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CN112970655A - Little electrolysis hypochlorous acid sterilizer device of deep sea aquaculture net case - Google Patents

Little electrolysis hypochlorous acid sterilizer device of deep sea aquaculture net case Download PDF

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Publication number
CN112970655A
CN112970655A CN202110206167.3A CN202110206167A CN112970655A CN 112970655 A CN112970655 A CN 112970655A CN 202110206167 A CN202110206167 A CN 202110206167A CN 112970655 A CN112970655 A CN 112970655A
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China
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face
negative electrode
hypochlorous acid
deep sea
positive electrode
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Application number
CN202110206167.3A
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Chinese (zh)
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CN112970655B (en
Inventor
李贵阳
何锐
徐歌
沈巍
王熊
曲心怡
沈政
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Qingdao Insight Exbio Co ltd
Qingdao Ocean Equipment R & D Center Co ltd
Qingdao Dinova Gene Technology Co ltd
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Qingdao Insight Exbio Co ltd
Qingdao Ocean Equipment R & D Center Co ltd
Qingdao Dinova Gene Technology Co ltd
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Priority to CN202110206167.3A priority Critical patent/CN112970655B/en
Publication of CN112970655A publication Critical patent/CN112970655A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K63/00Receptacles for live fish, e.g. aquaria; Terraria
    • A01K63/04Arrangements for treating water specially adapted to receptacles for live fish
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/24Halogens or compounds thereof
    • C25B1/26Chlorine; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/80Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
    • Y02A40/81Aquaculture, e.g. of fish

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Animal Husbandry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses a deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device, which is characterized in that a micro-electrolysis device with a special design is fixed at the top of a hollow conical support, when the device is electrified and put into seawater, the seawater can be electrolyzed to generate hypochlorous acid, and the seawater near the device is sterilized to prevent and control bacteria, viruses, parasites and the like. The negative electrode of the micro-electrolysis is designed to be thin-walled cylindrical, the positive electrode is wrapped in the center of the cylindrical center, and the voltage released by the positive electrode can be intercepted by the negative electrode, so that the voltage is prevented from leaking into the breeding net cage to influence breeding animals. The positive electrode is made of graphite, the negative electrode is made of stainless steel, and the inner surface of the negative electrode is provided with a galvanized coating, so that the corrosion speed can be slowed down in seawater.

Description

Little electrolysis hypochlorous acid sterilizer device of deep sea aquaculture net case
Technical Field
The invention relates to a deep sea aquaculture water disinfection technology, in particular to a deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device.
Background
Micro-electrolysis refers to electrolysis under the state of low-voltage direct current, can effectively remove calcium and magnesium ions in water so as to reduce the hardness of the water, and meanwhile, active hydroxyl radicals and active chlorine which can be sterilized are generated by electrolysis, and the adsorption effect on the surface of an electrode can kill bacteria. Is particularly suitable for the pretreatment of wastewater with high salt, high COD and difficult degradation. The net cage for deep sea aquaculture is located in the deep sea, is not favorable for disinfection management, and does not need additional disinfection treatment if hypochlorous acid generated by the micro-electrolysis device is used for disinfecting and disinfecting the deep sea aquaculture water.
Disclosure of Invention
According to the defects of the prior art, the invention provides a deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device which is applied to a deep sea aquaculture net cage through structural design based on a micro-electrolysis sterilization principle, realizes sterilization treatment on deep sea aquaculture water quality, and fills the gap in the field at present.
The invention relates to a deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device, which is characterized in that: comprises a conical hollow support, a hemispherical top shell, a positive electrode and a negative electrode;
the conical hollow support comprises an upper end face, a lower end face and a plurality of support rods, the bottom outer edge of the upper end face is connected with the top outer edge of the lower end face through the plurality of support rods, the upper end face is of a disc structure, and the lower end face is of a circular ring structure;
the improved air-conditioning device is characterized in that a plurality of vent holes are uniformly distributed in the surface of the upper end face, a circular-ring-shaped negative electrode fixing device is fixedly arranged at the bottom of the upper end face, the negative electrode fixing device is in threaded connection with an electrode joint of a negative electrode, the negative electrode is of a vertically through cylinder structure, a positive electrode fixing device is fixedly arranged at the bottom of the upper end face at the circle center of the negative electrode fixing device and is in threaded connection with the electrode joint of a positive electrode, the positive electrode is a cylinder, a positive electrode wire of the positive electrode and a negative electrode wire of the negative electrode penetrate through the upper end face to be electrically connected with an external power supply, a hollow hemispherical top shell is fixedly arranged at the top of the upper end face, the hemispherical top shell covers the area where.
In the invention, hypochlorous acid and chlorine gas formed by electrolysis are gathered in the hemispherical top shell, the vent holes on the surface of the hemispherical top shell are of a microporous structure, and the hypochlorous acid and the chlorine gas form smaller bubbles through the microporous structure, so that the dissolution rate of the gas in seawater is increased, and the disinfection effect is improved.
Wherein, the preferred scheme is as follows:
the diameter of the negative electrode is 4-10 cm, the height is 20-30 cm, and the wall thickness is 2-6 mm.
The negative electrode is made of stainless steel, and the inner surface of the negative electrode is provided with a galvanized coating, so that the seawater corrosion speed can be reduced.
The diameter of the positive electrode is 4-12 mm, and the height is 16-30 cm.
The positive electrode is made of graphite and can slow down the corrosion speed of seawater.
The number of the supporting rods is four, the supporting rods are evenly distributed between the upper end face and the lower end face, and the height of each supporting rod is 30-50 cm.
The diameter of the upper end face is 10-20 cm.
The diameter of the lower end face is 35-40 cm.
And a circle of cylindrical tooth-shaped structure is arranged at the bottom of the lower end face, so that the lower end face is convenient to fix at the bottom of the net cage.
Compared with the prior art, the micro-electrolysis negative electrode is designed into a thin-wall cylinder shape, the positive electrode is wrapped in the center of the cylinder shape, the voltage released by the positive electrode can be intercepted by the negative electrode, the influence on the cultured animals caused by the voltage leaked into the culture net cage is avoided, and the bottom of the device is provided with a cylindrical tooth-shaped structure which is convenient for the device to be fixed at the bottom in the deep-sea net cage. When the device is electrified and put into seawater, the seawater can be electrolyzed to generate hypochlorous acid, and the seawater near the device is disinfected to prevent and control bacteria, viruses, parasites and the like.
Drawings
FIG. 1 is a schematic perspective view of the present invention;
FIG. 2 is a schematic plan view of the present invention;
the labels in the figures are: 1-hemispherical top shell, 2-negative electrode fixing device, 3-positive electrode fixing device, 4-positive electrode, 5-negative electrode, 6-support rod, 7-lower end face, 8-cylindrical dentate structure, 9-positive wire, 10-negative wire and 11-upper end face.
Detailed Description
The invention is further illustrated by the following figures and examples, which are not to be construed as limiting the invention.
Example 1:
as shown in fig. 1 and 2, the deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device comprises a conical hollow bracket, a hemispherical top shell 1, a positive electrode 4 and a negative electrode 5;
the cone hollow support comprises an upper end surface 11, a lower end surface 7 and four support rods 6, wherein the outer edge of the bottom of the upper end surface 11 is connected with the outer edge of the top of the lower end surface 7 through the four support rods 6 which are uniformly distributed, the upper end surface 11 is of a disc structure, and the lower end surface 7 is of a circular ring structure; the height of the support rod 6 is 50cm, the diameter of the upper end face 11 is 15cm, and the diameter of the lower end face 7 is 40 cm. And a circle of cylindrical tooth-shaped structure 8 is arranged at the bottom of the lower end face 7, so that the lower end face is conveniently fixed at the bottom of the net cage.
The surface of the upper end face 11 is uniformly distributed with a plurality of vent holes, the bottom of the upper end face 11 is fixedly provided with a circular negative electrode fixing device 2, the negative electrode fixing device 2 is in threaded connection with an electrode joint of a negative electrode 5, the negative electrode 5 is of a cylindrical structure which is communicated up and down, the diameter of the negative electrode 5 is 10cm, the height of the negative electrode 5 is 30cm, and the wall thickness of the negative electrode 5 is 5 mm. The bottom of an upper end face 11 positioned at the circle center of the negative electrode fixing device 2 is fixedly provided with a positive electrode fixing device 3, the positive electrode fixing device 3 is in threaded connection with an electrode joint of a positive electrode 4, the positive electrode 4 is a cylinder, and the diameter of the positive electrode 4 is 10mm and the height of the positive electrode 4 is 25 cm. The positive wire 9 of the positive electrode 4 and the negative wire 10 of the negative electrode 5 penetrate through the upper end surface 11 to be electrically connected with an external power supply, the top of the upper end surface 11 is fixedly provided with a hollow hemispherical top shell 1, the hemispherical top shell 1 covers the area where the negative electrode 5 is located, and a plurality of vent holes are uniformly distributed on the surface of the hemispherical top shell 1.
In this embodiment, the positive electrode 4 is made of graphite, and the negative electrode 5 is made of stainless steel, so that the seawater corrosion speed can be reduced. Hypochlorous acid and chlorine that the electrolysis formed gather at hemisphere top shell 1, and the air vent on hemisphere top shell 1 surface is microporous structure, and hypochlorous acid and chlorine pass through microporous structure and form littleer bubble, increase the gas dissolution rate in the sea water, improve the disinfection effect.
In the actual culture process, a plurality of the devices are arranged in the culture net cage at fixed intervals, and form a defense network by depending on the mobility of seawater.

Claims (9)

1. The utility model provides a deep sea aquaculture net case micro-electrolysis hypochlorous acid sterilizer device which characterized in that: comprises a conical hollow support, a hemispherical top shell, a positive electrode and a negative electrode;
the conical hollow support comprises an upper end face, a lower end face and a plurality of support rods, the bottom outer edge of the upper end face is connected with the top outer edge of the lower end face through the plurality of support rods, the upper end face is of a disc structure, and the lower end face is of a circular ring structure;
the improved air-conditioning device is characterized in that a plurality of vent holes are uniformly distributed in the surface of the upper end face, a circular-ring-shaped negative electrode fixing device is fixedly arranged at the bottom of the upper end face, the negative electrode fixing device is in threaded connection with an electrode joint of a negative electrode, the negative electrode is of a vertically through cylinder structure, a positive electrode fixing device is fixedly arranged at the bottom of the upper end face at the circle center of the negative electrode fixing device and is in threaded connection with the electrode joint of a positive electrode, the positive electrode is a cylinder, a positive electrode wire of the positive electrode and a negative electrode wire of the negative electrode penetrate through the upper end face to be electrically connected with an external power supply, a hollow hemispherical top shell is fixedly arranged at the top of the upper end face, the hemispherical top shell covers the area where.
2. The deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device according to claim 1, characterized in that: the diameter of the negative electrode is 4-10 cm, the height is 20-30 cm, and the wall thickness is 2-6 mm.
3. The deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device according to claim 1 or 2, characterized in that: the negative electrode is made of stainless steel, and a galvanized coating is arranged on the inner surface of the negative electrode.
4. The deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device according to claim 2, characterized in that: the diameter of the positive electrode is 4-12 mm, and the height is 16-30 cm.
5. The deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device according to claim 1 or 4, characterized in that: the positive electrode is made of graphite.
6. The deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device according to claim 4, wherein: the number of the supporting rods is four, the supporting rods are evenly distributed between the upper end face and the lower end face, and the height of each supporting rod is 30-50 cm.
7. The deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device according to claim 6, characterized in that: the diameter of the upper end face is 10-20 cm.
8. The deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device according to claim 7, wherein: the diameter of the lower end face is 35-40 cm.
9. The deep sea aquaculture net cage micro-electrolysis hypochlorous acid sterilizer device according to claim 1 or 7, characterized in that: and the bottom of the lower end face is provided with a circle of cylindrical tooth-shaped structure.
CN202110206167.3A 2021-02-24 2021-02-24 Little electrolysis hypochlorous acid sterilizer device of deep sea aquaculture net case Active CN112970655B (en)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN88201147U (en) * 1988-01-17 1988-11-30 戚彬彬 Electrolytic fish-farming device
US5980727A (en) * 1996-09-10 1999-11-09 Putz; Leo Method and equipment for removing organic halogen compounds from water
JP2003158953A (en) * 2001-11-27 2003-06-03 Rikujo Yoshoku Kogaku Kenkyusho:Kk Circulating aquaculture system
CN1526653A (en) * 2003-09-22 2004-09-08 清华大学 A low-voltage-direct-current-open electrochemical sterilizer
KR101219752B1 (en) * 2012-07-31 2013-01-09 김선화 Sterilizer of seawater for fish farm
CN103141430A (en) * 2013-03-29 2013-06-12 宁忠斌 Tri-polar dual-circulation seawater purifying aerator
CN103435110A (en) * 2013-08-16 2013-12-11 上海元清环保科技有限公司 Electrolytic catalyzing adsorbent filter
CN205671269U (en) * 2016-05-27 2016-11-09 徐耕舵 A kind of aquiculture recycled water reuse purifier
CN106186216A (en) * 2016-08-25 2016-12-07 北京理工大学 A kind of Novel electric adsorptive liquid processing means
CN109179637A (en) * 2018-09-26 2019-01-11 傲自然成都生物科技有限公司 A kind of screw winding Electrode-biofilm electrochemistry water purification system

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN88201147U (en) * 1988-01-17 1988-11-30 戚彬彬 Electrolytic fish-farming device
US5980727A (en) * 1996-09-10 1999-11-09 Putz; Leo Method and equipment for removing organic halogen compounds from water
JP2003158953A (en) * 2001-11-27 2003-06-03 Rikujo Yoshoku Kogaku Kenkyusho:Kk Circulating aquaculture system
CN1526653A (en) * 2003-09-22 2004-09-08 清华大学 A low-voltage-direct-current-open electrochemical sterilizer
KR101219752B1 (en) * 2012-07-31 2013-01-09 김선화 Sterilizer of seawater for fish farm
CN103141430A (en) * 2013-03-29 2013-06-12 宁忠斌 Tri-polar dual-circulation seawater purifying aerator
CN103435110A (en) * 2013-08-16 2013-12-11 上海元清环保科技有限公司 Electrolytic catalyzing adsorbent filter
CN205671269U (en) * 2016-05-27 2016-11-09 徐耕舵 A kind of aquiculture recycled water reuse purifier
CN106186216A (en) * 2016-08-25 2016-12-07 北京理工大学 A kind of Novel electric adsorptive liquid processing means
CN109179637A (en) * 2018-09-26 2019-01-11 傲自然成都生物科技有限公司 A kind of screw winding Electrode-biofilm electrochemistry water purification system

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