CN1133601C - Grinding aid for cement - Google Patents
Grinding aid for cement Download PDFInfo
- Publication number
- CN1133601C CN1133601C CNB011283505A CN01128350A CN1133601C CN 1133601 C CN1133601 C CN 1133601C CN B011283505 A CNB011283505 A CN B011283505A CN 01128350 A CN01128350 A CN 01128350A CN 1133601 C CN1133601 C CN 1133601C
- Authority
- CN
- China
- Prior art keywords
- cement
- gram
- sodium
- grinding aid
- grams
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004568 cement Substances 0.000 title claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 6
- 229920001732 Lignosulfonate Polymers 0.000 claims abstract description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims abstract description 6
- 229930006000 Sucrose Natural products 0.000 claims abstract description 6
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000019357 lignosulphonate Nutrition 0.000 claims abstract description 6
- 239000001205 polyphosphate Substances 0.000 claims abstract description 6
- 235000011176 polyphosphates Nutrition 0.000 claims abstract description 6
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 6
- 239000011734 sodium Substances 0.000 claims abstract description 6
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 6
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims abstract description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000012452 mother liquor Substances 0.000 claims description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 5
- 150000005215 alkyl ethers Chemical class 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 5
- OGVSROVKLZVLES-UHFFFAOYSA-N C1(=CC=CC2=CC=CC=C12)S(=O)(=O)O.CC1=C(C=CC=C1)C Chemical compound C1(=CC=CC2=CC=CC=C12)S(=O)(=O)O.CC1=C(C=CC=C1)C OGVSROVKLZVLES-UHFFFAOYSA-N 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000003068 static effect Effects 0.000 abstract description 3
- -1 alkyl ether sulfate Chemical class 0.000 abstract description 2
- 230000005611 electricity Effects 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000004117 Lignosulphonate Substances 0.000 abstract 1
- 229920000388 Polyphosphate Polymers 0.000 abstract 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 abstract 1
- 229940043264 dodecyl sulfate Drugs 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 4
- 238000005242 forging Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/48—Clinker treatment
- C04B7/52—Grinding ; After-treatment of ground cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/52—Grinding aids; Additives added during grinding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention discloses a grinding aid for cement, which is composed of 70 to 80% of triethanolamine and 20 to 30% of mother liquid according to weight percentage, wherein the mother liquid is mainly prepared from alkylpolyglycoside, sodium humate, lignosulphonate, sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether, polyphosphate, beta-hydroxyalkylamine, sodium dodecanesulphonate, high-grade alkyl ether sulfate, xylene naphthalenesulfenesulfonate, sldium lauryl sulfate, white sugar and water according to a certain proportion. The grinding aid can well solve the ball holding and grinding holding phenomenon of a ball mill because of reasons of static electricity generation, etc. in the grinding process of the cement. The present invention not only can increase the machine-hour output of the cement but also can increase the intensity, the normal consistency and the setting time of the cement after the grinding aid is used, and the production cost is reduced.
Description
Technical field
The invention belongs to the cement manufacturing technology, is composition and the content that discloses a kind of cement grinding aid specifically.
Background technology
In the process of making cement, behind grog, additional materials and the gypsum mixtures feeding grinding machine of cement, in the process of grinding, because violent, frequent, complicated friction and bump between material and the material, between material and the grinding element, make material produce static, these materials that have electric charge can be adsorbed on the surface of steel ball and grinding element, cause cement mill serious bag ball, bag forging phenomenon to occur; When the humidity of the additional materials that feeds is higher than 5%, can in grinding machine, produce a large amount of water vapour again, the humidity of abrasive is increased, can produce above-mentioned bag ball, bag forging phenomenon equally, cement output and quality are descended significantly.For solving the electrostatic problem that cement mill produces at process of lapping, abroad some enterprises have taked external electricity to eliminate static, but effect is not so good.Have yet and adopt cement grinding aid, as the Xi Pu company of selling the U.S. in the market, the cement grinding aid that Luoyang, Henan Wan Shun company produces, though can improve the output of cement, its quality is not improved.
Technology contents
The purpose of this invention is to provide a kind of output that can improve cement, can improve the cement grinding aid of cement quality again.
The present invention is by forming by weight the trolamine of 70%-80% and the mother liquor of 20-30%, and described mother liquor per kilogram component and content are: alkyl polyglycoside 7-20 gram, sodium humate 17-53 gram, sulfonated lignin 4-10 gram, Sodium dodecylbenzene sulfonate 2-22 gram, fatty alcohol-polyoxyethylene ether 10-30, poly-phosphate 1-9 gram, beta-hydroxy amine 7-2 gram, sodium laurylsulfonate 1-14 restrain, senior alkyl ether sodium sulfate salt 2-13 restrains, dimethylbenzene naphthalenesulfonate 4-10 restrains, sodium laurylsulfate 3-30 restrains, white sugar 3-8 restrains, all the other are water.
Mother liquor of the present invention should prepare before use in advance, comprises the steps:
(1) with 20 °～30 ℃ water injection reactor, adds alkyl polyglycoside, fatty alcohol-polyoxyethylene ether then, stirring reaction;
(2) senior alkyl ether sodium sulfate salt, sodium laurylsulfate, Sodium dodecylbenzene sulfonate, poly-phosphate, beta-hydroxy amine, sodium laurylsulfonate are added in the aforesaid reaction vessel stirring reaction;
(3) sulfonated lignin, dimethylbenzene naphthalenesulfonate are added in the aforesaid reaction vessel stirring reaction;
(4) sodium humate, white sugar are added stirring reaction in the aforesaid reaction vessel.
Final mother liquor, but long-term storage.
Superior part of the present invention is:
(1) in grinding the process of cement, add this grinding aid after, can improve the unit-hour output of cement, thereby reduce power consumption;
(2) compare with similar cement grinding aid, addition per ton is little, and effect of increasing production is obvious;
(3) add this grinding aid after, the water consumption of system grout does not increase on the contrary sometimes and reduces, and can prolong cement setting time, but denseness is constant, its result is specially adapted to transmit cement with travelling belt, promptly large-scale cement is irrigated;
(4) use the quality of the cement of this grinding aid to be greatly improved, its compressive strength rate of 28 days does not add increase by the 2～5MPa of grinding aid;
(5) owing to use this grinding aid, the label of cement improves, thereby can add in cement into some additional materials, thereby the cost of producing cement is reduced.
Embodiment
Embodiment one: prepare 20 kilograms of mother liquors, get 80 kilograms of trolamines.Wherein the alkyl polyglycoside in the mother liquor 200 restrains, sodium humate 600 grams, sulfonated lignin 100 grams, Sodium dodecylbenzene sulfonate 200 grams, fat polyoxyethylenated alcohol 200 grams, poly-phosphate 100 grams, beta-hydroxy amine 160 grams, sodium laurylsulfonate 140 grams, senior alkyl ether sodium sulfate salt 160 grams, dimethylbenzene naphthalenesulfonate 120 grams, sodium laurylsulfate 300 grams, white sugar 80 grams add water 17640 grams at last.
Embodiment two: prepare 10 kilograms of mother liquors, get 90 kilograms of trolamines.Wherein the alkyl polyglycoside in the mother liquor 50 restrains, sodium humate 240 grams, sulfonated lignin 70 grams, Sodium dodecylbenzene sulfonate 130 grams, fatty alcohol-polyoxyethylene ether 210 grams, poly-phosphate 18 grams, beta-hydroxy amine 12 grams, sodium laurylsulfonate 46 grams, senior alkyl ether sodium sulfate salt 100 grams, dimethylbenzene naphthene sulfonic acid 94 grams, sodium laurylsulfate 84 grams, white sugar 50 grams add water 8896 grams at last.
Following table is U.S. Xi Pu company, Luoyang, Henan Wan Shun company, Chinese patent CN1240774A and comparing result of the present invention:
Table-1 cement grinding aid usage quantity contrast per ton
| Unit | The ton cement consumption | Ton cement optimum amount |
| The present invention | 80～140 grams | 100 grams |
| The U.S. is uncommon general | 150～250 grams | Preceding 2 hours using dosages are 300 grams |
| Luoyang ten thousand is suitable | 200～400 grams | |
| CN1240774A | The 100-500 gram |
Table-2 improves the output contrast after using cement grinding aid
| Unit | Unit-hour output raising rate % | |
| The present invention | 20～40 | |
| The U.S. is uncommon general | 15～30 | |
| Luoyang ten thousand is suitable | 20～40 | |
| CN1240774A | 10-25 |
Strength of cement contrasted after table-3 used cement grinding aid
| Unit | Yield trials | Quality test | ||
| 3 days intensity (%) | 28 days intensity (%) | 3 days intensity (%) | 28 days intensity (%) | |
| The present invention | 20-50 | 10-20 | 6-20 | 4-10 |
| Luoyang ten thousand is suitable | There is not this function | There is not this function | There is not this function | There is not this function |
| The U.S. is uncommon general | There is not this function | There is not this function | There is not this function | There is not this function |
| CN1240774A | 20-50 | 10-20 | ||
Cement normal consistency water consumption behind table-4 use cement grinding mill auxiliary agents
| Unit | Water consumption | |
| The present invention | Do not increase or reduce | |
| The U.S. is uncommon general | There is not this effect | |
| Luoyang ten thousand is suitable | There is not this effect | |
| CN1240774A | There is not this effect |
Claims (1)
1. cement grinding aid by forming by weight the trolamine of 70%-80% and the mother liquor of 20-30%, is characterized in that described mother liquor per kilogram component and content are:
Alkyl polyglycoside 7-20 gram
Sodium humate 17-53 gram
Sulfonated lignin 4-10 gram
Sodium dodecylbenzene sulfonate 2-22 gram
Fatty alcohol-polyoxyethylene ether 10-30 gram
Poly-phosphate 1-9 gram
Beta-hydroxy amine 7-21 gram
Sodium laurylsulfonate 1-14 gram
Senior alkyl ether sodium sulfate salt 2-13 gram
Dimethylbenzene naphthalenesulfonate 4-10 gram
Sodium laurylsulfate 3-30 gram
White sugar 3-8 gram
All the other are water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011283505A CN1133601C (en) | 2001-08-14 | 2001-08-14 | Grinding aid for cement |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011283505A CN1133601C (en) | 2001-08-14 | 2001-08-14 | Grinding aid for cement |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1346812A CN1346812A (en) | 2002-05-01 |
| CN1133601C true CN1133601C (en) | 2004-01-07 |
Family
ID=4668219
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011283505A Expired - Fee Related CN1133601C (en) | 2001-08-14 | 2001-08-14 | Grinding aid for cement |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1133601C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332903C (en) * | 2006-01-04 | 2007-08-22 | 胡佩龙 | Cement grinding aids |
| US10737979B2 (en) | 2017-04-20 | 2020-08-11 | United States Gypsum Company | Gypsum set accelerator and method of preparing same |
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|---|---|---|---|---|
| CN100404455C (en) * | 2006-11-21 | 2008-07-23 | 武汉理工大学 | A kind of cement composite grinding aid and preparation method thereof |
| CN101037311B (en) * | 2007-03-21 | 2010-05-19 | 刘立 | Concrete reinforced abrasion-aided additive and its application |
| CN100519460C (en) * | 2007-08-18 | 2009-07-29 | 洛阳万顺建材有限公司 | Cement grinding aid and preparation method thereof |
| CN101397199B (en) * | 2008-06-20 | 2013-01-09 | 淄博宜龙化工有限公司 | Cement grinding aid strengthening agent |
| CN101318792B (en) * | 2008-06-26 | 2012-05-09 | 袁玉乔 | Liquid cement grinding aid |
| EP2298710A1 (en) | 2009-09-21 | 2011-03-23 | Sika Technology AG | Additive for mineral bonding agent |
| CN101723614B (en) * | 2009-12-30 | 2011-11-30 | 南京神和新材料科技有限公司 | Liquid cement grinding aid |
| CN102491672B (en) * | 2011-11-29 | 2013-09-18 | 山东宏艺科技股份有限公司 | Cement grinding aid and preparing method thereof |
| CN103387351A (en) * | 2012-05-11 | 2013-11-13 | 天津博克尼科技发展有限公司 | Compound liquid cement grinding aid |
| WO2014067991A1 (en) * | 2012-11-05 | 2014-05-08 | Sika Technology Ag | Milling aid for cement clinker based on polycarboxylate ethers and/or lignosulphonates |
| CN103496872B (en) * | 2013-09-25 | 2015-05-13 | 周建平 | Cement additive and preparation method thereof |
| MX2016002965A (en) * | 2013-09-27 | 2016-11-07 | Kao Corp | Method for manufacturing hydraulic powder. |
| CN103539377B (en) * | 2013-11-06 | 2015-02-25 | 山东七星岩建材科技有限公司 | Energy-saving cement grinding aid mother liquor as well preparation method and application thereof |
| CN103819623B (en) * | 2014-02-12 | 2016-04-27 | 科之杰新材料集团有限公司 | A kind of preparation method of poly-alkanolamine ester carboxylic serials cement grinding aid reinforcing agent |
| CN104045257B (en) * | 2014-06-03 | 2015-11-18 | 南京永能新材料有限公司 | High-moisture mixed material cement grinding aid and preparation method thereof |
| CN105130260A (en) * | 2015-08-25 | 2015-12-09 | 建华建材（蚌埠）有限公司 | Special diluting grinding aid for cement production and preparation method for special diluting grinding aid |
| CN105130261A (en) * | 2015-08-25 | 2015-12-09 | 建华建材（蚌埠）有限公司 | Cement grinding aid for building and preparation method for cement grinding aid |
| CN105236807B (en) * | 2015-11-19 | 2017-08-11 | 杭州立平工贸有限公司 | Liquid cement grinding aid reinforcing agent and preparation method thereof, application process |
| CN106242350A (en) * | 2016-08-31 | 2016-12-21 | 苏州市湘园特种精细化工有限公司 | A kind of cement grinding aid |
| JP6310168B1 (en) * | 2018-01-09 | 2018-04-11 | 竹本油脂株式会社 | Synthetic fiber treatment agent and synthetic fiber |
-
2001
- 2001-08-14 CN CNB011283505A patent/CN1133601C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332903C (en) * | 2006-01-04 | 2007-08-22 | 胡佩龙 | Cement grinding aids |
| US10737979B2 (en) | 2017-04-20 | 2020-08-11 | United States Gypsum Company | Gypsum set accelerator and method of preparing same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1346812A (en) | 2002-05-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20040107 Termination date: 20110814 |