Disclosure of Invention
The invention aims to provide a corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column which can effectively prevent chloride ions from corroding the inner wall and the outer wall of a high-strength steel pipe, can improve the relevant bearing index and durability of the marine aggregate seawater concrete of the high-strength steel pipe and prolong the service life of the marine aggregate seawater concrete combined column.
In order to achieve the purpose, the technical scheme of the invention is as follows:
the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column consists of marine aggregate seawater concrete, a high-strength steel pipe and CFRP cloth; the CFRP cloth is adhered to the inner wall and the outer wall of the high-strength steel pipe to form a CFRP-high-strength steel composite pipe, and the marine aggregate concrete is filled in the CFRP-high-strength steel composite pipe. The CFRP cloth is adhered to the inner wall and the outer wall of the high-strength steel pipe, the external fiber bundles can prevent internal steel from being corroded and play a role in reinforcing the internal steel, and the CFRP cloth has the advantages of light weight, high strength, corrosion resistance and good mechanical property of steel pipe concrete.
Further, the marine aggregate seawater concrete comprises the following raw materials in parts by weight: 500 portions of cementing material 400-.
Further, the mineral admixture is any one or any combination of silica fume and fly ash.
Further, the cementing material is ordinary portland cement.
Further, the preparation method of the marine aggregate seawater concrete comprises the following steps:
s1, airing and drying the coral coarse aggregate and the sea sand, and controlling the water content within 1%;
s2, dry-mixing the coral coarse aggregate and the sea sand dried in the step S1 to be uniform, then adding part of seawater and stirring to enable the stirred mixture to be in a semi-wet state, and obtaining a mixture I;
s3, stirring the gelled material and the mineral admixture mixture I uniformly to obtain a mixture II;
and S4, adding the residual seawater into the mixture II, adding a water reducing agent, and uniformly stirring to obtain the marine aggregate seawater concrete.
The invention also provides a manufacturing method of the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column, which comprises the following steps:
(1) cutting the CFRP cloth into corresponding inner wall CFRP cloth and outer wall CFRP cloth according to the sizes of the inner wall and the outer wall of the high-strength steel pipe;
(2) cleaning dust and attached impurities on the inner and outer surfaces of the high-strength steel pipe, and keeping the inner and outer surfaces of the steel pipe dry;
(3) uniformly coating structural adhesive on the inner wall of the high-strength steel pipe and two surfaces of the CFRP cloth on the inner wall, and winding the CFRP cloth on the inner wall onto an acrylic rod with the diameter of 1/4-1/6 of the inner diameter of the high-strength steel pipe;
(4) placing the acrylic rod wound with the CFRP cloth on the inner wall into a high-strength steel pipe, aligning and fixing the CFRP cloth on the inner wall with two ends of the high-strength steel pipe, placing a carbon fiber rod behind the acrylic rod, slowly rotating the carbon fiber rod to drive the acrylic rod to roll forwards, simultaneously separating the CFRP cloth on the inner wall from the acrylic rod and sticking the CFRP cloth on the inner wall of the high-strength steel pipe to the inner wall of the high-strength steel pipe, rolling the carbon fiber rod around the inner wall of the high-strength steel pipe again to discharge air bubbles, and ensuring that the CFRP cloth on the inner wall is tightly attached to the inner wall of the high-strength steel pipe;
(5) paving outer wall CFRP cloth and uniformly coating structural adhesive, and uniformly coating the outer wall of the high-strength steel pipe with the structural adhesive; firstly, horizontally placing and fixing a high-strength steel pipe, aligning and attaching one end of outer wall CFRP cloth with the high-strength steel pipe, pressing the end of the outer wall CFRP cloth after leveling bubbles, rotating the high-strength steel pipe to attach the residual outer wall CFRP cloth to the outer wall of the high-strength steel pipe, and repeating the step until the outer wall CFRP cloth is completely attached to the high-strength steel pipe to obtain a composite pipe, vertically placing the composite pipe at a clean and dry place, and after the structural adhesive is solidified, if 2 or more than 2 layers of outer wall CFRP cloth need to be attached to the outer wall of the composite pipe;
(6) and injecting the marine aggregate seawater concrete into the composite pipe, capping the pipe top of the composite pipe by using cement mortar, and curing to obtain the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column.
Further, the structural adhesive is carbon fiber impregnated adhesive, and the mass ratio of the adhesive A to the adhesive B of the carbon fiber impregnated adhesive is 2: 1, mixing.
Furthermore, the CFRP cloth is formed by weaving unidirectional continuous carbon fibers, has the characteristics of high strength, small density, thin thickness and the like, and basically does not increase the self weight and the section size of a member.
Further, the strength of the high-strength steel pipe is Q345 or more.
The corrosion-resistant CFRP-high-strength steel composite pipe takes a high-strength steel pipe as an inner core, steel and fiber materials wrapped outside are bonded and glued to form a whole through a resin matrix, the external fiber bundles can prevent the internal steel from being corroded and play a role in reinforcing the internal steel, and the internal steel makes up the disadvantage of poor shearing resistance of the CFRP material. Therefore, the corrosion-resistant CFRP-high-strength steel composite pipe combines the advantages of steel and CFRP, is expected to become a substitute of the traditional steel to be applied to ocean engineering construction, and provides a new idea for the development of ocean civil engineering.
The invention at least comprises the following beneficial effects:
1. the CFRP cloth adopted by the invention is a lightweight material taking carbon fiber fabric as a reinforcement, has the advantages of high tensile strength, linear elasticity, light weight, strong corrosion resistance, environmental protection and the like, is adhered to the inner wall and the outer wall of the high-strength steel pipe to form the CFRP-high-strength steel composite pipe, the fiber bundles outside the composite pipe can prevent internal steel from being corroded and play a role in reinforcing the internal steel, and the internal steel overcomes the defects of poor shear resistance and easy brittle fracture of the CFRP material. In addition, limited by the current technical level, the composite column is manufactured by using the steel pipe and the CFRP cloth with greater difficulty, so that the manufacturing process is complex, the manufacturing period is long, and the cost is high. The CFRP-high-strength steel composite pipe combines the advantages of steel and CFRP, has the advantages of corrosion resistance, light weight, high strength, good ductility and the like, and can promote the development of marine and offshore construction according to local conditions.
2. The marine aggregate seawater concrete adopted by the invention is composed of the following raw materials: coral coarse aggregate, sea sand, a cementing material, seawater, a mineral admixture and a water reducing agent, wherein the coral and the sea sand are respectively used as concrete coarse aggregate and concrete fine aggregate, and the seawater is used as water for mixing and culturing, which can be obtained locally, thereby reducing the production and transportation time and the economic cost; the added mineral admixture can effectively fill gaps in the coral coarse aggregate and improve the mechanical property of the marine aggregate concrete; the added water reducing agent can greatly improve the construction performance of the marine concrete.
3. The corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete composite column manufactured by the invention simultaneously solves two fundamental problems of building material source shortage and building structure service life shortening in marine engineering construction. In addition, the novel combined column has the characteristics of high bearing capacity, high rigidity, high ductility and other mechanical properties, and has remarkable advantages in a large-span heavy-load structural system of ocean engineering.
Detailed Description
The invention is further described with reference to the following figures and specific examples.
Example 1
The method of the invention is used for manufacturing a corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete composite column. The height of the high-strength steel pipe is 600mm, the diameter is 152mm, the wall thickness is 5mm, and the strength is Q345; the length of the cut CFRP cloth is 500mm, the width of the cut CFRP cloth is 600mm, the core concrete adopts marine aggregate seawater concrete, and the strength grade is C40. The method specifically comprises the following steps:
(I) manufacturing corrosion-resistant CFRP-high-strength steel composite pipe
Firstly, cleaning dust and impurities on the inner and outer surfaces of the high-strength steel pipe, and keeping the inner and outer surfaces of the high-strength steel pipe dry;
cutting and splicing a piece of required inner wall CFRP cloth according to design requirements, and uniformly coating structural adhesive on the inner wall of the high-strength steel pipe and two sides of the inner wall CFRP cloth; the structural adhesive is carbon fiber impregnated adhesive HM-180C3P, and specifically comprises an adhesive A and an adhesive B of the carbon fiber impregnated adhesive HM-180C3P in a mass ratio of 2: 1 are mixed.
Thirdly, winding the CFRP cloth on the inner wall onto an acrylic rod with the diameter being about 1/5 of the high-strength steel pipe, placing the acrylic rod into the high-strength steel pipe, aligning and fixing the CFRP cloth on the inner wall with two ends of the high-strength steel pipe, placing a carbon fiber rod behind the acrylic rod, slowly rotating the carbon fiber rod to drive the acrylic rod to roll forwards and simultaneously separate the CFRP cloth on the inner wall from the acrylic rod to be adhered to the inner wall of the high-strength steel pipe, and rolling the carbon fiber rod again for a circle around the inner wall of the high-strength steel pipe to discharge air bubbles so as to ensure that the CFRP cloth on the inner wall is tightly adhered to the inner wall of the high-strength steel pipe;
fourthly, cutting and splicing a piece of needed outer wall CFRP cloth according to design requirements, tiling the outer wall CFRP cloth and uniformly coating structural adhesive, and uniformly coating the outer wall of the high-strength steel pipe with the structural adhesive; firstly, horizontally placing and fixing a high-strength steel pipe, aligning and attaching one end of outer wall CFRP cloth to the high-strength steel pipe, pressing the end of the outer wall CFRP cloth after leveling bubbles, rotating the high-strength steel pipe to attach the residual outer wall CFRP cloth to the outer wall of the high-strength steel pipe, and performing the process until the outer wall CFRP cloth is completely attached to the steel pipe as shown in figure 3, and then leveling uneven places to remove bubbles and supplement glue at required places; and after the structural adhesive is solidified, the process of adhering CFRP cloth on the outer wall of the inner wall and the outer wall of the high-strength steel pipe is finished, and the manufacturing of the corrosion-resistant CFRP-high-strength steel composite pipe is finished.
(II) preparing marine aggregate seawater concrete
The marine aggregate seawater concrete provided by the embodiment comprises coral coarse aggregate, sea sand, a cementing material, seawater, a mineral admixture and a water reducing agent, and is prepared from the following raw materials in parts by weight: 455 parts of ordinary portland cement, 656 parts of coral coarse aggregate, 760 parts of sea sand, 260 parts of seawater, 40 parts of silica fume, 40 parts of fly ash and 0.84 part of water reducing agent, wherein the water reducing agent is a polycarboxylic acid high-performance water reducing agent. The preparation method of the marine aggregate seawater concrete comprises the following steps:
step one, drying coral coarse aggregate and sea sand in the sun, and controlling the water content within 1%;
secondly, putting the coral coarse aggregate and the sea sand dried in the first step into a stirrer for dry stirring until the mixture is uniform, and then adding half of seawater for stirring for 2 minutes to ensure that the mixture is in a semi-wet state;
thirdly, putting the cementing material and the mineral admixture into a stirrer and stirring the mixture and the product obtained in the second step to be uniform;
and step four, adding the residual seawater used in the step two into the product obtained in the step three, adding a water reducing agent, and stirring uniformly to obtain the marine aggregate seawater concrete.
(III) manufacturing corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column
Firstly, sealing one end of a manufactured corrosion-resistant CFRP-high-strength steel composite pipe to prevent slurry leakage in the pouring process, and fixing the corrosion-resistant CFRP-high-strength steel composite pipe on a horizontal ground;
secondly, pouring the prepared marine aggregate seawater concrete into the composite pipe in three layers, and fully vibrating by using a vibrating rod when pouring each layer so as to prevent a honeycomb pitted surface formed due to insufficient concrete flow and prevent segregation and bleeding caused by excessive vibration;
and thirdly, performing slurry collection treatment on the poured surface concrete of the column top to ensure the flatness of the column top, capping the tube top with cement mortar, and periodically maintaining for 28 days to finish the manufacture of the corrosion-resistant CFRP-high-strength steel composite tube marine aggregate seawater concrete combined column.
As shown in fig. 1, in order to manufacture the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete composite column, the inner wall CFRP cloth is adhered to the inner wall of the high-strength steel pipe, the outer wall CFRP cloth is adhered to the outer wall of the high-strength steel pipe, and the marine aggregate concrete is filled in the CFRP-high-strength steel composite pipe.
Example 2
A corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column is composed of marine aggregate seawater concrete, a high-strength steel pipe and CFRP cloth; the CFRP cloth is adhered to the inner wall and the outer wall of the high-strength steel pipe to form a CFRP-high-strength steel composite pipe, and the marine aggregate concrete is filled in the CFRP-high-strength steel composite pipe. The manufacturing method of the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column comprises the following three main steps: CFRP cloth is pasted on the inner wall of the high-strength steel pipe, CFRP cloth is pasted on the outer wall of the high-strength steel pipe, and marine aggregate concrete is filled in the CFRP cloth and the CFRP cloth; the method comprises the following specific steps:
step 1) calculating the area of an inner wall according to the inner diameter of a high-strength steel pipe, designing the transverse and longitudinal lap joint lengths according to GB50608-2020 fiber reinforced composite engineering application technical standard, and splicing and pasting several cut sections of CFRP cloth into complete inner wall CFRP cloth capable of winding the inner wall for a circle;
step 2) carrying out rust removal treatment on the inner and outer surfaces of the high-strength steel pipe, then wiping and cleaning the inner and outer walls of the high-strength steel pipe by using alcohol, removing dust and attached impurities, and keeping the inner wall of the column dry and comfortable so as to ensure that the bonding property of the structural adhesive in the subsequent process is not influenced;
step 3) preparing a structural adhesive according to the method of the embodiment 1, preparing an acrylic rod with the diameter being about 1/5 of the high-strength steel pipe and a solid carbon fiber rod for adhering the CFRP cloth on the inner wall, wherein the acrylic rod with the proper size can ensure uniform adhesive coating when adhering the CFRP cloth on the inner wall by using the self weight of the acrylic rod, and simultaneously, the CFRP cloth is prevented from being driven to roll together when rolling due to too large self weight; spreading CFRP cloth on the inner wall on a table top, and uniformly coating structural adhesive on the inner wall of the high-strength steel pipe;
step 4) winding the inner wall CFRP cloth uniformly coated with the structural adhesive on an acrylic rod temporarily in a smooth manner, hanging the acrylic rod and the inner wall CFRP cloth in a horizontal manner to penetrate through the inner wall of the high-strength steel pipe, ensuring that the wound inner wall CFRP cloth does not fall off and does not contact the inner wall of the round pipe in the process, aligning the front end and the rear end of the inner wall CFRP cloth to be attached to the mark points at the upper end and the lower end of the high-strength steel pipe, and slowly putting down the acrylic rod to lightly press the inner wall of the steel pipe;
step 5) slowly rotating the acrylic rod along the inner wall of the high-strength steel pipe to enable the CFRP cloth on the inner wall to be separated from the acrylic rod and to be attached to the inner wall of the high-strength steel pipe, repeatedly extruding the CFRP cloth separated from the acrylic rod by using a solid carbon fiber rod, extruding bubbles on the inner wall and compacting the CFRP cloth on the inner wall, and ensuring that the CFRP cloth on the inner wall is completely attached to the inner wall of the steel pipe;
and 6) executing the step 5) until the CFRP cloth on the inner wall completely falls off from the acrylic rod and is completely compacted, suspending and drawing the acrylic rod and the solid carbon fiber rod out of the high-strength steel pipe in a suspending manner in sequence, wherein the CFRP cloth on the adhered inner wall cannot be touched in the process, horizontally placing the composite pipe on which the CFRP cloth on the inner wall is adhered at a clean and dry position for waiting for solidification of the structural adhesive, and finishing the process of adhering the CFRP cloth on the inner wall of the high-strength steel pipe.
Step 7) cutting the CFRP cloth into corresponding outer wall CFRP cloth according to the size of the outer wall of the high-strength steel pipe, tiling the outer wall CFRP cloth, uniformly coating structural adhesive on the joint surface of the outer wall CFRP cloth and the pipe, and uniformly coating the structural adhesive on the outer wall of the high-strength steel pipe; fixing the high-strength steel pipe, distributing CFRP (carbon fiber reinforced plastics) cloth close to the steel pipe horizontally to be attached to the steel pipe, leveling bubbles, pressing the end of the CFRP cloth to rotate the steel pipe to enable the residual CFRP cloth to be attached to the outer wall of the steel pipe, and carrying out the process until the CFRP cloth on the outer wall is completely attached to the steel pipe;
and 8) vertically placing the high-strength steel pipe adhered with the CFRP cloth on the outer wall, removing air bubbles at uneven places and supplementing glue at required places, vertically placing the finished composite pipe at a clean and dry place, after the structural glue is solidified, finishing the process of adhering the CFRP cloth on the outer wall of the high-strength steel pipe, and repeating the step of adhering the CFRP cloth on the outer wall of the high-strength steel pipe if 2 or more layers of CFRP cloth are adhered on the outer wall of the high-strength steel pipe.
Step 9) sealing one end of the manufactured corrosion-resistant CFRP-high-strength steel composite pipe to prevent slurry leakage in the pouring process, and fixing the corrosion-resistant CFRP-high-strength steel composite pipe on a horizontal ground; then injecting the prepared marine aggregate seawater concrete into the pipe, wherein the marine aggregate seawater concrete is prepared from the following raw materials in parts by weight: 425 parts of ordinary portland cement, 630 parts of coral coarse aggregate, 720 parts of sea sand, 240 parts of sea water, 40 parts of silica fume, 35 parts of fly ash and 0.82 part of water reducing agent, and reasonable layered vibration is needed to avoid honeycomb pitted surface of concrete in the pipe; and finally, sealing the top of the pipe by using cement mortar, and curing for 28 days at regular intervals to finish the manufacture of the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column.
The preparation method of the marine aggregate seawater concrete comprises the following steps:
s1, airing and drying the coral coarse aggregate and the sea sand, and controlling the water content within 1%;
s2, dry-mixing the coral coarse aggregate and the sea sand dried in the step S1 to be uniform, then adding part of seawater and stirring to enable the stirred mixture to be in a semi-wet state, and obtaining a mixture I;
s3, stirring the gelled material and the mineral admixture mixture I uniformly to obtain a mixture II;
and S4, adding the residual seawater into the mixture II, adding a water reducing agent, and uniformly stirring to obtain the marine aggregate seawater concrete.
Example 3
The manufacturing method of the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column is the same as that in the embodiment 1, wherein the marine aggregate seawater concrete is composed of the following raw materials in parts by weight: 400 parts of ordinary portland cement, 600 parts of coral coarse aggregate, 700 parts of sea sand, 200 parts of seawater, 30 parts of silica fume, 40 parts of fly ash and 0.8 part of water reducing agent, wherein the water reducing agent is a polycarboxylic acid high-performance water reducing agent.
Example 4
The manufacturing method of the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column is the same as that in the embodiment 2, wherein the marine aggregate seawater concrete is composed of the following raw materials in parts by weight: 500 parts of ordinary portland cement, 700 parts of coral coarse aggregate, 800 parts of sea sand, 300 parts of seawater, 50 parts of silica fume, 40 parts of fly ash and 0.9 part of water reducing agent, wherein the water reducing agent is a polycarboxylic acid high-performance water reducing agent.
Effect verification
In order to further illustrate that the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column has the characteristics of high bearing capacity, high rigidity, high ductility and other mechanical properties, and simultaneously proves that the manufacturing method of the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column has great influence on the mechanical properties of a finished product, the applicant performs the following comparative tests:
the test was carried out in six groups:
a first group: the high-strength steel marine aggregate seawater concrete column (without CFRP cloth) manufactured by the method of the embodiment 1 of the invention;
second group: firstly, manufacturing a CFRP cloth-coated high-strength pipe according to the method disclosed in the Chinese patent with the application number of CN201710200442.4, coating two layers of CFRP cloth, preparing marine aggregate seawater concrete according to the embodiment 1 of the invention, and finally combining to form the CFRP cloth-coated high-strength pipe marine aggregate seawater concrete column (CFRP cloth without an inner wall);
third group: manufacturing a CFRP cloth-coated high-strength pipe according to the method of the embodiment 1 of the invention, coating two layers of CFRP cloth, preparing marine aggregate seawater concrete according to the embodiment 1 of the invention, and finally combining to form a CFRP cloth-coated high-strength pipe marine aggregate seawater concrete column (CFRP cloth without an inner wall);
and a fourth group: the high-strength tube marine aggregate seawater concrete column internally adhered with the CFRP cloth manufactured according to the embodiment 1 of the invention has a layer of CFRP cloth (CFRP cloth without an outer wall) internally adhered;
fifth and sixth groups: the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column manufactured according to the embodiment 1 of the invention is characterized in that the fifth group is wrapped by one layer and internally pasted by one layer of CFRP cloth, and the sixth group is wrapped by two layers and internally pasted by one layer of CFRP cloth.
The six groups of marine aggregate seawater concrete composite columns are subjected to partial performance test, and the recorded data are shown in table 1:
TABLE 1
According to the table 1, the bearing capacity of the marine aggregate concrete column with the single-layer CFRP cloth high-strength steel pipes pasted on the inner side is higher than that of the marine aggregate concrete column with the double-layer CFRP cloth high-strength steel pipes pasted on the outer side, the bearing capacity of the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate concrete combined column formed by pasting CFRP cloth on the two sides is also obviously higher than that of the marine aggregate concrete columns with the CFRP cloth high-strength steel pipes pasted on the single sides of the second to the fourth groups, and the secondary rigidity of the combined column after yielding is also improved to a certain extent; meanwhile, the good mechanical property of the high-strength steel pipe enables the combined column to have a larger axial-pressure ductility coefficient and better deformation performance, so that the corrosion-resistant CFRP-high-strength steel composite pipe made by simultaneously adhering CFRP cloth on the inner wall and the outer wall has better mechanical property and corrosion resistance, and the corrosion-resistant CFRP-high-strength steel composite pipe marine aggregate seawater concrete combined column compounded with the marine aggregate seawater concrete is a novel combined structure with high bearing capacity, large rigidity and high ductility.
Although the present invention has been described with respect to the preferred embodiments, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.