CN113004707B - A kind of additive for high-viscosity and high-elastic asphalt and its preparation method and application - Google Patents
A kind of additive for high-viscosity and high-elastic asphalt and its preparation method and application Download PDFInfo
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Abstract
本发明涉及一种用于高粘高弹沥青的添加剂及其制备方法和应用,属于沥青助剂的技术领域,该添加剂包括如下重量份的组分:石油树脂5~15份、萜烯树脂5~15份、萜烯酚醛树脂3~8份、热塑性弹性体60~80份、乙烯‑醋酸乙烯共聚物5~15份、酰胺类分散剂1~2份;以热塑性弹性体为主材,添加石油树脂、萜烯树脂、萜烯酚醛树脂作为增粘树脂,添加乙烯‑醋酸乙烯共聚物作为增强剂与相容剂,该添加剂在与沥青、粗集料和细集料拌和过程中受高温的作用软化,与沥青和粗集料、细集料充分结合,并填充嵌挤到级配骨架的空隙中,限制了粗集料、细集料间的相对滑动,增强了沥青与粗集料、细集料的结合强度。The invention relates to an additive for high-viscosity and high-elastic asphalt, a preparation method and application thereof, and belongs to the technical field of asphalt additives. The additive comprises the following components in parts by weight: 5-15 parts of petroleum resin, 5 parts of terpene resin ~15 parts, 3-8 parts of terpene phenolic resin, 60-80 parts of thermoplastic elastomer, 5-15 parts of ethylene-vinyl acetate copolymer, 1-2 parts of amide-based dispersant; using thermoplastic elastomer as the main material, adding Petroleum resin, terpene resin, terpene phenolic resin are used as tackifying resin, and ethylene-vinyl acetate copolymer is added as reinforcing agent and compatibilizer. The additive is subjected to high temperature during mixing with asphalt, coarse aggregate and fine aggregate. It softens by action, fully combines with asphalt, coarse aggregate and fine aggregate, and fills and inserts into the gap of the graded skeleton, restricts the relative sliding between coarse aggregate and fine aggregate, and strengthens asphalt, coarse aggregate, and fine aggregate. Bond strength of fine aggregates.
Description
技术领域technical field
本发明涉及沥青助剂的技术领域,尤其是涉及一种用于高粘高弹沥青的添加剂及其制备方法和应用。The invention relates to the technical field of asphalt additives, in particular to an additive for high-viscosity and high-elasticity asphalt and a preparation method and application thereof.
背景技术Background technique
OGFC彩色透水沥青路面是采用高粘彩色改性沥青、颜料及大空隙(一般在20%左右)优质骨料铺设而成的彩色路面,它具有优良的排水、防滑、降噪等功能,为一种安全、环保的生态沥青混凝土路面铺装技术,适用于国家大力建设的海绵城市;另外,OGFC除具有排水、防滑、降噪等功能外,通过色彩变化还可划分不同性质的交通区间;通过在道路急转弯陡坡处、十字路口、儿童上学道路、加油站等特殊路段采用彩色路面铺装,可起到警示作用;还可缓解视觉疲劳;美化街路空间环境,使路街空间成为人们喜爱的城市高质量生活空间。OGFC color permeable asphalt pavement is a colored pavement made of high-viscosity colored modified asphalt, pigments and high-quality aggregates with large voids (generally about 20%). It has excellent drainage, anti-skid, noise reduction and other functions. It is a safe and environmentally friendly ecological asphalt concrete pavement pavement technology, which is suitable for the sponge city that the country is vigorously building; in addition, OGFC has functions such as drainage, anti-skid, noise reduction, etc. Color pavement is used in special sections such as sharp turns and steep slopes, intersections, children's school roads, and gas stations, which can play a warning role; it can also relieve visual fatigue; beautify the street space environment and make the street space a favorite among people Urban high-quality living space.
排水式OGFC路面一般包括以下几个结构层:排水沥青混合料上面层、乳化沥青防水粘层、密级配沥青混凝土中面层、密级沥青混凝土下面层、半刚性基层及底基层;其中,在排水沥青混合料上面层内,排水沥青混合料的粗集料多、细集料少,颗粒之间不能形成强有力的嵌锁作用,沥青与粗集料、细集料的结合强度主要依靠胶结料的粘结作用,因此,研发出能够将排水沥青混合料中粗集料、细集料与沥青牢固粘结的高粘添加剂迫在眉睫。Drainage OGFC pavement generally includes the following structural layers: drainage asphalt mixture upper layer, emulsified asphalt waterproof adhesive layer, dense-grade asphalt concrete middle surface layer, dense-grade asphalt concrete lower layer, semi-rigid base layer and sub-base; In the upper layer of the asphalt mixture, the drainage asphalt mixture has more coarse aggregates and less fine aggregates, and a strong interlocking effect cannot be formed between particles. The bonding strength of asphalt and coarse aggregates and fine aggregates mainly depends on cementitious materials. Therefore, it is imminent to develop a high-viscosity additive that can firmly bond the coarse aggregate, fine aggregate and asphalt in the drainage asphalt mixture.
发明内容SUMMARY OF THE INVENTION
本发明的目的是提供一种用于高粘高弹沥青的添加剂及其制备方法和应用,将该添加剂应用在排水沥青中,可显著提高沥青与粗集料、细集料的结合强度。The purpose of the present invention is to provide an additive for high-viscosity and high-elasticity asphalt and its preparation method and application. The additive can be used in drainage asphalt to significantly improve the bonding strength of asphalt and coarse aggregate and fine aggregate.
本发明的上述发明目的一是通过以下技术方案得以实现的:One of the above-mentioned purposes of the present invention is achieved through the following technical solutions:
一种用于高粘高弹沥青的添加剂,包括如下重量份的组分:An additive for high-viscosity and high-elastic asphalt, comprising the following components in parts by weight:
石油树脂5~15份、萜烯树脂5~15份、萜烯酚醛树脂3~8份、热塑性弹性体60~80份、乙烯-醋酸乙烯共聚物5~15份、酰胺类分散剂1~2份。5-15 parts of petroleum resin, 5-15 parts of terpene resin, 3-8 parts of terpene phenolic resin, 60-80 parts of thermoplastic elastomer, 5-15 parts of ethylene-vinyl acetate copolymer, 1-2 parts of amide type dispersant share.
通过采用上述技术方案,以热塑性弹性体为主材,保证该添加剂具有优异的高弹性,同时还可保证该添加剂具有良好的耐低温性;添加石油树脂、萜烯树脂、萜烯酚醛树脂作为增粘树脂,添加乙烯-醋酸乙烯共聚物后,可显著提高沥青在60℃下的动力粘度,两种组分均可提高粗集料、细集料与沥青的结合强度,乙烯-醋酸乙烯共聚物也可以作为相容剂,有助于增粘树脂与热塑性弹性体的结合;采用上述各组分进行复配,配伍设计合理,实现制备了一种添加剂,该添加剂在与沥青、粗集料和细集料拌和过程中受高温的作用软化,与沥青和粗集料、细集料充分结合,并填充嵌挤到级配骨架的空隙中,限制了粗集料、细集料间的相对滑动,增强了排水沥青混合料之间的相互作用力,从而提高沥青与粗集料、细集料的结合强度;该添加剂应用在沥青中,还可提高沥青的高弹性与耐低温性。By adopting the above technical scheme, the thermoplastic elastomer is used as the main material to ensure that the additive has excellent high elasticity, and at the same time, it can also ensure that the additive has good low temperature resistance; Adhesive resin, after adding ethylene-vinyl acetate copolymer, can significantly improve the dynamic viscosity of asphalt at 60 ℃, both components can improve the bonding strength of coarse aggregate, fine aggregate and asphalt, ethylene-vinyl acetate copolymer It can also be used as a compatibilizer to help the combination of tackifying resin and thermoplastic elastomer; the above components are used for compounding, and the compatibility design is reasonable. During the mixing process of fine aggregate, it is softened by the action of high temperature, fully combined with asphalt, coarse aggregate and fine aggregate, and is filled and extruded into the gap of the graded skeleton, which limits the relative sliding between coarse aggregate and fine aggregate. , which enhances the interaction between the drainage asphalt mixture, thereby improving the bonding strength of asphalt and coarse aggregate and fine aggregate; the additive is used in asphalt, and can also improve the high elasticity and low temperature resistance of asphalt.
本发明进一步设置为:所述热塑性弹性体选用充油SBS、TPU的一种或以重量比为1:1复配。The present invention is further provided as follows: the thermoplastic elastomer is selected from one of oil-extended SBS and TPU, or is compounded with a weight ratio of 1:1.
通过采用上述技术方案,SBS是丁苯热塑性弹性体的简称,具有质轻、弹性好和耐低温性的优点,采用充油SBS是小分子油脂嵌入大分子的SBS中,充油后可以减小大分子之间的相互作用力,产生润滑作用,宏观上表现为充油SBS具有良好的柔软性、流动性,易与其他组分进行混合,提高该添加剂与沥青的易结合性;TPU是热塑性聚氨酯弹性体橡胶,硬度范围宽,具有良好的耐磨、耐油、透明和高弹性能,而且在零下40~60℃不变形、扭曲不开裂,采用充油SBS、TPU中的一种或者二者复配,作为该添加剂的主材,可显著提高该添加剂的高弹性与耐低温性。By adopting the above technical solution, SBS is the abbreviation of styrene-butadiene thermoplastic elastomer, which has the advantages of light weight, good elasticity and low temperature resistance. Oil-filled SBS is a small-molecule grease embedded in macromolecular SBS, which can be reduced after oil-filled. The interaction between macromolecules produces lubricating effect. Macroscopically, oil-extended SBS has good softness and fluidity, and is easy to be mixed with other components to improve the easy combination of the additive and asphalt; TPU is thermoplastic. Polyurethane elastomer rubber, with a wide range of hardness, good wear resistance, oil resistance, transparency and high elastic properties, and no deformation, twisting and cracking at minus 40 ~ 60 ℃, using one or both of oil-filled SBS and TPU Compounding, as the main material of the additive, can significantly improve the high elasticity and low temperature resistance of the additive.
本发明进一步设置为:所述充油SBS采用如下方法制备:将10~15重量份芳烃油浸渍在100重量份SBS中静置1~2h,然后将充油SBS放置在开炼机上,在110~115℃下共混30~45min;滴入3~5重量份的脂肪醇聚氧乙烯醚,混炼均匀。The present invention is further provided as follows: the oil-extended SBS is prepared by the following method: 10-15 parts by weight of aromatic hydrocarbon oil is immersed in 100 parts by weight of SBS and allowed to stand for 1-2 hours; Blend at ~115°C for 30 to 45 minutes; drop 3 to 5 parts by weight of fatty alcohol polyoxyethylene ether, and mix uniformly.
通过采用上述技术方案,SBS中采用芳烃油浸渍,芳烃油具有改善加工性能的作用,充油SBS有助于提高与其他组分的混合、分散性能,芳烃油的主要成分为芳香分和胶质,沥青的主要成分为芳香分、胶质、沥青质等,根据相似相容作用,有利于提高充油SBS与沥青的结合性,另外,加入芳烃油后,可最大程度增大沥青的耐低温性;脂肪醇聚氧乙烯醚具有良好的去污力、润湿、乳化、抗硬水性,滴入脂肪醇聚氧乙烯醚,可促进芳烃油在SBS内的浸渍、溶解,采用上述方法制备的充油SBS具有优异的易加工性、耐低温性。By adopting the above technical solution, the SBS is impregnated with aromatic oil, which can improve the processing performance. The oil-extended SBS helps to improve the mixing and dispersing performance with other components. The main components of the aromatic oil are aromatics and colloids. The main components of asphalt are aromatics, colloids, asphaltenes, etc. According to the similar compatibility, it is beneficial to improve the binding between oil-extended SBS and asphalt. In addition, adding aromatic oil can maximize the low temperature resistance of asphalt. The fatty alcohol polyoxyethylene ether has good detergency, wetting, emulsifying, and hard water resistance. The dripping of the fatty alcohol polyoxyethylene ether can promote the impregnation and dissolution of the aromatic oil in SBS. Oil-extended SBS has excellent workability and low temperature resistance.
本发明进一步设置为:所述石油树脂选用以重量比为1:1复配的C5石油树脂和C9石油树脂。The present invention is further provided as follows: the petroleum resin is selected from C5 petroleum resin and C9 petroleum resin compounded in a weight ratio of 1:1.
通过采用上述技术方案,C5石油树脂具有较高的剥离粘接强度、快粘性好、粘接性能稳定,与沥青基组分的相容性良好,还具有优良的抗老化性;C9石油树脂含有双键,内聚力大,与萜烯树脂、热塑性弹性弹性体的相容性良好,还具有增粘作用,将C5石油树脂与C9石油树脂复配使用,具有优异的增粘作用和抗老化性能,复配后可显著提高与萜烯树脂、萜烯酚醛树脂与热塑性弹性体的相容性,并且与沥青基组分的相容性良好。By adopting the above technical solutions, C5 petroleum resin has high peeling adhesive strength, good fast tack, stable adhesive performance, good compatibility with asphalt-based components, and excellent anti-aging properties; C9 petroleum resin contains Double bond, large cohesion, good compatibility with terpene resin and thermoplastic elastomer, and also has a tackifying effect. The compound use of C5 petroleum resin and C9 petroleum resin has excellent tackifying effect and anti-aging properties. After compounding, the compatibility with terpene resin, terpene phenolic resin and thermoplastic elastomer can be significantly improved, and the compatibility with asphalt-based components is good.
本发明进一步设置为:所述乙烯-醋酸乙烯共聚物中醋酸乙烯含量为35~40%。The present invention is further set as follows: the vinyl acetate content in the ethylene-vinyl acetate copolymer is 35-40%.
通过采用上述技术方案,限定乙烯-醋酸乙烯共聚物中醋酸乙烯的含量为35~40%,大大降低了乙烯-醋酸乙烯共聚物中支链的结晶度,增大了分子链之间的距离,相比于采用PE材料,该添加剂具有更优异的弹性和柔软性。By adopting the above technical scheme, the content of vinyl acetate in the ethylene-vinyl acetate copolymer is limited to 35-40%, which greatly reduces the crystallinity of the branched chains in the ethylene-vinyl acetate copolymer, and increases the distance between the molecular chains. Compared with PE material, the additive has better elasticity and softness.
本发明的上述发明目的二是通过以下技术方案得以实现的:The second purpose of the present invention is achieved through the following technical solutions:
一种用于高粘高弹沥青的添加剂的制备方法,包括如下步骤:A preparation method of an additive for high-viscosity and high-elasticity asphalt, comprising the steps:
(1)配料:按照重量份,称量石油树脂5~15份、萜烯树脂5~15份、萜烯酚醛树脂3~8份、热塑性弹性体60~80份、乙烯-醋酸乙烯共聚物5~15份、酰胺类分散剂1~2份;(1) Ingredients: According to parts by weight, weigh 5-15 parts of petroleum resin, 5-15 parts of terpene resin, 3-8 parts of terpene phenolic resin, 60-80 parts of thermoplastic elastomer, 5 parts of ethylene-vinyl acetate copolymer ~15 parts, 1-2 parts of amide dispersant;
(2)将热塑性弹性体、石油树脂、萜烯树脂、萜烯酚醛树脂、乙烯-醋酸乙烯共聚物和酰胺类分散剂进行均匀混合,形成预成型体;(2) uniformly mixing thermoplastic elastomer, petroleum resin, terpene resin, terpene phenolic resin, ethylene-vinyl acetate copolymer and amide dispersant to form a preform;
(3)将预成型体投入双螺杆挤出机中,在205~215℃下剪切搅拌1.5~2h,然后模头在150~160℃下挤出成型;(3) Put the preform into a twin-screw extruder, shear and stir at 205-215°C for 1.5-2 hours, and then extrude the die at 150-160°C;
(4)造粒。(4) Granulation.
通过采用上述技术方案,将热塑性弹性体、石油树脂、萜烯树脂、萜烯酚醛树脂和乙烯-醋酸乙烯共聚物进行混合,待混合均匀后,将混合物投入双螺杆挤出机中,加工过程方便、快捷,成型稳定。By adopting the above technical scheme, thermoplastic elastomer, petroleum resin, terpene resin, terpene phenolic resin and ethylene-vinyl acetate copolymer are mixed, and after mixing uniformly, the mixture is put into a twin-screw extruder, and the processing process is convenient , fast, stable molding.
本发明的上述发明目的三是通过以下技术方案得以实现的:The third purpose of the present invention is achieved through the following technical solutions:
一种用于高粘高弹沥青的添加剂的应用,所述添加剂应用在制备高弹高粘沥青、铺装OTFG透水沥青路面、SMA路面或者钢桥面铺装中。An application of an additive for high-viscosity and high-elasticity asphalt, which is used in preparing high-elasticity and high-viscosity asphalt, paving OTFG permeable asphalt pavement, SMA pavement or steel bridge deck pavement.
通过采用上述技术方案,该添加剂可适用于制备高粘高弹沥青中,还可添加至铺装OTFG透水沥青路面、SMA路面或者钢桥面中,可显著提高沥青或者路面、桥面的整体强度、高弹性与耐低温性。By adopting the above technical solution, the additive can be applied to the preparation of high-viscosity and high-elastic asphalt, and can also be added to pavement of OTFG permeable asphalt pavement, SMA pavement or steel bridge deck, which can significantly improve the overall strength of asphalt or pavement and bridge deck. , High elasticity and low temperature resistance.
综上所述,本发明的有益技术效果为:To sum up, the beneficial technical effects of the present invention are:
1.高粘性:本申请以热塑性弹性体为主材,添加石油树脂、萜烯树脂与萜烯酚醛树脂作为增粘树脂,添加乙烯-醋酸乙烯共聚物,可进一步增粘,还可提高增粘树脂与主材的相容性,采用上述组分共混,可显著提高沥青与粗集料、细集料的结合强度;1. High viscosity: This application uses thermoplastic elastomer as the main material, adding petroleum resin, terpene resin and terpene phenolic resin as tackifying resin, adding ethylene-vinyl acetate copolymer, which can further increase the viscosity and improve the viscosity. Compatibility of resin and main material, blending the above components can significantly improve the bonding strength of asphalt with coarse aggregate and fine aggregate;
2.高弹性:该添加剂以热塑性弹性体为主材,有助于制备高弹性的添加剂,加入乙烯-醋酸乙烯共聚物,可进一步提高添加剂的弹性;采用充油SBS,可进一步提高沥青的高弹性;2. High elasticity: The additive is made of thermoplastic elastomer, which helps to prepare high-elasticity additives. The addition of ethylene-vinyl acetate copolymer can further improve the elasticity of the additive; the use of oil-extended SBS can further improve the high degree of asphalt. elasticity;
3.优异的耐低温性:以热塑性弹性体为主材,可保证该添加剂具有优良的耐低温性,三种树脂协同作用,还有利于促进成型沥青耐低温性的提高;添加乙烯-醋酸乙烯共聚物,还可促进成型后沥青的耐低温性;3. Excellent low temperature resistance: the thermoplastic elastomer as the main material can ensure that the additive has excellent low temperature resistance, and the synergistic effect of the three resins is also conducive to promoting the improvement of the low temperature resistance of molding asphalt; adding ethylene-vinyl acetate The copolymer can also promote the low temperature resistance of the asphalt after molding;
4.易加工性:选用的萜烯树脂、石油树脂和萜烯酚醛树脂熔解温度接近,加工难度低。4. Ease of processing: The selected terpene resin, petroleum resin and terpene phenolic resin have similar melting temperatures and low processing difficulty.
具体实施方式Detailed ways
以下结合实施例对本发明作进一步详细说明。The present invention will be described in further detail below in conjunction with the embodiments.
C5石油树脂、C9石油树脂、萜烯树脂、萜烯酚醛树脂均为市售,熔解温度约为120~140℃左右;酰胺类分散剂购自深圳市锦隆化工科技有限公司生产的沥青专用分散剂EBS;SBS选用巴陵石化公司生产的792E(YH-1401E)SBS颗粒;TPU选用德国巴斯夫生产的C85A10热塑性聚氨酯TPU颗粒;芳烃油选用淄博广懿石油化工有限公司生产的芳烃油。C5 petroleum resin, C9 petroleum resin, terpene resin, and terpene phenolic resin are all commercially available, and the melting temperature is about 120-140 °C; amide-based dispersants are purchased from Shenzhen Jinlong Chemical Technology Co., Ltd. Agent EBS; SBS selects 792E (YH-1401E) SBS particles produced by Baling Petrochemical Company; TPU selects C85A10 thermoplastic polyurethane TPU particles produced by Germany BASF; aromatic oil selects aromatic oil produced by Zibo Guangyi Petrochemical Co., Ltd.
原料制备例一:Example 1 of raw material preparation:
一种充油SBS,采用如下方法制备:将10重量份芳烃油浸渍在100重量份SBS中静置1.5h,然后将充油SBS放置在开炼机上,在110℃下共混40min;滴入3重量份的脂肪醇聚氧乙烯醚,混炼均匀。An oil-extended SBS is prepared by the following method: 10 parts by weight of aromatic hydrocarbon oil is immersed in 100 parts by weight of SBS and allowed to stand for 1.5 hours, then the oil-extended SBS is placed on an open mill, and blended at 110° C. for 40 minutes; 3 parts by weight of fatty alcohol polyoxyethylene ether, knead uniformly.
原料制备例二:Example 2 of raw material preparation:
一种充油SBS,采用如下方法制备:将12重量份芳烃油浸渍在100重量份SBS中静置1.5h,然后将充油SBS放置在开炼机上,在110℃下共混40min;滴入4重量份的脂肪醇聚氧乙烯醚,混炼均匀。An oil-extended SBS is prepared by the following method: 12 parts by weight of aromatic hydrocarbon oil is immersed in 100 parts by weight of SBS and allowed to stand for 1.5 hours, then the oil-extended SBS is placed on an open mill, and blended at 110° C. for 40 minutes; 4 parts by weight of aliphatic alcohol polyoxyethylene ether, knead uniformly.
原料制备例三:Raw material preparation example three:
一种充油SBS,采用如下方法制备:将15重量份芳烃油浸渍在100重量份SBS中静置1.5h,然后将充油SBS放置在开炼机上,在110℃下共混40min;滴入5重量份的脂肪醇聚氧乙烯醚,混炼均匀。An oil-extended SBS is prepared by the following method: 15 parts by weight of aromatic hydrocarbon oil is immersed in 100 parts by weight of SBS and allowed to stand for 1.5 hours, then the oil-extended SBS is placed on an open mill, and blended at 110° C. for 40 minutes; 5 parts by weight of fatty alcohol polyoxyethylene ether, knead uniformly.
实施例一:Example 1:
一种用于高粘高弹沥青的添加剂,采用如下方法制备:An additive for high-viscosity and high-elastic asphalt is prepared by the following method:
(1)配料:按照重量份,称量C5石油树脂2.5份、C9石油树脂2.5份、萜烯树脂5份、萜烯酚醛树脂3份、原料制备例一制备的充油SBS 60份、乙烯-醋酸乙烯共聚物5份、酰胺类分散剂1份;(1) batching: according to parts by weight, weigh 2.5 parts of C5 petroleum resins, 2.5 parts of C9 petroleum resins, 5 parts of terpene resins, 3 parts of terpene phenolic resins, 60 parts of oil-extended SBS prepared by raw material preparation example 1, ethylene- 5 parts of vinyl acetate copolymer, 1 part of amide dispersant;
(2)将充油SBS、石油树脂、萜烯树脂、萜烯酚醛树脂、乙烯-醋酸乙烯共聚物和酰胺类分散剂进行均匀混合,形成预成型体;(2) uniformly mixing oil-extended SBS, petroleum resin, terpene resin, terpene phenolic resin, ethylene-vinyl acetate copolymer and amide dispersant to form a preform;
(3)将预成型体投入双螺杆挤出机中,在210℃下剪切搅拌2h,然后模头温度为150℃下挤出成型;(3) Put the preform into a twin-screw extruder, shear and stir at 210°C for 2 hours, and then extrude at a die temperature of 150°C;
(4)造粒。(4) Granulation.
实施例二:Embodiment 2:
一种用于高粘高弹沥青的添加剂,与实施例一的区别之处在于充油SBS选用原料制备例二制备。An additive for high-viscosity and high-elasticity asphalt, the difference from Example 1 is that the oil-extended SBS is prepared by selecting raw materials from Preparation Example 2.
实施例三:Embodiment three:
一种用于高粘高弹沥青的添加剂,与实施例一的区别之处在于充油SBS选用原料制备例三制备。An additive for high-viscosity and high-elastic asphalt, the difference from Example 1 is that the oil-extended SBS is prepared by selecting raw materials from Preparation Example 3.
实施例四:Embodiment 4:
一种用于高粘高弹沥青的添加剂,采用如下方法制备:An additive for high-viscosity and high-elastic asphalt is prepared by the following method:
(1)配料:按照重量份,称量C5石油树脂4份、C9石油树脂4份、萜烯树脂7份、萜烯酚醛树脂5份、原料制备例二制备的充油SBS 65份、乙烯-醋酸乙烯共聚物8份、酰胺类分散剂1.2份;(1) batching: according to parts by weight, weigh 4 parts of C5 petroleum resins, 4 parts of C9 petroleum resins, 7 parts of terpene resins, 5 parts of terpene phenolic resins, 65 parts of oil-extended SBS prepared by raw material preparation example 2, ethylene- 8 parts of vinyl acetate copolymer, 1.2 parts of amide dispersant;
(2)将充油SBS、石油树脂、萜烯树脂、萜烯酚醛树脂、乙烯-醋酸乙烯共聚物和酰胺类分散剂进行均匀混合,形成预成型体;(2) uniformly mixing oil-extended SBS, petroleum resin, terpene resin, terpene phenolic resin, ethylene-vinyl acetate copolymer and amide dispersant to form a preform;
(3)将预成型体投入双螺杆挤出机中,在210℃下剪切搅拌2h,然后模头温度为150℃下挤出成型;(3) Put the preform into a twin-screw extruder, shear and stir at 210°C for 2 hours, and then extrude at a die temperature of 150°C;
(4)造粒。(4) Granulation.
实施例五:Embodiment 5:
一种用于高粘高弹沥青的添加剂,采用如下方法制备:An additive for high-viscosity and high-elastic asphalt is prepared by the following method:
(1)配料:按照重量份,称量C5石油树脂5份、C9石油树脂5份、萜烯树脂10份、萜烯酚醛树脂6份、原料制备例二制备的充油SBS 70份、乙烯-醋酸乙烯共聚物10份、酰胺类分散剂1.5份;(1) batching: according to parts by weight, weigh 5 parts of C5 petroleum resins, 5 parts of C9 petroleum resins, 10 parts of terpene resins, 6 parts of terpene phenolic resins, 70 parts of oil-extended SBS prepared by raw material preparation example 2, ethylene- 10 parts of vinyl acetate copolymer, 1.5 parts of amide dispersant;
(2)将充油SBS、石油树脂、萜烯树脂、萜烯酚醛树脂、乙烯-醋酸乙烯共聚物和酰胺类分散剂进行均匀混合,形成预成型体;(2) uniformly mixing oil-extended SBS, petroleum resin, terpene resin, terpene phenolic resin, ethylene-vinyl acetate copolymer and amide dispersant to form a preform;
(3)将预成型体投入双螺杆挤出机中,在205℃下剪切搅拌2h,然后模头温度为155℃下挤出成型;(3) Put the preform into a twin-screw extruder, shear and stir at 205°C for 2 hours, and then extrude at a die temperature of 155°C;
(4)造粒。(4) Granulation.
实施例六:Embodiment 6:
一种用于高粘高弹沥青的添加剂,采用如下方法制备:An additive for high-viscosity and high-elastic asphalt is prepared by the following method:
(1)配料:按照重量份,称量C5石油树脂6.5份、C9石油树脂6.5份、萜烯树脂12份、萜烯酚醛树脂7份、原料制备例二制备的充油SBS 75份、乙烯-醋酸乙烯共聚物12份、酰胺类分散剂1.7份;(1) batching: according to parts by weight, weigh 6.5 parts of C5 petroleum resins, 6.5 parts of C9 petroleum resins, 12 parts of terpene resins, 7 parts of terpene phenolic resins, 75 parts of oil-extended SBS prepared by raw material preparation example two, ethylene- 12 parts of vinyl acetate copolymer, 1.7 parts of amide dispersant;
(2)将充油SBS、石油树脂、萜烯树脂、萜烯酚醛树脂、乙烯-醋酸乙烯共聚物和酰胺类分散剂进行均匀混合,形成预成型体;(2) uniformly mixing oil-extended SBS, petroleum resin, terpene resin, terpene phenolic resin, ethylene-vinyl acetate copolymer and amide dispersant to form a preform;
(3)将预成型体投入双螺杆挤出机中,在210℃下剪切搅拌2h,然后模头温度为160℃下挤出成型;(3) Put the preform into a twin-screw extruder, shear and stir at 210°C for 2 hours, and then extrude at a die temperature of 160°C;
(4)造粒。(4) Granulation.
实施例七:Embodiment 7:
一种用于高粘高弹沥青的添加剂,采用如下方法制备:An additive for high-viscosity and high-elastic asphalt is prepared by the following method:
(1)配料:按照重量份,称量C5石油树脂7.5份、C9石油树脂7.5份、萜烯树脂15份、萜烯酚醛树脂8份、原料制备例二制备的充油SBS 80份、乙烯-醋酸乙烯共聚物15份、酰胺类分散剂2份;(1) batching: according to parts by weight, weigh 7.5 parts of C5 petroleum resins, 7.5 parts of C9 petroleum resins, 15 parts of terpene resins, 8 parts of terpene phenolic resins, 80 parts of oil-extended SBS prepared by raw material preparation example two, ethylene- 15 parts of vinyl acetate copolymer, 2 parts of amide dispersant;
(2)将充油SBS、石油树脂、萜烯树脂、萜烯酚醛树脂、乙烯-醋酸乙烯共聚物和酰胺类分散剂进行均匀混合,形成预成型体;(2) uniformly mixing oil-extended SBS, petroleum resin, terpene resin, terpene phenolic resin, ethylene-vinyl acetate copolymer and amide dispersant to form a preform;
(3)将预成型体投入双螺杆挤出机中,在210℃下剪切搅拌2h,然后模头温度为160℃下挤出成型;(3) Put the preform into a twin-screw extruder, shear and stir at 210°C for 2 hours, and then extrude at a die temperature of 160°C;
(4)造粒。(4) Granulation.
实施例八:Embodiment 8:
一种用于高粘高弹沥青的添加剂,采用如下方法制备:An additive for high-viscosity and high-elastic asphalt is prepared by the following method:
(1)配料:按照重量份,称量C5石油树脂6.5份、C9石油树脂6.5份、萜烯树脂12份、萜烯酚醛树脂7份、TPU 75份、乙烯-醋酸乙烯共聚物12份、酰胺类分散剂1.7份;(1) Ingredients: according to parts by weight, weigh 6.5 parts of C5 petroleum resin, 6.5 parts of C9 petroleum resin, 12 parts of terpene resin, 7 parts of terpene phenolic resin, 75 parts of TPU, 12 parts of ethylene-vinyl acetate copolymer, amide 1.7 parts of dispersant;
(2)将TPU、石油树脂、萜烯树脂、萜烯酚醛树脂、乙烯-醋酸乙烯共聚物和酰胺类分散剂进行均匀混合,形成预成型体;(2) uniformly mixing TPU, petroleum resin, terpene resin, terpene phenolic resin, ethylene-vinyl acetate copolymer and amide dispersant to form a preform;
(3)将预成型体投入双螺杆挤出机中,在210℃下剪切搅拌2h,然后模头温度为160℃下挤出成型;(3) Put the preform into a twin-screw extruder, shear and stir at 210°C for 2 hours, and then extrude at a die temperature of 160°C;
(4)造粒。(4) Granulation.
实施例九:Embodiment 9:
一种用于高粘高弹沥青的添加剂,与实施例八相比区别之处在于采用的主材不同,将TPU 75份替换为充油SBS37.5份和TPU 37.5份。An additive for high-viscosity and high-elasticity asphalt, which is different from Example 8 in that the main material used is different, and 75 parts of TPU are replaced by 37.5 parts of oil-extended SBS and 37.5 parts of TPU.
实施例十:Embodiment ten:
一种涉及实施例一~实施例九的添加剂,该添加剂应用在铺装OTFG透水沥青路面中。An additive related to Embodiment 1 to Embodiment 9, which is applied in paving OTFG permeable asphalt pavement.
实施例十一:Embodiment eleven:
一种涉及实施例一~实施例九的添加剂,该添加剂还可应用在高粘高弹SMA沥青混合公路铺装、机场覆盖铺装、高架桥、高等级路面公路中。An additive related to Embodiment 1 to Embodiment 9, the additive can also be used in high-viscosity and high-elasticity SMA asphalt mixed road pavement, airport overlay pavement, viaduct, and high-grade road.
实施例十二:Embodiment 12:
一种涉及实施例一~实施例九的添加剂,该添加剂还可应用在钢桥面铺装中。An additive related to the first embodiment to the ninth embodiment, the additive can also be used in the steel bridge deck pavement.
对比例一:Comparative example 1:
一种用于高粘高弹沥青的添加剂,与实施例六的区别之处在于缺少乙烯-醋酸乙烯共聚物。An additive for high-viscosity and high-elastic asphalt, the difference from Example 6 is the lack of ethylene-vinyl acetate copolymer.
对比例二:Comparative example two:
一种用于高粘高弹沥青的添加剂,与实施例六的区别之处在于缺少萜烯酚醛树脂。An additive for high-viscosity and high-elastic asphalt, the difference from Example 6 is the lack of terpene phenolic resin.
对比例三:Comparative example three:
一种用于高粘高弹沥青的添加剂,与实施例六的区别之处在于缺少石油树脂。An additive for high-viscosity and high-elastic asphalt, the difference from Example 6 is the lack of petroleum resin.
对比例四:Comparative example four:
一种用于高粘高弹沥青的添加剂,与实施例六的区别之处在于缺少萜烯树脂。An additive for high-viscosity and high-elastic asphalt, the difference from Example 6 is the lack of terpene resin.
对比例五:Comparative example five:
一种用于高粘高弹沥青的添加剂,与实施例六的区别之处在于缺少石油树脂和萜烯树脂。An additive for high-viscosity and high-elastic asphalt, the difference from Example 6 is the lack of petroleum resin and terpene resin.
对比例六:Comparative Example 6:
一种用于高粘高弹沥青的添加剂,与实施例六的区别之处在于缺少石油树脂和萜烯酚醛树脂。An additive for high-viscosity and high-elastic asphalt, the difference from Example 6 lies in the lack of petroleum resin and terpene phenolic resin.
对比例七:Comparative example seven:
一种用于高粘高弹沥青的添加剂,与实施例六的区别之处在于缺少萜烯树脂和萜烯酚醛树脂。An additive for high-viscosity and high-elastic asphalt, the difference from Example 6 is the lack of terpene resin and terpene phenolic resin.
对比例八:购买沈阳熠道科技有限公司生产的高粘沥青改性剂作为参照。Comparative Example 8: The high-viscosity asphalt modifier produced by Shenyang Yidao Technology Co., Ltd. was purchased as a reference.
对比例九:Comparative example nine:
一种用于高粘高弹沥青的添加剂,与实施例二的区别之处在于热塑性弹性体采用未充油SBS。An additive for high-viscosity and high-elastic asphalt, the difference from Example 2 is that the thermoplastic elastomer adopts unoil-extended SBS.
检测手段:testing method:
本次试验检测过程所用原料情况如下:粗、细集料:北京石灰岩碎石;沥青:70号A级道路石油沥青;矿粉:采用北京生产矿粉,细度为400m2/kg;试验依据参照《公路工程沥青及沥青混合料试验规程》(JTG E20-2011)和《公路沥青路面施工技术规范》(JTG F40-2004)。The raw materials used in this test are as follows: Coarse and fine aggregates: Beijing limestone crushed stone; Asphalt: No. 70 grade A road petroleum asphalt; Mineral powder: Mineral powder produced in Beijing with a fineness of 400m 2 /kg; test basis Refer to "Asphalt and Asphalt Mixture Test Regulations for Highway Engineering" (JTG E20-2011) and "Technical Specification for Highway Asphalt Pavement Construction" (JTG F40-2004).
本次检测采用沥青为70#A级道路石油沥青,检测结果如下表所示:The asphalt used in this test is 70#A grade road petroleum asphalt. The test results are shown in the following table:
本检测所用混合料类型为AC-20C,具体级配见下表:The type of mixture used in this test is AC-20C, and the specific gradation is shown in the following table:
(1)结合强度:分别采用实施例与对比例涉及的添加剂,掺加入70#道路沥青中,按照以上合成级配配料,在油石比为4.4%条件下进行马歇尔试验,其中,添加剂掺量为沥青混合料总量的0.4%,检测结果如下表所示:(1) Bonding strength: The additives involved in the examples and the comparative examples were respectively added to 70# road asphalt, and the Marshall test was carried out under the condition that the oil-to-stone ratio was 4.4% according to the above synthetic grading ingredients. 0.4% of the total amount of asphalt mixture, the test results are shown in the following table:
通过上表可知,实施例一~实施例三和对比例九,可知采用充油SBS对于提高沥青混合料的整体强度有促进作用;根据实施例二、实施例四~实施例九可知,本申请的添加剂具有优异的高粘作用,可将沥青与粗集料、细集料牢固粘结;根据实施例样品与对比例一可知,采用乙烯-醋酸乙烯共聚物与增粘树脂共混,可达到优异的高粘作用,从而将沥青与粗集料、细集料进行混合;通过对比例二~对比例七可知,采用石油树脂、萜烯树脂与萜烯酚醛树脂共混,三者产生协同作用,可显著提高该添加剂的粘性;通过各实施例与对比例八可知,本申请的添加剂性能远远优于市售产品,具有高度的增粘作用,可提高沥青混合料的整体强度;另外,本申请的添加剂拒水性优异,经水浸泡后残留度较高,也是体现沥青使用时整体强度的重要指标。From the above table, it can be seen that in Examples 1 to 3 and Comparative Example 9, it can be seen that the use of oil-extended SBS can promote the improvement of the overall strength of the asphalt mixture; The additive has excellent high viscosity, which can firmly bond the asphalt with the coarse aggregate and fine aggregate; according to the example sample and the comparative example 1, it can be seen that the blend of ethylene-vinyl acetate copolymer and tackifying resin can achieve Excellent high viscosity, so as to mix asphalt with coarse aggregates and fine aggregates; from Comparative Examples 2 to 7, it can be seen that petroleum resin, terpene resin and terpene phenolic resin are used to blend, and the three have a synergistic effect. , which can significantly improve the viscosity of the additive; it can be seen from each example and comparative example 8 that the performance of the additive of the present application is far superior to that of the commercial product, has a high viscosity increasing effect, and can improve the overall strength of the asphalt mixture; in addition, The additive of the present application has excellent water repellency and high residual degree after being soaked in water, which is also an important indicator reflecting the overall strength of the asphalt in use.
(2)耐低温性:分别采用实施例与对比例涉及的添加剂,掺加入70#道路沥青中,添加剂掺量为沥青混合料总量的0.4%,按照以上合成级配配料,在油石比为4.4%条件下,在室内成型AC-20C沥青混合料试件进行耐低温性检测,检测结果如下表所示:(2) Low temperature resistance: The additives involved in the examples and the comparative examples are respectively used and added to the 70# road asphalt. The amount of the additives is 0.4% of the total amount of the asphalt mixture. According to the above synthetic grading ingredients, the oil-to-stone ratio is Under the condition of 4.4%, the low temperature resistance test of AC-20C asphalt mixture test piece formed indoors is carried out. The test results are shown in the following table:
通过上表可知,根据各实施例与对比例九可知,充油SBS相比于未充油SBS,充油样品可明显地提高沥青的耐低温性;根据实施例六和实施例八可知,热塑性弹性体采用TPU的样品,可达到与充油SBS相当的耐低温性;根据各实施例与对比例一可知,添加乙烯-醋酸乙烯共聚物对沥青的耐低温性有促进作用;根据对比例二~对比例七可知,石油树脂、萜烯树脂与萜烯酚醛树脂三者产生协同作用,除增粘作用外,还可提高沥青的耐低温性;根据对比例八可知,本申请添加剂的耐低温性明显优于同行产品。As can be seen from the above table, according to each example and comparative example 9, oil-extended SBS can significantly improve the low temperature resistance of asphalt compared with non-oil-extended SBS; Elastomers using TPU samples can achieve low temperature resistance equivalent to oil-extended SBS; according to each example and comparative example 1, it can be seen that adding ethylene-vinyl acetate copolymer has a promoting effect on the low temperature resistance of asphalt; according to comparative example 2 ~Comparative example 7 shows that petroleum resin, terpene resin and terpene phenolic resin have a synergistic effect, which can improve the low temperature resistance of asphalt in addition to the tackifying effect; The performance is obviously better than that of its peers.
(3)高弹性:试件规格为直径100mm、高度100mm的圆柱体,采用侧面法,在每个试验条件下,动载作用200个循环,取最后5个循环的应力与弹性应变幅值的平均值计算弹性模量,检测结果如下表所示:(3) High elasticity: The specimen specification is a cylinder with a diameter of 100mm and a height of 100mm. The lateral method is used. Under each test condition, the dynamic load is applied for 200 cycles, and the stress and elastic strain amplitude of the last 5 cycles are taken. The average value is used to calculate the elastic modulus, and the test results are shown in the following table:
通过上表可知,本申请的添加剂具有更优异的弹性,并且弹性变形量很低,与对比例八的样品相比,高弹性能明显优于同行产品;根据实施例与对比例一相比,添加乙烯-醋酸乙烯共聚物可促进提高沥青的高弹性能;热塑性弹性体采用充油SBS,相比于未充油样品,具有更优异的高弹性。It can be seen from the above table that the additive of the present application has more excellent elasticity, and the amount of elastic deformation is very low. The addition of ethylene-vinyl acetate copolymer can promote the improvement of the high elastic properties of asphalt; the thermoplastic elastomer adopts oil-extended SBS, which has better high elasticity than the non-oil-extended sample.
本具体实施方式的实施例均为本发明的较佳实施例,并非依此限制本发明的保护范围,故:凡依本发明的结构、形状、原理所做的等效变化,均应涵盖于本发明的保护范围之内。The embodiments of this specific embodiment are all preferred embodiments of the present invention, and are not intended to limit the protection scope of the present invention. Therefore: all equivalent changes made according to the structure, shape and principle of the present invention should be covered in within the protection scope of the present invention.
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Denomination of invention: An additive for high viscosity and high elasticity asphalt, its preparation method and application Granted publication date: 20220705 Pledgee: China Construction Bank Corporation Changzhou Xinbei sub branch Pledgor: CHANGZHOU LEADE NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: Y2025980010418 |