[go: up one dir, main page]

CN113637255A - Color master batch for white photovoltaic packaging adhesive film and preparation method thereof - Google Patents

Color master batch for white photovoltaic packaging adhesive film and preparation method thereof Download PDF

Info

Publication number
CN113637255A
CN113637255A CN202010326589.XA CN202010326589A CN113637255A CN 113637255 A CN113637255 A CN 113637255A CN 202010326589 A CN202010326589 A CN 202010326589A CN 113637255 A CN113637255 A CN 113637255A
Authority
CN
China
Prior art keywords
master batch
titanium dioxide
adhesive film
parts
color masterbatch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202010326589.XA
Other languages
Chinese (zh)
Other versions
CN113637255B (en
Inventor
金旭
王梁
张定忠
黄冰艳
陈荣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiaxing Yougu Applied Materials Co ltd
Canadian Solar Inc
Original Assignee
Changshu Tegu New Material Technology CoLtd
Atlas Sunshine Power Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changshu Tegu New Material Technology CoLtd, Atlas Sunshine Power Group Co Ltd filed Critical Changshu Tegu New Material Technology CoLtd
Priority to CN202010326589.XA priority Critical patent/CN113637255B/en
Publication of CN113637255A publication Critical patent/CN113637255A/en
Application granted granted Critical
Publication of CN113637255B publication Critical patent/CN113637255B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/10—Adhesives in the form of films or foils without carriers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F19/00—Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
    • H10F19/80—Encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells
    • H10F19/804—Materials of encapsulations
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
    • C08J2423/30—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by oxidation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/003—Additives being defined by their diameter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/134—Phenols containing ester groups
    • C08K5/1345—Carboxylic esters of phenolcarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/204—Applications use in electrical or conductive gadgets use in solar cells
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00—Presence of polyolefin
    • C09J2423/04—Presence of homo or copolymers of ethene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides a color master batch for a white photovoltaic packaging adhesive film and a preparation method thereof. The color master batch comprises the following components in parts by weight: 40-60 parts of EVA resin, 40-60 parts of titanium dioxide, 1-5 parts of silicone master batch and 1-5 parts of dispersing agent. The color master batch is prepared by uniformly mixing the components except the titanium dioxide, and then extruding and granulating the mixture with the titanium dioxide by using an extruder. The titanium dioxide in the color master batch provided by the invention is well dispersed, and is used for preparing a photovoltaic packaging adhesive film, so that the extrusion torque can be effectively reduced, the die head accumulation in the extrusion casting process of the white photovoltaic packaging adhesive film can be reduced, the adhesive film agglomeration can be reduced, and the production efficiency can be improved.

Description

Color master batch for white photovoltaic packaging adhesive film and preparation method thereof
Technical Field
The invention belongs to the technical field of photovoltaic packaging materials, and particularly relates to a color master batch for a white photovoltaic packaging adhesive film and a preparation method thereof.
Background
With the cost reduction and efficiency improvement of photovoltaic modules and the development of high-efficiency photovoltaic modules in recent years, the amount of white EVA (ethylene vinyl acetate) packaging adhesive films for packaging the photovoltaic modules is increased year by year. The white EVA packaging adhesive film belongs to an upgrading and updating product of a common transparent EVA packaging adhesive film, can change the reflection path of light, and increases the absorption and utilization of the photovoltaic module on the cell gap light and the long-wave band light. The white EVA adhesive film in the single-glass assembly can increase the power gain of the assembly by 1-3W; in the dual glass assembly, the power gain can reach 2-5W.
The white EVA adhesive film is prepared by mixing the white EVA adhesive film with EVA particles and an auxiliary agent in proportion. In consideration of processing cost, the content of the titanium dioxide in the color master batch on the market is between 40 and 60 percent. Because the addition amount of the titanium dioxide in the color master batch is large, and in order to have a good reflection effect, the particle size of the selected titanium dioxide is small, the particle size is between 0.2 and 0.3 mu m, the specific surface area is large, the surface energy is high, the agglomeration or bridging phenomenon is easy to occur in the processing process, so that the titanium dioxide in the color master batch is not uniformly dispersed, the material accumulation phenomenon is easy to occur at a die head in the extrusion and casting process of the white EVA adhesive film, the caking problem is easy to occur in the extrusion process of the adhesive film, the yield of the white EVA adhesive film is reduced, the joint rate of the adhesive film is increased, and the production efficiency is reduced. Moreover, the cell of the photovoltaic module is very thin, and if the white EVA adhesive film is caked, the cell is easily hidden and cracked during module packaging.
Therefore, the caking phenomenon of the white packaging adhesive film for the photovoltaic module is reduced, and the method has important significance for improving the quality of the photovoltaic module and promoting the development of the photovoltaic industry.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide a color master batch for a white photovoltaic packaging adhesive film and a preparation method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
in a first aspect, the invention provides a color master batch for a white photovoltaic packaging adhesive film, which comprises the following components in parts by weight:
Figure BDA0002463434060000021
according to the invention, the dispersing agent can effectively improve the dispersibility of titanium dioxide in the color master batch extrusion processing process, inhibit the agglomeration and bridging of the titanium dioxide, reduce die head accumulation in the extrusion casting process of the white photovoltaic packaging adhesive film, reduce adhesive film agglomeration, reduce the joint rate, reduce defective products and improve the production efficiency. The silicone master batch taking EVA as a carrier has good compatibility with an EVA resin base material, good stability and non-migration property, and can reduce the extrusion torque, improve the fluidity of resin, improve the extrusion rate of the white photovoltaic packaging adhesive film and improve the production efficiency; the silicone master batch can also reduce equipment friction, improve resin demoulding performance, eliminate plastic melt fracture, reduce die head accumulation and reduce adhesive film agglomeration.
According to the invention, the silicone master batch and the dispersing agent are cooperatively matched at a specific ratio, so that the master batch capable of effectively reducing white photovoltaic packaging adhesive film agglomeration and improving the adhesive film yield is obtained.
In the present invention, the EVA resin may be 40 to 60 parts by weight, for example, 40 parts, 42 parts, 43 parts, 45 parts, 46 parts, 48 parts, 50 parts, 52 parts, 53 parts, 55 parts, 56 parts, 58 parts, or 60 parts.
In the invention, the weight portion of the titanium dioxide is 40-60 portions, such as 40 portions, 42 portions, 43 portions, 45 portions, 46 portions, 48 portions, 50 portions, 52 portions, 53 portions, 55 portions, 56 portions, 58 portions or 60 portions.
In the present invention, the silicone base particle may be 1 to 5 parts by weight, for example, 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, or 5 parts.
In the present invention, the dispersant may be used in an amount of 1 to 5 parts by weight, for example, 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, or the like.
In the invention, if the dosage of the silicone master batch or the dispersing agent is too small, the dispersibility of the titanium dioxide is improved, and the effect of reducing adhesive film agglomeration is not obvious; if the using amount of the silicone master batch is too much, the volume resistivity of the photovoltaic packaging adhesive film is obviously reduced; if the amount of the dispersant is too large, the yellowing resistance and the volume resistivity of the photovoltaic packaging adhesive film are obviously reduced.
As a preferred technical scheme of the invention, the melt flow rate of the EVA resin is 20-30g/10 min; for example, it may be 20g/10min, 21g/10min, 22g/10min, 23g/10min, 24g/10min, 25g/10min, 26g/10min, 27g/10min, 28g/10min, 29g/10min, or 30g/10 min.
The melt flow rate in the present invention means a melt flow rate measured at a temperature of 190 ℃ and a pressure of 2.16 kg.
Preferably, the EVA resin has a VA (vinyl acetate unit) content of 20 to 30 wt%; for example, it may be 20 wt%, 21 wt%, 22 wt%, 23 wt%, 24 wt%, 25 wt%, 26 wt%, 27 wt%, 28 wt%, 29 wt%, 30 wt%, or the like.
In the invention, the EVA resin with high melt index and high VA content is preferably selected as the EVA resin, which is beneficial to further improving the dispersibility of titanium dioxide in the extrusion processing process of color master batches and reducing the caking phenomenon of a photovoltaic packaging adhesive film.
As the preferred technical scheme of the invention, the average particle size of the titanium dioxide is 150-400 nm; for example, it may be 150nm, 200nm, 250nm, 300nm, 350nm, 400nm, or the like.
As a preferred technical scheme of the invention, the carrier of the silicone master batch is EVA resin, and the silicone content is more than or equal to 50 wt%; for example, it may be 50 wt%, 52 wt%, 55 wt%, 58 wt%, 60 wt%, 62 wt%, 65 wt%, 68 wt%, 70 wt%, or the like.
The silicone master batch taking the EVA resin as the carrier has good compatibility with the EVA matrix of the master batch, and is beneficial to further improving the dispersibility of the titanium pigment; the selection of high silicone content is favorable for improving the effects of the silicone master batch on reducing extrusion torque, equipment friction and adhesive film agglomeration
As a preferred technical scheme of the invention, the dispersing agent is polyethylene wax and/or oxidized polyethylene wax.
Preferably, the mass ratio of the silicone master batch to the dispersing agent is 1:3-1.5: 1; for example, 1:3, 1:2.5, 1:2, 1:1.5, 1:1, 1.2:1, or 1.5:1, etc.
As a preferable technical scheme of the present invention, the color master batch further comprises 0.1-0.5 part (for example, 0.1 part, 0.2 part, 0.3 part, 0.4 part or 0.5 part) of an antioxidant.
Preferably, the antioxidant is selected from one or a combination of at least two of pentaerythritol tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], N-octadecyl beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate, N '-bis- [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionyl ] hexanediamine, 2, 6-di-tert-butyl-p-cresol, 4' -thiobis (3-methyl-6-tert-butylphenol), dilaurate thiodipropionate and tris (2, 4-di-tert-butylphenyl) phosphite.
As a preferable embodiment of the present invention, the color masterbatch is cylindrical particles, and the length of the color masterbatch is 2.8mm ± 0.5mm, for example, 2.3mm, 2.4mm, 2.5mm, 2.6mm, 2.7mm, 2.8mm, 2.9mm, 3.0mm, 3.1mm, 3.2mm, or 3.3 mm; the diameter is 2.5 mm. + -. 0.5mm, and may be, for example, 2.0mm, 2.1mm, 2.2mm, 2.3mm, 2.4mm, 2.5mm, 2.6mm, 2.7mm, 2.8mm, 2.9mm or 3.0 mm.
Preferably, the continuous grain rate of the color master batch is less than or equal to 0.2 percent, and the water content is less than or equal to 0.1 percent by weight.
In a second aspect, the present invention provides a preparation method of the color master batch, including the following steps:
(1) mixing the components except the titanium dioxide according to the proportion;
(2) and (2) extruding the mixed material obtained in the step (1) and titanium dioxide by using an extruder, and pelletizing to obtain the color master batch.
As a preferred embodiment of the present invention, the mixing in step (1) is carried out in a high-speed mixer.
Preferably, the rotation speed of the high-speed mixer is 500-1000r/min, such as 500r/min, 550r/min, 600r/min, 650r/min, 700r/min, 750r/min, 800r/min, 850r/min, 900r/min, 950r/min or 1000 r/min; the mixing time is 5-10min, such as 5.5min, 6min, 6.5min, 7min, 7.5min, 8min, 8.5min, 9min, 9.5min or 10 min.
As a preferred technical scheme of the invention, the mixed material and the titanium dioxide in the step (2) are continuously added into an extruder according to the proportion by two weightless scales.
The method comprises the steps of mixing other components except the titanium dioxide, and then respectively and quantitatively and continuously adding the mixed material and the titanium dioxide into an extruder according to the proportion by adopting two weightless scales, so that the problem that the titanium dioxide is easy to agglomerate due to pressure generated by mixing by adopting a high-speed mixer is avoided, the problem of layering of the titanium dioxide and other materials due to different densities is avoided by accurately, quantitatively and continuously feeding, and the dispersibility of the titanium dioxide in the extrusion processing of the master batch is further improved, so that the agglomeration phenomenon of the photovoltaic packaging adhesive film is further reduced.
Preferably, the extruder in step (2) is a twin-screw extruder.
Preferably, the temperature of the extrusion in step (2) is 80-140 ℃.
The extruder is heated in a sectional mode, the heating set temperature of each section is different, and the temperature of the melt extrusion in the invention refers to the temperature range of the whole extruder.
Preferably, the pelletizing in step (2) is carried out in water.
Preferably, the drying operation is also performed after the dicing in step (2).
Compared with the prior art, the invention has the following beneficial effects:
according to the invention, by adopting the silicone master batch and the dispersing agent to be cooperatively matched in a specific proportion, the dispersion uniformity of the titanium dioxide in the master batch is improved, the agglomeration and bridging of the titanium dioxide are inhibited, the dispersion grade of the prepared master batch is 1-3.5, the filter pressing value is 0.8-3.6bar/g, the extrusion torque can be effectively reduced, the die head accumulation in the extrusion casting process of the white photovoltaic packaging adhesive film is reduced, the adhesive film agglomeration is reduced, and the production efficiency is improved.
In the preparation method, other components except the titanium dioxide are mixed firstly, and then the mixed material and the titanium dioxide are respectively and quantitatively and continuously added into the extruder according to the proportion by adopting two weightless scales, so that the problem that the titanium dioxide is easy to agglomerate due to the pressure generated by mixing by adopting a high-speed mixer is avoided, the problem of layering caused by different densities of the titanium dioxide and other materials is avoided, and the agglomeration phenomenon of the photovoltaic packaging adhesive film is further reduced.
Detailed Description
The technical solution of the present invention is further illustrated by the following specific examples. It should be understood by those skilled in the art that the examples are only for the understanding of the present invention and should not be construed as the specific limitations of the present invention.
The raw materials adopted in the embodiment of the invention are as follows:
EVA resin: hanhua E282PV (melt index 25g/10min, VA content 28%), Taiwan polymeric UE2825 (melt index 25g/10min, VA content 28%), Sponger UE2825 (melt index 25g/10min, VA content 28%), Singapore polyolefin VF024N00 (melt index 28g/10min, VA content 28%);
titanium dioxide: keveil R-706 (median particle size of 360nm), Cinza CR210 (average particle size of 200nm), Trinito 8400 (average particle size of 230nm), and TiONA288 (average particle size of 250 nm);
silicone master batch: dow Corning MB50-320 (silicone content is more than or equal to 50%), Shanghai Kangyan chemical company, ME-803 (silicone content is more than or equal to 50%), Zhongshan Honglijianpan trade company, HL-58 (silicone content is more than or equal to 65%), Shanghai Yinghe chemical company, MB50-B003 (silicone content is more than or equal to 50%).
Example 1
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which comprises the following components in parts by weight:
Figure BDA0002463434060000071
the preparation method of the color master batch comprises the following steps:
(1) adding the components except the titanium dioxide into a high-speed mixer according to the proportion, and mixing for 10min at the rotating speed of 500 r/min;
(2) and (2) quantitatively and continuously adding the mixed material obtained in the step (1) and titanium dioxide into a double-screw extruder by using two weightless scales according to a ratio, extruding at 80-140 ℃, and carrying out underwater granulation, spin-drying and hot air drying to obtain the color master batch.
Example 2
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which comprises the following components in parts by weight:
Figure BDA0002463434060000072
the preparation method of the color master batch comprises the following steps:
(1) adding the components except the titanium dioxide into a high-speed mixer according to the proportion, and mixing for 5min at the rotating speed of 1000 r/min;
(2) and (2) quantitatively and continuously adding the mixed material obtained in the step (1) and titanium dioxide into a double-screw extruder by using two weightless scales according to a ratio, extruding at 80-140 ℃, and carrying out underwater granulation, spin-drying and hot air drying to obtain the color master batch.
Example 3
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which comprises the following components in parts by weight:
Figure BDA0002463434060000081
the preparation method of the color master batch comprises the following steps:
(1) adding the components except the titanium dioxide into a high-speed mixer according to the proportion, and mixing for 8min at the rotating speed of 800 r/min;
(2) and (2) quantitatively and continuously adding the mixed material obtained in the step (1) and titanium dioxide into a double-screw extruder by using two weightless scales according to a ratio, extruding at 80-140 ℃, and carrying out underwater granulation, spin-drying and hot air drying to obtain the color master batch.
Example 4
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which comprises the following components in parts by weight:
Figure BDA0002463434060000082
the preparation method of the color master batch comprises the following steps:
(1) adding the components except the titanium dioxide into a high-speed mixer according to the proportion, and mixing for 8min at the rotating speed of 800 r/min;
(2) and (2) quantitatively and continuously adding the mixed material obtained in the step (1) and titanium dioxide into a double-screw extruder by using two weightless scales according to a ratio, extruding at 80-140 ℃, and carrying out underwater granulation, spin-drying and hot air drying to obtain the color master batch.
Example 5
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which comprises the following components in parts by weight:
Figure BDA0002463434060000091
the procedure for the preparation of the color masterbatch in this example was the same as in example 1.
Example 6
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which is different from the embodiment 1 in that the weight part of the silicone master batch is 1 part, the weight part of the dispersing agent is 5 parts, and other components, the using amounts and the preparation steps are the same as those of the embodiment 1.
Example 7
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which is different from the embodiment 1 in that the weight part of the silicone master batch is 2 parts, the weight part of the dispersing agent is 4 parts, and other components, the using amount and the preparation steps are the same as those of the embodiment 1.
Example 8
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which is different from the embodiment 1 in that the weight part of the silicone master batch is 4 parts, the weight part of the dispersing agent is 2 parts, and other components, the using amount and the preparation steps are the same as those of the embodiment 1.
Example 9
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which is different from the embodiment 1 in that the weight part of the silicone master batch is 5 parts, the weight part of the dispersing agent is 1 part, and other components, the using amount and the preparation steps are the same as those of the embodiment 1.
Example 10
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which is different from the embodiment 1 in that the weight part of EVA resin is 45 parts, and the weight part of titanium dioxide is 55 parts; other components, amounts and preparation steps were the same as in example 1.
Example 11
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which is different from the embodiment 1 in that 50 parts by weight of EVA resin and 50 parts by weight of titanium dioxide are used; other components, amounts and preparation steps were the same as in example 1.
Example 12
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which is different from the embodiment 1 in that the weight part of EVA resin is 55 parts, and the weight part of titanium dioxide is 45 parts; other components, amounts and preparation steps were the same as in example 1.
Example 13
The embodiment provides a color master batch for a white photovoltaic packaging adhesive film, which is different from the embodiment 1 in that the weight part of EVA resin is 60 parts, and the weight part of titanium dioxide is 40 parts; other components, amounts and preparation steps were the same as in example 1.
Comparative example 1
This example provides a color concentrate, which differs from example 1 in that it does not contain silicone concentrate and dispersant, and the other components, amounts, and preparation steps are the same as example 1.
Comparative example 2
This example provides a color masterbatch, which is different from example 1 in that it does not contain silicone masterbatch, the weight part of dispersant is 6 parts, and other components, amounts and preparation steps are the same as example 1.
Comparative example 3
This example provides a color masterbatch, which is different from example 1 in that no dispersant is contained, the weight part of silicone masterbatch is 6 parts, and other components, amounts and preparation steps are the same as those of example 1.
And (3) performance testing:
the performance of the color concentrates provided in examples 1-13 and comparative examples 1-3 above was tested as follows:
(1) and (3) testing the dispersion grade: and (3) performing sample preparation test according to the specification of the standard GB/T18251-2000, observing the dispersion state of the color master batch by using a magnifier with the magnification of 10 multiplied by 10 times, wherein the dispersion grade is 0-7 grade, the 0 grade represents the highest dispersion grade, and then sequentially decreasing, and the higher the dispersion grade, the better the dispersion.
(2) And (3) testing the filter pressing value: and (3) performing sample preparation test according to the specification of the standard BS EN13900-5:2005, wherein the smaller the filter pressing value is, the better the dispersibility of the titanium dioxide in the color master batch is.
(3) Testing the caking quantity: adding the prepared different color masterbatches into the same white EVA adhesive film formula (100 parts of EVA resin (the total amount of the EVA resin in the color masterbatches and the added EVA resin in addition, the added EVA resin is Hanhua E282PV), 8 parts of titanium dioxide (the amount of the color masterbatches is added according to the corresponding amount of the amount and the content of the titanium dioxide), 0.5 part of tert-butyl peroxy-2-ethylhexyl carbonate, 0.7 part of triacrylate, 0.7 part of propoxylated glycerol triacrylate, 0.25 part of bis (1,2,2,6, 6-pentamethyl-4-piperidyl) sebacate and 0.5 part of gamma-methacryloxypropyltrimethoxysilane), mixing and stirring for 2.5h at the stirring speed of 20r/min, mixing the materials in the same extrusion casting equipment under the same process production conditions (the extrusion temperature is 50-100 ℃, the casting line speed is 8m/min, and the gram weight is 470g/m2) The number of lumps generated by the continuous production of 24h white EVA film was tested.
The results of the above tests are shown in table 1 below:
TABLE 1
Test items Grade of dispersion Pressure filtration value (bar/g) Number of lumps formed in 24h
Example 1 2.5 2.4 5
Example 2 3.0 3.1 6
Example 3 1.5 1.1 3
Example 4 1 0.8 2
Example 5 2 1.8 3
Example 6 3.0 2.9 6
Example 7 2.5 2.3 5
Example 8 3.5 3.4 7
Example 9 3.5 3.6 7
Practice ofExample 10 2.5 2.0 4
Example 11 2 1.5 3
Example 12 1.5 1.2 3
Example 13 1 1 2
Comparative example 1 4.5 7.6 15
Comparative example 2 3.5 3.9 8
Comparative example 3 4.0 5.3 10
As can be seen from the test results in Table 1, the dispersion grade of the color master batch provided by the invention is 1-3.5, the filter pressing value is 0.8-3.6bar/g, and the titanium dioxide powder is well dispersed; compared with the color master batch (comparative example 1) without the silicone master batch and the dispersing agent, the white EVA adhesive film prepared by the color master batch provided by the invention has the advantage that the caking number in 24h of continuous production is obviously reduced.
Compared with the embodiment 1, the ratio of the consumption of the silicone master batch to the consumption of the dispersing agent in the embodiment 6 is smaller, the ratio of the consumption of the silicone master batch to the consumption of the dispersing agent in the embodiments 8 and 9 is larger, and the dispersibility of the titanium dioxide of the obtained color master batch is inferior to that of the titanium dioxide in the embodiment 1.
Compared with the embodiment 1, the silicone master batch is replaced by the same amount of the dispersing agent in the comparative example 2, the dispersing agent is replaced by the same amount of the silicone master batch in the comparative example 3, the dispersing grade and the filter pressing value of the master batches prepared by the silicone master batch and the dispersing agent are both obviously reduced, and the agglomeration phenomenon is obviously increased when the white EVA adhesive film is prepared by the master batches, so that the silicone master batch and the dispersing agent have the effects of synergistically improving the dispersibility of the titanium dioxide and reducing the agglomeration of the adhesive film.
The applicant declares that the above description is only a specific embodiment of the present invention, but the scope of the present invention is not limited thereto, and it should be understood by those skilled in the art that any changes or substitutions that can be easily conceived by those skilled in the art within the technical scope of the present invention are within the scope and disclosure of the present invention.

Claims (10)

1.一种白色光伏封装胶膜用色母粒，其特征在于，所述色母粒包括如下重量份数的组分：1. a color masterbatch for white photovoltaic encapsulation adhesive film, is characterized in that, described color masterbatch comprises the component of following parts by weight:
Figure FDA0002463434050000011
Figure FDA0002463434050000011
 2.根据权利要求1所述的色母粒，其特征在于，所述EVA树脂的熔体流动速率为20-30g/10min；2. masterbatch according to claim 1, is characterized in that, the melt flow rate of described EVA resin is 20-30g/10min; 优选地，所述EVA树脂的VA含量为20-30wt％。Preferably, the VA content of the EVA resin is 20-30wt%. 3.根据权利要求1或2所述的色母粒，其特征在于，所述钛白粉的平均粒径为150-400nm。3. The color masterbatch according to claim 1 or 2, wherein the average particle size of the titanium dioxide is 150-400 nm. 4.根据权利要求1-3任一项所述的色母粒，其特征在于，所述硅酮母粒的载体为EVA树脂，硅酮含量≥50wt％。4. The color masterbatch according to any one of claims 1-3, wherein the carrier of the silicone masterbatch is EVA resin, and the silicone content is greater than or equal to 50wt%. 5.根据权利要求1-4任一项所述的色母粒，其特征在于，所述分散剂为聚乙烯蜡和/或氧化聚乙烯蜡；5. The color masterbatch according to any one of claims 1-4, wherein the dispersant is polyethylene wax and/or oxidized polyethylene wax; 优选地，所述硅酮母粒与分散剂的质量比为1:3-1.5:1。Preferably, the mass ratio of the silicone masterbatch to the dispersant is 1:3-1.5:1. 6.根据权利要求1-5任一项所述的色母粒，其特征在于，所述色母粒还包括0.1-0.5份抗氧剂；6. The color masterbatch according to any one of claims 1-5, wherein the color masterbatch further comprises 0.1-0.5 part of antioxidant; 优选地，所述抗氧剂选自四[β-(3,5-二叔丁基-4-羟基苯基)丙酸]季戊四醇酯、β-(3,5-二叔丁基-4-羟基苯基)丙酸正十八碳醇酯、N,N'-双-[3-(3,5-二叔丁基-4-羟基苯基)丙酰基]己二胺、2,6-二叔丁基对甲酚、4,4'-硫代双(3-甲基-6-叔丁基苯酚)、硫代二丙酸二月桂酸酯和三(2,4-二叔丁基苯基)亚磷酸酯中的一种或至少两种的组合。Preferably, the antioxidant is selected from tetrakis[beta-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid]pentaerythritol ester, beta-(3,5-di-tert-butyl-4- Hydroxyphenyl) propionate n-octadecyl ester, N,N'-bis-[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl]hexanediamine, 2,6- Di-tert-butyl-p-cresol, 4,4'-thiobis(3-methyl-6-tert-butylphenol), dilaurate thiodipropionate and tris(2,4-di-tert-butyl) phenyl) one or a combination of at least two of the phosphites. 7.根据权利要求1-6任一项所述的色母粒，其特征在于，所述色母粒为圆柱形粒子，长为2.8mm±0.5mm，直径为2.5mm±0.5mm；7. The color masterbatch according to any one of claims 1-6, wherein the color masterbatch is a cylindrical particle with a length of 2.8mm±0.5mm and a diameter of 2.5mm±0.5mm; 优选地，所述色母粒的连粒率≤0.2％，含水量≤0.1wt％。Preferably, the continuous particle rate of the color masterbatch is less than or equal to 0.2%, and the water content is less than or equal to 0.1 wt%. 8.一种如权利要求1-7任一项所述的色母粒的制备方法，其特征在于，所述制备方法包括如下步骤：8. a preparation method of masterbatch as described in any one of claim 1-7, is characterized in that, described preparation method comprises the steps: (1)按配比将除钛白粉之外的组分混合；(1) Mix the components other than titanium dioxide according to the proportion; (2)将步骤(1)得到的混合物料和钛白粉用挤出机挤出，切粒后得到所述色母粒。(2) extruding the mixed material and titanium dioxide obtained in step (1) with an extruder, and dicing to obtain the color masterbatch. 9.根据权利要求8所述的制备方法，其特征在于，步骤(1)中所述混合是在高混机中进行；9. preparation method according to claim 8, is characterized in that, mixing described in step (1) is to carry out in high mixer; 优选地，所述高混机的转速为500-1000r/min，混合时间为5-10min。Preferably, the rotating speed of the high mixer is 500-1000r/min, and the mixing time is 5-10min. 10.根据权利要求8或9所述的制备方法，其特征在于，步骤(2)中所述混合物料和钛白粉是通过两个失重秤按配比连续加入挤出机中；10. preparation method according to claim 8 or 9, is characterized in that, described in step (2), mixed material and titanium dioxide are continuously added in extruder by proportioning by two loss-in-weight scales; 优选地，步骤(2)中所述挤出机为双螺杆挤出机；Preferably, the extruder described in step (2) is a twin-screw extruder; 优选地，步骤(2)中所述挤出的温度为80-140℃；Preferably, the extrusion temperature in step (2) is 80-140°C; 优选地，步骤(2)中所述切粒是在水中进行；Preferably, the dicing in step (2) is carried out in water; 优选地，步骤(2)中所述切粒之后还进行干燥操作。Preferably, a drying operation is also performed after the dicing in step (2).
CN202010326589.XA 2020-04-23 2020-04-23 Color master batch for white light photovoltaic packaging adhesive film and preparation method thereof Active CN113637255B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010326589.XA CN113637255B (en) 2020-04-23 2020-04-23 Color master batch for white light photovoltaic packaging adhesive film and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010326589.XA CN113637255B (en) 2020-04-23 2020-04-23 Color master batch for white light photovoltaic packaging adhesive film and preparation method thereof

Publications (2)

Publication Number Publication Date
CN113637255A true CN113637255A (en) 2021-11-12
CN113637255B CN113637255B (en) 2023-08-22

Family

ID=78414812

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010326589.XA Active CN113637255B (en) 2020-04-23 2020-04-23 Color master batch for white light photovoltaic packaging adhesive film and preparation method thereof

Country Status (1)

Country Link
CN (1) CN113637255B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114414423A (en) * 2021-11-25 2022-04-29 苏州腾晖光伏技术有限公司 Method for testing crosslinking degree of white adhesive film of photovoltaic module
CN115304856A (en) * 2022-05-19 2022-11-08 浙江苏达山新材料有限公司 Color master batch with good distribution effect and preparation process thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101691438A (en) * 2009-09-22 2010-04-07 广州市波斯塑胶颜料有限公司 ABS color master batch
CN106753056A (en) * 2016-12-29 2017-05-31 苏州度辰新材料有限公司 White polyolefin packaging adhesive film for solar cell module and preparation method thereof
CN106905669A (en) * 2016-03-21 2017-06-30 宁波长阳科技股份有限公司 A kind of titanium dioxide Masterbatch and preparation method thereof
CN107325214A (en) * 2017-08-29 2017-11-07 淄博华冠高分子材料有限公司 A kind of TPO vector resin, Masterbatch and preparation method thereof
CN108997957A (en) * 2018-07-23 2018-12-14 江苏鹿山光电科技有限公司 A kind of white EVA packaging adhesive film and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101691438A (en) * 2009-09-22 2010-04-07 广州市波斯塑胶颜料有限公司 ABS color master batch
CN106905669A (en) * 2016-03-21 2017-06-30 宁波长阳科技股份有限公司 A kind of titanium dioxide Masterbatch and preparation method thereof
CN106753056A (en) * 2016-12-29 2017-05-31 苏州度辰新材料有限公司 White polyolefin packaging adhesive film for solar cell module and preparation method thereof
CN107325214A (en) * 2017-08-29 2017-11-07 淄博华冠高分子材料有限公司 A kind of TPO vector resin, Masterbatch and preparation method thereof
CN108997957A (en) * 2018-07-23 2018-12-14 江苏鹿山光电科技有限公司 A kind of white EVA packaging adhesive film and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114414423A (en) * 2021-11-25 2022-04-29 苏州腾晖光伏技术有限公司 Method for testing crosslinking degree of white adhesive film of photovoltaic module
CN115304856A (en) * 2022-05-19 2022-11-08 浙江苏达山新材料有限公司 Color master batch with good distribution effect and preparation process thereof

Also Published As

Publication number Publication date
CN113637255B (en) 2023-08-22

Similar Documents

Publication Publication Date Title
CN1038422C (en) Water-insoluble product based on starch and preparation method thereof
CN113637255A (en) Color master batch for white photovoltaic packaging adhesive film and preparation method thereof
CN112500588B (en) Method for preparing high-fluidity carbon black masterbatch by in-situ degradation of polypropylene with peroxide
CN107540920B (en) Metallocene polyethylene composition and preparation method thereof
CN114249935A (en) Weather-resistant color master batch and preparation method thereof
CN110218388A (en) A kind of antiultraviolet ageing resistance polypropylene master batch and its manufacturing process
CN110240779B (en) High-precision non-plug straw FDM 3D printing consumable and preparation method thereof
CN104497406B (en) Filling master batch for transparent film and preparation method of filling master batch
CN112080067A (en) High-filling filler modified polyolefin composite material and preparation method and application thereof
CN102295796B (en) Conductive polyolefin sheathing compound for superhigh voltage cable sheath and preparation method thereof
CN111333956A (en) Antibacterial polypropylene material and preparation method thereof
CN102618189B (en) Novel polymer solid slow-release glue
CN113388201B (en) High-gloss spraying-free PP/PE composite material and preparation method thereof
WO2019100964A1 (en) Rice hull powder master batch and preparation method therefor
CN115572468A (en) Preparation method of master batch resin for high-performance, low-cost and active light calcium carbonate fully-degradable film
CN114479290A (en) PP-based food contact total migration volume standard sample and preparation method thereof
CN108059804B (en) PBAT degradation color master batch and preparation method thereof
CN106336680B (en) A kind of plastic masterbatch containing biomass, its preparation method and application
CN116482342B (en) Method for detecting application performance of titanium dioxide in HIPS injection molding system
CN116285062B (en) A matte functional masterbatch for artificial turf and preparation method thereof
CN115785641B (en) Preparation method of hyperspectral selective permeable material
CN117820753B (en) Metallocene polyethylene-containing composition and application thereof in silage films
CN116023729B (en) Special master batch for PE white film and preparation method thereof
CN111961279B (en) Black master batch and preparation method thereof
CN118876262A (en) A preparation method of masterbatch and its products and applications

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20250126

Address after: Room 102, No.1 Xingyuan Road, Xincheng Town, Xiuzhou District, Jiaxing City, Zhejiang Province, 314000

Patentee after: Jiaxing Yougu Applied Materials Co.,Ltd.

Country or region after: China

Patentee after: Atlas sunshine Power Group Co.,Ltd.

Address before: 215129 199 deer Road, Suzhou hi tech Development Zone, Jiangsu, Suzhou

Patentee before: Atlas sunshine Power Group Co.,Ltd.

Country or region before: China

Patentee before: CHANGSHU TEGU NEW MATERIAL TECHNOLOGY Co.,Ltd.