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CN113464087B - A selective water shutoff method for high water cut oil wells in bottom water reservoirs - Google Patents

A selective water shutoff method for high water cut oil wells in bottom water reservoirs Download PDF

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CN113464087B
CN113464087B CN202110863707.5A CN202110863707A CN113464087B CN 113464087 B CN113464087 B CN 113464087B CN 202110863707 A CN202110863707 A CN 202110863707A CN 113464087 B CN113464087 B CN 113464087B
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CN113464087A (en
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金发扬
李启航
王冕
宋书渝
杨振明
钱德升
廖伟
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Southwest Petroleum University
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B33/00Sealing or packing boreholes or wells
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    • C09K8/92Compositions for stimulating production by acting on the underground formation characterised by their form or by the form of their components, e.g. encapsulated material
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Abstract

The invention discloses a selective water plugging method for a bottom water reservoir high-water-cut oil well. And then the foam in the high permeability layer is cleaned by back drainage, so that the aims of temporarily blocking the low permeability and enabling the subsequent water plugging agent to enter the high permeability layer in an oriented manner are fulfilled. And then injecting a water shutoff agent, wherein the water shutoff agent establishes an artificial partition plate at a proper position in the water production layer to prevent bottom water from rising and inhibit bottom water coning. And finally, displacing the water shutoff agent out of a certain position near the well area through polymer solution displacement, ensuring certain liquid production capacity after plugging, preventing the injection pressure of the water injection well from being too high, and prolonging the effective period of the water shutoff agent. Under the combined action of the steps, the directional water shutoff is realized, and the problem that the yield is sharply reduced after the oil well is exposed to water in the early stage is solved.

Description

一种底水油藏高含水油井选择性堵水方法A selective water shutoff method for high water cut oil wells in bottom water reservoirs

技术领域technical field

本发明涉及底水油藏采油工程领域,尤其是一种底水油藏高含水油井选择性堵水方法。The invention relates to the field of oil recovery engineering in bottom water reservoirs, in particular to a selective water shutoff method for high water content oil wells in bottom water reservoirs.

背景技术Background technique

具有水体的油气运移成藏后,由于重力分异作用,使得油藏内总是油上水下,而根据油水接触关系可将这类油藏分为边水油藏和底水油藏。与其他类型的油藏相比,边底水油藏的含油面积会与水体直接接触。在油田开发的中前期,边底水会为油藏的开发提供一定的能量,使得油田稳产;但随着生产的继续进行,边底水进一步侵入油层,就会导致油水前缘被突破,地层水舌进或锥进,使油井开始见水,无水采油期缩短、含水上升加快、产油量降低、采出程度降低,从而油藏发效果变差。因而,如何抑制边底水油藏自有水体的侵入和锥进是其开发的重点。After the oil and gas with water bodies migrate and accumulate, due to gravity differentiation, the oil in the reservoir is always above the water, and according to the oil-water contact relationship, such reservoirs can be divided into edge water reservoirs and bottom water reservoirs. Compared with other types of reservoirs, the oil-bearing area of the edge-bottom water reservoir will be in direct contact with the water body. In the middle and early stages of oilfield development, the edge and bottom water will provide certain energy for the development of the oil reservoir, making the oil field stable; The water tongue or cone advance makes the oil well start to see water, the water-free oil production period is shortened, the water cut rises faster, the oil production rate decreases, and the recovery degree decreases, so the reservoir development effect becomes worse. Therefore, how to suppress the intrusion and coning of the natural water body of edge and bottom water reservoirs is the focus of its development.

传统堵水方法主要包括机械堵水以及化学堵水。机械堵水可以精确封堵产水层,后续条件允许时解封继续实施采油、洗井等作业,但需要对井下出水点/层有准确的认识,且成本高昂。化学堵水主要是通过向井下注入化学药品,对产水层实施封堵。化学堵水包括选择性堵水和非选择性堵水。非选择性堵水所用的堵水剂对水层和油层均可造成堵塞,而无选择性。施工时,先找出水层位,选择适当的工艺管柱,将油层与水层分开,而后将堵水剂挤入高含水层,达到封堵的目的;油井非选择性堵水主要用于水泥浆、树脂等一次堵死出水层位。而选择性堵水则是利用化学堵水剂大幅度降低水相渗透率,少降或不降低油(气)相渗透率的化学堵水措施称为选择性堵水;机理是堵水剂利用油、水和岩石性质,以及出油、出水层间的差异来达到选择性堵水。Traditional water shutoff methods mainly include mechanical water shutoff and chemical water shutoff. Mechanical water plugging can accurately seal the water-producing layer, and when the follow-up conditions permit, the blockage can be unblocked to continue oil production, well washing and other operations, but it requires an accurate understanding of the downhole water outlet point/layer, and the cost is high. Chemical water plugging is mainly to plug the water-producing layer by injecting chemicals downhole. Chemical water shutoff includes selective water shutoff and non-selective water shutoff. The water shutoff agent used in non-selective water shutoff can block both water layer and oil layer without selectivity. During construction, first find out the water level, select an appropriate process string, separate the oil layer from the water layer, and then squeeze the water shutoff agent into the high water-bearing layer to achieve the purpose of plugging; the non-selective water shutoff of oil wells is mainly used for Cement slurry, resin, etc. block the outlet layer at one time. Selective water shutoff is the use of chemical water shutoff agents to greatly reduce the permeability of the water phase, and the chemical water shutoff measures that reduce or do not reduce the permeability of the oil (gas) phase are called selective water shutoff; the mechanism is the use of water shutoff agents. Oil, water and rock properties, as well as the differences between oil-producing and water-producing layers, are used to achieve selective water shutoff.

专利CN104629698A公开了一种边底水油藏堵水办法,其采用氮气加强凝胶堵剂对高渗层进行封堵,但若注入压力超过低渗层启动压力,会导致堵剂流入低渗层,对低渗层造成损害。因此,需要发明一种底水油藏高含水油井选择性堵水方法。Patent CN104629698A discloses a water plugging method for edge and bottom water reservoirs, which uses nitrogen-enhanced gel plugging agent to plug high-permeability layers, but if the injection pressure exceeds the start-up pressure of low-permeability layers, the plugging agent will flow into low-permeability layers , causing damage to the low-permeability layer. Therefore, it is necessary to invent a selective water shutoff method for high water cut oil wells in bottom water reservoirs.

发明内容Contents of the invention

本发明的目的是针对目前边底水油藏堵水困难,堵水效果差的问题,提供一种底水油藏高含水油井选择性堵水方法。The purpose of the present invention is to provide a selective water shutoff method for high water content oil wells in bottom water reservoirs in view of the current problem of difficult water shutoff and poor water shutoff effect in edge and bottom water reservoirs.

本发明提供的底水油藏高含水油井选择性堵水方法,其步骤如下:The method for selective water shutoff of high water-cut oil wells in bottom water reservoirs provided by the present invention has the following steps:

S1、通过注入井向地层内高速高压注入氮气,下压井底水锥,增加产油层压力,使后续堵水剂优先进入高渗。S1. Inject nitrogen gas into the formation at high speed and high pressure through the injection well, press down the bottom water cone, increase the pressure of the oil-producing layer, and make the follow-up water shutoff agent preferentially enter the high permeability.

S2、下压井底水锥后,向井中注入起泡剂、高分子溶液、泡沫稳定剂与交联剂四种的混合溶液,混合溶液与步骤S1注入的氮气在多孔介质中混合,在地层中形成凝胶泡沫。S2. After pressing down the bottom hole water cone, inject four kinds of mixed solutions of foaming agent, polymer solution, foam stabilizer and cross-linking agent into the well, and mix the mixed solution with the nitrogen injected in step S1 in the porous medium, Forms a gel foam.

所述高分子溶液为质量百分含量0.3%-0.4%的聚丙烯酰胺溶液。所述起泡剂为脂肪醇醚硫酸钠盐。所述泡沫稳定剂为溴化N,N-二甲基二茂铁基十六烷基甲铵盐改性的疏水改性纳米SiO2颗粒。所述交联剂为有机铬与酚醛树脂按照质量比3:5的复合交联剂;复合交联剂与聚丙烯酰胺的交联时间小于由起泡剂与气体所形成泡沫的半衰期。The polymer solution is a polyacrylamide solution with a mass percent content of 0.3%-0.4%. The foaming agent is sodium fatty alcohol ether sulfate. The foam stabilizer is hydrophobically modified nano- SiO2 particles modified by N,N-dimethylferrocenyl hexadecylmethylammonium bromide. The cross-linking agent is a composite cross-linking agent composed of organic chromium and phenolic resin in a mass ratio of 3:5; the cross-linking time of the composite cross-linking agent and polyacrylamide is less than the half-life of the foam formed by the foaming agent and gas.

S3、开井返排,换小油嘴,以低生产压差,开井生产3-8小时,促进泡沫的形成,同时低生产压差使得高渗层泡沫优先返排,同时暂堵低渗层,有利于后续堵水剂优先进入高渗层。S3. Start the well and flow back, change the small oil nozzle, and use the low production pressure difference to open the well for 3-8 hours to promote the formation of foam. At the same time, the low production pressure difference makes the foam in the high permeability layer flow back preferentially, and at the same time temporarily plug the low permeability layer , which is beneficial for the follow-up water blocking agent to preferentially enter the hyperpermeable layer.

S4、注入堵水剂,堵水剂定向进入产水层,建立人工隔板,实现智能选择性堵水。S4. Inject the water shutoff agent, the water shutoff agent enters the water production layer in a directional manner, and establishes an artificial partition to realize intelligent selective water shutoff.

所述堵水剂筛选需要同时具备以下条件:The screening of the water blocking agent needs to meet the following conditions at the same time:

(1)堵水剂是整体固化或胶凝;(1) The water blocking agent is solidified or gelled as a whole;

(2)堵水剂为分子或离子分散的形式,反应时间长;(2) The water blocking agent is in the form of molecular or ion dispersion, and the reaction time is long;

(3)近井使用的堵剂必须保证在大生产压差下不产出;(3) The plugging agent used near the well must ensure no production under large production pressure difference;

(4)远井使用强度弱的堵剂,近井使用强度高的堵剂。(4) The plugging agent with weak strength is used far from the well, and the plugging agent with high strength is used near the well.

所述堵水剂用量可按下式计算:The amount of water blocking agent can be calculated as follows:

q=π(2r)2q=π(2r) 2

式中:q-堵水剂的总用量,m3;r-封堵半径,m;φ-油层孔隙度,%;h-隔板厚度,m。In the formula: q-total amount of water blocking agent, m 3 ; r-plugging radius, m; φ-reservoir porosity, %; h-thickness of diaphragm, m.

S5、采用聚合物溶液进行过顶替,防止注水井注入压力过高,并延长堵水剂的有效期。S5. Use polymer solution for over-displacement to prevent the injection pressure of the water injection well from being too high and prolong the validity period of the water shutoff agent.

通过以上五个步骤,可实现暂堵保持低渗油层,同时提高堵水剂定向进入高渗产水层能力,在合适位置形成人工隔板,有效堵水。Through the above five steps, temporary plugging can be achieved to maintain the low-permeability oil layer, and at the same time, the ability of the water blocking agent to enter the high-permeability water-producing layer can be improved, and an artificial partition can be formed at a suitable position to effectively block water.

与现有技术相比,本发明的有益之处在于:Compared with the prior art, the benefits of the present invention are:

(1)向井下高速高压注入氮气,氮气进入使水锥下压,方便后续堵水剂进入高渗层;(1) Nitrogen gas is injected downhole at high speed and high pressure, and the nitrogen gas enters to press down the water cone, so that the subsequent water shutoff agent can enter the high permeability layer;

(2)压锥所用氮气成为后续注入泡沫暂堵剂的气源,注入起泡剂后产生的泡沫可以加强压锥效果;通过注入起泡剂溶液及形成泡沫的密度比氮气高,进入产水层后,能进一步强化压锥效果,并且可以暂堵保护油层,保证后续堵水剂准确进入高渗产水层;(2) The nitrogen used for the compression of the cone becomes the gas source for the subsequent injection of the foam temporary plugging agent. The foam generated after the injection of the foaming agent can enhance the effect of the cone compression; the density of the foam formed by injecting the foaming agent solution is higher than that of nitrogen, and enters the produced water After the formation, it can further strengthen the cone pressure effect, and can temporarily plug and protect the oil layer to ensure that the follow-up water blocking agent can accurately enter the high-permeability water-producing layer;

(3)在注入的混合溶液中同时含有起泡剂、高分子溶液、泡沫稳定剂与交联剂,生成凝胶泡沫,有效增加了泡沫的稳定性和强度,同时增加其抗油能力。(3) The injected mixed solution contains a foaming agent, a polymer solution, a foam stabilizer and a crosslinking agent to form a gel foam, which effectively increases the stability and strength of the foam, and at the same time increases its oil resistance.

本发明的其它优点、目标和特征将部分通过下面的说明体现,部分还将通过对本发明的研究和实践而为本领域的技术人员所理解。Other advantages, objectives and features of the present invention will partly be embodied through the following descriptions, and partly will be understood by those skilled in the art through the study and practice of the present invention.

附图说明Description of drawings

图1为初始条件水淹下,地层情况示意图。Figure 1 is a schematic diagram of the stratum under the initial condition of water flooding.

图2为注氮气压锥后,地层情况示意图。Fig. 2 is a schematic diagram of formation conditions after nitrogen injection pressure cone.

图3为注起泡剂、高分子溶液、泡沫稳定剂及交联剂的混合溶液后,地层情况示意图。Fig. 3 is a schematic diagram of the stratum after injecting the mixed solution of foaming agent, polymer solution, foam stabilizer and crosslinking agent.

图4为小油嘴,低生产压差返排时,地层情况示意图。Figure 4 is a schematic diagram of the formation situation when the oil nozzle is small and the flowback is low production pressure difference.

图5为注入人工隔板后,地层情况示意图。Figure 5 is a schematic diagram of the stratum after injection into the artificial partition.

图中,1-低渗产油层,2-高渗产水层,3-底部水体,4-注入氮气,5-注起泡剂、高分子溶液、泡沫稳定剂及交联剂后产生的凝胶泡沫,6-注堵水剂后生成的人工隔板。In the figure, 1-low-permeability oil-producing layer, 2-high-permeability water-producing layer, 3-bottom water body, 4-nitrogen injection, 5-condensate produced after injection of foaming agent, polymer solution, foam stabilizer and cross-linking agent Adhesive foam, 6-artificial partition formed after injection of water blocking agent.

具体实施方式detailed description

以下结合附图对本发明的优选实施例进行说明,应当理解,此处所描述的优选实施例仅用于说明和解释本发明,并不用于限定本发明。The preferred embodiments of the present invention will be described below in conjunction with the accompanying drawings. It should be understood that the preferred embodiments described here are only used to illustrate and explain the present invention, and are not intended to limit the present invention.

实施例1Example 1

本发明的底水油藏高含水油井选择性堵水方法,具体如下:The selective water shutoff method of the high water-cut oil well in the bottom water reservoir of the present invention is specifically as follows:

如图1所示,随着长时间注水生产,油井进入高含水阶段,底水侵入严重,产生水锥,下部高渗层发生水淹。As shown in Fig. 1, with long-term water injection production, the oil well enters the stage of high water cut, and the bottom water invades seriously, resulting in water cone and water flooding in the lower high permeability layer.

此时,如图2所示,通过油管向井下高速高压注入氮气,此时氮气优先进入高渗层,提高高渗层压力,氮气的进入使得侵入水被向下部驱赶,达到下压水锥的目的,可以为后续堵水剂的进入创造条件。由于氮气在高速高压下被注入地层,低渗层也有部分氮气进入,这部分氮气进一步提高了低渗层本身的层内压力。相对于高渗层来说,单位时间内低渗层压力传导较慢,压力下降速度慢,这就导致了注气后高低渗层的层内压力之差会逐渐增大,这使得后续堵水剂在一定的注入压力下可以定向进入高渗产水层。At this time, as shown in Figure 2, nitrogen gas is injected downhole at high speed and high pressure through the tubing. At this time, nitrogen gas preferentially enters the hyperpermeable layer to increase the pressure of the hyperpermeable layer. The entry of nitrogen gas drives the intrusive water to the lower part to reach the pressure of the water cone. The purpose is to create conditions for the entry of subsequent water blocking agents. Since nitrogen is injected into the formation at high speed and high pressure, some nitrogen enters the low-permeability layer, and this part of nitrogen further increases the intralayer pressure of the low-permeability layer itself. Compared with the high-permeability layer, the pressure conduction of the low-permeability layer is slower per unit time, and the pressure drop rate is slower, which leads to the gradual increase of the pressure difference between the high- and low-permeability layers after gas injection, which makes the subsequent water plugging The agent can enter the high-permeability water-producing layer in a certain direction under a certain injection pressure.

随后向井下高速注入混合溶液(起泡剂、高分子溶液、泡沫稳定剂及交联剂的混合溶液),如图3所示。起泡剂在进入地层后,与上一段塞注入的氮气在多孔介质内混合形成凝胶泡沫,在高渗层内形成泡沫后,由于起泡剂及泡沫自身密度大于氮气,可以进一步强化氮气压锥的效果。同时,由于高渗层形成泡沫,降低了自身渗透率,混合溶液开始进入低渗层,在低渗层内与氮气混合产生泡沫,对低渗层产生了暂堵保护。作为优选的,所述高分子溶液可以为0.3%-0.4%的HPAM溶液。所述起泡剂为脂肪醇醚硫酸钠盐(AES)。所述泡沫稳定剂为使用溴化N,N-二甲基二茂铁基十六烷基甲铵盐(Fc16AB)改性的疏水改性纳米SiO2颗粒。所述交联剂为复合交联体系(有机铬:酚醛树脂=3:5)。复合交联剂与聚丙烯酰胺的交联时间小于由起泡剂与气体所形成泡沫的半衰期,保证在只有少量泡沫破裂时,交联剂就能与聚丙烯酰胺发生交联反应。Then inject the mixed solution (mixed solution of foaming agent, polymer solution, foam stabilizer and crosslinking agent) downhole at high speed, as shown in Fig. 3 . After the foaming agent enters the formation, it mixes with the nitrogen injected from the previous plug to form a gel foam in the porous medium. After the foam is formed in the hyperpermeable layer, the density of the foaming agent and the foam itself is greater than that of nitrogen, which can further strengthen the nitrogen pressure. cone effect. At the same time, due to the formation of foam in the high-permeability layer, which reduces its own permeability, the mixed solution begins to enter the low-permeability layer, and mixes with nitrogen in the low-permeability layer to generate foam, which produces temporary plugging protection for the low-permeability layer. Preferably, the polymer solution may be 0.3%-0.4% HPAM solution. The foaming agent is fatty alcohol ether sulfate sodium salt (AES). The foam stabilizer is hydrophobically modified nano-SiO 2 particles modified with N,N-dimethylferrocenyl hexadecylmethylammonium bromide (Fc16AB). The crosslinking agent is a composite crosslinking system (organic chromium: phenolic resin = 3:5). The cross-linking time of the composite cross-linking agent and polyacrylamide is shorter than the half-life of the foam formed by the foaming agent and gas, ensuring that the cross-linking agent and polyacrylamide can undergo cross-linking reaction when only a small amount of foam is broken.

注入一定量混合溶液后,换小油嘴,以低生产压差,开井生产3-8小时,如图4所示。返排时高渗层与低渗层均有产出趋势,地层内流体向井筒方向流动,由于氮气粘度远小于混合溶液及产生的凝胶泡沫,故氮气运移更为容易,返排时氮气从距井筒稍远处运移至井筒附近与起泡剂等溶液进一步充分混合,提高泡沫生成质量,强化暂堵及压锥效果;此外,由于高渗层启动压差小于低渗层,再以低生产压差生产时,高渗层内泡沫会优先返排,高渗层层内压力降低,提高了低渗层和高渗层之间压力的差值,有利于后续堵水剂定向进入高渗层。After injecting a certain amount of mixed solution, replace the nozzle with a small oil nozzle, and start the production for 3-8 hours with low production pressure difference, as shown in Figure 4. Both the high-permeability layer and the low-permeability layer tend to be produced during flowback, and the fluid in the formation flows toward the wellbore. Since the viscosity of nitrogen gas is much smaller than that of the mixed solution and the gel foam produced, nitrogen migration is easier. Move from a little distance away from the wellbore to the vicinity of the wellbore and further fully mix with foaming agent and other solutions to improve the quality of foam generation and strengthen the effect of temporary plugging and cone pressure; During production with low production pressure difference, the foam in the high-permeability layer will flow back preferentially, and the pressure in the high-permeability layer will decrease, which will increase the pressure difference between the low-permeability layer and the high-permeability layer, which is beneficial for the subsequent water shutoff agent to enter the high Seepage layer.

如图5所示,在上述步骤后,向地层内注入水堵剂建立人工隔板,堵水剂定向进入产水层,实现智能选择性堵水。所述堵水剂筛选条件如下:As shown in Figure 5, after the above steps, the water blocking agent is injected into the formation to establish an artificial partition, and the water blocking agent is directed into the water-producing layer to realize intelligent and selective water blocking. The screening conditions of the water blocking agent are as follows:

(1)是整体性堵水剂,即堵剂是整体固化或胶凝。(1) It is an integral water blocking agent, that is, the blocking agent is solidified or gelled as a whole.

(2)所使用的堵水剂最好为分子或离子分散的形式,反应时间应足够长。(2) The water blocking agent used is preferably in the form of molecular or ion dispersion, and the reaction time should be long enough.

(3)堵水剂应是组合型的,堵剂强度应尽量高。(3) The water blocking agent should be combined, and the strength of the blocking agent should be as high as possible.

(4)近井使用的堵水剂必须保证在大生产压差下不产出。(4) The water shutoff agent used near the well must ensure no production under large production pressure difference.

(5)堵水剂的配置和施工应简单易操作,且施工危险性小。(5) The configuration and construction of the water blocking agent should be simple and easy to operate, and the construction risk is small.

(6)堵水剂的成本低、来源广。(6) The cost of water blocking agent is low and the source is wide.

(7)建立隔板的堵剂远井可使用强度弱的堵水剂,近井使用强度高的堵水剂。(7) The plugging agent for establishing the partition can use weak water blocking agent in the far well, and use high strength water blocking agent in the near well.

所述堵水剂用量可按下式计算:The amount of water blocking agent can be calculated as follows:

q=π(2r)2q=π(2r) 2

式中:q-堵剂的总用量,m3;r-封堵半径,m;φ-油层孔隙度,%;h-隔板厚度,m。In the formula: q-total dosage of plugging agent, m 3 ; r-plugging radius, m; φ-reservoir porosity, %; h-baffle thickness, m.

最后,使用聚合物溶液进行过顶替,过顶替也将堵水剂顶替出近井地带一定位置,保证封堵后有一定的产液能力,防止注水井注入压力过高,并延长堵水剂的有效期。Finally, polymer solution is used for over-displacement, which also displaces the water-blocking agent from a certain position near the wellbore to ensure a certain liquid production capacity after plugging, prevent the injection pressure of the water injection well from being too high, and prolong the life of the water-blocking agent. expiration date.

在上述步骤的共同作用下,可实现底水油藏高含水油井智能选择性堵水,解决油井见水后,产量急剧下降的问题。Under the combined action of the above steps, intelligent selective water shutoff of high water cut oil wells in bottom water reservoirs can be realized, and the problem of sharp decline in production after water breakthrough in oil wells can be solved.

实施例2Example 2

将本发明的堵水方法应用于具体的某个底水油藏高含水油井。具体方法如下:The water shutoff method of the present invention is applied to a specific high water cut oil well in a certain bottom water reservoir. The specific method is as follows:

S1、向井中高速高压注入氮气,使氮气进入高渗产水层,氮气的进入使得侵入水被向下部驱赶,达到下压水锥的目的,为后续作业提供条件。根据凝胶泡沫体系研究,最佳氮气用量为步骤S2中注入的混合溶液体积的两倍,混合溶液的体积计算公式:Q=πR2hφ,式中R=10m,h=2m,φ=0.3。氮气注入量采用状态方程PV=nRT换算地面体积,气体注入速度控制在600-900m3/h,气体注入压力高于地层压力。S1. Inject nitrogen gas into the well at high speed and high pressure, so that nitrogen gas enters the high-permeability water-producing layer. The entry of nitrogen gas drives the intrusive water to the lower part, achieving the purpose of pressing down the water cone and providing conditions for subsequent operations. According to the study of the gel foam system, the optimum nitrogen dosage is twice the volume of the mixed solution injected in step S2, the volume calculation formula of the mixed solution: Q=πR 2 hφ, where R=10m, h=2m, φ=0.3 . The amount of nitrogen injection is converted to ground volume using the state equation PV=nRT, the gas injection rate is controlled at 600-900m 3 /h, and the gas injection pressure is higher than the formation pressure.

S2、向井中注入起泡剂、HPAM、交联剂及泡沫稳定剂的混合溶液,其中,起泡剂为脂肪醇醚硫酸钠盐,质量浓度为1%;HPAM质量浓度为0.3%-0.4%;交联剂为复合交联体系(有机铬:酚醛树脂=3:5)。复合交联剂与聚丙烯酰胺的交联时间小于由起泡剂与气体所形成泡沫的半衰期,保证在只有少量泡沫破裂时,交联剂就能与聚丙烯酰胺发生交联反应,质量浓度为0.1%;泡沫稳定剂为使用溴化N,N-二甲基二茂铁基十六烷基甲铵盐(Fc16AB)改性的疏水改性纳米SiO2颗粒,质量浓度为0.1%。混合溶液注入量以步骤S1中公式计算,注入量约为188.4m3S2. Inject a mixed solution of foaming agent, HPAM, cross-linking agent and foam stabilizer into the well, wherein the foaming agent is fatty alcohol ether sulfate sodium salt with a mass concentration of 1%; the mass concentration of HPAM is 0.3%-0.4% ; The cross-linking agent is a composite cross-linking system (organic chromium: phenolic resin = 3:5). The cross-linking time of the composite cross-linking agent and polyacrylamide is less than the half-life of the foam formed by the foaming agent and gas, so that the cross-linking agent can react with polyacrylamide when only a small amount of foam is broken, and the mass concentration is 0.1%; Foam stabilizer is the use of N,N-dimethylferrocenyl hexadecyl methylammonium bromide (Fc16AB) modified hydrophobically modified nano-SiO 2 particles, the mass concentration is 0.1%. The injection volume of the mixed solution is calculated according to the formula in step S1, and the injection volume is about 188.4 m 3 .

S3、混合溶液注入完成后,换小油嘴,以略大于高渗层启动压差的生产压差,开井生产3-8小时,使地层内的氮气与起泡剂充分混合,并排出高渗层内泡沫。S3. After the injection of the mixed solution is completed, change the oil nozzle to a production pressure difference slightly greater than the start-up pressure difference of the hyperpermeable layer, and open the well for 3-8 hours to fully mix the nitrogen in the formation with the foaming agent, and discharge the hyperpermeable Inner foam.

S4、在完成前述步骤后,注入隔板堵水剂,堵水剂采用专利CN104449618B中的耐温耐盐高温自交联就地聚合堵水凝胶。堵水剂用量采用公式q=π(2r)2hφ计算,其中r=10m,h=2m,φ=0.3,注入量约为753.6m3。由于低渗层被暂堵,堵剂注入地层后,会只进入高渗层,并在高渗层横向延伸,在合适的位置建立人工隔板。该堵剂在岩心中的突破压力梯度大于9MPa/m,封堵率达99%。S4. After completing the above steps, inject the water shutoff agent into the partition, and the water shutoff agent adopts the temperature-resistant, salt-resistant and high-temperature self-crosslinking in-situ polymerized water shutoff gel in the patent CN104449618B. The amount of water shutoff agent is calculated using the formula q=π(2r) 2 hφ, where r=10m, h=2m, φ=0.3, and the injection volume is about 753.6m 3 . Since the low-permeability layer is temporarily plugged, after the plugging agent is injected into the formation, it will only enter the high-permeability layer and extend laterally in the high-permeability layer to establish an artificial partition at a suitable position. The breakthrough pressure gradient of the plugging agent in the core is greater than 9MPa/m, and the plugging rate reaches 99%.

S5、使用HPAM聚合物溶液进行过顶替,过顶替液的粘度要大于被顶替液,过顶替也将堵剂顶替出近井地带一定位置,保证封堵后有一定的产液能力,防止注水井注入压力过高,并延长堵水剂的有效期。S5. Use HPAM polymer solution for over-displacement. The viscosity of the over-displacement fluid is greater than that of the displaced fluid. Over-displacement will also displace the plugging agent from a certain position near the wellbore to ensure a certain fluid production capacity after plugging and prevent water injection wells. The injection pressure is too high and the validity period of the water shutoff agent is extended.

采用上述工艺,措施井含水下降18.9%,堵水效果良好。Using the above-mentioned technology, the water content of the well is reduced by 18.9%, and the water plugging effect is good.

综上所述,本发明的堵水方法是在井筒中注入氮气压锥后,注入起泡剂、高分子溶液、泡沫稳定剂及交联剂的混合溶液,在地层内形成凝胶泡沫。再通过返排清理高渗层内泡沫,达到暂堵低渗,使后续堵水剂定向进入高渗层的目的。接下来注入堵水剂,堵水剂在产水层内合适位置建立人工隔板,防止底水上窜,抑制底水锥进。最后通过聚合物溶液过顶替,将堵水剂顶替出近井地带一定位置,保证封堵后有一定的产液能力,防止注水井注入压力过高,并延长堵水剂的有效期。In summary, the water plugging method of the present invention is to inject a mixed solution of foaming agent, polymer solution, foam stabilizer and crosslinking agent after injecting nitrogen pressure cone into the wellbore to form gel foam in the formation. Then, the foam in the high-permeability layer is cleaned by flowback to achieve the purpose of temporary plugging and low-permeability, so that the subsequent water blocking agent can enter the high-permeability layer in a directional manner. Next, water shutoff agent is injected, and water shutoff agent is used to establish artificial partitions at appropriate positions in the water-producing layer to prevent bottom water from escaping and suppress bottom water coning. Finally, through polymer solution over-displacement, the water blocking agent is displaced from a certain position near the wellbore to ensure a certain liquid production capacity after plugging, prevent the injection pressure of the water injection well from being too high, and prolong the validity period of the water blocking agent.

以上所述,仅是本发明的较佳实施例而已,并非对本发明作任何形式上的限制,虽然本发明已以较佳实施例揭露如上,然而并非用以限定本发明,任何熟悉本专业的技术人员,在不脱离本发明技术方案范围内,当可利用上述揭示的技术内容作出些许更动或修饰为等同变化的等效实施例,但凡是未脱离本发明技术方案的内容,依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与修饰,均仍属于本发明技术方案的范围内。The above description is only a preferred embodiment of the present invention, and does not limit the present invention in any form. Although the present invention has been disclosed as above with preferred embodiments, it is not intended to limit the present invention. Anyone familiar with this field Those skilled in the art, without departing from the scope of the technical solution of the present invention, can use the technical content disclosed above to make some changes or modify equivalent embodiments with equivalent changes. Any simple modifications, equivalent changes and modifications made to the above embodiments by the technical essence still belong to the scope of the technical solution of the present invention.

Claims (7)

1. The selective water plugging method for the high-water-cut oil well of the bottom water reservoir is characterized by comprising the following steps
S1, injecting nitrogen into a stratum through an injection well, and pressing down a well bottom water cone;
s2, injecting four mixed solutions of a foaming agent, a high molecular solution, a foam stabilizer and a cross-linking agent into the well, mixing the mixed solution with the nitrogen injected in the step S1 in a porous medium, and forming gel foam in the stratum;
s3, opening a well for flowback, replacing a small oil nozzle, opening the well for production for 3-8 hours at low production pressure difference, promoting the formation of foam, and simultaneously leading the foam of a high-permeability layer to preferentially flowback due to the low production pressure difference so as to temporarily block the low-permeability layer;
s4, injecting a water shutoff agent, enabling the water shutoff agent to directionally enter a water production layer, and establishing an artificial partition plate to realize intelligent selective water shutoff;
and S5, performing displacement, preventing the injection pressure of the water injection well from being too high, and prolonging the validity period of the water shutoff agent.
2. The selective water plugging method for the bottom water reservoir high water cut oil well as claimed in claim 1, wherein the polymer solution is 0.3-0.4% by mass of polyacrylamide solution.
3. The selective water shutoff method for the bottom water reservoir high water cut oil well according to claim 2, characterized in that the foaming agent is a sodium salt of fatty alcohol ether sulfate.
4. The selective water shutoff method for the bottom water reservoir high-water-cut oil well as defined in claim 3, characterized in that the foam stabilizer is nanometer SiO hydrophobically modified by N, N-dimethyl ferrocenyl hexadecyl methyl ammonium bromide 2 And (3) granules.
5. The selective water shutoff method for the bottom water reservoir high water cut oil well according to claim 4, characterized in that the cross-linking agent is a composite cross-linking agent of organic chromium and phenolic resin according to a mass ratio of 3; the crosslinking time of the composite crosslinking agent and the polyacrylamide is less than the half-life of the foam formed by the foaming agent and the gas.
6. The selective water shutoff method for the bottom water reservoir high water cut oil well according to claim 1, wherein the amount of the water shutoff agent is calculated according to the following formula:
q=π(2r) 2
in the formula: q-total amount of water shutoff agent, m 3 (ii) a r-plugging radius, m; phi-oil layer porosity,%; h-spacer thickness, m.
7. The selective water plugging method for the bottom water reservoir high water cut oil well according to claim 6, wherein the water plugging agent screening simultaneously needs to meet the following conditions:
(1) The water shutoff agent is integrally solidified or gelatinized;
(2) The water shutoff agent is in a molecular or ion dispersion form, and the reaction time is long;
(3) The plugging agent used near the well must ensure that the plugging agent is not produced under large production pressure difference;
(4) The far well uses a plugging agent with weak strength, and the near well uses a plugging agent with high strength.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111334268B (en) * 2020-03-13 2022-03-25 西安石油大学 Bottom water reservoir multi-section plugging agent and plugging method thereof
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CN115074098A (en) * 2022-07-26 2022-09-20 西南石油大学 Preparation and application of a double-crosslinked nano-reinforced foam gel water blocking agent
CN116104459B (en) * 2022-11-15 2024-12-13 长江大学 A method for controlling bottom water coning in oil reservoirs based on establishing microbial mineralization partitions
CN119122489A (en) * 2023-06-13 2024-12-13 中国石油天然气股份有限公司 A method for reducing the bottom water cone interface in heavy oil reservoirs

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5203834A (en) * 1990-12-21 1993-04-20 Union Oil Company Of California Foamed gels having selective permeability
US5259453A (en) * 1992-06-25 1993-11-09 Phillips Petroleum Company Blocking water coning in oil and gas producing reservoirs
CN101139920A (en) * 2007-10-26 2008-03-12 辽河石油勘探局 Dibasic composite horizontal well bottom water plugging technique
CN101493006A (en) * 2009-02-23 2009-07-29 中国海洋石油总公司 Method for controlling bottom water fingering by foam
CN101798500A (en) * 2010-04-01 2010-08-11 中国石油大学(华东) Plugging agent with double plugging function and filling method thereof
CN109025953A (en) * 2016-08-23 2018-12-18 中国石油化工股份有限公司 A kind of application method of the gel foamable composition of heavy crude heat extraction inhibition bottom water coning
CN109577909A (en) * 2018-12-24 2019-04-05 陕西明德石油科技有限公司 A kind of extra permeability oilfield selectivity frothy gel water plugging and profile controlling method
CN111334268A (en) * 2020-03-13 2020-06-26 西安石油大学 A kind of multi-slug plugging agent for bottom water reservoir and plugging method thereof
CN111810102A (en) * 2020-06-30 2020-10-23 中国石油天然气股份有限公司 Method for controlling bottom water channeling by utilizing gas water lock effect
CN111927387A (en) * 2020-08-28 2020-11-13 西南石油大学 Two-stage temporary plugging combined selective water plugging method
CN112831318A (en) * 2021-01-06 2021-05-25 山东科技大学 A kind of multifunctional plugging agent for coal mine and preparation method thereof

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5203834A (en) * 1990-12-21 1993-04-20 Union Oil Company Of California Foamed gels having selective permeability
US5259453A (en) * 1992-06-25 1993-11-09 Phillips Petroleum Company Blocking water coning in oil and gas producing reservoirs
CN101139920A (en) * 2007-10-26 2008-03-12 辽河石油勘探局 Dibasic composite horizontal well bottom water plugging technique
CN101493006A (en) * 2009-02-23 2009-07-29 中国海洋石油总公司 Method for controlling bottom water fingering by foam
CN101798500A (en) * 2010-04-01 2010-08-11 中国石油大学(华东) Plugging agent with double plugging function and filling method thereof
CN109025953A (en) * 2016-08-23 2018-12-18 中国石油化工股份有限公司 A kind of application method of the gel foamable composition of heavy crude heat extraction inhibition bottom water coning
CN109577909A (en) * 2018-12-24 2019-04-05 陕西明德石油科技有限公司 A kind of extra permeability oilfield selectivity frothy gel water plugging and profile controlling method
CN111334268A (en) * 2020-03-13 2020-06-26 西安石油大学 A kind of multi-slug plugging agent for bottom water reservoir and plugging method thereof
CN111810102A (en) * 2020-06-30 2020-10-23 中国石油天然气股份有限公司 Method for controlling bottom water channeling by utilizing gas water lock effect
CN111927387A (en) * 2020-08-28 2020-11-13 西南石油大学 Two-stage temporary plugging combined selective water plugging method
CN112831318A (en) * 2021-01-06 2021-05-25 山东科技大学 A kind of multifunctional plugging agent for coal mine and preparation method thereof

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
氮气泡沫凝胶复合堵水体系在中海油LD-52油田的应用;刘冬冬等;《辽宁化工》;20200925(第09期);全文 *
氮气泡沫在海上高含水油田选择性堵水中的应用;孙鹏霄等;《石油钻采工艺》;20160120(第01期);全文 *
氮气泡沫堵调技术在热采水平井开发中的应用――以LF油田馆陶组为例;韩红旭等;《石油地质与工程》;20170925(第05期);全文 *
氮气泡沫驱在黄沙坨油田中的应用;马东侠;《电子制作》;20131108(第17期);全文 *
缝洞型油藏不同井间连通模式对调剖的影响;金发扬等;《科技导报》;20151228(第24期);全文 *
缝洞型油藏提高"阁楼油"采出程度物理模拟实验;季晓靖等;《断块油气田》;20160525(第03期);全文 *

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