CN112931527A - Hydrogen peroxide silver ion disinfectant and preparation process thereof - Google Patents
Hydrogen peroxide silver ion disinfectant and preparation process thereof Download PDFInfo
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- CN112931527A CN112931527A CN202110167444.4A CN202110167444A CN112931527A CN 112931527 A CN112931527 A CN 112931527A CN 202110167444 A CN202110167444 A CN 202110167444A CN 112931527 A CN112931527 A CN 112931527A
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- 239000000645 desinfectant Substances 0.000 title claims abstract description 26
- RLLVZNQBQJNFBG-UHFFFAOYSA-N hydrogen peroxide;silver Chemical compound [Ag].[Ag].OO RLLVZNQBQJNFBG-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 238000002360 preparation method Methods 0.000 title claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 133
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 66
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000012190 activator Substances 0.000 claims abstract description 24
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 23
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 20
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 20
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 20
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 20
- 229920000570 polyether Polymers 0.000 claims abstract description 20
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 20
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 20
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 20
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 20
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 19
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 19
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 19
- 239000000661 sodium alginate Substances 0.000 claims abstract description 19
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 17
- 239000011734 sodium Substances 0.000 claims abstract description 17
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 17
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims abstract description 16
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims abstract description 16
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 14
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000015424 sodium Nutrition 0.000 claims abstract description 5
- 235000015165 citric acid Nutrition 0.000 claims abstract description 4
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 15
- ATBIAJXSKNPHEI-UHFFFAOYSA-N pyridine-3-carbonyl chloride Chemical compound ClC(=O)C1=CC=CN=C1 ATBIAJXSKNPHEI-UHFFFAOYSA-N 0.000 claims description 12
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical group CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 6
- 229960003512 nicotinic acid Drugs 0.000 claims description 6
- 235000001968 nicotinic acid Nutrition 0.000 claims description 6
- 239000011664 nicotinic acid Substances 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- 239000008213 purified water Substances 0.000 claims description 4
- 125000002252 acyl group Chemical group 0.000 claims description 3
- 125000005907 alkyl ester group Chemical group 0.000 claims description 3
- 238000009924 canning Methods 0.000 claims description 3
- 238000005660 chlorination reaction Methods 0.000 claims description 3
- 239000007859 condensation product Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 150000003951 lactams Chemical class 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 2
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 claims 2
- 241001474374 Blennius Species 0.000 claims 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000013589 supplement Substances 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 8
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 230000001954 sterilising effect Effects 0.000 description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 206010052428 Wound Diseases 0.000 description 5
- 208000027418 Wounds and injury Diseases 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- BDOYKFSQFYNPKF-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O BDOYKFSQFYNPKF-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 244000000010 microbial pathogen Species 0.000 description 3
- HFVMEOPYDLEHBR-UHFFFAOYSA-N (2-fluorophenyl)-phenylmethanol Chemical compound C=1C=CC=C(F)C=1C(O)C1=CC=CC=C1 HFVMEOPYDLEHBR-UHFFFAOYSA-N 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 241001478240 Coccus Species 0.000 description 2
- 208000035473 Communicable disease Diseases 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- 230000000968 intestinal effect Effects 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000001717 pathogenic effect Effects 0.000 description 2
- 239000003206 sterilizing agent Substances 0.000 description 2
- 239000001384 succinic acid Substances 0.000 description 2
- 241000606153 Chlamydia trachomatis Species 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- 241000588653 Neisseria Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 230000010261 cell growth Effects 0.000 description 1
- 229940038705 chlamydia trachomatis Drugs 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- -1 functional coatings Substances 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The embodiment of the invention discloses a hydrogen peroxide silver ion disinfectant, which comprises the following components: hydrogen peroxide solution, hydrogen peroxide activator, polyether, triethanolamine, trivalent silver ion solution, polyethylene glycol and fatty alcohol condensate, sodium hexametaphosphate, sodium alginate, disodium ethylene diamine tetraacetate, citric acid, sodium alkyl sulfosuccinate, reducing agent and water. The disinfectant provided by the invention has excellent bactericidal performance, good stability and durability, and reduces disinfection times, thereby saving labor cost.
Description
Technical Field
The invention belongs to the technical field of disinfectant, and particularly relates to a hydrogen peroxide silver ion disinfectant.
Background
The disinfectant is used for killing pathogenic microorganisms on a transmission medium, so that the requirement of harmlessness is met, the pathogenic microorganisms are killed out of a human body, the transmission path of infectious diseases is cut off, and the purpose of controlling the infectious diseases is achieved.
The disinfectant can be divided into a sterilizing agent, a high-efficiency disinfectant, a middle-efficiency disinfectant and a low-efficiency disinfectant according to the action level. The sterilizing agent can kill all microorganisms to meet the sterilizing requirement, and comprises formaldehyde, glutaraldehyde, ethylene oxide, peracetic acid, hydrogen peroxide, chlorine dioxide, chlorine gas, copper sulfate, quicklime, ethanol and the like, so that the sterilizing performance of silver in an ionic state is greatly improved. The ionic silver can generate strong sterilization effect under the condition of small dosage, has strong permeability, broad sterilization effect and no drug resistance; and the ionic silver can promote the healing of wounds, the growth of cells and the repair of damaged cells, has no toxic reaction and has no stimulation reaction on skin. Therefore, the ionic silver antibacterial material can be applied to the fields of functional plastics, functional coatings, textile fibers, air purification, food, daily chemicals, medical treatment and the like, has a very wide market prospect, and gradually becomes a research hotspot in recent years. The ionic silver has strong inhibiting and killing effects on dozens of pathogenic microorganisms such as escherichia coli, gonococcus, chlamydia trachomatis and the like, and can not generate drug resistance. The prior disinfectant has the defects of poor stability, poor disinfection effect and the like.
Disclosure of Invention
Therefore, the embodiment of the invention provides a hydrogen peroxide silver ion disinfectant and a preparation process thereof, which aim to solve the problems in the prior art.
In order to achieve the above object, the embodiments of the present invention provide the following technical solutions:
the hydrogen peroxide silver ion disinfectant disclosed by the embodiment of the invention is characterized by comprising the following components: hydrogen peroxide solution, hydrogen peroxide activator, polyether, triethanolamine, trivalent silver ion solution, polyethylene glycol and fatty alcohol condensation product, sodium hexametaphosphate, sodium alginate, disodium ethylene diamine tetraacetate, citric acid, sodium alkyl sulfosuccinate, reducing agent and water; pure hydrogen peroxide is light blue viscous liquid, can be mixed and dissolved with water in any proportion, and is a strong oxidant; the medical hydrogen peroxide can kill intestinal pathogenic bacteria, pyogenic coccus and pathogenic yeast, and is generally used for disinfecting the surfaces of objects. The hydrogen peroxide has the oxidation effect, but the concentration of the medical hydrogen peroxide is equal to or lower than 3 percent, when the medical hydrogen peroxide is wiped on a wound surface, the wound surface can be burnt, and the surface is oxidized into white and bubbles are generated. The hydrogen peroxide is a commercial product, and can be 27.5% of hydrogen peroxide, 35% of hydrogen peroxide and 50% of hydrogen peroxide, and the hydrogen peroxide is 35% of hydrogen peroxide in mass fraction in the application.
Wherein, calculated by the total mass of the raw materials in percentage by weight, the content of the hydrogen peroxide solution is 0.3-0.6%, the content of the hydrogen peroxide activator is 0.05-0.2%, the content of the polyether is 0.01-0.05%, the content of the triethanolamine is 0.04-0.08%, the content of the trivalent silver ion solution is 0.01-0.06%, the content of the polyethylene glycol and fatty alcohol condensate is 0.4-0.8%, the content of the sodium hexametaphosphate is 0.5-0.8%, the content of the sodium alginate is 0.02-0.5%, the content of the disodium ethylene diamine tetraacetate is 0.2-0.6%, the content of the citric acid is 0.3-0.6%, the content of the sodium alkyl sulfosuccinate is 0.2-0.7%, the content of the reducing agent is 0.2-0.7%, and the water is supplemented to 100%.
In a preferred technical scheme, the reducing agent is n-hexanol.
According to the preferable technical scheme, the content of the hydrogen peroxide solution is 0.3% -0.6%, the content of the hydrogen peroxide activator is 0.08% -2%, the content of the polyether is 0.01% -0.05%, the content of the triethanolamine is 0.06% -0.08%, the content of the trivalent silver ion solution is 0.03% -0.05%, the content of the polyethylene glycol and fatty alcohol condensate is 0.4% -0.7%, the content of the sodium hexametaphosphate is 0.6% -0.8%, the content of the sodium alginate is 0.4% -0.5%, the content of the disodium ethylenediamine tetraacetate is 0.4% -0.6%, the content of the citric acid is 0.3% -0.5%, the content of the sodium alkyl sulfosuccinate is 0.4% -0.7%, the content of the reducing agent is 0.5% -0.7%, and water is supplemented until 100%.
According to the preferable technical scheme, the content of the hydrogen peroxide solution is 0.6%, the content of the hydrogen peroxide activating agent is 0.2%, the content of the polyether is 0.02%, the content of the triethanolamine is 0.6%, the content of the trivalent silver ion solution is 0.01%, the content of a polyethylene glycol and fatty alcohol condensate is 0.4%, the content of the sodium hexametaphosphate is 0.6%, the content of the sodium alginate is 0.4%, the content of the disodium ethylene diamine tetraacetate is 0.6%, the content of the citric acid is 0.3%, the content of the citric acid is 0.4%, the content of the reducing agent is 0.5%, and water is supplemented until 100%.
A preparation process of a silver ion hydrogen peroxide disinfectant is characterized by firstly dissolving sodium hexametaphosphate, sodium alginate, ethylene diamine tetraacetic acid disodium and succinic acid alkyl ester sodium sulfonate in purified water, then adding citric acid and stirring, then adding a hydrogen peroxide solution, a hydrogen peroxide activator, polyether, triethanolamine, a trivalent silver ion solution, polyethylene glycol and a fatty alcohol condensation compound and stirring, finally adding a reducing agent, stirring until uniformly mixing, filtering after mixing, canning, and then sealing and storing;
the content of the hydrogen peroxide solution is 0.3-0.6 percent, the content of the hydrogen peroxide activator is 0.05-0.2 percent, the content of the polyether is 0.01-0.05 percent, the content of the triethanolamine is 0.04-0.08 percent, the content of the trivalent silver ion solution is 0.01-0.06 percent, the content of the polyethylene glycol and fatty alcohol condensate is 0.4-0.8 percent, the content of the sodium hexametaphosphate is 0.5-0.8 percent, the content of the sodium alginate is 0.02-0.5 percent, the content of the disodium ethylene diamine tetraacetate is 0.2-0.6 percent, the content of the citric acid is 0.3-0.6 percent, the content of the sodium alkyl succinate sulfonate is 0.2-0.7 percent, the content of the reducing agent is 0.2-0.7 percent, and the water is supplemented until the total mass of the raw materials is 100 percent.
According to the preferred technical scheme, the temperature is kept at 20-30 ℃ during stirring, and the stirring time is 2-4 hours.
According to the preferable technical scheme, the hydrogen peroxide activator takes nicotinic acid or a nicotinic acid derivative as a precursor, the nicotinic acid or the nicotinic acid derivative is subjected to acyl chlorination reaction in the step (1) to obtain nicotinoyl chloride or a nicotinoyl chloride derivative, and the nicotinoyl chloride or the nicotinoyl chloride derivative is subjected to reaction with lactam to obtain the hydrogen peroxide activator in the step (2).
The embodiment of the invention has the following advantages: the sterilization agent has excellent sterilization performance, good stability and good durability, and reduces the sterilization times, thereby saving the labor cost.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a hydrogen peroxide silver ion disinfectant which is characterized by comprising the following components: hydrogen peroxide solution, hydrogen peroxide activator, polyether, triethanolamine, trivalent silver ion solution, polyethylene glycol and fatty alcohol condensation product, sodium hexametaphosphate, sodium alginate, disodium ethylene diamine tetraacetate, citric acid, sodium alkyl sulfosuccinate, reducing agent and water; pure hydrogen peroxide is light blue viscous liquid, can be mixed and dissolved with water in any proportion, and is a strong oxidant; the medical hydrogen peroxide can kill intestinal pathogenic bacteria, pyogenic coccus and pathogenic yeast, and is generally used for disinfecting the surfaces of objects. The hydrogen peroxide has the oxidation effect, but the concentration of the medical hydrogen peroxide is equal to or lower than 3 percent, when the medical hydrogen peroxide is wiped on a wound surface, the wound surface can be burnt, and the surface is oxidized into white and bubbles are generated. The hydrogen peroxide is a commercial product, and can be 27.5% of hydrogen peroxide, 35% of hydrogen peroxide and 50% of hydrogen peroxide, and the hydrogen peroxide is 35% of hydrogen peroxide in mass fraction in the application.
Wherein, calculated by the total mass of the raw materials in percentage by weight, the content of the hydrogen peroxide solution is 0.3-0.6%, the content of the hydrogen peroxide activator is 0.05-0.2%, the content of the polyether is 0.01-0.05%, the content of the triethanolamine is 0.04-0.08%, the content of the trivalent silver ion solution is 0.01-0.06%, the content of the polyethylene glycol and fatty alcohol condensate is 0.4-0.8%, the content of the sodium hexametaphosphate is 0.5-0.8%, the content of the sodium alginate is 0.02-0.5%, the content of the disodium ethylene diamine tetraacetate is 0.2-0.6%, the content of the citric acid is 0.3-0.6%, the content of the sodium alkyl sulfosuccinate is 0.2-0.7%, the content of the reducing agent is 0.2-0.7%, and the water is supplemented until 100%.
In a preferred technical scheme, the reducing agent is n-hexanol.
According to the preferable technical scheme, the content of the hydrogen peroxide solution is 0.3% -0.6%, the content of the hydrogen peroxide activator is 0.08% -2%, the content of the polyether is 0.01% -0.05%, the content of the triethanolamine is 0.06% -0.08%, the content of the trivalent silver ion solution is 0.03% -0.05%, the content of the polyethylene glycol and fatty alcohol condensate is 0.4% -0.7%, the content of the sodium hexametaphosphate is 0.6% -0.8%, the content of the sodium alginate is 0.4% -0.5%, the content of the disodium ethylenediamine tetraacetate is 0.4% -0.6%, the content of the citric acid is 0.3% -0.5%, the content of the sodium alkyl sulfosuccinate is 0.4% -0.7%, the content of the reducing agent is 0.5% -0.7%, and water is supplemented until 100%.
According to the preferable technical scheme, the content of the hydrogen peroxide solution is 0.6%, the content of the hydrogen peroxide activating agent is 0.2%, the content of the polyether is 0.02%, the content of the triethanolamine is 0.6%, the content of the trivalent silver ion solution is 0.01%, the content of a polyethylene glycol and fatty alcohol condensate is 0.4%, the content of the sodium hexametaphosphate is 0.6%, the content of the sodium alginate is 0.4%, the content of the disodium ethylene diamine tetraacetate is 0.6%, the content of the citric acid is 0.3%, the content of the citric acid is 0.4%, the content of the reducing agent is 0.5%, and water is supplemented until 100%.
A preparation process of a silver ion hydrogen peroxide disinfectant is characterized by firstly dissolving sodium hexametaphosphate, sodium alginate, ethylene diamine tetraacetic acid disodium and succinic acid alkyl ester sodium sulfonate in purified water, then adding citric acid and stirring, then adding a hydrogen peroxide solution, a hydrogen peroxide activator, polyether, triethanolamine, a trivalent silver ion solution, polyethylene glycol and a fatty alcohol condensation compound and stirring, finally adding a reducing agent, stirring until uniformly mixing, filtering after mixing, canning, and then sealing and storing;
wherein the total mass of the raw materials is calculated by percentage, the content of the hydrogen peroxide solution is 0.3-0.6%, the content of the hydrogen peroxide activator is 0.05-0.2%, the content of the polyether is 0.01-0.05%, the content of the triethanolamine is 0.04-0.08%, the content of the trivalent silver ion solution is 0.01-0.06%, the content of the polyethylene glycol and fatty alcohol condensate is 0.4-0.8%, the content of the sodium hexametaphosphate is 0.5-0.8%, the content of the sodium alginate is 0.02-0.5%, the content of the disodium ethylene diamine tetraacetate is 0.2-0.6%, the content of the citric acid is 0.3-0.6%, the content of the sodium alkyl sulfosuccinate is 0.2-0.7%, the content of the reducing agent is 0.2-0.7%, and the water is supplemented until 100%.
The optimized technical scheme is that the hydrogen peroxide solution comprises 0.4-0.6 percent of hydrogen peroxide activator, 0.08-2 percent of polyether, 0.06-0.08 percent of triethanolamine, 0.03-0.05 percent of trivalent silver ion solution, 0.4-0.7 percent of polyethylene glycol and fatty alcohol condensate, 0.6-0.8 percent of sodium hexametaphosphate, 0.4-0.5 percent of sodium alginate, 0.4-0.6 percent of disodium ethylenediamine tetraacetic acid, 0.3-0.5 percent of citric acid, 0.4-0.7 percent of sodium alkyl succinate sulfonate, 0.5-0.7 percent of reducing agent and water until 100 percent of water is supplemented
According to the preferred technical scheme, the temperature is kept at 20-30 ℃ during stirring, and the stirring time is 2-4 hours.
According to the preferable technical scheme, the hydrogen peroxide activator takes nicotinic acid or a nicotinic acid derivative as a precursor, the nicotinic acid or the nicotinic acid derivative is subjected to acyl chlorination reaction in the step (1) to obtain nicotinoyl chloride or a nicotinoyl chloride derivative, and the nicotinoyl chloride or the nicotinoyl chloride derivative is subjected to reaction with lactam to obtain the hydrogen peroxide activator in the step (2).
The disinfectant provided by the invention has excellent bactericidal performance, good stability and durability, and reduces disinfection times, thereby saving labor cost.
And finally: the above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that are within the spirit and principle of the present invention are intended to be included in the scope of the present invention.
Claims (8)
1. The hydrogen peroxide silver ion disinfectant is characterized by comprising the following components: hydrogen peroxide solution, hydrogen peroxide activator, polyether, triethanolamine, trivalent silver ion solution, polyethylene glycol and fatty alcohol condensation product, sodium hexametaphosphate, sodium alginate, disodium ethylene diamine tetraacetate, citric acid, sodium alkyl sulfosuccinate, reducing agent and water;
wherein, calculated by the total mass of the raw materials in percentage by weight, the content of the hydrogen peroxide solution is 0.3-0.6%, the content of the hydrogen peroxide activator is 0.05-0.2%, the content of the polyether is 0.1-0.05%, the content of the triethanolamine is 0.04-0.08%, the content of the trivalent silver ion solution is 0.01-0.06%, the content of the polyethylene glycol and fatty alcohol condensate is 0.4-0.8%, the content of the sodium hexametaphosphate is 0.5-0.8%, the content of the sodium alginate is 0.02-0.5%, the content of the disodium ethylene diamine tetraacetate is 0.2-0.6%, the content of the citric acid is 0.3-0.6%, the content of the sodium alkyl sulfosuccinate is 0.2-0.7%, the content of the reducing agent is 0.2-0.7%, and the water is supplemented until 100%.
2. The silver peroxide ion disinfectant as set forth in claim 1, wherein the reducing agent is n-hexanol.
3. The silver ion hydrogen peroxide disinfectant as set forth in claim 1, wherein: 0.3 to 0.6 percent of hydrogen peroxide solution, 0.08 to 2 percent of hydrogen peroxide activator, 0.01 to 0.05 percent of polyether, 0.06 to 0.08 percent of triethanolamine, 0.03 to 0.05 percent of trivalent silver ion solution, 0.4 to 0.7 percent of polyethylene glycol and fatty alcohol condensate, 0.6 to 0.8 percent of sodium hexametaphosphate, 0.4 to 0.5 percent of seaweed sodium, 0.4 to 0.6 percent of disodium ethylenediamine tetraacetic acid, 0.3 to 0.5 percent of citric acid, 0.4 to 0.7 percent of alkyl ester sodium sulfosuccinate, 0.5 to 0.7 percent of reducing agent and water supplement to 100 percent.
4. The silver ion hydrogen peroxide disinfectant as set forth in claim 1, wherein: the hydrogen peroxide solution content is 0.6%, the hydrogen peroxide activator content is 0.2%, the polyether content is 0.02%, the triethanolamine content is 0.6%, the trivalent silver ion solution content is 0.01%, the polyethylene glycol and fatty alcohol condensate content is 0.4%, the sodium hexametaphosphate content is 0.6%, the sodium alginate content is 0.4%, the disodium ethylene diamine tetraacetate content is 0.6%, the citric acid content is 0.3%, the content is 0.4%, the reducing agent content is 0.5%, and water is supplemented until 100%.
5. The disinfectant liquid comprising silver peroxide ions as set forth in claim 1, wherein said water is purified water.
6. The preparation process of silver ion hydrogen peroxide disinfectant as claimed in claims 1-5, wherein the preparation process comprises dissolving sodium hexametaphosphate, sodium alginate, disodium ethylene diamine tetraacetate, and sodium alkyl sulfosuccinate in purified water, adding citric acid, stirring, adding hydrogen peroxide solution, hydrogen peroxide activator, polyether, triethanolamine, trivalent silver ion solution, polyethylene glycol and fatty alcohol condensate, stirring, adding reducing agent, stirring, mixing, filtering, canning, and sealing;
calculated by the total mass of the raw materials in percentage by weight, the content of the hydrogen peroxide solution is 0.3-0.6%, the content of the hydrogen peroxide activator is 0.05-0.2%, the content of the polyether is 0.01-0.05%, the content of the triethanolamine is 0.04-0.08%, the content of the trivalent silver ion solution is 0.01-0.06%, the content of the polyethylene glycol and fatty alcohol condensate is 0.4-0.8%, the content of the sodium hexametaphosphate is 0.5-0.8%, the content of the sodium alginate is 0.02-0.5%, the content of the disodium ethylenediamine tetraacetate is 0.2-0.6%, the content of the citric acid is 0.3-0.6%, the content of the sodium alkyl succinate sulfonate is 0.2-0.7%, the content of the reducing agent is 2-7%, and the water is supplemented to 100%.
7. The process for preparing a silver ion hydrogen peroxide disinfectant as claimed in claim 6, wherein: the temperature is kept between 20 and 30 ℃ during the stirring process, and the stirring time is 2 to 4 hours.
8. The method for preparing the silver ion hydrogen peroxide disinfectant as claimed in claim 1, wherein the hydrogen peroxide activator is prepared by using nicotinic acid or nicotinic acid derivative as a precursor, performing acyl chlorination on the nicotinic acid or nicotinic acid derivative to obtain nicotinoyl chloride or nicotinoyl chloride derivative, and reacting the nicotinoyl chloride or nicotinoyl chloride derivative with lactam to obtain the hydrogen peroxide activator.
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