CN113022185B - Production process of water-based digital ink-jet transfer printing intermediate medium - Google Patents
Production process of water-based digital ink-jet transfer printing intermediate medium Download PDFInfo
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- CN113022185B CN113022185B CN202110134420.9A CN202110134420A CN113022185B CN 113022185 B CN113022185 B CN 113022185B CN 202110134420 A CN202110134420 A CN 202110134420A CN 113022185 B CN113022185 B CN 113022185B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 72
- 238000010023 transfer printing Methods 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 238000012546 transfer Methods 0.000 claims abstract description 50
- 239000003795 chemical substances by application Substances 0.000 claims description 46
- 238000000576 coating method Methods 0.000 claims description 34
- 239000011248 coating agent Substances 0.000 claims description 31
- -1 polysiloxane Polymers 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 19
- 239000000839 emulsion Substances 0.000 claims description 17
- 239000004816 latex Substances 0.000 claims description 17
- 229920000126 latex Polymers 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 14
- 239000002518 antifoaming agent Substances 0.000 claims description 12
- 125000002091 cationic group Chemical group 0.000 claims description 12
- 239000003755 preservative agent Substances 0.000 claims description 12
- 230000002335 preservative effect Effects 0.000 claims description 12
- 239000000853 adhesive Substances 0.000 claims description 11
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- 239000000123 paper Substances 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 8
- 229920002635 polyurethane Polymers 0.000 claims description 8
- 239000004814 polyurethane Substances 0.000 claims description 8
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 7
- 239000011256 inorganic filler Substances 0.000 claims description 6
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 6
- 239000002562 thickening agent Substances 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical group [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 claims description 4
- 229960002026 pyrithione Drugs 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 244000215068 Acacia senegal Species 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- 229920002873 Polyethylenimine Polymers 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 239000002174 Styrene-butadiene Substances 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 235000010216 calcium carbonate Nutrition 0.000 claims description 2
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 239000011115 styrene butadiene Substances 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 239000012974 tin catalyst Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 abstract description 24
- 238000007639 printing Methods 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 9
- 239000004831 Hot glue Substances 0.000 abstract description 6
- 238000004043 dyeing Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 75
- 239000000976 ink Substances 0.000 description 68
- 239000002609 medium Substances 0.000 description 42
- 230000000052 comparative effect Effects 0.000 description 28
- 239000010408 film Substances 0.000 description 28
- 238000005336 cracking Methods 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 4
- 238000004873 anchoring Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000007754 air knife coating Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 238000007766 curtain coating Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000007641 inkjet printing Methods 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
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- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 2
- 239000011112 polyethylene naphthalate Substances 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002052 molecular layer Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000007767 slide coating Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0082—Digital printing on bodies of particular shapes
- B41M5/0088—Digital printing on bodies of particular shapes by ink-jet printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/06—Copolymers with styrene
- C09D109/08—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D111/00—Coating compositions based on homopolymers or copolymers of chloroprene
- C09D111/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D139/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C09D179/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/162—Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
- C08K2003/3063—Magnesium sulfate
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Ink Jet (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention discloses a production process of a water-based digital ink-jet transfer printing intermediate medium, and relates to the technical field of printing and dyeing consumables. The production process of the water-based digital ink-jet transfer printing intermediate medium comprises the following steps: a water-based interfacial release layer and a water-based ink-bearing layer are coated on the surface of an intermediate transfer medium support. After the intermediate transfer medium obtained by the production process is digitally spray-printed and sprayed with the high-molecular hot-melt adhesive powder, the effects of shaking coarse powder and fine powder are excellent, so that the powder does not adhere to the periphery of the transferred pattern, and the obtained pattern has high color fastness and strong weather resistance.
Description
Technical Field
The invention relates to the technical field of printing and dyeing consumables, in particular to a production process of a water-based digital ink-jet transfer printing intermediate medium.
Background
Thermal transfer printing typically involves printing/jet printing an ink onto a film-based or paper support surface having a single/multi-layer functional coating, and then transferring the ink to a textile fiber fabric in a mirror-inverted fashion under heat and pressure. At present, the thermal transfer printing is mainly thermal sublimation transfer printing and thermosetting transfer printing. Among them, the thermosetting transfer printing technology using a thin film material (usually a coppy type ironing film) coated with a release layer and other functional coatings has been rapidly developed because of its wide application range (including cotton, nylon, high elastic fabrics, chemical fiber fabrics, etc.), bright color, soft hand feeling, etc.
The prior known technology mainly adopts a release film/a Keye film as an intermediate transfer medium support body, and a single-layer/multi-layer functional coating is coated to realize thermal transfer printing. Patent CN109334292a discloses an inkjet transfer printing method for personalized printing of textiles. The method adopts a PP release film as an intermediary transfer medium support body, an aqueous microporous structure inking layer is coated on the surface of the PP release film, color ink and transparent/white ink are subjected to ink-jet printing to form a surface ink layer, hot-melt powder resin is spread on the surface of the PP release film after the ink layer is subjected to ink-jet printing, and the PP release film is attached to a printing stock and subjected to hot stamping after being dried. However, this technique employs a PP support coated with an organic solvent type release agent. Patent CN105538941a discloses a thermal transfer printing method. The method comprises the steps of printing an ink absorption coating, an ink-jet printing layer, a screen printing nano layer and a white transfer printing layer on release paper, then scattering hot melt adhesive powder, and drying to obtain the transfer printing release paper for thermal transfer printing. The ink absorbing coating has limited adsorption capacity to color ink and white ink, ink flowing phenomenon is easy to occur, manual alignment is complex due to the adoption of screen printing, and especially small characters are difficult to align. The patent CN104077959B discloses a Korotkon type thermal transfer trademark identification, forming process and forming equipment, wherein a release layer is coated on a PET film, a four-color printer is adopted to print an ink layer, and a screen printer is adopted to sequentially print a white ink layer, an elastic permeable layer and a hot melt adhesive layer. However, in the technology, the release layer needs to be coated at least three times, and the white ink and the hot melt adhesive layer need to be printed three times, so that the cost is high and the operation is complex.
Disclosure of Invention
Based on the above, the invention aims to overcome the defects of the prior art and provide a production process of a water-based digital ink-jet transfer printing intermediate medium suitable for medium and large-scale production.
In order to realize the purpose, the technical scheme adopted by the invention is as follows: a production process of a water-based digital ink-jet transfer printing intermediate medium comprises the following steps: and coating a water-based interface stripping layer and a water-based ink bearing layer on the surface of the intermediate transfer medium support.
The water-based interfacial release layer and water-based ink-bearing layer compositions used herein are each water-soluble/dispersible compounds. Organic dispersion media such as toluene, xylene and butanone are not needed to be used as the solvent, therefore, the method has less load on the environment and is more energy-saving and environment-friendly.
Preferably, the water-based interfacial release layer comprises the following components in parts by weight: 30-90 parts of interface stripping agent, 0-10 parts of catalyst, 1-10 parts of adhesion agent, 0.2-5 parts of flatting agent, 0.2-2 parts of defoaming agent and 0.1-2 parts of preservative. Further preferably, the water-based interface release layer comprises the following components in parts by weight: 40-80 parts of interface stripping agent, 3-8 parts of catalyst, 2-6 parts of adhesion agent, 0.5-3 parts of flatting agent, 0.5-1 part of defoaming agent and 0.1-0.5 part of preservative. The inventors of the present application have found through extensive research that the interfacial remover, the catalyst and the adhesion agent have better effects within the above component selection range.
Preferably, the production process of the water-based digital ink-jet transfer intermediate medium comprises at least one of the following steps (a) to (f):
(a) The interface stripping agent is at least one of PE wax emulsion, polysiloxane emulsion and fluorine-silicon emulsion;
(b) The catalyst is a platinum catalyst or an organic tin catalyst;
(c) The adhesion agent is at least one of modified organic siloxane, polyurethane and acrylate;
(d) The leveling agent is at least one of polyether modified siloxane, water-based acrylate copolymer and fluorocarbon modified acrylate polymer;
(e) The defoaming agent is organic modified polysiloxane or fatty alcohol emulsion;
(f) The preservative is pyrithione or isothiazolinone.
Further preferably, the interface release agent is a silicone emulsion; the catalyst is a platinum catalyst; the adhesion agent is acrylate. The inventor of the application finds that the effect is better when the selection is adopted through a large amount of researches. The preferable polysiloxane emulsion as the interface stripping agent is based on the characteristics of small critical surface tension, high melting temperature, good chemical stability and the like; the optimized platinum is used as the catalyst and is based on the characteristics of good chemical stability, strong durability, high curing efficiency and the like; the preferable acrylate is used as the adhesion agent based on the characteristics of good compatibility, strong adhesion to the intermediate transfer medium support body and the like.
Preferably, the ink bearing layer comprises the following components in parts by weight: 1-15 parts of inorganic filler, 5-40 parts of color fixing agent, 5-30 parts of latex adhesive, 0.2-5 parts of flatting agent, 1-5 parts of thickening agent, 0.2-2 parts of defoaming agent and 0.1-2 parts of preservative. Further preferably, the ink bearing layer comprises the following components in parts by weight: 5-15 parts of inorganic filler, 10-25 parts of color fixing agent, 10-20 parts of latex adhesive, 1-3 parts of flatting agent, 1-3 parts of thickening agent, 0.5-1 part of defoaming agent and 0.1-0.5 part of preservative. The inventor of the application finds that the effect is better within the selection range of the components through a great deal of research.
Preferably, the water-based digital ink-jet transfer intermediate medium is produced by at least one of the following processes (a) to (g):
(a) The inorganic filler is at least one of silicon dioxide, calcium carbonate and kaolin;
(b) The color fixing agent is at least one of polyethyleneimine, polyalkenyl amine chloride and inorganic metal salt compounds; the inorganic metal salt compound is at least one of calcium chloride, magnesium sulfate and aluminum sulfate;
(c) The latex adhesive is at least one of cationic neoprene latex, cationic acrylate copolymer emulsion, cationic styrene-butadiene latex and cationic polyurethane;
(d) At least one of leveling agent polyether modified siloxane, water-based acrylate copolymer and fluorocarbon modified acrylate polymer;
(e) The thickener is at least one of nonionic polyurethane, guar gum, gum arabic, polyvinyl alcohol and polyacrylic acid;
(f) The defoaming agent is organic modified polysiloxane or fatty alcohol emulsion;
(g) The preservative is pyrithione or isothiazolinone.
The latex adhesive selected by the invention has film forming property, has certain interface adhesive force (usually main valence force) to a support body after being dried, and has good compatibility and anchoring effect to each composition of the coating. The color fixing agent selected by the invention can quickly absorb a large amount of solvent in the ink when the color ink and the white ink are sprayed, thereby effectively solving the problems of ink hanging and ink flowing.
Further preferably, the latex-based binder is a cationic acrylate copolymer emulsion or a cationic polyurethane. The preferable cationic acrylate copolymer emulsion or cationic polyurethane as the latex adhesive has the characteristics of good compatibility, low VOc content, strong film forming property and the like.
Preferably, the intermediate transfer medium support is a paper-based material or a film-based material; wherein the paper-based material or film-based material is a high temperature resistant (higher than 120 ℃); the paper base material is at least one of release base paper, laminating paper and glassine paper, and the film base material is at least one of polyethylene terephthalate thermal transfer film, polyethylene naphthalate thermal transfer film and polyamide thermal transfer film.
Preferably, the coating method of the present invention is not particularly limited, and may be conventionally known curtain coating, air knife coating, blade coating, bar coating, film transfer, slit coating, slide coating, and the like.
Preferably, the total coating weight of the water-based interface release layer and the water-based ink bearing layer is 2-10g/m in terms of dry solid component per single side 2 . Further preferably, the total coating weight of the water-based interfacial release layer and the water-based ink-bearing layer is dry solids per single sideThe component is 3-7g/m 2 。
In addition, the invention provides the water-based digital ink-jet transfer intermediate medium prepared by the production process of the water-based digital ink-jet transfer intermediate medium.
Further, the invention provides application of the water-based digital ink-jet transfer printing intermediate medium in the field of pyrograph films.
Compared with the prior art, the invention has the beneficial effects that:
(1) The conventional paper base or heat-resistant film base can be used as the intermediate transfer medium support body, and the film (such as a Korotkoff type pyrograph film) containing a plurality of functional coatings such as a release layer and the like is not limited, so that the application range of the film is widened, and the use cost of the film is reduced.
(2) The production process of the digital transfer printing intermediate transfer printing medium only needs to coat the surface of the support body of the intermediate transfer printing medium with the water-based interface stripping layer and the water-based ink bearing layer, so that the required thermocuring time is short, the production process is simple and the effect is obvious; and each composition of the coating has good compatibility and good stability, can be coated by adopting the conventional curtain type, air knife, scraper, film transfer and other modes, has convenient operation and low difficulty, and is suitable for medium-scale and large-scale production.
(3) The interface stripping layer and the ink bearing layer are both water-soluble/water-dispersible compounds, organic dispersion media such as toluene, xylene and butanone are not needed to be used as solvents, so that the load on the environment is less, and the ink bearing layer is more energy-saving and environment-friendly.
(4) The components and the proportion of the color fixing agent in the ink bearing layer composition are regulated and controlled, so that a large amount of solvent in the ink can be quickly absorbed when the color ink and the white ink are sprayed, and the problems of ink hanging, ink flowing and the like are effectively solved.
(5) After the intermediate transfer medium obtained by the production process is subjected to digital spray printing and high-molecular hot-melt adhesive powder scattering, the effects of shaking coarse powder and fine powder are excellent, so that the powder does not adhere to the periphery of the transferred pattern, and the obtained pattern is high in color fastness and weather resistance.
Drawings
FIG. 1 is a graph comparing the powder adhesion of example 5 and comparative example 2; wherein (a 1) is a sticky powder situation diagram of comparative example 2; (b 1) is a powder adhesion condition chart of example 5;
FIG. 2 is a graph comparing cracking of the printed inks of example 5 and comparative example 3; wherein (a 2) is the printed pattern cracking pattern of example 5; (b 2) is a printed pattern cracking pattern of comparative example 3;
FIG. 3 is a comparative graph showing peeling of the release layers of example 5 and comparative example 2; wherein (a 3) is a release layer peel-off diagram of example 5; (b 3) is a release layer peeling pattern of comparative example 2;
FIG. 4 is a comparison of inkjet color/white inks for example 5 and comparative example 4; wherein (a 4) is the jet printed color/white ink image of example 5; (b 4) is the inkjet color/white ink image of comparative example 4.
Detailed Description
To better illustrate the objects, technical solutions and advantages of the present invention, the present invention will be further described with reference to the accompanying drawings and specific examples, wherein the raw materials used in the examples and comparative examples of the present invention are commercially available, and the polyether modified siloxane leveling agent used in the present invention is provided by BYK company, specifically model No. BYK-348; the water-based acrylate copolymer used in the application is provided by TEGO company, and the specific model is TEGO-450; the fluorocarbon modified acrylate polymer used in the application is provided by Uniqchem, and the specific model is UNIQFLOW377S, and the organic modified polysiloxane is provided by TEGO, and the specific model is TEGO-204.
The present application sets forth examples 1-5, with the components and parts by weight selections for the water-based interfacial release layer and ink-bearing layer in specific examples 1-5 shown in tables 1 and 2:
TABLE 1 selection of parts by weight of water-based interfacial release layer and ink-bearing layer for specific examples 1-5
TABLE 2 selection of components for water-based interfacial release layer and ink-bearing layer in specific examples 1-5
Meanwhile, the application is provided with comparative examples 1-9, the weight parts of the water-based interface stripping layer and the ink bearing layer in specific comparative examples 1-4 are selected as shown in the table 3, and the component selection of the comparative examples 1-4 is completely the same as that of the example 5; the selection of the components of the water-based interfacial peeling layer and the ink carrying layer in specific comparative examples 5 to 9 is shown in Table 4, and the selection of the parts by weight of comparative examples 5 to 9 is completely the same as that of example 5;
TABLE 3 selection of parts by weight of water-based interfacial release layer and ink-bearing layer in specific comparative examples 1-4
TABLE 4 selection of components for water-based interfacial release layer and ink-bearing layer in specific comparative examples 5-9
In the embodiment 1 of the present application, after selecting the components and the parts by weight according to the above table 1-2, a production process of a water-based digital inkjet transfer intermediate medium includes the following steps: on the surface of an intermediate transfer medium support bodyA surface coating water-based interface stripping layer and a water-based ink bearing layer, wherein the intermediate transfer medium support body is release base paper, the coating mode is curtain coating, and the total coating amount is 2g/m in terms of dry solid component per single surface 2 ；
In example 2 of the present application, a process for producing a water-based digital inkjet transfer intermediate medium, after selecting components and parts by weight according to the above tables 1 to 2, comprises the steps of: coating a water-based interface stripping layer and a water-based ink bearing layer on the surface of an intermediate transfer medium support, wherein the intermediate transfer medium support is a polyethylene terephthalate thermal transfer film, the coating mode is curtain coating, and the total coating weight is 10g/m in terms of dry solid component per single surface 2 ；
In example 3 of the present application, a process for producing a water-based digital inkjet transfer intermediate medium, after selecting components and parts by weight according to the above tables 1 to 2, comprises the steps of: coating a water-based interface stripping layer and a water-based ink bearing layer on the surface of an intermediate transfer medium support body, wherein the intermediate transfer medium support body is glassine paper, the coating mode is coating by a scraper, and the total coating weight is 3g/m calculated by the dry solid component amount on each side 2 ；
In example 4 of the present application, a process for producing a water-based digital inkjet transfer intermediate medium, selected in terms of components and parts by weight according to the above tables 1 to 2, comprises the steps of: coating a water-based interface stripping layer and a water-based ink bearing layer on the surface of an intermediate transfer medium support, wherein the intermediate transfer medium support is a polyethylene naphthalate thermal transfer film, the coating mode is air knife coating, and the total coating amount is 7g/m in terms of dry solid component per single surface 2 ；
In example 5 of the present application, a process for producing a water-based digital inkjet transfer intermediate medium, selected in terms of components and parts by weight according to the above tables 1 to 2, comprises the steps of: coating a water-based interface stripping layer and a water-based ink bearing layer on the surface of an intermediate transfer medium support, wherein the intermediate transfer medium support is a polyethylene terephthalate thermal transfer film, the coating mode is air knife coating, and the total coating weight is 5g/m in terms of dry solid component per single surface 2 ；
The production process of the water-based digital ink jet transfer intermediate of the comparative example of the present application was exactly the same as that of example 5. The comparative graph of the powder adhesion conditions of the application example 5 and the comparative example 2 is shown in fig. 1, wherein the powder adhesion and the interface stripping layer have no positive/negative correlation and mainly depend on the amounts of the fixing agent and the latex binder in the ink bearing layer; the comparative graph of the cracking of the printing ink of example 5 and comparative example 3 is shown in fig. 2, wherein the cracking condition also depends on the amount of the fixing agent and the latex binder in the ink bearing layer, and when the amount is too large, the cracking condition of the printing pattern can be caused; the release layer peeling comparison of example 5 and comparative example 2 is shown in fig. 3, the release layer peeling condition mainly depends on the interfacial peeling agent, the catalyst and the adhesion agent, and when the amount is too small, the poor peeling phenomenon occurs; the comparative images of the jet printed color/white inks of example 5 and comparative example 4 are shown in FIG. 4; as can be seen from FIGS. 1-4, the best results were obtained when the composition and the weight of the intermediate were within the ranges selected in the present application.
Test examples Water-based digital ink-jet transfer intermediate Performance testing
Test procedures and standards:
1) White ink bearing ratio: controlling the ink output amount of the white coating ink through printing a spot color channel, wherein the ink output amount is increased when the numerical value is increased; the printing white ink amount of the universal digital pyrograph film is more than 70 percent.
2) Powder sticking condition: at 0.125m 2 The digital ink-jet transfer printing intermediate medium is sprayed and printed with a standard CMYK picture, quantitative high-molecular hot-melt adhesive powder is uniformly scattered and covered on the surface of the medium, and the weight ratio of the adhesive powder is measured after the powder is shaken; the powder sticking amount of the universal CMYK image is 30 percent, the value lower than the value indicates that the powder sticking amount is insufficient, the color fastness of the pattern after subsequent transfer printing is influenced, and the value higher than the value indicates that the powder sticking is excessive, namely, the powder sticking phenomenon also occurs at the non-image part.
3) Pattern stripping condition: at 0.125m 2 The digital ink-jet transfer printing intermediate medium is sprayed and printed with a standard CMYK image, powder is scattered and shaken on the surface of the digital ink-jet transfer printing intermediate medium, the digital ink-jet transfer printing intermediate medium is peeled after being thermoprinted, and the weight ratio of residual images on the surface of the intermediate medium after transfer printing is measured.
And (3) test results: the test results are shown in Table 5
TABLE 5 results of performance test of examples and comparative examples
Note: 1) In comparative examples 1 and 5, the interface peeling layer could not be completely cured, and thus no relevant test was performed;
2) The linear polyacrylamide, styrene acrylate emulsion, and pure acrylic acid latex used in comparative examples 8 and 9 were poor in color/ink curing ability and poor in compatibility with the rest of the components of the ink bearing layer, and therefore no correlation test was performed.
When the interface stripping agent, the catalyst and the adhesion agent in the water-based interface stripping layer are in the preferable component selection range, the prepared transfer intermediate medium has good stripping effect and good compatibility of the interface stripping layer and the ink bearing layer, so that the pattern stripping condition after hot stamping is good. When the above three components are less than the preferable range, the release effect of the interface release layer is weak, resulting in difficulty in complete peeling of the transferred pattern; when the above three components are higher than the preferable ranges, the interfacial release layer is difficult to be completely cured, and compatibility with an ink-bearing layer coating the surface thereof is deteriorated, resulting in failure to normally jet-print a pattern.
When the color fixing agent and the latex adhesive in the ink bearing layer are in the preferable component selection range, the prepared transfer printing intermediate medium has strong fixing/anchoring capacity to the water-based color/white ink, and the patterns obtained after hot stamping have moderate hand feeling. When the above two components are less than the preferred ranges, the fixing/anchoring ability to the color/white ink is significantly reduced, resulting in the occurrence of a bleeding phenomenon in the printed pattern; when the two components are higher than the preferable range, the fixation/anchoring capability and the moisture absorption capability of the color/white ink are too high, so that the cracking phenomenon occurs during the pattern spray printing, and the hand feeling of the pattern after hot stamping is influenced.
Finally, it should be noted that the above embodiments are only used for illustrating the technical solutions of the present invention and not for limiting the protection scope of the present invention, and although the present invention is described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions can be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention.
Claims (8)
1. A production process of a water-based digital ink-jet transfer printing intermediate medium is characterized by comprising the following steps: coating a water-based interface stripping layer and a water-based ink bearing layer on the surface of the intermediate transfer medium support; the water-based ink bearing layer bears color ink and white ink;
wherein the water-based interface stripping layer comprises the following components in parts by weight: 30-90 parts of interface stripping agent, 0-10 parts of catalyst, 1-10 parts of adhesion agent, 0.2-5 parts of flatting agent, 0.2-2 parts of defoaming agent and 0.1-2 parts of preservative; the ink bearing layer comprises the following components in parts by weight: 1-15 parts of inorganic filler, 5-40 parts of color fixing agent, 5-30 parts of latex adhesive, 0.2-5 parts of flatting agent, 1-5 parts of thickening agent, 0.2-2 parts of defoaming agent and 0.1-2 parts of preservative.
2. The process for producing a water-based digital ink-jet transfer intermediate medium according to claim 1, wherein the water-based interfacial release layer comprises the following components in parts by weight: 40-80 parts of interface stripping agent, 3-8 parts of catalyst, 2-6 parts of adhesion agent, 0.5-3 parts of flatting agent, 0.5-1 part of defoaming agent and 0.1-0.5 part of preservative.
3. The process for producing a water-based digital ink-jet transfer intermediate medium according to claim 1 or 2, wherein at least one of the following (a) to (f):
(a) The interface stripping agent is at least one of PE wax emulsion, polysiloxane emulsion and fluorine-silicon emulsion;
(b) The catalyst is a platinum catalyst or an organic tin catalyst;
(c) The adhesion agent is at least one of modified organic siloxane, polyurethane and acrylate;
(d) The leveling agent is at least one of polyether modified siloxane, water-based acrylate copolymer and fluorocarbon modified acrylate polymer;
(e) The defoaming agent is organic modified polysiloxane or fatty alcohol emulsion;
(f) The preservative is pyrithione or isothiazolinone.
4. The process for producing a water-based digital ink jet transfer intermediate according to claim 1, wherein the ink bearing layer comprises the following components in parts by weight: 5-15 parts of inorganic filler, 10-25 parts of color fixing agent, 10-20 parts of latex adhesive, 1-3 parts of flatting agent, 1-3 parts of thickening agent, 0.5-1 part of defoaming agent and 0.1-0.5 part of preservative.
5. The process for producing a water-based digital ink-jet transfer intermediate medium according to claim 4, wherein at least one of the following (a) to (g):
(a) The inorganic filler is at least one of silicon dioxide, calcium carbonate and kaolin;
(b) The color fixing agent is at least one of polyethyleneimine, polyalkenyl amine chloride and inorganic metal salt compounds;
(c) The latex adhesive is at least one of cationic neoprene latex, cationic acrylate copolymer emulsion, cationic styrene-butadiene latex and cationic polyurethane;
(d) The leveling agent is at least one of polyether modified siloxane, water-based acrylate copolymer and fluorocarbon modified acrylate polymer;
(e) The thickener is at least one of nonionic polyurethane, guar gum, gum arabic, polyvinyl alcohol and polyacrylic acid;
(f) The defoaming agent is organic modified polysiloxane or fatty alcohol emulsion;
(g) The preservative is pyrithione or isothiazolinone.
6. The process for producing a water-based digital ink jet transfer intermediate according to claim 1, wherein the intermediate support is a paper-based material or a film-based material.
7. A water-based digital ink-jet transfer intermediate prepared by the process for manufacturing a water-based digital ink-jet transfer intermediate according to claim 1.
8. Use of the water-based digital ink-jet transfer intermediate prepared by the process for producing a water-based digital ink-jet transfer intermediate according to claim 7 in the field of pyrography films.
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