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CN113265295A - Environment-friendly water-based gear broaching fluid with high lubrication and high cleaning rate - Google Patents

Environment-friendly water-based gear broaching fluid with high lubrication and high cleaning rate Download PDF

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Publication number
CN113265295A
CN113265295A CN202110588520.9A CN202110588520A CN113265295A CN 113265295 A CN113265295 A CN 113265295A CN 202110588520 A CN202110588520 A CN 202110588520A CN 113265295 A CN113265295 A CN 113265295A
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China
Prior art keywords
cleaning rate
environment
acid
friendly water
based gear
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Pending
Application number
CN202110588520.9A
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Chinese (zh)
Inventor
俞威
角川徹
常建忠
唐晓磊
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Shanghai Yushiro Chemical Industry Co Ltd
Qidong Yushiro Chemical Industry Co Ltd
Original Assignee
Shanghai Yushiro Chemical Industry Co Ltd
Qidong Yushiro Chemical Industry Co Ltd
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Priority to CN202110588520.9A priority Critical patent/CN113265295A/en
Publication of CN113265295A publication Critical patent/CN113265295A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/18—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/22—Acids obtained from polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046—Overbased sulfonic acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses an environment-friendly water-based gear broaching fluid with high lubrication and high cleaning rate, which consists of organic acid, organic amine, a corrosion inhibitor, a lubricating additive, a surfactant, base oil, water and a defoaming agent. The invention selects surfactant groups with excellent performance, such as ethylenediamine polyoxyethylene polyoxypropylene condensation compound, secondary alkanol polyoxyethylene polyoxypropylene block polyether and the like, and when the product is 5% of diluent, the cleaning rate of residues on the surface of a workpiece is more than or equal to 99.3%, and the cleaning rate is high.

Description

Environment-friendly water-based gear broaching fluid with high lubrication and high cleaning rate
Technical Field
The invention relates to a water-based gear broaching fluid.
Background
Broaching refers to cutting a very thin metal layer from a workpiece in sequence tooth by using a special broach so that the surface reaches higher dimensional accuracy and lower roughness. This is a highly efficient processing method.
Since the cutting speed of the broaching is low and the increase in cutting temperature is small, the relief angle is preferably small in consideration of the regrinding, but this makes it difficult for the broaching oil to penetrate, and makes it complicated in terms of the generation of the chips, the surface quality, and the machining accuracy, and therefore, it is very important to select an appropriate and high-performance broaching oil. For a long time, users have traditionally used oily broaching oils, which have the advantages: the preparation process is mature, the use history is long, the wear resistance, extreme pressure property and lubricity are good, and the product is not aged or deteriorated and can be used for a long time. But there are some outstanding drawbacks: firstly, the cooling performance is poor, the workpiece is easy to deform due to the heat generated by the accumulation during broaching, and the work error occurs; secondly, the broaching resistance is large, chips are not easy to remove, the surface of a workpiece is easy to scratch (the smoothness is affected) and the broach is easy to scrape (the service life is shortened); thirdly, the cleaning performance is poor, and the workpiece and the broach are easy to rust. The aqueous broaching solution which is marketed in the last decade not only overcomes the disadvantages, but also is easy to treat (environment-friendly) due to low resource consumption (low carbon) and low waste liquid, and is favored by users. However, the current commercial aqueous broaching fluids also have some problems to be solved: firstly, the lubricating property is poor, the cleaning rate is low, and the use requirements of the gear broaching processing technique which is continuously promoted by customers are difficult to meet; secondly, the formula contains toxic and harmful substances such as chlorine, phosphorus and the like, is poor in safety and sanitation quality, and cannot meet the increasingly concerned environment-friendly requirement of people. These drawbacks seriously affect and restrict the application of aqueous broaching fluids in the market, especially in the high-end market.
Disclosure of Invention
The invention aims to provide the environment-friendly water-based gear broaching fluid with good lubricating property, high cleaning rate, high product safety and sanitary quality, high lubricating and high cleaning rate.
The technical solution of the invention is as follows:
the utility model provides a high lubrication, high cleaning rate, environment-friendly aqueous gear broaching liquid which characterized by: the paint consists of the following components in percentage by weight:
10 to 25 percent of organic acid
10 to 15 percent of organic amine
0.5 to 3 percent of corrosion inhibitor
5 to 10 percent of lubricating additive
7 to 15 percent of surfactant
25 to 35 percent of base oil
5 to 20 percent of water
0.3 to 2 percent of defoaming agent.
The organic acid is lauric acid, C10~C12One or more of straight chain dibasic acid, sulfamic acid compound, tall oil fatty acid, polymerized ricinoleic acid, erucic acid and vegetable oleic acid.
The organic amine is one or more of triisopropanolamine, monoisopropanolamine and diethylaminoethanol.
The lubricant additive is one or more of high base number synthetic calcium sulfonate (base number 300mgKOH/g, 400mgKOH/g, 500 mgKOH/g).
The corrosion inhibitor is one or more of benzotriazole and 2-mercaptobenzothiazole.
The surfactant is one or more of ethylenediamine polyoxyethylene polyoxypropylene condensation compound, secondary alkanol polyoxyethylene polyoxypropylene block polyether and castor oil polyoxyethylene ether.
The defoaming agent is one or more of emulsified silicone oil and methyl silicone oil.
The product of the invention selects a special lubricant calcium petroleum sulfonate and a long-chain organic acid group. Maximum no-seizing load P at 5% dilution of the productB1972N, sintering load PD>7848N, excellent lubricating property.
The invention selects surfactant groups with excellent performance, such as ethylenediamine polyoxyethylene polyoxypropylene condensation compound, secondary alkanol polyoxyethylene polyoxypropylene block polyether and the like. When the product is diluted by 5 percent, the cleaning rate of residues on the surface of the workpiece is more than or equal to 99.3 percent, and the cleaning rate is high.
The raw materials of the invention do not use poisonous and harmful substances (selecting the design formula of the replaceable substances with excellent performance and friendly to human and environment) which endanger the environment and human body such as chlorine, phosphorus and the like, and the product has high safety and sanitation quality (the product is acute)Oral toxicity LD50>5000mg/kg, acute inhalation toxicity LC50>5000mg/m3The respiratory tract mucosa stimulation intensity reaches 0 grade).
The present invention will be further described with reference to the following examples.
Detailed Description
Example 1:
mixing and stirring certain weight components under certain conditions to obtain a product:
5 percent of lauric acid
0.5 percent of benzotriazole
8 percent of isopropanolamine
Diethylaminoethanol 6%
Polymerized ricinoleic acid 6%
Tall oil fatty acid 4%
Vegetable oil acid 7%
8 percent of castor oil polyoxyethylene ether
High base number synthetic calcium sulfonate 7%
Ethylenediamine polyoxyethylene polyoxypropylene condensation compound 2.5%
30.5 percent of base oil
0.5 percent of emulsified silicone oil
15 percent of water
Maximum no-seizing load P at 5% dilution of the productB1972N, sintering load PDIs 8000N; the cleaning rate of the residues on the surface of the workpiece is 99.7%.
Example 2:
mixing and stirring certain weight components under certain conditions to obtain a product:
5 percent of lauric acid
0.5 percent of benzotriazole
Triisopropanolamine 7%
Diethylaminoethanol 7%
Polymerized ricinoleic acid 6%
Tall oil fatty acid 4%
Erucic acid 7%
8 percent of castor oil polyoxyethylene ether
High base number synthetic calcium sulfonate 7%
Ethylenediamine polyoxyethylene polyoxypropylene condensation compound 2.5%
30.5 percent of base oil
0.5 percent of emulsified silicone oil
15 percent of water
Maximum no-seizing load P at 5% dilution of the productB1776N, sintering load PD6082N; the cleaning rate of the residues on the surface of the workpiece is 99.4%.
Example 3:
mixing and stirring certain weight components under certain conditions to obtain a product:
5 percent of lauric acid
0.5 percent of benzotriazole
8 percent of isopropanolamine
Diethylaminoethanol 6%
Polymerized ricinoleic acid 6%
5 percent of sulfamic acid compound
Vegetable oil acid 6%
8 percent of castor oil polyoxyethylene ether
High base number synthetic calcium sulfonate 7%
Secondary alkanol polyoxyethylene polyoxypropylene block polyether 2.5%
30.5 percent of base oil
0.5 percent of emulsified silicone oil
15 percent of water
Maximum no-seizing load P at 5% dilution of the productB1874N, sintering load PD6082N; the cleaning rate of the residues on the surface of the workpiece is 99.3 percent.
Example 1 was finally selected as the final formulation based on product lubricity and wash rate results.

Claims (7)

1.一种高润滑、高清洗率、环保型水性齿轮拉削液，其特征是：由下列重量百分比的成分组成：1. a high lubricating, high cleaning rate, environment-friendly water-based gear broaching fluid is characterized in that: be made up of the following composition by weight: 有机酸 10-25%Organic acid 10-25% 有机胺 10-15%Organic amine 10-15% 缓蚀剂 0.5-3%Corrosion inhibitor 0.5-3% 润滑添加剂 5-10%Lubricant additive 5-10% 表面活性剂 7-15%Surfactant 7-15% 基础油 25-35%Base oil 25-35% 水 5-20%Water 5-20% 消泡剂 0.3-2%。Defoamer 0.3-2%. 2.根据权利要求1所述的高润滑、高清洗率、环保型水性齿轮拉削液，其特征是：有机酸是月桂二酸、C10~C12直链二元酸、氨基磺酸化合物、妥儿油脂肪酸、聚合蓖麻油酸、芥酸、植物油酸中的一种或几种。2. high lubricating, high cleaning rate, environment-friendly water-based gear broaching fluid according to claim 1, is characterized in that: organic acid is lauric acid, C 10 ～C 12 linear dibasic acid, sulfamic acid compound , one or more of tall oil fatty acid, polymerized ricinoleic acid, erucic acid and vegetable oleic acid. 3.根据权利要求1所述的高润滑、高清洗率、环保型水性齿轮拉削液，其特征是：有机胺是三异丙醇胺、一异丙醇胺、二乙氨基乙醇中的一种或几种。3. high lubricating, high cleaning rate, environment-friendly water-based gear broaching fluid according to claim 1, is characterized in that: organic amine is one in triisopropanolamine, one isopropanolamine, diethylaminoethanol species or several. 4.根据权利要求1所述的高润滑、高清洗率、环保型水性齿轮拉削液，其特征是：润滑添加剂是高碱值合成磺酸钙（碱值300mgKOH/g、400mgKOH/g、500mgKOH/g）中的一种或几种。4. high lubricating, high cleaning rate, environment-friendly water-based gear broaching fluid according to claim 1, is characterized in that: the lubricating additive is high base number synthetic calcium sulfonate (base number 300mgKOH/g, 400mgKOH/g, 500mgKOH /g) one or more of them. 5.根据权利要求1所述的高润滑、高清洗率、环保型水性齿轮拉削液，其特征是：缓蚀剂是苯并三氮唑、2-巯基苯并噻唑中的一种或几种。5. high lubricating, high cleaning rate, environment-friendly water-based gear broaching fluid according to claim 1, is characterized in that: corrosion inhibitor is one or more in benzotriazole, 2-mercaptobenzothiazole kind. 6.根据权利要求1所述的高润滑、高清洗率、环保型水性齿轮拉削液，其特征是：表面活性剂是乙二胺聚氧乙烯聚氧丙烯缩合物、仲烷醇聚氧乙烯聚氧丙烯嵌段聚醚、蓖麻油聚氧乙烯醚中的一种或几种。6. high lubricating, high cleaning rate, environment-friendly water-based gear broaching fluid according to claim 1, is characterized in that: surfactant is ethylenediamine polyoxyethylene polyoxypropylene condensate, secondary alkanol polyoxyethylene One or more of polyoxypropylene block polyether and castor oil polyoxyethylene ether. 7.根据权利要求1所述的高润滑、高清洗率、环保型水性齿轮拉削液，其特征是：消泡剂是乳化硅油、甲基硅油的一种或几种。7. The high lubricating, high cleaning rate, environment-friendly water-based gear broaching fluid according to claim 1, wherein the defoamer is one or more of emulsified silicone oil and methyl silicone oil.
CN202110588520.9A 2021-05-28 2021-05-28 Environment-friendly water-based gear broaching fluid with high lubrication and high cleaning rate Pending CN113265295A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116751623A (en) * 2023-06-30 2023-09-15 合肥工业大学智能制造技术研究院 High-performance environment-friendly microemulsion cutting fluid

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4171558A (en) * 1976-09-20 1979-10-23 Idemitsu Kosan Co., Ltd. Cutting oil composition for processing cemented carbide skiving hob
US20080280791A1 (en) * 2007-05-01 2008-11-13 Chip Hewette Lubricating Oil Composition for Marine Applications
CN101560433A (en) * 2009-05-11 2009-10-21 启东尤希路化学工业有限公司 Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution
CN102660361A (en) * 2012-05-09 2012-09-12 上海金兆节能科技有限公司 Trace lubricating oil for exposed gear and preparation method of trace lubricating oil
CN102703174A (en) * 2012-06-12 2012-10-03 重庆德蒙特科技发展有限公司 Oil-soluble gravity cutting oil
CN104087404A (en) * 2014-07-29 2014-10-08 马思特（上海）化学有限公司 High-cleanliness economical microemulsion metal cutting fluid
CN111732994A (en) * 2020-07-21 2020-10-02 南京正明观新材料有限公司 Water-based metal machining cutting fluid for steel and aluminum and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4171558A (en) * 1976-09-20 1979-10-23 Idemitsu Kosan Co., Ltd. Cutting oil composition for processing cemented carbide skiving hob
US20080280791A1 (en) * 2007-05-01 2008-11-13 Chip Hewette Lubricating Oil Composition for Marine Applications
CN101560433A (en) * 2009-05-11 2009-10-21 启东尤希路化学工业有限公司 Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution
CN102660361A (en) * 2012-05-09 2012-09-12 上海金兆节能科技有限公司 Trace lubricating oil for exposed gear and preparation method of trace lubricating oil
CN102703174A (en) * 2012-06-12 2012-10-03 重庆德蒙特科技发展有限公司 Oil-soluble gravity cutting oil
CN104087404A (en) * 2014-07-29 2014-10-08 马思特（上海）化学有限公司 High-cleanliness economical microemulsion metal cutting fluid
CN111732994A (en) * 2020-07-21 2020-10-02 南京正明观新材料有限公司 Water-based metal machining cutting fluid for steel and aluminum and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116751623A (en) * 2023-06-30 2023-09-15 合肥工业大学智能制造技术研究院 High-performance environment-friendly microemulsion cutting fluid

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