[go: up one dir, main page]

CN113355600B - On-line quenching 800MPa grade extra-thick steel plate for construction machinery and its manufacturing method - Google Patents

On-line quenching 800MPa grade extra-thick steel plate for construction machinery and its manufacturing method Download PDF

Info

Publication number
CN113355600B
CN113355600B CN202110596153.7A CN202110596153A CN113355600B CN 113355600 B CN113355600 B CN 113355600B CN 202110596153 A CN202110596153 A CN 202110596153A CN 113355600 B CN113355600 B CN 113355600B
Authority
CN
China
Prior art keywords
temperature
rolling
cooling
reduction
steel plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202110596153.7A
Other languages
Chinese (zh)
Other versions
CN113355600A (en
Inventor
李新宇
宋欣
李伟
马鑫
于涛
毕建伟
邴纯
欧阳宇
杨志强
杨清山
冯仰峰
张硕
马林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jingye (Yingkou) Medium Plate Co.,Ltd.
Original Assignee
Rizhao Steel Yingkou Medium Plate Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rizhao Steel Yingkou Medium Plate Co Ltd filed Critical Rizhao Steel Yingkou Medium Plate Co Ltd
Priority to CN202110596153.7A priority Critical patent/CN113355600B/en
Publication of CN113355600A publication Critical patent/CN113355600A/en
Application granted granted Critical
Publication of CN113355600B publication Critical patent/CN113355600B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

An extra-thick steel plate for an on-line quenching 800 MPa-grade engineering machine comprises C:0.050-0.080%, si:0.10 to 0.25%, mn:1.30-1.50%, P is less than or equal to 0.015%, S is less than or equal to 0.005%, al:0.020 to 0.040%, nb:0.010-0.020%, ti:0.008-0.015%, ni:0.40-0.50%, cr:0.30-0.40%, mo 0.20-0.30%, cu 0.20-0.30%, B:0.0010-0.0020%, and the balance iron. The steel plate prepared by the invention has stable mechanical property, good internal quality, good strength, toughness and plasticity and low yield ratio, and can effectively meet the requirements of special steel in the engineering machinery industry.

Description

在线淬火800MPa级工程机械用特厚钢板及其制造方法On-line quenching 800MPa grade extra-thick steel plate for construction machinery and its manufacturing method

技术领域technical field

本发明属于金属材料技术领域,具体涉及一种抗拉强度800MPa级工程机械用钢及其制造方法,尤其涉及一种在线淬火工艺条件下,厚度规格0-120mm、高强度、高韧性、低屈强比工程机械用特厚钢板。The invention belongs to the technical field of metal materials, and in particular relates to a steel for construction machinery with a tensile strength of 800 MPa and a manufacturing method thereof, and in particular to a thickness specification of 0-120 mm, high strength, high toughness and low yield under the condition of an online quenching process. Stronger than extra thick steel plate for construction machinery.

背景技术Background technique

工程机械行业是机械工业的重要组成部分,其中钢铁材料在工程机械制造中占有重要地位。随着工程机械向高效率、高参数、大型化方向发展,工程机械构件材料在强韧性、焊接性等方面的要求更为突出,促进了工程机械用钢的开发和生产不断向更高级别、更优综合性能方向发展。传统工程机械用钢,一般基本采用调质(离线再加热淬火+回火)工艺生产,存在工序多、能耗高、合金加入量多等问题。随着冶金技术及装备的发展,在线淬火技术正在受到钢铁行业的广泛关注,在线淬火装备也成为中厚板生产线控制冷却的主流装备。采用在线淬火工艺生产中厚板,可有效利用钢板轧后余热,将变形与热处理工艺有机结合起来;与传统的 调质工艺相比,可减少离线再加热工序,缩短工艺流程,降低生产成本。随着新一代在线淬火技术的发展,工程机械用钢生产过程中正逐步采用在线淬火工艺,且可生产钢板厚度规格越来越大。The construction machinery industry is an important part of the machinery industry, of which iron and steel materials play an important role in the manufacture of construction machinery. With the development of construction machinery in the direction of high efficiency, high parameters, and large-scale, the requirements of construction machinery component materials in terms of strength, toughness and weldability are more prominent, which promotes the development and production of construction machinery steel. Development in the direction of better comprehensive performance. Traditional construction machinery steel is generally produced by quenching and tempering (off-line reheating quenching + tempering) process, which has problems such as many processes, high energy consumption, and large amount of alloy added. With the development of metallurgical technology and equipment, on-line quenching technology is receiving extensive attention in the steel industry, and on-line quenching equipment has also become the mainstream equipment for controlled cooling in medium and heavy plate production lines. The on-line quenching process is used to produce medium and heavy plates, which can effectively utilize the waste heat after rolling of the steel plate, and organically combine the deformation and heat treatment process; compared with the traditional quenching and tempering process, it can reduce the off-line reheating process, shorten the process flow, and reduce the production cost. With the development of a new generation of on-line quenching technology, the on-line quenching process is gradually being adopted in the production process of steel for construction machinery, and the thickness specifications of the steel plates that can be produced are getting larger and larger.

专利“一种特厚规格Q690高强度结构钢板及其制造方法”(申请号:CN201410467565),采用“0.15-0.18%C、1.00-1.20%Mn、1.00-1.20% Cr、0.54~0.60% Mo、0.80~1.00% Ni、0.03~0.05% V、0.02~0.04%Nb、0.001-0.002% B”成分设计,通过再结晶区轧制加“DQ+ACC在线淬火”工艺,试制160-180mm 厚度规格Q690;其中,加热温度1190-1230℃,终轧温度920-980℃,开冷温度900-910℃,终冷温度150-200℃、冷却速度0.60-0.75℃/s,回火温度600-660℃,回火时间3-3.5mm/min;不同厚度规格钢板厚度1/4处、1/2处、3/4处0℃冲击功范围为51-68J。该专利采用中C基础上并添加大量贵重合金,同时加入微合金元素Nb、V等,碳当量势必较高,对后续加工使用过程不利,尤其是焊接过程。大量贵重合金的加入,成本增加过多。轧制过程中,采用较高温轧制策略,轧制过程可能处于混晶区,对特厚钢板综合力学性能不利。水冷过程中,冷却速度<1.0℃/s;较低的冷却速度,如何获得理想的在线淬火组织及相应的力学性能,如何保证强度及塑韧性的匹配,值得商榷和探讨。该专利实施例中的冲击功偏低,仅能达到0℃要求,无法满足高强韧性工程机械用高强钢需求。The patent "An extra-thick Q690 high-strength structural steel plate and its manufacturing method" (application number: CN201410467565), using "0.15-0.18% C, 1.00-1.20% Mn, 1.00-1.20% Cr, 0.54~0.60% Mo, 0.80~1.00% Ni, 0.03~0.05% V, 0.02~0.04% Nb, 0.001-0.002% B" composition design, through recrystallization zone rolling and "DQ+ACC online quenching" process, trial production of 160-180mm thickness specification Q690 ; Among them, the heating temperature is 1190-1230°C, the final rolling temperature is 920-980°C, the cooling temperature is 900-910°C, the final cooling temperature is 150-200°C, the cooling rate is 0.60-0.75°C/s, and the tempering temperature is 600-660°C , the tempering time is 3-3.5mm/min; the impact energy at 1/4, 1/2 and 3/4 of the thickness of steel plates with different thickness specifications ranges from 51-68J at 0°C. This patent uses medium C and adds a large amount of precious alloys, and at the same time adds micro-alloying elements Nb, V, etc., the carbon equivalent is bound to be high, which is unfavorable for the subsequent processing and use process, especially the welding process. The addition of a large amount of precious alloys increases the cost too much. During the rolling process, if a higher temperature rolling strategy is adopted, the rolling process may be in the mixed crystal region, which is unfavorable for the comprehensive mechanical properties of the extra-thick steel plate. In the process of water cooling, the cooling rate is less than 1.0℃/s; with a lower cooling rate, how to obtain the ideal online quenching structure and corresponding mechanical properties, and how to ensure the matching of strength and plastic toughness is worthy of discussion and discussion. The impact energy in the embodiment of the patent is low, and can only meet the requirement of 0°C, which cannot meet the requirement of high-strength steel for high-strength and toughness construction machinery.

专利“一种高强韧厚钢板的在线淬火生产工艺方法”(申请号:CN 200810013604),利用在线淬火生产工艺生产厚度规格20-50mm高强韧性厚钢板。在成分设计方面,采用“0.05-0.15% C、0.15-0.35% Si、1.40-2.00% Mn、P≤0.010%、S≤0.005%、Nb≤0.06%、V≤0.06%、Ti≤0.04%、Ni≤0.40%、Mo≤0.20%、Cu≤0.40%、Cr≤0.50%、0.0005-0.0020% B”设计。在轧制工艺控制方面,钢坯加热温度1100-1250℃,终轧温度860℃-950℃,采用气雾及水幕两阶段冷却方式实现钢板在线淬火,平均冷却速度25-45℃/s,终冷温度150-300℃并采用580-650℃高温回火。实施例中,所涉及钢种抗拉强度均在640MPa及以下,屈服强度在565MPa以下,-20℃冲击功>200J,实际性能数据与Q500D接近。该专利采用较为宽泛C、Mn及部分合金元素设计,工艺设计尤其是终轧温度范围也过于宽泛,处于再结晶与非再结晶温度过渡区,对钢板质量的稳定控制,尤其是力学性能及微观组织产生不利影响,凸显其设计的局限性。同时该专利采用超低P设计,势必造成冶炼成本增加。较高的冷速导致钢板厚度方向温度梯度大,组织均匀性差。另外,该专利采用复杂的气雾及水幕两阶段冷却方式,却仅可生产50mm及以下规格钢板,强度级别低且冲击韧性仅达到-20℃,无法达到高强韧性特厚钢板要求。The patent "On-line quenching production process method of high-strength and toughness thick steel plate" (application number: CN 200810013604), uses the on-line quenching production process to produce high-strength and toughness thick steel plate with thickness specification of 20-50mm. In terms of composition design, "0.05-0.15% C, 0.15-0.35% Si, 1.40-2.00% Mn, P≤0.010%, S≤0.005%, Nb≤0.06%, V≤0.06%, Ti≤0.04%, Ni≤0.40%, Mo≤0.20%, Cu≤0.40%, Cr≤0.50%, 0.0005-0.0020% B" design. In terms of rolling process control, the heating temperature of the billet is 1100-1250 °C, the final rolling temperature is 860 °C-950 °C, and the two-stage cooling method of aerosol and water curtain is used to realize on-line quenching of the steel plate. The average cooling rate is 25-45 °C/s. Cold temperature 150-300℃ and high temperature tempering at 580-650℃. In the examples, the tensile strength of the steels involved are all below 640MPa, the yield strength is below 565MPa, the impact energy at -20°C is >200J, and the actual performance data is close to that of Q500D. The patent adopts a relatively broad design of C, Mn and some alloying elements. The process design, especially the temperature range of finishing rolling, is too wide. It is in the transition zone of recrystallization and non-recrystallization temperature, and it can control the quality of the steel plate stably, especially the mechanical properties and microstructure. The organization adversely affects the limitations of its design. At the same time, the patent adopts ultra-low P design, which will inevitably increase the smelting cost. The higher cooling rate results in a large temperature gradient in the thickness direction of the steel plate and poor microstructure uniformity. In addition, this patent adopts a complex two-stage cooling method of aerosol and water curtain, but it can only produce steel plates of 50mm and below, with low strength level and impact toughness only reaching -20℃, which cannot meet the requirements of high-strength toughness and extra-thick steel plates.

专利“大厚度高强钢板在线淬火工艺”(申请号:CN201811375040),采用“0 .13-0.18% C、0 .2-0 .4% Si、1 .35-1 .6% Mn、P≤0 .02%、S≤0 .008%、0 .15-0 .4%Ni、0 .2-0 .5% Cr、Nb≤0 .05%、0 .03-0 .06%V、0 .01-0 .035% Ti、0 .2- 0.35%Mo、0.001-0.002% B”成分设计,坯料厚度300-350mmmm,加热温度1170-Patent "On-line quenching process of large thickness and high strength steel plate" (application number: CN201811375040), using "0.13-0.18% C, 0.2-0.4% Si, 1.35-1.6% Mn, P≤0 .02%, S≤0.008%, 0.15-0.4% Ni, 0.2-0.5% Cr, Nb≤0.05%, 0.03-0.06% V, 0.05% 01-0.035%Ti, 0.2-0.35%Mo, 0.001-0.002%B" composition design, blank thickness 300-350mmmm, heating temperature 1170-

1250℃,终轧温度840-890℃,开冷温度810-850℃,终冷温度<200℃,回火温度620-660℃,保温时间15-30min。在中C成分基础上,加入大量合金元素Ni、Cr、Mo及微合金元素Nb、V,通过在线淬火(DQ)+离线回火(T)可生产厚度60-80mm、屈服强度≥700Mpa,抗拉强度为790-900MPa,屈强比≤0.92,延伸率≥16%,-20℃冲击功≥100J高强钢。在成分设计方面,C偏高且合金元素加入量大,在增加合金成本的同时,对力学性能不利,尤其是冲击韧性。另外,较低的终冷温度要求,对冷却设备能力要求较高。其实施例中部分回火后微观组织与调质钢类似,为回火索氏体,而非在线淬火钢回火后的低碳板条贝氏体组织。成分和工艺设计,与实施例结果或理论不符合,该专利未必具备批量推广的价值。1250℃, the final rolling temperature is 840-890℃, the cooling temperature is 810-850℃, the final cooling temperature is less than 200℃, the tempering temperature is 620-660℃, and the holding time is 15-30min. On the basis of medium C component, a large amount of alloying elements Ni, Cr, Mo and micro-alloying elements Nb, V are added. Through online quenching (DQ) + offline tempering (T), it can produce thickness of 60-80mm, yield strength ≥700Mpa, and resistance to The tensile strength is 790-900MPa, the yield ratio is less than or equal to 0.92, the elongation is greater than or equal to 16%, and the impact energy at -20°C is greater than or equal to 100J high-strength steel. In terms of composition design, C is too high and the amount of alloying elements added is large, which increases the cost of the alloy and is not conducive to the mechanical properties, especially the impact toughness. In addition, lower final cooling temperature requirements require higher cooling equipment capacity. Part of the tempered microstructure in the examples is similar to that of the quenched and tempered steel, which is tempered sorbite, rather than the low-carbon lath bainite structure of the in-line quenched steel after tempering. The composition and process design are inconsistent with the results or theories of the examples, and the patent may not have the value of mass promotion.

专利“一种80-120mm特厚高强度钢板及其利用连铸坯生产的方法”(申请号:CN103276312A),采用常规的成分设计,即在“0.15-0.19% C、1.15-1.35% Mn”基础上,加入Ni、Cr、Mo、Nb、B等,并对高温再结晶区轧制阶段道次压下率做严格限制,采用离线再加热淬火+回火处理,生产厚度规格80-120mm、Rp0.2>700MPa、Rm>800MPa、A>14%、-20℃冲击功70-160J的高强钢。正常的成分设计,过多合金元素加入,合金成本显著增加。正常的离线调质处理工艺,工序多,生产周期长,生产成本高。总体上看,从设计到工艺,该专利不具备优势和特点。The patent "A kind of 80-120mm extra-thick high-strength steel plate and its production method using continuous casting slab" (application number: CN103276312A) adopts conventional composition design, that is, "0.15-0.19% C, 1.15-1.35% Mn" On the basis, Ni, Cr, Mo, Nb, B, etc. are added, and the rolling reduction rate of the high temperature recrystallization zone is strictly limited. High-strength steel with Rp0.2>700MPa, Rm>800MPa, A>14%, -20℃ impact energy 70-160J. With normal composition design, too many alloying elements are added, and the alloy cost will increase significantly. The normal off-line quenching and tempering process has many processes, long production cycle and high production cost. In general, from design to process, this patent has no advantages and features.

文献“在线淬火 Q690D 高强钢板组织和性能研究”(金属材料与冶金工程,2016.06(004),张勇伟等),采用低C-Mn-Cr-Mo成分设计,以“在线淬火+回火工艺”生产16-30mm 规格 Q690D 试验钢板并对其微观组织进行研究。该文献仅针对薄规格Q690D进行在线淬火试验研究,厚度规格薄,韧性指标低,且对轧制过程提出较多要求。对于常规厚度的Q690D,采用在线淬火技术进行生产,难度较小。另外,针对薄规格在线淬火Q690D,贵重合金Mo的添加有无必要也需要考虑。Document "On-line Quenching Q690D High Strength Steel Plate Microstructure and Properties" (Metallic Materials and Metallurgical Engineering, 2016.06 (004), Zhang Yongwei, etc.), designed with low C-Mn-Cr-Mo composition and produced by "on-line quenching + tempering process" 16-30mm specification Q690D test steel plate and study its microstructure. This document only conducts on-line quenching test research on thin gauge Q690D, which has thin thickness gauge and low toughness index, and puts forward more requirements for the rolling process. For Q690D with conventional thickness, it is less difficult to use in-line quenching technology to produce. In addition, for thin gauge in-line quenching Q690D, the necessity of adding precious alloy Mo also needs to be considered.

工程机械行业正向轻量化和大型化方向不断发展。因此,亟需一种成本低,工艺简单的高强度高韧性工程机械用钢,以期通过合理经济的成分设计和简单工艺控制,获得综合性能优良的低合金高强度或超高强度工程机械用钢。The construction machinery industry is developing in the direction of lightweight and large-scale. Therefore, there is an urgent need for a high-strength and high-toughness steel for construction machinery with low cost and simple process, in order to obtain low-alloy high-strength or ultra-high-strength construction machinery steel with excellent comprehensive properties through reasonable and economical composition design and simple process control. .

发明内容SUMMARY OF THE INVENTION

本发明的目的在于提供一种在线淬火条件下抗拉强度800MPa级特厚规格工程机械用钢,以解决现有技术中的问题。The purpose of the present invention is to provide a steel for construction machinery with a tensile strength of 800 MPa grade and extra-thick specifications under the condition of online quenching, so as to solve the problems in the prior art.

本发明是通过如下技术方案实现的:一种在线淬火800MPa级工程机械用特厚钢板,其特征在于:包括如下质量百分比的各组分:C:0.050-0.080%,Si:0.10-0.25%,Mn:1.30-1.50%,P≤0.015%,S≤0.005%,Al:0.020-0.040%,Nb:0.010-0.020%,Ti:0.008-0.015%,Ni:0.40-0.50%,Cr:0.30-0.40%,Mo:0.20-0.30%,Cu:0.20-0.30%,B:0.0010-0.0020%,N≤45ppm,H≤1.5ppm,O≤30ppm,余量为Fe及不可避免的杂质。The invention is realized by the following technical scheme: an extra-thick steel plate for on-line quenching of 800MPa grade engineering machinery, which is characterized in that: each component comprises the following mass percentages: C: 0.050-0.080%, Si: 0.10-0.25%, Mn: 1.30-1.50%, P≤0.015%, S≤0.005%, Al: 0.020-0.040%, Nb: 0.010-0.020%, Ti: 0.008-0.015%, Ni: 0.40-0.50%, Cr: 0.30-0.40 %, Mo: 0.20-0.30%, Cu: 0.20-0.30%, B: 0.0010-0.0020%, N≤45ppm, H≤1.5ppm, O≤30ppm, the balance is Fe and inevitable impurities.

本发明还公开了一种在线淬火800MPa级工程机械用特厚钢板的制造方法,其特征在于:包括如下步骤:钢水冶炼、LF炉精炼、RH真空处理、厚板坯浇铸、板坯加热、钢板轧制、DQ+ACC冷却、回火热处理;其中,The invention also discloses a method for manufacturing an extra-thick steel plate for on-line quenching of 800MPa grade engineering machinery, which is characterized by comprising the following steps: molten steel smelting, LF furnace refining, RH vacuum treatment, thick slab casting, slab heating, steel plate Rolling, DQ+ACC cooling, tempering heat treatment; among them,

(1)钢水冶炼步骤,铁水通过脱硫扒渣,进入转炉冶炼,并经过“LF+RH”进行精炼;转炉出钢温度1650±20℃,LF结束温度1635±10℃,RH结束温度1585±5℃,软吹结束温度1565±5℃,中包温度1538±5℃;过程中,控制各组分含量如下:C:0.050-0.0.080%,P≤0.015%,S≤0.005%,N≤45ppm,H≤1.5ppm,O≤30ppm;深真空处理时间为15-20min;(1) The molten steel smelting step, the molten iron enters the converter for smelting through desulfurization and slag removal, and is refined by "LF+RH"; ℃, the end temperature of soft blowing is 1565±5℃, and the temperature of the middle bag is 1538±5℃; during the process, the content of each component is controlled as follows: C: 0.050-0.0.080%, P≤0.015%, S≤0.005%, N≤ 45ppm, H≤1.5ppm, O≤30ppm; deep vacuum treatment time is 15-20min;

(2)厚板坯浇铸步骤:浇铸过程中保持恒拉速,拉速范围0.45m-0.55 m/min,平均过热度20-25℃;动态轻压下增加两相区及固相区压下量,压下速率1.10-1.30mm/m,两相区压下量8-10mm,固相区压下量0.5-1.5mm;保证板坯中心偏析C类≤0.5;(2) Casting steps for thick slabs: keep constant pulling speed during casting, the pulling speed range is 0.45m-0.55m/min, the average superheat is 20-25℃; dynamic light reduction increases the reduction of two-phase region and solid-phase region The reduction rate is 1.10-1.30mm/m, the reduction in the two-phase area is 8-10mm, and the reduction in the solid phase area is 0.5-1.5mm; ensure that the center segregation of the slab is C class ≤ 0.5;

(3)板坯加热步骤:采用步进梁式加热炉将板坯分段加热至均热温度1180-1220℃;其中,第一加热段温度950-1050℃,第二加热段温度1050-1150℃,第三加热段温度1150-1200℃,第四加热段均热段温度为1180-1220℃,板坯在炉时间450-550min;(3) Slab heating step: use a walking beam heating furnace to heat the slab segmentally to a soaking temperature of 1180-1220°C; wherein the temperature of the first heating section is 950-1050°C, and the temperature of the second heating section is 1050-1150°C °C, the temperature of the third heating section is 1150-1200 °C, the temperature of the soaking section of the fourth heating section is 1180-1220 °C, and the slab is in the furnace for 450-550min;

(4)钢板轧制步骤:采用再结晶区及非再结晶区分段轧制;再结晶区轧制阶段开始温度≥1100℃,结束温度范围为1000-1050℃,再结晶区轧制阶段总压下量为55-70%,其中第一阶段轧制最后2-3道次的单道次压下量在35-50mm;再结晶区轧制阶段轧制结束前2-3轧制道次的单道次压下率≥15-20%;再结晶区轧制完成后,中间坯待温厚度为1.7-2.0倍钢板成品厚度;非再结晶区轧制阶段开始温度830-850℃,结束温度为800-820℃,且非再结晶区轧制单道次压下率≤12%,累积压下率≥40-50%;(4) Steel plate rolling steps: the recrystallization zone and the non-recrystallization zone are used for segment rolling; the starting temperature of the rolling stage in the recrystallization zone is ≥1100 °C, the ending temperature is 1000-1050 °C, and the total pressure of the rolling stage in the recrystallization zone is 1000-1050 °C. The reduction is 55-70%, and the single-pass reduction of the last 2-3 passes of the first stage rolling is 35-50mm; The single-pass reduction ratio is ≥15-20%; after the recrystallization zone rolling is completed, the thickness of the intermediate billet to be warmed is 1.7-2.0 times the thickness of the finished steel plate; the starting temperature of the rolling stage in the non-recrystallization zone is 830-850℃, and the end temperature The temperature is 800-820℃, and the single-pass rolling reduction rate in the non-recrystallization zone is ≤12%, and the cumulative reduction rate is ≥40-50%;

(5)DQ+ACC冷却步骤:冷却过程开启DQ缝隙集管及ACC高密快冷集管进行冷却,其中DQ缝隙集管进水压力0.4-0.5MPa,水流密度范围2000-3000L/(m2.min),ACC高密快冷集管进水压力0.2-0.3MPa,水流密度范围1000-2000L/(m2.min),总水量≥15000m3/h,辊道速度0.30-0.33m/min;开始冷却温度780-800℃,终冷温度200-300℃,冷速10-15℃/s;(5) DQ+ACC cooling step: During the cooling process, open the DQ slit header and the ACC high-density fast cooling header for cooling, where the water inlet pressure of the DQ slit header is 0.4-0.5MPa, and the water flow density range is 2000-3000L/(m 2 . min), the water inlet pressure of the ACC high-density fast cooling header is 0.2-0.3MPa, the water flow density range is 1000-2000L/(m 2 .min), the total water volume is ≥15000m 3 /h, and the roller speed is 0.30-0.33m/min; start Cooling temperature 780-800℃, final cooling temperature 200-300℃, cooling rate 10-15℃/s;

(6)回火热处理步骤:采用高温回火工艺;其中,回火温度及保温时间分别为“600-650℃”和“80-120min”,回火过程中加热系数为2.4±0.1min/cm。(6) Tempering heat treatment step: high temperature tempering process is adopted; among them, the tempering temperature and holding time are "600-650℃" and "80-120min" respectively, and the heating coefficient during the tempering process is 2.4±0.1min/cm .

本发明的优点是:(1)在现有工装能力基础上,采用简单合理的成分设计及工艺要求,实现大厚度在线淬火工程机械用钢开发,突破了传统厚规格特厚钢板必须采用“离线再加热淬火+回火”工艺生产限制,在减少生产工序的同时,提高生产效率,降低生产成本。The advantages of the invention are: (1) On the basis of the existing tooling capacity, simple and reasonable component design and process requirements are adopted to realize the development of large-thickness on-line quenching engineering machinery steel, breaking through the traditional thick specification and extra-thick steel plate that must be "off-line" Reheating quenching + tempering" process production limit, while reducing production processes, improving production efficiency and reducing production costs.

(2)本发明所涉及800MPa级特厚规格钢板,力学性能稳定,内部质量良好,强度、韧性及塑性良好,屈强比低,探伤满足国标要求,满足工程机械行业特殊用钢需求,具有一定的工业推广应用价值。(2) The 800MPa grade extra-thick steel plate involved in the present invention has stable mechanical properties, good internal quality, good strength, toughness and plasticity, low yield-to-strength ratio, flaw detection meets the requirements of the national standard, and meets the needs of special steel in the construction machinery industry. The value of industrial promotion and application.

附图说明Description of drawings

图1为80mm规格钢板厚度 1/4位置微观组织;Figure 1 shows the microstructure at the 1/4 position of the thickness of the 80mm steel plate;

图2为80mm规格钢板厚度 1/2位置微观组织;Figure 2 shows the microstructure at the 1/2 position of the thickness of the 80mm steel plate;

图3为120mm规格钢板厚度 1/4位置微观组织;Figure 3 shows the microstructure at the 1/4 position of the thickness of the 120mm steel plate;

图4为120mm规格钢板厚度 1/2位置微观组织。Figure 4 shows the microstructure at the 1/2 position of the thickness of the 120mm steel plate.

具体实施方式Detailed ways

实施例1Example 1

一种在线淬火800MPa级工程机械用特厚钢板,包括质量百分比的如下组分:C:0.058%,Si:0.22%,Mn:1.32%,P:0.014%,S:0.004%,Al:0.022%,Nb:0.013%,Ti:0.015%,Ni:0.49%,Cr:0.32%,Mo:0.23%,Cu:0.21,B:0.0015%,N:42ppm,H:1.2ppm,O:23ppm,余量为Fe及不可避免的杂质;焊接裂纹敏感性指数Pcm(%):0.189%。An on-line quenching 800MPa grade extra-thick steel plate for construction machinery, comprising the following components by mass percentage: C: 0.058%, Si: 0.22%, Mn: 1.32%, P: 0.014%, S: 0.004%, Al: 0.022% , Nb: 0.013%, Ti: 0.015%, Ni: 0.49%, Cr: 0.32%, Mo: 0.23%, Cu: 0.21, B: 0.0015%, N: 42ppm, H: 1.2ppm, O: 23ppm, remainder For Fe and inevitable impurities; welding crack sensitivity index Pcm (%): 0.189%.

连铸坯坯型:475mm*2000mm*2800mm;轧制钢板规格:80mm*2600mm*12750mm。Continuous casting billet type: 475mm*2000mm*2800mm; rolled steel plate size: 80mm*2600mm*12750mm.

钢水冶炼过程,转炉出钢1655℃,LF结束1642℃,RH结束1580℃,软吹结束温度1560℃,中包温度1537℃,深真空处理时间为16min。In the molten steel smelting process, the converter tapping is 1655°C, the LF end is 1642°C, the RH end is 1580°C, the soft blowing end temperature is 1560°C, the middle bag temperature is 1537°C, and the deep vacuum treatment time is 16min.

浇铸过程中拉速0.48m/min,过热度22℃。动态轻压下增加两相区及固相区压下量,压下速率1.25mm/m,两相区压下量9mm,固相区压下量1.4mm,板坯中心偏析C类0。During the casting process, the pulling speed is 0.48m/min, and the superheat degree is 22℃. The dynamic light reduction increases the reduction of the two-phase area and the solid-phase area, the reduction rate is 1.25mm/m, the reduction of the two-phase area is 9mm, the reduction of the solid-phase area is 1.4mm, and the center segregation of the slab is C class 0.

板坯加热过程中,第一加热段温度980-1045℃,第二加热段温度1053-1142℃,第三加热段温度1155-1190℃,第四加热段均热段温度为1195-1215℃,板坯在炉时间470min。During the slab heating process, the temperature of the first heating section is 980-1045 °C, the temperature of the second heating section is 1053-1142 °C, the temperature of the third heating section is 1155-1190 °C, and the temperature of the soaking section of the fourth heating section is 1195-1215 °C, Slab in furnace time 470min.

钢板轧制过程中,再结晶区轧制阶段开始温度1132℃,结束温度范围为1020℃,中间坯待温厚度为160mm;非再结晶区轧制阶段开始温度848℃,结束温度为812℃。轧制过程中道次压下量压下率见表1。During the steel plate rolling process, the starting temperature of the rolling stage in the recrystallization zone is 1132 °C, the ending temperature range is 1020 °C, and the thickness of the intermediate slab to be warmed is 160 mm; the starting temperature of the rolling stage in the non-recrystallization zone is 848 °C, and the ending temperature is 812 °C. Table 1 shows the reduction ratio of the pass reduction in the rolling process.

Figure 147930DEST_PATH_IMAGE002
Figure 147930DEST_PATH_IMAGE002

在冷却过程中,4组DQ缝隙集管进水压力0.48MPa,水流密度范围2500-2800L/(m2.min)),26组ACC高密快冷集管,进水压力0.21MPa,水流密度范围1200-1500L/(m2.min)),总水量,15500m3/h,辊道速度33m/s;开始冷却温度793℃,终冷温度262℃,平均冷速14℃/s。During the cooling process, the water inlet pressure of 4 groups of DQ gap headers is 0.48MPa, the water flow density range is 2500-2800L/(m 2 .min)), and the 26 groups of ACC high-density fast cooling headers, the water inlet pressure is 0.21MPa, and the water flow density range is 1200-1500L/(m 2 .min)), total water volume, 15500m 3 /h, roller speed 33m/s; starting cooling temperature 793℃, final cooling temperature 262℃, average cooling speed 14℃/s.

回火热处理过程中,回火温度640℃,保温时间80min,回火过程加热系数为2.35min/cm。During the tempering heat treatment process, the tempering temperature was 640°C, the holding time was 80 min, and the heating coefficient during the tempering process was 2.35 min/cm.

实施例1所生产80mm规格力学性能见表2,探伤结果见表3。The mechanical properties of the 80mm specification produced in Example 1 are shown in Table 2, and the flaw detection results are shown in Table 3.

Figure 924125DEST_PATH_IMAGE004
Figure 924125DEST_PATH_IMAGE004

由图1可见,回火后主要为板条贝氏体(居多)、粒状贝氏体和多边形铁素体,晶粒比较细小和均匀。由图2可见,回火后主要为板条贝氏体、粒状贝氏体和多边形铁素体,晶粒相对细小和均匀。It can be seen from Figure 1 that after tempering, it is mainly lath bainite (mostly), granular bainite and polygonal ferrite, and the grains are relatively fine and uniform. It can be seen from Figure 2 that after tempering, lath bainite, granular bainite and polygonal ferrite are mainly formed, and the grains are relatively fine and uniform.

本方案不同于中、高碳钢调质生产的回火索氏组织,本方案中组织主要为板条贝氏体、粒状贝氏体和多边形铁素体,晶粒比较细小和均匀。由于低碳贝氏体钢中的含量大大降低,极大的减弱了碳对于贝氏体组织韧性的不利影响。钢板的强度不再依靠传统调质钢中的碳含量,而是通过细晶、位错、亚结构以及铌、钒、钛的析出强化和沉淀强化来保证。钢板的强韧性匹配较好,有着良好的经济效益和焊接性能。This scheme is different from the tempered Soxhlet structure produced by quenching and tempering of medium and high carbon steel. The structure in this scheme is mainly lath bainite, granular bainite and polygonal ferrite, and the grains are relatively fine and uniform. Since the content of low carbon bainite steel is greatly reduced, the adverse effect of carbon on bainite structure and toughness is greatly weakened. The strength of the steel plate no longer depends on the carbon content in traditional quenched and tempered steel, but is ensured by fine grains, dislocations, substructures, and precipitation strengthening and precipitation strengthening of niobium, vanadium, and titanium. The strength and toughness of the steel plate is well matched, and it has good economic benefits and welding performance.

实施例2:Example 2:

一种在线淬火800MPa级工程机械用特厚钢板,其化学成分为(重量百分比),C:0.076%,Si:0.16%,Mn:1.48%,P:0.010%,S:0.002%,Al:0.036%,Nb:0.018%,Ti:0.014%,Ni:0.46%,Cr:0.37%,Mo:0.25%,Cu:0.28%,B:0.0018%,N:35ppm,H:1.0ppm,O:25ppm,余量为Fe及不可避免的杂质;焊接裂纹敏感性指数Pcm(%): 0.221%。An on-line quenching 800MPa grade extra-thick steel plate for construction machinery, its chemical composition is (weight percentage), C: 0.076%, Si: 0.16%, Mn: 1.48%, P: 0.010%, S: 0.002%, Al: 0.036 %, Nb: 0.018%, Ti: 0.014%, Ni: 0.46%, Cr: 0.37%, Mo: 0.25%, Cu: 0.28%, B: 0.0018%, N: 35ppm, H: 1.0ppm, O: 25ppm, The balance is Fe and inevitable impurities; welding crack sensitivity index Pcm (%): 0.221%.

连铸坯坯型:475mm*2000mm*3750mm;轧制钢板规格:120mm*2300mm*12900mm,1定尺。Continuous casting billet type: 475mm*2000mm*3750mm; rolled steel plate specification: 120mm*2300mm*12900mm, 1 fixed length.

钢水冶炼过程,转炉出钢1648℃,LF结束1640℃,RH结束1582℃,软吹结束温度1559℃,中包温度1535℃,深真空处理时间为19min。In the molten steel smelting process, the converter tapping is 1648°C, the LF end is 1640°C, the RH end is 1582°C, the soft blowing end temperature is 1559°C, the middle bag temperature is 1535°C, and the deep vacuum treatment time is 19min.

浇铸过程中拉速0.45m/min,过热度24℃。动态轻压下增加两相区及固相区压下量,压下速率1.29mm/m,两相区压下量8mm,固相区压下量1.5mm,板坯中心偏析C类0。During the casting process, the pulling speed is 0.45m/min, and the superheat degree is 24℃. The dynamic light reduction increases the reduction amount of the two-phase area and the solid phase area, the reduction rate is 1.29mm/m, the reduction amount of the two-phase area is 8mm, the reduction amount of the solid phase area is 1.5mm, and the center segregation of the slab is C class 0.

板坯加热过程中,第一加热段温度985-1050℃,第二加热段温度1055-1148℃,第三加热段温度1161-1194℃,第四加热段均热段温度为1200-1218℃,板坯在炉时间495min。During the slab heating process, the temperature of the first heating section is 985-1050 °C, the temperature of the second heating section is 1055-1148 °C, the temperature of the third heating section is 1161-1194 °C, and the temperature of the soaking section of the fourth heating section is 1200-1218 °C, Slab in furnace time 495min.

钢板轧制过程中,再结晶区轧制阶段开始温度1139℃,结束温度范围为1008℃,中间坯待温厚度为210mm;非再结晶区轧制阶段开始温度841℃,结束温度为807℃。轧制过程中道次压下量压下率见表4。During the steel plate rolling process, the starting temperature of the rolling stage in the recrystallization zone is 1139 °C, the ending temperature range is 1008 °C, and the thickness of the intermediate billet to be warmed is 210 mm; the starting temperature of the rolling stage in the non-recrystallization zone is 841 °C, and the ending temperature is 807 °C. Table 4 shows the reduction ratio of the pass reduction in the rolling process.

Figure 500600DEST_PATH_IMAGE006
Figure 500600DEST_PATH_IMAGE006

在冷却过程中,4组DQ缝隙集管进水压力0.49MPa,水流密度范围2600-3000L/(m2.min)),26组ACC高密快冷集管,进水压力0.23MPa,水流密度范围1250-1500L/(m2.min)),总水量,15800m3/h,辊道速度0.33m/s;开始冷却温度796℃,终冷温度165℃,平均冷速11℃/s。During the cooling process, the water inlet pressure of 4 groups of DQ slit headers is 0.49MPa, the water flow density range is 2600-3000L/(m 2 .min)), and the 26 groups of ACC high-density fast cooling headers, the water inlet pressure is 0.23MPa, and the water flow density range is 1250-1500L/(m 2 .min)), total water volume, 15800m 3 /h, roller speed 0.33m/s; starting cooling temperature 796℃, final cooling temperature 165℃, average cooling rate 11℃/s.

回火热处理过程中,回火温度610℃,保温时间120min,回火过程加热系数为2.42min/cm。During the tempering heat treatment, the tempering temperature was 610°C, the holding time was 120min, and the heating coefficient during the tempering process was 2.42min/cm.

实施例2所生产120mm规格力学性能见表5,探伤结果见表6。The mechanical properties of the 120mm specification produced in Example 2 are shown in Table 5, and the flaw detection results are shown in Table 6.

Figure 630230DEST_PATH_IMAGE008
Figure 630230DEST_PATH_IMAGE008

由图3可见,回火后主要为粒状贝氏体、板条贝氏体和多边形铁素体。由图4可见,回火后主要为粒状贝氏体和多边形铁素体,少部分为板条贝氏体。It can be seen from Figure 3 that after tempering, mainly granular bainite, lath bainite and polygonal ferrite are formed. It can be seen from Figure 4 that after tempering, it is mainly granular bainite and polygonal ferrite, and a small part is lath bainite.

综上,本发明在现有工装能力基础上,采用简单合理的成分设计及工艺要求,实现大厚度在线淬火工程机械用钢开发,突破了传统厚规格特厚钢板必须采用“离线再加热淬火+回火”工艺生产限制,在减少生产工序的同时,提高生产效率,降低生产成本。To sum up, on the basis of the existing tooling capabilities, the present invention adopts simple and reasonable component design and process requirements to realize the development of large-thickness on-line quenching engineering machinery steel, breaking through the traditional thick-specification extra-thick steel plate that must use "off-line reheating and quenching+". "Tempering" process production limitations, while reducing production processes, improve production efficiency and reduce production costs.

此外,本发明所涉及800MPa级特厚规格钢板,力学性能稳定,内部质量良好,强度、韧性及塑性良好,屈强比低,探伤满足国标要求,满足工程机械行业特殊用钢需求,具有优异的工业推广应用价值。In addition, the 800MPa grade extra-thick steel plate involved in the present invention has stable mechanical properties, good internal quality, good strength, toughness and plasticity, low yield-to-strength ratio, flaw detection meets the requirements of the national standard, meets the needs of special steel in the construction machinery industry, and has excellent Industrial promotion and application value.

Claims (2)

1.在线淬火800MPa级工程机械用特厚钢板,其特征在于:包括如下质量百分比的各组分:C:0.050-0.080%,Si:0.10-0.25%,Mn:1.30-1.50%,P≤0.015%,S≤0.005%,Al:0.020-0.040%,Nb:0.010-0.020%,Ti:0.008-0.015%,Ni:0.40-0.50%,Cr:0.30-0.40%,Mo:0.20-0.30%,Cu:0.20-0.30%,B:0.0010-0.0020%,N≤45ppm,H≤1.5ppm,O≤30ppm,余量为Fe及不可避免的杂质;1. On-line quenching 800MPa grade extra-thick steel plate for construction machinery, characterized in that it includes the following components in mass percentage: C: 0.050-0.080%, Si: 0.10-0.25%, Mn: 1.30-1.50%, P≤0.015 %, S≤0.005%, Al: 0.020-0.040%, Nb: 0.010-0.020%, Ti: 0.008-0.015%, Ni: 0.40-0.50%, Cr: 0.30-0.40%, Mo: 0.20-0.30%, Cu : 0.20-0.30%, B: 0.0010-0.0020%, N≤45ppm, H≤1.5ppm, O≤30ppm, the balance is Fe and inevitable impurities; 所述在线淬火800MPa级工程机械用特厚钢板通过如下方法制备而成:包括如下步骤:钢水冶炼、LF炉精炼、RH真空处理、厚板坯浇铸、板坯加热、钢板轧制、DQ+ACC冷却、回火热处理;其中,The on-line quenching 800MPa grade extra-thick steel plate for construction machinery is prepared by the following method: including the following steps: molten steel smelting, LF furnace refining, RH vacuum treatment, thick slab casting, slab heating, steel plate rolling, DQ+ACC Cooling, tempering heat treatment; of which, (1)钢水冶炼步骤,铁水通过脱硫扒渣,进入转炉冶炼,并经过“LF+RH”进行精炼;转炉出钢温度1650±20℃,LF结束温度1635±10℃,RH结束温度1585±5℃,软吹结束温度1565±5℃,中包温度1538±5℃;过程中,控制各组分含量如下:C:0.050-0.0.080%,P≤0.015%,S≤0.005%,N≤45ppm,H≤1.5ppm,O≤30ppm;深真空处理时间为15-20min;(1) The molten steel smelting step, the molten iron enters the converter for smelting through desulfurization and slag removal, and is refined by "LF+RH"; ℃, the end temperature of soft blowing is 1565±5℃, and the temperature of the middle bag is 1538±5℃; during the process, the content of each component is controlled as follows: C: 0.050-0.0.080%, P≤0.015%, S≤0.005%, N≤ 45ppm, H≤1.5ppm, O≤30ppm; deep vacuum treatment time is 15-20min; (2)厚板坯浇铸步骤:浇铸过程中保持恒拉速,拉速范围0.45m-0.55 m/min,平均过热度20-25℃;动态轻压下增加两相区及固相区压下量,压下速率1.10-1.30mm/m,两相区压下量8-10mm,固相区压下量0.5-1.5mm;保证板坯中心偏析C类≤0.5;(2) Casting steps for thick slabs: keep constant pulling speed during casting, the pulling speed range is 0.45m-0.55m/min, the average superheat is 20-25℃; dynamic light reduction increases the reduction of two-phase region and solid-phase region The reduction rate is 1.10-1.30mm/m, the reduction in the two-phase area is 8-10mm, and the reduction in the solid phase area is 0.5-1.5mm; ensure that the center segregation of the slab is C class ≤ 0.5; (3)板坯加热步骤:采用步进梁式加热炉将板坯分段加热至均热温度1180-1220℃;其中,第一加热段温度950-1050℃,第二加热段温度1050-1150℃,第三加热段温度1150-1200℃,第四加热段均热段温度为1180-1220℃,板坯在炉时间450-550min;(3) Slab heating step: use a walking beam heating furnace to heat the slab segmentally to a soaking temperature of 1180-1220°C; wherein the temperature of the first heating section is 950-1050°C, and the temperature of the second heating section is 1050-1150°C °C, the temperature of the third heating section is 1150-1200 °C, the temperature of the soaking section of the fourth heating section is 1180-1220 °C, and the slab is in the furnace for 450-550min; (4)钢板轧制步骤:采用再结晶区及非再结晶区分段轧制;再结晶区轧制阶段开始温度≥1100℃,结束温度范围为1000-1050℃,再结晶区轧制阶段总压下量为55-70%,其中第一阶段轧制最后2-3道次的单道次压下量在35-50mm;再结晶区轧制阶段轧制结束前2-3轧制道次的单道次压下率≥15-20%;再结晶区轧制完成后,中间坯待温厚度为1.7-2.0倍钢板成品厚度;非再结晶区轧制阶段开始温度830-850℃,结束温度为800-820℃,且非再结晶区轧制单道次压下率≤12%,累积压下率≥40-50%;(4) Steel plate rolling steps: the recrystallization zone and the non-recrystallization zone are used for segment rolling; the starting temperature of the rolling stage in the recrystallization zone is ≥1100 °C, the ending temperature is 1000-1050 °C, and the total pressure of the rolling stage in the recrystallization zone is 1000-1050 °C. The reduction is 55-70%, and the single-pass reduction of the last 2-3 passes of the first stage rolling is 35-50mm; The single-pass reduction ratio is ≥15-20%; after the recrystallization zone rolling is completed, the thickness of the intermediate billet to be warmed is 1.7-2.0 times the thickness of the finished steel plate; the starting temperature of the rolling stage in the non-recrystallization zone is 830-850℃, and the end temperature The temperature is 800-820℃, and the single-pass rolling reduction rate in the non-recrystallization zone is ≤12%, and the cumulative reduction rate is ≥40-50%; (5)DQ+ACC冷却步骤:冷却过程开启DQ缝隙集管及ACC高密快冷集管进行冷却,其中DQ缝隙集管进水压力0.4-0.5MPa,水流密度范围2000-3000L/(m2· min),ACC高密快冷集管进水压力0.2-0.3MPa,水流密度范围1000-2000L/(m2·min),总水量≥15000m3/h,辊道速度0.30-0.33m/min;开始冷却温度780-800℃,终冷温度200-300℃,冷速10-15℃/s;(5) DQ+ACC cooling step: During the cooling process, open the DQ slit header and the ACC high-density fast cooling header for cooling, where the water inlet pressure of the DQ slit header is 0.4-0.5MPa, and the water flow density range is 2000-3000L/(m 2 · min), the water inlet pressure of the ACC high-density fast cooling header is 0.2-0.3MPa, the water flow density range is 1000-2000L/(m 2 ·min), the total water volume is ≥15000m 3 /h, and the roller speed is 0.30-0.33m/min; start Cooling temperature 780-800℃, final cooling temperature 200-300℃, cooling rate 10-15℃/s; (6)回火热处理步骤:采用高温回火工艺;其中,回火温度及保温时间分别为“600-650℃”和“80-120min”,回火过程中加热系数为2.4±0.1min/cm;(6) Tempering heat treatment step: high temperature tempering process is adopted; among them, the tempering temperature and holding time are "600-650℃" and "80-120min" respectively, and the heating coefficient during the tempering process is 2.4±0.1min/cm ; 所述在线淬火800MPa级工程机械用特厚钢板的厚度为80-120mm。The thickness of the extra-thick steel plate for on-line quenching of 800MPa grade construction machinery is 80-120mm. 2.如权利要求1所述的一种在线淬火800MPa级工程机械用特厚钢板的制造方法,其特征在于:包括如下步骤:钢水冶炼、LF炉精炼、RH真空处理、厚板坯浇铸、板坯加热、钢板轧制、DQ+ACC冷却、回火热处理;其中,2. the manufacture method of a kind of on-line quenching 800MPa grade construction machinery extra-thick steel plate as claimed in claim 1, it is characterized in that: comprise the steps: molten steel smelting, LF furnace refining, RH vacuum treatment, thick slab casting, plate Billet heating, steel plate rolling, DQ+ACC cooling, tempering heat treatment; among them, (1)钢水冶炼步骤,铁水通过脱硫扒渣,进入转炉冶炼,并经过“LF+RH”进行精炼;转炉出钢温度1650±20℃,LF结束温度1635±10℃,RH结束温度1585±5℃,软吹结束温度1565±5℃,中包温度1538±5℃;过程中,控制各组分含量如下:C:0.050-0.0.080%,P≤0.015%,S≤0.005%,N≤45ppm,H≤1.5ppm,O≤30ppm;深真空处理时间为15-20min;(1) The molten steel smelting step, the molten iron enters the converter for smelting through desulfurization and slag removal, and is refined by "LF+RH"; ℃, the end temperature of soft blowing is 1565±5℃, and the temperature of the middle bag is 1538±5℃; during the process, the content of each component is controlled as follows: C: 0.050-0.0.080%, P≤0.015%, S≤0.005%, N≤ 45ppm, H≤1.5ppm, O≤30ppm; deep vacuum treatment time is 15-20min; (2)厚板坯浇铸步骤:浇铸过程中保持恒拉速,拉速范围0.45m-0.55 m/min,平均过热度20-25℃;动态轻压下增加两相区及固相区压下量,压下速率1.10-1.30mm/m,两相区压下量8-10mm,固相区压下量0.5-1.5mm;保证板坯中心偏析C类≤0.5;(2) Casting steps for thick slabs: keep constant pulling speed during casting, the pulling speed range is 0.45m-0.55m/min, the average superheat is 20-25℃; dynamic light reduction increases the reduction of two-phase region and solid-phase region The reduction rate is 1.10-1.30mm/m, the reduction in the two-phase area is 8-10mm, and the reduction in the solid phase area is 0.5-1.5mm; ensure that the center segregation of the slab is C class ≤ 0.5; (3)板坯加热步骤:采用步进梁式加热炉将板坯分段加热至均热温度1180-1220℃;其中,第一加热段温度950-1050℃,第二加热段温度1050-1150℃,第三加热段温度1150-1200℃,第四加热段均热段温度为1180-1220℃,板坯在炉时间450-550min;(3) Slab heating step: use a walking beam heating furnace to heat the slab segmentally to a soaking temperature of 1180-1220°C; wherein the temperature of the first heating section is 950-1050°C, and the temperature of the second heating section is 1050-1150°C °C, the temperature of the third heating section is 1150-1200 °C, the temperature of the soaking section of the fourth heating section is 1180-1220 °C, and the slab is in the furnace for 450-550min; (4)钢板轧制步骤:采用再结晶区及非再结晶区分段轧制;再结晶区轧制阶段开始温度≥1100℃,结束温度范围为1000-1050℃,再结晶区轧制阶段总压下量为55-70%,其中第一阶段轧制最后2-3道次的单道次压下量在35-50mm;再结晶区轧制阶段轧制结束前2-3轧制道次的单道次压下率≥15-20%;再结晶区轧制完成后,中间坯待温厚度为1.7-2.0倍钢板成品厚度;非再结晶区轧制阶段开始温度830-850℃,结束温度为800-820℃,且非再结晶区轧制单道次压下率≤12%,累积压下率≥40-50%;(4) Steel plate rolling steps: the recrystallization zone and the non-recrystallization zone are used for segment rolling; the starting temperature of the rolling stage in the recrystallization zone is ≥1100 °C, the ending temperature is 1000-1050 °C, and the total pressure of the rolling stage in the recrystallization zone is 1000-1050 °C. The reduction is 55-70%, and the single-pass reduction of the last 2-3 passes of the first stage rolling is 35-50mm; The single-pass reduction ratio is ≥15-20%; after the recrystallization zone rolling is completed, the thickness of the intermediate billet to be warmed is 1.7-2.0 times the thickness of the finished steel plate; the starting temperature of the rolling stage in the non-recrystallization zone is 830-850℃, and the end temperature The temperature is 800-820℃, and the single-pass rolling reduction rate in the non-recrystallization zone is ≤12%, and the cumulative reduction rate is ≥40-50%; (5)DQ+ACC冷却步骤:冷却过程开启DQ缝隙集管及ACC高密快冷集管进行冷却,其中DQ缝隙集管进水压力0.4-0.5MPa,水流密度范围2000-3000L/(m2· min),ACC高密快冷集管进水压力0.2-0.3MPa,水流密度范围1000-2000L/(m2·min),总水量≥15000m3/h,辊道速度0.30-0.33m/min;开始冷却温度780-800℃,终冷温度200-300℃,冷速10-15℃/s;(5) DQ+ACC cooling step: During the cooling process, open the DQ slit header and the ACC high-density fast cooling header for cooling, where the water inlet pressure of the DQ slit header is 0.4-0.5MPa, and the water flow density range is 2000-3000L/(m 2 · min), the water inlet pressure of the ACC high-density fast cooling header is 0.2-0.3MPa, the water flow density range is 1000-2000L/(m 2 ·min), the total water volume is ≥15000m 3 /h, and the roller speed is 0.30-0.33m/min; start Cooling temperature 780-800℃, final cooling temperature 200-300℃, cooling rate 10-15℃/s; (6)回火热处理步骤:采用高温回火工艺;其中,回火温度及保温时间分别为“600-650℃”和“80-120min”,回火过程中加热系数为2.4±0.1min/cm。(6) Tempering heat treatment step: high temperature tempering process is adopted; among them, the tempering temperature and holding time are "600-650℃" and "80-120min" respectively, and the heating coefficient during the tempering process is 2.4±0.1min/cm .
CN202110596153.7A 2021-05-30 2021-05-30 On-line quenching 800MPa grade extra-thick steel plate for construction machinery and its manufacturing method Active CN113355600B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110596153.7A CN113355600B (en) 2021-05-30 2021-05-30 On-line quenching 800MPa grade extra-thick steel plate for construction machinery and its manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110596153.7A CN113355600B (en) 2021-05-30 2021-05-30 On-line quenching 800MPa grade extra-thick steel plate for construction machinery and its manufacturing method

Publications (2)

Publication Number Publication Date
CN113355600A CN113355600A (en) 2021-09-07
CN113355600B true CN113355600B (en) 2022-10-25

Family

ID=77528184

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110596153.7A Active CN113355600B (en) 2021-05-30 2021-05-30 On-line quenching 800MPa grade extra-thick steel plate for construction machinery and its manufacturing method

Country Status (1)

Country Link
CN (1) CN113355600B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114107819B (en) * 2021-11-26 2022-09-20 宝武集团鄂城钢铁有限公司 800 MPa-grade tempering-resistant high-strength steel plate and preparation method thereof
CN115216608A (en) * 2022-07-28 2022-10-21 湖南华菱湘潭钢铁有限公司 Production method of Q420 grade high-corrosion-resistance high-strength quenched and tempered steel plate for offshore structure
CN116536591B (en) * 2023-06-25 2025-06-03 新余钢铁股份有限公司 600MPa steel plate for bifurcated pipe ribs
CN117644188B (en) * 2023-12-12 2024-06-04 北京科技大学 Method for improving quality of ultra-thick plate blank

Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008266758A (en) * 2007-04-25 2008-11-06 Jfe Steel Kk High tensile steel with excellent low temperature toughness and low strength anisotropy and method for producing the same
CN102851615A (en) * 2011-06-28 2013-01-02 鞍钢股份有限公司 Tensile strength 800 MPa-grade low-yield-ratio structural steel plate and manufacturing method thereof
CN103290339A (en) * 2013-06-29 2013-09-11 首钢总公司 High-strength steel plate for 800MPa hydropower station pressure pipeline and production method thereof
CN104131235A (en) * 2014-07-22 2014-11-05 武汉钢铁(集团)公司 LPG boat storage tank steel plate and production method thereof
CN104264064A (en) * 2014-09-15 2015-01-07 江阴兴澄特种钢铁有限公司 Extra-thick-gauge Q690 high-strength Structural steel plate and preparation method of structural steel plate
CN104831181A (en) * 2015-03-27 2015-08-12 武汉钢铁(集团)公司 Liquefied petroleum gas (LPG) marine storage tank steel plate and making method thereof
WO2016119500A1 (en) * 2015-01-30 2016-08-04 宝山钢铁股份有限公司 Steel plate having high crack-arresting performance, and manufacturing method thereof
CN107675096A (en) * 2017-08-15 2018-02-09 河钢股份有限公司邯郸分公司 A kind of strong steel for engineering machinery plate Q800C of superelevation and its production method
CN109161790A (en) * 2018-08-22 2019-01-08 江阴兴澄特种钢铁有限公司 The high-level high tenacity pipe fitting steel plate and its manufacturing method used under a kind of acid condition
CN109207855A (en) * 2018-10-16 2019-01-15 五矿营口中板有限责任公司 Microstructure uniform shock has the special heavy plate and its manufacturing method of excellent toughness
CN109487163A (en) * 2018-12-13 2019-03-19 河钢股份有限公司 Direct quenching type surrenders 800MPa level structure steel plate and its production method
CN109628828A (en) * 2018-12-27 2019-04-16 江阴兴澄特种钢铁有限公司 A kind of low yield strength ratio super thick water power high-strength steel sheet and its manufacturing method
CN111020376A (en) * 2019-11-14 2020-04-17 舞阳钢铁有限责任公司 Low-yield-ratio high-toughness 770 MPa-grade weather-resistant bridge steel plate and production method thereof
CN111118401A (en) * 2020-02-28 2020-05-08 五矿营口中板有限责任公司 High-performance large-thickness easy-to-weld bridge structural steel and manufacturing method thereof
WO2020130354A1 (en) * 2018-12-19 2020-06-25 주식회사 포스코 Method for manufacturing ultra-thick steel sheet and cast piece for ultra-thick steel sheet
CN111876687A (en) * 2020-08-12 2020-11-03 宝武集团鄂城钢铁有限公司 Easy-to-weld high-strength steel with excellent low-temperature toughness and tensile strength of 800MPa and production method thereof
CN112143968A (en) * 2020-08-30 2020-12-29 五矿营口中板有限责任公司 Ultra-thick X70M-grade double-resistance pipeline steel plate and manufacturing method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4637516B2 (en) * 2004-06-28 2011-02-23 株式会社神戸製鋼所 Steel sheet with excellent low temperature toughness of welded joints

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008266758A (en) * 2007-04-25 2008-11-06 Jfe Steel Kk High tensile steel with excellent low temperature toughness and low strength anisotropy and method for producing the same
CN102851615A (en) * 2011-06-28 2013-01-02 鞍钢股份有限公司 Tensile strength 800 MPa-grade low-yield-ratio structural steel plate and manufacturing method thereof
CN103290339A (en) * 2013-06-29 2013-09-11 首钢总公司 High-strength steel plate for 800MPa hydropower station pressure pipeline and production method thereof
CN104131235A (en) * 2014-07-22 2014-11-05 武汉钢铁(集团)公司 LPG boat storage tank steel plate and production method thereof
CN104264064A (en) * 2014-09-15 2015-01-07 江阴兴澄特种钢铁有限公司 Extra-thick-gauge Q690 high-strength Structural steel plate and preparation method of structural steel plate
WO2016119500A1 (en) * 2015-01-30 2016-08-04 宝山钢铁股份有限公司 Steel plate having high crack-arresting performance, and manufacturing method thereof
CN104831181A (en) * 2015-03-27 2015-08-12 武汉钢铁(集团)公司 Liquefied petroleum gas (LPG) marine storage tank steel plate and making method thereof
CN107675096A (en) * 2017-08-15 2018-02-09 河钢股份有限公司邯郸分公司 A kind of strong steel for engineering machinery plate Q800C of superelevation and its production method
CN109161790A (en) * 2018-08-22 2019-01-08 江阴兴澄特种钢铁有限公司 The high-level high tenacity pipe fitting steel plate and its manufacturing method used under a kind of acid condition
CN109207855A (en) * 2018-10-16 2019-01-15 五矿营口中板有限责任公司 Microstructure uniform shock has the special heavy plate and its manufacturing method of excellent toughness
CN109487163A (en) * 2018-12-13 2019-03-19 河钢股份有限公司 Direct quenching type surrenders 800MPa level structure steel plate and its production method
WO2020130354A1 (en) * 2018-12-19 2020-06-25 주식회사 포스코 Method for manufacturing ultra-thick steel sheet and cast piece for ultra-thick steel sheet
CN109628828A (en) * 2018-12-27 2019-04-16 江阴兴澄特种钢铁有限公司 A kind of low yield strength ratio super thick water power high-strength steel sheet and its manufacturing method
CN111020376A (en) * 2019-11-14 2020-04-17 舞阳钢铁有限责任公司 Low-yield-ratio high-toughness 770 MPa-grade weather-resistant bridge steel plate and production method thereof
CN111118401A (en) * 2020-02-28 2020-05-08 五矿营口中板有限责任公司 High-performance large-thickness easy-to-weld bridge structural steel and manufacturing method thereof
CN111876687A (en) * 2020-08-12 2020-11-03 宝武集团鄂城钢铁有限公司 Easy-to-weld high-strength steel with excellent low-temperature toughness and tensile strength of 800MPa and production method thereof
CN112143968A (en) * 2020-08-30 2020-12-29 五矿营口中板有限责任公司 Ultra-thick X70M-grade double-resistance pipeline steel plate and manufacturing method thereof

Also Published As

Publication number Publication date
CN113355600A (en) 2021-09-07

Similar Documents

Publication Publication Date Title
CN113355600B (en) On-line quenching 800MPa grade extra-thick steel plate for construction machinery and its manufacturing method
CN109536846B (en) High-toughness hot-rolled steel plate with yield strength of 700MPa and manufacturing method thereof
CN101161847B (en) High-toughness steel for hot-bending pipe and production method of hot-rolled flat plate thereof
CN101775559A (en) Easily welded high-strength-and-toughness ship plate steel and production process
CN115652211B (en) Economical 420 MPa-level steel plate cooling uniformity control method for engineering structure
CN115572912B (en) An economical 460MPa level steel plate cooling uniformity control method for engineering structures
CN112981257A (en) Economical thick-wall high-strength high-toughness X70M hot-rolled steel plate and manufacturing method thereof
CN112226673A (en) Hot rolled steel plate with 650 MPa-grade tensile strength and manufacturing method thereof
CN114717482A (en) Low-yield-ratio rare earth titanium weathering steel and production method thereof
CN113957359A (en) High-strength steel for automobile wheels and preparation method thereof
CN103160747A (en) Low-welding crack sensitivity off-line quenched and tempered super-thick steel plate and manufacturing method thereof
CN105112810B (en) Steel for high heat input resisting welding and preparation method thereof
CN111979499A (en) Production method of low-cost Q460C thick steel plate
CN116043128B (en) 460E-grade super-thick steel plate and production method thereof
CN114737109B (en) Steel for X52 straight welded pipe for thick-wall HIC-resistant oil and gas pipeline and manufacturing method thereof
WO2024002043A1 (en) Hot-rolled complex-phase steel with 800-mpa-grade tensile strength and manufacturing method therefor
CN112981258B (en) X70M hot-rolled steel plate for thin-specification gas transmission straight welded pipe and manufacturing method
CN116145048A (en) Economical high-toughness L555M pipeline steel hot-rolled coil and production method thereof
CN111910128B (en) Steel plate for Q690-grade coal mine hydraulic support and production method thereof
CN114737124A (en) Low-yield-ratio and low-cost weathering steel and production method thereof
CN112831724A (en) A kind of S420 high-strength low-temperature structural steel and normalizing rolling preparation method thereof
CN116426828B (en) A low-cost, thick, high-performance NM450 steel plate and its manufacturing method
CN115679216B (en) An economical 345MPa level steel plate cooling uniformity control method for engineering structures
CN113174536B (en) Economical low-temperature toughness E-grade high-strength steel plate for ship and manufacturing method thereof
CN112126851B (en) Easy-weldable low-alloy structural steel with high Ti and micro Al in ultra-fast cooling mode and its manufacturing method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: 115005 metallurgical street, old border district, Yingkou City, Liaoning Province

Applicant after: Japan Steel Yingkou Medium Plate Co.,Ltd.

Address before: 115005 metallurgical street, old border district, Yingkou City, Liaoning Province

Applicant before: MINMETALS YINGKOU MEDIUM PLATE Co.,Ltd.

CB02 Change of applicant information
GR01 Patent grant
GR01 Patent grant
CP03 Change of name, title or address

Address after: 115005 metallurgical street, old border district, Yingkou City, Liaoning Province

Patentee after: Jingye (Yingkou) Medium Plate Co.,Ltd.

Country or region after: China

Address before: 115005 metallurgical street, old border district, Yingkou City, Liaoning Province

Patentee before: Japan Steel Yingkou Medium Plate Co.,Ltd.

Country or region before: China

CP03 Change of name, title or address