CN113201318B - A kind of high temperature and high salt reinforced foam plugging agent and reservoir injection method thereof - Google Patents
A kind of high temperature and high salt reinforced foam plugging agent and reservoir injection method thereof Download PDFInfo
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Abstract
本发明属于石油开采的技术领域,具体的涉及一种耐高温高盐的强化泡沫堵剂及其油藏注入方法。该耐高温高盐的强化泡沫堵剂,主剂为木质素,交联剂为乌洛托品,起泡剂为HZ‑1型,强化剂为分子量在8~20万的甲基纤维素。所述强化泡沫堵剂能够改善地层的非均质性,提高波及系数以及洗油效率,从而能够提高驱油效果和采收率。
The invention belongs to the technical field of petroleum exploitation, and particularly relates to a high-temperature and high-salt-resistant reinforced foam plugging agent and a reservoir injection method thereof. The high-temperature and high-salt-resistant reinforced foam plugging agent comprises lignin as the main agent, urotropine as the cross-linking agent, HZ-1 type foaming agent, and methylcellulose with a molecular weight of 80,000 to 200,000 as the strengthening agent. The enhanced foam plugging agent can improve the heterogeneity of the formation, improve the sweep coefficient and the oil washing efficiency, so as to improve the oil displacement effect and the recovery factor.
Description
技术领域technical field
本发明属于石油开采的技术领域,具体的涉及一种耐高温高盐的强化泡沫堵剂及其油藏注入方法。The invention belongs to the technical field of petroleum exploitation, and particularly relates to a high-temperature and high-salt-resistant reinforced foam plugging agent and a reservoir injection method thereof.
背景技术Background technique
随着稠油开采力度的增大,注蒸汽热力采油技术应用越来越广泛。但是在开采过程中,由于地层的非均质性、流体流度的差异以及吞吐后期地层能量亏空等原因,导致在开采过程中容易出现边底水入侵和汽窜等问题。油井高含水的问题将会严重影响蒸汽吞吐效果,进而影响油井的开采效果。而对于一些深层的高温高盐油层,堵剂的使用会严重受到地层温度以及矿化度的影响,目前的堵剂大部分无法适应于高温环境中,因此亟需寻找一种堵剂在能够调整地层非均质性,有效预防水侵和汽窜等问题的同时,更重要地可以耐高温高盐以面对复杂的深层油藏。With the increase of heavy oil recovery, steam injection thermal oil recovery technology is more and more widely used. However, in the mining process, due to the heterogeneity of the formation, the difference in fluid mobility, and the formation energy deficit in the late huff and puff, problems such as edge and bottom water intrusion and steam channeling are prone to occur during the mining process. The problem of high water cut in oil wells will seriously affect the effect of steam huff and puff, thereby affecting the production effect of oil wells. For some deep high-temperature and high-salt oil layers, the use of plugging agents will be seriously affected by formation temperature and salinity. Most of the current plugging agents cannot be adapted to high temperature environments. Therefore, it is urgent to find a plugging agent that can adjust Formation heterogeneity can effectively prevent water intrusion and steam channeling, and more importantly, it can withstand high temperature and high salt to face complex deep reservoirs.
现有堵水技术主要是聚合物冻胶堵水技术。如公开号CN111892918A公开了一种冻胶类堵水调剖剂,主要组成为聚丙烯酰胺、乳化剂、缓凝剂等。该发明中所形成的冻胶耐温75℃,不能适用于更高的油层环境中。The existing water plugging technology is mainly polymer jelly water plugging technology. For example, publication number CN111892918A discloses a jelly-type water blocking and profile control agent, which is mainly composed of polyacrylamide, emulsifier, retarder and the like. The jelly formed in the invention has a temperature resistance of 75°C and cannot be applied to a higher oil layer environment.
文献《耐温耐盐冻胶调剖堵水剂的制备及性能研究》中冻胶主剂为聚丙烯酰胺,该冻胶体系耐温90℃,耐盐只能达到5×104mg/L。The main ingredient of the jelly is polyacrylamide, the temperature resistance of the jelly system is 90℃, and the salt resistance can only reach 5×10 4 mg/L .
综上所述,现有堵剂虽然能够对一些复杂油层起到很好的调剖作用,提高稠油开采的效率,但仍存在以下缺陷:(1)对于深层高温储层,由于其油层温度高、地层水矿化度高等复杂的油层条件,导致普通堵剂在应用时,存在着堵剂耐温耐盐能力弱、稳定性差、封堵强度低以及有效期短等问题;(2)普通聚合物冻胶普遍存在韧性差、易破碎和有效作用时间短等问题,由于韧性差,会导致冻胶体系的稳定性差,封堵效果差,提采效率低等问题;(3)对于蒸汽驱以及蒸汽吞吐井,由于地层的非均质性,会在高渗层位形成汽窜的问题,导致增产措施无效,因此堵剂的性质最好是“堵高不堵低”。然而常规堵剂在应用时,虽然会对高渗地层有一定的封堵作用,但是堵剂的注入也会涉及到低渗层,进而影响原油的采收程度。In summary, although the existing plugging agents can play a good role in profile control for some complex oil layers and improve the efficiency of heavy oil production, they still have the following defects: (1) For deep high-temperature reservoirs, due to the temperature of the oil layer The complex reservoir conditions with high formation water salinity and high formation water lead to problems such as weak temperature and salt resistance, poor stability, low plugging strength and short validity period of common plugging agents when they are applied; (2) common polymerization Physical jelly generally has problems such as poor toughness, easy breakage and short effective time. Due to poor toughness, it will lead to poor stability of the jelly system, poor plugging effect, and low recovery efficiency; (3) For steam flooding and For steam huff and puff wells, due to the heterogeneity of the formation, the problem of steam channeling will be formed in the high-permeability layer, resulting in ineffective production stimulation measures. However, when the conventional plugging agent is applied, although it will have a certain plugging effect on the high-permeability formation, the injection of the plugging agent will also involve the low-permeability layer, thereby affecting the recovery degree of crude oil.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于针对上述存在的缺陷而提供一种耐高温高盐的强化泡沫堵剂及其油藏注入方法,该强化泡沫堵剂耐高温,耐矿化度;成胶稳定性高且封堵性能强,能够在注入到地层的过程中仅涉及高渗区域而不涉及低渗区域。The object of the present invention is to provide a high-temperature and high-salt-resistant reinforced foam plugging agent and a reservoir injection method for the above-mentioned defects. The reinforced foam plugging agent is resistant to high temperature and salinity; It has strong plugging performance and can only involve high-permeability regions and not low-permeability regions during injection into the formation.
本发明的技术方案为:一种耐高温高盐的强化泡沫堵剂,主剂为木质素,交联剂为乌洛托品,起泡剂为HZ-1型,强化剂为分子量在8~20万的甲基纤维素。The technical scheme of the invention is as follows: a high-temperature and high-salt-resistant strengthening foam plugging agent, the main agent is lignin, the cross-linking agent is urotropine, the foaming agent is HZ-1 type, and the strengthening agent is a molecular weight of 8-8 200,000 methylcellulose.
所述耐高温高盐的强化泡沫堵剂,按照质量百分比木质素为4.0~6.0%,乌洛托品为3.5~5.5%,甲基纤维素为0.3~0.6%,HZ-1型耐温起泡剂为0.5%,余量为水。The high-temperature and high-salt-resistant reinforced foam plugging agent contains 4.0-6.0% of lignin, 3.5-5.5% of urotropine, 0.3-0.6% of methyl cellulose, and HZ-1 type temperature-resistant The foaming agent is 0.5%, and the balance is water.
所述耐高温高盐的强化泡沫堵剂,按照质量百分比木质素为4.3%,乌洛托品为4%,甲基纤维素为0.35%,HZ-1型起泡剂为0.5%,余量为水。The high-temperature and high-salt reinforced foam plugging agent is 4.3% of lignin, 4% of urotropine, 0.35% of methyl cellulose, 0.5% of HZ-1 foaming agent, and the remainder according to the mass percentage. for water.
该强化泡沫堵剂适用于温度为175℃,矿化度为20×104mg/L的油藏;强化泡沫的起泡体积为500mL,半衰期为14.4min;所述强化泡沫堵剂在175℃条件下加热老化一个月,脱水率不高于9%。The reinforced foam plugging agent is suitable for oil reservoirs with a temperature of 175°C and a salinity of 20×10 4 mg/L; the foaming volume of the reinforced foam is 500mL, and the half-life is 14.4min; the reinforced foam plugging agent is heated at 175°C Heating and aging for one month under conditions, the dehydration rate is not higher than 9%.
该强化泡沫堵剂在80~175℃环境中形成冻胶的成胶时间为3~22h,其中在80℃环境中成胶时间为22h;在100℃环境中成胶时间为6.5h;在120℃环境中成胶时间为5h;在160℃环境中成胶时间为3h;在175℃环境中成胶2.5h。The gel-forming time of the reinforced foam plugging agent to form jelly in the environment of 80-175°C is 3-22h, of which the gel-forming time is 22h in the environment of 80°C; the gel-forming time is 6.5h in the environment of 100°C; The gel formation time is 5h in the ℃ environment; the gel formation time is 3h in the 160 ℃ environment; the gel formation time is 2.5h in the 175 ℃ environment.
所述耐高温高盐强化泡沫堵剂的油藏注入方法,包括以下步骤:The oil reservoir injection method of the high temperature resistant and high salt reinforced foam plugging agent comprises the following steps:
(1)选井:选取地层非均质性强;渗透率差异大;边底水活跃且产出液含水率高的油井;(1) Well selection: select oil wells with strong formation heterogeneity; large difference in permeability; active edge and bottom water and high water content of produced fluid;
(2)配置强化泡沫堵剂:首先在搅拌条件下将强化剂甲基纤维素加入至水中,搅拌均匀;然后再将主剂木质素、交联剂乌洛托品以及HZ-1型起泡剂按照相应比例搅拌均匀,配得强化泡沫堵剂溶液;(2) Configure strengthening foam plugging agent: first add the strengthening agent methyl cellulose into the water under stirring conditions, and stir evenly; then add the main agent lignin, cross-linking agent urotropine and HZ-1 type foaming The agent is stirred evenly according to the corresponding proportion, and the solution of strengthening foam plugging agent is prepared;
(3)注液:以200~400L/min的小排量向油井中注入步骤(2)所配强化泡沫堵剂液体,总注入液量为100~300m3,该强化泡沫堵剂液体自身低粘度特性,加上注入参数的设计协同作用使得冻胶溶液尽可能地波及到高渗区域,注入过程中记录初始井口注入压力;(3) Liquid injection: inject the reinforced foam plugging agent liquid prepared in step (2) into the oil well with a small displacement of 200-400L/min. The total injected liquid volume is 100-300m 3 , and the reinforced foam plugging agent liquid itself is low The viscosity characteristics and the synergy of the design of the injection parameters make the gel solution spread to the high-permeability area as much as possible, and the initial wellhead injection pressure is recorded during the injection process;
(4)注气:将氮气注入至油层中,注入排量为600~2400Nm3/h,记录井口注气压力,当井口注气压力相对于初始井口注入压力升高3~5MPa时,停止注气;(4) Gas injection: inject nitrogen gas into the oil layer, the injection displacement is 600-2400Nm 3 /h, record the gas injection pressure at the wellhead, and stop the injection when the wellhead gas injection pressure increases by 3-5MPa relative to the initial wellhead injection pressure gas;
(5)焖井:焖井1~5天,使强化泡沫堵剂发生交联反应,形成稳定冻胶泡沫体系;(5) Boil the well: Boil the well for 1 to 5 days, so that the strengthened foam plugging agent undergoes a cross-linking reaction to form a stable jelly foam system;
(6)生产:开井生产,记录产液量、产油量、产气量等数据的变化趋势。(6) Production: open wells for production, record the changing trends of data such as liquid production, oil production, and gas production.
所述耐高温高盐的强化泡沫堵剂在注入到地层的过程中,仅波及高渗区域而不污染低渗区域。In the process of injecting the high-temperature and high-salt reinforced foam plugging agent into the formation, it only affects the high-permeability area and does not pollute the low-permeability area.
本发明的有益效果为:本发明所述强化泡沫堵剂能够改善地层的非均质性,提高波及系数以及洗油效率,从而能够提高驱油效果和采收率。The beneficial effects of the present invention are as follows: the enhanced foam plugging agent of the present invention can improve the heterogeneity of the formation, improve the sweep coefficient and the oil washing efficiency, so as to improve the oil displacement effect and the recovery factor.
1.该强化泡沫堵剂的成胶时间可控,成胶强度大,成胶稳定性强,能够适用于温度为175℃、矿化度为20×104mg/L的油藏;可应用于热采稠油油藏、深层高温高矿化度油藏的调剖堵水。1. The gel-forming time of the reinforced foam plugging agent is controllable, the gel-forming strength is high, and the gel-forming stability is strong, and it can be applied to oil reservoirs with a temperature of 175℃ and a salinity of 20×10 4 mg/L; it can be applied Profile control and water shutoff in thermal recovery heavy oil reservoirs and deep high temperature and high salinity reservoirs.
2.该强化泡沫堵剂所形成的强化泡沫体系稳定性高、封堵效果强,可以有效地封堵高渗层位,从而控制在开采过程中出现的水侵、汽窜等问题。2. The reinforced foam system formed by the reinforced foam plugging agent has high stability and strong blocking effect, and can effectively block the high-permeability layer, thereby controlling the problems of water intrusion and steam channeling in the mining process.
3、本发明所述强化泡沫堵剂液体自身黏度低,稍大于水的粘度。在注入过程中基本上没有渗流阻力。只有在成胶过程中黏度才会增加,随着冻胶粘度的增大进而封堵高渗层。3. The liquid self-viscosity of the reinforced foam plugging agent of the present invention is low, slightly larger than the viscosity of water. There is essentially no seepage resistance during injection. The viscosity increases only during the gelation process, and the high-permeability layer is blocked with the increase of the gel viscosity.
4、所述强化泡沫堵剂的油藏注入方法能够使得该堵剂在一定条件下注入到高渗层而保护低渗层不被污染,从而对高渗层位进行有效封堵,改善地层的非均质性,防止油井生产过程中的汽窜、水侵等复杂情况。4. The reservoir injection method for strengthening the foam plugging agent can make the plugging agent injected into the high-permeability layer under certain conditions to protect the low-permeability layer from being polluted, so as to effectively block the high-permeability layer and improve the formation. Heterogeneity prevents complex situations such as steam channeling and water intrusion in the production process of oil wells.
附图说明Description of drawings
图1为实验例1的整个实验过程中强化泡沫体系在不同温度下成胶时间和成胶强度变化图。Fig. 1 is a graph showing the change of gel formation time and gel strength of the reinforced foam system at different temperatures during the whole experiment of Experimental Example 1.
图2为实验例1的整个实验过程中强化泡沫体系的脱水率与强度随老化时间变化图。FIG. 2 is a graph showing the variation of dehydration rate and strength of the reinforced foam system with aging time in the whole experimental process of Experimental Example 1. FIG.
图3为实验例1的整个实验过程中强化泡沫体系成胶前的扫描电镜图。3 is a scanning electron microscope image of the reinforced foam system before gelation in the whole experimental process of Experimental Example 1.
图4为实验例1的整个实验过程中强化泡沫体系成胶后的扫描电镜图。FIG. 4 is a scanning electron microscope image of the reinforced foam system after gelation in the whole experimental process of Experimental Example 1. FIG.
图5为实验例2在强化剂分别为0.5%、0.4%、0.3%的情况下,按照正交试验方法依次改变乌洛托品和木质素的用量,成胶时间变化图。Fig. 5 is a graph showing the change of gelation time by changing the dosage of urotropine and lignin in turn according to the orthogonal test method when the strengthening agent is 0.5%, 0.4% and 0.3% respectively in Experimental Example 2.
图6为实验例2在强化剂分别为0.5%、0.4%、0.3%的情况下,按照正交试验方法依次改变乌洛托品和木质素的用量,成胶强度变化图。Figure 6 is a graph showing the change of gel strength in Experimental Example 2 when the reinforcing agent is 0.5%, 0.4% and 0.3% respectively, according to the orthogonal test method, the dosages of urotropine and lignin are changed in turn.
图7为实验例3中木质素浓度对成胶时间以及成胶强度影响变化图。FIG. 7 is a graph showing the effect of lignin concentration on gelation time and gelation strength in Experimental Example 3. FIG.
图8为实验例3中乌洛托品浓度对成胶时间以及成胶强度影响变化图。FIG. 8 is a graph showing the effect of urotropine concentration on gel formation time and gel formation strength in Experimental Example 3. FIG.
图9为实验例4的整个实验过程中高渗、低渗两根岩心管的采收率变化情况图。FIG. 9 is a graph showing the change of the recovery factor of the high-permeability and low-permeability two core pipes in the whole experiment process of Experimental Example 4. FIG.
图10为对比例1的整个实验过程中在100℃情况下加强化剂前后冻胶状态。FIG. 10 shows the jelly state before and after strengthening the agent at 100° C. during the whole experimental process of Comparative Example 1. FIG.
具体实施方式Detailed ways
下面结合附图,对本发明的技术方案进行详细的说明。The technical solutions of the present invention will be described in detail below with reference to the accompanying drawings.
实施例1Example 1
所述耐高温高盐的强化泡沫堵剂,按照质量百分比主剂木质素4.3%,交联剂乌洛托品4%,强化剂分子量在8~20万的甲基纤维素0.35%,HZ-1型起泡剂0.5%,余量为水。The high-temperature and high-salt reinforced foam plugging agent is based on the mass percentage of the main agent lignin 4.3%, the
该强化泡沫堵剂适用于温度为175℃,矿化度为20×104mg/L的油藏。The enhanced foam plugging agent is suitable for reservoirs with a temperature of 175℃ and a salinity of 20×10 4 mg/L.
该强化泡沫堵剂在80~175℃环境中形成冻胶的成胶时间为2.5~22h,其中在80℃环境中成胶时间为22h;在100℃环境中成胶时间为6.5h;在120℃环境中成胶时间为5h;在160℃环境中成胶时间为3h;在175℃环境中成胶时间为2.5h。The gel-forming time of the reinforced foam plugging agent to form jelly in the environment of 80-175°C is 2.5-22h, of which the gel-forming time is 22h in the environment of 80°C; the gel-forming time is 6.5h in the environment of 100°C; The gel-forming time is 5h in ℃ environment; the gel-forming time is 3h in 160 ℃ environment; the gel-forming time is 2.5h in 175 ℃ environment.
所述耐高温高盐强化泡沫堵剂的油藏注入方法,包括以下步骤:The oil reservoir injection method of the high temperature resistant and high salt reinforced foam plugging agent comprises the following steps:
(1)选井:选取地层非均质性强,渗透率差异大,边底水活跃且产出液含水率高的油井;(1) Well selection: select oil wells with strong formation heterogeneity, large difference in permeability, active edge and bottom water, and high water content of produced fluid;
(2)配置强化泡沫堵剂溶液:首先在搅拌条件下按照比例将质量比为0.35%强化剂甲基纤维素加入至水中,搅拌均匀;然后再将4.3%主剂木质素、4%交联剂乌洛托品以及0.5%HZ-1型起泡剂按照比例搅拌均匀,配得强化泡沫堵剂溶液;(2) Configure the strengthening foam plugging agent solution: first, under stirring conditions, add 0.35% of the strengthening agent methyl cellulose to the water in proportion by mass, and stir evenly; then add 4.3% of the main agent lignin, 4% of cross-linking Proportion of urotropine and 0.5% HZ-1 foaming agent were mixed uniformly to obtain a solution of strengthening foam plugging agent;
(3)注液:以320L/min的小排量向油井中注入步骤(2)所配强化泡沫堵剂,总注入液量为155m3,该强化泡沫堵剂自身特性加上注入参数的设计协同作用使得冻胶溶液尽可能地波及到高渗区域时,记初始始井口压力;(3) Liquid injection: inject the enhanced foam plugging agent prepared in step (2) into the oil well at a small displacement of 320L/min. The total injected liquid volume is 155m 3 . The characteristics of the enhanced foam plugging agent plus the design of injection parameters When the synergistic effect makes the jelly solution spread to the high permeability area as much as possible, record the initial initial wellhead pressure;
(4)注气:将氮气注入至油层中,注入排量为1200Nm3/h,记录井口注气压力,当井口注气压力相对于初始井口注入压力升高4.1MPa时,停止注气;(4) Gas injection: inject nitrogen into the oil layer, the injection displacement is 1200Nm 3 /h, record the gas injection pressure at the wellhead, and stop the gas injection when the gas injection pressure at the wellhead increases by 4.1MPa relative to the initial wellhead injection pressure;
(5)焖井:焖井3天,使强化泡沫堵剂发生交联反应,形成稳定冻胶泡沫体系;(5) Boil the well: Boil the well for 3 days, so that the strengthened foam plugging agent undergoes a cross-linking reaction to form a stable jelly foam system;
(6)生产:开井生产,记录产液量、产油量、产气量等数据的变化趋势。(6) Production: open wells for production, record the changing trends of data such as liquid production, oil production, and gas production.
实验例1Experimental example 1
下面通过实验分析本发明所述强化泡沫堵剂高温状况下的强化泡沫稳定性以及成胶状况。The reinforced foam stability and gel formation state of the reinforced foam plugging agent of the present invention under high temperature conditions are analyzed below through experiments.
一、实验步骤1. Experimental steps
配置强化泡沫堵剂,包括以下步骤:To configure a reinforced foam plug, include the following steps:
(1)向烧杯中加入181.7g的超纯水;(1) add 181.7g of ultrapure water to the beaker;
(2)在搅拌的条件下将0.7g甲基纤维素溶液加入到装有超纯水的烧杯中,充分搅拌均匀;(2) 0.7g of methylcellulose solution was added to the beaker containing ultrapure water under stirring conditions, and stirred well;
(3)向烧杯中加入8.6g木质素、8g乌洛托品交联剂、1gHZ-1型起泡剂,用玻璃棒搅拌均匀,进而得到强化泡沫体系;(3) add 8.6g lignin, 8g urotropine cross-linking agent, 1g HZ-1 type foaming agent to the beaker, stir with glass rod, and then obtain the strengthening foam system;
(4)将得到的上述强化泡沫溶液分别放置在密封性良好的安瓿瓶中,然后将装有强化泡沫溶液的安瓿瓶分别放置在90℃、100℃、125℃、150℃、175℃的环境中加热成胶,记录成胶时间和成胶强度变化。(4) Place the obtained reinforced foam solution in ampoules with good airtightness, and then place the ampoules containing the reinforced foam solution in an environment of 90°C, 100°C, 125°C, 150°C, and 175°C, respectively. The gel was heated in the middle to form the gel, and the gel-forming time and the change of the gel-forming strength were recorded.
二、实验结果与分析2. Experimental results and analysis
通过记录强化泡沫体系成胶过程中的成胶时间以及成胶强度变化,可以准确的判断成胶时间和成胶强度随温度的变化情况,从而分析高温状况下强化泡沫的稳定性以及成胶状况。By recording the gelation time and gel strength changes of the reinforced foam system during gelation, the gelation time and gel strength changes with temperature can be accurately judged, so as to analyze the stability of the reinforced foam and the gelation state under high temperature conditions. .
从图1中可以看出,随着温度的升高,成胶时间不断缩短,成胶强度先增大然后下降。在温度为100℃的情况下,成胶强度达到最大,成胶强度为H+级别,成胶时间为6.5h。在100~140℃范围内,成胶强度的变化幅度比较小,说明该冻胶具有较好的耐温性能,在高温的情况下仍具有较好的稳定性。It can be seen from Figure 1 that with the increase of temperature, the gel formation time is shortened continuously, and the gel formation strength first increases and then decreases. When the temperature is 100 ℃, the gel strength reaches the maximum, the gel strength is H + level, and the gel time is 6.5h. In the range of 100-140 ℃, the change range of gel strength is relatively small, indicating that the jelly has good temperature resistance and still has good stability under high temperature.
由图2中可以看出,强化泡沫在175℃环境中连续加热1个月,成胶强度仅损失2个级别,脱水率仅为9%左右,因此该强化泡沫体系具有很强的稳定性,能够很好的应用于高温油藏中。It can be seen from Figure 2 that the reinforced foam is continuously heated at 175 °C for 1 month, the gel strength is only lost by 2 levels, and the dehydration rate is only about 9%, so the reinforced foam system has strong stability. It can be well used in high temperature oil reservoirs.
由图3可以看出,强化泡沫体系成胶之前,整个体系的交联点还没有连接成一个整体的网络结构。这主要是因为在交联之前,强化泡沫体系还没有在高温下成胶,乌洛托品的交联作用只有在高温下才能够发挥作用。It can be seen from Figure 3 that before the reinforced foam system gels, the cross-linking points of the entire system have not been connected to form a whole network structure. This is mainly because the reinforced foam system has not been gelatinized at high temperature before crosslinking, and the crosslinking effect of urotropine can only work at high temperature.
由图4可以看出,强化泡沫体系成胶之后,整个体系的交联点都连接在一块,形成一个致密的网状结构。从图5还可以看出,整个空间没有空缺之处,这也是强化泡沫体系稳定性强、成胶强度比较大的原因。It can be seen from Figure 4 that after the reinforced foam system is gelled, the cross-linking points of the entire system are connected together to form a dense network structure. It can also be seen from Figure 5 that there is no vacancy in the entire space, which is also the reason for the strong stability of the reinforced foam system and the relatively high gel strength.
实验例2Experimental example 2
一、实验目的1. The purpose of the experiment
在强化剂分别为0.5%、0.4%、0.3%的情况下,按照正交试验方法依次改变乌洛托品和木质素的用量,观察泡沫体系成胶强度和成胶时间。When the strengthening agent was 0.5%, 0.4% and 0.3% respectively, the dosage of urotropine and lignin were changed in turn according to the orthogonal test method, and the gel strength and gel time of the foam system were observed.
二、实验结果与分析2. Experimental results and analysis
表1正交试验数据Table 1 Orthogonal test data
结合图5和图6可知:当乌洛托品的浓度在3.5~5.5%、木质素的浓度在4~6%,等值线比较致密,说明在该浓度范围内成胶时间与成胶强度变化的比较明显,且成胶时间比较短,成胶强度比较大,能够满足实际的油田生产要求。Combining Figure 5 and Figure 6, it can be seen that when the concentration of urotropine is 3.5-5.5% and the concentration of lignin is 4-6%, the contour lines are relatively dense, indicating that the gelation time and gelation strength are within this concentration range. The change is obvious, the gel formation time is relatively short, and the gel formation strength is relatively large, which can meet the actual oil field production requirements.
实验例3Experimental example 3
一、实验目的1. Purpose of the experiment
分别通过单因素实验,研究主剂木质素浓度、乌洛托品浓度以及强化剂浓度对成胶时间以及成胶强度的影响。The effects of main agent lignin concentration, urotropine concentration and strengthening agent concentration on gel formation time and gel strength were studied through single factor experiments respectively.
二、实验结果与分析2. Experimental results and analysis
通过图7可知,随着木质素浓度的增加,成胶时间与成胶强度均不断增大,当木质素的浓度为4~6%时,成胶强度的变化范围最剧烈。It can be seen from Fig. 7 that with the increase of lignin concentration, the gel forming time and gel strength increase continuously. When the lignin concentration is 4-6%, the range of gel strength is the most severe.
通过图8可知,随着乌洛托品浓度的增加,成胶时间越来越小,成胶强度越来越大。当乌洛托品的浓度在3~6%时,成胶强度变化趋势较为明显,说明两者的交联反应剧烈。It can be seen from Figure 8 that with the increase of the concentration of urotropine, the gel formation time is getting smaller and smaller, and the gel formation strength is getting bigger and bigger. When the concentration of urotropine is 3-6%, the change trend of gel strength is more obvious, indicating that the cross-linking reaction of the two is severe.
表2强化剂浓度变化时冻胶变化状态Table 2 jelly change state when the concentration of fortifier changes
通过表2可知,强化剂的加入与否,主要影响冻胶的状态。“橡皮泥状”的冻胶自身具有一定的弹性,也就是说在经受适当外力的状况下,具有一定的自我恢复能力。“豆腐状”冻胶是指在经受外力状况下,本身没有自我恢复的能力,受到外力会导致冻胶破碎。当强化剂的浓度大于0.2%时,豆腐状的比例就已经减小至40%。所以当强化剂的浓度高于0.3%时,强化泡沫体系的稳定性以及韧性就能够满足油田生产的要求。It can be seen from Table 2 that the addition or not of the fortifier mainly affects the state of the jelly. The "plasticine-like" jelly itself has a certain elasticity, that is to say, it has a certain self-recovery ability under the condition of appropriate external force. "Tofu-like" jelly refers to the fact that it has no self-recovery ability under the condition of external force, and the jelly will be broken by external force. When the concentration of the fortifier is greater than 0.2%, the tofu-like proportion has been reduced to 40%. Therefore, when the concentration of the strengthening agent is higher than 0.3%, the stability and toughness of the strengthened foam system can meet the requirements of oilfield production.
实验例4Experimental example 4
对所述强化泡沫堵剂调剖性能进行实验。Experiments were carried out on the profile control performance of the enhanced foam plugging agent.
一、实验目的1. Purpose of the experiment
模拟油藏注蒸汽驱油过程,考察注入强化泡沫后高渗、低渗区域采油的效果,实验温度保持在100℃恒温。The steam flooding process was simulated in the reservoir, and the effect of oil recovery in high and low permeability areas after injection of enhanced foam was investigated. The experimental temperature was kept at a constant temperature of 100 °C.
二、实验步骤2. Experimental steps
(1)先填制两个渗透率(9646.41mD和940.31mD)不相同的岩心管(φ30cm×2.5cm),将两个岩心管抽真空4h左右;(1) First fill two core tubes (φ30cm×2.5cm) with different permeability (9646.41mD and 940.31mD), and vacuum the two core tubes for about 4h;
(2)称取岩心管的干重,饱和水,称取湿重,计算岩心管的孔隙体积;(2) Weigh the dry weight of the core pipe, saturated water, and weigh the wet weight, and calculate the pore volume of the core pipe;
(3)以1mL/min的速度进行水驱,依据达西公式进行渗透率的计算;(3) Carry out water flooding at a speed of 1 mL/min, and calculate the permeability according to Darcy's formula;
(4)用粘度为1200cP的原油进行饱和油,饱和油的速度为0.1mL/min;(4) Saturate oil with crude oil with a viscosity of 1200 cP, and the speed of saturated oil is 0.1 mL/min;
(5)将两个岩心管置于温度为100℃的环境中,前两个轮次将300℃的蒸汽以5mL/min的速度注入0.3PV,记录岩心管两端的压差变化;(5) Place the two core tubes in an environment with a temperature of 100 °C, inject 300 °C steam at a rate of 5 mL/min to 0.3PV in the first two rounds, and record the pressure difference changes at both ends of the core tubes;
(6)关闭岩心管阀门进行焖井,焖井时间为0.5h。开井生产,记录产油速度、产液速度、采收率、压差等参数;(6) Close the core tube valve to soak the well, and the soaking time is 0.5h. Open well for production, record oil production rate, liquid production rate, recovery factor, differential pressure and other parameters;
(7)后两个轮次首先将冻胶(配方为4.3%木质素+4%乌洛托品+0.35%强化剂)、冻胶泡沫(冻胶泡沫体系配方为4.3%木质素+4%乌洛托品+0.35%强化剂+0.5%起泡剂、气液比为1:1)以1mL/min的速度注入到岩心管中,注入量为0.3PV,记录岩心管两端的压差变化;然后在100℃的条件下静置7h成胶;(7) In the last two rounds, the jelly (the formula is 4.3% lignin + 4% urotropine + 0.35% fortifier), the jelly foam (the formula of the jelly foam system is 4.3% lignin + 4% Urotropine + 0.35% strengthening agent + 0.5% foaming agent, gas-liquid ratio of 1:1) was injected into the core tube at a rate of 1 mL/min, the injection volume was 0.3PV, and the pressure difference at both ends of the core tube was recorded. ; Then stand at 100℃ for 7h to form a gel;
(8)成胶后,在往岩心内注入300℃的蒸汽0.3PV,记录压差变化;(8) After gelation, inject 0.3PV of steam at 300°C into the core, and record the pressure difference change;
(9)关闭岩心管阀门进行焖井,焖井时间为0.5h。开井生产,记录产油速度、产液速度、采收率、压差等参数;(9) Close the core tube valve to soak the well, and the soaking time is 0.5h. Open well for production, record oil production rate, liquid production rate, recovery factor, differential pressure and other parameters;
三、实验结果与分析3. Experimental results and analysis
通过记录在整个开采过程中不同周期的产油、产液、采收率变化,可以清楚地看出在各个阶段的采收率增加情况,了解各个阶段产油产油量,进而总结强化泡沫所产生的增产效果。By recording the changes of oil production, liquid production and recovery factor in different periods during the whole production process, it is possible to clearly see the increase in oil recovery at each stage, understand the oil production and oil production at each stage, and then summarize the reasons for strengthening foam. yield increase effect.
整个生产阶段一共分为四个轮次,前两个轮次是注入蒸汽的过程,后两个轮次是先注入强化泡沫体系,然后再注入蒸汽的过程。The whole production stage is divided into four rounds. The first two rounds are the process of injecting steam, and the last two rounds are the process of injecting the enhanced foam system first, and then injecting steam.
如图9所示,在第一个轮次中,高渗管开采出来的油量比较多,采收率能达到17%,低渗管的采收率在5%。随着开采轮次的增加,第二周期高渗采收率只增加了5%,低渗增加了1%,而且在第二开采周期中,高渗的含水率已经增加到90%。当注入强化泡沫体系后,低渗管中的采收率增大,高渗采收率增加3%,低渗采收率增加13%,并且含水率也有一定程度的下降,由原来的90%下降到60%。As shown in Figure 9, in the first round, the high-permeability pipe produced more oil, and the recovery factor could reach 17%, while the low-permeability pipe had a recovery factor of 5%. With the increase of mining rounds, the high-permeability recovery factor in the second cycle increased by only 5%, and the low-permeability increased by 1%, and in the second production cycle, the high-permeability water cut has increased to 90%. When the enhanced foam system is injected, the recovery factor in the low-permeability pipe increases, the high-permeability recovery factor increases by 3%, the low-permeability recovery factor increases by 13%, and the water content also decreases to a certain extent, from the original 90% down to 60%.
应用例1Application example 1
现场应用方法:工艺现场实施时,采用段塞注入的方式,按照0.5%起泡剂+4%乌洛托品+0.35%甲基纤维素+4.3%木质素的比例注入,现场配备搅拌机对稳泡剂进行分散搅匀,保证药剂均匀的分布在溶液中。Field application method: When the process is implemented on site, the method of slug injection is adopted, and the injection is carried out according to the ratio of 0.5% foaming agent + 4% urotropine + 0.35% methyl cellulose + 4.3% lignin, and a mixer is equipped on site to stabilize The foaming agent is dispersed and stirred to ensure that the agent is evenly distributed in the solution.
井例分析:井号为CH-13,自2005年11月投产,已进行了5轮注汽,受边水侵入的影响,2015年8月以来,该井一直高含水生产,平均含水为95.3%,长期维持在日产油1.9吨左右的低产状态。上一轮普通氮气泡沫调剖实施于2017年12月,实施后峰值日产油2.6吨,周期平均日产油2.0吨。2019年1月实施强化泡沫调剖工艺,注入冻胶泡沫液120m3,氮气7.3×104Nm3,该井开井8天后迅速见油,日产油峰值达到7.5吨,目前平均日产油量4.8吨,较上轮普通氮气泡沫调剖工艺平均日增油2.8吨,目前累增油528吨,比上轮氮气调剖同期多增油176吨,工艺效果显著。Well case analysis: The well number is CH-13. Since it was put into production in November 2005, 5 rounds of steam injection have been carried out. Affected by the intrusion of edge water, the well has been producing with high water cut since August 2015, with an average water cut of 95.3 %, maintaining a low output of about 1.9 tons of oil per day for a long time. The last round of ordinary nitrogen foam profile control was implemented in December 2017. After the implementation, the peak daily oil production was 2.6 tons, and the cycle average daily oil production was 2.0 tons. In January 2019, the enhanced foam profile control process was implemented, and 120m 3 of jelly foam liquid and 7.3×10 4 Nm 3 of nitrogen were injected into the well. The well saw oil quickly 8 days after it was opened, and the daily peak oil production reached 7.5 tons. The current average daily oil production is 4.8 Compared with the previous round of ordinary nitrogen foam profile control process, the average daily oil increase is 2.8 tons. At present, the cumulative oil increase is 528 tons, which is 176 tons more than the previous round of nitrogen profile control. The process effect is remarkable.
对比例1Comparative Example 1
一、实验步骤1. Experimental steps
配置泡沫堵剂,包括以下步骤:To configure a foam blocker, include the following steps:
(1)向烧杯中加入182.4g的超纯水;(1) add 182.4g of ultrapure water to the beaker;
(2)向烧杯中加入8.6g木质素、8g乌洛托品交联剂、1gHZ-1型起泡剂,用玻璃棒搅拌均匀,进而得到对比例1的泡沫体系;(2) add 8.6g lignin, 8g urotropine cross-linking agent, 1g HZ-1 type foaming agent to the beaker, stir with glass rod, and then obtain the foam system of Comparative Example 1;
(3)将该对比例所得到的上述泡沫溶液分别放置在密封性良好的安瓿瓶中,然后将装有泡沫溶液的安瓿瓶分别放置在90℃、100℃、125℃、150℃、175℃的环境中加热老化,记录成胶时间和成胶强度变化。(3) The above-mentioned foam solutions obtained in this comparative example were placed in ampoules with good airtightness, and then the ampoules with foam solutions were placed at 90°C, 100°C, 125°C, 150°C, and 175°C, respectively. Heat aging in the environment, record the gel time and gel strength changes.
二、实验结果与分析2. Experimental results and analysis
表3强化前后成胶时间与成胶强度之间的对比Table 3 Comparison between gel time and gel strength before and after strengthening
通过图10可以看出,加入强化剂时,冻胶整体稳定性比较高,成胶强度比较大,外形看上去像是具有一定弹性的“橡皮泥”状态。在经受外力的状态下,能够具有一定的自我恢复能力。但是不加强化剂的泡沫体系,形成的冻胶稳定性比较差,容易破碎,主要呈现的是“豆腐”状态,弹性以及韧性都很差。在经受一定外力的状态下,无法自我恢复。It can be seen from Figure 10 that when the strengthening agent is added, the overall stability of the jelly is relatively high, the gelling strength is relatively large, and the shape looks like a "plasticine" state with certain elasticity. Under the condition of external force, it can have a certain self-recovery ability. However, the foam system without strengthening agent has poor stability and is easy to break. It mainly presents a "tofu" state, and its elasticity and toughness are very poor. In the state of being subjected to a certain external force, it cannot recover by itself.
由表3可以看出,未加入强化剂时,泡沫体系成胶之后的强度小于加入强化剂的强化泡沫体系,而且从封堵率也可以看出,加入强化剂后,冻胶的封堵效果增强,说明强化剂与主剂以及交联剂之间的复配效果很好,强化剂的加入能够增强冻胶的韧性以及稳定性。It can be seen from Table 3 that when no strengthening agent is added, the strength of the foam system after gelation is lower than that of the strengthened foam system with the strengthening agent added, and it can also be seen from the blocking rate that after adding the strengthening agent, the blocking effect of the gelatin Strengthening, indicating that the compounding effect between the strengthening agent, the main agent and the cross-linking agent is very good, and the addition of the strengthening agent can enhance the toughness and stability of the jelly.
对比例2Comparative Example 2
(1)向烧杯中加入181.7g的超纯水;(1) add 181.7g of ultrapure water to the beaker;
(2)在搅拌的条件下将0.7g甲基纤维素溶液加入到装有超纯水的烧杯中,充分搅拌均匀;(2) 0.7g of methylcellulose solution was added to the beaker containing ultrapure water under stirring conditions, and stirred well;
(3)向烧杯中加入8.6g木质素、8g酚醛树脂、1gHZ-1型起泡剂,用玻璃棒搅拌均匀,进而得到强化泡沫体系;(3) add 8.6g lignin, 8g phenolic resin, 1g HZ-1 type foaming agent to the beaker, stir evenly with a glass rod, and then obtain a reinforced foam system;
(4)将得到的上述强化泡沫溶液分别放置在密封性良好的安瓿瓶中,然后将装有强化泡沫溶液的安瓿瓶分别放置在90℃、100℃、125℃、150℃、175℃的环境中加热成胶。(4) Place the obtained reinforced foam solution in ampoules with good airtightness, and then place the ampoules containing the reinforced foam solution in an environment of 90°C, 100°C, 125°C, 150°C, and 175°C, respectively. Heat to gel.
表4不同交联剂的泡沫体系成胶时间与成胶强度之间的对比Table 4. Comparison between gel formation time and gel strength of foam systems with different cross-linking agents
通过表4中的对比可以看出,当乌洛托品作为交联剂时,成胶时间比较快,说明交联剂与主剂之间的反应比较迅速,所形成冻胶的强度也比较大,最终产生的封堵效果大于酚醛树脂作交联剂时的效果。可见乌洛托品与主剂、强化剂之间产生的复配效果远远大于酚醛树脂与主剂、强化剂的效果。From the comparison in Table 4, it can be seen that when urotropine is used as the cross-linking agent, the gel formation time is relatively fast, indicating that the reaction between the cross-linking agent and the main agent is relatively fast, and the strength of the formed gel is relatively large. , the final blocking effect is greater than that when phenolic resin is used as the crosslinking agent. It can be seen that the compound effect between urotropine and the main agent and the strengthening agent is far greater than the effect of the phenolic resin and the main agent and the strengthening agent.
对比例3Comparative Example 3
(1)向烧杯中加入181.7g的超纯水;(1) add 181.7g of ultrapure water to the beaker;
(2)在搅拌的条件下将0.7g甲基纤维素溶液加入到装有超纯水的烧杯中,充分搅拌均匀;(2) 0.7g of methylcellulose solution was added to the beaker containing ultrapure water under stirring conditions, and stirred well;
(3)向烧杯中加入0.5g主剂HPAM、1g乌洛托品、1gHZ-1型起泡剂,用玻璃棒搅拌均匀,进而得到强化泡沫体系;(3) add 0.5g main agent HPAM, 1g urotropine, 1g HZ-1 type foaming agent to the beaker, stir evenly with a glass rod, and then obtain a strengthened foam system;
(4)将得到的上述强化泡沫溶液分别放置在密封性良好的安瓿瓶中,然后将装有强化泡沫溶液的安瓿瓶分别放置在90℃、100℃、125℃、150℃、175℃的环境中加热成胶。(4) Place the obtained reinforced foam solution in ampoules with good airtightness, and then place the ampoules containing the reinforced foam solution in an environment of 90°C, 100°C, 125°C, 150°C, and 175°C, respectively. Heat to gel.
表5不同主剂种类的泡沫体系成胶时间与成胶强度之间的对比Table 5. Comparison between gel formation time and gel strength of foam systems with different main agent types
从表5中可以看出,将主剂换成HPAM后,冻胶强度变化很大,成胶时间也在不断延长。说明HPAM与交联剂之间的聚合作用比较缓慢,两者的反应不是很充分,最后形成的冻胶强度比较小而且封堵率也比较差。因此木质素与交联剂、强化剂的复配作用大于HPAM所产生的复配作用。It can be seen from Table 5 that after replacing the main agent with HPAM, the jelly strength changes greatly, and the gel formation time is also prolonged. It shows that the polymerization between HPAM and the cross-linking agent is relatively slow, the reaction between the two is not very sufficient, and the final gel strength is relatively small and the blocking rate is relatively poor. Therefore, the compounding effect of lignin, cross-linking agent and strengthening agent is greater than that produced by HPAM.
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Application publication date: 20210803 Assignee: Shandong Ruiheng Xingyu Petroleum Technology Development Co.,Ltd. Assignor: CHINA University OF PETROLEUM (EAST CHINA) Contract record no.: X2023980037469 Denomination of invention: An enhanced foam plugging agent with high temperature and salt resistance and its reservoir injection method Granted publication date: 20220531 License type: Common License Record date: 20230703 |