CN113546680A - Chemical reaction type deodorant containing betaine modified bentonite and preparation method thereof - Google Patents
Chemical reaction type deodorant containing betaine modified bentonite and preparation method thereof Download PDFInfo
- Publication number
- CN113546680A CN113546680A CN202110735406.4A CN202110735406A CN113546680A CN 113546680 A CN113546680 A CN 113546680A CN 202110735406 A CN202110735406 A CN 202110735406A CN 113546680 A CN113546680 A CN 113546680A
- Authority
- CN
- China
- Prior art keywords
- betaine
- chemical reaction
- bentonite
- modified bentonite
- deodorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 43
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 229960003237 betaine Drugs 0.000 title claims abstract description 37
- 238000006757 chemical reactions by type Methods 0.000 title claims abstract description 31
- -1 betaine modified bentonite Chemical class 0.000 title claims description 10
- 238000002360 preparation method Methods 0.000 title abstract description 7
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical class O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000003054 catalyst Substances 0.000 claims abstract description 35
- 239000000463 material Substances 0.000 claims abstract description 30
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims abstract description 27
- 239000000440 bentonite Substances 0.000 claims abstract description 21
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 19
- 239000002131 composite material Substances 0.000 claims abstract description 18
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 15
- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910003446 platinum oxide Inorganic materials 0.000 claims abstract description 15
- 238000011068 loading method Methods 0.000 claims abstract description 13
- 238000001354 calcination Methods 0.000 claims abstract description 12
- 238000004332 deodorization Methods 0.000 claims abstract description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 19
- 239000000725 suspension Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 7
- 239000012018 catalyst precursor Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 238000013329 compounding Methods 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000005470 impregnation Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 3
- 239000012279 sodium borohydride Substances 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 2
- 238000005034 decoration Methods 0.000 claims description 2
- 235000013305 food Nutrition 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 4
- 230000005923 long-lasting effect Effects 0.000 abstract description 3
- 230000009965 odorless effect Effects 0.000 abstract description 3
- 230000003197 catalytic effect Effects 0.000 abstract description 2
- 150000002500 ions Chemical class 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 235000019645 odor Nutrition 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000001877 deodorizing effect Effects 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0239—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
Abstract
The invention belongs to the technical field of deodorization, and discloses a betaine-modified bentonite-containing chemical reaction type deodorant and a preparation method thereof, wherein the preparation method of the betaine-modified bentonite-containing chemical reaction type deodorant comprises the following steps: calcining bentonite at linear temperature by microwave to obtain a material A; loading betaine and nano silver on platinum oxide to synthesize a surface catalyst B; and loading the composite catalyst B on the surface of the material A to obtain the betaine-modified bentonite-containing chemical reaction type deodorant. According to the invention, betaine and metal are compounded to be used as a catalyst material, so that the material and ion conductivity are improved, the conductivity of the catalyst is improved, and the betaine and the metal have a synergistic effect, so that the catalytic activity of the catalyst is greatly improved. The deodorant of the present invention uses malodorous components as odorless substances according to chemical reactions, and can deodorize rapidly and has a long lasting effect.
Description
Technical Field
The invention belongs to the technical field of deodorization, and particularly relates to a betaine-modified bentonite-containing chemical reaction type deodorant and a preparation method thereof.
Background
At present: typical malodorous gases, basic odors (ammonia, trimethylamine, etc.), acidic odors (hydrogen sulfide, methanol, low fatty acids, etc.), and malodors generated in various places by neutral odors (formaldehyde, methyl sulfide, oils and fats, etc.) are often combined into these odors, and conventional deodorants cannot cope with a wide range of odors.
Through the above analysis, the problems and defects of the prior art are as follows: the existing deodorant can not deal with wide compound odor.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides a chemical reaction type deodorant containing betaine modified bentonite and a preparation method thereof.
The invention is realized in such a way that a betaine-modified bentonite-containing chemical reaction type deodorant is composed of 75-85 parts of bentonite and 10-20 parts of a composite catalyst;
the composite catalyst consists of betaine, nano silver and platinum oxide.
Another object of the present invention is to provide a method for preparing the betaine-containing modified bentonite chemical reaction type deodorant, the method comprising:
step one, calcining bentonite by microwave at a linear temperature to obtain a material A;
compounding betaine and metal to prepare a composite catalyst B;
and step three, loading the composite catalyst B on the surface of the material A to obtain the betaine-modified bentonite-containing chemical reaction type deodorant.
Further, the microwave calcination of bentonite at linear temperature to obtain material a comprises:
and (3) carrying out vacuum impregnation treatment on the bentonite by adopting an acidic potassium permanganate solution to obtain pretreated bentonite, and calcining the pretreated bentonite at a linear temperature to obtain the material A.
Further, the preparation of the composite catalyst B by compounding betaine and metal comprises the following steps: the betaine and the nano silver are loaded on the platinum oxide, and the surface catalyst B can be synthesized.
Further, the loading of betaine and nano silver on platinum oxide comprises:
mixing the mixed solution of nano silver and platinum oxide with betaine solution to carry out a first reaction to obtain suspension;
adding sodium borohydride into the obtained suspension for a second reaction, and separating and vacuum-drying a reaction product to obtain a catalyst precursor;
and roasting the obtained catalyst precursor in an inert atmosphere to obtain the surface catalyst B.
Further, the method for preparing the chemical reaction type deodorant containing betaine modified bentonite by loading the composite catalyst B on the surface of the material A comprises the following steps:
crushing the material A, sieving the crushed material A by a 120-mesh sieve to obtain powder, adding water into the obtained powder, stirring, and standing to obtain a suspension;
adding the catalyst mixed solution into the suspension at 30-35 ℃, stirring for 1-2h, performing precipitation separation, and drying at 90-95 ℃;
placing the dried product in a 800W microwave oven, and performing microwave irradiation for 8-10 min;
and adding the product subjected to microwave irradiation into deionized water, stirring, carrying out precipitation separation, drying at the temperature of 120-.
Further, the chemical reaction type deodorant containing betaine-modified bentonite is gray powder.
The invention also aims to provide application of the betaine-containing modified bentonite chemical reaction type deodorant in resin manufacture and tire casting.
The invention also aims to provide application of the chemical reaction type deodorant containing the betaine modified bentonite in decoration deodorization, pet animal houses, kitchen deodorization and drainage deodorization.
The invention also aims to provide application of the chemical reaction type deodorant containing the betaine modified bentonite in food processing.
By combining all the technical schemes, the invention has the advantages and positive effects that: the betaine is added, so that the detergent has excellent solubility and compatibility, excellent foamability and remarkable thickening property, low irritation and sterilization, and the softness, conditioning and low-temperature stability of washing products can be remarkably improved by using the betaine, and the detergent has favorable hard water resistance, antistatic property and biodegradability.
According to the invention, betaine and metal are compounded to be used as a catalyst material, so that the material and ion conductivity are improved, the conductivity of the catalyst is improved, and the betaine and the metal have a synergistic effect, so that the catalytic activity of the catalyst is greatly improved.
The deodorant of the present invention uses malodorous components as odorless substances according to chemical reactions, and can deodorize rapidly and has a long lasting effect.
Drawings
Fig. 1 is a flow chart of a method for preparing a chemical reaction type deodorant containing betaine-modified bentonite according to an embodiment of the present invention.
FIG. 2 is a flow chart of a method for microwave calcination of bentonite at linear temperature according to an embodiment of the present invention.
Fig. 3 is a flow chart of a method for loading betaine and nano silver on platinum oxide according to an embodiment of the present invention.
Fig. 4 is a flow chart of a method for obtaining the betaine-modified bentonite-containing chemical reaction deodorant by loading a composite catalyst B on the surface of a material a according to an embodiment of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
In view of the problems in the prior art, the present invention provides a chemical reaction type deodorant containing betaine-modified bentonite, and the present invention is described in detail below with reference to the accompanying drawings.
The chemical reaction type deodorant containing the betaine modified bentonite provided by the embodiment of the invention comprises bentonite and a composite catalyst.
The composite catalyst provided by the embodiment of the invention consists of betaine, nano silver and platinum oxide.
As shown in fig. 1, a method for preparing a chemical reaction type deodorant containing betaine-modified bentonite according to an embodiment of the present invention includes:
s101, calcining bentonite at a linear temperature by using microwaves to obtain a material A;
s102, loading betaine and nano silver on platinum oxide to synthesize a surface catalyst B;
s103, loading the composite catalyst B on the surface of the material A to obtain the chemical reaction type deodorant containing the betaine modified bentonite.
The chemical reaction type deodorant containing the betaine modified bentonite provided by the embodiment of the invention is gray powder.
As shown in fig. 2, the microwave calcination of bentonite at linear temperature provided by the embodiment of the present invention, to obtain material a, includes:
s201, carrying out vacuum impregnation treatment on bentonite by adopting an acidic potassium permanganate solution to obtain pretreated bentonite;
s202, calcining the pretreated bentonite at a linear temperature to obtain the material A.
As shown in fig. 3, the loading of betaine and nano silver on platinum oxide according to the embodiment of the present invention includes:
s301, mixing the mixed solution of nano silver and platinum oxide with betaine solution to perform a first reaction to obtain a suspension;
s302, adding sodium borohydride into the obtained suspension for a second reaction, and separating and vacuum-drying a reaction product to obtain a catalyst precursor;
s303, roasting the obtained catalyst precursor in an inert atmosphere to obtain the surface catalyst B.
As shown in fig. 4, the method for preparing a chemical reaction type deodorant containing betaine-modified bentonite by loading a composite catalyst B on the surface of a material a according to an embodiment of the present invention includes:
s401, crushing the material A, sieving the material A by a 120-mesh sieve to obtain powder, adding water into the obtained powder, stirring, and standing to obtain a suspension;
s402, adding the catalyst mixed solution into the suspension at the temperature of 30-35 ℃, stirring for 1-2h, carrying out precipitation separation, and drying at the temperature of 90-95 ℃;
s403, placing the dried product in a 800W microwave oven, and performing microwave irradiation for 8-10 min;
s404, adding the product subjected to microwave irradiation into deionized water, stirring, carrying out precipitation separation, drying at the temperature of 120-130 ℃, and crushing to obtain the betaine-modified bentonite-containing chemical reaction type deodorant.
The technical solution of the present invention is further illustrated by the following specific examples.
Example 1:
the main raw materials and the process of the invention are as follows:
1. microwave calcination of bentonite, linear temperature (material a).
2. Betaine and noble metal nano silver are loaded on platinum oxide to synthesize a surface catalyst (material B).
3. B is loaded on the surface A.
Appearance: 1 micron grey powder.
Example 2:
the deodorant of the invention is used for deodorization:
reaction with formaldehyde (HCHO): R-NH2+HCHO→R-NHCH2OH→R-N＝CH2
With ammonia (NH)3) The reaction of (1): R-COOH + NH3→R-COONH4
With trimethylamine [ (CH)3)]3Reaction of N: R-COOH + (CH)3)3N→R-COONH(CH3)3
The deodorizing method of the present invention is different from a physical adsorption deodorizing and aromatic substance masking method in that malodorous components are treated as odorless substances according to chemical reactions, so that its deodorizing action is quick-acting and has a long-lasting effect.
The above description is only for the purpose of illustrating the present invention and the appended claims are not to be construed as limiting the scope of the invention, which is intended to cover all modifications, equivalents and improvements that are within the spirit and scope of the invention as defined by the appended claims.
Claims (10)
1. A chemical reaction type deodorant containing betaine modified bentonite is characterized by comprising 75-85 parts of bentonite and 10-20 parts of a composite catalyst;
the composite catalyst consists of betaine, nano silver and platinum oxide.
2. A method for preparing a deodorant for chemical reaction containing betaine-modified bentonite according to any one of claim 1, wherein the method for preparing a deodorant for chemical reaction containing betaine-modified bentonite comprises:
step one, calcining bentonite by microwave at a linear temperature to obtain a material A;
compounding betaine and metal to prepare a composite catalyst B;
and step three, loading the composite catalyst B on the surface of the material A to obtain the betaine-modified bentonite-containing chemical reaction type deodorant.
3. The method for preparing a chemical reaction type deodorant containing betaine-modified bentonite according to claim 2, wherein the microwave calcination of bentonite at a linear temperature to obtain the material a comprises:
and (3) carrying out vacuum impregnation treatment on the bentonite by adopting an acidic potassium permanganate solution to obtain pretreated bentonite, and calcining the pretreated bentonite at a linear temperature to obtain the material A.
4. The method for preparing a chemical reaction type deodorant containing betaine-modified bentonite according to claim 2, wherein the step of preparing the composite catalyst B by compounding betaine and a metal comprises: the betaine and the nano silver are loaded on the platinum oxide, and the surface catalyst B can be synthesized.
5. The method for preparing a chemical reaction type deodorant containing betaine-modified bentonite according to claim 4, wherein the loading of betaine and nano silver on platinum oxide comprises:
mixing the mixed solution of nano silver and platinum oxide with betaine solution to carry out a first reaction to obtain suspension;
adding sodium borohydride into the obtained suspension for a second reaction, and separating and vacuum-drying a reaction product to obtain a catalyst precursor;
and roasting the obtained catalyst precursor in an inert atmosphere to obtain the surface catalyst B.
6. The method for preparing a deodorant for chemical reaction containing betaine-modified bentonite according to claim 2, wherein the step of supporting the composite catalyst B on the surface of the material a to obtain the deodorant for chemical reaction containing betaine-modified bentonite comprises:
crushing the material A, sieving the crushed material A by a 120-mesh sieve to obtain powder, adding water into the obtained powder, stirring, and standing to obtain a suspension;
adding the catalyst mixed solution into the suspension at 30-35 ℃, stirring for 1-2h, performing precipitation separation, and drying at 90-95 ℃;
placing the dried product in a 800W microwave oven, and performing microwave irradiation for 8-10 min;
and adding the product subjected to microwave irradiation into deionized water, stirring, carrying out precipitation separation, drying at the temperature of 120-.
7. The method for preparing a deodorant for chemical reactions containing betaine-modified bentonite according to claim 2, wherein the deodorant for chemical reactions containing betaine-modified bentonite is gray powder.
8. Use of the betaine-modified bentonite-containing deodorant of the chemical reaction type as defined in any one of claims 1 to 2 in resin production and tire casting.
9. Use of the betaine-modified bentonite-containing chemical reaction type deodorant according to any one of claims 1 to 2 for decoration deodorization, pet animal house deodorization, kitchen deodorization, and drain deodorization.
10. Use of the betaine-modified bentonite-containing chemical reaction type deodorant according to any one of claims 1 to 2 in food processing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110735406.4A CN113546680A (en) | 2021-06-30 | 2021-06-30 | Chemical reaction type deodorant containing betaine modified bentonite and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110735406.4A CN113546680A (en) | 2021-06-30 | 2021-06-30 | Chemical reaction type deodorant containing betaine modified bentonite and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113546680A true CN113546680A (en) | 2021-10-26 |
Family
ID=78131113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110735406.4A Pending CN113546680A (en) | 2021-06-30 | 2021-06-30 | Chemical reaction type deodorant containing betaine modified bentonite and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113546680A (en) |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01190362A (en) * | 1988-01-22 | 1989-07-31 | Mitsubishi Heavy Ind Ltd | Deodorant |
| JPH09299460A (en) * | 1996-05-14 | 1997-11-25 | Catalysts & Chem Ind Co Ltd | Deodorant, precursor substance and manufacture of the same |
| JPH1157470A (en) * | 1997-08-20 | 1999-03-02 | Daikin Ind Ltd | Air purification catalyst structure |
| CN1438064A (en) * | 2003-03-14 | 2003-08-27 | 王金锡 | New-type deodouring catalyst and preparation method |
| JP2004148173A (en) * | 2002-10-29 | 2004-05-27 | Toyota Central Res & Dev Lab Inc | Toxic substance purification catalyst and method for producing the same |
| CN103816859A (en) * | 2014-02-26 | 2014-05-28 | 江苏神力特生物科技有限公司 | Preparation method of betaine-modified attapulgite |
| CN105664859A (en) * | 2016-02-17 | 2016-06-15 | 济南大学 | Preparation method of lauramidopropyl betaine modified sand |
| CN107602509A (en) * | 2017-08-02 | 2018-01-19 | 广东椰氏实业股份有限公司 | A kind of betaine surfactant and its synthetic method and application |
| CN109415857A (en) * | 2016-06-29 | 2019-03-01 | 王子控股株式会社 | Absorbing sheet |
| CN109499360A (en) * | 2018-12-27 | 2019-03-22 | 佛山市顺德区阿波罗环保器材有限公司 | A kind of deodorizing module and preparation method thereof containing composite coating |
| CN110156440A (en) * | 2019-05-28 | 2019-08-23 | 西南大学 | A modification method of sludge ceramsite that enhances the performance of adsorbing formaldehyde |
| CN111871200A (en) * | 2020-08-10 | 2020-11-03 | 桂林新竹大自然生物材料有限公司 | Silver series inorganic aldehyde gas purifying agent |
| KR20210026012A (en) * | 2019-08-29 | 2021-03-10 | 박새롬 | Deodorant particles, deodorant composition comprising the same and manufacturing method thereof |
-
2021
- 2021-06-30 CN CN202110735406.4A patent/CN113546680A/en active Pending
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01190362A (en) * | 1988-01-22 | 1989-07-31 | Mitsubishi Heavy Ind Ltd | Deodorant |
| JPH09299460A (en) * | 1996-05-14 | 1997-11-25 | Catalysts & Chem Ind Co Ltd | Deodorant, precursor substance and manufacture of the same |
| JPH1157470A (en) * | 1997-08-20 | 1999-03-02 | Daikin Ind Ltd | Air purification catalyst structure |
| JP2004148173A (en) * | 2002-10-29 | 2004-05-27 | Toyota Central Res & Dev Lab Inc | Toxic substance purification catalyst and method for producing the same |
| CN1438064A (en) * | 2003-03-14 | 2003-08-27 | 王金锡 | New-type deodouring catalyst and preparation method |
| CN103816859A (en) * | 2014-02-26 | 2014-05-28 | 江苏神力特生物科技有限公司 | Preparation method of betaine-modified attapulgite |
| CN105664859A (en) * | 2016-02-17 | 2016-06-15 | 济南大学 | Preparation method of lauramidopropyl betaine modified sand |
| CN109415857A (en) * | 2016-06-29 | 2019-03-01 | 王子控股株式会社 | Absorbing sheet |
| CN107602509A (en) * | 2017-08-02 | 2018-01-19 | 广东椰氏实业股份有限公司 | A kind of betaine surfactant and its synthetic method and application |
| CN109499360A (en) * | 2018-12-27 | 2019-03-22 | 佛山市顺德区阿波罗环保器材有限公司 | A kind of deodorizing module and preparation method thereof containing composite coating |
| CN110156440A (en) * | 2019-05-28 | 2019-08-23 | 西南大学 | A modification method of sludge ceramsite that enhances the performance of adsorbing formaldehyde |
| KR20210026012A (en) * | 2019-08-29 | 2021-03-10 | 박새롬 | Deodorant particles, deodorant composition comprising the same and manufacturing method thereof |
| CN111871200A (en) * | 2020-08-10 | 2020-11-03 | 桂林新竹大自然生物材料有限公司 | Silver series inorganic aldehyde gas purifying agent |
Non-Patent Citations (4)
| Title |
|---|
| M.F. SANTOS ET AL.: "Bactericidal properties of bentonite treated with Ag+ and acid", 《INTERNATIONAL JOURNAL OF MINERAL PROCESSING》 * |
| 任爽等: "两性修饰磁性膨润土的表征及其对苯酚的吸附", 《农业环境科学学报》 * |
| 余璐等: "CTMAB对BS-12修饰膨润土的复配修饰模式", 《土壤学报》 * |
| 贾丽华等, 哈尔滨工程大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106563417B (en) | A kind of Biosorbent for heavy metals and preparation method thereof | |
| CN106881059B (en) | A kind of preparation method of iron/carbon composite | |
| Zazo et al. | Highly stable Fe on activated carbon catalysts for CWPO upon FeCl3 activation of lignin from black liquors | |
| CN104667860B (en) | Adsorbent and preparation method thereof | |
| CN113828332B (en) | A cobalt sulfide supported biochar catalyst and its preparation method and application | |
| CN109569729B (en) | A supported bimetallic advanced oxidation catalyst, preparation method and analysis method for the contribution of each strengthening function | |
| Fukuoka et al. | Preparation, XAFS characterization, and catalysis of platinum nanowires and nanoparticles in mesoporous silica FSM-16 | |
| CN111215123B (en) | Can simultaneously remove COS and H in garbage gasification2S catalyst and preparation method thereof | |
| CN113546680A (en) | Chemical reaction type deodorant containing betaine modified bentonite and preparation method thereof | |
| Amiri et al. | Combined experimental and computational study on Ag-NPs immobilized on rod-like hydroxyapatite for promoting Hantzsch reaction | |
| Fernández-Velayos et al. | Highly efficient Cu2O@ CuxFeyO4 nanohybrid catalyst for the degradation of emerging pollutants | |
| KR20190138024A (en) | Deodorant and Method for Producing the Same | |
| Zhang et al. | Transition-state defect structure: A new strategy for TiO2-based porous materials to enhance photodegradation of pollutants | |
| CN107320757B (en) | Deodorant based on resource utilization | |
| Ramírez‐Hernández et al. | Electrocatalytic Degradation of Tetracycline by Cu‐PANI‐SBA‐15 on Nickel Foam via Peroxymonosulfate‐Based Advanced Oxidation Process | |
| CN113877602A (en) | Household deodorizing material for old people and preparation method thereof | |
| KR102289660B1 (en) | Composition for removing odor and method of preparing same | |
| CN113134347A (en) | Preparation method and application of heteroatom porous carbon | |
| CN115228490B (en) | Iron phosphide/iron single-atom type Fenton photocatalyst, and preparation method and application thereof | |
| Jiang et al. | Increased oxygen vacancies and Sc doping in ZnO promote bacterial disinfection and methyl orange degradation | |
| Zhang et al. | Co nanoparticle decorated and S, N doped porous carbon synthetized by in situ doping strategy for hydrogenation of 4-nitrophenol | |
| KR101036931B1 (en) | Manufacturing method of deodorant for removing odor derived from polymer material and deodorant obtained according to the manufacturing method | |
| KR20150087095A (en) | Photocatalyst composite for odor deodorizing, photocatalyst fixing unit including the same and preparing method of the same, and non-contact odor deodorizing system including the same | |
| KR100457699B1 (en) | Deodorant and method for making the same using multiporous adsorbent | |
| JP2012245206A (en) | Deodorizing material and method for manufacturing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20211026 |
|
| RJ01 | Rejection of invention patent application after publication |