CN112956477A - Permeation synergist and preparation method and application thereof - Google Patents
Permeation synergist and preparation method and application thereof Download PDFInfo
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- CN112956477A CN112956477A CN202110163224.4A CN202110163224A CN112956477A CN 112956477 A CN112956477 A CN 112956477A CN 202110163224 A CN202110163224 A CN 202110163224A CN 112956477 A CN112956477 A CN 112956477A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 241000196324 Embryophyta Species 0.000 claims abstract description 83
- 239000003961 penetration enhancing agent Substances 0.000 claims abstract description 78
- 239000000341 volatile oil Substances 0.000 claims abstract description 54
- 238000002156 mixing Methods 0.000 claims abstract description 50
- 239000000575 pesticide Substances 0.000 claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 29
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 29
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 27
- 239000003337 fertilizer Substances 0.000 claims abstract description 17
- 239000003921 oil Substances 0.000 claims abstract description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 8
- NTZRDKVFLPLTPU-UHFFFAOYSA-N CC[Na] Chemical compound CC[Na] NTZRDKVFLPLTPU-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000003368 amide group Chemical group 0.000 claims abstract description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 25
- -1 oleoyl aminoethyl sulfonate Chemical compound 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- 235000012424 soybean oil Nutrition 0.000 claims description 13
- 239000003549 soybean oil Substances 0.000 claims description 13
- OORIKNJWZHTXDC-UHFFFAOYSA-N CCCC(CC)C(CC)(C(=O)OCC)N Chemical compound CCCC(CC)C(CC)(C(=O)OCC)N OORIKNJWZHTXDC-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 235000019198 oils Nutrition 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- IVJQGBHYRPCKGH-UHFFFAOYSA-N 2-methoxy-4-nitrophenol;sodium Chemical compound [Na].COC1=CC([N+]([O-])=O)=CC=C1O IVJQGBHYRPCKGH-UHFFFAOYSA-N 0.000 claims description 2
- 240000000560 Citrus x paradisi Species 0.000 claims 1
- 230000035515 penetration Effects 0.000 abstract description 22
- 239000007921 spray Substances 0.000 abstract description 10
- 230000035699 permeability Effects 0.000 abstract description 7
- 239000003814 drug Substances 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 230000029553 photosynthesis Effects 0.000 abstract description 3
- 238000010672 photosynthesis Methods 0.000 abstract description 3
- 230000004071 biological effect Effects 0.000 abstract description 2
- 230000000361 pesticidal effect Effects 0.000 abstract description 2
- 229940079593 drug Drugs 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 26
- 230000000694 effects Effects 0.000 description 17
- 240000008067 Cucumis sativus Species 0.000 description 10
- KBRKFTKQRMYINW-UHFFFAOYSA-M sodium;2-methoxy-5-nitrophenolate Chemical compound [Na+].COC1=CC=C([N+]([O-])=O)C=C1[O-] KBRKFTKQRMYINW-UHFFFAOYSA-M 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 6
- 241000221785 Erysiphales Species 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 6
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 5
- 241000238631 Hexapoda Species 0.000 description 5
- 241000256247 Spodoptera exigua Species 0.000 description 5
- 125000004442 acylamino group Chemical group 0.000 description 5
- 239000006013 carbendazim Substances 0.000 description 5
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 5
- 238000007865 diluting Methods 0.000 description 5
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 4
- 240000007124 Brassica oleracea Species 0.000 description 4
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 4
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 4
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 239000003899 bactericide agent Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000149 penetrating effect Effects 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229940087305 limonene Drugs 0.000 description 3
- 235000001510 limonene Nutrition 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 2
- 235000001759 Citrus maxima Nutrition 0.000 description 2
- 244000276331 Citrus maxima Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000003175 pesticide synergist Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 244000003416 Asparagus officinalis Species 0.000 description 1
- 235000005340 Asparagus officinalis Nutrition 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 210000000805 cytoplasm Anatomy 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000033458 reproduction Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds
- A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
- A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/50—Surfactants; Emulsifiers
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the technical field of agriculture, and particularly discloses a permeation synergist and a preparation method and application thereof, wherein the permeation synergist comprises the following components: 20-45 parts of penetration enhancer, 1-16 parts of plant regulator, 3-20 parts of plant essential oil, 8-25 parts of auxiliary agent and 30-80 parts of water, wherein the penetration enhancer is prepared by mixing N-methyl oil amido ethyl sodium sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of (1-6) to 1. The penetration synergist prepared by the invention has good emulsibility, permeability and wettability, can be mixed with pesticide preparations, foliar spray fertilizers and the like, is beneficial to spreading and adhering pesticides and fertilizers on the surfaces of plant leaves, reduces the drift of the pesticides and the fertilizers, can also dissolve a wax layer on the leaf surfaces of the plants, enhances the penetration of the pesticides and the fertilizers, promotes absorption, and achieves the purposes of prolonging the effective period of pesticide effect, improving the biological activity of the pesticides and the fertilizers, reducing the usage amount of the pesticides and the fertilizers and reducing the medication cost; moreover, the photosynthesis of plants can be promoted, and the stress resistance of crops can be enhanced.
Description
Technical Field
The invention relates to the technical field of agriculture, in particular to a permeation synergist.
Background
The pesticide is used for preventing, killing or controlling diseases, insects, grass and other harmful organisms which harm agriculture and forestry, is purposefully regulated, controlled and influenced in the processes of metabolism, growth, development and reproduction of plants and harmful organisms, is derived from chemical synthesis of organisms and other natural products and a substance or a mixture of several substances produced by applying biotechnology, and is a preparation thereof, and is an essential product in food crops, melon, fruit and vegetable planting and forestry. However, most pesticides have active ingredients that are difficult to effectively diffuse, penetrate and coat onto the plant crop to be protected.
The synergist is a substance which has no activity, but can obviously improve the wetting, spreading, dispersing, retaining and permeability properties of the pesticide when being mixed with the corresponding pesticide. A plurality of pesticides need to be diluted before use, and a certain pesticide synergist is added, so that the dilution of the pesticides can be realized, and the pesticide effect of the pesticides can be improved. The synergist is very important to the using effect of the pesticide, and directly influences the efficacy of the pesticide.
Most of the existing pesticide synergists are oily preparations, are difficult to disperse uniformly in water and have poor penetration effect; moreover, the wetting and spreading performance on the plant leaf surfaces is poor, which is not favorable for the medicine to be quickly absorbed by the plants. In order to improve the surface tension of the pesticide and improve the wetting and spreading performance of the pesticide, the prior agricultural synergist is added with organosilicon, which is a polysiloxane surfactant and can reduce the surface tension and improve the wetting and spreading performance, but the organosilicon is unstable to acid and alkali, can be decomposed when the moisture is high, and is expensive. Therefore, it is necessary to research a synergist having good wettability and permeability.
Disclosure of Invention
In view of the problems and deficiencies of the prior art, it is an object of the present invention to provide a permeation enhancer.
In order to realize the purpose of the invention, the technical scheme adopted by the invention is as follows:
the invention provides a permeation synergist, which comprises the following components in parts by weight: 20-45 parts of a penetration enhancer, 1-16 parts of a plant regulator, 3-20 parts of plant essential oil, 8-25 parts of an auxiliary agent and 30-80 parts of water, wherein the penetration enhancer is prepared by mixing N-methyl oil amido ethyl sodium sulfonate and fatty alcohol-polyoxyethylene ether JFC according to a mass ratio of (1-6) to 1.
According to the permeation enhancer, preferably, the permeation enhancer comprises the following components in parts by weight: 35 parts of penetration enhancer, 12 parts of plant regulator, 12 parts of plant essential oil, 15 parts of auxiliary agent and 66 parts of water.
According to the permeation enhancer, preferably, the mass ratio of the sodium N-methyl oleoyl aminoethyl sulfonate to the fatty alcohol-polyoxyethylene ether JFC in the permeation enhancer is 5: 1.
According to the penetration enhancer, the plant regulator is preferably at least one of diethyl aminoethyl hexanoate and sodium 5-nitroguaiacol. More preferably, the plant regulator is prepared by mixing diethyl aminoethyl hexanoate and 5-nitroguaiacol sodium according to the mass ratio of 1: 1.
According to the permeation enhancer, preferably, the plant essential oil is at least one of orange peel essential oil, orange peel essential oil and shaddock peel essential oil. More preferably, the plant essential oil is orange peel essential oil.
According to the permeation synergist, the auxiliary agent is preferably prepared by mixing methyl esterified soybean oil, ethanol and n-butyl alcohol according to a mass ratio of 1:5: 3.
In a second aspect, the present invention provides a method for preparing the permeation enhancer of the first aspect, comprising the following steps:
(1) adding penetration enhancer into water, stirring and mixing uniformly, adding plant regulator, stirring and mixing uniformly to obtain component A;
(2) adding plant essential oil into the auxiliary agent, and stirring and mixing uniformly to obtain a component B;
(3) and adding the component B into the component A, and stirring and mixing uniformly to obtain the permeation synergist.
In a third aspect, the invention provides a use of the permeation enhancer of the first aspect in pesticides and fertilizers.
In a fourth aspect, the present invention provides the use of a penetration enhancer of the first aspect as described above in a fertiliser. More preferably, the fertilizer is a foliar spray fertilizer.
Compared with the prior art, the invention has the following positive beneficial effects:
(1) the penetration enhancer in the penetration enhancer is prepared by mixing N-methyl oil acyl amino ethyl sodium sulfonate and fatty alcohol-polyoxyethylene ether JFC according to a reasonable mass ratio, wherein the N-methyl oil acyl amino ethyl sodium sulfonate is an anionic surfactant, the fatty alcohol-polyoxyethylene ether JFC is a nonionic surfactant, and the N-methyl oil acyl amino ethyl sodium sulfonate and the fatty alcohol-polyoxyethylene ether JFC are mixed to form a mixed micelle, so that the critical micelle concentration of a mixed solution is reduced, the interfacial tension is reduced, and the surface activity is improved. In addition, the N-methyl oil acyl amino ethyl sodium sulfonate and fatty alcohol-polyoxyethylene ether JFC are compounded, and the mass ratio of the N-methyl oil acyl amino ethyl sodium sulfonate to the fatty alcohol-polyoxyethylene ether JFC is finally found to be controlled to be 5:1, so that the prepared penetration enhancer has good emulsibility, permeability and wettability, and can be quickly wetted, adhered, spread and permeated on the surface of a plant leaf; meanwhile, the N-methyl oleoyl aminoethyl sulfonate water soluble penetration enhancer has good water solubility and temperature resistance, greatly improves the applicability of the penetration enhancer, and solves the problems of poor water solubility and difficult dilution of the N-methyl oleoyl aminoethyl sulfonate.
(2) The penetration synergist contains plant essential oil components, limonene in the orange peel essential oil can dissolve a wax layer on a plant leaf surface, so that liquid medicine is promoted to be quickly penetrated and absorbed on the surface of the plant leaf, and the medicine effect is improved; moreover, limonene in the orange peel essential oil can also dissolve a waxy layer on the body surface of the pests, so that when the limonene in the orange peel essential oil is mixed with an insecticide pesticide for use, the insecticidal effect of the pesticide can be greatly improved, the pesticide consumption is reduced, and the pesticide cost is reduced.
(3) The auxiliary agent in the penetration synergist is prepared by mixing methyl-esterified soybean oil, ethanol and n-butyl alcohol according to the mass ratio of 1:5:3, and the compatibility of the penetration synergist and a pesticide can be improved through the reasonable matching of the dosage of the methyl-esterified soybean oil, the ethanol and the n-butyl alcohol, and the adhesion and the anti-drift performance of the penetration synergist can be further improved by adding the methyl-esterified soybean oil.
(4) The penetration synergist is also added with a plant regulator, and the plant regulator can promote the protoplasm flow of cells, improve the cell activity, promote the photosynthesis of plants, promote the growth, enhance the stress resistance of crops, simultaneously reduce the phytotoxicity of methyl esterified soybean oil to the crops and enhance the activity and the absorption capacity of the plants.
(5) The penetration synergist prepared by compounding the penetration enhancer, the plant regulator, the plant essential oil, the auxiliary agent and the water has good emulsibility, permeability and wettability, can be mixed with a pesticide preparation, a foliar spray fertilizer and the like, is beneficial to spreading and adhering pesticides and fertilizers on the surfaces of plant leaves, reduces drift of the pesticides and the fertilizers, can also dissolve a wax layer on the leaf surfaces of the plants, enhances penetration of the pesticides and the fertilizers, promotes absorption, and achieves the purposes of prolonging the effective period of the pesticide, improving the biological activity of the pesticides and the fertilizers, reducing the using amount of the pesticides and the fertilizers, reducing the pesticide cost and protecting the environment; moreover, the photosynthesis of plants can be promoted, and the stress resistance of crops can be enhanced.
(6) The penetration synergist has good compatibility with pesticide preparation products, is suitable for various pesticide formulations, and has wide universality.
(7) The penetration synergist disclosed by the invention is high in safety to plants, is easy to biodegrade, and is a safe and environment-friendly green synergist.
(8) The permeation enhancer is prepared by uniformly mixing the permeation enhancer and water, adding the plant regulator to prepare the component A, mixing the plant essential oil and the auxiliary agent to obtain the component B, and mixing the component A and the component B to facilitate the dissolution of the plant regulator in the water without influencing the activity of the plant regulator.
Detailed Description
The present invention is further illustrated by the following specific examples. But not to limit the scope of the invention. Materials and chemical reagents used in the examples are all conventional commercial products unless otherwise specified, and the technical means used are conventional means known to those skilled in the art.
Example 1: research on mass ratio of N-methyl oleoyl aminoethyl sulfonic acid sodium to fatty alcohol-polyoxyethylene ether JFC in penetration enhancer
In order to research the influence of the mass ratio of the N-methyl oleoyl aminoethyl sulfonate to the fatty alcohol-polyoxyethylene ether JFC in the penetration enhancer on the performance of the penetration enhancer, the invention carries out the following embodiments 1-1 to 1-6. The details of examples 1-1 to 1-6 are as follows.
Example 1-1:
the permeation synergist comprises the following components in parts by weight: 35g of penetration enhancer, 12g of plant regulator, 12g of plant essential oil, 15g of auxiliary agent and 66g of water; the penetration enhancer is formed by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of 1: 1; the plant regulator is prepared by mixing diethyl aminoethyl hexanoate and 5-nitroguaiacol sodium according to the mass ratio of 1: 1; the plant essential oil is orange peel essential oil; the auxiliary agent is prepared by mixing methyl esterified soybean oil, ethanol and n-butanol according to the mass ratio of 1:5: 3.
The preparation method of the permeation enhancer comprises the following steps:
(1) adding penetration enhancer into water, stirring and mixing uniformly, adding plant regulator, stirring and mixing uniformly to obtain component A;
(2) adding plant essential oil into the auxiliary agent, and stirring and mixing uniformly to obtain a component B;
(3) and adding the component B into the component A, and stirring and mixing uniformly to obtain the permeation synergist.
Examples 1 to 2:
the contents of example 1-2 are substantially the same as those of example 1-1, except that:
the penetration enhancer is prepared by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of 2: 1.
Examples 1 to 3:
examples 1 to 3 are substantially the same as examples 1 to 1 except that:
the penetration enhancer is prepared by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of 3: 1.
Examples 1 to 4:
examples 1 to 4 are substantially the same as examples 1 to 1 except that:
the penetration enhancer is prepared by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to a mass ratio of 4: 1.
Examples 1 to 5:
examples 1 to 5 are substantially the same as examples 1 to 1 except that:
the penetration enhancer is prepared by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of 5: 1.
Examples 1 to 6:
examples 1 to 6 are substantially the same as examples 1 to 1 except that:
the penetration enhancer is prepared by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of 6: 1.
The permeation enhancers prepared in examples 1-1 to 1-6 were diluted 500 times with water and then examined for liquid surface tension, permeability, and deposition amount at room temperature. The surface tension is detected by a platinum ring method; the detection method of the seepage force comprises the following steps: a cotton disc (35 mm diameter canvas) of known characteristics was immersed in the permeation enhancer solution and the time required for the cotton disc to settle from contact with the liquid surface was measured; the deposition amount detection is the deposition amount of the permeation enhancer dripped on the surface of the paraffin plate.
TABLE 1 results of measuring surface tension, penetration force and deposition amount of permeation enhancers prepared in examples 1-1 to 1-6
As can be seen from Table 1, with the increase of the mass ratio of the sodium N-methyl oleoyl aminoethyl sulfonate to the fatty alcohol-polyoxyethylene ether in the penetration enhancer, the surface tension of the penetration enhancer is gradually reduced, the penetration force is gradually improved, and the deposition amount is gradually increased; when the mass ratio of the N-methyl oleoyl aminoethyl sulfonic acid sodium to the fatty alcohol-polyoxyethylene ether in the penetration enhancer is 5:1, the surface tension of the penetration enhancer is 20.4mN/m, the penetration force at 25 ℃ is 23.5s, and the deposition amount on the surface of the paraffin plate reaches 4.21mg/cm2The permeation synergist prepared by the invention has good wettability, permeability and adhesiveness; when the mass ratio of the N-methyl oleoyl aminoethyl sulfonic acid sodium to the fatty alcohol-polyoxyethylene ether is further increased, the surface tension and the osmotic force of the permeation synergist are not changed greatly, and the mass ratio of the N-methyl oleoyl aminoethyl sulfonic acid sodium to the fatty alcohol-polyoxyethylene ether is preferably 5:1 in consideration of the cost.
Example 2:
the permeation synergist comprises the following components in parts by weight: 20g of penetration enhancer, 8g of plant regulator, 20g of plant essential oil, 25g of auxiliary agent and 40g of water; the penetration enhancer is formed by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of 5: 1; the plant regulator is prepared by mixing diethyl aminoethyl hexanoate and 5-nitroguaiacol sodium according to the mass ratio of 1: 1; the plant essential oil is orange peel essential oil; the auxiliary agent is prepared by mixing methyl esterified soybean oil, ethanol and n-butanol according to the mass ratio of 1:5: 3.
The preparation method of the permeation enhancer is the same as that of example 1.
Example 3:
the permeation synergist comprises the following components in parts by weight: 30g of penetration enhancer, 10g of plant regulator, 10g of plant essential oil, 10g of auxiliary agent and 50g of water; the penetration enhancer is formed by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of 5: 1; the plant regulator is prepared by mixing diethyl aminoethyl hexanoate and 5-nitroguaiacol sodium according to the mass ratio of 1: 1; the plant essential oil is orange peel essential oil; the auxiliary agent is prepared by mixing methyl esterified soybean oil, ethanol and n-butanol according to the mass ratio of 1:5: 3.
The preparation method of the permeation enhancer is the same as that of example 1.
Example 4:
the permeation synergist comprises the following components in parts by weight: 45g of penetration enhancer, 16g of plant regulator, 3g of plant essential oil, 20g of auxiliary agent and 80g of water; the penetration enhancer is formed by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of 5: 1; the plant regulator is prepared by mixing diethyl aminoethyl hexanoate and 5-nitroguaiacol sodium according to the mass ratio of 1: 1; the plant essential oil is orange peel essential oil; the auxiliary agent is prepared by mixing methyl esterified soybean oil, ethanol and n-butanol according to the mass ratio of 1:5: 3.
The preparation method of the permeation enhancer is the same as that of example 1.
Example 5:
the permeation synergist comprises the following components in parts by weight: 35g of penetration enhancer, 1g of plant regulator, 15g of plant essential oil, 8g of auxiliary agent and 60g of water; the penetration enhancer is formed by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of 5: 1; the plant regulator is prepared by mixing diethyl aminoethyl hexanoate and 5-nitroguaiacol sodium according to the mass ratio of 1: 1; the plant essential oil is orange peel essential oil; the auxiliary agent is prepared by mixing methyl esterified soybean oil, ethanol and n-butanol according to the mass ratio of 1:5: 3.
The preparation method of the permeation enhancer is the same as that of example 1.
Example 6:
the permeation synergist comprises the following components in parts by weight: 40g of penetration enhancer, 12g of plant regulator, 8g of plant essential oil, 16g of auxiliary agent and 30g of water; the penetration enhancer is formed by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of 5: 1; the plant regulator is prepared by mixing diethyl aminoethyl hexanoate and 5-nitroguaiacol sodium according to the mass ratio of 1: 1; the plant essential oil is orange peel essential oil; the auxiliary agent is prepared by mixing methyl esterified soybean oil, ethanol and n-butanol according to the mass ratio of 1:5: 3.
The preparation method of the permeation enhancer is the same as that of example 1.
Example 7:
the permeation synergist comprises the following components in parts by weight: 35g of penetration enhancer, 4g of plant regulator, 12g of plant essential oil, 20g of auxiliary agent and 70g of water; the penetration enhancer is formed by mixing N-methyl oleoyl aminoethyl sulfonate and fatty alcohol-polyoxyethylene ether JFC according to the mass ratio of 5: 1; the plant regulator is prepared by mixing diethyl aminoethyl hexanoate and 5-nitroguaiacol sodium according to the mass ratio of 1: 1; the plant essential oil is orange peel essential oil; the auxiliary agent is prepared by mixing methyl esterified soybean oil, ethanol and n-butanol according to the mass ratio of 1:5: 3.
The preparation method of the permeation enhancer is the same as that of example 1.
Example 8:
example 8 is essentially the same as examples 1-5, except that: the plant regulator is diethyl aminoethyl hexanoate; the plant essential oil is formed by mixing orange peel essential oil, orange peel essential oil and shaddock peel essential oil according to the mass ratio of 1:1: 1.
Example 9:
example 9 is substantially the same as examples 1-5, except that: the plant regulator is 5-nitroguaiacol sodium; the plant essential oil is orange peel essential oil.
Example 10:
example 10 is substantially the same as examples 1-5, except that: the plant regulator is 5-nitroguaiacol sodium; the plant essential oil is orange peel essential oil.
Example 11:
example 11 is substantially the same as examples 1-5, except that: the plant regulator is diethyl aminoethyl hexanoate; the plant essential oil is orange peel essential oil.
The application efficacy of the permeation enhancer of the invention is verified as follows:
taking the penetration synergist prepared in preparation examples 1-5 of the invention as an example, the penetration synergist is compounded with pesticide to carry out efficacy verification experiment research. Meanwhile, for comparison, the invention is also provided with a comparative example. The specific contents of the comparative examples are as follows:
comparative example 1:
a penetrant, wherein the penetration synergist is prepared by compounding 35g N-methyl oleoyl aminoethyl sulfonate and 105g of water.
Comparative example 2:
a penetrant is prepared from 35g of fatty alcohol-polyoxyethylene ether JFC and 105g of water through compounding.
1. The application of the permeation synergist of the invention in pesticides is as follows:
(1) test 1: diluting the permeation enhancer prepared in the embodiment 1-5 of the invention by 200 times with water to obtain the diluted permeation enhancer; according to the weight percentage, 97.5 percent of diluted permeation synergist of the invention and 2.5 percent of high-permeability type beta-cypermethrin are uniformly mixed and diluted by 2000 times with water to spray the insect pest, namely spodoptera exigua 3 instar on the cabbage.
(2) Test 2: diluting the penetrating agent prepared in the comparative example 1 by 200 times with water to obtain a diluted penetrating agent; according to the weight percentage, 97.5 percent of diluted penetrant and 2.5 percent of high-permeability type beta-cypermethrin are uniformly mixed and then diluted by 2000 times by adding water to spray the 3 rd instar insect of the insect pest spodoptera exigua on the cabbage.
(3) Test 3: diluting the penetrating agent prepared in the comparative example 2 by 200 times with water to obtain a diluted penetrating agent; according to the weight percentage, 97.5 percent of diluted penetrant and 2.5 percent of high-permeability type beta-cypermethrin are uniformly mixed and then diluted by 2000 times by adding water to spray the 3 rd instar insect of the insect pest spodoptera exigua on the cabbage.
(4) Test 4: directly diluting 2.5% of hypertonic beta-cypermethrin solution with water by 2000 times, and spraying 3 instar insects of the asparagus caterpillars on the cabbages.
The mortality of the 3 rd instar spodoptera exigua of test 1, test 2, test 3 and test 4 was counted 48 hours after application, and the specific results are shown in table 2.
TABLE 2 EXPERIMENTS 1-4 CONTROL EFFECT ON SOPER BIRTH
| Test of | Test 1 | Test 2 | Test 3 | Test 4 |
| Mortality after 48h | 98.9％ | 84.1％ | 77.6％ | 62.3％ |
As can be seen from Table 2, after the penetration enhancer prepared by the invention is compounded with the pyrethroid pesticide for use, the control effect on the beet armyworm reaches 98.9 percent, which is far higher than that of the test 2 and the test 3. Therefore, the penetration synergist prepared by the invention can be compounded with pesticide, and the control effect of the pesticide on target pests can be obviously improved.
2. The application of the permeation synergist of the invention in the bactericide is as follows:
(1) test 1: according to the weight percentage, 70% of the penetration synergist of the invention and 30% of carbendazim are uniformly mixed, then the mixture is diluted 3000 times by adding water to spray cucumber powdery mildew plants, the control effect of the penetration synergist on cucumber powdery mildew is calculated according to GB T17980.30-2000, and the results are shown in Table 3.
(2) Test 2: according to the weight percentage, 70% of the penetrant prepared in the comparative example 1 and 30% of carbendazim are uniformly mixed, then water is added for diluting 3000 times to spray the cucumber powdery mildew plants, the control effect on the cucumber powdery mildew is calculated according to GB T17980.30-2000, and the results are shown in Table 3.
(3) Test 3: according to the weight percentage, 70% of the penetrant prepared in the comparative example 2 and 30% of carbendazim are uniformly mixed, then the penetrant is diluted by 3000 times by adding water to spray cucumber powdery mildew plants, the control effect on the cucumber powdery mildew is calculated according to GB T17980.30-2000, and the results are shown in Table 3.
(4) Test 4: the 30% carbendazim solution is directly diluted 3000 times by adding water to spray cucumber powdery mildew plants, and the control effect of the carbendazim solution on cucumber powdery mildew is calculated according to GB T17980.30-2000, and the results are shown in Table 3.
Table 3 test 1-test 4 control of cucumber powdery mildew
| Test of | Test 1 | Test 2 | Test 3 | Test 4 |
| Disease index after 7 days | 1.2％ | 9.3％ | 11.6％ | 18.5％ |
| Controlling effect | 97.8％ | 82.5％ | 75.3％ | 64.2％ |
As can be seen from Table 3, the control effect of the permeation enhancer prepared by the invention on cucumber powdery mildew reaches 97.8% after being compounded with a bactericide, which is much higher than that of the experiments 2 and 3. Therefore, the penetration synergist prepared by the invention can be compounded with the bactericide, and the control effect of the bactericide on target diseases can be obviously improved.
Finally, it should be noted that: the above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.
Claims (8)
1. The permeation synergist is characterized by comprising the following components in parts by weight: 20-45 parts of a penetration enhancer, 1-16 parts of a plant regulator, 3-20 parts of plant essential oil, 8-25 parts of an auxiliary agent and 30-80 parts of water, wherein the penetration enhancer is prepared by mixing N-methyl oil amido ethyl sodium sulfonate and fatty alcohol-polyoxyethylene ether JFC according to a mass ratio of (1-6) to 1.
2. The permeation enhancer as claimed in claim 1, wherein the permeation enhancer comprises the following components in parts by weight: 35 parts of penetration enhancer, 12 parts of plant regulator, 12 parts of plant essential oil, 15 parts of auxiliary agent and 66 parts of water.
3. The permeation enhancer of claim 1, wherein the mass ratio of the sodium N-methyl oleoyl aminoethyl sulfonate to the fatty alcohol-polyoxyethylene ether in the permeation enhancer is 5: 1.
4. The permeation enhancer as claimed in claim 3, wherein the plant regulator is at least one of diethyl aminoethyl hexanoate and sodium 5-nitroguaiacol.
5. The penetration enhancer of claim 3, wherein the plant essential oil is at least one of orange peel essential oil, and grapefruit peel essential oil.
6. The penetration enhancer of claim 3, wherein the auxiliary agent is prepared by mixing methyl esterified soybean oil, ethanol and n-butanol according to a mass ratio of 1:5: 3.
7. A process for the preparation of a permeation enhancer as claimed in any one of claims 1 to 6, comprising the steps of:
(1) adding penetration enhancer into water, stirring and mixing uniformly, adding plant regulator, stirring and mixing uniformly to obtain component A;
(2) adding plant essential oil into the auxiliary agent, and stirring and mixing uniformly to obtain a component B;
(3) and adding the component B into the component A, and stirring and mixing uniformly to obtain the permeation synergist.
8. Use of a penetration enhancer according to any one of claims 1 to 6 in pesticides, fertilizers.
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