CN113175665B - System and method for low NOx of semicoke and anti-slagging and co-firing - Google Patents
System and method for low NOx of semicoke and anti-slagging and co-firing Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 14
- 238000010344 co-firing Methods 0.000 title description 5
- 239000002028 Biomass Substances 0.000 claims abstract description 154
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 69
- 239000003546 flue gas Substances 0.000 claims abstract description 69
- 238000002485 combustion reaction Methods 0.000 claims abstract description 61
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 59
- 239000001301 oxygen Substances 0.000 claims abstract description 59
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 59
- 239000000571 coke Substances 0.000 claims abstract description 53
- 239000002245 particle Substances 0.000 claims abstract description 49
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 44
- 238000001035 drying Methods 0.000 claims abstract description 29
- 239000000428 dust Substances 0.000 claims abstract description 26
- 238000002156 mixing Methods 0.000 claims abstract description 25
- 238000002360 preparation method Methods 0.000 claims abstract description 19
- 239000002918 waste heat Substances 0.000 claims abstract description 8
- 239000000446 fuel Substances 0.000 claims description 61
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 239000007789 gas Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 16
- 238000000227 grinding Methods 0.000 claims description 12
- 238000006477 desulfuration reaction Methods 0.000 claims description 8
- 230000023556 desulfurization Effects 0.000 claims description 8
- 239000000919 ceramic Substances 0.000 claims description 7
- 230000006835 compression Effects 0.000 claims description 7
- 238000007906 compression Methods 0.000 claims description 7
- 229910000514 dolomite Inorganic materials 0.000 claims description 7
- 239000010459 dolomite Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 238000000605 extraction Methods 0.000 claims description 6
- 230000005611 electricity Effects 0.000 claims description 4
- 230000009469 supplementation Effects 0.000 claims description 4
- 239000002893 slag Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 238000002309 gasification Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000009841 combustion method Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000008400 supply water Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/006—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber the recirculation taking place in the combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22D—PREHEATING, OR ACCUMULATING PREHEATED, FEED-WATER FOR STEAM GENERATION; FEED-WATER SUPPLY FOR STEAM GENERATION; CONTROLLING WATER LEVEL FOR STEAM GENERATION; AUXILIARY DEVICES FOR PROMOTING WATER CIRCULATION WITHIN STEAM BOILERS
- F22D11/00—Feed-water supply not provided for in other main groups
- F22D11/02—Arrangements of feed-water pumps
- F22D11/06—Arrangements of feed-water pumps for returning condensate to boiler
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22G—SUPERHEATING OF STEAM
- F22G1/00—Steam superheating characterised by heating method
- F22G1/02—Steam superheating characterised by heating method with heat supply by hot flue gases from the furnace of the steam boiler
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K1/00—Preparation of lump or pulverulent fuel in readiness for delivery to combustion apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K3/00—Feeding or distributing of lump or pulverulent fuel to combustion apparatus
- F23K3/02—Pneumatic feeding arrangements, i.e. by air blast
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L1/00—Passages or apertures for delivering primary air for combustion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L15/00—Heating of air supplied for combustion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L9/00—Passages or apertures for delivering secondary air for completing combustion of fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K2201/00—Pretreatment of solid fuel
- F23K2201/10—Pulverizing
- F23K2201/1006—Mills adapted for use with furnaces
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
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- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
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- Combustion & Propulsion (AREA)
- Water Supply & Treatment (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
Abstract
本发明公开了一种半焦低NOx抗结渣掺烧的系统及方法,包括由生物质仓、生物质烘干装置、生物质磨粉机、抗结渣剂制备桶、生物质与抗结渣剂混合罐、半焦仓、半焦磨粉机、锅炉底层燃烧器、中间层燃烧器、再燃燃烧器、燃尽风喷嘴、屏式过热器、对流过热器、省煤器、锅炉尾部除尘器、氧气预热器等构成的半焦‑生物质混燃系统和抗结渣生物质颗粒制备装置。本发明通过将半焦‑生物质掺烧系统和生物质抗结渣颗粒制备方法有机地结合起来,并借助富氧燃烧技术,既改善了半焦的着火燃尽特性,降低了NOx生成,又克服了生物质的严重结渣问题,同时减少了CO2的排放,并充分利用了烟气中的余热和水分。本发明经济环保,简单可靠,适用范围广,具有广阔的应用前景。
The invention discloses a system and method for semi-coke low NO x anti-slagging mixed combustion, which comprises a biomass bin, a biomass drying device, a biomass mill, an anti-slagging agent preparation barrel, a biomass and an anti-slagging Slagging agent mixing tank, semi-coke bin, semi-coke pulverizer, boiler bottom burner, middle layer burner, reburning burner, overfire air nozzle, panel superheater, convection superheater, economizer, boiler tail Semi-coke-biomass co-combustion system and anti-slagging biomass particle preparation device composed of dust collector, oxygen preheater, etc. The present invention organically combines the semi-coke-biomass blending system with the preparation method of biomass anti-slagging particles, and uses oxygen-enriched combustion technology to improve the ignition and burnout characteristics of semi-coke and reduce the generation of NOx . It also overcomes the serious slagging problem of biomass, reduces the emission of CO2 , and makes full use of the waste heat and moisture in the flue gas. The invention is economical and environment-friendly, simple and reliable, has a wide application range and has broad application prospects.
Description
技术领域technical field
本发明属于固体碳基燃料清洁高效利用领域,特别涉及一种半焦低NOx抗结渣掺烧的系统及方法。The invention belongs to the field of clean and high-efficiency utilization of solid carbon-based fuels, and in particular relates to a system and method for blending semi-coke with low NOx and anti-slagging.
背景技术Background technique
煤热解副产品半焦作为高品位洁净燃料燃烧发电,是实现煤炭清洁高效梯级利用的重要组成部分。随着我国煤化工行业的快速发展,目前有大量这类燃料亟待实现燃烧利用。然而半焦的挥发分含量很低,实现清洁高效燃烧难度很大,通常存在着火稳燃困难、燃尽率低、NOx排放高等问题。因此,如何实现此类燃料的清洁高效燃烧利用,已成为制约我国煤炭清洁高效梯级利用产业化应用的关键技术瓶颈,并亟待解决。另一方面,我国生物质能分布广泛、污染小,且可有效缓减“温室效应”,但由于生物质挥发分高且含有大量易挥发的碱性金属和氯元素,其燃烧过程中易引起严重的炉内结渣、沉积及腐蚀等与灰分相关的问题,极大地制约了生物质的大规模利用。As a high-grade clean fuel, semi-coke, a by-product of coal pyrolysis, is burned to generate electricity, which is an important part of realizing clean and efficient cascade utilization of coal. With the rapid development of my country's coal chemical industry, there are a large number of such fuels that need to be burned and utilized urgently. However, the volatile content of semi-coke is very low, and it is very difficult to achieve clean and efficient combustion. Usually, there are problems such as difficulty in ignition and stable combustion, low burnout rate, and high NOx emissions. Therefore, how to realize the clean and efficient combustion and utilization of such fuels has become a key technical bottleneck restricting the industrial application of clean and efficient cascade utilization of coal in my country, and needs to be resolved urgently. On the other hand, my country's biomass energy is widely distributed, has little pollution, and can effectively mitigate the "greenhouse effect". Serious problems related to ash content such as slagging, deposition and corrosion in the furnace greatly restrict the large-scale utilization of biomass.
发明内容Contents of the invention
本发明的目的在于提供一种半焦低NOx抗结渣掺烧的系统及方法,其结合富氧燃烧技术,借助抗结渣生物质颗粒,采用生物质和半焦在炉内分层掺烧的方式,并利用燃料分级和氧气分级燃烧技术,在改善半焦难着火、燃尽差并降低锅炉NOx生成的同时,缓减了生物质高碱金属带来的结渣问题,且充分利用了烟气余热,并节约了水资源。The purpose of the present invention is to provide a system and method for semi-coke low NO x slagging-resistant blended combustion, which combines oxygen-enriched combustion technology, with the help of anti-slagging biomass particles, and adopts biomass and semi-coke to be blended in layers in the furnace. Combustion method, and the use of fuel staged and oxygen staged combustion technology, while improving the difficulty of semi-coke ignition, poor burnout and reducing NOx generation in boilers, it also alleviates the slagging problem caused by high alkali metals in biomass, and fully The waste heat of the flue gas is utilized and water resources are saved.
为达到上述目的,本发明采用如下的技术方案来实现:In order to achieve the above object, the present invention adopts following technical scheme to realize:
一种半焦低NOx抗结渣掺烧的系统,包括半焦-生物质混燃系统和抗结渣生物质颗粒制备装置;其中,A semi-coke low NO x anti-slagging blended combustion system, including a semi-coke-biomass co-combustion system and an anti-slagging biomass particle preparation device; wherein,
半焦-生物质混燃系统包括生物质仓、生物质烘干装置、生物质磨粉机、半焦仓、半焦磨粉机、锅炉底层燃烧器、中间层燃烧器、再燃燃烧器、燃尽风喷嘴、循环风机、混气器、化学处理装置、补给水泵、汽轮机和蒸汽泵,依次设置在烟气管道内的屏式过热器、对流过热器和省煤器,以及与烟气管道出口依次连接的锅炉尾部除尘器、氧气预热器、脱硫装置、烟气冷凝器和CO2压缩装置;The semi-coke-biomass co-combustion system includes biomass bin, biomass drying device, biomass pulverizer, semi-coke bin, semi-coke pulverizer, boiler bottom burner, middle layer burner, reburning burner, combustion Exhaust nozzles, circulating fans, gas mixers, chemical treatment devices, make-up water pumps, steam turbines and steam pumps, panel superheaters, convective superheaters and economizers arranged in sequence in the flue gas pipeline, and outlets connected to the flue gas pipeline Boiler tail dust collector, oxygen preheater, desulfurization device, flue gas condenser and CO2 compression device connected in sequence;
抗结渣生物质颗粒制备装置包括抗结渣剂制备桶和生物质与抗结渣剂混合罐;The anti-slagging biomass particle preparation device includes an anti-slagging agent preparation tank and a mixing tank of biomass and anti-slagging agent;
生物质仓通过输送管道与生物质烘干装置的上入口相连,蒸汽泵的入口与汽轮机的抽汽管道相连,蒸汽泵的出口与生物质烘干装置的侧入口相连,生物质烘干装置的出口与生物质磨粉机的入口相连,生物质磨粉机的出口与锅炉底层燃烧器的燃料喷嘴相连;半焦仓通过输送管道与半焦磨粉机的入口相连,半焦磨粉机的出口与锅炉中间层燃烧器的燃料喷嘴相连;抗结渣剂制备桶的出口与生物质与抗结渣剂混合罐的入口相连,生物质与抗结渣剂混合罐的出口与再燃燃烧器的燃料喷嘴相连;The biomass bin is connected to the upper inlet of the biomass drying device through the conveying pipeline, the inlet of the steam pump is connected to the steam extraction pipe of the steam turbine, the outlet of the steam pump is connected to the side inlet of the biomass drying device, and the biomass drying device The outlet is connected to the inlet of the biomass pulverizer, and the outlet of the biomass pulverizer is connected to the fuel nozzle of the bottom burner of the boiler; the semi-coke bin is connected to the inlet of the semi-coke pulverizer through a conveying pipeline, The outlet is connected to the fuel nozzle of the burner in the middle layer of the boiler; the outlet of the anti-slagging agent preparation tank is connected to the inlet of the biomass and anti-slagging agent mixing tank, and the outlet of the biomass and anti-slagging agent mixing tank is connected to the reburning burner Fuel nozzles are connected;
锅炉尾部除尘器后的部分热烟气通过烟气管道与循环风机的入口相连,循环风机的出口通过三通阀分别与再燃燃烧器的进风喷嘴和混气器的下入口相连,空气分离器的入口接大气,下出口通过三通阀分别与锅炉底层燃烧器的一次风喷嘴和混气器的侧入口相连,混气器的出口分别与锅炉底层燃烧器的二次风喷嘴、中间层燃烧器的一、二次风喷嘴及燃尽风喷嘴相连;Part of the hot flue gas after the dust collector at the tail of the boiler is connected to the inlet of the circulating fan through the flue gas pipe, and the outlet of the circulating fan is respectively connected to the air inlet nozzle of the reburning burner and the lower inlet of the gas mixer through a three-way valve. The inlet of the boiler is connected to the atmosphere, and the lower outlet is respectively connected to the primary air nozzle of the bottom burner of the boiler and the side inlet of the gas mixer through a three-way valve. The primary and secondary air nozzles and the burn-off air nozzles of the device are connected;
烟气冷凝器的冷凝水出口连接至化学处理装置的入口,化学处理装置的出口通过补给水泵连接至省煤器。The condensed water outlet of the flue gas condenser is connected to the inlet of the chemical treatment device, and the outlet of the chemical treatment device is connected to the economizer through a feed water pump.
本发明进一步的改进在于,生物质烘干装置采用来自汽轮机的蒸汽作为干燥热源。A further improvement of the present invention is that the biomass drying device uses steam from a steam turbine as a drying heat source.
本发明进一步的改进在于,生物质磨粉机是风扇磨,磨制后的干燥生物质颗粒和抗结渣剂制备桶中的抗结渣剂在生物质与抗结渣剂混合罐中混合,形成抗结渣生物质颗粒。A further improvement of the present invention is that the biomass pulverizer is a fan mill, and the dried biomass particles after grinding are mixed with the anti-slagging agent in the anti-slagging agent preparation tank in the biomass and anti-slagging agent mixing tank, Formation of anti-slagging biomass particles.
本发明进一步的改进在于,生物质磨粉机磨制后的干燥生物质颗粒和生物质与抗结渣剂混合罐中的抗结渣生物质颗粒分别作为引燃燃料和再燃燃料在锅炉底层燃烧器和再燃燃烧器的燃料喷嘴喷入炉膛,半焦磨粉机磨制后的半焦粉从锅炉中间层燃烧器的燃料喷嘴喷入炉膛,形成了“易燃燃料包难燃燃料”的分层燃烧布置方式。The further improvement of the present invention is that the dried biomass particles after the biomass pulverizer is ground and the anti-slagging biomass particles in the biomass and anti-slagging agent mixing tank are used as the pilot fuel and the reburning fuel respectively to burn at the bottom of the boiler The fuel nozzles of the burner and the reburning burner are sprayed into the furnace, and the semi-coke powder ground by the semi-coke pulverizer is sprayed into the furnace from the fuel nozzle of the burner in the middle layer of the boiler, forming a separation of "combustible fuel and difficult-to-combustible fuel". Layer combustion arrangement.
本发明进一步的改进在于,锅炉底层燃烧器的一次风喷嘴喷入经空气分离器分离得到的氧气,底层燃烧器的二次风喷嘴、中间层燃烧器的一二次风喷嘴及燃尽风喷嘴中喷入氧气和锅炉尾部循环烟气的混合气,再燃燃烧器的一二次风喷嘴喷入锅炉尾部除尘器后的循环烟气。The further improvement of the present invention is that the primary air nozzle of the bottom burner of the boiler injects the oxygen separated by the air separator; The mixture of oxygen and flue gas at the end of the boiler is sprayed into the middle, and the primary and secondary air nozzles of the reburning burner are injected into the flue gas after the dust collector at the end of the boiler.
本发明进一步的改进在于,从烟气冷凝器得到的冷凝水在化学处理装置中净化和除氧处理之后,作为锅炉补给水经补给水泵供给省煤器。The further improvement of the present invention is that the condensed water obtained from the flue gas condenser is purified and deoxidized in the chemical treatment device, and then supplied to the economizer as boiler feed water through a feed water pump.
一种半焦低NOx抗结渣掺烧的方法,该方法基于所述的一种半焦低NOx抗结渣掺烧的系统,包括:A semi-coke low NO x slagging-resistant co-firing method, the method is based on the semi-coke low-NO x slagging-resistant co-firing system, comprising:
生物质仓中的生物质经输送管道进入生物质烘干装置进行干燥,干燥的热源来源于汽轮机的部分抽汽;The biomass in the biomass bin enters the biomass drying device through the conveying pipeline for drying, and the heat source for drying comes from the partial steam extraction of the steam turbine;
干燥的生物质进入生物质磨粉机进行磨制,磨制完成的生物质颗粒部分作为引燃燃料从锅炉底层燃烧器的燃料喷嘴进入炉膛,经空气分离器分离得到的部分氧气从锅炉底层燃烧器的一次风喷嘴喷入炉膛,低着火点的生物质与高浓度氧气结合促进了燃料的着火和放热;燃烧所需二次风为锅炉尾部除尘器后的部分循环烟气与经空气分离器分离得到的氧气的混合气;半焦仓中的半焦经半焦磨粉机磨制后从锅炉中间层燃烧器的燃料喷嘴进入炉膛,燃烧所需一、二次风均为循环热烟气和氧气的混合气;The dried biomass enters the biomass pulverizer for grinding, and the biomass particles after grinding are used as pilot fuel to enter the furnace from the fuel nozzle of the burner at the bottom of the boiler, and part of the oxygen separated by the air separator is burned from the bottom of the boiler The primary air nozzle of the boiler is sprayed into the furnace, and the combination of biomass with low ignition point and high concentration of oxygen promotes the ignition and heat release of the fuel; the secondary air required for combustion is part of the circulating flue gas after the dust collector at the end of the boiler and the air separator The mixture of oxygen obtained by separation; the semi-coke in the semi-coke bin is ground by the semi-coke pulverizer and enters the furnace from the fuel nozzle of the burner in the middle layer of the boiler, and the primary and secondary air required for combustion are circulating hot flue gas Mixed gas with oxygen;
经生物质磨粉机磨制得到的剩余生物质颗粒进入生物质与抗结渣剂混合罐,制备抗结渣的生物质颗粒,将其作为再燃燃料从再燃燃烧器的燃料喷嘴进入炉膛,燃烧所需一、二次风均为锅炉尾部除尘器后的部分循环热烟气,抗结渣生物质颗粒在贫氧环境下再燃,降低灰的结渣率,以及降低燃烧过程中NOx的生成;The remaining biomass particles obtained by grinding by the biomass mill enter the mixing tank of biomass and anti-slagging agent to prepare anti-slagging biomass particles, which are used as reburning fuel and enter the furnace from the fuel nozzle of the reburning burner, and burn The required primary and secondary air are part of the circulating hot flue gas after the dust collector at the bottom of the boiler, and the anti-slagging biomass particles are reburned in an oxygen-poor environment, reducing the slagging rate of ash and reducing the formation of NO x during the combustion process ;
锅炉尾部循环热烟气和经空气分离器分离得到氧气的混合气从燃尽风喷嘴喷入炉膛,结合炉膛燃料深度分级、氧气分级和燃烧后期局部补氧,进一步降低了NOx的生成;The mixture of circulating hot flue gas at the tail of the boiler and oxygen separated by the air separator is sprayed into the furnace through the burn-off air nozzle, and combined with furnace fuel depth classification, oxygen classification and local oxygen supplementation in the later stage of combustion, the formation of NO x is further reduced;
完全燃烧后的烟气依次经过屏式过热器、对流过热器、省煤器、锅炉尾部除尘器、氧气预热器、脱硫装置、烟气冷凝器和CO2压缩装置,最终将CO2封存处理;The flue gas after complete combustion passes through the panel superheater, convection superheater, economizer, boiler tail dust collector, oxygen preheater, desulfurization device, flue gas condenser and CO2 compression device in sequence, and finally CO2 is stored and processed ;
经空气分离器分离得到的氧气在氧气预热器中预热后进入炉膛助燃,利用烟气余热的同时提高了锅炉效率;The oxygen separated by the air separator is preheated in the oxygen preheater and then enters the furnace to support combustion, which improves the efficiency of the boiler while utilizing the waste heat of the flue gas;
烟气冷凝器得到的冷凝水在化学处理装置中净化和除氧之后,作为锅炉补给水经补给水泵供给省煤器。After the condensed water obtained from the flue gas condenser is purified and deoxidized in the chemical treatment device, it is used as boiler feed water and supplied to the economizer through the feed water pump.
本发明进一步的改进在于,还包括:A further improvement of the present invention is to also include:
高温烟气将工质水加热至过热蒸汽状态,通过主蒸汽管道送入汽轮机中膨胀做功,驱动汽轮机转动,汽轮机带动发电机发电。The high-temperature flue gas heats the working medium water to the state of superheated steam, and sends it into the steam turbine through the main steam pipeline to expand and do work, driving the steam turbine to rotate, and the steam turbine drives the generator to generate electricity.
本发明进一步的改进在于,抗结渣剂为多孔陶瓷和白云石粉末的混合物,多孔陶瓷与白云石粉末的质量比为1:0.1-10,抗结渣剂粒径为生物质颗粒粒径的1/10-1/20,以保证抗结渣剂和生物质颗粒能同步悬浮于锅炉炉膛内燃烧。The further improvement of the present invention is that the anti-slagging agent is a mixture of porous ceramics and dolomite powder, the mass ratio of porous ceramics and dolomite powder is 1:0.1-10, and the particle size of the anti-slagging agent is the particle size of the
相对于现有技术,本发明至少具有如下有益的技术效果:Compared with the prior art, the present invention has at least the following beneficial technical effects:
本发明提供的一种半焦低NOx抗结渣掺烧的系统,其中半焦-生物质混燃系统采用分层掺混和富氧燃烧技术相结合的方式,利用除尘后的锅炉尾部热烟气和空气分离后制得纯氧的混合气代替助燃空气,且氧气浓度可根据燃烧器区域变化进行灵活调节,用布置在锅炉尾部除尘器之后的氧气预热器代替传统的空气预热器,充分利用了烟气余热;收集净化烟气凝结水作为锅炉补给水,变废为宝;抗结渣剂采用多孔陶瓷和白云石粉末的混合物,原料成分简单、成本低廉,且生物质抗结渣颗粒制作过程方便快捷,只需控制各成分粒径并掺混均匀,使其能同步悬浮于锅炉炉膛内进行燃烧。抗结渣剂不仅能通过提高生物质灰熔点而缓减结渣,其成分还有脱硫和吸附有害气体的功效。The present invention provides a semi-coke low NO x slagging-resistant blended combustion system, wherein the semi-coke-biomass co-combustion system adopts a combination of layered blending and oxygen-enriched combustion technology, and utilizes the hot smoke at the tail of the boiler after dust removal Gas and air are separated to produce pure oxygen mixed gas instead of combustion air, and the oxygen concentration can be flexibly adjusted according to the change of the burner area. The traditional air preheater is replaced by an oxygen preheater arranged after the dust collector at the end of the boiler. Make full use of the waste heat of the flue gas; collect and purify the condensed water of the flue gas as boiler feed water, turning waste into treasure; the anti-slagging agent is a mixture of porous ceramics and dolomite powder, the raw material composition is simple, the cost is low, and the biomass is anti-slagging The production process of particles is convenient and fast. It only needs to control the particle size of each component and mix them evenly, so that they can be suspended in the boiler furnace for combustion simultaneously. The anti-slagging agent can not only reduce slagging by increasing the melting point of biomass ash, but also has the effect of desulfurization and adsorption of harmful gases.
本发明提供的一种半焦低NOx抗结渣掺烧的方法,半焦与生物质掺烧过程中,采用“生物质抗结渣处理”、“炉内分层掺烧”、“燃料再燃”和“燃烧后期局部补氧”相结合的燃烧方式,将部分生物质作为引燃燃料在炉膛的底层燃烧器喷入,并利用纯氧作为一次风,高氧浓度环境和低着火点特征会促进生物质的着火放热,对应的区域形成着火区或助燃区,该区域温度较低,结渣和NOx生成均较少;将半焦在中间层燃烧器喷入,并将循环烟气和纯氧的混合气作为半焦的一、二次风,对应区域形成主燃区,该过程半焦可充分利用生物质燃烧放出的热量进行点燃,结合生物质含氮量低和富氧燃烧技术,可降低半焦NOx的生成,同时该区域生物质较少,结渣也较少;将剩余生物质进行抗结渣处理,该部分生物质作为再燃燃料经锅炉的再燃燃烧器喷入炉膛,将循环烟气作为一、二次风,对应的区域形成再燃区或气化区,适当降低的区域温度和抗结渣的生物质颗粒共同缓减了生物质的结渣,生物质颗粒以及生物质气化生成的还原性气体会还原半焦在主燃区生成的NOx;将循环烟气和纯氧的混合气作为燃尽风,保证了燃料的燃烧效率;氧气预热器结构简单,体积较小,且布置在锅炉尾部除尘器之后,较传统空气预热器节省材料,且充分利用了烟气的余热,整体提高了锅炉的效率;烟气凝结水经化学净化和除氧处理后作为锅炉补给水,节约了水资源。The invention provides a low NO x anti-slagging co-firing method for semi-coke. Combustion method combining "reburning" and "partial oxygen supplementation in the later stage of combustion", injecting part of biomass as pilot fuel into the bottom burner of the furnace, and using pure oxygen as primary air, high oxygen concentration environment and low ignition point characteristics will be Promote the ignition and heat release of biomass, and the corresponding area forms an ignition area or a combustion-supporting area. The temperature in this area is relatively low, and slagging and NOx generation are less; inject semi-coke into the middle layer burner, and circulate the flue gas The mixed gas with pure oxygen is used as the primary and secondary air of semi-coke, and the corresponding area forms the main combustion zone. During this process, semi-coke can be ignited by making full use of the heat released by biomass combustion, combined with low nitrogen content of biomass and oxygen-rich combustion technology, which can reduce the formation of semi-coke NOx , and at the same time, there is less biomass and less slagging in this area; the remaining biomass is subjected to anti-slagging treatment, and this part of biomass is injected as reburning fuel through the reburning burner of the boiler In the furnace, the circulating flue gas is used as the primary and secondary air, and the corresponding area forms a reburning zone or a gasification zone. The appropriately lowered regional temperature and the anti-slagging biomass particles jointly slow down the slagging of the biomass, and the biomass particles And the reducing gas generated by biomass gasification will reduce the NOx generated by the semi-coke in the main combustion zone; the mixture of circulating flue gas and pure oxygen is used as the exhaust air to ensure the combustion efficiency of the fuel; the structure of the oxygen preheater Simple, small in size, and arranged after the dust collector at the end of the boiler, it saves materials compared with the traditional air preheater, and makes full use of the waste heat of the flue gas, which improves the efficiency of the boiler as a whole; the condensed water of the flue gas is chemically purified and deoxidized After treatment, it is used as boiler make-up water, saving water resources.
综上所述,本发明解决了半焦和生物质单独燃烧时存在的诸多问题,实现了能量的充分、梯级利用,且不受地区和环境限制,系统简单可靠、经济环保,便于管理。To sum up, the present invention solves many problems existing in the separate combustion of semi-coke and biomass, realizes full and cascaded utilization of energy, and is not limited by regions and environments. The system is simple, reliable, economical and environmentally friendly, and easy to manage.
附图说明Description of drawings
图1为本发明的结构原理图。Fig. 1 is the structure schematic diagram of the present invention.
附图标记说明:Explanation of reference signs:
1为生物质仓,2为生物质烘干装置,3为生物质磨粉机,4为半焦仓,5为半焦磨粉机,6为抗结渣剂制备桶,7为生物质与抗结渣剂混合罐,8为空气分离器,9为混气器,10为循环风机,11为锅炉底层燃烧器,12为锅炉中间层燃烧器,13为再燃燃烧器,14为燃尽风喷嘴,15为屏式过热器,16为对流过热器,17为省煤器,18为锅炉尾部除尘器,19为氧气预热器,20为脱硫装置,21为烟气冷凝器,22为CO2压缩装置,23为化学处理装置,24为补给水泵,25为汽轮机,26为发电机,27为蒸汽泵。1 is the biomass bin, 2 is the biomass drying device, 3 is the biomass pulverizer, 4 is the semi-coke bin, 5 is the semi-coke pulverizer, 6 is the anti-slagging agent preparation barrel, 7 is the biomass and Anti-slagging agent mixing tank, 8 is the air separator, 9 is the gas mixer, 10 is the circulation fan, 11 is the bottom burner of the boiler, 12 is the middle layer burner of the boiler, 13 is the reburning burner, and 14 is the exhaust air Nozzle, 15 is panel superheater, 16 is convective superheater, 17 is economizer, 18 is boiler tail dust collector, 19 is oxygen preheater, 20 is desulfurization device, 21 is flue gas condenser, 22 is CO 2 is a compression device, 23 is a chemical treatment device, 24 is a feed water pump, 25 is a steam turbine, 26 is a generator, and 27 is a steam pump.
a为空气,b为氮气,c为氧气,d为压缩的CO2封存处置,e为循环烟气。a is air, b is nitrogen, c is oxygen, d is compressed CO2 storage and disposal, and e is circulating flue gas.
A为着火区或助燃区,B为主燃区,C为再燃区或气化区,D为燃尽区。A is the ignition zone or combustion-supporting zone, B is the main combustion zone, C is the reburning zone or gasification zone, and D is the burnout zone.
实线为半焦、生物质等固体输运路线,虚线为气体(烟气、蒸汽或氧气输运路线),双点划线为补给水输运路线。The solid line is the transportation route of semi-coke, biomass and other solids, the dotted line is the gas (flue gas, steam or oxygen transportation route), and the double-dotted line is the supply water transportation route.
具体实施方式Detailed ways
以下结合附图对本发明做进一步的详细说明The present invention will be described in further detail below in conjunction with accompanying drawing
如图1所示,本发明提供的一种半焦低NOx抗结渣掺烧的系统,包括半焦-生物质混燃系统和抗结渣生物质颗粒制备装置。As shown in Figure 1, the present invention provides a semi-coke low NO x anti-slagging blended combustion system, including a semi-coke-biomass co-combustion system and an anti-slagging biomass particle preparation device.
其中,半焦-生物质混燃系统包括生物质仓1、生物质烘干装置2、生物质磨粉机3、半焦仓4、半焦磨粉机5、锅炉底层燃烧器11、中间层燃烧器12、再燃燃烧器13、燃尽风喷嘴14、屏式过热器15、对流过热器16、省煤器17、锅炉尾部除尘器18、氧气预热器19、循环风机10、混气器9、汽轮机25、蒸汽泵27、燃尽风管道、热烟气管道和蒸汽管道。Among them, the semi-coke-biomass co-combustion system includes
抗结渣生物质颗粒制备装置包括抗结渣剂制备桶6和生物质与抗结渣剂混合罐7。The anti-slagging biomass particle preparation device includes an anti-slagging
生物质仓1通过输送管道与生物质烘干装置2的上入口相连,蒸汽泵24的入口与汽轮机22的抽汽管道相连,蒸汽泵27的出口与生物质烘干装置2的侧入口相连,生物质烘干装置2的出口与生物质磨粉机3的入口相连,生物质磨粉机3的出口与锅炉底层燃烧器11的燃料喷嘴相连;半焦仓4通过输送管道与半焦磨粉机5的入口相连,半焦磨粉机5的出口与锅炉中间层燃烧器12的燃料喷嘴相连。抗结渣剂制备桶6的出口与生物质与抗结渣剂混合罐7的入口相连,生物质与抗结渣剂混合罐7的出口与再燃燃烧器13的燃料喷嘴相连。The
锅炉尾部除尘器18后的部分热烟气通过烟气管道与循环风机10的入口相连,循环风机10的出口通过三通阀分别与再燃燃烧器13的进风喷嘴和混气器9的下入口相连,空气分离器8的入口接大气,下出口通过三通阀分别与锅炉底层燃烧器11的一次风喷嘴和混气器9的侧入口相连,混气器9的出口分别与锅炉底层燃烧器11的二次风喷嘴、中间层燃烧器12的一、二次风喷嘴及燃尽风喷嘴14相连。Part of the hot flue gas behind the
屏式过热器15、对流过热器16和省煤器17依次设置在烟气管道内,锅炉尾部除尘器18、氧气预热器19、脱硫装置20、烟气冷凝器21和CO2压缩装置22与烟气管道出口依次连接,烟气冷凝器21的冷凝水出口连接至化学处理装置23的入口,化学处理装置23的出口通过补给水泵24连接至省煤器17。
进一步的,生物质烘干装置2采用来自汽轮机25的蒸汽作为干燥热源。Further, the
进一步的,生物质磨粉机3是风扇磨,磨制后的干燥生物质颗粒和抗结渣剂在生物质与抗结渣剂混合罐7中混合,形成抗结渣生物质颗粒,抗结渣剂为多孔陶瓷和白云石粉末的混合物,多孔陶瓷与白云石粉末的质量比为1:0.1-10,其粒径为生物质颗粒粒径的1/10-1/20,以保证抗结渣剂和生物质颗粒能同步悬浮于锅炉炉膛内燃烧。Further, the
进一步的,生物质磨粉机3磨制后的干燥生物质颗粒和生物质与抗结渣剂混合罐7中的抗结渣生物质颗粒分别作为引燃燃料和再燃燃料在锅炉底层燃烧器11和再燃燃烧器13的燃料喷嘴喷入炉膛,半焦磨粉机5磨制后的半焦粉从锅炉中间层燃烧器12的燃料喷嘴喷入炉膛,形成“易燃燃料包难燃燃料”的分层燃烧布置方式。Further, the dry biomass particles ground by the
进一步的,锅炉底层燃烧器11的一次风喷嘴喷入经空气分离器8分离得到的氧气,底层燃烧器11的二次风喷嘴、中间层燃烧器12的一二次风喷嘴及燃尽风喷嘴14中喷入氧气和锅炉尾部循环烟气的混合气,再燃燃烧器13的一二次风喷嘴喷入锅炉尾部除尘器18后的循环烟气。Further, the primary air nozzle of the bottom burner 11 of the boiler injects the oxygen separated by the air separator 8, the secondary air nozzle of the bottom burner 11, the secondary air nozzle of the middle layer burner 12 and the exhaust air nozzle 14 is sprayed into the mixture of oxygen and boiler tail circulating flue gas, and the primary and secondary air nozzles of the reburning burner 13 are sprayed into the circulating flue gas after the boiler
进一步的,在锅炉尾部除尘器18后设置结构较传统烟气预热器简单的氧气预热器,利用除尘烟气的余热加热进入炉膛的氧气,减少了能量损失且提高锅炉效率。Furthermore, an oxygen preheater with a simpler structure than the traditional flue gas preheater is installed behind the
进一步的,从烟气冷凝器21得到的冷凝水在化学处理装置23中净化和除氧处理之后,作为锅炉补给水经补给水泵24供给省煤器17。Further, after the condensed water obtained from the
本发明一种超低挥发分碳基燃料和褐煤低NOx掺烧的方法,包括:The present invention relates to a method for co-firing ultra-low volatile carbon-based fuel and lignite with low NOx , comprising:
1)生物质仓1中的生物质经输送管道进入生物质烘干装置2进行干燥,干燥的热源来源于汽轮机的部分抽汽;1) The biomass in the
2)干燥的生物质进入生物质磨粉机3进行磨制,磨制完成的生物质颗粒部分作为引燃燃料从锅炉底层燃烧器11的燃料喷嘴进入炉膛,经空气分离器8分离得到的部分氧气从锅炉底层燃烧器11的一次风喷嘴喷入炉膛,低着火点的生物质与高浓度氧气结合促进了燃料的着火和放热;燃烧所需二次风为锅炉尾部除尘器18后的部分循环烟气与经空气分离器8分离得到的氧气的混合气;半焦仓4中的半焦经半焦磨粉机5磨制后从锅炉中间层燃烧器12的燃料喷嘴进入炉膛,燃烧所需一、二次风均为循环热烟气和氧气的混合气;2) The dried biomass enters the
3)经生物质磨粉机3磨制得到的剩余生物质颗粒进入生物质与抗结渣剂混合罐7,制备抗结渣的生物质颗粒,将其作为再燃燃料从再燃燃烧器13的燃料喷嘴进入炉膛,燃烧所需一、二次风均为锅炉尾部除尘器18后的部分循环热烟气,抗结渣生物质颗粒在贫氧环境下再燃不仅可以降低灰的结渣率,还能降低燃烧过程中SO2和NOx的生成;3) The remaining biomass particles obtained by grinding the
4)锅炉尾部循环热烟气和经空气分离器8分离得到氧气的混合气从燃尽风喷嘴14喷入炉膛,结合炉膛燃料深度分级、氧气分级和燃烧后期局部补氧,进一步降低了NOx的生成;4) The mixture of circulating hot flue gas at the tail of the boiler and oxygen separated by the air separator 8 is sprayed into the furnace from the overburning air nozzle 14, combined with furnace fuel depth classification, oxygen classification and local oxygen supplementation in the later stage of combustion, further reducing NO x generation;
5)完全燃烧后的烟气依次经过屏式过热器15、对流过热器16、省煤器17、锅炉尾部除尘器18、氧气预热器19、脱硫装置20、烟气冷凝器21和CO2压缩装置22,最终将CO2封存处理;5) Flue gas after complete combustion passes through
6)经空气分离器8分离得到的氧气在氧气预热器19中加热后进入炉膛助燃,利用烟气余热的同时提高了锅炉效率;6) The oxygen separated by the air separator 8 is heated in the
7)烟气冷凝器得到的冷凝水在化学处理装置23中净化和除氧之后,作为锅炉补给水经补给水泵24供给省煤器17。7) After the condensed water obtained by the flue gas condenser is purified and deoxidized in the
8)高温烟气将工质水加热至过热蒸汽状态,通过主蒸汽管道送入汽轮机25中膨胀做功,驱动汽轮机转动,汽轮机带动发电机26发电。8) The high-temperature flue gas heats the working medium water to the superheated steam state, and sends it into the
概括来说,本发明借助富氧燃烧技术和抗结渣生物质颗粒制备技术,将干燥的生物质颗粒和抗结渣生物质颗粒分别作为引燃燃料和再燃燃料与半焦在锅炉内形成“易燃燃料包难燃燃料”的分层掺烧方式,结合炉膛燃料氧气深度分级和燃烧后期局部补氧技术,炉膛从下到上分为着火/助燃区、主燃区、再燃/气化区和燃尽区四个燃烧区域。该系统设计既解决了半焦着火燃尽困难和NOx生成量大的问题,又克服了生物质碱金属含量高导致的严重结渣问题,同时降低了燃煤锅炉CO2的排放。本发明充分利用了不同品位能量,适应范围广,经济环保,便于管理。In a nutshell, the present invention utilizes oxygen-enriched combustion technology and anti-slagging biomass particle preparation technology to use dry biomass particles and anti-slagging biomass particles as pilot fuel and reburning fuel respectively and semi-coke to form " The layered blending method of flammable fuel including non-combustible fuel, combined with furnace fuel oxygen depth classification and local oxygen supplement technology in the later stage of combustion, the furnace is divided into ignition/combustion zone, main combustion zone, reburning/gasification zone from bottom to top and burnout zone four combustion zones. The system design not only solves the problems of difficult ignition and burnout of semi-coke and large amount of NOx , but also overcomes the serious slagging problem caused by high alkali metal content in biomass, and at the same time reduces the CO 2 emission of coal-fired boilers. The invention makes full use of energy of different grades, has wide adaptability, is economical and environment-friendly, and is convenient for management.
应理解,该实施例仅用于说明本发明而不用于限制本发明的范围。此外,还应理解,在阅读了本发明讲授的内容之后,本领域的技术人员可以对本发明做出各种改动或修改,然而,这些等价形式同样落于本申请所附权利要求书所限定的范围。It should be understood that this embodiment is only used to illustrate the present invention and is not intended to limit the scope of the present invention. In addition, it should also be understood that after reading the content taught by the present invention, those skilled in the art can make various changes or modifications to the present invention, however, these equivalent forms also fall within the limits of the appended claims of the present application range.
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