CN113046639A - 460 MPa-grade hot-rolled steel for ship structure and manufacturing method thereof - Google Patents
460 MPa-grade hot-rolled steel for ship structure and manufacturing method thereof Download PDFInfo
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
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- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
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- B21B37/00—Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
- B21B37/74—Temperature control, e.g. by cooling or heating the rolls or the product
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- C22C33/04—Making ferrous alloys by melting
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
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- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B2001/225—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length by hot-rolling
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Abstract
The invention discloses 460 MPa-grade hot-rolled steel for a ship structure and a manufacturing method thereof, which relate to the technical field of steel production and comprise the following chemical components in percentage by mass: c: 0.04 to 0.07 percent of Si: 0.20-0.30%, Mn: 1.55 to 1.75 percent of Nb, less than or equal to 0.012 percent of P, less than or equal to 0.0020 percent of S, and the weight ratio of Nb: 0.030-0.050%, V: 0.020-0.040%, Ti: 0.006-0.020%, Cr: 0.10% -0.30%, Ni: 0.30-0.40%, Mo is less than or equal to 0.10%, Cu: 0.20-0.30%, Al: 0.005-0.015%, Mg: 0.0008 to 0.0015 percent, less than or equal to 0.0005 percent of B, less than or equal to 0.0050 percent of N, no Ca, and the balance of Fe and inevitable impurities. Microalloying improves the cleanliness of molten steel, and a TMCP rolling process is adopted to obtain a steel plate mainly based on acicular ferrite, thereby meeting the performance requirements of the steel for high-strength wide and thick ship plates.
Description
Technical Field
The invention relates to the technical field of steel production, in particular to 460 MPa-grade hot-rolled steel for a ship body structure and a manufacturing method thereof.
Background
The rapid development of economy drives the vigorous development of the marine transportation industry, the development process of ships towards large-scale and high-speed is accelerated continuously, large-scale transportation ships need weldable and formable steel plates with high strength, high toughness and thick specifications, and the development of steel plates with high grade and excellent welding performance requirements becomes the trend of future development. The problems of strength reduction of a welding area, unqualified flaw detection of a welding and heat affected zone and the like frequently occur in the using process of the steel for the thick-specification ship plate, and the problem is brought to product development.
Disclosure of Invention
Aiming at the technical problems, the invention overcomes the defects of the prior art and provides 460 MPa-grade hot-rolled steel for ship structure, which comprises the following chemical components in percentage by mass: c: 0.04 to 0.07 percent of Si: 0.20-0.30%, Mn: 1.55 to 1.75 percent of Nb, less than or equal to 0.012 percent of P, less than or equal to 0.0020 percent of S, and the weight ratio of Nb: 0.030-0.050%, V: 0.020-0.040%, Ti: 0.006-0.020%, Cr: 0.10% -0.30%, Ni: 0.30-0.40%, Mo is less than or equal to 0.10%, Cu: 0.20-0.30%, Al: 0.005-0.015%, Mg: 0.0008 to 0.0015 percent, less than or equal to 0.0005 percent of B, less than or equal to 0.0050 percent of N, no Ca, and the balance of Fe and inevitable impurities.
The technical scheme of the invention is further defined as follows:
the 460 MPa-grade hot-rolled steel for the ship structure comprises the following chemical components in percentage by mass: c: 0.04-0.06%, Si: 0.20-0.30%, Mn: 1.55 to 1.65 percent of Nb, less than or equal to 0.010 percent of P, less than or equal to 0.0020 percent of S, and the mass percent of Nb: 0.030-0.040%, V: 0.030-0.040%, Ti: 0.006-0.018%, Cr: 0.10% -0.20%, Ni: 0.30-0.35%, Mo is less than or equal to 0.10%, Cu: 0.20-0.25%, Al: 0.005-0.013%, Mg: 0.0008 to 0.0013 percent, less than or equal to 0.0005 percent of B, less than or equal to 0.0050 percent of N, no Ca, and the balance of Fe and inevitable impurities.
The 460 MPa-grade hot-rolled steel for the ship structure comprises the following chemical components in percentage by mass: c: 0.045% -0.065%, Si: 0.20-0.30%, Mn: 1.60-1.70%, P is less than or equal to 0.011%, S is less than or equal to 0.0015%, Nb: 0.035% -0.045%, V: 0.025-0.035%, Ti: 0.008-0.018%, Cr: 0.15% -0.25%, Ni: 0.31-0.38%, Mo is less than or equal to 0.10%, Cu: 0.22-0.28%, Al: 0.006% -0.013%, Mg: 0.0009 to 0.0015 percent, less than or equal to 0.0005 percent of B, less than or equal to 0.0050 percent of N, no Ca, and the balance of Fe and inevitable impurities.
The 460 MPa-grade hot-rolled steel for the ship structure comprises the following chemical components in percentage by mass: c: 0.05 to 0.07 percent, Si: 0.20-0.30%, Mn: 1.65-1.75%, P is less than or equal to 0.010%, S is less than or equal to 0.0010%, Nb: 0.040% -0.050%, V: 0.030-0.040%, Ti: 0.008-0.020%, Cr: 0.20-0.30%, Ni: 0.35-0.40%, Mo is less than or equal to 0.10%, Cu: 0.25-0.30%, Al: 0.006-0.015%, Mg: 0.0009 to 0.0015 percent, less than or equal to 0.0005 percent of B, less than or equal to 0.0050 percent of N, no Ca, and the balance of Fe and inevitable impurities.
Another object of the present invention is to provide a method for manufacturing a 460 MPa-grade hot-rolled steel for a ship hull structure, comprising:
smelting by adopting an alkaline converter, carrying out LF slagging desulfurization and carrying out vacuum degassing treatment to obtain pure killed steel;
casting by a continuous casting machine, wherein the casting blank is low-power B0.5 grade or better;
and heating the casting blank to 1150-1250 ℃, the rough rolling temperature is 1080-1160 ℃, the secondary opening temperature is 750-850 ℃, the final rolling temperature is 750-820 ℃, the water inlet temperature is 730-760 ℃ and the red returning temperature is 590-630 ℃ through a heating furnace after surface detection.
The manufacturing method of the 460 MPa-grade hot-rolled steel for the ship structure has the advantage that the thickness of a steel plate product is 50-100 mm.
The manufacturing method of the 460 MPa-grade hot-rolled steel for the ship structure adopts a 260-320 mm section arc continuous casting machine.
The invention has the beneficial effects that:
(1) aiming at the characteristics of the steel for the thick-specification ship plate, the microalloying component design is carried out, the cleanliness of the product is improved, the center segregation of a casting blank is reduced, fine-grained acicular ferrite is formed in the rolling process, the grain size of the structure is refined, and the service performance of the steel for the high-strength thick-wall-specification ship plate is improved;
(2) according to the invention, a magnesium microalloying technology is adopted, and the inclusions are effectively modified through vacuum treatment, so that most of nano-scale micro inclusions smaller than 10 mu m are formed in a casting blank, the nano-scale micro inclusions become nucleation quality for structure transformation again in the welding process, and a structure type mainly comprising acicular ferrite is formed in the cooling process, so that the purity of molten steel is effectively improved, and the product performance is effectively improved;
(3) the invention adopts the magnesium alloying technology, reduces the harm of sulfur in steel, effectively spheroidizes A-type inclusions, and improves the internal quality of the steel;
(4) the low-carbon and low-phosphorus and sulfur design is beneficial to improving the core quality of the casting blank and improving the weldability of the product;
(5) the high manganese design is beneficial to refining the structure grain size and promoting the generation of acicular ferrite, the use of Nb, V and Ti is beneficial to refining the structure grain size, the magnesium alloying technology is combined with TMCP rolling and other means, the traditional aluminum refining mode is replaced in the structure grain refinement, the product grain is finer, and the molten steel is cleaner;
(6) the use of Cr, Ni and Cu in the invention is beneficial to improving the strength of products and the strength of welding areas after welding;
(7) the invention adopts thick casting blank section production, which is beneficial to improving the compression ratio, refining the structure grain size and improving the product strength, and the TMCP rolling process is beneficial to refining the structure grain size and promoting the production of acicular ferrite.
Drawings
FIG. 1 is a metallographic structure diagram of example 1 of the present invention.
Detailed Description
Example 1
The 460 MPa-grade hot-rolled steel for ship structure provided by the embodiment has a product thickness of 55mm, and comprises the following chemical components by mass percent: c: 0.046%, Si: 0.23%, Mn: 1.56%, P: 0.008%, S: 0.0012%, Nb: 0.033%, V: 0.039%, Ti: 0.016%, Cr: 0.12%, Ni: 0.31%, Mo: 0.10%, Cu: 0.23%, Al: 0.009%, Mg: 0.0011%, B: 0.0002%, N: 0.0033%, Ca is not added, and the balance is Fe and inevitable impurities.
The steel sheet manufacturing method includes:
smelting by adopting an alkaline converter, carrying out LF slagging desulfurization and carrying out vacuum degassing treatment to obtain low-carbon, low-phosphorus and low-sulfur pure killed steel;
casting by adopting an arc-shaped continuous casting machine with a section of 260mm, wherein the casting blank is low-power B0.5 grade;
after the surface inspection of the casting blank, the casting blank is heated to 1180 ℃ by a heating furnace, the rough rolling temperature is 1110 ℃, the secondary opening temperature is 836 ℃, the final rolling temperature is 815 ℃, the temperature of the entering water is 755 ℃, and the temperature of the re-reddening is 610 ℃.
Example 2
The 460 MPa-grade hot-rolled steel for ship structure provided by the embodiment has a product thickness of 70mm, and comprises the following chemical components by mass percent: c: 0.051%, Si: 0.21%, Mn: 1.67%, P: 0.010%, S: 0.0013%, Nb: 0.039%, V: 0.0295%, Ti: 0.009%, Cr: 0.19%, Ni: 0.37%, Mo: 0.008%, Cu: 0.26%, Al: 0.007%, Mg: 0.0013%, B: 0.0003%, N: 0.0039%, Ca is not added, and the balance is Fe and inevitable impurities.
The steel sheet manufacturing method includes:
smelting by adopting an alkaline converter, carrying out LF slagging desulfurization and carrying out vacuum degassing treatment to obtain low-carbon, low-phosphorus and low-sulfur pure killed steel;
casting by using a 320mm section arc continuous casting machine, wherein the casting blank is C0.5 grade;
after surface inspection, the casting blank is heated to 1171 ℃ by a heating furnace, the rough rolling temperature is 1096 ℃, the secondary opening temperature is 789 ℃, the final rolling temperature is 773 ℃, the water inlet temperature is 750 ℃ and the re-reddening temperature is 603 ℃.
Example 3
The 460 MPa-grade hot-rolled steel for ship structure provided by the embodiment has a product thickness of 86mm, and comprises the following chemical components in percentage by mass: c: 0.069%, Si: 0.29%, Mn: 1.73%, P: 0.006%, S: 0.0009%, Nb: 0.049%, V: 0.036%, Ti: 0.013%, Cr: 0.29%, Ni: 0.39%, Mo: 0.009%, Cu: 0.29%, Al: 0.011%, Mg: 0.0012%, B: 0.0001%, N: 0.0043%, Ca is not added, and the balance is Fe and inevitable impurities.
The steel sheet manufacturing method includes:
smelting by adopting an alkaline converter, carrying out LF slagging desulfurization and carrying out vacuum degassing treatment to obtain low-carbon, low-phosphorus and low-sulfur pure killed steel;
casting by using a 320mm section arc continuous casting machine, wherein the casting blank is of a C1.0 level;
and heating the casting blank to 1215 ℃ through a heating furnace after surface detection, wherein the rough rolling temperature is 1150 ℃, the secondary opening temperature is 778 ℃, the final rolling temperature is 760 ℃, the water inlet temperature is 745 ℃, and the re-reddening temperature is 598 ℃.
The results of the mechanical property tests of the products of example 1, example 2 and example 3 are shown in the following table:
the steel plate of the invention adopts a microalloying process to obtain pure molten steel of nano-scale oxides, and a rolling cooling process is adopted to obtain the steel plate mainly comprising acicular ferrite, as shown in figure 1, thereby meeting the requirements of large-line energy welding of products and customers.
In addition to the above embodiments, the present invention may have other embodiments. All technical solutions formed by adopting equivalent substitutions or equivalent transformations fall within the protection scope of the claims of the present invention.
Claims (7)
1. A460 MPa-grade hot-rolled steel for ship structure is characterized in that: the chemical components and the mass percentage are as follows: c: 0.04 to 0.07 percent of Si: 0.20-0.30%, Mn: 1.55 to 1.75 percent of Nb, less than or equal to 0.012 percent of P, less than or equal to 0.0020 percent of S, and the weight ratio of Nb: 0.030-0.050%, V: 0.020-0.040%, Ti: 0.006-0.020%, Cr: 0.10% -0.30%, Ni: 0.30-0.40%, Mo is less than or equal to 0.10%, Cu: 0.20-0.30%, Al: 0.005-0.015%, Mg: 0.0008 to 0.0015 percent, less than or equal to 0.0005 percent of B, less than or equal to 0.0050 percent of N, no Ca, and the balance of Fe and inevitable impurities.
2. The 460MPa grade steel for hot rolled hull structures according to claim 1, wherein: the chemical components and the mass percentage are as follows: c: 0.04-0.06%, Si: 0.20-0.30%, Mn: 1.55 to 1.65 percent of Nb, less than or equal to 0.010 percent of P, less than or equal to 0.0020 percent of S, and the mass percent of Nb: 0.030-0.040%, V: 0.030-0.040%, Ti: 0.006-0.018%, Cr: 0.10% -0.20%, Ni: 0.30-0.35%, Mo is less than or equal to 0.10%, Cu: 0.20-0.25%, Al: 0.005-0.013%, Mg: 0.0008 to 0.0013 percent, less than or equal to 0.0005 percent of B, less than or equal to 0.0050 percent of N, no Ca, and the balance of Fe and inevitable impurities.
3. The 460MPa grade steel for hot rolled hull structures according to claim 1, wherein: the chemical components and the mass percentage are as follows: c: 0.045% -0.065%, Si: 0.20-0.30%, Mn: 1.60-1.70%, P is less than or equal to 0.011%, S is less than or equal to 0.0015%, Nb: 0.035% -0.045%, V: 0.025-0.035%, Ti: 0.008-0.018%, Cr: 0.15% -0.25%, Ni: 0.31-0.38%, Mo is less than or equal to 0.10%, Cu: 0.22-0.28%, Al: 0.006% -0.013%, Mg: 0.0009 to 0.0015 percent, less than or equal to 0.0005 percent of B, less than or equal to 0.0050 percent of N, no Ca, and the balance of Fe and inevitable impurities.
4. The 460MPa grade steel for hot rolled hull structures according to claim 1, wherein: the chemical components and the mass percentage are as follows: c: 0.05 to 0.07 percent, Si: 0.20-0.30%, Mn: 1.65-1.75%, P is less than or equal to 0.010%, S is less than or equal to 0.0010%, Nb: 0.040% -0.050%, V: 0.030-0.040%, Ti: 0.008-0.020%, Cr: 0.20-0.30%, Ni: 0.35-0.40%, Mo is less than or equal to 0.10%, Cu: 0.25-0.30%, Al: 0.006-0.015%, Mg: 0.0009 to 0.0015 percent, less than or equal to 0.0005 percent of B, less than or equal to 0.0050 percent of N, no Ca, and the balance of Fe and inevitable impurities.
5. A manufacturing method of 460 MPa-level hot-rolled steel for ship structure is characterized in that: application to any one of claims 1 to 4, comprising:
smelting by adopting an alkaline converter, carrying out LF slagging desulfurization and carrying out vacuum degassing treatment to obtain pure killed steel;
casting by a continuous casting machine, wherein the casting blank is low-power B0.5 grade or better;
and heating the casting blank to 1150-1250 ℃, the rough rolling temperature is 1080-1160 ℃, the secondary opening temperature is 750-850 ℃, the final rolling temperature is 750-820 ℃, the water inlet temperature is 730-760 ℃ and the red returning temperature is 590-630 ℃ through a heating furnace after surface detection.
6. The manufacturing method of the 460 MPa-grade hot-rolled steel for ship hull structures according to claim 5, characterized in that: the thickness of the steel plate product is 50-100 mm.
7. The manufacturing method of the 460 MPa-grade hot-rolled steel for ship hull structures according to claim 5, characterized in that: an arc-shaped continuous casting machine with a section of 260-320 mm is adopted.
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Cited By (4)
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CN113444975A (en) * | 2021-07-02 | 2021-09-28 | 东北大学 | Pre-heating-free high-strength hydroelectric steel with low carbon equivalent weight of 600MPa grade before welding and manufacturing method thereof |
CN114855085A (en) * | 2022-05-19 | 2022-08-05 | 南京钢铁股份有限公司 | Marine low-temperature L-shaped steel and welding process thereof |
CN114892082A (en) * | 2022-04-28 | 2022-08-12 | 湖南华菱湘潭钢铁有限公司 | Large-thickness 460 MPa-grade steel plate for ocean engineering and production method thereof |
WO2023087979A1 (en) * | 2021-11-22 | 2023-05-25 | 南京钢铁股份有限公司 | X80-grade hot-bent elbow having excellent welding performance, and manufacturing method therefor |
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CN113444975A (en) * | 2021-07-02 | 2021-09-28 | 东北大学 | Pre-heating-free high-strength hydroelectric steel with low carbon equivalent weight of 600MPa grade before welding and manufacturing method thereof |
WO2023087979A1 (en) * | 2021-11-22 | 2023-05-25 | 南京钢铁股份有限公司 | X80-grade hot-bent elbow having excellent welding performance, and manufacturing method therefor |
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CN114855085A (en) * | 2022-05-19 | 2022-08-05 | 南京钢铁股份有限公司 | Marine low-temperature L-shaped steel and welding process thereof |
CN114855085B (en) * | 2022-05-19 | 2023-08-15 | 南京钢铁股份有限公司 | Marine low-temperature L-shaped steel and welding process thereof |
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