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CN113097358B - Light-emitting diode and method of making the same - Google Patents

Light-emitting diode and method of making the same Download PDF

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CN113097358B
CN113097358B CN202110347588.8A CN202110347588A CN113097358B CN 113097358 B CN113097358 B CN 113097358B CN 202110347588 A CN202110347588 A CN 202110347588A CN 113097358 B CN113097358 B CN 113097358B
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layer
type
back electrode
protrusion
metal
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CN113097358A (en
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徐洲
吴奇隆
马英杰
蔡和勋
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Xiamen Changelight Co Ltd
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Xiamen Changelight Co Ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/84Coatings, e.g. passivation layers or antireflective coatings
    • H10H20/841Reflective coatings, e.g. dielectric Bragg reflectors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/01Manufacture or treatment
    • H10H20/011Manufacture or treatment of bodies, e.g. forming semiconductor layers
    • H10H20/013Manufacture or treatment of bodies, e.g. forming semiconductor layers having light-emitting regions comprising only Group III-V materials
    • H10H20/0133Manufacture or treatment of bodies, e.g. forming semiconductor layers having light-emitting regions comprising only Group III-V materials with a substrate not being Group III-V materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/81Bodies
    • H10H20/819Bodies characterised by their shape, e.g. curved or truncated substrates
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/83Electrodes
    • H10H20/831Electrodes characterised by their shape
    • H10H20/8312Electrodes characterised by their shape extending at least partially through the bodies
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/83Electrodes
    • H10H20/831Electrodes characterised by their shape
    • H10H20/8316Multi-layer electrodes comprising at least one discontinuous layer
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/01Manufacture or treatment
    • H10H20/032Manufacture or treatment of electrodes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/01Manufacture or treatment
    • H10H20/034Manufacture or treatment of coatings

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Abstract

本发明提供了一种发光二极管及其制作方法,所述ODR反射镜层包括金属反射层及位于所述金属反射层背离所述背电极一侧的介质膜层,其中,所述ODR反射镜层包括多个第一通孔或多个第二通孔;所述P型窗口层包括主体层及与所述主体层相连的多个第一凸起或多个第二凸起,所述第一凸起位于所述第一通孔内且与所述金属反射层形成欧姆接触,所述第二凸起位于所述第二通孔内且与所述金属键合层形成欧姆接触。本发明制作发光二极管时采用Lift‑off工艺实现P型窗口层的凸起与ODR反射镜层的自对准。本发明提供的技术方案,保证发光二极管的可靠性高,同时能够解决填充金属材料所带来的制备成本高、工艺流程复杂的问题。

Figure 202110347588

The present invention provides a light-emitting diode and a manufacturing method thereof. The ODR mirror layer includes a metal reflection layer and a dielectric film layer located on the side of the metal reflection layer away from the back electrode, wherein the ODR reflection mirror layer including a plurality of first through holes or a plurality of second through holes; the P-type window layer includes a main body layer and a plurality of first protrusions or a plurality of second protrusions connected with the main body layer, the first The protrusion is located in the first through hole and forms an ohmic contact with the metal reflective layer, and the second protrusion is located in the second through hole and forms an ohmic contact with the metal bonding layer. The present invention adopts Lift-off process to realize the self-alignment of the protrusion of the P-type window layer and the ODR reflecting mirror layer when manufacturing the light-emitting diode. The technical scheme provided by the present invention ensures high reliability of the light emitting diode, and at the same time can solve the problems of high preparation cost and complicated process flow caused by filling metal materials.

Figure 202110347588

Description

Light emitting diode and manufacturing method thereof
Technical Field
The invention relates to the technical field of semiconductor devices, in particular to a light emitting diode and a manufacturing method thereof.
Background
With the development of the light emitting diode technology, the existing light emitting diode is widely applied to the fields of electronics, optics and the like, and has a great deal of development in the aspects of illumination, display and digital code. In addition, as the application of LEDs (Light Emitting diodes) is gradually expanded, the market demand for LED performance is higher and higher. Therefore, the reliability of the light emitting diode is to be improved.
Disclosure of Invention
In view of this, the present invention provides a light emitting diode and a method for manufacturing the same, which effectively solve the technical problems in the prior art and improve the reliability of the light emitting diode.
In order to achieve the purpose, the technical scheme provided by the invention is as follows:
a light emitting diode comprising:
a back electrode;
a conductive substrate on one side of the back electrode;
the metal bonding layer is positioned on one side, away from the back electrode, of the conductive substrate;
the ODR reflector layer is positioned on one side, away from the back electrode, of the metal bonding layer and comprises a metal reflecting layer and a dielectric film layer positioned on one side, away from the back electrode, of the metal reflecting layer, wherein the ODR reflector layer comprises a plurality of first through holes or a plurality of second through holes, the first through holes penetrate through the dielectric film layer from one side, away from the back electrode, of the ODR reflector layer, and the second through holes penetrate through the laminated layer of the dielectric film layer and the metal reflecting layer from one side, away from the back electrode, of the ODR reflector layer;
the epitaxial layer is positioned on one side, away from the back electrode, of the ODR reflector layer and comprises a P-type window layer facing one side of the back electrode, the P-type window layer comprises a main body layer and a plurality of first bulges or a plurality of second bulges connected with the main body layer, the first bulges are positioned in the first through holes and form ohmic contact with the metal reflecting layer, and the second bulges are positioned in the second through holes and form ohmic contact with the metal bonding layer;
and the positive electrode is positioned on one side of the epitaxial layer, which is far away from the back electrode.
Optionally, the doping concentration of the first protrusion and the second protrusion is greater than the doping concentration of the body layer.
Optionally, when the ODR mirror layer includes the first through hole, the metal reflective layer is an Au metal reflective layer;
when the ODR reflector layer comprises the second through hole, the metal reflecting layer is an Ag metal reflecting layer, and the metal bonding layer is an Au metal bonding layer.
Optionally, the thickness of the P-type window layer ranges from 0.1 to 11 μm, inclusive.
Optionally, the exposed surface of the epitaxial layer is a roughened surface.
Optionally, the epitaxial layer includes the P-type window layer;
the P-type limiting layer is positioned on one side, away from the back electrode, of the P-type window layer;
the active layer is positioned on one side, away from the back electrode, of the P-type limiting layer;
the N-type limiting layer is positioned on one side, away from the back electrode, of the active layer;
the N-type current expansion layer is positioned on one side, away from the back electrode, of the N-type limiting layer;
the N-type rough layer is positioned on one side, away from the back electrode, of the N-type current expansion layer;
and the N-type ohmic contact layer is positioned on one side, deviating from the back electrode, of the N-type rough layer, and the positive electrode is positioned on one side, deviating from the back electrode, of the N-type ohmic contact layer.
Optionally, the epitaxial layer is an AlGaInP-based epitaxial layer, and the P-type window layer is a P-type GaP window layer;
or, the epitaxial layer is an AlGaAs-based epitaxial layer, the P-type window layer comprises a superposed P-type AlGaAs current expansion layer and a P-type GaP ohmic contact layer, wherein the first protrusion and the second protrusion are formed by the P-type GaP ohmic contact layer, and the main body layer is the P-type AlGaAs current expansion layer.
Correspondingly, the invention also provides a manufacturing method of the light-emitting diode, which comprises the following steps:
sequentially epitaxially growing a buffer layer, a corrosion stop layer and an epitaxial layer on a temporary substrate, wherein a P-type window layer is arranged on one side of the epitaxial layer, which is far away from the temporary substrate;
forming a photoresist layer on one side of the P-type window layer, which is far away from the temporary substrate, wherein the photoresist layers are distributed in a mutually independent point shape;
etching the surface layer of the P-type window layer to form a structure which comprises a main body layer and a plurality of first bulges or a plurality of second bulges, wherein the plurality of first bulges or the plurality of second bulges are connected with the main body layer and correspond to the photoresist layer;
forming an ODR reflector layer on one side, away from the temporary substrate, of the P-type window layer, wherein the ODR reflector layer comprises a dielectric film layer and a metal reflecting layer located on one side, away from the temporary substrate, of the dielectric film layer, when the P-type window layer comprises the first protrusion, the dielectric film layer is formed, then the photoresist layer and redundant dielectric film layer materials on the photoresist layer are stripped through a Lift-off process, and the first protrusion and the metal reflecting layer form ohmic contact; when the P-type window layer comprises the second protrusion, after the dielectric film layer and the metal reflecting layer are formed, stripping the photoresist layer and redundant dielectric film layer materials and redundant metal reflecting layer materials on the photoresist layer by a Lift-off process;
forming a first sub-metal bonding layer on one side, away from the temporary substrate, of the ODR reflector layer, wherein when the P-type window layer comprises the second protrusion, the second protrusion forms ohmic contact with the first sub-metal bonding layer;
bonding the conductive substrate with the second sub-metal bonding layer formed on the surface with the first sub-metal bonding layer to form a metal bonding layer comprising the first sub-metal bonding layer and the second sub-metal bonding layer;
removing the temporary substrate, the buffer layer and the corrosion stop layer;
and forming a positive electrode on one side of the epitaxial layer, which is far away from the conductive substrate, and forming a back electrode on one side of the conductive substrate, which is far away from the epitaxial layer.
Optionally, the doping concentration of the first protrusion and the second protrusion is greater than the doping concentration of the body layer.
Optionally, when the P-type window layer includes the first protrusion, the metal reflective layer is an Au metal reflective layer;
when the P-type window layer comprises the second protrusion, the metal reflecting layer is an Ag metal reflecting layer, and the metal bonding layer is an Au metal bonding layer.
Compared with the prior art, the technical scheme provided by the invention at least has the following advantages:
the invention provides a light-emitting diode and a manufacturing method thereof, wherein an ODR reflector layer comprises a metal reflecting layer and a dielectric film layer positioned on one side of the metal reflecting layer, which is far away from a back electrode, wherein the ODR reflector layer comprises a plurality of first through holes or a plurality of second through holes, the first through holes penetrate through the dielectric film layer from the side, which is far away from the back electrode, of the ODR reflector layer, and the second through holes penetrate through the lamination of the dielectric film layer and the metal reflecting layer from the side, which is far away from the back electrode, of the ODR reflector layer; the P-type window layer comprises a main body layer and a plurality of first bulges or a plurality of second bulges connected with the main body layer, the first bulges are positioned in the first through holes and form ohmic contact with the metal reflecting layer, and the second bulges are positioned in the second through holes and form ohmic contact with the metal bonding layer. And when the light-emitting diode is manufactured, the self-alignment of the protrusion of the P-type window layer and the ODR reflector layer is realized by adopting a Lift-off process. Therefore, the P-type window layer provided by the invention respectively and correspondingly realizes ohmic contact with the metal reflecting layer or the metal bonding layer through the first protrusion or the second protrusion, the condition that metal faults in the through hole are generated when metal materials are filled in the through hole to realize ohmic contact is avoided, the high reliability of the light-emitting diode is ensured, and the problems of high preparation cost and complex process flow caused by filling the metal materials can be solved.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the provided drawings without creative efforts.
Fig. 1 is a schematic structural diagram of a light emitting diode according to an embodiment of the present invention;
fig. 2 is a schematic structural diagram of another light emitting diode according to an embodiment of the present invention;
fig. 3 is a schematic structural diagram of another light emitting diode according to an embodiment of the present invention;
fig. 4 is a schematic structural diagram of another light emitting diode according to an embodiment of the present invention;
fig. 5 is a flowchart of a method for manufacturing a light emitting diode according to an embodiment of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
As mentioned in the background, as the application of LED (Light Emitting Diode) is gradually expanded, the market demand for LED performance is higher and higher. Therefore, the reliability of the light emitting diode is to be improved.
Therefore, the embodiment of the invention provides the light-emitting diode and the manufacturing method thereof, which effectively solve the technical problems in the prior art and improve the reliability of the light-emitting diode.
To achieve the above object, the technical solutions provided by the embodiments of the present invention are described in detail below with reference to fig. 1 to 5.
As shown in fig. 1, which is a schematic structural diagram of a light emitting diode according to an embodiment of the present invention, the light emitting diode includes:
a back electrode 100.
A conductive substrate 200 at one side of the back electrode 100.
A metal bonding layer 300 on a side of the conductive substrate 200 facing away from the back electrode 100.
The ODR mirror layer 400 is located on a side of the metal bonding layer 300 away from the back electrode 100, where the ODR mirror layer 400 includes a metal reflective layer 410 and a dielectric film layer 420 located on a side of the metal reflective layer 410 away from the back electrode, and the ODR mirror layer 400 includes a plurality of first through holes penetrating through the dielectric film layer 420 from a side of the ODR mirror layer 400 away from the back electrode 100.
The epitaxial layer 500 is located on a side of the ODR mirror layer 400 away from the back electrode 100, the epitaxial layer 500 includes a P-type window layer 510 facing the back electrode 100, the P-type window layer 510 includes a main body layer 511 and a plurality of first protrusions 512 connected to the main body layer 511, and the first protrusions 512 are located in the first through holes and form ohmic contact with the metal reflective layer 410.
And the positive electrode 600 is positioned at the side of the epitaxial layer 500, which is far away from the back electrode 100, wherein the occupied area of the positive electrode 600 is smaller than the area of the surface of the side of the epitaxial layer 500, which is far away from the back electrode 100.
Referring to fig. 1, the P-type window layer 510 provided by the embodiment of the invention may form an ohmic contact with the metal reflective layer 410, that is, the depth of the first through hole is the same as the height of the first protrusion 512, that is, the height of the first protrusion 512 is the same as the thickness of the dielectric film layer 420; and, when the ODR mirror layer 400 provided by the embodiment of the present invention includes the first through hole, the metal reflective layer 410 may be an Au metal reflective layer.
Or, the P-type window layer provided by the embodiment of the present invention may also form an ohmic contact with the metal bonding layer, that is, the depth of the second through hole is the same as the height of the second protrusion, that is, the height of the second protrusion is the same as the stacking thickness of the dielectric film layer and the metal reflective layer; and when the ODR mirror layer provided in the embodiment of the present invention includes the second through hole, the metal reflective layer is an Ag metal reflective layer, and the metal bonding layer is an Au metal bonding layer. Specifically, as shown in fig. 2, a schematic structural diagram of a light emitting diode provided in an embodiment of the present invention is shown, where the light emitting diode includes:
a back electrode 100.
A conductive substrate 200 at one side of the back electrode 100.
A metal bonding layer 300 on a side of the conductive substrate 200 facing away from the back electrode 100.
The ODR mirror layer 400 is located on a side of the metal bonding layer 300 facing away from the back electrode 100, where the ODR mirror layer 400 includes a metal reflective layer 410 and a dielectric film layer 420 located on a side of the metal reflective layer 410 facing away from the back electrode, and the ODR mirror layer 400 includes a plurality of second through holes penetrating through a stack of the dielectric film layer 420 and the metal reflective layer 410 from a side of the ODR mirror layer 400 facing away from the back electrode 100.
The epitaxial layer 500 is located on the side of the ODR mirror layer 400 departing from the back electrode 100, the epitaxial layer 500 includes a P-type window layer 510 facing the side of the back electrode 100, the P-type window layer includes a main body layer 511 and a plurality of second protrusions 513 connected to the main body layer, and the second protrusions 513 are located in the second through holes and form ohmic contact with the metal bonding layer 300.
And a positive electrode 600 located on a side of the epitaxial layer 500 facing away from the back electrode 100.
As can be seen from the above, in the technical solution provided in the embodiment of the present invention, the ODR mirror layer includes a metal reflective layer and a dielectric film layer located on a side of the metal reflective layer away from the back electrode, where the ODR mirror layer includes a plurality of first through holes or a plurality of second through holes, the first through holes penetrate through the dielectric film layer from the side of the ODR mirror layer away from the back electrode, and the second through holes penetrate through a stack of the dielectric film layer and the metal reflective layer from the side of the ODR mirror layer away from the back electrode; the P-type window layer comprises a main body layer and a plurality of first bulges or a plurality of second bulges connected with the main body layer, the first bulges are positioned in the first through holes and form ohmic contact with the metal reflecting layer, and the second bulges are positioned in the second through holes and form ohmic contact with the metal bonding layer. Therefore, the P-type window layer provided by the embodiment of the invention respectively and correspondingly realizes ohmic contact with the metal reflecting layer or the metal bonding layer through the first protrusion or the second protrusion, thereby avoiding the occurrence of metal faults in the through hole when the metal material is filled in the through hole to realize ohmic contact, ensuring high reliability of the light-emitting diode, and simultaneously solving the problems of high preparation cost and complex process flow caused by filling the metal material.
In an embodiment of the invention, the doping concentration of the first protrusion and the second protrusion provided by the invention is greater than the doping concentration of the body layer. Wherein the doping concentration of the first and second protrusions may be greater than or equal to 1E19/cm3And of the body layerThe doping concentration may be greater than or equal to 1E18/cm3. Optionally, the thickness of the P-type window layer provided by the embodiment of the present invention may be in a range of 0.1 to 11 μm, inclusive.
It can be understood that, in the P-type window layer provided by the embodiment of the invention, the high-doping concentration region is formed only at the first protrusion and the second protrusion, and the low-doping concentration region is formed at the body layer, so that the protrusion and the metal structure are ensured to form good ohmic contact, the problem of light absorption on the surface of the high-doping P-type window layer is avoided, and the light extraction efficiency of the light emitting diode is improved.
In an embodiment of the invention, the exposed surface of the epitaxial layer provided by the invention is a roughened surface. As shown in fig. 3, a schematic structural diagram of another light emitting diode according to an embodiment of the present invention is provided, wherein an exposed surface of the epitaxial layer 500 is a roughened surface, so as to further ensure high light extraction efficiency of the light emitting diode.
Fig. 4 is a schematic structural diagram of another light emitting diode according to an embodiment of the present invention, wherein the epitaxial layer 500 includes the P-type window layer 510.
And the P-type limiting layer 520 is positioned on the side, facing away from the back electrode 100, of the P-type window layer 510.
And the active layer 530 is positioned on the side, away from the back electrode 100, of the P-type confinement layer 520, and the active layer 530 is a multi-quantum well active layer.
And an N-type confinement layer 540 on a side of the active layer 530 facing away from the back electrode 100.
An N-type current spreading layer 550 located on a side of the N-type confinement layer 540 facing away from the back electrode 100.
An N-type roughened layer 560 on a side of the N-type current spreading layer 550 facing away from the back electrode 100.
And an N-type ohmic contact layer 570 on a side of the N-type roughened layer 560 facing away from the back electrode 100, where the N-type ohmic contact layer 570 may be an N-type GaAs ohmic contact layer, and the positive electrode 600 is located on a side of the N-type ohmic contact layer 570 facing away from the back electrode 100.
In an embodiment of the invention, the epitaxial layer provided by the invention may be an AlGaInP-based epitaxial layer, wherein the P-type confinement layer, the N-type current spreading layer and the N-type roughened layer are all structural layers made of AlGaInP materials, and components in each structural layer made of AlGaInP materials may be specifically adjusted according to practical applications. The P-type window layer is a P-type GaP window layer, namely the first protrusion, the second protrusion and the main body layer are all made of P-type GaP materials; the thickness of the P-type window layer can be 0.1-10 μm inclusive, and specifically can be 1-3 μm inclusive.
Alternatively, the epitaxial layer provided in the embodiment of the present invention may also be an AlGaAs-based epitaxial layer, where the P-type confinement layer, the N-type current spreading layer, and the N-type coarse layer are all structural layers made of AlGaAs material, and components in each structural layer made of AlGaAs material may be specifically adjusted according to actual applications. And the P-type window layer comprises a superposed P-type AlGaAs current expansion layer and a P-type GaP ohmic contact layer, wherein the first protrusion and the second protrusion are formed by the P-type GaP ohmic contact layer, and the main body layer is the P-type AlGaAs current expansion layer. Optionally, the thickness of the P-type AlGaAs current spreading layer may range from 0.9 to 9.9 μm, inclusive, and may specifically be 3 μm; the thickness of the P-type GaP ohmic contact layer may range from 0.1 to 1 μm, inclusive, and may specifically be 0.2 μm.
Correspondingly, the embodiment of the invention also provides a manufacturing method of the light-emitting diode. As shown in fig. 5, a flowchart of a method for manufacturing a light emitting diode according to an embodiment of the present invention is provided, where the method includes:
s1, sequentially epitaxially growing a buffer layer, a corrosion stop layer and an epitaxial layer on the temporary substrate, wherein a P-type window layer is arranged on one side, away from the temporary substrate, of the epitaxial layer.
In an embodiment of the invention, the temporary substrate provided by the invention may be a GaAs temporary substrate, the buffer layer may be an N-type GaAs buffer layer, and the etch stop layer may be an N-type GaInP etch stop layer. The epitaxial layer may be an AlGaInP-based epitaxial layer or an AlGaAs-based epitaxial layer, and the present invention is not particularly limited thereto.
And S2, forming a photoresist layer on one side of the P-type window layer, which is far away from the temporary substrate, wherein the photoresist layers are distributed in a mutually independent point shape.
It can be understood that the mutually independent point-like photoresist layers are photoresist patterns for defining a plurality of first protrusions or a plurality of second protrusions.
S3, etching the surface layer of the P-type window layer to form a structure which comprises a main body layer and a plurality of first bulges or a plurality of second bulges, wherein the first bulges or the second bulges are connected with the main body layer and correspond to the photoresist layer.
It can be understood that the photoresist layer is used as a mask, and a material with a certain thickness, which is not covered by the P-type window layer, of the photoresist layer is removed through a dry etching process or a wet etching process to form the body layer and the first protrusion or the second protrusion.
S4, forming an ODR reflector layer on one side, away from the temporary substrate, of the P-type window layer, wherein the ODR reflector layer comprises a dielectric film layer and a metal reflecting layer located on one side, away from the temporary substrate, of the dielectric film layer, and when the P-type window layer comprises the first protrusion, after the dielectric film layer is formed, the photoresist layer and redundant dielectric film layer materials on the photoresist layer are stripped through a Lift-off process, and the first protrusion and the metal reflecting layer form ohmic contact; and when the P-type window layer comprises the second protrusion, after the dielectric film layer and the metal reflecting layer are formed, stripping the photoresist layer and redundant dielectric film layer materials and redundant metal reflecting layer materials on the photoresist layer by a Lift-off process.
In an embodiment of the invention, the thickness of the dielectric film provided by the invention can be obtained according to (2k +1) λ/4n, where k is 0 or a positive integer, λ is the light-emitting wavelength of the light-emitting diode, and n is the refractive index of the material of the dielectric film. Wherein the dielectric film layer may be MgF2The present invention is not particularly limited.
S5, forming a first sub-metal bonding layer on the side, away from the temporary substrate, of the ODR reflector layer, wherein when the P-type window layer comprises the second protrusion, the second protrusion forms ohmic contact with the first sub-metal bonding layer.
In an embodiment of the invention, the metal reflective layer and the first sub-metal bonding layer provided by the invention can be formed by an evaporation process. Meanwhile, an annealing process is adopted to enable the metal reflecting layer to form ohmic contact with the first protrusion, or the annealing process is adopted to enable the first sub-metal bonding layer to form ohmic contact with the second protrusion.
And S6, bonding the conductive substrate with the second sub-metal bonding layer on the surface with the first sub-metal bonding layer to form a metal bonding layer comprising the first sub-metal bonding layer and the second sub-metal bonding layer.
In an embodiment of the present invention, the conductive substrate provided in the present invention may be a P-type low-resistance silicon wafer, and the present invention is not particularly limited.
And S7, removing the temporary substrate, the buffer layer and the corrosion stop layer.
In an embodiment of the present invention, the epitaxial layer provided by the present invention may include an N-type ohmic contact layer. After the corrosion stop layer is removed, the N-type ohmic contact layer can be subjected to patterning treatment to form an N-type ohmic contact pattern, and then an N-type electrode, namely a positive electrode, is prepared through subsequent photoetching, evaporation, stripping and annealing processes.
S8, forming a positive electrode on the side, away from the conductive substrate, of the epitaxial layer, and forming a back electrode on the side, away from the epitaxial layer, of the conductive substrate.
Optionally, after the positive electrode is formed on the conductive substrate, if the sheet source is required to be split, the reserved cutting channel can be etched to the P-type window layer through a photoetching or dry etching process; then, the exposed surface of the epitaxial layer can be further subjected to roughening treatment to form a roughened surface; then, grinding and thinning the conductive substrate, and preparing a P-type electrode, namely preparing a back electrode, by a lattice evaporation annealing process; finally, the wafer source can be divided into independent light emitting diodes through tangent, back cut and splitting procedures, which are the same as the prior art, so redundant description is not needed in the invention.
In an embodiment of the invention, the doping concentration of the first protrusion and the second protrusion provided by the invention is greater than the doping concentration of the body layer.
And when the P-type window layer provided by the embodiment of the invention comprises the first protrusion, the metal reflecting layer is an Au metal reflecting layer. When the P-type window layer provided by the embodiment of the invention comprises the second protrusion, the metal reflecting layer is an Ag metal reflecting layer, and the metal bonding layer is an Au metal bonding layer.
The embodiment of the invention provides a light-emitting diode and a manufacturing method thereof, wherein an ODR reflector layer comprises a metal reflecting layer and a dielectric film layer positioned on one side of the metal reflecting layer, which is far away from a back electrode, wherein the ODR reflector layer comprises a plurality of first through holes or a plurality of second through holes, the first through holes penetrate through the dielectric film layer from the side, which is far away from the back electrode, of the ODR reflector layer, and the second through holes penetrate through a lamination of the dielectric film layer and the metal reflecting layer from the side, which is far away from the back electrode, of the ODR reflector layer; the P-type window layer comprises a main body layer and a plurality of first bulges or a plurality of second bulges connected with the main body layer, the first bulges are positioned in the first through holes and form ohmic contact with the metal reflecting layer, and the second bulges are positioned in the second through holes and form ohmic contact with the metal bonding layer. And when the embodiment of the invention is used for manufacturing the light-emitting diode, the Lift-off process is adopted to realize the self-alignment of the bulge of the P-type window layer and the ODR reflector layer. Therefore, the P-type window layer provided by the embodiment of the invention respectively and correspondingly realizes ohmic contact with the metal reflecting layer or the metal bonding layer through the first protrusion or the second protrusion, thereby avoiding the occurrence of metal faults in the through hole when the metal material is filled in the through hole to realize ohmic contact, ensuring high reliability of the light-emitting diode, and simultaneously solving the problems of high preparation cost and complex process flow caused by filling the metal material.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (10)

1.一种发光二极管,其特征在于,包括:1. A light-emitting diode, characterized in that, comprising: 背电极;back electrode; 位于所述背电极一侧的导电衬底;a conductive substrate on one side of the back electrode; 位于所述导电衬底背离所述背电极一侧的金属键合层;a metal bonding layer on the side of the conductive substrate facing away from the back electrode; 位于所述金属键合层背离所述背电极一侧的ODR反射镜层,所述ODR反射镜层包括金属反射层及位于所述金属反射层背离所述背电极一侧的介质膜层,其中,所述ODR反射镜层包括多个第一通孔或多个第二通孔,所述第一通孔自所述ODR反射镜层背离所述背电极一侧起透过所述介质膜层,所述第二通孔自所述ODR反射镜层背离所述背电极一侧起透过所述介质膜层和所述金属反射层的叠层;an ODR mirror layer located on the side of the metal bonding layer away from the back electrode, the ODR mirror layer comprising a metal reflection layer and a dielectric film layer located on the side of the metal reflection layer away from the back electrode, wherein , the ODR mirror layer includes a plurality of first through holes or a plurality of second through holes, and the first through holes pass through the dielectric film layer from the side of the ODR mirror layer away from the back electrode , the second through hole passes through the stack of the dielectric film layer and the metal reflective layer from the side of the ODR mirror layer away from the back electrode; 位于所述ODR反射镜层背离所述背电极一侧的外延层,所述外延层包括朝向所述背电极一侧的P型窗口层,所述P型窗口层包括主体层及与所述主体层相连的多个第一凸起或多个第二凸起,所述第一凸起位于所述第一通孔内且与所述金属反射层形成欧姆接触,所述第二凸起位于所述第二通孔内且与所述金属键合层形成欧姆接触;An epitaxial layer located on the side of the ODR mirror layer away from the back electrode, the epitaxial layer includes a P-type window layer facing the back electrode side, and the P-type window layer includes a main body layer and the main body A plurality of first bumps or a plurality of second bumps connected to the layers, the first bumps are located in the first through holes and form ohmic contact with the metal reflective layer, and the second bumps are located in the first through holes. forming ohmic contact with the metal bonding layer in the second through hole; 及位于所述外延层背离所述背电极一侧的正电极。and a positive electrode on the side of the epitaxial layer facing away from the back electrode. 2.根据权利要求1所述的发光二极管,其特征在于,所述第一凸起和所述第二凸起的掺杂浓度大于所述主体层的掺杂浓度。2 . The light emitting diode according to claim 1 , wherein the doping concentration of the first protrusion and the second protrusion is greater than the doping concentration of the main body layer. 3 . 3.根据权利要求1所述的发光二极管,其特征在于,所述ODR反射镜层包括所述第一通孔时,所述金属反射层为Au金属反射层;3 . The light-emitting diode according to claim 1 , wherein when the ODR mirror layer includes the first through hole, the metal reflection layer is an Au metal reflection layer; 3 . 所述ODR反射镜层包括所述第二通孔时,所述金属反射层为Ag金属反射层,所述金属键合层为Au金属键合层。When the ODR mirror layer includes the second through hole, the metal reflection layer is an Ag metal reflection layer, and the metal bonding layer is an Au metal bonding layer. 4.根据权利要求1所述的发光二极管,其特征在于,所述P型窗口层的厚度范围为0.1-11μm,包括端点值。4 . The light emitting diode according to claim 1 , wherein the thickness of the P-type window layer ranges from 0.1 to 11 μm, inclusive. 5 . 5.根据权利要求1所述的发光二极管,其特征在于,所述外延层的裸露表面为粗化表面。5 . The light emitting diode of claim 1 , wherein the exposed surface of the epitaxial layer is a roughened surface. 6 . 6.根据权利要求1所述的发光二极管,其特征在于,所述外延层包括所述P型窗口层;6. The light emitting diode according to claim 1, wherein the epitaxial layer comprises the P-type window layer; 位于所述P型窗口层背离所述背电极一侧的P型限制层;a P-type confinement layer on the side of the P-type window layer away from the back electrode; 位于所述P型限制层背离所述背电极一侧的有源层;an active layer on the side of the P-type confinement layer away from the back electrode; 位于所述有源层背离所述背电极一侧的N型限制层;an N-type confinement layer located on the side of the active layer facing away from the back electrode; 位于所述N型限制层背离所述背电极一侧的N型电流扩展层;an N-type current spreading layer located on the side of the N-type confinement layer away from the back electrode; 位于所述N型电流扩展层背离所述背电极一侧的N型粗化层;an N-type roughening layer located on the side of the N-type current spreading layer away from the back electrode; 及位于所述N型粗化层背离所述背电极一侧的N型欧姆接触层,所述正电极位于所述N型欧姆接触层背离所述背电极一侧。and an N-type ohmic contact layer located on the side of the N-type roughened layer facing away from the back electrode, and the positive electrode is located on the side of the N-type ohmic contact layer facing away from the back electrode. 7.根据权利要求1所述的发光二极管,其特征在于,所述外延层为AlGaInP基外延层,所述P型窗口层为P型GaP窗口层;7. The light-emitting diode according to claim 1, wherein the epitaxial layer is an AlGaInP-based epitaxial layer, and the P-type window layer is a P-type GaP window layer; 或者,所述外延层为AlGaAs基外延层,所述P型窗口层包括叠加的P型AlGaAs电流扩展层和P型GaP欧姆接触层,其中,所述第一凸起和所述第二凸起由所述P型GaP欧姆接触层形成,且所述主体层为所述P型AlGaAs电流扩展层。Alternatively, the epitaxial layer is an AlGaAs-based epitaxial layer, the P-type window layer includes a superimposed P-type AlGaAs current spreading layer and a P-type GaP ohmic contact layer, wherein the first protrusion and the second protrusion are It is formed by the P-type GaP ohmic contact layer, and the main body layer is the P-type AlGaAs current spreading layer. 8.一种发光二极管的制作方法,其特征在于,包括:8. A method for manufacturing a light-emitting diode, comprising: 在临时衬底上依次外延生长缓冲层、腐蚀截止层和外延层,所述外延层背离所述临时衬底一侧为P型窗口层;epitaxially growing a buffer layer, an etching stop layer and an epitaxial layer in sequence on the temporary substrate, the side of the epitaxial layer facing away from the temporary substrate is a P-type window layer; 对所述P型窗口层背离所述临时衬底一侧形成光刻胶层,所述光刻胶层呈相互独立的点状分布;forming a photoresist layer on the side of the P-type window layer away from the temporary substrate, and the photoresist layer is distributed in a dot shape independent of each other; 对所述P型窗口层的表层进行刻蚀,形成包括主体层及与所述主体层相连、且对应所述光刻胶层的多个第一凸起或多个第二凸起的结构;etching the surface layer of the P-type window layer to form a structure including a main body layer and a plurality of first protrusions or a plurality of second protrusions connected to the main body layer and corresponding to the photoresist layer; 在所述P型窗口层背离所述临时衬底一侧形成ODR反射镜层,所述ODR反射镜层包括介质膜层及位于所述介质膜层背离所述临时衬底一侧的金属反射层,其中,所述P型窗口层包括所述第一凸起时,形成所述介质膜层后,通过Lift-off工艺剥离所述光刻胶层及光刻胶层上多余介质膜层材料,所述第一凸起与所述金属反射层形成欧姆接触;所述P型窗口层包括所述第二凸起时,形成所述介质膜层及所述金属反射层后,通过Lift-off工艺剥离所述光刻胶层及光刻胶层上多余介质膜层材料和多余金属反射层材料;An ODR mirror layer is formed on the side of the P-type window layer away from the temporary substrate, and the ODR mirror layer includes a dielectric film layer and a metal reflection layer on the side of the dielectric film layer away from the temporary substrate , wherein, when the P-type window layer includes the first protrusion, after the dielectric film layer is formed, the photoresist layer and the excess dielectric film material on the photoresist layer are peeled off by a Lift-off process, The first protrusion forms an ohmic contact with the metal reflection layer; when the P-type window layer includes the second protrusion, after the dielectric film layer and the metal reflection layer are formed, a Lift-off process is performed. peeling off the photoresist layer and the excess dielectric film layer material and excess metal reflective layer material on the photoresist layer; 在所述ODR反射镜层背离所述临时衬底一侧形成第一子金属键合层,其中,所述P型窗口层包括所述第二凸起时,所述第二凸起与所述第一子金属键合层形成欧姆接触;A first sub-metal bonding layer is formed on the side of the ODR mirror layer facing away from the temporary substrate, wherein when the P-type window layer includes the second protrusion, the second protrusion is connected to the second protrusion. The first sub-metal bonding layer forms an ohmic contact; 将表面形成有第二子金属键合层的导电衬底与所述第一子金属键合层键合,形成包括第一子金属键合层和第二子金属键合层的金属键合层;Bonding the conductive substrate with the second sub-metal bonding layer formed on the surface thereof and the first sub-metal bonding layer to form a metal bonding layer including the first sub-metal bonding layer and the second sub-metal bonding layer ; 去除所述临时衬底、缓冲层和腐蚀截止层;removing the temporary substrate, buffer layer and etch stop layer; 在所述外延层背离所述导电衬底一侧形成正电极,及在所述导电衬底背离所述外延层一侧形成背电极。A positive electrode is formed on the side of the epitaxial layer facing away from the conductive substrate, and a back electrode is formed on the side of the conductive substrate facing away from the epitaxial layer. 9.根据权利要求8所述的发光二极管的制作方法,其特征在于,所述第一凸起和所述第二凸起的掺杂浓度大于所述主体层的掺杂浓度。9 . The manufacturing method of the light emitting diode according to claim 8 , wherein the doping concentration of the first protrusion and the second protrusion is greater than the doping concentration of the main body layer. 10 . 10.根据权利要求8所述的发光二极管的制作方法,其特征在于,所述P型窗口层包括第一凸起时,所述金属反射层为Au金属反射层;10 . The manufacturing method of a light emitting diode according to claim 8 , wherein when the P-type window layer includes the first protrusion, the metal reflection layer is an Au metal reflection layer; 10 . 所述P型窗口层包括第二凸起时,所述金属反射层为Ag金属反射层,所述金属键合层为Au金属键合层。When the P-type window layer includes the second protrusion, the metal reflection layer is an Ag metal reflection layer, and the metal bonding layer is an Au metal bonding layer.
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