[go: up one dir, main page]

CN113119549A - 一种抗静电防辐射石墨烯改性纤维面料及其制备工艺 - Google Patents

一种抗静电防辐射石墨烯改性纤维面料及其制备工艺 Download PDF

Info

Publication number
CN113119549A
CN113119549A CN201911405876.3A CN201911405876A CN113119549A CN 113119549 A CN113119549 A CN 113119549A CN 201911405876 A CN201911405876 A CN 201911405876A CN 113119549 A CN113119549 A CN 113119549A
Authority
CN
China
Prior art keywords
parts
fiber fabric
modified fiber
graphene modified
spinning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911405876.3A
Other languages
English (en)
Inventor
俞建辉
朱文峰
季卫斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Lansiyu Home Textile Co ltd
Original Assignee
Jiangsu Lansiyu Home Textile Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Lansiyu Home Textile Co ltd filed Critical Jiangsu Lansiyu Home Textile Co ltd
Priority to CN201911405876.3A priority Critical patent/CN113119549A/zh
Publication of CN113119549A publication Critical patent/CN113119549A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D13/00—Complete machines for producing artificial threads
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/48—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0223—Vinyl resin fibres
    • B32B2262/0238—Vinyl halide, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B32B2262/0284—Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21—Anti-static
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/212—Electromagnetic interference shielding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/718—Weight, e.g. weight per square meter
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)

Abstract

本发明公开了一种抗静电防辐射石墨烯改性纤维面料，包括涤纶纤维层，所述涤纶纤维层上具有石墨烯改性纤维面料层。本发明中，以聚氯乙烯树脂为主要成分，添加了偶氮二甲酰胺以及适当的添加剂，具有机械强度高、柔韧性好的特点，同时有添加了芦荟凝胶，使得面料抗静电性能好，起到了抗静电的作用，该面料中还添加了纳米陶瓷吸收剂和纳米导电聚合物，纳米陶瓷吸收剂和纳米导电聚合物能够对电磁波进行很好的吸收，起到了抗辐射的作用，同时纳米陶瓷吸收剂和纳米导电聚合物还具有质量轻、耐高温和强度大的特点，提高了面料的整体性能，相比传统的石墨烯面料，综合性能更强。

Description

一种抗静电防辐射石墨烯改性纤维面料及其制备工艺
技术领域
本发明涉及纺织物技术领域，尤其涉及一种抗静电防辐射石墨烯改性纤维面料及其制备工艺。
背景技术
石墨烯作为一种高科技新材料，在许多领域都有着广阔的发展空间，利用生物质石墨烯制作成的床上用品是科技进步带给消费者的“红利”，舒适健康的亲肤体验或将会打开一个千亿级的产业新市场。随着经济的发展，纺织品应用领域不断地扩大，如何赋予纺织品更多的功能性，给人们的生产生活带来更多便利的同时，提高产品的核心竞争力，有着重要的现实意义。一种石墨烯生物质纤维面料，因为纬纱采用50D石墨烯生物质纤维，所以织物强力显著增加，达到棉纤维材料的2.2倍以上。
石墨烯面料是指石墨烯材料与普通纺织品有效结合，在保持纺织品各项基本性能的同时，具有石墨烯某一种或几种独特性质的面料纺织产品，但现有的石墨烯面料通常不具备抗静电防辐射的作用，使用起来存在不足。
因此，提出一种抗静电防辐射石墨烯改性纤维面料。
发明内容
本发明的目的在于：为了解决现有技术中的石墨烯面料不具备抗静电和抗辐射的功能的问题，而提出的一种抗静电防辐射石墨烯改性纤维面料及其制备工艺。
为了实现上述目的，本发明采用了如下技术方案：
一种抗静电防辐射石墨烯改性纤维面料，包括涤纶纤维层，所述涤纶纤维层上具有石墨烯改性纤维面料层，所述石墨烯改性纤维面料层由下列重量份的原料制成：聚氯乙烯树脂30-40份、偶氮二甲酰胺5-10份、芦荟凝胶5-10份、纳米陶瓷吸收剂3-6、纳米导电聚合物5-8、纳米甲壳素3-8、锗酸盐6-12份、氧化石墨烯8-15份、滑石粉7-10份、增塑剂3-5份。
作为上述技术方案的进一步描述：
所述涤纶纤维层为涤纶长丝编织而成。
作为上述技术方案的进一步描述：
所述涤纶纤维层在高温环境下上染抗菌助剂。
作为上述技术方案的进一步描述：
所述锗酸盐为锗酸钠、锗酸锌、锗酸铜中的其中一种。
作为上述技术方案的进一步描述：
一种抗静电防辐射石墨烯改性纤维面料的制备工艺，包括以下步骤：a.将聚氯乙烯树脂、偶氮二甲酰胺、滑石粉和增塑剂放置在搅拌机中进行搅拌，得到材料一；b.将纳米陶瓷吸收剂和纳米导电聚合物放入搅拌装置中进行搅拌，在搅拌的过程中添加芦荟凝胶和纳米甲壳素,得到材料二；c.将氧化石墨烯与锗酸盐粉碎，并混合得到材料三；d.将材料一和材料二混合后放置在双螺杆挤出机中，制成纺丝熔体；e.将纺丝熔体与材料三搅拌均匀，得改性的纺丝熔体；f.改性的纺丝熔体进行熔融纺丝，得到纺丝纤维；g.纺丝纤维再经水洗、漂白、干燥、纺织成面料，得到石墨烯改性纤维面料层；h.将石墨烯改性纤维面料层与涤纶纤维层采用大圆机织造，即得含石墨烯面料。
作为上述技术方案的进一步描述：
所述a步骤中的搅拌时间为10-20mhn。
作为上述技术方案的进一步描述：
所述b步骤中的搅拌时间为10-15mhn。
作为上述技术方案的进一步描述：
所述c步骤中的材料三在400-500目。
综上所述，由于采用了上述技术方案，本发明的有益效果是：
1、本发明中，以聚氯乙烯树脂为主要成分，添加了偶氮二甲酰胺以及适当的添加剂，具有机械强度高、柔韧性好的特点，同时有添加了芦荟凝胶，使得面料抗静电性能好，起到了抗静电的作用，该面料中还添加了纳米陶瓷吸收剂和纳米导电聚合物，纳米陶瓷吸收剂和纳米导电聚合物能够对电磁波进行很好的吸收，起到了抗辐射的作用，同时纳米陶瓷吸收剂和纳米导电聚合物还具有质量轻、耐高温和强度大的特点，提高了面料的整体性能，相比传统的石墨烯面料，综合性能更强。
2、本发明中，涤纶纤维层在高温环境下上染抗菌助剂，使得该面料具有抗菌、抑菌的作用，提高了该面料的保健性。
3、本发明中，添加了纳米甲壳素，增加了该纤维面料的强度，改善了手感和耐水性，使得面料的手感更加柔软。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其它实施例，都属于本发明保护的范围。
实施例1
一种抗静电防辐射石墨烯改性纤维面料，包括涤纶纤维层，涤纶纤维层为涤纶长丝编织而成，涤纶纤维层在高温环境下上染抗菌助剂，涤纶纤维层上具有石墨烯改性纤维面料层，石墨烯改性纤维面料层由下列重量份的原料制成：聚氯乙烯树脂30份、偶氮二甲酰胺5份、芦荟凝胶5份、纳米陶瓷吸收剂3、纳米导电聚合物5、纳米甲壳素3、锗酸盐6份、氧化石墨烯8份、滑石粉7份、增塑剂3份，锗酸盐为锗酸钠、锗酸锌、锗酸铜中的其中一种。
一种抗静电防辐射石墨烯改性纤维面料的制备工艺，包括以下步骤：
a.将聚氯乙烯树脂、偶氮二甲酰胺、滑石粉和增塑剂放置在搅拌机中进行搅拌，得到材料一，b.将纳米陶瓷吸收剂和纳米导电聚合物放入搅拌装置中进行搅拌，在搅拌的过程中添加芦荟凝胶和纳米甲壳素,得到材料二，c.将氧化石墨烯与锗酸盐粉碎，并混合得到材料三，d.将材料一和材料二混合后放置在双螺杆挤出机中，制成纺丝熔体，e.将纺丝熔体与材料三搅拌均匀，得改性的纺丝熔体，f.改性的纺丝熔体进行熔融纺丝，得到纺丝纤维，g.纺丝纤维再经水洗、漂白、干燥、纺织成面料，得到石墨烯改性纤维面料层，h.将石墨烯改性纤维面料层与涤纶纤维层采用大圆机织造，即得含石墨烯面料。
实施例2
一种抗静电防辐射石墨烯改性纤维面料，包括涤纶纤维层，涤纶纤维层为涤纶长丝编织而成，涤纶纤维层在高温环境下上染抗菌助剂，涤纶纤维层上具有石墨烯改性纤维面料层，石墨烯改性纤维面料层由下列重量份的原料制成：聚氯乙烯树脂25份、偶氮二甲酰胺6份、芦荟凝胶7份、纳米陶瓷吸收剂4、纳米导电聚合物6、纳米甲壳素5、锗酸盐8份、氧化石墨烯9份、滑石粉8份、增塑剂4份，锗酸盐为锗酸钠、锗酸锌、锗酸铜中的其中一种。
一种抗静电防辐射石墨烯改性纤维面料的制备工艺，包括以下步骤：
a.将聚氯乙烯树脂、偶氮二甲酰胺、滑石粉和增塑剂放置在搅拌机中进行搅拌，得到材料一，b.将纳米陶瓷吸收剂和纳米导电聚合物放入搅拌装置中进行搅拌，在搅拌的过程中添加芦荟凝胶和纳米甲壳素,得到材料二，c.将氧化石墨烯与锗酸盐粉碎，并混合得到材料三，d.将材料一和材料二混合后放置在双螺杆挤出机中，制成纺丝熔体，e.将纺丝熔体与材料三搅拌均匀，得改性的纺丝熔体，f.改性的纺丝熔体进行熔融纺丝，得到纺丝纤维，g.纺丝纤维再经水洗、漂白、干燥、纺织成面料，得到石墨烯改性纤维面料层，h.将石墨烯改性纤维面料层与涤纶纤维层采用大圆机织造，即得含石墨烯面料。
实施例3
一种抗静电防辐射石墨烯改性纤维面料，包括涤纶纤维层，涤纶纤维层为涤纶长丝编织而成，涤纶纤维层在高温环境下上染抗菌助剂，涤纶纤维层上具有石墨烯改性纤维面料层，石墨烯改性纤维面料层由下列重量份的原料制成：聚氯乙烯树脂38份、偶氮二甲酰胺8份、芦荟凝胶9份、纳米陶瓷吸收剂5、纳米导电聚合物7、纳米甲壳素6、锗酸盐10份、氧化石墨烯13份、滑石粉9份、增塑剂4份，锗酸盐为锗酸钠、锗酸锌、锗酸铜中的其中一种。
一种抗静电防辐射石墨烯改性纤维面料的制备工艺，包括以下步骤：
a.将聚氯乙烯树脂、偶氮二甲酰胺、滑石粉和增塑剂放置在搅拌机中进行搅拌，得到材料一，b.将纳米陶瓷吸收剂和纳米导电聚合物放入搅拌装置中进行搅拌，在搅拌的过程中添加芦荟凝胶和纳米甲壳素,得到材料二，c.将氧化石墨烯与锗酸盐粉碎，并混合得到材料三，d.将材料一和材料二混合后放置在双螺杆挤出机中，制成纺丝熔体，e.将纺丝熔体与材料三搅拌均匀，得改性的纺丝熔体，f.改性的纺丝熔体进行熔融纺丝，得到纺丝纤维，g.纺丝纤维再经水洗、漂白、干燥、纺织成面料，得到石墨烯改性纤维面料层，h.将石墨烯改性纤维面料层与涤纶纤维层采用大圆机织造，即得含石墨烯面料。
实施例4
一种抗静电防辐射石墨烯改性纤维面料，包括涤纶纤维层，涤纶纤维层为涤纶长丝编织而成，涤纶纤维层在高温环境下上染抗菌助剂，涤纶纤维层上具有石墨烯改性纤维面料层，石墨烯改性纤维面料层由下列重量份的原料制成：聚氯乙烯树脂40份、偶氮二甲酰胺10份、芦荟凝胶10份、纳米陶瓷吸收剂6、纳米导电聚合物8、纳米甲壳素8、锗酸盐12份、氧化石墨烯15份、滑石粉10份、增塑剂5份，锗酸盐为锗酸钠、锗酸锌、锗酸铜中的其中一种。
一种抗静电防辐射石墨烯改性纤维面料的制备工艺，包括以下步骤：
a.将聚氯乙烯树脂、偶氮二甲酰胺、滑石粉和增塑剂放置在搅拌机中进行搅拌，得到材料一，b.将纳米陶瓷吸收剂和纳米导电聚合物放入搅拌装置中进行搅拌，在搅拌的过程中添加芦荟凝胶和纳米甲壳素,得到材料二，c.将氧化石墨烯与锗酸盐粉碎，并混合得到材料三，d.将材料一和材料二混合后放置在双螺杆挤出机中，制成纺丝熔体，e.将纺丝熔体与材料三搅拌均匀，得改性的纺丝熔体，f.改性的纺丝熔体进行熔融纺丝，得到纺丝纤维，g.纺丝纤维再经水洗、漂白、干燥、纺织成面料，得到石墨烯改性纤维面料层，h.将石墨烯改性纤维面料层与涤纶纤维层采用大圆机织造，即得含石墨烯面料。
下面对各实施例的性能进行测试，其结果列于表1中：
表1
Figure BDA0002348606370000071
从表1中可以看出，实施例1-4中的面料具有优异的抗静电和抗辐射性能。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (8)

1.一种抗静电防辐射石墨烯改性纤维面料，其特征在于，包括涤纶纤维层，所述涤纶纤维层上具有石墨烯改性纤维面料层，所述石墨烯改性纤维面料层由下列重量份的原料制成：聚氯乙烯树脂30-40份、偶氮二甲酰胺5-10份、芦荟凝胶5-10份、纳米陶瓷吸收剂3-6、纳米导电聚合物5-8、纳米甲壳素3-8、锗酸盐6-12份、氧化石墨烯8-15份、滑石粉7-10份、增塑剂3-5份。
2.根据权利要求1所述的一种抗静电防辐射石墨烯改性纤维面料，其特征在于，所述涤纶纤维层为涤纶长丝编织而成。
3.根据权利要求1所述的一种抗静电防辐射石墨烯改性纤维面料，其特征在于，所述锗酸盐为锗酸钠、锗酸锌、锗酸铜中的其中一种。
4.根据权利要求1所述的一种抗静电防辐射石墨烯改性纤维面料，其特征在于，所述涤纶纤维层在高温环境下上染抗菌助剂。
5.根据权利要求1-4所述的一种抗静电防辐射石墨烯改性纤维面料的制备工艺，其特征在于，包括以下步骤：
a.将聚氯乙烯树脂、偶氮二甲酰胺、滑石粉和增塑剂放置在搅拌机中进行搅拌，得到材料一；
b.将纳米陶瓷吸收剂和纳米导电聚合物放入搅拌装置中进行搅拌，在搅拌的过程中添加芦荟凝胶和纳米甲壳素,得到材料二；
c.将氧化石墨烯与锗酸盐粉碎，并混合得到材料三；
d.将材料一和材料二混合后放置在双螺杆挤出机中，制成纺丝熔体；
e.将纺丝熔体与材料三搅拌均匀，得改性的纺丝熔体；
f.改性的纺丝熔体进行熔融纺丝，得到纺丝纤维；
g.纺丝纤维再经水洗、漂白、干燥、纺织成面料，得到石墨烯改性纤维面料层；
h.将石墨烯改性纤维面料层与涤纶纤维层采用大圆机织造，即得含石墨烯面料。
6.根据权利要求5所述的一种抗静电防辐射石墨烯改性纤维面料的制备工艺，其特征在于，所述a步骤中的搅拌时间为10-20mhn。
7.根据权利要求5所述的一种抗静电防辐射石墨烯改性纤维面料的制备工艺，其特征在于，所述b步骤中的搅拌时间为10-15mhn。
8.根据权利要求5所述的一种抗静电防辐射石墨烯改性纤维面料的制备工艺，其特征在于，所述c步骤中的材料三在400-500目。
CN201911405876.3A 2019-12-30 2019-12-30 一种抗静电防辐射石墨烯改性纤维面料及其制备工艺 Pending CN113119549A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911405876.3A CN113119549A (zh) 2019-12-30 2019-12-30 一种抗静电防辐射石墨烯改性纤维面料及其制备工艺

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911405876.3A CN113119549A (zh) 2019-12-30 2019-12-30 一种抗静电防辐射石墨烯改性纤维面料及其制备工艺

Publications (1)

Publication Number Publication Date
CN113119549A true CN113119549A (zh) 2021-07-16

Family

ID=76768713

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911405876.3A Pending CN113119549A (zh) 2019-12-30 2019-12-30 一种抗静电防辐射石墨烯改性纤维面料及其制备工艺

Country Status (1)

Country Link
CN (1) CN113119549A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116103828A (zh) * 2022-10-25 2023-05-12 东莞市凯信针织有限公司 一种石墨烯防辐射面料及其生产工艺

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103952792A (zh) * 2014-04-18 2014-07-30 安徽省中日农业环保科技有限公司 一种导磁、防静电艾叶纤维面料及其制备方法
CN103966689A (zh) * 2014-04-23 2014-08-06 安徽依采妮纤维材料科技有限公司 一种抗静电竹纤维面料及其制备方法
CN107119466A (zh) * 2017-05-11 2017-09-01 佛山高明骏腾塑胶有限公司 一种抗紫外线pvc人造革及其制备方法
CN110079924A (zh) * 2019-05-09 2019-08-02 常熟市大发经编织造有限公司 一种含石墨烯面料及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103952792A (zh) * 2014-04-18 2014-07-30 安徽省中日农业环保科技有限公司 一种导磁、防静电艾叶纤维面料及其制备方法
CN103966689A (zh) * 2014-04-23 2014-08-06 安徽依采妮纤维材料科技有限公司 一种抗静电竹纤维面料及其制备方法
CN107119466A (zh) * 2017-05-11 2017-09-01 佛山高明骏腾塑胶有限公司 一种抗紫外线pvc人造革及其制备方法
CN110079924A (zh) * 2019-05-09 2019-08-02 常熟市大发经编织造有限公司 一种含石墨烯面料及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116103828A (zh) * 2022-10-25 2023-05-12 东莞市凯信针织有限公司 一种石墨烯防辐射面料及其生产工艺

Similar Documents

Publication Publication Date Title
EP3378978B1 (en) Modified fiber and preparation method therefor
CN109938419A (zh) 排汗裸感三重抑菌内裤及其制备方法
CN104963048A (zh) 一种具有防辐射功效的混纺再生棉纱及其制备方法
CN113119549A (zh) 一种抗静电防辐射石墨烯改性纤维面料及其制备工艺
CN201713643U (zh) 一种新型的防辐射面料
CN108823667A (zh) 多元素协效阻燃剂及再生阻燃纤维素纤维的制造工艺
CN206244975U (zh) 一种防水抗静电纱线
CN110699963B (zh) 一种防水、耐刮婴儿推车挂包面料及其制备方法
CN111020815A (zh) 一种具有屏蔽电磁波、永久阻燃且无熔滴被芯面料及其制备方法
CN114277493B (zh) 一种纳米抗皱面料及其制备方法
CN106087443B (zh) 一种含竹活性炭粉的可降解环保机织粘合衬及其制备工艺
KR100622684B1 (ko) 기능성 폴리염화비닐 세사의 제조방법
CN103680656A (zh) 一种防辐射纤维布料的制作工艺
Khamrayeva et al. Development of a New Blended Fabric on the RIFA-RFJW-10 Machine and Performance Analysis
CN113308760A (zh) 一种防电磁辐射自净式多功能面料及制备方法
CN113699795A (zh) 一种长效抗静电锁温面料及其制备方法
CN106751582A (zh) 一种聚酯‑聚乙烯双组份纤维用着色母料及其制备方法
CN111560690A (zh) 一种阻燃型弹性纺织面料及其加工方法
CN104562665B (zh) 一种耐酸碱阻燃蚕丝的制备方法
CN201049992Y (zh) 羊毛与改性涤纶混纺呢绒面料
CN205893785U (zh) 一种含竹活性炭粉的可降解环保机织粘合衬
CN215512705U (zh) 一种高弹性抗菌复合经编面料
CN115928254B (zh) 一种抗静电纤维毛条及其制备方法
CN101824665A (zh) 多功能远红外ptt扁平长丝的制备方法
CN109778399A (zh) 一种含竹纤维的混纺羊绒衫织造方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20210716