CN113481511A - Power-free long-life self-driven antifouling device for ship seawater box body environment - Google Patents
Power-free long-life self-driven antifouling device for ship seawater box body environment Download PDFInfo
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- CN113481511A CN113481511A CN202110541987.8A CN202110541987A CN113481511A CN 113481511 A CN113481511 A CN 113481511A CN 202110541987 A CN202110541987 A CN 202110541987A CN 113481511 A CN113481511 A CN 113481511A
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- antifouling
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- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 72
- 239000013535 sea water Substances 0.000 title claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims abstract description 72
- 239000002184 metal Substances 0.000 claims abstract description 69
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910001431 copper ion Inorganic materials 0.000 claims abstract description 8
- 150000002739 metals Chemical class 0.000 claims abstract description 7
- 238000004090 dissolution Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 14
- 230000007797 corrosion Effects 0.000 claims description 10
- 238000005260 corrosion Methods 0.000 claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 9
- -1 platinum niobium metal oxide Chemical class 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 239000007769 metal material Substances 0.000 claims description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 229910001369 Brass Inorganic materials 0.000 claims description 3
- 229910000906 Bronze Inorganic materials 0.000 claims description 3
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 3
- 239000010951 brass Substances 0.000 claims description 3
- 239000010974 bronze Substances 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 238000005253 cladding Methods 0.000 claims description 3
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 238000004880 explosion Methods 0.000 claims 1
- 229910052755 nonmetal Inorganic materials 0.000 claims 1
- 238000012986 modification Methods 0.000 abstract description 6
- 230000004048 modification Effects 0.000 abstract description 6
- 238000013461 design Methods 0.000 abstract description 3
- 150000002500 ions Chemical class 0.000 abstract description 2
- 239000000126 substance Substances 0.000 description 5
- 238000005868 electrolysis reaction Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000000053 physical method Methods 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000010170 biological method Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- JRBRVDCKNXZZGH-UHFFFAOYSA-N alumane;copper Chemical compound [AlH3].[Cu] JRBRVDCKNXZZGH-UHFFFAOYSA-N 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007227 biological adhesion Effects 0.000 description 1
- 230000007321 biological mechanism Effects 0.000 description 1
- 230000003592 biomimetic effect Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F15/00—Other methods of preventing corrosion or incrustation
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Prevention Of Electric Corrosion (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The invention provides a power-free long-life self-driven antifouling device for a marine tank environment of a ship, which structurally comprises an antifouling electrode and a mounting base, wherein the antifouling electrode is a main functional structure, and the potential difference between dissimilar metals is utilized to drive the accelerated dissolution of a cathode plate so as to generate copper ions with the effective antifouling concentration of more than 5 ppb; the antifouling electrode consists of an anode metal plate, a cathode metal plate, clamping plates and fasteners, wherein the anode metal plate and the cathode metal plate are fixed by the clamping plates at two ends and the fasteners, and the number of the fasteners is determined by the total number of the anode and cathode plates so as to fix the anode and cathode plates without loosening. In the device application, need not the external power source drive, consequently avoided the power cord to wear the influence of cabin to the hull structure, this device can independently design the antifouling ability of modification according to protected space size simultaneously, and this device can independently produce antifouling ion under the sea water environment to effectively restrain marine organism's stained.
Description
Technical Field
The invention belongs to the field of marine organism pollution protection of ships or marine facilities, and particularly relates to a power-free long-life self-driven antifouling device for a ship seawater tank environment.
Background
Under the natural seawater state, the fouling problem caused by the adhesion and growth of marine organisms is very easy to occur in the metal box environments such as ship titanium alloy, steel structures and the like. The ship is usually damaged to cause a plurality of problems of reduced navigation speed, blocked pipeline, induced corrosion, reduced heat exchange efficiency, increased noise and the like. Therefore, it is necessary to combine the target structural materials and environmental factors for use, and to adopt effective measures to prevent marine fouling.
The marine organism pollution protection technology for ships is generally divided into a physical method, a chemical method and a biological method. Wherein, the physical method is physical cleaning or biological adhesion reduction or prevention, and mainly comprises mechanical cleaning, water jet decontamination, ultrasonic wave, ultraviolet ray, low surface energy coating and the like. The chemical method is to utilize specific chemical substances to kill or inhibit the attachment of organisms, and comprises the steps of directly adding medicaments, chemical antifouling paint, electrolytic seawater antifouling, electrolytic copper aluminum antifouling and the like. Biological antifouling is the inhibition of adhesion by certain biological mechanisms, including biological antifouling agents, biomimetic coatings, and the like. The selection of the anti-fouling technology is related to factors such as use conditions, materials, economy, reliability and the like.
However, for the internal box structure of the ship, because the internal operation space is small, mechanical equipment or paint coating workers are difficult to enter, and the construction difficulty is too high, the internal box structure is not suitable for pollution prevention by a physical method and a biological method. In addition, the cost of adding chemical agents is too high for chemical antifouling; the anti-fouling measures for the seawater electrolysis have large power consumption and complex structure, the electrolytic cell needs to be maintained, and hydrogen is generated in the using process; the electrolytic copper and aluminum can not meet the antifouling requirement of large water flow temporarily, and the service life of the copper bar and the aluminum bar is short (1 year), and the use cost is high. And moreover, external power supplies are required to be introduced by adopting the anti-fouling measures of the electrolysis method, and pipelines are required to penetrate through the tanks in an anti-fouling system, so that the structural strength of the ship body is influenced to a certain extent, and the hidden danger of stray current corrosion exists.
According to a search of the prior art, for example, CN1109790C discloses an antifouling device for a structure in contact with seawater, which generates oxygen on the surface of the structure in contact with seawater to inhibit marine organisms from adhering to the surface of the structure in contact with seawater, and which has an external dc power supply with an automatic potential control means built therein. Patent CN102409353A discloses a distributed titanium alloy pipeline electrolysis anti-fouling device, and the device handles titanium alloy pipeline inner wall, utilizes external power source to produce chlorine and the effective antifouling compound of hypochlorite at the inner wall electrolysis sea water thereby reaches antifouling purpose.
In summary, the application of the anti-fouling technology in the field of marine organism fouling protection of ships is increasingly wide, but an anti-fouling measure which can be applied in the marine environment of the ship box is lacked.
Disclosure of Invention
The invention aims at solving the problem of marine organism pollution in the seawater environment of the conventional ship box body, and provides a power-free long-life self-driven antifouling device which does not need an external power supply for self-driving and is used in the seawater box body environment of a ship. The device utilizes the principle of dissimilar metal galvanic corrosion, in the application of device, need not external power source drive, has consequently avoided the power cord to wear the influence of cabin to the hull structure, and this device can independently design according to protected space size and revise antifouling ability simultaneously, and this device can independently produce antifouling ion under the sea water environment to effectively restrain marine organism's stained.
The technical scheme adopted by the invention for solving the technical problems is as follows:
a power-free long-life self-driven antifouling device for a marine tank environment of a ship comprises an antifouling electrode and a mounting base, wherein the antifouling electrode is used as a main functional structure, and the potential difference between dissimilar metals is utilized to drive the accelerated dissolution of a cathode plate so as to generate copper ions with effective antifouling concentration (more than 5 ppb);
the antifouling electrode consists of an anode metal plate, a cathode metal plate, clamping plates and fasteners, wherein the anode metal plate and the cathode metal plate are fixed by the clamping plates at two ends and the fasteners, and the number of the fasteners is determined by the total number of the anode and cathode plates so as to fix the anode and cathode plates without loosening;
the anode metal plate material includes but is not limited to pure copper, red copper, bronze, brass or copper alloy doped with other metal elements.
Preferably, the cathode metal plate is made of an inert metal material, which includes but is not limited to titanium alloy, titanium-based platinum metal oxide, and titanium-based platinum niobium metal oxide, and the material of the clamping plate is consistent with that of the cathode metal plate.
Preferably, the fastener material includes, but is not limited to, metallic or non-metallic materials such as titanium alloy, stainless steel, polytetrafluoroethylene, and the like, which are resistant to seawater corrosion.
Preferably, the antifouling electrodes are arranged in a mode that anode metal plates and cathode metal plates are alternately arranged, the anode metal plates and the cathode metal plates are subjected to insulation treatment, the number of the anode metal plates and the number of the cathode metal plates are designed according to the size of a protected water tank, and the concentration of effective antifouling copper ions in a protected space can be adjusted according to the proportion of the anode metal plates and the cathode metal plates.
Preferably, the material of the mounting base is consistent with that of the protected water tank, one end of the base is welded with the water tank, the other end of the base is provided with a stud and a corresponding fastener, and the fastener comprises a nut and an insulating assembly so as to ensure that no galvanic corrosion hidden trouble exists between the water tank mounting base and the antifouling electrode.
Preferably, the insulating component material includes, but is not limited to, teflon, and ceramic rubber.
The scheme is preferred, the fixing mode between positive pole metal sheet, the negative pole metal sheet is not only limited to through splint fixed, contains other modes that can make different metal sheets link to each other such as wire connection, fastener direct linking to each other, draw-in groove connection, mortise-tenon joint, explosive cladding simultaneously.
Compared with the prior art, the power-free long-life self-driven antifouling device for the marine tank environment of the ship has the beneficial effects that:
1. the marine organism pollution prevention effect is achieved on the marine tank body material of the ship;
2. the device is free from a power supply, does not penetrate a cabin, has small involvement engineering, is free from the damage of stray current and does not destroy the structural strength;
3. the occupied space is small, the structure size can be adjusted, and the environmental suitability is strong;
4. economic and environment-friendly, free from maintenance and with designable service life.
Drawings
FIG. 1 is a schematic front view of a self-driven anti-fouling device according to the present invention;
FIG. 2 is a schematic top view of the self-driven anti-fouling device of the present invention;
FIG. 3 is a schematic view of the installation of the self-driven anti-fouling device of the present invention;
fig. 4 is a schematic view of the mounting base of the present invention.
In the drawings, each reference numeral denotes:
1. a fixing bolt 2, a mounting base 3, a clamping plate 4, an anode metal plate 5 and a cathode metal plate,
6. fastener, 7, titanium alloy sea water tank, 8, insulating assembly, 9, antifouling electrode.
Detailed Description
The power-free long-life self-driven antifouling device for the marine tank environment of the ship is described in detail below with reference to the attached drawings 1 to 4.
Example 1
Aiming at the current antifouling situation of the ship box body environment, the invention designs and develops a power-free long-life self-driven antifouling device for the ship seawater box body environment according to the principle of galvanic corrosion of dissimilar metals.
As shown in attached figures 1-4, the invention relates to a power-free long-life self-driven antifouling device for a marine tank environment of a ship, which comprises an antifouling electrode 9 and a mounting base 2, wherein the antifouling electrode 9 is used as a main functional structure, and the potential difference between dissimilar metals is used for driving the accelerated dissolution of a cathode plate so as to generate copper ions with the effective antifouling concentration of more than 5 ppb;
the antifouling electrode 9 is composed of an anode metal plate 5, a cathode metal plate 4, clamping plates 3 and fasteners 6, wherein the cathode metal plate 4 and the anode metal plate 5 are fixed with the fasteners 6 through the clamping plates 3 at the two ends, and the number of the fasteners 6 is determined by the total number of the cathode and anode plates so as to fix the cathode and anode plates without loosening;
the cathode metal plate 4 is made of an inert metal material, and the anode metal plate 5 includes, but is not limited to, titanium alloy, titanium-based platinum metal oxide, and titanium-based platinum niobium metal oxide.
The material of the cathode metal plate 4 includes, but is not limited to, pure copper, red copper, bronze, brass or copper alloy doped with other metal elements, and the material of the clamping plate 3 is consistent with the material of the cathode metal plate 4.
The material of the fastening member 6 includes, but is not limited to, a metallic or non-metallic material such as titanium alloy, stainless steel, polytetrafluoroethylene, etc., which is resistant to seawater corrosion.
The arrangement mode of the antifouling electrodes 9 is that the cathode metal plates 4 and the anode metal plates 5 are alternately arranged, the cathode metal plates 4 and the anode metal plates 5 are subjected to insulation treatment, wherein the number of the cathode metal plates 4 and the number of the anode metal plates 5 are designed according to the size of a protected water tank, and the concentration of effective antifouling copper ions in a protected space can be adjusted according to the proportion of the cathode metal plates 4 to the anode metal plates 5.
The material of the mounting base 2 is consistent with that of the protected water tank, one end of the base is welded with the water tank, the other end of the base is provided with a stud and a corresponding fastener 6, and the fastener 6 comprises a nut and an insulating assembly 8 so as to ensure that no galvanic corrosion hidden trouble exists between the water tank mounting base 2 and the antifouling electrode 9.
The material of the insulating member 8 includes, but is not limited to, teflon and ceramic rubber.
The fixing mode between the cathode metal plate 4 and the anode metal plate 5 is not limited to fixing through the clamping plate 3, and other modes such as wire connection, direct connection of the fastening piece 6, clamping groove connection, mortise and tenon connection, explosive cladding and the like can be used for connecting dissimilar metals.
In this embodiment, the titanium alloy seawater tank 7 is protected, and the antifouling device of the present invention is installed on the side wall of the tank where seawater passes through, and the base of the antifouling device is made of titanium alloy. The anode plate material of the antifouling device is red copper, and the cathode plate material is titanium alloy plate. The size of the protected titanium alloy water tank is 1000mm multiplied by 500mm, the size of the cathode plate and the anode plate is 200mm multiplied by 50mm multiplied by 5mm, 4 cathode plates and 4 anode plates are alternately arranged. After a period of marine organism pollution acceleration test of the water tank in a seawater environment, the problem of obvious marine organism pollution is found in the water tank.
While the preferred embodiments of the present application have been described, additional variations and modifications in those embodiments may occur to those skilled in the art once they learn of the basic inventive concepts. Therefore, it is intended that the appended claims be interpreted as including preferred embodiments and all alterations and modifications as fall within the scope of the application.
It will be apparent to those skilled in the art that various changes and modifications may be made in the present application without departing from the spirit and scope of the application. Thus, if such modifications and variations of the present application fall within the scope of the claims of the present application and their equivalents, the present application is intended to include such modifications and variations as well.
In addition to the technical features described in the specification, the technology is known to those skilled in the art.
Claims (8)
1. A power-free long-life self-driven antifouling device for a marine tank environment of a ship is characterized by comprising an antifouling electrode (9) and a mounting base (2), wherein the antifouling electrode (9) is used as a main functional structure, and the potential difference between dissimilar metals is utilized to drive the accelerated dissolution of a cathode plate so as to generate copper ions reaching effective antifouling concentration;
the antifouling electrode (9) consists of a cathode metal plate (4), an anode metal plate (5), clamping plates (3) and fasteners (6), wherein the cathode metal plate (4) and the anode metal plate (5) are fixed with the fasteners (6) through the clamping plates (3) at two ends, and the number of the fasteners (6) is determined by the total number of the cathode and anode plates so as to fix the cathode and anode plates without loosening;
the cathode metal plate (4) is made of an inert metal material, the anode metal plate (5) is made of copper alloy limited to pure copper, red copper, bronze, brass or other metal elements, and the material of the clamping plate (3) is consistent with that of the anode metal plate (5).
2. The power-free long-life self-driven antifouling device for the marine tank environment of the ship as claimed in claim 1, wherein the cathode metal plate (4) is made of a material selected from titanium alloy, titanium-based platinum metal oxide and titanium-based platinum niobium metal oxide.
3. The power-free long-life self-driven antifouling device for the marine tank body environment of the ship as claimed in claim 1 or 2, wherein the fastening member (6) is made of titanium alloy, stainless steel, polytetrafluoroethylene or nonmetal materials with seawater corrosion resistance.
4. The power-free long-life self-driven antifouling device for the marine tank environment of the ship as claimed in claim 1 or 2, wherein the antifouling electrodes (9) are arranged in a manner that cathode metal plates (4) and anode metal plates (5) are alternately arranged, insulation treatment is performed between the cathode metal plates (4) and the anode metal plates (5), the number of the cathode metal plates (4) and the number of the anode metal plates (5) are designed according to the size of the protected water tank, and the effective antifouling copper ion concentration in the protected space is adjusted according to the ratio of the cathode metal plates (4) to the anode metal plates (5).
5. The power-free long-life self-driven antifouling device for the marine tank body environment of the ship as claimed in claim 1 or 2, wherein the material of the mounting base (2) is consistent with that of the protected water tank, one end of the base is welded with the water tank, the other end of the base is provided with a stud and a corresponding fastener (6), and the fastener (6) comprises a nut and an insulating component (8) so as to ensure that no galvanic corrosion hidden danger exists between the water tank mounting base (2) and the antifouling electrode (9).
6. The power-free long-life self-driven antifouling device for the marine tank body environment of the ship as claimed in claim 5, wherein the insulating component (8) is made of polytetrafluoroethylene or ceramic rubber.
7. The power-free long-life self-driven antifouling device for the marine tank environment of the ship as claimed in claim 1, 2 or 6, wherein the cathode metal plate (4) and the anode metal plate (5) are fixed by the clamp plate (3), and can be connected by wire, fasteners (6) directly, clamping groove, mortise and tenon joint, explosion cladding and other modes which can connect dissimilar metals.
8. The power-free long-life self-driven antifouling device for the marine sea tank environment of claim 1, 2 or 6, wherein the effective antifouling concentration of copper ions is more than 5 ppb.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110541987.8A CN113481511A (en) | 2021-05-18 | 2021-05-18 | Power-free long-life self-driven antifouling device for ship seawater box body environment |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110541987.8A CN113481511A (en) | 2021-05-18 | 2021-05-18 | Power-free long-life self-driven antifouling device for ship seawater box body environment |
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| CN113481511A true CN113481511A (en) | 2021-10-08 |
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| CN202110541987.8A Pending CN113481511A (en) | 2021-05-18 | 2021-05-18 | Power-free long-life self-driven antifouling device for ship seawater box body environment |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5035759A (en) * | 1989-09-19 | 1991-07-30 | Andoe, Inc. | Method of protecting hulls of marine vessels from fouling |
| CN106222691A (en) * | 2016-08-22 | 2016-12-14 | 中国船舶重工集团公司第七二五研究所 | A kind of titanium alloy antifouling electrode of seawaterline integrated high-efficiency and electrolysis anti-soil apparatus |
| CN106222567A (en) * | 2016-10-24 | 2016-12-14 | 青岛双瑞海洋环境工程股份有限公司 | Electrolysis copper-iron alloy composite anode materials, electrode assemblie and electrolysis unit |
| CN110294083A (en) * | 2019-05-07 | 2019-10-01 | 王耀 | Underbody anti-fouling method |
| RU201745U1 (en) * | 2020-06-16 | 2020-12-30 | Общество с ограниченной ответственностью "ПСС "Инжиниринг" | Anti-fouling device for underwater objects |
| CN112662222A (en) * | 2020-11-13 | 2021-04-16 | 西安交通大学 | Anti-biological fouling coating based on micron-sized primary battery with double-metal-layer sheet structure and preparation method thereof |
-
2021
- 2021-05-18 CN CN202110541987.8A patent/CN113481511A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5035759A (en) * | 1989-09-19 | 1991-07-30 | Andoe, Inc. | Method of protecting hulls of marine vessels from fouling |
| CN106222691A (en) * | 2016-08-22 | 2016-12-14 | 中国船舶重工集团公司第七二五研究所 | A kind of titanium alloy antifouling electrode of seawaterline integrated high-efficiency and electrolysis anti-soil apparatus |
| CN106222567A (en) * | 2016-10-24 | 2016-12-14 | 青岛双瑞海洋环境工程股份有限公司 | Electrolysis copper-iron alloy composite anode materials, electrode assemblie and electrolysis unit |
| CN110294083A (en) * | 2019-05-07 | 2019-10-01 | 王耀 | Underbody anti-fouling method |
| RU201745U1 (en) * | 2020-06-16 | 2020-12-30 | Общество с ограниченной ответственностью "ПСС "Инжиниринг" | Anti-fouling device for underwater objects |
| CN112662222A (en) * | 2020-11-13 | 2021-04-16 | 西安交通大学 | Anti-biological fouling coating based on micron-sized primary battery with double-metal-layer sheet structure and preparation method thereof |
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Application publication date: 20211008 |
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