CN113530726A

CN113530726A - Nano noble metal far infrared energy conversion device capable of improving fuel energy efficiency for long term and manufacturing method thereof

Info

Publication number: CN113530726A
Application number: CN202010319461.0A
Authority: CN
Inventors: 张文礼
Original assignee: Individual
Current assignee: Individual
Priority date: 2020-04-21
Filing date: 2020-04-21
Publication date: 2021-10-22
Anticipated expiration: 2040-04-21
Also published as: CN113530726B

Abstract

A nano-precious metal far-infrared energy conversion device capable of long-term improvement of fuel energy efficiency and a manufacturing method thereof. It smoothly penetrates into the surface of an energy conversion material, so that after the energy conversion material is completely dried by high temperature treatment, a layer of composite film can be formed on its surface, so that the energy conversion device formed by the energy conversion material can be installed in each When the fuel supply pipeline of the internal combustion engine is used, the far-infrared rays generated by the composite film can carry out high-efficiency energy conversion treatment for the fuel flowing through it for a long time, and the fuel molecules of long-chain hydrocarbons to be cracked into short chains. After the fuel molecules are put into the combustion chambers of the internal combustion engines in sequence, they are burned so that the fuel can exert the best combustion efficiency.

Description

Nano noble metal far infrared energy conversion device capable of improving fuel energy efficiency for long term and manufacturing method thereof

Technical Field

The invention relates to an energy conversion device, in particular to a device which utilizes the permeation effect generated by the temperature difference effect to lead the aqueous solution containing noble metal nano particles and far infrared particles to smoothly permeate into holes which are densely distributed on an energy conversion device made of porous materials, so that after the energy conversion device is completely dried by high-temperature treatment, a layer of composite film containing noble metal nano particles and far infrared particles can be formed on the surface and the inner wall of the holes, and when the energy conversion device is arranged on fuel supply pipelines of various internal combustion engines, the far infrared rays generated by the composite film can carry out high-efficiency energy conversion treatment for a long time on the fuel (no matter liquid or gaseous fuel) flowing through the composite film; in addition, the composite film can be additionally provided with nano particles such as cerium (Ce), ruthenium (Ru) and/or rhodium (Rh) in or outside the composite film, so that the nano platinum particles always have clean surfaces through the strong oxygen absorption effect generated by the nano platinum particles, and the energy conversion material can excite the fuel flowing through the energy conversion material to have the maximum energy conversion efficiency.

Background

Currently, the combustion exhaust gas discharged from various vehicles and various industries has undoubtedly proved to be a main and important cause of air pollution. Through detailed investigation and research analysis, the exhaust gas generated by various vehicles and industries mainly comes from the combustion exhaust gas (55%) discharged from the exhaust pipe of various internal combustion engines, the oil gas (25%) leaked from the crank cases of various internal combustion engines and the oil gas (20%) leaked from the oil tank, and the combustion exhaust gas and the leaked oil gas contain pollutants harmful to human bodies, such as: sulfur dioxide (SO)₂) Carbon monoxide (CO), Hydrocarbons (HC), Nitrogen Oxides (NO)_x) Etc.; among them, since petroleum fuels (gasoline, diesel oil, kerosene, etc.) and coal, which are generally used, contain a small amount of sulfur (0.5% to 5%), when these fuels are burned, sulfur (S) therein is mixed with oxygen (O) in the air₂) A chemical reaction takes place, and sulfur dioxide (SO) is produced₂). Taking coal with 5% sulfur as an example, a one thousand megawatt thermal power plant will produce up to six hundred tons of sulfur dioxide per day. Other pollution sources of sulfur dioxide include metal refineries, sulfuric acid plants, petroleum refineries, etc. of sulfur ores, SO that sulfur dioxide is very commonly and abundantly present in various vehicles burning fossil fuels or coals or various industrial waste gases, and is finally discharged directly into the air, whereby sulfur dioxide (SO) is generated₂) Is called "" primary contaminant ""; in addition, there is another air pollutant, which is generated by the chemical reaction of the primary pollutant in the air, and is called "secondary pollutant", wherein sulfur trioxide (SO)₃) A typical example of "secondary pollutants" in industrial air pollution, which is sulfur dioxide (SO)₂) Under the irradiation of sunlight, with oxygen O in the air₂The following chemical reactions were carried out:

2SO₂+O₂→2SO₃

in fact, sulfur trioxide (SO)₃) The life cycle in the air is quite short, and the water molecules in the air are very easy to react chemically to generate sulfuric acid molecules; on the other hand, sulfuric acid also reacts chemically with ammonia in the air to produce ammonium sulfate (NH)₄)₂SO₄And thus sulfuric acid and ammonium sulfate are also secondary pollutants of industrial pollution.

Urban light smoke is particularly severe on warm, dry and sunny days because its primary pollutants are primarily Nitric Oxide (NO), which is the nitrogen and oxygen in the air, produced by the following chemical reactions at the high temperatures of various urban vehicle engines (i.e., the aforementioned internal combustion engines):

N₂+O₂+ Hot → 2NO

In fact, this nitric oxide generation process is the same as the nitric oxide process that occurs in lightning. Other primary pollutants of "light smoke" include Hydrocarbons (HC) and carbon monoxide (CO) produced by gasoline evaporation. According to research, a general internal combustion engine often generates about 230 g of carbon monoxide pollutants per 1 l of gasoline burned due to poor combustion efficiency of fuel, and in addition, although nitrogen monoxide (NO) is a colorless gas, it slowly chemically reacts with oxygen in the air to generate yellowish brown nitrogen dioxide (NO) when it is discharged into the air along with vehicle exhaust gas₂) (ii) a Then, under the irradiation of ultraviolet rays in sunlight, nitrogen dioxide (NO)₂) It is also cleaved to yield Nitric Oxide (NO) and atomic oxygen O by the following photochemical reaction:

NO₂+ UV → NO + O

At this time, the chemical reaction capability phase due to atomic oxygen OWhen strong, it is very easy to react with oxygen molecule O in air₂The following chemical action takes place to generate ozone (O)₃)：

O*+O₂+M→O₃+M*；

Wherein, M can be nitrogen molecule, oxygen molecule or solid particle, which is used to absorb the heat released in the process of generating ozone molecule; ozone (O)₃) Is a very pungent molecule whose presence can be easily identified by our nose if there is one ozone molecule per hundred million gas molecules in the air. The formation of "light smoke" also causes different pollutants to be hidden in "light smoke", wherein, referring to fig. 1, the periods of highest concentration occurring in each working day are different from each other, and the concentration of nitric oxide in the air will reach the maximum value in the working period of seven am; subsequently, the nitric oxide will decrease due to the gradual interaction with oxygen, and instead the concentration of nitrogen dioxide will gradually increase until around nine am, the maximum concentration will be reached; on a sunny day, ultraviolet rays in sunlight can continuously catalyze the cracking reaction of nitrogen dioxide, so that the concentration of ozone in the air reaches the maximum value in the noon.

On the other hand, if the nitrogen dioxide does not undergo the photochemical reaction, the following chemical reaction with water molecules in the air occurs to produce nitric acid (HNO)₃) And nitrous acid (HNO)₂)：

2NO₂+H₂O→HNO₃+HNO₂

The chemical reaction also helps the condensation of moisture in the air. However, because nitric acid and nitrous acid are extremely acidic, inhalation of air containing such liquid droplets can cause considerable harm to the human body. Furthermore, Hydrocarbon (HC) emitted from gasoline volatilization or combustion will also be mixed with ozone (O)₃) Or oxygen (O) in atomic form, to produce aldehyde compounds (RCHO) or ketone compounds (RCOR):

HC+O*→HCO

HC+O₃→HCO₃

HCO+O₂→HCO₃

HCO₃+ HC → RCHO or RCOR;

wherein HC is a hydrocarbon, R represents an alkyl group, RCHO is an aldehyde compound, and RCOR is a ketone compound. In addition, in Nitrogen Oxide (NO) and ozone (O)₃) In the presence of a Hydrocarbon (HCO)₃) The following chemical reactions also occur to produce peroxyacyl nitrates (peroxicy nitrates PANs) and other products:

HCO₃+NO→HCO₂+NO₂

HCO₃+O₂→O₃+HCO₂

HCO₃+NO₂→RCO₃NO₂(i.e., PANs) + other products

These nitrogen dioxide (NO)₂) Ozone (O)₃) Nitric acid (HNO)₃) Nitrous acid (HNO)₂) Aldehydes (RCHO), ketones (RCOR), peroxyacyl nitrates (PANs) and various other organic compounds that are formed therewith are secondary pollutants of the "haze".

When the exhaust gas and the oil-gas leakage are inhaled into the body, not only can the light people hurt the organs and nerves of the people, but also the serious people may cause poisoning and death, so in order to avoid the harm of the exhaust gas and the oil-gas leakage to the human body, the relevant companies and the governing organs of all countries in the world are not involved in the research, how to perform the corresponding oxidation and reduction treatment on the exhaust gas and the oil-gas leakage to change the exhaust gas and the oil-gas leakage into the nontoxic gas, and then the nontoxic gas is safely exhausted into the atmosphere. Particularly, in recent thirty years, under the strong pressure of increasing consciousness of environmental protection, energy saving and carbon reduction, all countries in the world do not aim at various air pollution causes derived from various internal combustion engines (no matter the internal combustion engines burning liquid or gaseous fuel) to make extensive research and analysis, and the following important causes of air pollution are summarized according to the research and analysis results:

1. fuel (whether liquid or gaseous fuel) air-to-air ratio:generally, when the fuel-air mixture ratio used in each internal combustion engine is lean as compared with the theoretical fuel-air mixture ratio, the CO and HC discharged therefrom are reduced, but NO is discharged therefrom_xWill increase, when more diluted, NO_xAlso decrease, but easily extinguish to increase HC; conversely, when the fuel-air mixture ratio used in each of the internal combustion engines is rich in the theoretical fuel-air mixture ratio, NO is generated_xWill decrease, but CO, HC will increase;

2. ignition period: when the ignition timing is retarded, the temperature of each combustion chamber of the internal combustion engine is lowered to make NO_xThe obvious reduction, the slow burning result also can make the exhaust system maintain the high temperature state, promote the oxidation, thus make HC reduce.

3. Atmospheric conditions: the increase in atmospheric humidity and decrease in oxygen concentration lower the combustion temperature and reduce NO_xOccurs. Atmospheric pressure affects intake pressure, engine horsepower, but does not directly affect combustion temperature, but only indirectly affects fuel-air mixture ratio.

4. Load and revolution: when the load increases, the intake pressure rises, with the result that the combustion temperature rises, and NO is caused to flow_xThe concentration is increased. At the same load, the discharge amount increases as the rotation speed increases.

5. Fuel quality: the composition of the fuel has little influence on CO, the hydrogen-carbon ratio of the common fuel is small, and the combustion temperature is high for olefinic and aromatic fuels NO_xThe emissions are high and the emission of HC is also affected by the fuel quality.

6. The main design of each of these internal combustion engines: such as: the stroke volume, stroke/internal diameter ratio, surface area/volume ratio, combustion chamber shape, spark plug position, compression ratio, intake ports, intake valve configuration, valve timing, etc. have a significant impact on the composition of the exhaust pollutants.

Based on the important reasons for air pollution caused by the various internal combustion engines, the relevant industries in all countries around the world take different countermeasures for reducing the emission of the polluted gas according to the design of various internal combustion engines; some of them are used to reduce CO and HC, and some are used to reduce NO_xAnd some can be reduced at the same timeCO, HC and NO_xThe content of (a). Now, in order to make sure that the various air pollution reducing devices and designs which are widely applied to various internal combustion engines at present are briefly described as follows:

1. an automatic temperature-regulating air filter is additionally arranged: because the change of the temperature in the combustion chamber of each internal combustion engine changes the atomization state of the fuel, the operation performance of each internal combustion engine is poor, and the concentration of harmful substances such as CO, HC and the like in the discharged exhaust gas is increased; therefore, the temperature of the sucked air can be always maintained at a proper temperature (such as 40 ℃) by additionally arranging the automatic temperature-adjusting air filter on each internal-combustion engine, the running performance during warm-up (warm up) can be effectively improved, the atomization state of the fuel can be changed along with the change of the temperature in the combustion chamber of each internal-combustion engine, and the fuel atomization can be promoted, so that the stable fuel-air mixing ratio is maintained, each internal-combustion engine can be always operated at the optimal state, and harmful substances such as CO, HC and the like in the exhaust gas can be greatly reduced;

2. improvement of intake manifold and intake port configuration: the design improvement is carried out aiming at the inner diameters and the internal shapes of the steam inlet manifold and the air inlet of each internal combustion engine, so that the steam inlet manifold and the air inlet after the design improvement can ensure that the fuel mixture is uniformly distributed to each combustion chamber (namely, a cylinder), thereby fully combusting the fuel to generate the optimal combustion efficiency and effectively reducing the contents of CO and HC in the waste gas;

3. the improvement of the carburetor configuration: the carburetor structure of each internal combustion engine is improved, so that the precision of the improved carburetor and each oil nozzle in the carburetor is increased, the efficiency of a choke valve control system, an idle speed compensation device, an idle speed fuel cut-off device and the like can be effectively improved, fuel mixed gas can be uniformly distributed to each combustion chamber, fuel can be fully combusted, the optimal combustion efficiency is generated, and the content of CO and HC in waste gas is effectively reduced;

4. improvement of carburetor control device during deceleration: the design improvement is carried out on the devices (such as a throttle valve opener, a buffer and the like) which discharge the waste gas during the deceleration in the carburetor of each internal combustion engine, so that the carburetor after the design improvement can be effective during the decelerationThe emission quantity of the exhaust gas is reduced, thereby greatly reducing CO, HC and NO in the exhaust gas_xAnd (4) content.

5. Improvement of combustion chamber configuration: the design improvement is carried out aiming at the configuration of each combustion chamber of the internal combustion engine, so that the designed and improved combustion chamber can fully combust fuel to generate the optimal combustion efficiency, thereby greatly reducing CO, HC and NO in the exhaust gas_xContent (c);

6. using a lean fuel mixture: although the most fundamental way to reduce CO and HC is to use a relatively lean fuel/air mixture, if the fuel/air mixture is too lean, the fuel/air mixture is likely to be difficult to combust, and the speed after combustion tends to be slow; in view of the above, the industry has developed and designed a new invention technology named CVCC (compound wind controlled combustion), in which CVCC ignites with a richer fuel mixture and then combusts with a leaner fuel mixture;

7. addition of Exhaust Gas Recirculation (EGR): according to the research, the reduction of the maximum combustion temperature in the combustion chamber can reduce NO_xTherefore, the maximum combustion temperature can be lowered by taking out a part of the exhaust gas from the exhaust manifold and returning it to the intake manifold, thereby greatly reducing NO_xGeneration of (1);

8. various devices capable of increasing the combustion speed are additionally arranged: such as: the auxiliary inlet valve, the projecting wall in the combustion chamber and two spark plugs are added to increase the combustion speed, so that the fuel can be fully combusted to generate the best combustion efficiency, thereby greatly reducing CO, HC and NO in the waste gas_xContent (c);

9. the secondary air supply device is added: the secondary air supply device makes CO and HC discharged from the combustion chamber obtain sufficient oxygen in the exhaust manifold and the catalytic converter, so as to perform oxidation reaction, so that CO and HC can be completely oxidized into CO₂And H₂O, thereby greatly reducing CO, HC and NO_xA discharge amount;

10. improvement of ignition device: in order to ensure that the ignition system has more reliable ignition performance, the industry also makes many improvements on the ignition device so as to lead the spark plug to emit stronger spark by improving high voltage; among them, the most improvement is made to increase the energy of the ignition coil, others are: the improved designs such as changing the shape of the spark plug, increasing the electrode gap, improving the wiring connection and high voltage wires are not exhaustive; recently, the most widely used users are electronic ignition devices, microcomputer ignition devices and direct ignition devices;

11. improvement and addition of oxidation catalyst converter: the oxidation catalyst can oxidize CO and HC in the exhaust gas into harmless CO₂And steam H₂O, and the catalyst only promotes the oxidation and has no change per se;

12. improvement and addition of the three-way catalyst converter: the three-way catalytic converter can oxidize the toxic components CO and HC in the exhaust gas into CO when the exhaust gas discharged by each internal combustion engine passes through the three-way catalytic converter₂And H₂O, and NO_xReduction to N₂. Three-way catalyst for CO, HC and NO in narrow region near theoretical fuel-air mixture ratio_xThe three pollution components have high purification effect, thereby greatly reducing CO, HC and NO_xThe discharge amount of (4);

13. adding a fuel injection device: various internal combustion engines using fuel injection supply devices can strictly and accurately control the injection quantity, the injection time and the fuel-air mixing ratio of fuel, so that the generation of CO, HC and NOx can be effectively reduced at the same time;

14. a reduction device for leaked oil gas is additionally arranged; the leaked and volatilized oil gas can be recovered from the crank case and the oil tank by additionally arranging the reduction device, and the recovered oil gas is reversely thrown into the air inlet system to be completely combusted, so that the leaked and volatilized oil gas cannot be discharged to the outside of various internal combustion engines.

In fact, in spite of the above-mentioned improvement design of the internal combustion engines in the industry, until now, the harmful pollutants discharged from the internal combustion engines still continuously poisons the vulnerable ecological environment, so that the ecological environment gradually deteriorates to the extent that it is difficult to recover to normal, and the extreme climate has also seriously affected the normal life of human beings with the occurrence of hole-breaking and greenhouse effect in the ozone layer. In order to solve the problem of air pollution caused by various internal combustion engines, the most fundamental method is to reduce the use of various internal combustion engines, and to effectively improve the energy efficiency of the fuel, so that the fuel can not only be optimally combusted during the combustion process to generate the maximum power, but also harmful pollutants can be eliminated during the optimal combustion process without remaining in the discharged exhaust gas. Therefore, the usage amount of petrochemical fuel can be reduced effectively, the aim of low-pollution or zero-pollution exhaust emission can be effectively achieved, and only then, a clean and comfortable sustainable living space can be provided for the subsequent generation.

Therefore, how to utilize a novel device which has a simple structure and is easy to be implemented on various internal combustion engines (no matter liquid or gaseous fuel) used in the market at present, so that the novel device can perform the conversion of improving the energy efficiency on the fuel for a long time before the fuel is supplied to each combustion chamber of the internal combustion engine, so as to effectively improve the combustion efficiency of the fuel, thereby the fuel can be fully combusted after being input into each combustion chamber of the internal combustion engine, not only can generate the maximum power, but also can burn up the harmful pollutants contained in the fuel, and cannot remain in the exhaust gas discharged by the fuel, thereby ensuring that the new and old vehicles or the new and old industries can rapidly and effectively reduce the usage amount of petrochemical fuel and the pollution problem caused by the fossil fuel with the improvement cost which is easy to bear, particularly realizing the optimal effects of energy saving, carbon reduction and air pollution prevention, and the like, the present invention is an important issue to be solved in the countries and related industries in the world, and is also an important issue to be discussed in detail later.

Disclosure of Invention

In view of the foregoingThe inventor of the present invention has made a long-term research and experiment to develop and design an energy conversion device of nano noble metal far infrared rays and a method for manufacturing the same, which can improve the fuel energy efficiency for a long time, so as to utilize the noble metal nanoparticles attached to the surface of the energy conversion device as an efficient energy conversion material to absorb surrounding light energy and heat energy to effectively excite the far infrared rays to convert the light energy and heat energy into far infrared rays and return the far infrared rays to the fuel (no matter liquid or gaseous fuel) to be supplied to a combustion chamber of an internal combustion engine, thereby making the original long-chain hydrocarbon fuel molecules, can be cracked into short chain hydrocarbon fuel molecules due to molecular oscillation caused by far infrared ray to effectively improve the combustion efficiency, so that the fuel can be fully combusted after being input into each combustion chamber of the internal combustion engine, thereby not only generating maximum power, but also leading the harmful pollutants contained in the fuel to be completely lost in the full combustion process and not remaining in the discharged waste gas (CO)₂) And wastewater (H)₂O) to ensure that both new and old vehicles and new and old industries can reduce the cost with easy burden, specifically realize the best effects of energy saving, carbon reduction and air pollution prevention, and quickly and effectively reduce the usage amount of petrochemical fuel and the air pollution problem caused by the petrochemical fuel.

An object of the present invention is to provide a method for manufacturing a nano noble metal far infrared energy conversion device capable of improving the fuel energy efficiency for a long time, which utilizes the permeation effect generated by the temperature difference effect to enable a first aqueous solution containing nano noble metal particles, far infrared particles and medium particles to smoothly permeate into the surface and pores of an energy conversion material made of a porous material, so that a layer of composite film containing nano platinum particles and far infrared particles can be formed on the surface and in the pores of the energy conversion material after the energy conversion material is completely dried by high temperature treatment, and the far infrared rays generated by the composite film can convect the fuel passing through the energy conversion device when the energy conversion device formed by the energy conversion material is installed on the fuel supply pipeline of various internal combustion engines, so as to perform the conversion treatment for improving the energy efficiency for a long time, after the fuel molecules of long chain hydrocarbon are cracked into fuel molecules of short chain hydrocarbon by the far infrared ray generated by the composite film, the fuel is put into the combustion chambers of the internal combustion engines in sequence for combustion. Therefore, the fuel can exert the best combustion efficiency, not only can enable each internal combustion engine to generate the maximum power, but also can enable various pollutants contained in the fuel to disappear due to the best combustion efficiency and not to remain in exhaust gas discharged by each internal combustion engine, thereby ensuring that new and old vehicles or new and old industries can improve cost with easy burden, particularly realizing the best effects of saving energy, reducing carbon and preventing and treating empty pollution, and quickly and effectively reducing the using amount of petrochemical fuel and the problem of the empty pollution caused by the petrochemical fuel.

Another objective of the present invention is to provide the method further comprising utilizing the permeation effect generated by the temperature difference effect to make a second aqueous solution containing nano gold particles and medium particles smoothly permeate into the surface and pores of the energy conversion material, so that after the energy conversion material is completely dried by high temperature treatment, a composite film containing nano platinum particles, nano gold particles and far infrared particles is formed on the surface and pores of the energy conversion material, so that when the energy conversion device is installed in the fuel supply pipeline of various internal combustion engines, the far infrared generated by the composite film can not only perform the conversion treatment for improving the energy efficiency for a long time on the fuel (no matter liquid or gaseous fuel) flowing through the composite film, so that the fuel molecules in the form of long-chain hydrocarbons are cracked into fuel molecules in the form of short-chain hydrocarbons, but also perform the conversion treatment for increasing the oxygen content of the short-chain fuel molecules for a long time, the fuel can exert better combustion efficiency, not only enables each internal combustion engine to generate maximum power, but also enables various pollutants contained in the fuel to disappear due to the better combustion efficiency and not to remain in exhaust gas discharged by each internal combustion engine, thereby ensuring that new and old vehicles or new and old industries can improve cost with the most easy burden, particularly realizing the best effects of saving energy and reducing carbon and preventing and treating empty pollution, and quickly and effectively reducing the using amount of petrochemical fuel and the problem of the empty pollution caused by the petrochemical fuel. In addition, the method can effectively reduce the usage amount of petrochemical fuel and thoroughly realize the aim of low-pollution or zero-pollution exhaust emission, thereby really providing a clean and comfortable sustainable living space and environment for the subsequent generation.

Another object of the present invention is to provide an energy conversion device for nano noble metal far infrared rays capable of improving the fuel energy efficiency for a long time, the energy conversion device is composed of at least one energy conversion material, a composite film containing nano noble metal particles and far infrared particles is formed on the surface of each energy conversion material, wherein the nano noble metal particles can excite the far infrared particles to generate far infrared rays, and at least one fuel channel is formed in the energy conversion device along the axial direction; thus, when the energy conversion devices are respectively installed on the fuel supply pipeline of an internal combustion engine, the fuel conveyed in the fuel supply pipeline can smoothly pass through each fuel channel, and the composite film applies the conversion treatment of the lifting energy to the fuel, after the fuel molecules of long-chain hydrocarbons are cracked into fuel molecules of short-chain hydrocarbons due to the far infrared rays generated by the composite film, the fuel molecules are sequentially thrown into the combustion chambers of the internal combustion engines for combustion, so that the fuel not only can exert the optimal combustion efficiency and enable each internal combustion engine to generate the maximum power, but also various pollutants contained in the fuel can be completely lost due to the optimal combustion efficiency and can not remain in the exhaust gas discharged by each internal combustion engine, thereby ensuring that the old and new vehicles or the old and new industries can improve the cost with the most easy burden, the best effects of energy saving, carbon reduction and air pollution prevention are realized, so that the consumption of petrochemical fuel and the air pollution problem caused by the petrochemical fuel are quickly and effectively reduced.

Still another object of the present invention is to provide the composite thin film of the energy conversion device, further comprising nano gold particles; thus, after the energy conversion devices are respectively installed on the fuel supply pipeline of an internal combustion engine, the fuel conveyed in the fuel supply pipeline can smoothly pass through each fuel channel, so that the composite film not only can perform the conversion treatment for improving the energy efficiency for a long time on the fuel flowing through the composite film, but also can perform the conversion treatment for increasing the oxygen content on the short-chain fuel molecules for a long time besides cracking the long-chain hydrocarbon fuel molecules into short-chain hydrocarbon fuel molecules, so that the fuel can exert better combustion efficiency, not only can the internal combustion engine generate the maximum power, but also can various pollutants contained in the fuel disappear due to the better combustion efficiency and not remain in the exhaust gas discharged by each internal combustion engine, thereby ensuring that the new and old vehicles or the new and old industries can improve the cost with extremely easy burden, the best effects of energy saving, carbon reduction and air pollution prevention are realized, so that the consumption of petrochemical fuel and the air pollution problem caused by the petrochemical fuel are quickly and effectively reduced.

For the purpose of facilitating the examination of the objects, features and advantages of the present invention, further understanding and appreciation of the invention will be gained by reference to the following detailed description of the embodiments taken in conjunction with the accompanying drawings, in which:

drawings

FIG. 1 is a schematic view of the concentration distribution of urban light smoke at different times of the day;

figure 2 is a schematic longitudinal section through a fuel supply line with a screening device consisting of granular screening material mounted thereto;

figure 3 is a schematic longitudinal section of a screening device consisting of a cylindrical screening material mounted to a fuel supply line;

FIG. 4 is a flow chart illustrating a manufacturing method according to a first preferred embodiment of the present invention;

FIG. 5 is a schematic cross-sectional view of the composite material of nano platinum particles, nano gold particles and far infrared particles sintered and coated on the surface of the sieving material according to the present invention, and then the energy conversion process is performed;

FIG. 6 is a flow chart illustrating a manufacturing method according to a second preferred embodiment of the present invention;

FIG. 7 is a schematic view of an energy conversion material of a third embodiment of the present invention; and

fig. 8 is a schematic view of an energy conversion apparatus according to a third embodiment of the present invention.

Description of reference numerals:

energy conversion device … 1, 2, 8

Energy conversion materials … 10, 20, 70, 80A, 80B

Holes … 101, 201, 701

Fuel passages … 102, 202

Fuel supply line … 3

Fuel … 4

Media particles … 50

Far infrared particles … 51

Nano platinum particles … 52

Nanometer gold particle … 54

Light energy … 60

Thermal energy … 61

Far infrared ray … 62

Composite films … 702, 802, 803

Auxiliary film … 703

Steps … 401-404, 601-604

Detailed Description

In order that the objects, technical solutions and advantages of the present invention will become more apparent, the present invention will be further described in detail with reference to the accompanying drawings in conjunction with the following specific embodiments.

The far infrared ray raw materials generally used today can be broadly classified into two kinds, one is natural ore having far infrared ray radiation energy, such as: at present, the industry mainly grinds the far infrared raw materials into powder, mixes the powder into polymer fiber raw materials, and produces far infrared heat-storage and heat-preservation fiber products through the processes of spinning, weaving and the like; among them, the most remarkable is the far infrared products which can generate the most beneficial 4 μm to 14 μm wavelength (i.e. the breeding light) to the human body, especially, for the old living in cold climate, because the exercise amount is less and the physical strength is weaker, and many pathological changes are easy to generate, the heat preservation effect of the old can be effectively improved by using the far infrared heat-storage heat-preservation fiber product, absorbing the solar energy and the heat energy released by the human body, and then converting to emit the far infrared with the 4 μm to 14 μm wavelength, thereby achieving the functions and effects of promoting the blood circulation, activating the cells and promoting the health.

Generally speaking, water molecules in blood usually exist by mixing single water molecules and large water molecular groups, and when far infrared rays or electromagnetic waves with the wavelength of 4-14 μm) irradiate the large water molecular groups, the large water molecular groups are induced to vibrate and disperse, so that the large water molecular groups are cracked and refined into single water molecules; after the supply of far infrared ray energy is terminated, the refined single water molecules are gradually agglomerated and are recovered to form large water molecular groups, so that if the far infrared ray is continuously generated on the surface of a human body, the far infrared ray can continuously generate resonance action with water molecules, the large water molecular groups in water are continuously decomposed and refined, and the water molecules in the human body are further activated, thus effectively achieving the functions and effects of activating tissue cells in the human body, promoting blood circulation and improving metabolism.

There are many materials with far infrared radiation characteristics, and the materials (hereinafter referred to as "far infrared materials") capable of generating far infrared radiation substances are classified into the following five types according to their chemical structures:

(1) oxide: such as: alumina (Al)₂O₃) Zirconium oxide (ZrO)₂) Magnesium oxide (MgO), titanium oxide (TiO)₂) Silicon oxide (SiO)₂) Etc.;

(2) carbide: such as: zirconium carbide (ZrC), silicon carbide (SiC), boron carbide (B)₄C) Tantalum carbide (TaC);

(3) boride:such as: titanium boride (TiB)₂) Zirconium boride (ZrB)₂) Chromium boride (CrB)₂) Etc.;

(4) silicide: such as: titanium silicide (TiSi)₂) Molybdenum silicide (MoSi)₂) Tungsten silicide (WSi)₂) Etc.; and

(5) nitride: such as: silicon nitride (Si)₃N4), titanium nitride (TiN), and the like.

Among these far infrared ray materials, oxides and carbides are most commonly used in the industry, and therefore, although the following examples of the present invention are described by taking only the oxide-based far infrared ray material particles as examples, the present invention is not limited thereto, and carbide-based or other far infrared ray material particles may be substituted for the oxide-based far infrared ray material particles in other examples of the present invention according to actual needs, and thus, it is clarified that the far infrared ray particles mentioned in the following description and claims of the present invention refer to any one of the above-mentioned far infrared ray material particles or a mixture of the above-mentioned far infrared ray material particles.

Generally, Gasoline (the aforementioned fossil fuel) is a fraction of crude oil distillation products, and is a hydrocarbon compound mainly composed of five to ten carbons and having a boiling point of about fifteen to two hundred degrees celsius. Typically, the crude oil produced at an oil field contains only ten to forty percent (on average about twenty-seven percent) of gasoline. The structure of the hydrocarbon constituting gasoline includes paraffin hydrocarbons (i.e., chain hydrocarbons (parafins)), cyclic hydrocarbons (naphethenes), aromatic hydrocarbons (Aromatics), and the like; wherein paraffin hydrocarbon is used as the main component of the gasoline. Since the last century, the number of automobiles in all countries of the world is increased sharply, and the gasoline demand is increased day by day, and in order to increase the gasoline ratio of crude oil, the industry especially utilizes high temperature to crack the high molecular hydrocarbon into gasoline with smaller molecular weight; conversely, gasoline with larger molecules can be polymerized from gasoline with smaller molecules. Thus, the gasoline content of the crude oil can be adjusted to seventy percent in addition to gasoline originally existing in the crude oil and formed by cracking or polymerization. Then, in order to improve the quality of gasoline, the gasoline can have better combustion effect when being combusted in an engine. There have also been many oil refining processes developed in the industry, such as cyclizing long chain hydrocarbons to form cyclic hydrocarbons, and dehydrogenating (dehydrogenating) the cyclic hydrocarbons to aromatic hydrocarbons by three reactions:

cracking;

second, Polymerization (Polymerization); and

and thirdly, Dehydrogenation.

Because the gasoline formed by changing the molecular structure of hydrocarbon has higher Octane value (Octane Rating), the gasoline does not need to be added with tetraethane Lead (Pb (C)₂H₅)₄) To increase its octane number. Generally, when gasoline is ignited in a cylinder of an automobile engine (i.e., the internal combustion engine), firstly, the gasoline is detonated in each cylinder, and then, secondary explosion which damages the engine is caused, the secondary explosion can cause vibration of the engine, in order to reduce the impact shock of the engine, chemists try to add different chemical agents in a laboratory to observe the effect of the gasoline on the shock resistance, and the experimental result shows that tetraethane lead has a remarkable shock resistance effect, and only one to three cc of tetra-ethane lead is added into one gallon of gasoline, so that the impact shock of the engine can be reduced to a degree of almost completely disappearing; meanwhile, chemists have also observed the effect of different gasoline compositions on engine shock, and found that the minimum shock of gasoline consisting of pure isooctane is defined as the octane number of isooctane being one hundred, and n-heptane, which is enough to cause considerable shock, being zero, and the octane number is used as an index of octane number, and the shock caused by the combustion of all hydrocarbons or fuels is compared with the index determined by isooctane and n-heptane.

In 1951, Livingston found that all hydrocarbons containing Structural Group (Structural Group) have the property of inhibiting gasoline oxidation and reducing shock. Thus, hydrocarbons having a ring bond, such as: aromatic hydrocarbons and cyclic hydrocarbons are required to be burnt at a relatively high temperature to be oxidized because they contain branched isoalkanes; as for the paraffin hydrocarbons in the form of long chainIt will oxidize at low temperatures and cause subsequent combustion to produce a knock that damages the engine. Accordingly, increasing the number of branches of the chain hydrocarbon increases the oxidation temperature and octane number, such as C₈H₁₈The oxidation temperature and octane number of the hydrocarbon compound (2) are increased due to the increase of the number of the branches; as for the cyclic hydrocarbons and aromatic hydrocarbons, both have generally higher octane numbers than paraffins, because the cyclic and aromatic hydrocarbons have a cyclic structure and are denser in structure; on the other hand, if a long chain paraffin hydrocarbon is added to a cyclic hydrocarbon, the octane number is lowered.

Symmetric molecules in the cyclic hydrocarbon having a higher octane number than asymmetric molecules; therefore, in order to increase the octane number without adding additional additives to gasoline, the best method developed in the industry is to convert paraffins and cyclic hydrocarbons into aromatic hydrocarbons, which is also an important technology in the refining process. Further, the most useful hydrocarbon constituting gasoline is benzene, which is a main raw material for petrochemistry; many petroleum by-products are refined from benzene; the benzene itself can also be prepared from methylcyclopentane (methylcyclopentane), Cyclohexane (Cyclohexane), hexane, etc. under the catalysis of platinum as catalyst.

Platinum (Platinum) is a chemically very stable inert noble metal, which is silver in normal form, but if it is made into nano-scale particles, its color will be changed from silver to black, so it is called "Platinum black", at this time, due to size effect and large proportion of surface area effect, Platinum will be changed from inert substance to catalyst with excellent activity, which can generate approximate atomic property and has electric potential, and can reach antioxidation effect by means of transmitting electric potential to active oxygen, besides, because the reflectivity of nano Platinum particles to light energy and heat energy is very low, usually less than 1%, i.e. about several microns diameter can be completely extinguished, and becomes a high-efficiency energy conversion material.

Based on the above characteristics of nano platinum particles, far infrared particles and gasoline, the inventors thought and utilized the characteristics of nano platinum particles and far infrared particles to develop a nano noble metal far infrared energy conversion device capable of improving the fuel energy efficiency for a long time and a manufacturing method thereof, so that nano platinum particles can be firmly attached to far infrared particles to form a nano composite film, the nano composite film can efficiently absorb the heat energy or light energy emitted from the surroundings through nano platinum particles in the light or dark environment to excite the far infrared particles to generate far infrared rays for a long time, the nano composite film can be sintered and coated on the surface and holes of an energy conversion material or device made of porous material, when the energy conversion material or device is installed on the fuel supply pipeline of an internal combustion engine, the far infrared rays generated by the excitation are introduced into the fuel to be supplied to the combustion chambers of the respective internal combustion engines to perform the energy-increasing conversion process on the fuel, thereby effectively exciting the optimum energy efficiency of the fuel, enabling the fuel to be completely combusted in the combustion chambers of the respective internal combustion engines to generate the maximum power, and enabling the pollutants contained in the fuel to be completely eliminated by the high-efficiency combustion without remaining in the exhaust gas discharged from the respective internal combustion engines.

In addition, since other noble metals (such as palladium (Pd) and nickel (Ni)) become black (such as palladium black or nickel black) after being nanocrystallized, and have very low reflectivity to light energy and heat energy, the present invention is not limited to the nano platinum particles in the following embodiments of the present invention, and other nano noble metal particles can be used according to actual requirements in other embodiments of the present invention. Accordingly, the nano noble metal particles mentioned in the following description and claims of the present invention are not limited to nano platinum particles, but generally refer to all nano noble metal particles that become black after being nano-sized, or a mixture of the nano noble metal particles, and it is well known that the nano noble metal particles are mixed.

Referring to fig. 2 and 3, the energy conversion device 1 of the present invention can be composed of a plurality of energy conversion materials 10, or the energy conversion device 2 can be composed of only a single energy conversion material, that is, the energy conversion device 1 of the present invention can be composed of a plurality of energy conversion materials 10, and the energy conversion device 2 itself can be equivalent to an energy conversion material, as will be shown in advance. The energy conversion material is in a granular form (as shown in fig. 2) or a columnar form (as shown in fig. 3), and can be made of a porous material (such as a ceramic material or other porous material with far infrared radiation characteristic), such that a plurality of

holes

101, 201 are uniformly distributed on the surface and inside the material, and at least one

fuel channel

102, 202 is formed in the energy conversion device 1, 2 along the axial direction, so as to refer to fig. 2 and 3, when the energy conversion device 1, 2 is respectively installed on a fuel supply pipeline 3 of an internal combustion engine, the fuel 4 (no matter liquid or gaseous fuel) conveyed in the fuel supply pipeline 3 can smoothly pass through each

fuel channel

102, 202, and after the energy conversion device 1, 2 applies conversion processing for improving energy efficiency to the fuel, the fuel is sequentially put into a combustion chamber (i.e., cylinder), combustion is performed.

Now referring to the manufacturing method of the present invention, referring to fig. 2 and 3 again, in the first embodiment, a worker can first add the nano platinum particles, the far infrared particles and the medium particles (such as the reducing agent, the water-soluble acryl powder and the water-based adhesive) into an aqueous solution, so as to utilize the penetration effect generated by the temperature difference, so that the nano platinum particles, the far infrared particles and the medium particles can penetrate into the surface and the holes 101 of the energy conversion material 10 (or the energy conversion device 2) along with the aqueous solution; then, the medium particles infiltrated into the surface of the energy conversion material 10 (or the energy conversion device 2) and the holes 101 (or the holes 201) are melted at a high temperature, and combined with the nano platinum particles and the far infrared particles, and uniformly sintered and coated on the surface of the energy conversion material 10 (or the energy conversion device 2) and the holes 101 (or the holes 201) to form a layer of nano platinum particles and far infrared particle film. In particular, the present invention can perform the above-mentioned manufacturing method for each energy conversion material 10 one by one, or can combine a plurality of energy conversion materials 10 into the energy conversion device 1 and then perform the above-mentioned manufacturing method, which will be described in the foregoing.

In the first embodiment, referring to fig. 2 and 4, the manufacturing method includes the following steps:

(401) uniformly mixing components such as water-soluble platinum salt, far infrared particles and medium particles into water according to a predetermined weight percentage to form a first mixed solution, wherein platinum ions are dissociated in the first mixed solution due to the fact that the water-soluble platinum salt can be completely dissolved in the first mixed solution, and each platinum ion is easily bonded with each far infrared particle so as to be uniformly and stably attached to the surface of each far infrared particle in the preparation process of the first mixed solution; the reducing agent can provide electrons in the first mixed solution, so that the platinum ions can be respectively reduced into nano platinum particles by acquiring the electrons and are gradually and stably attached to the surfaces of the far infrared particles; after the components are uniformly mixed in the first mixed solution, keeping the first mixed solution at a first temperature (such as room temperature 25-30 ℃);

(402) placing each energy conversion material 10 into an oven, baking to a second temperature (such as 75-95 ℃), keeping the second temperature for 1-2 hours, and then placing each energy conversion material 10 into the first mixed solution, so that the first mixed solution can uniformly permeate the surfaces and the holes 101 of the energy conversion materials 10 along with the nano platinum particles, the far infrared particles and the medium particles by utilizing the permeation effect generated by the temperature difference;

(403) putting each energy conversion material 10 into an oven again, baking to the second temperature (such as 75-95 ℃), and keeping the second temperature for 1-2 hours, so that after the moisture contained in each energy conversion material 10 is completely volatilized, the materials are allowed to stand to room temperature; and

(404) finally, each energy conversion material 10 is placed into a high-temperature sintering furnace, and each energy conversion material 10 is heated to a third temperature (for example, 175-200 ℃) within two hours; then, heating each energy conversion material 10 to a fourth temperature (e.g., 500-600 ℃) within six hours; at this time, since the material properties of the dielectric particles are similar to those of the energy conversion materials 10, the dielectric particles can be melted by the high temperature applied by the high temperature sintering furnace, and sintered together with the nano platinum particles and the far infrared particles and coated on the surface and the holes 101 of the energy conversion materials 10, thereby forming a composite film containing the nano platinum particles and the far infrared particles.

Referring to fig. 4, in the first embodiment, the first mixed solution is formed by uniformly mixing water, far infrared particles of oxides, water-soluble platinum salt, reducing agent, water-soluble acrylic powder, and water-based adhesive according to the following weight percentages:

(1) water: the weight percentage is 35 percent to 97 percent;

(2) oxide-based far infrared particles: 0.2-10 wt%, in the first embodiment, the larger oxide far infrared particles are ground into particles of about 1-100 μm;

(3) water-soluble platinum gold salt: the weight percentage is 0.001% -5%, the platinum salt can be hydrogen chloroplatinic acid (H)₂PtCl₆) Potassium chloroplatinate (k)₂PtCl₆) Or potassium chloroplatinate (K)₂PtCl₄) In the first embodiment, only potassium chloroplatinate is taken as an example to illustrate, since platinum salt has the characteristics of being completely dissolved in water and dissociating platinum ions in water, and platinum ions have the characteristics of being oxophilic, platinum salts are easy to bond with oxygen on far infrared particles, and are uniformly and stably attached to the surface of each far infrared particle in the preparation process of the first mixed solution;

(4) reducing agent: 0.5-10 wt% of disodium salt of ethylene diamine tetraacetic acid (EDTA.2Na), potassium hydroxide (KOH) and potassium bicarbonate (KHCO)₃) The components are mixed into aqueous solution according to the predetermined weight percentage; wherein, the weight percentage of the ethylene diamine tetraacetic acid disodium salt in the reducing agent is 0.15 percent to 3 percent, and the weight of the potassium hydroxide0.08-1.5 percent of potassium bicarbonate and 0.3-6 percent of potassium bicarbonate, wherein the reducing agent can provide electrons required by platinum ions to be reduced into nano platinum particles in the first mixed solution, so that the platinum ions can gradually and stably form the nano platinum particles on the surfaces of the far infrared particles respectively through the oxidation action of the reducing agent;

(5) water-soluble acryl powder: 2-30 wt%, wherein the water-soluble acryl powder is a water-soluble dispersant, and after being dissolved in water, the water-soluble acryl powder can make the far infrared particles uniformly and dispersedly suspended in the first mixed solution, and in the first embodiment, the water-soluble acryl powder is a Polyacrylic acid derivative (Polyacrylic acid derivative), which can make the far infrared particles uniformly dispersed in the first mixed solution, without precipitation or agglomeration; and

(6) water-soluble adhesive: the weight percentage of the water-soluble adhesive is 0.2% -10%, the water-soluble adhesive is used for coating the surfaces of the far infrared particles and the platinum nanoparticles which are uniformly and dispersedly in the first mixed solution, and in the first embodiment, the water-soluble adhesive comprises polyurethane resin (urea prepolymer), N-Methyl pyrrolidone (N-Methyl pyrrolidone), Triethylamine (triethyl amine) and other components.

In addition, according to the actual requirement, 500-2,000 ppm nano platinum particles are directly added according to the predetermined weight percentage in the process of preparing the first mixed solution to replace the water-soluble platinum salt and the reducing agent, and after uniform mixing, the first mixed solution required by the invention can also be obtained.

Since the nano platinum particles in the first mixed solution can be uniformly and stably attached to the surface of each far infrared particle during the preparation process of the first mixed solution, when the far infrared particles are sintered and coated on the surface of the energy conversion material 10 and the holes 101 to manufacture the energy conversion device 1, as shown in fig. 5, the far infrared particles 51 in the nano composite film can be uniformly distributed on the surface of each energy conversion material 10 and the holes 101 through the medium particles 50, and at this time, the nano platinum particles 52 are also uniformly and stably attached to the surface of the far infrared particles 51, and the nano platinum particles 52 have an extremely low reflectivity (less than 1%) to the light energy 60 and the heat energy 61. As shown in fig. 2 and 3, when the energy conversion devices 1 and 2 are installed in the fuel supply pipeline 3 of an internal combustion engine, the fuel 4 conveyed in the fuel supply pipeline 3 can smoothly pass through the energy conversion devices 1 and 2, and after the energy conversion devices 1 and 2 apply the conversion treatment for improving the energy efficiency to the fuel 4, the fuel is sequentially input into the combustion chambers of the internal combustion engines for combustion.

In the above-mentioned conversion process for improving energy efficiency, the far infrared particles 51 of the energy conversion devices 1, 2 can fully utilize the platinum nanoparticles 52, as a high-efficiency energy conversion material, fully absorb the light energy 60 and heat energy 61 of the internal combustion engine and its surroundings, convert the light energy into far infrared rays 62 with a wavelength of 4 μm to 14 μm, and feed back the far infrared rays to the fuel 4, so that the molecules and atoms of the fuel 4 flowing through the energy conversion devices 1, 2 resonate, and the fuel molecules of long-chain oxyhydrogen compound are broken into short-chain oxyhydrogen compound fuel molecules by vibration, and the maximum energy efficiency of the fuel 4 is excited, so that the fuel 4 can exert the best combustion efficiency, not only the internal combustion engine can generate the maximum power, but also the pollutants contained in the combustion 4 can be eliminated by the best combustion efficiency, without remaining in the exhaust gas discharged from each of the internal combustion engines. Experimental tests prove that the energy conversion devices 1 and 2 manufactured according to the invention can actually greatly reduce the oil consumption rate of each internal combustion engine by 8%.

Although gold (Au) is a very stable material, it can be used as a catalyst because of its strong adsorption of oxygen due to its unique potential characteristics, and also as a catalyst for oxidizing carbon monoxide into carbon dioxide according to the findings of japanese scientists, it is commonly used to manufacture masks, gas masks, water heaters, etc. to effectively prevent and treat carbon monoxide poisoning. In addition, compared with the platinum catalyst commonly used in industry, the gold catalyst needs to react at high temperature and cannot have water vapor; on the contrary, the nano gold catalyst can react at room temperature and is not influenced by water vapor; the following description is briefly made with respect to the aforementioned platinum nanoparticles and the photocatalyst effect of the gold nanoparticles:

generally, after platinum and gold are nanocrystallized, since the grain size of platinum and gold becomes equal to or smaller than that of light wave, this size effect will result in the increase of the interval between conduction band and valence band, so that the light absorption capability thereof is significantly enhanced, so that when a photon with certain energy or a photon with energy exceeding the band gap energy of the semiconductor is incident on the semiconductor electronic structure of platinum nanoparticle or gold nanoparticle under the irradiation of light, an electron is excited from valence band to conduction band, and a hole is left, the hole of valence band will rob the hydroxyl electron in the surrounding environment, so that the hydroxyl becomes a radical, and thus can be used as a strong oxidant.

Based on the photocatalyst and strong oxidation characteristics of the nano platinum particles and the nano gold particles, the inventors also think that the characteristics are utilized to effectively improve the energy conversion efficiency of the far infrared particles, and enable the energy conversion devices 1 and 2 of the invention to have better catalyst or catalysis, so that the oxygen content of the fuel 4 flowing through the energy conversion devices 1 and 2 can be effectively increased due to the better catalyst or catalysis, and the energy conversion devices 1 and 2 can provide the best conversion effect for improving the energy efficiency for the fuel 4 more quickly and stably; accordingly, referring to fig. 2 and 3, in a second embodiment of the present invention, the method further comprises mixing the components such as the nano gold particles and the dielectric particles (such as the water-soluble acrylic powder and the water-based adhesive) into an aqueous solution according to a predetermined weight percentage to form a second mixed solution required by the present invention; then, by using the permeation effect generated by the temperature difference, the nano gold particles and the medium particles can permeate into the surface of the energy conversion material 10 (or the energy conversion device 2) and the holes 101 (or the holes 201) along with the second aqueous solution; finally, melting the medium particles infiltrated into the surface of the energy conversion material 10 (or the energy conversion device 2) and the holes 101 (or the holes 201) at a high temperature, so that the nano gold particles can be combined with the nano platinum particles and the far infrared particles thereon, and then sintering and coating the mixture on the energy conversion material 10 (or the energy conversion device 2) together to form a composite film containing the nano gold particles, the nano platinum particles and the far infrared particles, as shown in fig. 6, the manufacturing method of the second embodiment comprises the following steps:

(601) uniformly mixing the components such as nano gold particles, medium particles and the like into water according to a predetermined weight percentage to form a second mixed solution, and keeping the second mixed solution at the first temperature (such as 25-30 ℃ at room temperature) after the components are uniformly mixed in the second mixed solution;

(602) placing the energy conversion material 10 (or the energy conversion device 2) manufactured in the first embodiment into an oven, baking to a second temperature (e.g., 75-95 ℃), maintaining the second temperature for 1-2 hours, and then placing the energy conversion material 10 (or the energy conversion device 2) into the second mixed solution, so that the second mixed solution can uniformly permeate the surface of the energy conversion material 10 (or the energy conversion device 2) and the holes 101 (or the holes 201) along with the second mixed solution by utilizing a permeation effect generated by a temperature difference effect;

(603) then, putting the energy conversion material 10 (or the energy conversion device 2) into an oven again, baking to the second temperature (such as 75-95 ℃), and keeping the second temperature for 1-2 hours, so that the energy conversion material 10 (or the energy conversion device 2) is allowed to stand to room temperature after the moisture contained in the material is completely volatilized; and

(604) finally, the energy conversion material 10 (or the energy conversion device 2) is placed into a high-temperature sintering furnace, and the energy conversion material 10 (or the energy conversion device 2) is heated to the third temperature (for example, 175-200 ℃) within two hours; then, the energy conversion material 10 (or the energy conversion device 2) is heated to the fourth temperature (e.g. 500-700 ℃) within six hours, at this time, because the material characteristics of the medium particles are similar to the material characteristics of the energy conversion material 10 (or the energy conversion device 2), the medium particles can be melted by the high temperature applied by the high temperature sintering furnace, and the nano gold particles can be sintered together with the nano platinum particles and the far infrared particles and coated on the surface of the energy conversion material 10 (or the energy conversion device 2) and the holes 101 (or the holes 201), so as to form a layer of composite film containing the nano gold particles, the nano platinum particles and the far infrared particles.

Referring to fig. 6 again, in the second embodiment, the second mixed solution is formed by uniformly mixing water, nano gold particles, water-soluble acrylic powder, and water-based adhesive according to the following weight percentages:

(1) water: the weight percentage is 35 percent to 97 percent;

(2) nano gold particles: the content is 500-1, 500ppm, because the nano gold particles have the characteristic of oxygen affinity, the nano gold particles are easy to bond with oxygen on the far infrared particles in the sintering process and are uniformly attached to the surfaces of the far infrared particles;

(3) water-soluble acryl powder: 2-30 wt%, wherein the water-soluble acryl powder is a water-soluble dispersant, which can make the nano gold particles uniformly and dispersedly suspended in the second mixed solution after being dissolved in water, and in the above embodiment of the present invention, the water-soluble acryl powder is a Polyacrylic acid derivative (Polyacrylic acid derivative), which can make the nano gold particles uniformly dispersed in the second mixed solution, without precipitation or agglomeration; and

(4) water-soluble adhesive: the weight percentage of the water-soluble adhesive is 0.2% -10%, the water-soluble adhesive is used for coating the surfaces of the nano gold particles uniformly dispersed in the second mixed solution, in the second embodiment, the water-soluble adhesive comprises polyurethane resin (urea polymer), N-Methyl pyrrolidone (N-Methyl pyrrolidone), Triethylamine (triethyl amine) and other components.

Referring to fig. 2, 3 and 5, after the second embodiment of the present invention is completed, the energy conversion devices 1 and 2 can respectively utilize the nano platinum particles 52 and the nano gold particles 54 attached to the far infrared particles 51 thereon to perform a conversion treatment for improving energy efficiency, so as to effectively absorb the light energy 60 and the heat energy 61 of the internal combustion engine and the surrounding thereof in an environment without light or light, and smoothly convert and excite the far infrared rays 62 with a wavelength of 4 μm to 14 μm, and feed back the far infrared rays to the fuel 4, so that the molecules and atoms of the fuel 4 flowing through the energy conversion devices 1 and 2 generate resonance, thereby accelerating the chemical reaction rate of the conversion treatment, promoting the molecular structure of the fuel 4 from long-chain oxyhydrogen compounds, and being rapidly, smoothly and stably cracked into a molecular structure of short-chain oxyhydrogen compounds due to vibration, meanwhile, the oxygen content in the molecular structure of the short-chain oxyhydrogen compound can be greatly increased through the strong oxidation of the nano gold particles 54, so that the fuel 4 converted by the method can effectively excite the maximum energy efficiency during combustion.

In addition, experimental tests prove that the energy conversion devices 1 and 2 manufactured by the second embodiment of the invention can actually greatly reduce the fuel consumption of each internal combustion engine by 15%. Accordingly, the energy conversion device 1, 2 of the present invention can clearly make the fuel 4 exert the optimum combustion efficiency, and not only can make each internal combustion engine generate the maximum power, but also can make the pollutants contained in the fuel 4 disappear due to the optimum combustion efficiency, and do not remain in the exhaust gas discharged from each internal combustion engine. Therefore, the usage amount of petrochemical fuel can be reduced, and the aim of low-pollution or zero-pollution exhaust emission can be effectively achieved.

As described above, although only some preferred embodiments of the present invention are described, the present invention is not limited to the above-mentioned features, and any person skilled in the art can form a composite film containing nano gold particles, nano platinum particles and far infrared particles by sintering and coating the nano gold particles, nano platinum particles and far infrared particles on the surface and holes 101, 201 of the energy conversion device 1, 2 according to the design concept of the present invention, so as to perform the conversion treatment for improving energy efficiency and oxygen content for a long time on the fuel 4 flowing through the energy conversion device 1, 2 in the light or dark environment, regardless of the step sequence of the first preferred embodiment and the second preferred embodiment of the present invention. Moreover, any person skilled in the art, according to the design concept of the present invention, should substitute the above-mentioned other far infrared particles for the oxide far infrared particles, or substitute other equivalent nano noble metal particles for the nano platinum particles or the nano gold particles, and also shall be covered by the following claims of the present invention.

Furthermore, although the nano gold particles used in the foregoing embodiments of the present invention have strong oxidation characteristics, they can absorb oxygen and also attract other contaminants (e.g., dust, etc.), so that the surface of the energy conversion devices 1 and 2 is covered by the contaminants, thereby negatively affecting the subsequent energy conversion efficiency, and therefore, in order to solve this problem, in other embodiments of the present invention, the composite film further comprises nano cerium (Ce) particles, wherein the nano cerium (Ce) particles can be converted between Ce and CeO, and the cerium oxide (CeO) itself has a self-cleaning (self-cleaning) characteristic, so as to effectively remove the contaminants adsorbed on the surface of the energy conversion material 10 (or the energy conversion device 2), so that the surface of the energy conversion material 10 (or the energy conversion device 2) is always maintained in a clean state, thereby, the energy conversion devices 1 and 2 can always exhibit the expected energy conversion efficiency for a long period of time. In addition, in another embodiment of the present invention, since the nanoparticles of ruthenium (Ru) and rhodium (Rh) can generate a strong oxygen absorption effect after being matched with the nano platinum particles, taking the nano ruthenium particles as an example, the nano ruthenium particles and the nano platinum particles can also form a chemical reaction shown by the following formula, so that each nano platinum particle always has a clean surface, and the quantity conversion materials 10 (or the energy conversion device 2) can excite the fuel flowing through them with the maximum energy efficiency:

2Ru_OH+Pt^-CO→Pt+2Ru+CO₂+H₂O。

in view of the above, in other embodiments of the present invention, in addition to adding nano cerium particles, nano ruthenium particles, and nano rhodium particles to the composite film, the energy conversion device of the present invention further includes the following embodiments to achieve the aforementioned effects as contemplated by the present invention, as shown in fig. 7, in a third embodiment of the present invention, an energy conversion material 70 is formed on the surface and in the holes 701 of the composite film 702, and the outer layer of the composite film 702 is further covered with at least one auxiliary film 703, wherein another nano noble metal particle contained in the auxiliary film 703 is different from the nano noble metal particle contained in the composite film 702, for example, the composite film 702 contains nano platinum particles and nano gold particles, the auxiliary film 703 contains nano cerium particles, that is, the energy conversion material of the present invention is used in practice, can have a single film layer (i.e., a composite film) or a plurality of film layers, and particularly, the auxiliary film referred to herein means a film layer containing no far infrared ray particles therein, as described in the foregoing.

In addition, in a fourth embodiment of the present invention, referring to fig. 8, the energy conversion device 8 can include more than two

energy conversion materials

80A, 80B, and the types or the number of the nano noble metal particles contained in each of the

energy conversion materials

80A, 80B are different from each other, and the following forms of the fourth embodiment are listed for reference only:

(a1) all species are different, and the number is also different: the composite film 802 of the energy conversion material 80A contains nano platinum particles and nano gold particles, and the composite film 803 of the energy conversion material 80B contains nano cerium particles;

(a2) all species are different, but the number is the same: the composite film 802 of the energy conversion material 80A contains nano platinum particles, and the composite film 803 of the energy conversion material 80B contains nano gold particles; or

(a3) The parts are of the same type but in different quantities: the composite thin film 802 of the energy conversion material 80A includes nano platinum particles, nano gold particles, and nano cerium particles, and the composite thin film 803 of the energy conversion material 80B includes nano gold particles and nano cerium particles.

Furthermore, although the

energy conversion materials

80A and 80B in fig. 8 are only provided with a single film layer, in other embodiments of the invention, not limited thereto, each

energy conversion material

80A and 80B can be a multi-film layer (including a composite film and/or an auxiliary film), so that a manufacturer can self-adjust the number of different

energy conversion materials

80A and 80B according to different vehicle requirements, and for practical tests of the applicant, 180 energy conversion materials are used to form an energy conversion device, wherein the surface film layers of 22 energy conversion materials (composite films and/or auxiliary film layers) contain nano ruthenium (Ru) particles, the surface film layers of 53 energy conversion materials contain nano gold (Au) particles, the surface film layers of 55 energy conversion materials contain nano platinum (Pt) particles, the surface film layers of 50 energy conversion materials contain nano cerium (Ce) particles, the nano noble metal particles account for about 1000ppm in each film layer; thus, the fuel saving rate is more than 96% compared with the vehicle without the energy conversion device.

The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are only exemplary embodiments of the present invention and are not intended to limit the present invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims

1. A method of making an energy conversion device of nano-precious metal far-infrared rays that can improve fuel energy efficiency for a long time, wherein, this energy conversion device is made up of at least one energy conversion material, and it can form at least one fuel channel along the axial direction , for the fuel transported in the fuel supply pipeline of an internal combustion engine to pass through, the manufacturing method utilizes the infiltration effect generated by the temperature difference, so that a first mixed solution containing at least nano-precious metal particles, far-infrared particles and medium particles can be Infiltrate into the energy conversion material, and after the energy conversion material is completely dried by high temperature treatment, a layer of composite film can be formed thereon, and the nano-precious metal particles in the composite film can excite the far-infrared particles to produce far-infrared particles. Infrared, when the fuel passes through the fuel channel, the composite film will apply a conversion treatment to increase energy, so that the far-infrared generated by the composite film can make long-chain hydrocarbon fuel molecules, After being cracked into short-chain hydrocarbon fuel molecules, they are sequentially put into the combustion chamber of the internal combustion engine for combustion.

2. The manufacturing method of claim 1, wherein the energy conversion material is a porous material, and a plurality of holes are evenly distributed on its surface and inside, and the first mixed solution can penetrate into the surface and the surface of the energy conversion material. In each of the holes, the finally formed composite film can be coated on the surface and each of the holes.

3. preparation method as claimed in claim 2, comprises the following steps:

After the components in the first mixed solution are uniformly mixed, the first mixed solution is kept at a first temperature;

Put the energy conversion material into an oven, bake it to a second temperature, and keep the energy conversion material at the second temperature for 1-2 hours, then put the energy conversion material into the first mixed solution, so that the first The mixed solution can utilize the osmotic effect produced by the temperature difference, so that each component particle in it can evenly penetrate into the surface of the energy conversion material and each of the holes along with the first mixed solution;

Then, the energy conversion material is put back into the oven, baked to the second temperature, and kept at the second temperature for 1 to 2 hours, so that after the water contained in the energy conversion material is completely volatilized, let it stand to room temperature; and

Finally, put the energy conversion material into a high-temperature sintering furnace, and heat the energy conversion material to a third temperature within 2 hours; then, heat the energy conversion material to a fourth temperature within 6 hours At this time, since the material properties of these medium particles will be similar to those of the energy conversion material, the high temperature applied by the high-temperature sintering furnace can make these medium particles melt, and the nano-precious metal particles and the remote The infrared particles are sintered together and coated on the surface of the energy conversion material and in each of the holes to form the composite film.

4. The manufacturing method of claim 3, wherein the first mixed solution comprises the components of water, far-infrared particles, water-soluble platinum salt, reducing agent, water-soluble acrylic powder and water-based adhesive, and is as follows Weight percentage, evenly mixed to form:

Water, its weight percentage is 35% to 97%;

far-infrared particles, the weight percentage of which is 0.2% to 10%, and the particles are ground into a size of 1 to 100 microns;

Water-soluble platinum salt, its weight percentage is 0.001% to 5%, the platinum salt is hydrochloroplatinic acid, potassium chloroplatinate or potassium chloroplatinite, after the platinum salt is dissolved in water, it will dissociate in water Platinum ions, and because platinum ions have oxygen-loving properties, will bond with the oxygen on the far-infrared particles, and during the preparation process of the first mixed solution, they are uniformly and firmly attached to the far-infrared particles. on the surface;

Reducing agent, its percentage by weight is 0.5%～10%, by the composition of disodium EDTA, potassium hydroxide and potassium bicarbonate, according to predetermined weight percentage, mixed an aqueous solution; wherein, ethylene diamine The weight percent of disodium amine tetraacetate in this reducing agent is 0.15%～3%, the weight percent of potassium hydroxide is 0.08%～1.5%, the weight percent of potassium bicarbonate is 0.3%～6%, this reducing agent The electrons required for the reduction of platinum ions into nano platinum particles can be provided in the first mixed solution, so that platinum ions can gradually and steadily form nano platinum particles on the surface of each far-infrared particle through the oxidation of the reducing agent. ;

The water-soluble acrylic powder is 2% to 30% by weight. The water-soluble acrylic powder is a water-soluble dispersant, and is a polyacrylic acid derivative. The far-infrared particles and the nano-platinum particles are evenly and dispersedly suspended in the first mixed solution, and the far-infrared particles and the nano-platinum particles are uniformly dispersed in the first mixed solution without precipitation or fouling. agglomeration; and

A water-soluble adhesive, whose weight percentage is 0.2% to 10%, and contains the components of polyurethane resin, N-methylpyrrolidone and triethylamine, wherein the water-soluble adhesive is used to coat the first The far-infrared particles and the platinum nanoparticles are uniformly and dispersed in a mixed solution.

5. The manufacturing method as claimed in claim 3, wherein, the first mixed solution comprises the composition of water, far-infrared particles, nano-platinum particles, water-soluble acrylic powder and water-based adhesive, and according to the following weight percentages, uniform Mix it up:

Water, its weight percentage is 35% to 97%;

Nano platinum particles, the weight percentage of which is 500-2,000 ppm;

A water-soluble adhesive, whose weight percentage is 0.2% to 10%, and contains the components of polyurethane resin, N-methylpyrrolidone and triethylamine, wherein the water-soluble adhesive is used to coat the first The far-infrared particles and the nano-platinum particles are uniformly and dispersed in a mixed solution.

6. The manufacturing method of claim 4 or 5, wherein the composite film further comprises nano-gold particles, and the manufacturing method has the following steps:

Using the infiltration effect generated by the temperature difference, a second aqueous solution containing nano-gold particles and medium particles can smoothly penetrate into the surface and pores of the energy conversion material, so that after the energy conversion material is completely dried by high temperature treatment, The composite film can be formed on its surface and in the holes, so that when the energy conversion device is installed in the fuel supply pipeline of the internal combustion engine, the composite film can perform a long-term conversion treatment to improve the energy efficiency of the fuel flowing therethrough and treatment to increase oxygen content.

7. The manufacturing method of claim 6, further comprising:

The components of the nano-gold particles and the medium particles are uniformly mixed into water to form the second mixed solution. After these components are uniformly mixed in the second mixed solution, the second mixed solution is kept at the first temperature ;

Put the energy conversion materials into the oven, bake to the second temperature, and keep at the second temperature for 1 to 2 hours, put the energy conversion materials into the second mixed solution, so that the second mixed solution The solution can utilize the osmotic effect produced by the temperature difference, so that the nano-gold particles and the medium particles can evenly penetrate into the surface of the energy conversion material and each of the holes along with the second mixed solution;

Then, the energy conversion materials are put back into an oven, baked to the second temperature, and kept at the second temperature for 1-2 hours, so that the water contained in the energy conversion materials is completely volatilized. , let it stand to room temperature; and

Finally, the energy conversion materials are put into a high temperature sintering furnace, and the energy conversion materials are heated to the third temperature within 2 hours; then, the energy conversion materials are heated to the fourth temperature within 6 hours At this time, since the material properties of these medium particles are similar to those of the energy conversion material, the high temperature applied by the high-temperature sintering furnace can melt these medium particles, and make these nano-gold particles and these nano-platinum particles The particles and far-infrared particles are sintered together and coated on the surface of the energy conversion material or the device and in each of the holes to form the composite film.

8. The manufacturing method as claimed in claim 7, wherein, the second mixed solution is uniformly mixed by the ingredients such as water, nano-gold particles, water-soluble acrylic powder and water-based adhesive, according to the following weight percentages:

Water, its weight percentage is 35% to 97%;

Nano-gold particles, the content of which is 500-1,500ppm, and the nano-gold particles have oxygen-loving properties, and in the aforementioned sintering process, bond with the oxygen on the far-infrared particles and uniformly adhere to the surface of the far-infrared particles;

The water-soluble acrylic powder is 2% to 30% by weight. The water-soluble acrylic powder is a water-soluble dispersant, and is a polyacrylic acid derivative. The nano gold particles are uniformly and dispersedly suspended in the second mixed solution, and the nano gold particles are uniformly dispersed in the second mixed solution without causing precipitation or accumulation and agglomeration; and

A water-soluble adhesive, the weight percentage of which is 0.2% to 10%, and contains the components of polyurethane resin, N-methylpyrrolidone and triethylamine, wherein the water-soluble adhesive is used to coat the first The two mixed solutions were uniformly dispersed on the surface of these nano-gold particles.

9. A nano-precious metal far-infrared energy conversion device capable of improving the energy efficiency of fuel for a long time, which can form at least one fuel channel along the axial direction, so that the fuel transported in the fuel supply pipeline of an internal combustion engine passes through, and the energy Transformation devices include:

At least one energy conversion material is covered with a layer of composite film, and the composite film contains at least nano-precious metal particles and far-infrared particles, wherein the nano-precious metal particles can excite the far-infrared particles to generate far-infrared rays;

When the fuel passes through the fuel channel, the composite film will apply a conversion treatment to increase energy, wherein the far infrared rays generated by the composite film will cause the long-chain hydrocarbon fuel molecules to be cracked. After the fuel molecules are formed into short-chain hydrocarbons, they are sequentially put into the combustion chamber of the internal combustion engine for combustion.

10. The energy conversion device according to claim 9, wherein the energy conversion material is in the form of particles or columns, and a plurality of holes are uniformly distributed on the surface and in the interior thereof, and the composite film is coated on the energy conversion material. surface and each of the holes.

11. The energy conversion device of claim 10, wherein the energy conversion material further comprises at least one auxiliary film, each of which is located on the outer layer of the composite film, and contains another nano-noble metal particle, and the other auxiliary film is located in the outer layer of the composite film. A nanometer noble metal particle is different from the nanometer noble metal particle in the composite film.

12. The energy conversion device according to any one of claims 9 to 11, wherein the energy conversion device comprises more than two kinds of energy conversion materials, and the type or quantity of nano-precious metal particles contained on each energy conversion material , are different from each other.

13. The energy conversion device according to claim 12, wherein in this composite film of a kind of energy conversion material, containing nano-gold particles, nano-platinum particles and nano-cerium particles, in this composite film of another energy conversion material, It contains nano gold particles and nano cerium particles.

14. The energy conversion device according to any one of claims 9 to 11, wherein the composite film further comprises nano-gold particles.

15. The energy conversion device of claim 14, wherein the energy conversion material is made of ceramic material or other porous material having far-infrared radiation properties.

16. The energy conversion device of claim 15, wherein the far-infrared material comprises oxide-based, carbide-based, boride-based, silicide-based and/or nitride-based far-infrared materials and mixtures thereof.

17 . The energy conversion device of claim 16 , wherein the nano-precious metal particles further comprise platinum, palladium, nickel, rhodium, ruthenium or other nano-precious metal particles that will turn black after nano-ization and mixtures thereof. 18 .

18. The energy conversion device of claim 17, wherein the composite film further comprises nano-cerium particles.