硫(dimethyl disulfide)、烯酰吗啉(dimethomorph)、霜脲氰(cymoxanil)、醚菌胺(dimoxystrobin)、福美锌(ziram)、硅噻菌胺(silthiofam)、链霉素(streptomycin)、螺环菌胺(spiroxamine)、氟唑环菌胺(sedaxane)、苯酰菌胺(zoxamide)、棉隆(dazomet)、噻酰菌胺(tiadinil)、噻菌灵(thiabendazole)、福美双(thiram)、硫菌灵(thiophanate)、甲基硫菌灵(thiophanate-methyl)、噻氟菌胺(thifluzamide)、四氯硝基苯(tecnazene)、叶枯酞(tecloftalam)、四氟醚唑(tetraconazole)、咪菌威(debacarb)、戊唑醇(tebuconazole)、Tebufloquin、特比萘芬(terbinafine)、多果定(dodine)、十二环吗啉(dodemorph)、三唑醇(triadimenol)、三唑酮(triadimefon)、咪唑嗪(triazoxide)、水杨菌胺(trichlamide)、氯啶菌酯(triclopyricarb)、三环唑(tricyclazole)、灭菌唑(triticonazole)、十三吗啉(tridemorph)、氟菌唑(triflumizole)、肟菌酯(trifloxystrobin)、嗪氨灵(triforine)、甲苯氟磺胺(tolylfluanid)、甲基立枯磷(tolclofos-methyl)、甲磺菌胺(tolnifanide)、Tolprocarb、代森钠(nabam)、纳他霉素(natamycin)、萘替芬(naftifine)、三氯甲基吡啶(nitrapyrin)、酞菌酯(nitrothal-isopropyl)、氟苯嘧啶醇(nuarimol)、壬基苯酚磺酸铜(copper nonyl phenol sulphonate)、枯草芽孢杆菌(Bacillus subtilis)(菌株：QST713)、井冈霉素(validamycin)、缬菌胺(valifenalate)、Picarbutrazox、联苯吡菌胺(bixafen)、啶氧菌酯(picoxystrobin)、氟唑菌酰羟胺(pydiflumetofen)、联苯三唑醇(bitertanol)、乐杀螨(binapacryl)、联苯(biphenyl)、病花灵(piperalin)、

霉灵(hymexazol)、唑菌酯(pyraoxystrobin)、吡唑醚菌酯(pyraclostrobin)、Pyraziflumid、吡菌磷(pyrazophos)、唑胺菌酯(pyrametostrobin)、Pyriofenone、啶菌

唑(pyrisoxazole)、啶斑肟(pyrifenox)、稗草丹(pyributicarb)、吡菌苯威(pyribencarb)、嘧霉胺(pyrimethanil)、咯喹酮(pyroquilon)、乙烯菌核利(vinclozolin)、福美铁(ferbam)、

唑菌酮(famoxadone)、叶枯净(phenazine oxide)、咪唑菌酮(fenamidone)、烯肟菌胺(fenaminstrobin)、氯苯嘧啶醇(fenarimol)、稻瘟酰胺(fenoxanil)、嘧菌腙(ferimzone)、拌种咯(fenpiclonil)、Fenpicoxamid、胺苯吡菌酮(fenpyrazamine)、腈苯唑(fenbuconazole)、甲呋酰胺(fenfuram)、苯锈啶(fenpropidin)、丁苯吗啉(fenpropimorph)、环酰菌胺(fenhexamid)、灭菌丹(folpet)、四氯苯酞(phthalide)、乙嘧酚磺酸酯(bupirimate)、麦穗宁(fuberidazole)、灭瘟素(blasticidin-S)、呋吡菌胺(furametpyr)、呋霜灵(furalaxyl)、呋喃甲酸(furancarboxylic acid)、氟啶胺(fluazinam)、Fluindapyr、氟嘧菌酯(fluoxastrobin)、氟吡菌胺(fluopicolide)、氟吡菌酰胺(fluopyram)、氟氯菌核利(fluoroimide)、氟唑菌酰胺(fluxapyroxad)、氟喹唑(fluquinconazole)、呋菌唑(furconazole)、呋醚唑(furconazole-cis)、咯菌腈(fludioxonil)、氟硅唑(flusilazole)、磺菌胺(flusulfamide)、氟噻菌净(flutianil)、氟酰胺(flutolanil)、粉唑醇(flutriafol)、氟菌螨酯(flufenoxystrobin)、氟酰菌胺(flumetover)、氟吗啉(flumorph)、丙氧喹啉(proquinazid)、咪鲜胺(prochloraz)、腐霉利(procymidone)、硫菌威(prothiocarb)、丙硫菌唑(prothioconazole)、溴硝醇(bronopol)、霜霉威盐酸盐(propamocarb-hydrochloride)、丙环唑(propiconazole)、丙森锌(propineb)、烯丙苯噻唑(probenazole)、糠菌唑(bromuconazole)、Flometoquin、己唑醇(hexaconazole)、苯霜灵(benalaxyl)、精苯霜灵(benalaxyl-M)、麦锈灵(benodanil)、苯菌灵(benomyl)、稻瘟酯(pefurazoate)、戊菌唑(penconazole)、戊菌隆(pencycuron)、苯并烯氟菌唑(benzovindiflupyr)、苯噻硫氰(benthiazole)、苯噻菌胺酯(benthiavalicarb-isopropyl)、吡噻菌胺(penthiopyrad)、氟唑菌苯胺(penflufen)、烟酰胺(boscalid)、三乙膦酸(fosetyl)(铝、钙、钠)、多抗霉素(polyoxin)、代森福美锌(polycarbamate)、波尔多液(bordeaux mixture)、代森锰锌(mancozeb)、双炔酰菌胺(mandipropamid)、Mandestrobin、代森锰(maneb)、腈菌唑(myclobutanil)、机油(mineral oils)、米多霉素(mildiomycin)、磺菌威(methasulfocarb)、威百亩(metam)、甲霜灵(metalaxyl)、精甲霜灵(metalaxyl-M)、代森联(metiram)、叶菌唑(metconazole)、苯氧菌胺(metominostrobin)、苯菌酮(metrafenone)、嘧菌胺(mepanipyrim)、氯氟醚菌唑(mefentrifluconazole)、二硝巴豆酸酯(meptyldinocap)、灭锈胺(mepronil)、碘代丙炔基丁基甲胺酸酯(iodocarb)、昆布多糖(laminarin)、亚磷酸及盐(phosphorous acid and salts)、王铜(copper oxychloride)、银(silver)、氧化亚铜(cuprous oxide)、氢氧化铜(copper hydroxide)、碳酸氢钾(potassium bicarbonate)、碳酸氢钠(sodium bicarbonate)、硫(sulfur)、硫酸羟基喹啉(oxyquinoline sulfate)、硫酸铜(copper sulfate)、4-(叔丁基)苯甲酸(3,4-二氯异噻唑-5-基)甲酯(化学名，CAS登录号：1231214-23-5)、BAF-045(代号)、BAG-010(代号)、UK-2A(代号)、十二烷基苯磺酸双乙二胺铜络盐[II](DBEDC)、MIF-1002(代号)、三苯基乙酸锡(TPTA)、三苯基氯化锡(TPTC)、三苯基氢氧化锡(TPTH)、非病原性胡萝卜欧文氏杆菌(Erwinia carotovora)等杀菌活性成分；azaconazole, acibenzolar-S-methyl, azoxystrobin, anilazine, amisulbrom, ametoctradin, azoxystrobin aldimorph, isotianil, isopyrazam, isofetamid, isoprothiolane, ipconazole, ipfentrifluconazole, isobacterium Urea (iprodione), iprovalicarb, iprobenfos, imazalil, iminoctadine-trialbesilate, iminoctadine -triacetate), imibenconazole, edifenphos, etaconazole, ethaboxam, ethirimol, ethoxyquin, terbenazole (etridiazole), enestroburin, Enoxastrobin, epoxiconazole, organic oils,

Oxadixyl, Oxazinylazole, oxathiapiprolin, oxycarboxin, oxine-copper, oxytetracycline,

Imidazole (oxpoconazole-fumarate), oxolinic acid (oxolinic acid), copper octoate (copper dioctanoate), octhilinone (octhilinone), furamide (ofurace), orysastrobin (orysastrobin), o-phenylphenol (o- phenylphenol), kasugamycin, captafol, carpropamid, carbendazim, carboxin, carvone, phenoxyquin quinoxyfen, Quinofumelin, chinomethionat, captan, Quinconazole, quintozene, guazatine, cufraneb, syringylstrobin (coumoxystrobin), kresoxim-methyl, Clozylacon, chlozolinate, chlorothalonil, chloroneb, cyazofamid, diethofencarb, Diclocymet, dichlofluanid, Dichlobenthiazox, diclomezine, dicloran, dichlorophen, dithianon, diconazole (diniconazole), R-diconazole (diniconazole-M), zineb, dinitrocrotonate (dinocap), Dipymetitrone, diphenylamine, difenoconazole, cyclofluoride Benzylamide (cyflufenamid), diflumetorim (diflumetorim), cyproconazole (cyproconazole), cyprodinil (cyprodinil), simeconazole (simeconazole), dimethirimol (dimethirimol), dimethyl disulfide ( dimethyl disulfide), dimethomorph, cymoxanil, dimoxystrobin, ziram, silthiofam, streptomycin, spirulina spiroxamine, fluoxazone Sedaxane, zoxamide, dazomet, tiadinil, thiabendazole, thiram, thiophanate, methyl sulfide Thiophanate-methyl, thifluzamide, tecnazene, tecloftalam, tetraconazole, debacarb, tebuconazole (tebuconazole), Tebufloquin, terbinafine, dodine, dodemorph, triadimenol, triadimefon, triazoxide, trichlamide, triclopyricarb, tricyclazole, triticonazole, tridemorph, triflumizole, trifloxystrobin ), Triforine, Tolylfluanid, Tolclofos-methyl, Tolnifanide, Tolprocarb, Nabam, Natamycin ), naftifine, nitrapyrin, nitrothal-isopropyl, nuarimol, copper nonyl phenol sulphonate, Bacillus subtilis Bacillus subtilis (strain: QST713), validamycin, valifenalate, Picarbutrazox, bixafen, picoxystrobin, fluconazole ( pydiflumetofen), bitertanol, binapacryl, biphenyl, piperalin,

Hymexazol, pyraoxystrobin, pyraclostrobin, Pyraziflumid, pyrazophos, pyrametostrobin, Pyriofenone, pyridoxine

pyrisoxazole, pyrifenox, pyributicarb, pyribencarb, pyrimethanil, pyroquilon, vinclozolin, fome iron (ferbam),

Famoxadone, phenazine oxide, fenamidone, fenaminstrobin, fenarimol, fenoxanil, ferimzone ), fenpiclonil, Fenpicoxamid, fenpyrazamine, fenbuconazole, fenfuram, fenpropidin, fenpropimorph, ring Fenhexamid, folpet, phthalide, bupirimate, fuberidazole, blasticidin-S, furopyr Furametpyr, furalaxyl, furancarboxylic acid, fluazinam, Fluindapyr, fluoxastrobin, fluopicolide, fluopyram ( fluopyram), fluoroimide, fluxapyroxad, fluquinconazole, furconazole, furconazole-cis, fludioxonil, Flusilazole, flusulfamide, flutianil, flutolanil, flutriafol, flufenoxystrobin, flumetover , Flumorph, Proquinazid, Prochloraz, Procymidone, Prothiocarb, Prothioconazole, Bronopol ), propamocarb-hydrochloride, propiconazole, propineb, probenazole, bromuconazole, flometoquin, hexaconazole ), benalaxyl, benalaxyl nalaxyl-M), benodanil, benomyl, pefurazoate, penconazole, pencycuron, benzovindiflupyr, Benthiazole, benthiavalicarb-isopropyl, penthiopyrad, penflufen, boscalid, fosetyl (aluminum) , calcium, sodium), polyoxin, polycarbamate, bordeaux mixture, mancozeb, mandipropamid, Mandestrobin, Manganese (maneb), myclobutanil (myclobutanil), oil (mineral oils), midiomycin (mildiomycin), methasulfocarb (methasulfocarb), metam (metam), metalaxyl (metalaxyl), fine nail cream Metalaxyl-M, Metiram, Metconazole, Metominostrobin, Metrafenone, Mepanipyrim, Mefentrifluconazole ), meptyldinocap, mepronil, iodocarb, laminarin, phosphorous acid and salts, king copper (copper oxychloride), silver (silver), cuprous oxide (cuprous oxide), copper hydroxide (copper hydroxide), potassium bicarbonate (potassium bicarbonate), sodium bicarbonate (sodium bicarbonate), sulfur (sulfur), hydroxyquine sulfate Oxyquinoline sulfate, copper sulfate, (3,4-dichloroisothiazol-5-yl) methyl 4-(tert-butyl)benzoate (chemical name, CAS accession number: 1231214-23- 5), BAF-045 (code), BAG-010 (code), UK-2A (code), dodecylbenzenesulfonic acid bisethylenediamine copper complex salt [II] (DBEDC), MIF-10 02 (code name), triphenyltin acetate (TPTA), triphenyltin chloride (TPTC), triphenyltin hydroxide (TPTH), non-pathogenic Erwinia carotovora and other bactericidal active ingredients;

(mepiquat chloride)、正癸醇(n-decanol)、多效唑(paclobutrazol)、调环酸钙(prohexadione-calcium)、茉莉酮(prohydrojasmon)、杀雄啉(sintofen)、噻苯隆(thidiazuron)、三十烷醇(triacontanol)、抗倒酯(trinexapac-ethyl)、烯效唑(uniconazole)、精烯效唑(uniconazole-P)、4-氧代-4-(2-苯基乙基)氨基丁酸(化学名，CAS登录号：1083-55-2)、过氧化钙等植物生长调节活性成分。1-methylcyclopropene (1-methylcyclopropene), 1-naphthylacetamide (1-naphthylacetamide), 2,6-diisopropylnaphthalene (2,6-diisopropyl naphthalene), 4-chlorophenoxyacetic acid (4 -CPA), benzylaminopurine, cymidol, aviglycine, carvone, chlormequat, cloprop, citric acid (cloxyfonac), cloxyfonac-potassium, cyclanilide, cytokinins, daminozide, dikegulac, dimethipin, Ethephon, epocholeone, ethychlozate, flumetralin, flurenol, flurprimidol, forchlorfenuron ), gibberellins, inabenfide, indole acetic acid, indole butyric acid, maleic hydrazide, mefluidide ), methylphenidate

(mepiquat chloride), n-decanol, paclobutrazol, prohexadione-calcium, prohydrojasmon, sintofen, thidiazuron, three Triacontanol, trinexapac-ethyl, uniconazole, uniconazole-P, 4-oxo-4-(2-phenylethyl)aminobutane Acid (chemical name, CAS accession number: 1083-55-2), calcium peroxide and other plant growth regulating active ingredients.

嗪草酮(oxaziclomefone)、唑草胺(cafenstrole)、氯甲酰草胺(clomeprop)、Dichlobenthiazox、呋虫胺(dinotefuran)、西草净(simetryn)、杀草隆(daimuron)、特糠酯酮(tefuryltrione)、氟酮磺草胺(triafamone)、双唑草腈(pyraclonil)、吡嘧磺隆(pyrazosulfuron-ethyl)、环酯草醚(pyriftalid)、嘧氟磺草胺(pyrimisulfan)、嘧草醚(pyriminobac-methyl)、咯喹酮(pyroquilon)、Fenoxasulfone、Fenquinotrione、四唑酰草胺(fentrazamide)、丙嗪嘧磺隆(propyrisulfuron)、溴丁酰草胺(bromobutide)、苄嘧磺隆(bensulfuron-methyl)、双环磺草酮(benzobicyclon)、吡草酮(benzofenap)、环戊

草酮(pentoxazone)、甲基磺草酮(mesotrione)、嗪吡嘧磺隆(metazosulfuron)、苯氧菌胺(metominostrobin)、以及，苯噻酰草胺(mefenacet)。These pesticide active ingredients are preferably used alone or in combination of two or more. In addition, among these pesticide active ingredients, preferred: imazosulfuron, ethiprole,

oxaziclomefone, cafenstrole, clomeprop, Dichlobenthiazox, dinotefuran, simetryn, daimuron, furfuryl ketone (tefuryltrione), triafamone, pyraclonil, pyrazosulfuron-ethyl, pyriftalid, pyrimisulfan, pyrimox Pyriminobac-methyl, pyroquilon, Fenoxasulfone, Fenquinotrione, fentrazamide, propyrisulfuron, bromobutide, bensulfuron ( bensulfuron-methyl), benzobicyclon, benzofenap, cyclopentazone

pentoxazone, mesotrione, metazosulfuron, metminostrobin, and mefenacet.

The said agrochemical active ingredient is 0.1-70 mass parts per 100 mass parts of the composition of this invention, Preferably it is 2.0-60 mass parts.

The organic hollow body used in the composition of the present invention is not particularly limited as long as it is an organic substance having voids, and examples thereof include phenol microspheres made of phenol resin, ecospheres made of epoxy resin, and polyurethane foam made of polyurethane. , Microspheres, plastic balls, etc. composed of polyacrylonitrile. These organic hollow bodies may be used alone or in combination of two or more. In addition, among these organic hollow bodies, plastic spheres are preferable.

The said organic hollow body is 0.3-15 mass parts with respect to 100 mass parts of the composition of this invention, Preferably it is 1-5 mass parts.

The inorganic hollow body used in the composition of the present invention is not particularly limited as long as it is an inorganic material having voids. Silicates are hollow aluminosilicates calcined, glass balls made of foamed sodium silicate or borax, fly ash balls, pumice, ceramic hollow bodies, and the like. These inorganic hollow bodies may be used alone or in combination of two or more. Among these inorganic hollow bodies, glass spheres and/or hollow aluminosilicates are preferred.

As the above-mentioned inorganic hollow bodies, for example, shirasu balls are sold under the trade names of トワナライト (Fungwa Nao Co., Ltd.), マールライト (Marunaka Shirai Earth Co., Ltd.), and タイセツバルーン (Beiei Shiroite Industry Co., Ltd.), and the hollow aluminosilicates are sold under the trade names of Microsil ( Tolsa Corporation), Hedolite (Showa Chemical Industry Co., Ltd.) and other trade names, glass balls are sold under the trade names of グラスバブルス (3M Corporation), Q-CEL (ポッターズ・バロティーニ Corporation), Sphericel (ポッターズ・バロティーニ Corporation), etc. For sale, fly ash balls are sold under trade names such as イースフィアーズ (Pacific Cement Company) and the like, and ceramic hollow bodies are sold under trade names such as Ceramic Multi Cellular (ボッターズ・バロティーニ Co., Ltd.), so they can be used.

The said inorganic hollow body is 0.01-9.99 mass parts with respect to 100 mass parts of compositions of this invention, Preferably it is 3-7 mass parts.

The composition of the present invention can suppress the pulverization of the granular pesticide composition only by the above-mentioned essential components, and may further contain a surfactant, a binder, a spreading agent, an organic solvent, a water-soluble carrier, a carrier as long as the effect of the present invention is not impaired. Wait.

盐等阳离子性表面活性剂；烷基芳基磺酸盐、二烷基磺酸盐、二烷基琥珀酸盐、芳基磺酸盐及其缩合物、烷基硫酸酯盐、烷基磷酸酯盐、烷基芳基硫酸酯盐、烷基芳基磷酸酯盐、聚羧酸盐、聚氧化烯芳基醚硫酸盐、聚氧化烯芳基醚磷酸盐等阴离子性表面活性剂；烷基甜菜碱、烷基氧化胺、烷基咪唑啉甜菜碱、氨基酸、卵磷脂等两性表面活性剂、其它有机硅系表面活性剂、氟系表面活性剂等。这些表面活性剂可单独使用1种或适当并用2种以上。使用上述表面活性剂时的含量相对于本发明组合物的每100质量份，通常为1～15质量份，优选为3～10质量份。As said surfactant, polyalkylene glycol higher fatty acid ester, polyoxyalkylene aryl phenyl ether, sorbitan monoalkyl ester, acetylene alcohol, acetylene glycol, and these epoxy resins are mentioned, for example. Nonionic surfactants such as alkane adducts; tetraalkylammonium salts, alkylamines, alkylpyrimidines

Cationic surfactants such as salts; alkyl aryl sulfonates, dialkyl sulfonates, dialkyl succinates, aryl sulfonates and their condensates, alkyl sulfates, alkyl phosphates Anionic surfactants such as salts, alkyl aryl sulfates, alkyl aryl phosphates, polycarboxylates, polyoxyalkylene aryl ether sulfates, polyoxyalkylene aryl ether phosphates; alkyl beets Amphoteric surfactants such as alkalis, alkyl amine oxides, alkyl imidazoline betaines, amino acids, lecithin, other silicone-based surfactants, fluorine-based surfactants, and the like. These surfactants may be used alone or in combination of two or more as appropriate. The content in the case of using the above-mentioned surfactant is usually 1 to 15 parts by mass, preferably 3 to 10 parts by mass per 100 parts by mass of the composition of the present invention.

As said binder, carboxymethylcellulose sodium salt, dextrin, water-soluble starch, xanthan gum, guar gum, sucrose, polyvinylpyrrolidone, polyvinyl alcohol, polyacrylate sodium salt, average Polyoxyethylene with a molecular weight of 60-5 million, etc. These binders may be used alone or in combination of two or more as appropriate. The content in the case of using the above-mentioned binder is usually 0.5 to 10 parts by mass, preferably 1 to 8 parts by mass per 100 parts by mass of the composition of the present invention.

As the above-mentioned extender, in addition to the above-mentioned surfactant, for example, cellulose powder, dextrin, modified starch, polyaminocarboxylic acid chelate compound, cross-linked polyvinylpyrrolidone, maleic acid and styrene can be mentioned. such as copolymers, (meth)acrylic copolymers, half esters of polymers composed of polyols and dicarboxylic anhydrides, water-soluble salts of polystyrene sulfonic acid, and the like. These extenders may be used alone or in combination of two or more as appropriate. The content in the case of using the above-mentioned expanding agent is usually 0.5 to 10 parts by mass, preferably 1 to 8 parts by mass, per 100 parts by mass of the composition of the present invention.

烷、乙二醇单乙醚、二丙基醚、四氢呋喃等醚类；正链烷烃、环烷烃、异链烷烃、煤油、矿物油等脂族烃类；苯、甲苯、二甲苯、溶剂石脑油、烷基苯、烷基萘等芳族烃类；二氯甲烷、氯仿、四氯化碳等卤代烃类；乙酸乙酯、邻苯二甲酸二异丙酯、邻苯二甲酸二丁酯、邻苯二甲酸二辛酯、己二酸二甲酯等酯类；γ-丁内酯等内酯类；二甲基甲酰胺、二乙基甲酰胺、二甲基乙酰胺、N-烷基吡咯烷酮等酰胺类；乙腈等腈类；二甲亚砜等硫化合物类；大豆油、菜籽油、棉籽油、蓖麻油等植物油等。这些有机溶剂可单独使用1种或适当并用2种以上。使用上述有机溶剂时的含量相对于本发明组合物的每100质量份，通常为1～10质量份，优选为2～6质量份。Examples of the organic solvent include monohydric alcohols such as methanol, ethanol, propanol, isopropanol, and butanol; ethylene glycol, diethylene glycol, propylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol, Alcohols such as polyols such as glycerin; polyol compounds such as propylene glycol ether; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, cyclohexanone;

alkane, ethylene glycol monoethyl ether, dipropyl ether, tetrahydrofuran and other ethers; n-paraffin, naphthenic, isoparaffin, kerosene, mineral oil and other aliphatic hydrocarbons; benzene, toluene, xylene, solvent naphtha , Aromatic hydrocarbons such as alkylbenzene, alkylnaphthalene; halogenated hydrocarbons such as dichloromethane, chloroform, carbon tetrachloride; ethyl acetate, diisopropyl phthalate, dibutyl phthalate , dioctyl phthalate, dimethyl adipate and other esters; γ-butyrolactone and other lactones; dimethylformamide, diethylformamide, dimethylacetamide, N-alkane amides such as pyrrolidone; nitriles such as acetonitrile; sulfur compounds such as dimethyl sulfoxide; vegetable oils such as soybean oil, rapeseed oil, cottonseed oil, castor oil, etc. These organic solvents may be used alone or in combination of two or more as appropriate. The content in the case of using the above-mentioned organic solvent is usually 1 to 10 parts by mass, preferably 2 to 6 parts by mass, per 100 parts by mass of the composition of the present invention.

Examples of the above-mentioned water-soluble carrier include ammonium sulfate, ammonium bicarbonate, ammonium nitrate, ammonium chloride, potassium chloride, sodium sulfate, magnesium sulfate, sodium citrate, sodium carbonate, sodium bicarbonate, sodium acetate, lemon Sodium, potassium hydrogen tartrate and other organic or inorganic acid salts, citric acid, succinic acid and other organic acids, sucrose, lactose and other sugars, urea, etc. These water-soluble carriers may be used alone or in combination of two or more as appropriate. The content in the case of using the above-mentioned water-soluble carrier is usually 10 to 99 parts by mass, preferably 20 to 80 parts by mass, per 100 parts by mass of the composition of the present invention.

As the above-mentioned carrier, in addition to the above-mentioned water-soluble carrier, for example, quartz, clay, silica sand, kaolinite, pyrophyllite, sericite, talc, bentonite, acid clay, attapulgite, zeolite, silicon Minerals such as algae; inorganic salts such as calcium carbonate and barium carbonate; organic solid carriers such as synthetic silicic acid, synthetic silicate, starch, cellulose, plant powder; plastics such as polyethylene, polypropylene, and polyvinylidene chloride Carrier; alumina, fumed silica (white carbon black), etc. These carriers may be used alone or in combination of two or more as appropriate. The content in the case of using the above-mentioned carrier is usually 10 to 99 parts by mass, preferably 20 to 80 parts by mass per 100 parts by mass of the composition of the present invention.

The composition of the present invention can be produced by kneading, granulating, and granulating the above-mentioned components in accordance with a conventional method, followed by drying. The kneading can be performed using a known kneader such as a belt type, a V type, a conical spiral type, and a high-speed flow type. The granulation can be performed using a known granulator such as rolling granulation, extrusion granulation, compression granulation, and stirring granulation. Next, this granulated product may be granulated by a known granulator such as a rolling granulator, and then dried using a known dryer such as a fluidized bed dryer, a vibration flow dryer, and an air flow dryer. In addition, in order to make the composition of the present invention have the properties described later, the conditions for granulation and granulation can be appropriately set.

The thus obtained composition of the present invention has high hardness and is not easily pulverized. Here, the hardness means 10 to 100N, preferably 30 to 60N, as a value of compressive strength measured by a digital load meter as in Examples to be described later. In addition, "pulverization is not easy" means that the pulverization rate of the formulation measured as in the examples described later is 20% or less, preferably 10% or less.

In addition, the composition of the present invention preferably has the property of floating (floating) on the water surface and the property of disintegrating on the water surface within 30 minutes. Whether or not it has the property of floating on the water surface can be confirmed by putting 50 grains of the composition of the present invention into a 1L beaker containing 500 mL of normal temperature water and measuring the number of grains floating on the water surface, and whether it has the water surface within 30 minutes. The disintegration property can be confirmed by measuring the time until the disintegration after the composition of the present invention is floated on the water surface. The compositions of the present invention having such properties are also referred to as surface-dispersable granular pesticide compositions.

Furthermore, the composition of the present invention preferably has a particle size distribution in which particles with a particle diameter of 3 mm or more are 80% or more. Granulation and sizing can be suitably performed to provide the compositions of the present invention with this particle size and particle size distribution. In addition, the particle size and particle size distribution are values measured by sieving the composition with a sieve of a predetermined mesh.

In addition, the composition of the present invention preferably has a mass per grain of 0.03 to 0.3 g, an apparent specific gravity of 0.3 to 1, an aspect ratio of 1 to 3, and an outer shape composed of a curved surface. Granulation and sizing can be suitably performed to give the composition of the present invention the mass, apparent specific gravity, aspect ratio. In addition, granulation and granulation can be appropriately performed so that the composition of the present invention has an outer shape composed of a curved surface, and as a specific shape, for example, spherical shape and the like can be mentioned.

The composition of the present invention can be applied to agricultural land (farmland) according to a conventional method, but because of the above-mentioned properties, it is particularly preferably applied to agricultural land such as paddy fields in a water storage state using a power spreader. When applied to farmland, the amount of the composition of the present invention is 50 to 500 g, preferably 200 to 400 g, relative to 10a of farmland.

The power spreader used for the above-mentioned application is not particularly limited, and examples thereof include a knapsack type power spreader, a rice planting synchronized spreader, an impeller-type granule spreader, and the like. The powered spreader is preferably mounted on an aircraft and spreads from the air. The aircraft is not particularly limited, for example, fixed-wing aircraft such as small light aircraft commonly called Cessna aircraft, rotary-wing aircraft such as manned helicopters and unmanned helicopters, tilt-rotor aircraft having both characteristics, and unmanned aircraft. Agricultural multi-rotor aircraft (so-called drones) driven by electric motors and batteries developed from human helicopters. Among these aircrafts, small unmanned helicopters and unmanned aerial vehicles exclusively used for pesticide dispersal are preferred, and unmanned aerial vehicles are particularly preferred.

The drone is smaller than a known unmanned helicopter equipped with an internal combustion engine, has small turns, and can perform precise maneuvers. Due to this feature, it is suitable for dispersing pesticides in small and medium-sized fields, mountainous areas, urban areas, etc. On the other hand, the loadable weight is small. Therefore, as the agricultural chemical composition to be sprayed by the drone, a so-called labor-saving formulation which requires a small amount of spraying per unit area is preferable. The composition of the present invention satisfies the need for such a pesticide composition dispersed by drones. In particular, among the compositions of the present invention, the water-surface-dispersable granular pesticide composition is very suitable for spreading by an unmanned aerial vehicle.

The following is an overview of the power dispersers mounted on aircraft such as unmanned helicopters and unmanned aerial vehicles. The power spreader for spreading the composition of the present invention is provided with: a tank for accommodating the composition of the present invention; an ejection part located on the lower side of the tank and ejecting the composition of the present invention from the power spreader; and a hopper , which is located in the middle of the tank and the spouting part for transferring the composition of the present invention from the tank to the spouting part, the boundary between the hopper and the spouting part is separated by a gate with an adjustable opening degree, and in addition The ejection portion includes an impeller and a drive portion for rotating the impeller, and in the power dispersing machine, the outer edge of the circumference around which the impeller rotates has an ejection port that is open to the outside of the device. When dispersing pesticides, when the shutter is opened, the composition of the present invention in the tank falls to the ejection part through the hopper due to its own weight, collides with the blades of the rotating impeller, and applies a revolving motion in the same direction as the rotation of the impeller into the ejection part. force, and finally ejected from the ejection port to the outside of the power disperser through centrifugal force. Although pulverization and pulverization due to collision with the impeller also occur in ordinary pesticide granules, the composition of the present invention has such a large particle size that particles with a particle size of 3 mm or more have a particle size distribution of 80% or more and each Substances with a large grain weight are not easily pulverized.

It should be noted that according to Japanese law, "spraying (spraying)" or "aerial spreading (spraying)", "unmanned helicopter spreading (spraying)" is registered as a method of use of pesticides, so the composition of the present invention can be described on the pesticide label this method of use.

Example

Hereinafter, the present invention will be described in detail by way of Examples, but the present invention is not limited by these Examples at all.

Examples 1 to 15 and Comparative Examples 1 to 4

Granular pesticide composition:

(1) Preparation of granular pesticide composition

The mixture of the components described in Table 1 below was kneaded by adding an appropriate amount of water to a plastic bag, and granulated into a particle size of 5 mm using an extrusion granulator. Next, after this granulated material was granulated by a rolling granulator, it was dried by a fluidized bed dryer to obtain a granular agricultural chemical composition. In this granular agricultural chemical composition, 80% or more of particles having a particle diameter of 3 mm or more have an outer shape composed of a curved surface. When 50 grains of this granular agricultural composition were put into a 1-liter beaker containing 500 mL of normal-temperature water, all the grains floated on the water surface, and then all the grains disintegrated within 30 minutes. Table 1 shows the mass, apparent specific gravity, and aspect ratio per grain of the granular agrochemical composition.

(2) Evaluation of granular pesticide compositions

The compressive strength (N) of the granular agricultural chemical composition obtained in (1) was measured using a digital load meter SV55 (manufactured by Imada, Ltd.). Moreover, the pulverization rate of the granular agricultural chemical composition obtained in (1) was measured as follows. These results are shown in Table 1.

<Pulverization rate measurement>

The sample was sieved with a sieve of 500 μm mesh, and 50 g of the sample on the sieve was put into a plastic bottle with a capacity of 250 mL (diameter φ62 mm, height 130 mm, inner diameter φ32 mm), and installed it horizontally on a shaker (Ocean Science Industry Co., Ltd.) SR-1). After shaking at 300 rpm (movement distance 12 cm/reciprocation) for 15 minutes, the sample in the plastic bottle was sieved on a sieve with a mesh of 500 μm, and after sieving, the mass of the sample on the sieve was measured. The pulverization rate of the formulation was calculated according to the following formula.

[Formula 1]

Powdering rate of preparation (%)

= (sample mass before shaking - sample mass after shaking)/sample mass before shaking × 100

Values in the table are parts by mass

R: the amount for setting to 100 parts by mass

+: Not determined

Bactericide Prototype A: pyroquilon

Herbicide Prototype A: pyrimisulfan

Herbicide Prototype B: Fenquinotrione

Herbicide Prototype C: Simetryn

Fungicide Prototype B: Dichlobenthiazox

Surfactant A: ニューカルゲンWG-101 (manufactured by Takemoto Oil Co., Ltd.)

Surfactant B: ソルポール 5284 (manufactured by Toho Chemical Industry Co., Ltd.)

Surfactant C: デモール SN-B (manufactured by Kao Co., Ltd.)

Surfactant D: ニューカルゲン BX-C (manufactured by Takemoto Oil Co., Ltd.)

Surfactant E: Safar 440 (manufactured by Nissin Chemical Industry Co., Ltd.)

Adhesive A: アクアリックDL-100 (manufactured by Nippon Shokubai Co., Ltd.)

Binder B: Amikoru 6L (manufactured by Nippon Chemical Co., Ltd.)

Carrier A: Bentonite

Carrier B: Silica (manufactured by Japan Aerogel Co., Ltd.)

Organic hollow body A: MFL-HD60CA (manufactured by Matsumoto Oil Pharmaceutical Co., Ltd.)

Organic hollow body B: Microsphere F-50E (manufactured by Matsumoto Oil Pharmaceutical Co., Ltd.)

Inorganic hollow body A: トワナイトSYB-5000 (manufactured by Toyohanao Co., Ltd.)

Inorganic hollow body B: マールライト 722B (manufactured by Marunaka White Earth Co., Ltd.)

Inorganic hollow body C: Microsil 325S (manufactured by Tolsa Corporation)

Inorganic hollow body D: Microsil 100 (manufactured by Tolsa Corporation)

Extender A: Calcium Carbonate

Example 16

Pesticide distribution:

The granular agricultural chemical composition of Example 1 was applied in an amount of 250 g to the paddy field 10a in a water storage state using a power spreader, and as a result, it floated on the water surface and disintegrated on the water surface within 30 minutes. In addition, chalking was not observed at this time.

Industrial Applicability

The granular pesticide composition of the present invention can be used for the spreading of pesticides using a power spreader.

Claims (25)

1. A granular pesticide composition comprising 0.1 to 70 parts by mass of agrochemical active ingredients, 0.3 to 15 parts by mass of organic hollow bodies, and 0.01 to 9.99 parts by mass of inorganic hollow bodies per 100 parts by mass. 2 . The granular pesticide composition according to claim 1 , which has the property of floating on the water surface and the property of disintegrating on the water surface within 30 minutes. 3 . 3 . The granular agrochemical composition according to claim 2 , which has a particle size distribution in which particles with a particle diameter of 3 mm or more are 80% or more. 4 . 4 . The granular agricultural chemical composition according to claim 3 , which has a mass per grain of 0.03 to 0.3 g, an apparent specific gravity of 0.3 to 1, an aspect ratio of 1 to 3, and an outer shape composed of a curved surface. 5 . The granular agrochemical composition according to claim 1 , wherein the organic hollow body is a plastic ball. 6 . 6 . The granular agrochemical composition according to claim 1 , wherein the organic hollow body is 1 to 5 parts by mass. 7 . 7 . The granular agrochemical composition according to claim 1 , wherein the inorganic hollow body is a glass sphere and/or a hollow aluminosilicate. 8 . 8 . The granular agrochemical composition according to claim 1 , wherein the amount of the inorganic hollow body is 3 to 7 parts by mass. 9 . 9. The granular pesticide composition according to any one of claims 1 to 8, which is used in a power spreader. 10. The granular agricultural chemical composition according to claim 9, wherein a power spreader is mounted on an aircraft. 11. The granular pesticide composition according to claim 10, wherein the aircraft is an unmanned aerial vehicle. 12. A method of spreading an agricultural chemical, comprising applying the granular agricultural chemical composition according to any one of claims 1 to 11 to a farmland using a power spreading machine. 13. The method of dispersing an agricultural chemical according to claim 12, wherein the farmland is a paddy field in a water storage state. 14. The method of spreading an agricultural chemical according to claim 12 or 13, wherein a power spreader is mounted on an aircraft and spreads from the air. 15. The method of dispersing an agricultural chemical according to claim 14, wherein the aircraft is an unmanned aerial vehicle. 16 . The method of spreading an agricultural chemical according to claim 12 , wherein the amount of the granular agricultural chemical composition to be spread is 50 to 500 g per 10 a of farmland. 17 . 17. A method for producing a granular pesticide composition, comprising: 0.1 to 70 parts by mass of an agriculturally active ingredient, 0.3 to 15 parts by mass of an organic hollow body, and 0.01 to 9.99 parts by mass of an inorganic hollow body per 100 parts by mass The mixture is kneaded, granulated, granulated, and then dried. The method for producing a granular agricultural chemical composition according to claim 17, wherein the granular agricultural chemical composition has a property of floating on the water surface and a property of disintegrating on the water surface within 30 minutes. The method for producing a granular agricultural chemical composition according to claim 17 or 18, wherein the granular agricultural chemical composition has a particle size distribution of 80% or more of particles having a particle diameter of 3 mm or more. The method for producing a granular agricultural chemical composition according to any one of claims 17 to 19, wherein the mass per granular agricultural chemical composition is 0.03 to 0.3 g, the apparent specific gravity is 0.3 to 1, and the aspect ratio is 1 ~3, has an outer shape composed of a curved surface. 21 . The method for producing a granular agrochemical composition according to claim 17 , wherein the organic hollow body is a plastic sphere. 22 . 22 . The method for producing a granular agrochemical composition according to claim 17 , wherein the amount of the organic hollow body is 1 to 5 parts by mass. 23 . 23. The method for producing a granular agricultural chemical composition according to any one of claims 17 to 22, wherein the inorganic hollow body is a glass sphere and/or a hollow aluminosilicate. 24. The method for producing a granular agricultural pesticide composition according to any one of claims 17 to 23, wherein the amount of the inorganic hollow body is 3 to 7 parts by mass. 25. A method for suppressing pulverization of a granular pesticide composition, characterized in that 0.3 to 15 parts by mass of an organic hollow body and 0.3 to 15 parts by mass of the organic hollow body and 0.01 to 9.99 parts by mass of an inorganic hollow body.