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CN113308760A - Electromagnetic radiation prevention self-cleaning multifunctional fabric and preparation method thereof - Google Patents

Electromagnetic radiation prevention self-cleaning multifunctional fabric and preparation method thereof Download PDF

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Publication number
CN113308760A
CN113308760A CN202110625843.0A CN202110625843A CN113308760A CN 113308760 A CN113308760 A CN 113308760A CN 202110625843 A CN202110625843 A CN 202110625843A CN 113308760 A CN113308760 A CN 113308760A
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China
Prior art keywords
parts
electromagnetic radiation
fabric
preparation
multifunctional fabric
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Pending
Application number
CN202110625843.0A
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Chinese (zh)
Inventor
吴永慧
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Jiangsu Xinshijia Home Textile High Tech Co ltd
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Jiangsu Xinshijia Home Textile High Tech Co ltd
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Priority to CN202110625843.0A priority Critical patent/CN113308760A/en
Publication of CN113308760A publication Critical patent/CN113308760A/en
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/106Radiation shielding agents, e.g. absorbing, reflecting agents
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses an anti-electromagnetic radiation self-cleaning multifunctional fabric and a preparation method thereof, wherein the anti-electromagnetic radiation self-cleaning multifunctional fabric comprises the following raw materials: the antibacterial fabric comprises bamboo charcoal fibers, graphene-based carbon nanofibers, nano-silver antibacterial master batches, silk fibers, methyl cellulose, chitosan, a dispersing agent, a coupling agent, a thickening agent and a compatilizer, wherein the dispersing agent is one or more of fatty alcohol-polyoxyethylene ether, alkylphenol ethoxylates, fatty acid-polyoxyethylene ether or glyceryl stearate, the coupling agent is a silane coupling agent, and the compatilizer is an epoxy compatilizer. The invention adopts the specially-made radiation-proof fiber, endows the fabric with excellent antibacterial and radiation-proof performance, and has the advantages of reasonable component design, low preparation cost and good economic benefit.

Description

Electromagnetic radiation prevention self-cleaning multifunctional fabric and preparation method thereof
Technical Field
The invention relates to the technical field of fabric preparation, in particular to an anti-electromagnetic radiation self-cleaning multifunctional fabric and a preparation method thereof.
Background
The rapid development of modern high-tech products and electrical equipment brings convenience, high efficiency and joy to the life and work of people and brings a lot of harm to people, a new invisible and untouchable pollution source attracts the attention of all over the world, which is just the electromagnetic radiation called as invisible killer by people and becomes the fourth pollution source which affects the health of people after water pollution, air pollution and noise pollution. Electromagnetic radiation affects the micro-magnetic field balance of internal tissues of a human body mainly through a magnetic field, and further affects the health of the human body. The energy derived from the electromagnetic radiation mainly depends on the frequency of the electromagnetic radiation source, and generally, the higher the frequency value is, the larger the generated energy is, and the degree of injury to human body is increased. Therefore, the clothes with the function of preventing electromagnetic radiation has become one of the textiles in which people seek healthy life in the present society, and is more and more paid more attention by people with the development of the society.
At present, four common methods for improving the electromagnetic wave shielding efficiency of the fabric are mainly used, and the methods respectively adopt a spraying process, a film coating process, a metal fiber and pure cotton fiber blending process and nano silver fibers as main raw materials. The radiation-proof fabric has many technical problems to be broken through, the diversification of the functional garment is not like common garments, the positioning of products is well selected, the fabric selection and the style design are carried out aiming at specific target groups, and the radiation-proof garment also needs the support of some product technical layers. At present, many radiation-proof clothes can only be worn as an outer coat under normal conditions and cannot be worn close to the skin, because sweat contains salt which is in direct contact with metal fibers and is easy to generate chemical reaction, the metal fibers are corroded, the radiation-proof effect is damaged, and the fabric is rough in hand feeling and is not suitable for underwear; the metal ion type fabric is often washed or rubbed frequently, the shielding effect is weakened, and therefore the metal ion type fabric cannot be washed frequently; when the anti-radiation storage box is stored, the anti-radiation storage box can only be hung or horizontally placed, and cannot be folded and pressed repeatedly, otherwise, the anti-radiation effect is weakened. Therefore, the development of novel anti-radiation fabrics and the improvement of the anti-radiation effect are the main direction of the development of anti-radiation fabrics and the problems to be solved urgently.
Disclosure of Invention
The invention aims to provide an anti-electromagnetic radiation self-cleaning multifunctional fabric and a preparation method thereof, so as to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: an anti-electromagnetic radiation self-cleaning multifunctional fabric comprises the following raw materials in parts by weight: 25-30 parts of bamboo charcoal fiber, 5-10 parts of graphene-based carbon nanofiber, 20-30 parts of nano-silver antibacterial master batch, 15-20 parts of silk fiber, 10-20 parts of methyl cellulose, 5-10 parts of chitosan, 4-6 parts of dispersing agent, 5-10 parts of coupling agent, 5-10 parts of thickening agent and 2-8 parts of compatilizer.
Preferably, the dispersing agent is one or more of fatty alcohol-polyoxyethylene ether, alkylphenol ethoxylate, fatty acid-polyoxyethylene ether or glyceryl stearate.
Preferably, the coupling agent is a silane coupling agent.
Preferably, the compatibilizer is an epoxy-type compatibilizer.
A preparation method of an anti-electromagnetic radiation self-cleaning multifunctional fabric comprises the following steps:
step 1, uniformly mixing bamboo charcoal fibers, graphene-based carbon nanofibers and silk fibers to form mixed fibers;
step 2, adding the nano-silver antibacterial master batch, methyl cellulose, chitosan, a dispersing agent, a coupling agent, a thickening agent, a water-soluble adhesive and a compatilizer into the mixed fiber, and stirring and blending to form a mixed solution;
step 3, adding the mixed solution into a screw extruder for melt extrusion, and conveying the molten melt into a spinning box to obtain spinning;
step 4, cooling and solidifying the spun yarn into filaments, and then boiling and drying the filaments to obtain radiation-proof fibers;
and 5, weaving the radiation-proof fibers into a radiation-proof fabric.
Preferably, in step 3, the spinning temperature in the spinning box is 280-300 ℃, and the spinning speed is 2800-3400 m/min.
Preferably, in step 4, cooling air is adopted for cooling, wherein the temperature of the cooling air is 18-20 ℃, and the humidity of the cooling air is 58-60%.
Preferably, in step 4, the boiling time is 15-20 min.
Compared with the prior art, the invention has the beneficial effects that:
the invention adopts the specially-made radiation-proof fiber, endows the fabric with excellent antibacterial and radiation-proof performance, and has reasonable component design of the antibacterial and radiation-proof fiber, low preparation cost and good economic benefit; meanwhile, the chitin fiber is added, so that the softness and comfort of the fabric are further enhanced by utilizing the good flexibility and antibacterial performance of the chitin fiber, and the fabric has good antibacterial performance; meanwhile, the functions of the fabric can be improved by adding the quantitative dispersing agent, the coupling agent, the thickening agent and the compatilizer, so that the performance of the original fiber fabric is improved, the fabric is softer and more durable, the radiation-proof performance of the radiation-proof fabric can be enhanced, and the radiation-proof performance and the ultraviolet-proof performance of the fabric are effectively improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a technical scheme that: an anti-electromagnetic radiation self-cleaning multifunctional fabric comprises the following raw materials: the antibacterial fabric comprises bamboo charcoal fibers, graphene-based carbon nanofibers, nano-silver antibacterial master batches, silk fibers, methyl cellulose, chitosan, a dispersing agent, a coupling agent, a thickening agent and a compatilizer, wherein the dispersing agent is one or more of fatty alcohol-polyoxyethylene ether, alkylphenol ethoxylates, fatty acid-polyoxyethylene ether or glyceryl stearate, the coupling agent is a silane coupling agent, and the compatilizer is an epoxy compatilizer.
Example 1:
an anti-electromagnetic radiation self-cleaning multifunctional fabric comprises the following raw materials in parts by weight: 25 parts of bamboo charcoal fiber, 5 parts of graphene-based carbon nanofiber, 20 parts of nano-silver antibacterial master batch, 15 parts of silk fiber, 10 parts of methyl cellulose, 5 parts of chitosan, 4 parts of dispersing agent, 5 parts of coupling agent, 5 parts of thickening agent and 2 parts of compatilizer.
A preparation method of an anti-electromagnetic radiation self-cleaning multifunctional fabric comprises the following steps:
step 1, uniformly mixing bamboo charcoal fibers, graphene-based carbon nanofibers and silk fibers to form mixed fibers;
step 2, adding the nano-silver antibacterial master batch, methyl cellulose, chitosan, a dispersing agent, a coupling agent, a thickening agent, a water-soluble adhesive and a compatilizer into the mixed fiber, and stirring and blending to form a mixed solution;
step 3, adding the mixed solution into a screw extruder for melt extrusion, and conveying the molten melt into a spinning box to obtain spinning, wherein the spinning temperature in the spinning box is 280 ℃, and the spinning speed is 2800 m/min;
step 4, cooling and solidifying the spun yarn into filaments, boiling and drying the filaments, and cooling the filaments by cooling air, wherein the temperature of the cooling air is 18 ℃, the humidity of the cooling air is 58%, and the boiling time is 15min to obtain the radiation-proof fiber;
and 5, weaving the radiation-proof fibers into a radiation-proof fabric.
Example 2:
an anti-electromagnetic radiation self-cleaning multifunctional fabric comprises the following raw materials in parts by weight: 25-30 parts of bamboo charcoal fiber, 8 parts of graphene-based carbon nanofiber, 25 parts of nano-silver antibacterial master batch, 15 parts of silk fiber, 15 parts of methyl cellulose, 8 parts of chitosan, 5 parts of dispersing agent, 8 parts of coupling agent, 8 parts of thickening agent and 6 parts of compatilizer.
A preparation method of an anti-electromagnetic radiation self-cleaning multifunctional fabric comprises the following steps:
step 1, uniformly mixing bamboo charcoal fibers, graphene-based carbon nanofibers and silk fibers to form mixed fibers;
step 2, adding the nano-silver antibacterial master batch, methyl cellulose, chitosan, a dispersing agent, a coupling agent, a thickening agent, a water-soluble adhesive and a compatilizer into the mixed fiber, and stirring and blending to form a mixed solution;
step 3, adding the mixed solution into a screw extruder for melt extrusion, and conveying the molten melt into a spinning box to obtain spinning, wherein the spinning temperature in the spinning box is 290 ℃, and the spinning speed is 3000 m/min;
step 4, cooling and solidifying the spun yarn into filaments, boiling and drying the filaments, and cooling the filaments by cooling air, wherein the temperature of the cooling air is 19 ℃, the humidity of the cooling air is 59%, and the boiling time is 18min to obtain radiation-proof fibers;
and 5, weaving the radiation-proof fibers into a radiation-proof fabric.
Example 3:
an anti-electromagnetic radiation self-cleaning multifunctional fabric comprises the following raw materials in parts by weight: 30 parts of bamboo charcoal fiber, 10 parts of graphene-based carbon nanofiber, 30 parts of nano-silver antibacterial master batch, 20 parts of silk fiber, 20 parts of methyl cellulose, 10 parts of chitosan, 6 parts of dispersing agent, 10 parts of coupling agent, 10 parts of thickening agent and 8 parts of compatilizer.
A preparation method of an anti-electromagnetic radiation self-cleaning multifunctional fabric comprises the following steps:
step 1, uniformly mixing bamboo charcoal fibers, graphene-based carbon nanofibers and silk fibers to form mixed fibers;
step 2, adding the nano-silver antibacterial master batch, methyl cellulose, chitosan, a dispersing agent, a coupling agent, a thickening agent, a water-soluble adhesive and a compatilizer into the mixed fiber, and stirring and blending to form a mixed solution;
step 3, adding the mixed solution into a screw extruder for melt extrusion, and conveying the molten melt into a spinning box to obtain spinning, wherein the spinning temperature in the spinning box is 300 ℃, and the spinning speed is 3400 m/min;
step 4, cooling and solidifying the spun yarn into filaments, boiling and drying the filaments, and cooling the filaments by cooling air, wherein the temperature of the cooling air is 20 ℃, the humidity of the cooling air is 60%, and the boiling time is 20min to obtain radiation-proof fibers;
and 5, weaving the radiation-proof fibers into a radiation-proof fabric.
The invention adopts the specially-made radiation-proof fiber, endows the fabric with excellent antibacterial and radiation-proof performance, and has reasonable component design of the antibacterial and radiation-proof fiber, low preparation cost and good economic benefit; meanwhile, the chitin fiber is added, so that the softness and comfort of the fabric are further enhanced by utilizing the good flexibility and antibacterial performance of the chitin fiber, and the fabric has good antibacterial performance; meanwhile, the functions of the fabric can be improved by adding the quantitative dispersing agent, the coupling agent, the thickening agent and the compatilizer, so that the performance of the original fiber fabric is improved, the fabric is softer and more durable, the radiation-proof performance of the radiation-proof fabric can be enhanced, and the radiation-proof performance and the ultraviolet-proof performance of the fabric are effectively improved.
Application method
A preparation method of an anti-electromagnetic radiation self-cleaning multifunctional fabric comprises the following steps:
step 1, uniformly mixing bamboo charcoal fibers, graphene-based carbon nanofibers and silk fibers to form mixed fibers;
step 2, adding the nano-silver antibacterial master batch, methyl cellulose, chitosan, a dispersing agent, a coupling agent, a thickening agent, a water-soluble adhesive and a compatilizer into the mixed fiber, and stirring and blending to form a mixed solution;
step 3, adding the mixed solution into a screw extruder for melt extrusion, and conveying the molten melt into a spinning box to obtain spinning;
step 4, cooling and solidifying the spun yarn into filaments, and then boiling and drying the filaments to obtain radiation-proof fibers;
and 5, weaving the radiation-proof fibers into a radiation-proof fabric.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (8)

1. The utility model provides an anti-electromagnetic radiation self-purification formula multifunctional fabric which characterized in that: the feed comprises the following raw materials in parts by weight: 25-30 parts of bamboo charcoal fiber, 5-10 parts of graphene-based carbon nanofiber, 20-30 parts of nano-silver antibacterial master batch, 15-20 parts of silk fiber, 10-20 parts of methyl cellulose, 5-10 parts of chitosan, 4-6 parts of dispersing agent, 5-10 parts of coupling agent, 5-10 parts of thickening agent and 2-8 parts of compatilizer.
2. The electromagnetic radiation preventing self-cleaning multifunctional fabric as claimed in claim 1, wherein: the dispersing agent is one or more of fatty alcohol-polyoxyethylene ether, alkylphenol ethoxylates, fatty acid-polyoxyethylene ether or glyceryl stearate.
3. The electromagnetic radiation preventing self-cleaning multifunctional fabric as claimed in claim 1, wherein: the coupling agent is a silane coupling agent.
4. The electromagnetic radiation preventing self-cleaning multifunctional fabric as claimed in claim 1, wherein: the compatilizer is an epoxy compatilizer.
5. The preparation method of the electromagnetic radiation preventing self-cleaning multifunctional fabric, which adopts the electromagnetic radiation preventing self-cleaning multifunctional fabric of claims 1-4, is characterized by comprising the following steps:
step 1, uniformly mixing bamboo charcoal fibers, graphene-based carbon nanofibers and silk fibers to form mixed fibers;
step 2, adding the nano-silver antibacterial master batch, methyl cellulose, chitosan, a dispersing agent, a coupling agent, a thickening agent, a water-soluble adhesive and a compatilizer into the mixed fiber, and stirring and blending to form a mixed solution;
step 3, adding the mixed solution into a screw extruder for melt extrusion, and conveying the molten melt into a spinning box to obtain spinning;
step 4, cooling and solidifying the spun yarn into filaments, and then boiling and drying the filaments to obtain radiation-proof fibers;
and 5, weaving the radiation-proof fibers into a radiation-proof fabric.
6. The preparation method of the electromagnetic radiation preventing self-cleaning multifunctional fabric as claimed in claim 5, wherein the preparation method comprises the following steps: in step 3, the spinning temperature in the spinning box is 280-300 ℃, and the spinning speed is 2800-3400 m/min.
7. The preparation method of the electromagnetic radiation preventing self-cleaning multifunctional fabric as claimed in claim 5, wherein the preparation method comprises the following steps: in the step 4, cooling air is adopted for cooling, the temperature of the cooling air is 18-20 ℃, and the humidity of the cooling air is 58-60%.
8. The preparation method of the electromagnetic radiation preventing self-cleaning multifunctional fabric as claimed in claim 5, wherein the preparation method comprises the following steps: in step 4, boiling time is 15-20 min.
CN202110625843.0A 2021-06-04 2021-06-04 Electromagnetic radiation prevention self-cleaning multifunctional fabric and preparation method thereof Pending CN113308760A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110625843.0A CN113308760A (en) 2021-06-04 2021-06-04 Electromagnetic radiation prevention self-cleaning multifunctional fabric and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110625843.0A CN113308760A (en) 2021-06-04 2021-06-04 Electromagnetic radiation prevention self-cleaning multifunctional fabric and preparation method thereof

Publications (1)

Publication Number Publication Date
CN113308760A true CN113308760A (en) 2021-08-27

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Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113882144A (en) * 2021-11-02 2022-01-04 广东鹏运实业有限公司 Anti-electromagnetic radiation fabric with surface coated with nano wave absorber and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113882144A (en) * 2021-11-02 2022-01-04 广东鹏运实业有限公司 Anti-electromagnetic radiation fabric with surface coated with nano wave absorber and preparation method thereof

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Application publication date: 20210827

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