CN113004728A - Coating with hydrophilic self-cleaning capability and preparation method thereof - Google Patents
Coating with hydrophilic self-cleaning capability and preparation method thereof Download PDFInfo
- Publication number
- CN113004728A CN113004728A CN202110135464.3A CN202110135464A CN113004728A CN 113004728 A CN113004728 A CN 113004728A CN 202110135464 A CN202110135464 A CN 202110135464A CN 113004728 A CN113004728 A CN 113004728A
- Authority
- CN
- China
- Prior art keywords
- coating
- weight
- hydrophilic
- solution
- cleaning ability
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 115
- 239000011248 coating agent Substances 0.000 title claims abstract description 102
- 238000004140 cleaning Methods 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims description 24
- 239000003999 initiator Substances 0.000 claims abstract description 29
- -1 polyethylene Polymers 0.000 claims abstract description 29
- 239000002243 precursor Substances 0.000 claims abstract description 29
- 239000000178 monomer Substances 0.000 claims abstract description 19
- 239000002904 solvent Substances 0.000 claims abstract description 19
- 239000002216 antistatic agent Substances 0.000 claims abstract description 18
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 16
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 12
- 239000004698 Polyethylene Substances 0.000 claims abstract description 4
- 239000004743 Polypropylene Substances 0.000 claims abstract description 4
- 239000004793 Polystyrene Substances 0.000 claims abstract description 4
- 229920000573 polyethylene Polymers 0.000 claims abstract description 4
- 229920001155 polypropylene Polymers 0.000 claims abstract description 4
- 229920002223 polystyrene Polymers 0.000 claims abstract description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 4
- 239000000243 solution Substances 0.000 claims description 49
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000011941 photocatalyst Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 14
- 239000004408 titanium dioxide Substances 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 10
- 238000005245 sintering Methods 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 8
- 239000003085 diluting agent Substances 0.000 claims description 8
- 239000002135 nanosheet Substances 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- 238000010790 dilution Methods 0.000 claims description 7
- 239000012895 dilution Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 6
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 5
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- 239000002127 nanobelt Substances 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 230000001588 bifunctional effect Effects 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 229910021389 graphene Inorganic materials 0.000 claims description 3
- 238000001471 micro-filtration Methods 0.000 claims description 3
- 239000012982 microporous membrane Substances 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002074 nanoribbon Substances 0.000 claims description 3
- 239000012966 redox initiator Substances 0.000 claims description 3
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 3
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical compound S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 claims description 3
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 claims description 3
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 claims description 3
- 229910000859 α-Fe Inorganic materials 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims 2
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims 1
- 239000012990 dithiocarbamate Substances 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 claims 1
- 150000004756 silanes Chemical class 0.000 claims 1
- 238000004132 cross linking Methods 0.000 abstract description 8
- 238000002834 transmittance Methods 0.000 abstract description 7
- 238000006116 polymerization reaction Methods 0.000 abstract description 5
- 150000003973 alkyl amines Chemical class 0.000 abstract description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 47
- 230000001699 photocatalysis Effects 0.000 description 17
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 12
- 230000003373 anti-fouling effect Effects 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- 239000011521 glass Substances 0.000 description 9
- 238000000691 measurement method Methods 0.000 description 8
- 230000032683 aging Effects 0.000 description 7
- 239000002585 base Substances 0.000 description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 7
- 239000003344 environmental pollutant Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 231100000719 pollutant Toxicity 0.000 description 6
- 239000011247 coating layer Substances 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 238000007146 photocatalysis Methods 0.000 description 5
- 230000003712 anti-aging effect Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052724 xenon Inorganic materials 0.000 description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 3
- NLSFWPFWEPGCJJ-UHFFFAOYSA-N 2-methylprop-2-enoyloxysilicon Chemical compound CC(=C)C(=O)O[Si] NLSFWPFWEPGCJJ-UHFFFAOYSA-N 0.000 description 2
- XXLJGBGJDROPKW-UHFFFAOYSA-N antimony;oxotin Chemical compound [Sb].[Sn]=O XXLJGBGJDROPKW-UHFFFAOYSA-N 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000008204 material by function Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 2
- 229960000907 methylthioninium chloride Drugs 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 239000002096 quantum dot Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000005341 toughened glass Substances 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- SKRWFPLZQAAQSU-UHFFFAOYSA-N stibanylidynetin;hydrate Chemical compound O.[Sn].[Sb] SKRWFPLZQAAQSU-UHFFFAOYSA-N 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000036561 sun exposure Effects 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
A coating with hydrophilic self-cleaning capability comprises 80-100 parts by weight of hydrophilic solvent, 0.01-10 parts by weight of precursor monomer, 0.01-0.5 part by weight of chain initiator, 0.01-1 part by weight of silane coupling agent, 0.01-1 part by weight of photoinitiator and 0-1 part by weight of antistatic agent; the precursor monomer comprises one or more of polyethylene, polypropylene, polyvinyl chloride and polystyrene; the precursor monomer forms a network structure after crosslinking, interconnection or polymerization; the antistatic agent comprises one or more of alkyl quaternary ammonium salt, alkyl phosphonium salt, alkyl sulfonic acid alkali metal salt, alkyl phosphoric acid alkali metal salt, alkyl dithio-carbamic acid alkali metal salt and ethoxylated fatty alkylamine. The coating has the characteristics of all weather, durability and good light transmittance.
Description
Technical Field
The invention relates to a coating, in particular to a coating with hydrophilic self-cleaning capability and a preparation method thereof.
Background
With the rapid development of economy, the infrastructure of China is continuously improved and developed, the problem of cleaning various buildings such as skyscrapers, giant stone carvings, large billboards and the like becomes a great problem, the traditional manual cleaning method not only consumes time and labor and has extremely high cost, but also has great potential safety hazard in cleaning work. In order to overcome the problems, in recent years, a plurality of antifouling paints applied to the outer wall of the building are developed, and the antifouling materials can reduce the deposition of pollutants on the surface of the building and delay the pollution of the outer wall of the building to a certain extent. However, the material is a temporary solution and a permanent solution, and according to the feedback discovery of the effect of the current practical application, the common antifouling paint in the market at present has the following defects:
firstly, the mechanical strength of the material is insufficient: the current antifouling material is basically a simple aqueous phase or alcohol phase solution, and is naturally solidified on the surface of the outer wall of the building by a spraying or wiping method. The bonding method is basically simple van der waals force or hydrogen bonding, has extremely low mechanical strength, and is difficult to resist the corrosion of natural conditions such as long-term wind blowing, sun exposure, rain and the like. Therefore, functional materials such as super-hydrophilic materials, photocatalytic materials and the like in the solution can be stripped from the surface of the coating, the coating can gradually lose the functional effects such as super-hydrophilicity, photocatalysis and the like, and the coating can be separated from the surface of the base material, so that the coating effect is completely lost;
secondly, the photocatalytic performance is lower: the photocatalyst adopted by the existing antifouling coating is basically titanium dioxide, the titanium dioxide really endows the material with photocatalytic performance, and the hydrophilicity of the coating can be improved to a certain extent, but the requirement of the titanium dioxide on a dissolving system and the particle size is extremely high, if a better dissolving system and a smaller particle size do not exist, the antifouling material added with the titanium dioxide can generate obvious white floccules, the transmittance of the coating on a series of base materials such as glass and the like is directly influenced, and the applicability, the operation simplicity and the attractiveness of the antifouling coating are reduced. In addition, as a photocatalyst which is relatively well researched, the lower photoelectric conversion efficiency and the lower visible light utilization rate of the titanium dioxide are always problematic, and the two defects also limit the application effect of the titanium dioxide as the photocatalyst in an antifouling material;
thirdly, poor removal capability of solid particles: in the time period of drought and rain, wind sand and flying dust are main pollution factors on the surface of a building, sand, dust and other solid pollutants with small particle size are easily adsorbed on the surface of the building under the condition, and the pollutants are gradually deposited and solidified when the rain wash is not in time, so that the pollutants are remained on the surface of an outer wall of the building, and the attractiveness of the building is influenced. Thus, conventional antifouling materials have difficulty in resisting such solid particulate contamination during rainy seasons or areas lacking rain water.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide an all-weather durable coating with good light transmittance and hydrophilic self-cleaning capability and a preparation method thereof.
In order to solve the technical problems, the technical scheme provided by the invention is as follows: a coating with hydrophilic self-cleaning capability comprises 80-100 parts by weight of hydrophilic solvent, 0.01-10 parts by weight of precursor monomer, 0.01-0.5 part by weight of chain initiator, 0.01-1 part by weight of silane coupling agent, 0.01-1 part by weight of photoinitiator and 0-1 part by weight of antistatic agent; the precursor monomer comprises one or more of polyethylene, polypropylene, polyvinyl chloride, polystyrene and derivatives thereof with crosslinking, interconnection or polymerization; the precursor monomer forms a network structure after crosslinking, interconnection or polymerization; the antistatic agent comprises one or more of alkyl quaternary ammonium salt, alkyl phosphonium salt, alkyl sulfonic acid alkali metal salt, alkyl phosphoric acid alkali metal salt, alkyl dithio-carbamic acid alkali metal salt and ethoxylated fatty alkylamine.
In the above coating material having hydrophilic self-cleaning ability, preferably, the silane coupling agent includes one or more of vinyl silane, amino silane, epoxy silane, mercapto silane and methacryloxy silane.
Preferably, the chain initiator is one or more of a series of initiators including azo initiators, redox initiators, bifunctional and multifunctional initiators.
Preferably, the coating with hydrophilic self-cleaning capability further comprises one or more of doped titanium dioxide, composite titanium dioxide, graphene, bismuth ferrite, bismuth vanadate and carbon nitride as a photocatalyst.
The above coating material with hydrophilic self-cleaning ability preferably comprises one or more of ethanol, methanol, propylene glycol and propylene glycol methyl ether.
A preparation method of a coating with hydrophilic self-cleaning capability comprises the following steps:
1) dissolving a precursor monomer in a half of hydrophilic solvent or pure water, and stirring for more than 1 minute at the water bath temperature of 25-50 ℃ to fully dissolve the precursor monomer in the hydrophilic solvent;
2) adding a chain initiator into the solution in the step 1) and uniformly mixing;
3) adding the remaining hydrophilic solvent to the solution in step 2);
4) adding a silane coupling agent into the solution obtained in the step 3), and stirring at normal temperature for more than 3 min;
5) adding a photoinitiator into the solvent in the step 4), and stirring for more than 5 minutes; and then standing to obtain the coating with hydrophilic self-cleaning capability.
In the preparation method of the coating with hydrophilic self-cleaning capability, the antistatic agent is preferably added before stirring in the step 1).
In the preparation method of the coating with hydrophilic self-cleaning capability, the photocatalyst is preferably added before stirring in the step 1).
In the preparation method of the coating with hydrophilic self-cleaning capability, preferably, the preparation method of the carbon nitride in the photocatalyst comprises the following steps:
Preferably, in the step 2), before the chain initiator is added to the solution in the step 1), the chain initiator is added to a diluent for dilution, and the weight concentration of the diluted chain initiator is 5-15%; the diluent is tetrahydrofuran.
Compared with the prior art, the invention has the advantages that: 1. the materials of the invention are common raw materials in industrial production, are cheap and easily available, and have better price advantage in practical application production. 2. By using high molecular materials such as acrylamide and the like, the functional materials can be well fixed on the surface of the base material. 3. The material disclosed by the invention has good hardness, adhesion performance and ageing resistance, and has small influence on the appearance and light transmittance of substrates such as glass and the like. 4. The material of the invention not only improves the utilization rate of sunlight, but also improves the degradation efficiency of pollutants. 5. The material disclosed by the invention has an antistatic property, and can reduce the adhesion condition of solid particles on the surface of a coating, so that the antifouling property of the coating is improved.
Drawings
FIG. 1 is a digital photograph of a coating having hydrophilic self-cleaning ability prepared in example 9.
Fig. 2 is a contact angle test digital photo of the coating with hydrophilic self-cleaning ability prepared in example 9 after being cured on tempered glass.
Detailed Description
In order to facilitate an understanding of the present invention, the present invention will be described more fully and in detail with reference to the preferred embodiments, but the scope of the present invention is not limited to the specific embodiments described below.
It should be particularly noted that when an element is referred to as being "fixed to, connected to or communicated with" another element, it can be directly fixed to, connected to or communicated with the other element or indirectly fixed to, connected to or communicated with the other element through other intermediate connecting components.
Unless otherwise defined, all terms of art used hereinafter have the same meaning as commonly understood by one of ordinary skill in the art. The terminology used herein is for the purpose of describing particular embodiments only and is not intended to limit the scope of the present invention.
A coating with hydrophilic self-cleaning capability comprises 80-100 parts by weight of hydrophilic solvent, 0.01-10 parts by weight of precursor monomer, 0.01-0.5 part by weight of chain initiator, 0.01-1 part by weight of silane coupling agent, 0.01-1 part by weight of photoinitiator and 0-1 part by weight of antistatic agent; the precursor monomer comprises one or more of polyethylene, polypropylene, polyvinyl chloride, polystyrene and derivatives thereof with crosslinking, interconnection or polymerization; the precursor monomer forms a network structure after crosslinking, interconnection or polymerization; the antistatic agent comprises one or more of alkyl quaternary ammonium salt, alkyl phosphonium salt, alkyl sulfonic acid alkali metal salt, alkyl phosphoric acid alkali metal salt, alkyl dithio-carbamic acid alkali metal salt and ethoxylated fatty alkylamine.
Antistatic agents are additives that are added to plastics or applied to the surface of molded articles to reduce static buildup. The antistatic agent is added into the coating, so that the resistivity of the surface of the material is reduced, solid small particles are difficult to adsorb on the surface of the base material, and the cleanness of the surface of the base material is kept.
In the present invention, the silane coupling agent includes one or more of vinyl silane, amino silane, epoxy silane, mercapto silane, and methacryloxy silane. The silane coupling agent is rich in siloxane groups and organic functional groups, wherein the siloxane groups have reactivity with inorganic substances, and the organic functional groups have reactivity or compatibility with organic substances. Thus, when a silane coupling agent intervenes between the inorganic and organic interfaces, a bonding layer of organic matrix-silane coupling agent-inorganic matrix may be formed. When the material is applied to the material, a bridge can be erected between the coating and the base material, and the adhesion of the coating on the base material is improved. It should be noted that the selection of the corresponding silane coupling agent should be easily soluble in the whole solution system, and cannot cause flocculation and precipitation reactions, which may damage the overall transparency of the solution. The silane coupling agent can be directly added into the precursor solution in the form of solution, or can be hydrolyzed in advance and then added into the precursor solution, and different adding modes are selected according to the characteristics of different silane coupling agents.
In the invention, the chain initiator comprises one or more of azo initiator, redox initiator, bifunctional and multifunctional initiator series. The chain initiator is a compound which is easily decomposed into free radicals (namely primary free radicals) by heating, can be used for initiating free radical polymerization and copolymerization of alkene and diene monomers, and can also be used for crosslinking curing and high polymer crosslinking of unsaturated polyester. In the present invention, the chain initiator mainly helps the precursor to polymerize into chains in the solution, and provides for the next crosslinking to form a network structure. The chain initiator can be directly added into the solution or dissolved in advance, and the adopted solvent comprises one or more of ethanol, methanol, propylene glycol methyl ether and the like.
The photocatalyst is also called photocatalyst, and is a generic name of semiconductor materials having a photocatalytic function represented by nano-sized titanium dioxide. A typical photocatalytic material is titanium dioxide, which generates a substance having a strong oxidizing property (e.g., hydroxyl radical, oxygen, etc.) under light irradiation, and is useful for decomposing organic compounds, partially inorganic compounds, killing bacteria and viruses, etc. The photocatalyst is added into the coating, so that the removal capability of the coating on organic pollutants in the air can be improved, the organic pollutants attached to the coating can be decomposed through a photoelectric reaction, and the effect of keeping the surface of the base material clean is finally achieved. The photocatalyst applied by the invention should be a nano-scale photocatalyst, including but not limited to a series of photocatalytic materials such as doped titanium dioxide, composite titanium dioxide, graphene, bismuth ferrite, bismuth vanadate, carbon nitride and the like, and in addition, the nano-scale photocatalyst can be directly prepared by a production unit through a separate preparation method. The photocatalyst is dissolved in a corresponding solution system in advance, so that the photocatalyst can be combined in the whole coating layer in the later reaction to the maximum extent, and the stability and the transparency of the solution are maintained.
In the present invention, the coating material may further contain a pH adjuster including one or more of dilute hydrochloric acid, perchloric acid and sodium hydroxide solution, or other pH adjusters may be used.
In the present invention, the hydrophilic solvent includes one or more of ethanol, methanol, propylene glycol and propylene glycol methyl ether.
The invention also provides a preparation method of the coating with hydrophilic self-cleaning capability,
the method comprises the following steps:
1) dissolving a precursor monomer in a half of hydrophilic solvent or pure water, and stirring for more than 1 minute at the water bath temperature of 25-50 ℃ to fully dissolve the precursor monomer in the hydrophilic solvent;
2) adding a chain initiator into the solution in the step 1) and uniformly mixing;
3) adding the remaining hydrophilic solvent to the solution in step 2);
4) adding a silane coupling agent into the solution obtained in the step 3), and stirring at normal temperature for more than 3 min;
5) adding a photoinitiator into the solvent in the step 4), and stirring for more than 5 minutes; and then standing to obtain the coating with hydrophilic self-cleaning capability.
In the present invention, an antistatic agent may be added before the stirring in step 1).
In the present invention, the photocatalyst may be added before the stirring in step 1).
In the invention, in the step 2), before the chain initiator is added into the solution in the step 1), the chain initiator is firstly added into a diluent for dilution, and the weight concentration of the diluted chain initiator is 5-15%; the diluent is tetrahydrofuran.
In the present invention, the photocatalyst is preferably graphite-phase carbon nitride (g-C)3N4) Also called carbon nitride quantum dots, the preparation method of the graphite phase carbon nitride comprises the following steps:
Example 1
In this embodiment, a precursor acrylamide is used to prepare a polymer material, and the polymer material is modified to have hydrophilicity, and the specific preparation process is as follows:
14.216 g of acrylamide solid is dissolved in 100 mL of ultrapure water, the solution is stirred for 3min at the rotation speed of 200 rpm in a water bath kettle at the temperature of 30 ℃ to be fully dissolved, then 0.1 mL of (3-mercaptopropyl) trimethoxysilane solution is added, the volume fraction of the (3-mercaptopropyl) trimethoxysilane solution is 10 percent, the diluent of the (3-mercaptopropyl) trimethoxysilane is tetrahydrofuran, then 1 mL of acetic acid solution with the concentration of 0.1 mol/L is added, then 0.57 mL of silane coupling agent TMSPMA is added, the mixture is stirred for 5 min at the temperature of 30 ℃, finally 0.2 mL of 0.1 mol/L photoinitiator I-2959 is added, and the mixture is stirred for 10min and then stands for standby;
spraying the prepared coating on toughened glass by a high-pressure spray gun, naturally drying for 24 hours, and then curing to form a film, wherein the transparency of the coating is measured by observing the light transmittance of the glass surface; judging the hydrophilicity of the solution through a water contact angle; the hardness of the coating layer on the surface of the glass is judged by rubbing for 50 times by a rubbing machine; judging the anti-aging performance of the coating layer on the surface of the glass through a xenon lamp aging test of 50 hours, and measuring the photocatalysis performance of the coating through a removal test of methylene blue liquid drops with the concentration of 5 mg/L; the antistatic properties of the coating were measured by observing the retention of the powder on the glass surface.
The coating according to the invention was tested by the test method described in the supplementary contents of the examples, the test results of example 1 are shown in table 1, and based on the test results we found that example 1 already has hydrophilic properties and at the same time has good hardness and aging resistance, but the coating described in example 1 has poor transparency, which severely limits the application range of the coating. The inventors searched a large number of documents and found that the concentration of the precursor has a great influence on the viscosity of the coating layer, and therefore, it is presumed that the transparency of the coating layer can be improved by lowering the concentration of the precursor, and thus, example 2 and example 3 were designed.
Example 2
The amount of acrylamide added in step (1) was changed to 7.1797 g, and the amounts of other test materials and the preparation steps were the same as those of example 1 to obtain the coating material prepared in example 2, and then the same coating method and measurement method as those of example 1 were performed to measure the properties of the coating material prepared in example 2;
example 3
The amount of acrylamide added in step (1) was changed to 3.5899 g, and the amounts of other test materials and the preparation steps were the same as those of example 1 to obtain the coating material prepared in example 3, and then the same coating method and measurement method as those of example 1 were performed to measure the properties of the coating material prepared in example 3;
from the effects of examples 2 and 3 shown in table 1, it can be seen that the transparency of the coating is indeed improved by reducing the concentration of the precursor, but as the concentration of the precursor is reduced, the anti-aging performance and hardness of the coating are gradually reduced, which leads to the coating losing its hydrophilicity and anti-fouling performance very quickly, so that a better precursor concentration, which has both good transparency and good anti-aging performance and hardness, needs to be found.
Example 4
The amount of acrylamide added in step (1) was changed to 5.3848 g, and the amounts of other test materials and the preparation steps were the same as those of example 1 to obtain the coating material prepared in example 4, and then the same coating method and measurement method as those of example 1 were performed to measure the properties of the coating material prepared in example 4;
table 1: comparison of the Properties of the coatings of examples 1, 2, 3, 4
| Example of implementation | Transparency of | Hydrophilicity | Hardness of | Aging resistance | Photocatalytic property | Antistatic properties |
| Example 1 | × | √ | √ | √ | × | × |
| Example 2 | × | √ | √ | √ | × | × |
| Example 3 | √ | √ | × | × | × | × |
| Example 4 | √ | √ | √ | √ | × | × |
Note: in the table, "×" indicates that the coating had no or poor properties, and "√" indicates that the properties are superior
The results in Table 1 show that the transparency of the coating gradually improves with decreasing precursor concentration, but the hardness and the aging resistance are attenuated. The inventor finds out a better precursor concentration through a large number of literature consultations and experimental verifications so as to carry out the next experiment. Meanwhile, it can also be seen that the coatings described in examples 1 to 4 do not have antistatic and photocatalytic properties and do not achieve the desired effects because no photocatalyst and antistatic agent are added, and the following examples are listed for discussion.
Example 5
The amount of acrylamide added in step (1) in example 1 was fixed at 5.3848 g, and step (2) and step (3):
(2) preparation method of graphite phase carbon nitride
First, melamine was put in a muffle furnace at 5 ℃ for min-1Heating to 500 ℃ at a heating rate and maintaining for 4 hours to synthesize flake g-C3N4Solid, then flake g-C3N4Ground into a powder for further use. Then 1 g of flakes g-C3N4Placing into a ceramic crucible at 2.3 deg.C for min-1Is heated to 550 ℃ and kept for 2 hours to obtain the twice calcined g-C3N4Nanosheets. Subsequently, under sonication, 200 mg of g-C3N420 mL HNO for nanosheet3And H2SO4And oxidizing for 18 hours. The clear isThe clear solution was diluted with 300 mL of deionized water to form a colloidal suspension, filtered through a 0.45um microporous membrane to remove the acid, and washed with deionized water to obtain g-C3N4Nanobelts (CNNR), isolation yield about 50% CNNRs were dispersed in 20 mL of deionized water under ultrasonic conditions for 2h, and then the suspension was transferred to a 20 mL teflon-lined stainless steel autoclave and heated at a temperature of 200 ℃ for 10 h. Finally, after naturally cooling to room temperature, the resulting solution was filtered through a 0.22 μm microporous membrane to obtain colorless g-C3N4Quantum dots (graphite phase carbon nitride).
(3) Compounding method
Adding 1mg of carbon quantum dots into the acrylamide solution prepared in the first step to ensure that the coating has certain photocatalysis, stirring the solution for 5 min in a water bath kettle at 30 ℃ at a rotating speed of 200 rpm, finally placing the solution under a 200W 365nm ultraviolet lamp, and illuminating for 60min to obtain the coating described in the example 5, and then performing the same coating method and measuring method as those in the example 1 to measure the performance of the coating prepared in the example 5;
example 6
Fixing the addition amount of acrylamide in the step (1) to 5.3848 g, changing the addition amount of carbon quantum dots in the step (3) to 2 mg, and using the amount and preparation steps of other experimental materials to the same as those of the example 5 to obtain the coating prepared in the example 6, and then performing the same coating method and measurement method as those of the example 1 to measure the performance of the coating prepared in the example 6;
example 7
Fixing the addition amount of acrylamide in the step (1) to 5.3848 g, changing the addition amount of carbon quantum dots in the step (3) to 3 mg, and using the amounts and preparation steps of other experimental materials to the same as those of the example 5 to obtain the coating prepared in the example 7, and then performing the same coating method and measurement method as those of the example 1 to measure the performance of the coating prepared in the example 7;
example 8
Fixing the addition amount of acrylamide in the step (1) to 5.3848 g, changing the addition amount of carbon quantum dots in the step (3) to 0mg, simultaneously adding an antistatic agent of tin antimony oxide before heating and stirring in a water bath kettle in the step (3) to ensure that the mass fraction of the antistatic agent in the solution is 2 ‱, and carrying out the same application and preparation steps as those of the example 5 on the other experimental materials to obtain the coating prepared in the example 8, and then carrying out the same application method and measurement method as those of the example 1 to measure the performance of the coating prepared in the example 8;
the performance effects of the coatings described in examples 5-8 are shown in Table 2, and the addition of carbon quantum dots imparts photocatalytic performance to the coatings, but does not impart antistatic properties to the coatings; antistatic properties can be achieved by the specific addition of antistatic agents to the solution.
Example 9
The amount of acrylamide added in step (1) was fixed to 5.3848 g, the amount of carbon quantum dots added in step (3) was fixed to 1mg, antimony tin oxide was added as an antistatic agent to the solution so that the final mass fraction was 2 ‱, the amounts of other experimental materials and the preparation steps were the same as those of example 5, to obtain the coating material prepared in example 9, and then the same coating method and measurement method as those of example 1 were performed to measure the properties of the coating material prepared in example 9.
Table 2: comparison of the Properties of the coatings of examples 4, 5, 6, 7, 8, 9
| Example of implementation | Transparency of | Hydrophilicity | Hardness of | Aging resistance | Photocatalytic property | Antistatic properties |
| Example 4 | √ | √ | √ | √ | × | × |
| Example 5 | √ | √ | √ | √ | √ | × |
| Example 6 | √ | √ | √ | √ | √ | × |
| Example 7 | × | √ | √ | √ | √ | × |
| Example 8 | √ | √ | √ | √ | × | √ |
| Example 9 | √ | √ | √ | √ | √ | √ |
From table 2, it is known that the addition of a certain amount of carbon quantum dots and tin antimony oxide not only does not affect the basic performance of the coating, but also enables the coating to have good photocatalysis and antistatic properties, which indicates that the coating prepared by the method of the present invention not only has good transparency and hydrophilicity and good adhesion, but also has both photocatalysis and antistatic properties, and has good effects on antifouling and self-cleaning of building material surfaces.
The invention relates to a method and a basis for measuring the performance of a coating of an article.
(1) Transparency: according to the GB/T5433-2008 daily glass luminous transmittance determination method, the transmissivity of glass coated with the coating is detected by a spectrophotometer, if the luminous transmittance of the coating is more than 51 percent, the coating is judged to have transparency, the color difference between the coating and a blank coating can be visually observed, and if no obvious difference exists, the coating can be judged to have transparency;
(2) hydrophilicity: according to the national standard GB/T24368-2009 glass surface hydrophobic pollutant detection contact angle measurement method, dripping liquid drops on a detected surface through an installed syringe, photographing lying drops, measuring an angle by using a protractor, and judging that the coating has hydrophilicity if the water contact angle is less than 20 degrees;
(3) hardness: according to the national standard GB/T6739-2006 colored paint and varnish pencil method for determining paint film hardness, a mechanical trolley for fixing a pencil with certain hardness is placed on a test plate coated with a coating to be detected, the test plate is pushed for at least 7mm, then a magnifier is used for observing whether scratches exceeding 3mm are left, and if the pencil with the hardness of 2H is scratched, no trace is left, the pencil with the hardness of 2H can be judged to have better hardness;
(4) aging resistance: according to the national standard GB/T1865-2009 color paint and varnish artificial weathering and artificial radiation exposure filtering xenon arc radiation, a test plate coated with a coating is placed in an artificial weathering box, and the radiation intensity of a xenon lamp is set to be 50W/m2If the coating still has hydrophilicity after being irradiated for 50 hours, judging that the coating has the anti-aging performance;
(5) photocatalytic performance: spraying 10mg/L methylene blue solution on the coating, standing for 10h under natural illumination, and observing the surface of the coating by visual observation, wherein if blue liquid drop traces are not obvious, the coating can be judged to be photocatalytic;
(6) antistatic property: referring to GB/T1410-2006 solid insulating material volume resistivity and surface resistivity test method, a surface resistance tester is directly placed on the surface of the coating, and if the surface resistivity is measured to be less than 1 multiplied by 109 Omega/m, the coating is judged to have antistatic property, or if the amount of the loose powder staying on the surface of the coating is less than 20 percent, the coating is judged to have antistatic property by lightly scattering the loose powder on the surface of the coating which is vertically placed.
Claims (10)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110135464.3A CN113004728A (en) | 2021-02-01 | 2021-02-01 | Coating with hydrophilic self-cleaning capability and preparation method thereof |
| CN202210063901.XA CN114350192B (en) | 2021-02-01 | 2022-01-20 | A kind of coating with hydrophilic self-cleaning ability and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110135464.3A CN113004728A (en) | 2021-02-01 | 2021-02-01 | Coating with hydrophilic self-cleaning capability and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113004728A true CN113004728A (en) | 2021-06-22 |
Family
ID=76385533
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110135464.3A Pending CN113004728A (en) | 2021-02-01 | 2021-02-01 | Coating with hydrophilic self-cleaning capability and preparation method thereof |
| CN202210063901.XA Active CN114350192B (en) | 2021-02-01 | 2022-01-20 | A kind of coating with hydrophilic self-cleaning ability and preparation method thereof |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210063901.XA Active CN114350192B (en) | 2021-02-01 | 2022-01-20 | A kind of coating with hydrophilic self-cleaning ability and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN113004728A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115594998A (en) * | 2022-11-02 | 2023-01-13 | 中南林业科技大学（Cn） | A composite coating with photocatalytic self-cleaning ability and its preparation method and application |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102391430A (en) * | 2005-06-03 | 2012-03-28 | 三菱化学株式会社 | Method for producing modified polyolefin solution |
| KR101603932B1 (en) * | 2011-09-30 | 2016-03-25 | 디아이씨 가부시끼가이샤 | Active energy beam-curable resin composition, method for producing thereof, coating, coating film, and film |
| KR20130091593A (en) * | 2012-02-08 | 2013-08-19 | (주)석경에이티 | Hybrid resin comprising acryl monomer and silica microparticle having good transparency and, uv curing composition using the same |
| CN102585691B (en) * | 2012-02-13 | 2014-06-11 | 长沙市原鹏化工科技有限公司 | Ultraviolet-cured hydrophilic coating composition and preparation method thereof |
| CN104479437B (en) * | 2015-01-06 | 2017-01-25 | 东华大学 | Preparation method for super-hydrophobic self-luminous coating |
| CN106185846A (en) * | 2015-05-08 | 2016-12-07 | 香港中文大学深圳研究院 | The preparation method of graphite phase carbon nitride nanometer sheet, nano belt and quantum dot |
| CN105176293B (en) * | 2015-08-31 | 2018-06-01 | 福州富兰机电技术开发有限公司 | Super hydrophilic coating and preparation method thereof and super-hydrophilic coating and preparation method |
| CN105671951B (en) * | 2016-01-26 | 2018-05-18 | 苏州榕绿纳米科技有限公司 | A kind of method of substrate surface wellability regulation and control |
| CN106497302B (en) * | 2016-10-17 | 2018-10-23 | 东华大学 | Photocatalytic self-cleaning parents' network marine anti-pollution coating and preparation method thereof |
| CN106497391A (en) * | 2016-10-26 | 2017-03-15 | 上海维凯光电新材料有限公司 | Ultraviolet light polymerization Weather-proof self-cleaning coating composition |
| CN106752857A (en) * | 2016-11-28 | 2017-05-31 | 江南大学 | A kind of preparation method of the super hydrophilic antifogging coating of dual cure acrylate |
| CN107236425B (en) * | 2017-06-23 | 2019-12-24 | 南京工业大学 | A self-cleaning UV-cured transparent heat-insulating coating and its preparation method |
| CN108300200A (en) * | 2017-12-23 | 2018-07-20 | 湛江正信科技服务有限公司 | A kind of waterborne UV coating and preparation method thereof |
| CN108250942A (en) * | 2018-01-29 | 2018-07-06 | 南通科达建材股份有限公司 | A kind of preparation method of the waterproof coating of spliced house wall surface |
| CN108948290B (en) * | 2018-05-25 | 2020-11-24 | 东南大学 | A kind of flexible hydrophilic material and its preparation method and application |
| CN108913023A (en) * | 2018-06-13 | 2018-11-30 | 北京化工大学 | A kind of preparation method of ultraviolet curing acrylic ester polysiloxanes clear coat |
| CN112262189B (en) * | 2018-07-06 | 2022-05-03 | 楠本化成株式会社 | Surface conditioner for water-based coating, water-based coating composition, coating film, and multilayer coating film |
| CN109111850A (en) * | 2018-07-16 | 2019-01-01 | 福建师范大学 | A method of super hydrophilic antifog spray is prepared by mercapto alkenyl click-reaction |
| CN109868025B (en) * | 2019-02-27 | 2021-06-08 | 江西省龙海化工有限公司 | Preparation method of water-based normal-temperature self-crosslinking super-hydrophilic anti-fog coating |
| CN109929359A (en) * | 2019-02-27 | 2019-06-25 | 江西省龙海化工有限公司 | Super hydrophilic anti-fog coating of a kind of UV solidification and preparation method thereof |
| CN111021043B (en) * | 2019-12-31 | 2020-12-22 | 华南理工大学 | Ultraviolet light curing organosilicon/silica hybrid superhydrophobic fabric and preparation method thereof |
| CN111234288A (en) * | 2020-01-19 | 2020-06-05 | 东华大学 | Preparation method of hydrophilic polymer antifogging coating |
-
2021
- 2021-02-01 CN CN202110135464.3A patent/CN113004728A/en active Pending
-
2022
- 2022-01-20 CN CN202210063901.XA patent/CN114350192B/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115594998A (en) * | 2022-11-02 | 2023-01-13 | 中南林业科技大学（Cn） | A composite coating with photocatalytic self-cleaning ability and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114350192B (en) | 2023-01-06 |
| CN114350192A (en) | 2022-04-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109181536B (en) | Transparent super-hydrophobic super-oleophobic SiO2Preparation method and application of nano functional liquid | |
| CN110317476B (en) | Nano functional coating and preparation method and application thereof | |
| CN106380981B (en) | A kind of modified nano-titanium dioxide self-cleaning coating and preparation method thereof | |
| CN107902918B (en) | Preparation method of anti-reflection and anti-reflection film layer | |
| CN103289031B (en) | High-transparency super-hydrophobicity coating material and application thereof | |
| CN108299869A (en) | High-strength super-hydrophobic self-cleaning coating, high-strength anti-reflection super-hydrophobic self-cleaning coating and preparation methods thereof | |
| CN105349036B (en) | A kind of water-based transparent superamphiphobic nano coating and its preparation method and application | |
| CN108003710B (en) | A superhydrophobic visible light photocatalytic self-cleaning coating and its preparation method | |
| WO2007097284A1 (en) | Uniformly dispersed photocatalyst coating liquid, method for producing same, and photocatalytically active composite material obtained by using same | |
| CN102849962A (en) | Preparation method of SiO2 super-hydrophobic film and super-hydrophobic material | |
| CN111534162A (en) | Montmorillonite-based photocatalytic super-hydrophobic coating and preparation method thereof | |
| CN105038338B (en) | Transparent hydrophobic spray and its preparation method and application | |
| CN113061357B (en) | A kind of antireflection hydrophobic coating and preparation method thereof | |
| CN111040527A (en) | Heat-reflecting super-hydrophobic PVDF coating and preparation method thereof | |
| CN113683953A (en) | Preparation method of renewable double self-cleaning super-hydrophobic photocatalytic coating | |
| WO2021139215A1 (en) | Self-healing or reusable product, preparation method therefor, and application thereof | |
| CN113754308A (en) | Preparation method of super-amphiphobic antifouling transparent coating | |
| CN113500838B (en) | High-strength self-cleaning reflective film and preparation method thereof | |
| CN106433219A (en) | Tungsten/fluorine codoped vanadium dioxide nanometer heat insulation sizing agent, tungsten/fluorine codoped vanadium dioxide paint film by means of sizing agent and preparation method | |
| CN115806748A (en) | A preparation method and application of a nano-coating material for photovoltaic panels | |
| CN105820710B (en) | It is a kind of can practical application the super-hydrophobic protective coating of high intensity preparation method | |
| CN113004728A (en) | Coating with hydrophilic self-cleaning capability and preparation method thereof | |
| CN105273454B (en) | Nano inorganic zinc-rich composite anticorrosion coating and preparation method thereof | |
| CN109306243A (en) | A kind of oil-resistant superhydrophobic coating and preparation method and application thereof | |
| CN110373050B (en) | A kind of hydrophobic SiO2 nanometer mixed liquid, functional coating and preparation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20210622 |