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CN113320251A - 一种高粘连强度防水卷材组合物及其制备方法 - Google Patents

一种高粘连强度防水卷材组合物及其制备方法 Download PDF

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CN113320251A
CN113320251A CN202110577107.2A CN202110577107A CN113320251A CN 113320251 A CN113320251 A CN 113320251A CN 202110577107 A CN202110577107 A CN 202110577107A CN 113320251 A CN113320251 A CN 113320251A
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coiled material
rubber
waterproof coiled
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孔春果
宋昭萍
方伟
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Nanjing Numanco New Materials Co ltd
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Abstract

本发明适用于高分子材料加工技术领域，提供了一种高粘连强度防水卷材组合物，包括：高饱和疏水橡胶、极性官能团橡胶、高黏结性功能材料、高强度纤维布基层、补强剂、硫化剂、增塑剂。本发明还提供了一种高粘连强度防水卷材组合物的制备方法，包括以下步骤：预硫化防水卷材上层橡胶组合物片材的制备；预硫化防水卷材下层橡胶组合物片材的制备；防水卷材基础纤维布的制备；预硫化防水卷材组合物片材的制备；高粘连强度防水卷材组合物的制备。本发明实施例提供的一种高粘连强度防水卷材组合物，不仅防水性能好、耐候及耐老化性能优异，还具有与建材部件黏结强度高的特点，适用于堤坝、建筑屋顶、道路等工程施工过程的防水处理。

Description

一种高粘连强度防水卷材组合物及其制备方法
技术领域
本发明属于高分子材料加工技术领域，尤其涉及一种高粘连强度防水卷材组合物及其制备方法。
背景技术
防水卷材主要是用于建筑墙体、屋面、以及隧道、公路、垃圾填埋场等领域，起到抵御外界雨水、地下水渗漏的一种可卷曲成卷状的柔性建材产品，作为工程基础与建筑物之间无渗漏连接，是整个工程防水的第一道屏障，对整个工程起着至关重要的作用，产品主要有沥青防水卷材和高分子防水卷材。
在沥青防水卷材方面，现有技术中公开了一种耐酸碱的弹性体改性沥青防水卷材，其构成主要为上下聚乙烯膜隔离层及弹性体改性沥青胶胎基层，胎基层为少量SBS改性的沥青组合物；公开了一种耐根穿刺自粘聚合物改性沥青防水卷材，其上下隔离层为聚乙烯膜，中间隔离层为丁苯橡胶、SBS改性的石油沥青。可见，沥青防水橡胶需要有上下隔离层，中间层通常为沥青胎基层或聚合物改性的沥青胎基层。
在高分子防水卷材方面，现有技术中公开了一种可粘连的TPO防水卷材，其结构为中间是聚酯网格布，上下层为TPO材料，网格布与上下层之间用胶粘层粘连；还公开了一种高铁用防水卷材，其特点是含有三层纤维布，其中上下层纤维布为聚酯无纺布，中间层纤维布为合成纤维交织布，在纤维布中间为硫化橡胶层；还公开了一种高分子自粘胶膜防水材料，其制备方法是防水卷材中间为三元乙丙橡胶防水层，三元乙丙橡胶防水层上下表面贴付自粘膜，在上下自粘膜上在贴附隔离层，隔离层可以是PE膜、PET膜、PVC膜等；还提供了一种屋面用聚烯烃高分子防水卷材的制备方法，其特点是防水层为含有抗氧剂、紫外光吸收剂的聚乙烯，防老化层为SEBS。
可以看出，现有技术中的沥青防水卷材和高分子防水卷材构成体系单一，针对性不强。
发明内容
本发明实施例的目的在于提供一种高粘连强度防水卷材组合物，旨在解决现有技术中沥青防水卷材和高分子防水卷材构成体系单一，针对性不强的问题。
本发明实施例是这样实现的，一种高粘连强度防水卷材组合物，包括：高饱和疏水橡胶、极性官能团橡胶、高黏结性功能材料、高强度纤维布基层、补强剂、硫化剂、增塑剂；
所述高饱和疏水橡胶为分子主链为线型且主链不含-C＝C-双键的高饱和疏水性橡胶、弹性体；
所述极性官能团橡胶为分子链含有极性官能团且具有线型结构的橡胶、弹性体；
所述高黏结性功能材料为具有极性或非极性基团的液体橡胶或反应性液体低分子化合物。
本发明实施例的另一目的在于提供一种高粘连强度防水卷材组合物的制备方法，包括以下步骤：
预硫化防水卷材上层橡胶组合物片材的制备：将高饱和疏水橡胶、硫化剂、补强剂和增塑剂在密炼机中密炼均匀得到预硫化防水卷材上层橡胶组合物母料，密炼温度为80～100℃，将预硫化防水卷材上层橡胶组合物母料通过开炼机或多辊压延机辊压成片得到预硫化防水卷材上层橡胶组合物片材，辊压温度为40～60℃，片材厚度为0.5～5.0mm；
预硫化防水卷材下层橡胶组合物片材的制备：将极性官能团橡胶，硫化剂、补强剂和增塑剂在密炼机中密炼均匀得到预硫化防水卷材下层橡胶组合物母料，密炼温度为80～120℃，将预硫化防水卷材下层橡胶组合物母料通过开炼机或多辊压延机辊压成片得到预硫化防水卷材上层橡胶组合物片材，辊压温度为40～60℃，片材厚度为0.5～5.0mm之间；
防水卷材基础纤维布的制备：将高黏结性功能材料溶于溶剂中搅拌均匀形成功能化粘连胶液，溶剂为甲苯、环烷油、二甲苯中的一种，使功能化粘连胶液附着在高强度纤维布基层的表面得到防水卷材基础纤维布；
预硫化防水卷材组合物片材的制备：将预硫化防水卷材上层橡胶组合物片材、防水卷材基础纤维布及预硫化防水卷材下层橡胶组合物片材经过辊压贴合加工成预硫化防水卷材组合物片材，片材厚度为0.5～5.0mm；
高粘连强度防水卷材组合物的制备：将预硫化防水卷材组合物片材放入硫化箱交联熟化，硫化箱的硫化温度为140～200℃，硫化时间为30～60min，制备出高粘连强度防水卷材组合物。
本发明实施例提供的一种高粘连强度防水卷材组合物，不仅防水性能好、耐候及耐老化性能优异，还具有与建材部件黏结强度高的特点，适用于堤坝、建筑屋顶、道路等工程施工过程的防水处理。
附图说明
图1为本发明实施例提供的一种高粘连强度防水卷材组合物的剖视图。
附图中：1、预硫化防水卷材上层橡胶组合物片材；2、防水卷材基础纤维布；3、预硫化防水卷材下层橡胶组合物片材。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合附图及实施例，对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
以下结合具体实施例对本发明的具体实现进行详细描述。
一种高粘连强度防水卷材组合物，包括：高饱和疏水橡胶、极性官能团橡胶、高黏结性功能材料、高强度纤维布基层、补强剂、硫化剂、增塑剂；
其中，所述高饱和疏水橡胶为分子主链为线型且主链不含-C＝C-双键的高饱和疏水性橡胶、弹性体，具体可以为所述高饱和疏水橡胶为三元乙丙橡胶、氢化天然橡胶、氢化丁苯橡胶、氢化苯乙烯-丁二烯-苯乙烯嵌段共聚物、氢化苯乙烯-异戊二烯-苯乙烯嵌段共聚物、丁基橡胶、乙烯-辛烯共聚物、无规共聚聚丙烯中的一种；
所述极性官能团橡胶为分子链含有极性官能团且具有线型结构的橡胶、弹性体，具体可以为氢化丁腈橡胶、氯丁橡胶、氯磺化聚乙烯、氯醚橡胶、聚氨酯橡胶、氯化聚乙烯、环氧化天然橡胶、软质聚氯乙烯中一种；
所述高黏结性功能材料为具有极性或非极性基团的液体橡胶或反应性液体低分子化合物，具体可以为液体丁腈橡胶、端羧基液体丁腈橡胶、端羟基液体聚丁二烯橡胶、二苯基甲烷二异氰酸酯中的一种；
所述高强度纤维布基层为玻璃纤维布、碳纤维布、尼龙纤维布、高分子量聚乙烯纤维布、聚丙烯纤维布、聚甲醛纤维布中一种；
所述补强剂为炭黑，型号可以是N110、N220、N330、N550、N660等、白炭黑，可以是气相法白炭黑，也可以是沉淀法白炭黑，级别为橡胶级、纳米碳酸钙、纳米滑石粉、纳米二氧化硅、纳米硫酸钙、钛酸钾晶须中的一种或多种；
所述硫化剂为硫磺、二硫化四甲基秋兰姆、过氧化二异丙苯、三烯丙基异三聚氰酸酯、二苯基甲烷二异氰酸酯、马来酸酐接枝聚丙烯中的一种或多种；
所述增塑剂为氯化石蜡、领苯二甲酸二丁酯、邻苯二甲酸二辛脂、环氧大豆油、己二酸二辛脂、磷酸三甲苯酯中的一种或多种。
如图1所示，一种高粘连强度防水卷材组合物的制备方法，包括以下步骤：
预硫化防水卷材上层橡胶组合物片材的制备：将高饱和疏水橡胶、硫化剂、补强剂和增塑剂在密炼机中密炼均匀得到预硫化防水卷材上层橡胶组合物母料，密炼温度为80～100℃，将预硫化防水卷材上层橡胶组合物母料通过开炼机或多辊压延机辊压成片得到预硫化防水卷材上层橡胶组合物片材，辊压温度为40～60℃，片材厚度为0.5～5.0mm，片材宽度由辊压设备出胶调节挡板控制，片材长度由滑动切刀根据需求切割；
预硫化防水卷材下层橡胶组合物片材的制备：将极性官能团橡胶，硫化剂、补强剂和增塑剂在密炼机中密炼均匀得到预硫化防水卷材下层橡胶组合物母料，密炼温度为80～120℃，将预硫化防水卷材下层橡胶组合物母料通过开炼机或多辊压延机辊压成片得到预硫化防水卷材上层橡胶组合物片材，辊压温度为40～60℃，片材厚度为0.5～5.0mm之间，片材宽度由辊压设备出胶调节挡板控制，片材长度由滑动切刀根据需求切割；
防水卷材基础纤维布的制备：将高黏结性功能材料溶于溶剂中搅拌均匀形成功能化粘连胶液，溶剂为甲苯、环烷油、二甲苯中的一种，使功能化粘连胶液附着在高强度纤维布基层的表面得到防水卷材基础纤维布，可以采用浸渍方法或涂覆方法，采用浸渍方法时，将高强度纤维布基层在功能化粘连胶液中浸渍10～30min，使胶液均匀浸渍于纤维布内外，再脱除溶剂即可，采用涂覆方法时，将高粘连性功能材料，用机械涂刷的方法均聚涂覆在高强度纤维布基层表面即可；
预硫化防水卷材组合物片材的制备：将预硫化防水卷材上层橡胶组合物片材、防水卷材基础纤维布及预硫化防水卷材下层橡胶组合物片材经过辊压贴合加工成预硫化防水卷材组合物片材，片材厚度为0.5～5.0mm，其中，防水卷材基础纤维布的作用是作为防水卷材的结构支撑或基础载体，通过辊压操作将预硫化防水卷材上层橡胶组合物片材和预硫化防水卷材下层橡胶组合物片材紧密牢固的贴合在防水卷材基础纤维布的上下表面，以便后续硫化操作制备防水卷材；
高粘连强度防水卷材组合物的制备：将预硫化防水卷材组合物片材放入硫化箱交联熟化，硫化箱的硫化温度为140～200℃，硫化时间为30～60min，制备出高粘连强度防水卷材组合物。
实施例1
(1)将100份高饱和疏水的三元乙丙橡胶EPDM，1.5份硫磺，0.75份二硫化四甲基秋兰姆，2.5份炭黑N330，2.5份纳米碳酸钙及适量增塑剂，加入到密炼机中于80℃下密炼15min排料；将密炼好的预硫化防水卷材上层橡胶组合物母料在开炼机或多辊压延机上压片，形成预硫化防水卷材上层橡胶组合物片材，压片温度为45℃，胶片厚度为2.8mm；
(2)将100份含极性官能团的氯化聚乙烯橡胶CPE，1.5份硫磺，0.5份过氧化二异丙苯，2.5份炭黑N330，2.5份纳米滑石粉，3.0份端羧基液体丁腈橡胶及适量增塑剂，加入到密炼机中于85℃下密炼15min排料；将密炼好的预硫化防水卷材下层橡胶组合物母料在开炼机或多辊压延机上压片，形成预硫化防水卷材下层橡胶组合物片材，压片温度为45℃，胶片厚度为2.7mm；
(3)采用涂刷工艺，将高粘连液体橡胶端羧基液体丁腈橡胶均匀的涂覆在玻璃纤维布的两侧，形成具有高粘连性的防水卷材基础纤维布；
(4)分别将预硫化防水卷材上层橡胶组合物片材和预硫化防水卷材下层橡胶组合物片材密实贴附在防水卷材基础纤维布上下表面，通过多辊压延机将上述混合胶片压延、压实，形成预硫化高粘连强度防水卷材组合物片材，胶片厚度为5.0mm；
(5)通过鼓式硫化箱硫化交联上述预硫化高粘连强度防水卷材组合物片材，硫化温度为175℃，硫化时间为30min，经过硫化交联工艺后，得到高粘连强度防水卷材组合物。
实施例2
(1)将100份高饱和疏水的氢化苯乙烯-丁二烯-苯乙烯共聚物SEBS，1.5份三烯丙基异三聚氰酸酯，2.5份炭黑N220，2.5份纳米二氧化硅及适量增塑剂，加入到密炼机中于85℃下密炼20min排料；将密炼好的预硫化防水卷材上层橡胶组合物母料在开炼机或多辊压延机上压片，形成预硫化防水卷材上层橡胶组合物片材，压片温度为50℃，胶片厚度为2.6mm；
(2)将100份含极性官能团的聚氨酯橡胶，1.5份二苯甲烷二异氰酸酯，2.5份炭黑N220，2.5份纳米碳酸钙，2.5份端羟基液体聚丁二烯及适量增塑剂，加入到密炼机中于85℃下密炼20min排料；将密炼好的预硫化防水卷材下层橡胶组合物母料在开炼机或多辊压延机上压片，形成预硫化防水卷材下层橡胶组合物片材，压片温度为45℃，胶片厚度为2.8mm；
(3)采用涂刷工艺，将高粘连液体橡胶羟基液体聚丁二烯均匀的涂覆在玻璃纤维布的两侧，形成具有高粘连性的防水卷材基础纤维布；
(4)分别将预硫化防水卷材上层橡胶组合物片材和预硫化防水卷材下层橡胶组合物片材密实贴附在防水卷材基础纤维布上下表面，通过多辊压延机将上述混合胶片压延、压实，形成预硫化高粘连强度防水卷材组合物片材，胶片厚度为4.9mm；
(5)通过鼓式硫化箱硫化交联上述预硫化高粘连强度防水卷材组合物片材，硫化温度为175℃，硫化时间为30min，经过硫化交联工艺后，得到高粘连强度防水卷材组合物。
实施例3
(1)将100份高饱和疏水的丁基橡胶，1.5份硫磺，0.5份二硫化四甲基秋兰姆，2.5份炭黑N550，2.5份纳米碳酸钙及适量增塑剂，加入到密炼机中于90℃下密炼25min排料；将密炼好的预硫化防水卷材上层橡胶组合物母料在开炼机或多辊压延机上压片，形成预硫化防水卷材上层橡胶组合物片材，压片温度为45℃，胶片厚度为2.7mm；
(2)将100份含极性官能团的软质聚氯乙烯，1.0份二苯甲烷二异氰酸酯，2.5份炭黑N550，2.5份纳米碳酸钙，2.5份端羧基液体丁腈橡胶及适量增塑剂，加入到密炼机中于90℃下密炼25min排料；将密炼好的预硫化防水卷材下层橡胶组合物母料在开炼机或多辊压延机上压片，形成预硫化防水卷材下层橡胶组合物片材，压片温度为45℃，胶片厚度为2.8mm；
(3)采用涂刷工艺，将高粘连液体丁腈橡胶均匀的涂覆在尼龙纤维布的两侧，形成具有高粘连性的防水卷材基础纤维布；
(4)分别将预硫化防水卷材上层橡胶组合物片材和预硫化防水卷材下层橡胶组合物片材密实贴附在防水卷材基础纤维布上下表面，通过多辊压延机将上述混合胶片压延、压实，形成预硫化高粘连强度防水卷材组合物片材，胶片厚度为5.0mm；
(5)通过鼓式硫化箱硫化交联上述预硫化高粘连强度防水卷材组合物片材，硫化温度为175℃，硫化时间为30min，经过硫化交联工艺后，得到高粘连强度防水卷材组合物。
实施例4
(1)将100份高饱和疏水的乙烯-辛烯共聚物，2.5份马来酸酐接枝聚丙烯，2.5份炭黑N330，2.5份纳米二氧化硅及适量增塑剂，加入到密炼机中于85℃下密炼20min排料；将密炼好的预硫化防水卷材上层橡胶组合物母料在开炼机或多辊压延机上压片，形成预硫化防水卷材上层橡胶组合物片材，压片温度为45℃，胶片厚度为2.8mm；
(2)将100份含极性官能团的环氧化天然橡胶，1.5份硫磺，0.5份二硫化四甲基秋兰姆，2.5份炭黑N330，2.5份纳米二氧化硅，2.5份端二苯基甲烷二异氰酸酯及适量增塑剂，加入到密炼机中于80℃下密炼20min排料；将密炼好的预硫化防水卷材下层橡胶组合物母料在开炼机或多辊压延机上压片，形成预硫化防水卷材下层橡胶组合物片材，压片温度为45℃，胶片厚度为2.8mm。
(3)采用涂刷工艺，将高粘连液体氢化丁腈橡胶均匀的涂覆在尼龙纤维布的两侧，形成具有高粘连性的防水卷材基础纤维布；
(4)分别将预硫化防水卷材上层橡胶组合物片材和预硫化防水卷材下层橡胶组合物片材密实贴附在防水卷材基础纤维布上下表面，通过多辊压延机将上述混合胶片压延、压实，形成预硫化高粘连强度防水卷材组合物片材，胶片厚度为5.0mm；
(5)通过鼓式硫化箱硫化交联上述预硫化高粘连强度防水卷材组合物片材，硫化温度为175℃，硫化时间为30min，经过硫化交联工艺后，得到高粘连强度防水卷材组合物。
实施例5
(1)将100份高饱和疏水的无规共聚聚丙烯，2.5份马来酸酐接枝聚丙烯，2.5份炭黑N330，2.5份纳米二氧化硅及适量增塑剂，加入到密炼机中于85℃下密炼20min排料；将密炼好的预硫化防水卷材上层橡胶组合物母料在开炼机或多辊压延机上压片，形成预硫化防水卷材上层橡胶组合物片材，压片温度为45℃，胶片厚度为2.8mm；
(2)将100份含极性官能团的氯醚橡胶，1.5份三烯丙基异三聚氰酸酯，2.5份炭黑N330，2.5份纳米二氧化硅，2.5份液体丁腈橡胶及适量增塑剂，加入到密炼机中于80℃下密炼20min排料；将密炼好的预硫化防水卷材下层橡胶组合物母料在开炼机或多辊压延机上压片，形成预硫化防水卷材下层橡胶组合物片材，压片温度为45℃，胶片厚度为2.8mm；
(3)采用涂刷工艺，将高粘连液体丁腈橡胶均匀的涂覆在聚丙烯纤维布的两侧，形成具有高粘连性的防水卷材基础纤维布；
(4)分别将预硫化防水卷材上层橡胶组合物片材和预硫化防水卷材下层橡胶组合物片材密实贴附在防水卷材基础纤维布上下表面，通过多辊压延机将上述混合胶片压延、压实，形成预硫化高粘连强度防水卷材组合物片材，胶片厚度为5.0mm；
(5)通过鼓式硫化箱硫化交联上述预硫化高粘连强度防水卷材组合物片材，硫化温度为175℃，硫化时间为30min，经过硫化交联工艺后，得到高粘连强度防水卷材组合物。
对比例1
(1)将100份通用乙丙橡胶，1.5份硫磺，0.5份二硫化四甲基秋兰姆，2.5份炭黑N330及适量增塑剂，加入到密炼机中于80℃下密炼25min排料；将密炼好的预硫化橡胶母料在开炼机或多辊压延机上压片，形成预硫化乙丙橡胶胶片，压片温度为45℃，胶片厚度为5.0mm；
(2)采用涂刷工艺，将高粘连液体丁腈橡胶均匀的涂覆在聚丙烯纤维布的两侧，形成具有高粘连性的防水卷材基础纤维布；
(3)分别将两片预硫化乙丙橡胶胶片密实贴附在防水卷材基础纤维布上下表面，通过多辊压延机将上述混合胶片压延、压实，形成预硫化高粘连强度防水卷材组合物片材，胶片厚度为5.0mm；
(4)通过鼓式硫化箱硫化交联上述预硫化高粘连强度防水卷材组合物片材，硫化温度为175℃，硫化时间为30min，经过硫化交联工艺后，得到对比防水卷材组合物。
对比例2
(1)将100苯乙烯-丁二烯-苯乙烯共聚物，1.5份过氧化二异丙苯，3.5份炭黑N330，5份纳米二氧化硅及适量增塑剂，加入到密炼机中于80℃下密炼25min排料；将密炼好的预硫化橡胶母料在开炼机或多辊压延机上压片，形成预硫化乙烯-丁二烯-苯乙烯共聚物胶片，压片温度为45℃，胶片厚度为5.0mm；
(2)采用涂刷工艺，将高粘连液体丁腈橡胶均匀的涂覆在聚丙烯纤维布的两侧，形成具有高粘连性的防水卷材基础纤维布；
(3)分别将两片预硫化乙烯-丁二烯-苯乙烯共聚物胶片密实贴附在防水卷材基础纤维布上下表面，通过多辊压延机将上述混合胶片压延、压实，形成预硫化高粘连强度防水卷材组合物片材，胶片厚度为5.0mm；
(4)通过鼓式硫化箱硫化交联上述预硫化高粘连强度防水卷材组合物片材，硫化温度为175℃，硫化时间为30min，经过硫化交联工艺后，得到对比防水卷材组合物。
性能测试：
1、测试方法和要求
Figure BDA0003084812450000111
Figure BDA0003084812450000121
2、测试结果
Figure BDA0003084812450000122
由上表可以看出，实施例1-实施例5制备的防水卷材组合物在密度、硬度、断裂伸长率、拉伸强度、剥离强度和防水性上均明显优于对比例1和对比例2制备的防水卷材组合物。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等，均应包含在本发明的保护范围之内。

Claims (9)

1.一种高粘连强度防水卷材组合物，其特征在于，包括：高饱和疏水橡胶、极性官能团橡胶、高黏结性功能材料、高强度纤维布基层、补强剂、硫化剂、增塑剂；
所述高饱和疏水橡胶为分子主链为线型且主链不含-C＝C-双键的高饱和疏水性橡胶、弹性体；
所述极性官能团橡胶为分子链含有极性官能团且具有线型结构的橡胶、弹性体；
所述高黏结性功能材料为具有极性或非极性基团的液体橡胶或反应性液体低分子化合物。
2.根据权利要求1所述的高粘连强度防水卷材组合物，其特征在于，所述高饱和疏水橡胶为三元乙丙橡胶、氢化天然橡胶、氢化丁苯橡胶、氢化苯乙烯-丁二烯-苯乙烯嵌段共聚物、氢化苯乙烯-异戊二烯-苯乙烯嵌段共聚物、丁基橡胶、乙烯-辛烯共聚物、无规共聚聚丙烯中的一种。
3.根据权利要求1所述的高粘连强度防水卷材组合物，其特征在于，所述极性官能团橡胶为氢化丁腈橡胶、氯丁橡胶、氯磺化聚乙烯、氯醚橡胶、聚氨酯橡胶、氯化聚乙烯、环氧化天然橡胶、软质聚氯乙烯中一种。
4.根据权利要求1所述的高粘连强度防水卷材组合物，所述高黏结性功能材料为液体丁腈橡胶、端羧基液体丁腈橡胶、端羟基液体聚丁二烯橡胶、二苯基甲烷二异氰酸酯中的一种。
5.根据权利要求1所述的高粘连强度防水卷材组合物，所述高强度纤维布基层为玻璃纤维布、碳纤维布、尼龙纤维布、高分子量聚乙烯纤维布、聚丙烯纤维布、聚甲醛纤维布中一种。
6.根据权利要求1所述的高粘连强度防水卷材组合物，所述补强剂为炭黑、白炭黑、纳米碳酸钙、纳米滑石粉、纳米二氧化硅、纳米硫酸钙、钛酸钾晶须中的一种或多种；
所述硫化剂为硫磺、二硫化四甲基秋兰姆、过氧化二异丙苯、三烯丙基异三聚氰酸酯、二苯基甲烷二异氰酸酯、马来酸酐接枝聚丙烯中的一种或多种；
所述增塑剂为氯化石蜡、领苯二甲酸二丁酯、邻苯二甲酸二辛脂、环氧大豆油、己二酸二辛脂、磷酸三甲苯酯中的一种或多种。
7.根据权利要求1-6任一所述的高粘连强度防水卷材组合物的制备方法，其特征在于，包括以下步骤：
预硫化防水卷材上层橡胶组合物片材的制备：将高饱和疏水橡胶、硫化剂、补强剂和增塑剂在密炼机中密炼均匀得到预硫化防水卷材上层橡胶组合物母料，密炼温度为80～100℃，将预硫化防水卷材上层橡胶组合物母料通过开炼机或多辊压延机辊压成片得到预硫化防水卷材上层橡胶组合物片材，辊压温度为40～60℃，片材厚度为0.5～5.0mm；
预硫化防水卷材下层橡胶组合物片材的制备：将极性官能团橡胶，硫化剂、补强剂和增塑剂在密炼机中密炼均匀得到预硫化防水卷材下层橡胶组合物母料，密炼温度为80～120℃，将预硫化防水卷材下层橡胶组合物母料通过开炼机或多辊压延机辊压成片得到预硫化防水卷材上层橡胶组合物片材，辊压温度为40～60℃，片材厚度为0.5～5.0mm之间；
防水卷材基础纤维布的制备：将高黏结性功能材料溶于溶剂中搅拌均匀形成功能化粘连胶液，溶剂为甲苯、环烷油、二甲苯中的一种，使功能化粘连胶液附着在高强度纤维布基层的表面得到防水卷材基础纤维布；
预硫化防水卷材组合物片材的制备：将预硫化防水卷材上层橡胶组合物片材、防水卷材基础纤维布及预硫化防水卷材下层橡胶组合物片材经过辊压贴合加工成预硫化防水卷材组合物片材，片材厚度为0.5～5.0mm；
高粘连强度防水卷材组合物的制备：将预硫化防水卷材组合物片材放入硫化箱交联熟化，硫化箱的硫化温度为140～200℃，硫化时间为30～60min，制备出高粘连强度防水卷材组合物。
8.根据权利要求7所述的高粘连强度防水卷材组合物，所述防水卷材基础纤维布的制备采用浸渍的方法。
9.根据权利要求7所述的高粘连强度防水卷材组合物，所述防水卷材基础纤维布的制备采用涂覆的方法。
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