CN112726229A - Dyeing method of silk peptide modified cotton fabric by using coptis chinensis dye - Google Patents
Dyeing method of silk peptide modified cotton fabric by using coptis chinensis dye Download PDFInfo
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- CN112726229A CN112726229A CN202011586511.8A CN202011586511A CN112726229A CN 112726229 A CN112726229 A CN 112726229A CN 202011586511 A CN202011586511 A CN 202011586511A CN 112726229 A CN112726229 A CN 112726229A
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- cotton fabric
- silk peptide
- dyeing
- oxidant
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- 239000004744 fabric Substances 0.000 title claims abstract description 99
- 229920000742 Cotton Polymers 0.000 title claims abstract description 76
- 108090000765 processed proteins & peptides Proteins 0.000 title claims abstract description 50
- 238000004043 dyeing Methods 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 33
- 241000037740 Coptis chinensis Species 0.000 title abstract description 15
- 239000007800 oxidant agent Substances 0.000 claims abstract description 24
- 230000001590 oxidative effect Effects 0.000 claims abstract description 23
- 238000009990 desizing Methods 0.000 claims abstract description 11
- 241000218202 Coptis Species 0.000 claims abstract description 10
- 235000002991 Coptis groenlandica Nutrition 0.000 claims abstract description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000009999 singeing Methods 0.000 claims abstract description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 4
- 239000011734 sodium Substances 0.000 claims abstract description 4
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims abstract description 4
- 229960002218 sodium chlorite Drugs 0.000 claims abstract description 4
- 102000004190 Enzymes Human genes 0.000 claims abstract description 3
- 108090000790 Enzymes Proteins 0.000 claims abstract description 3
- 239000003513 alkali Substances 0.000 claims abstract description 3
- 238000004061 bleaching Methods 0.000 claims abstract description 3
- 238000007689 inspection Methods 0.000 claims description 9
- 230000007547 defect Effects 0.000 claims description 7
- 238000012986 modification Methods 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 230000004584 weight gain Effects 0.000 claims description 4
- 235000019786 weight gain Nutrition 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000009958 sewing Methods 0.000 claims description 3
- 238000011160 research Methods 0.000 claims description 2
- 238000012360 testing method Methods 0.000 claims description 2
- 239000000975 dye Substances 0.000 abstract description 26
- 229930182559 Natural dye Natural products 0.000 abstract description 10
- 239000000978 natural dye Substances 0.000 abstract description 10
- JQWHASGSAFIOCM-UHFFFAOYSA-M sodium periodate Chemical compound [Na+].[O-]I(=O)(=O)=O JQWHASGSAFIOCM-UHFFFAOYSA-M 0.000 abstract description 8
- -1 amino, hydroxyl Chemical group 0.000 abstract description 2
- 241000219146 Gossypium Species 0.000 description 48
- 239000004753 textile Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 5
- 238000011161 development Methods 0.000 description 4
- 241000099774 Cuscuta salina Species 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000000979 synthetic dye Substances 0.000 description 3
- 241000411851 herbal medicine Species 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 206010002198 Anaphylactic reaction Diseases 0.000 description 1
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 240000002024 Gossypium herbaceum Species 0.000 description 1
- 235000004341 Gossypium herbaceum Nutrition 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000036783 anaphylactic response Effects 0.000 description 1
- 208000003455 anaphylaxis Diseases 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- YBHILYKTIRIUTE-UHFFFAOYSA-N berberine Chemical compound C1=C2CC[N+]3=CC4=C(OC)C(OC)=CC=C4C=C3C2=CC2=C1OCO2 YBHILYKTIRIUTE-UHFFFAOYSA-N 0.000 description 1
- 229940093265 berberine Drugs 0.000 description 1
- QISXPYZVZJBNDM-UHFFFAOYSA-N berberine Natural products COc1ccc2C=C3N(Cc2c1OC)C=Cc4cc5OCOc5cc34 QISXPYZVZJBNDM-UHFFFAOYSA-N 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 230000001516 effect on protein Effects 0.000 description 1
- 238000010011 enzymatic desizing Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007721 medicinal effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention relates to a dyeing method of silk peptide modified cotton fabric by using coptis dye, which comprises the following raw materials: oxidant, silk peptide solution and cotton fabric, the operation steps include: (1) preparing raw cloth; (2) singeing; (3) desizing; (4) dyeing; the oxidant and the silk peptide solution are respectively provided with three different concentration specifications; the oxidant is used in combination with enzyme desizing and alkali desizing; and (3) bleaching the cotton fabric after the step (3), wherein any one of a sodium nitrilate method, a hydrogen peroxide method and a sodium chlorite method can be selected. The dyeing method of the silk peptide modified cotton fabric by using the coptis chinensis dye adopts silk peptide to pretreat the cotton fabric, firstly uses sodium periodate to oxidize the cotton fabric, and then the oxidized cotton fabric reacts with the silk peptide solution, so that a large number of active groups such as amino, hydroxyl and the like are deposited on the cotton fiber, the dyeability of the natural dye is improved, and meanwhile, the excellent performance of silk is endowed to the cotton fabric.
Description
Technical Field
The invention relates to the technical field of dyeing, in particular to a dyeing method of silk peptide modified cotton fabric by utilizing coptis dye.
Background
In the textile industry, the use of dyes and the development of dyeing techniques have made textile garments more elegant and loved. Since the advent of synthetic dyes in the 19 th century, synthetic dyes have been rapidly developed in the twentieth century by virtue of their full chromatograms, bright colors, fastness to washing, fastness to sunlight, mass production, low price, etc., and have become the main colorants for textiles, gradually replacing natural dyes, and becoming the most important colorants for textiles. However, the synthetic dyes bring great pollution to the environment in the industrial production process, seriously destroy the ecological balance, and have certain influence on the human health. The natural dye is non-toxic and harmless, has no anaphylaxis and carcinogenicity to skin, and many of the plant dyes are Chinese herbal medicines, and have unique medicinal health care function to human body. Because most textile fabrics are in direct contact with human bodies, the natural dye has wide development prospects in the fields of high-grade silk products, health-care underwear, home textile products, decorative articles and the like. If the drug effect function of the dye plant and the dyeing function of the dye plant can be combined and applied to the development of textile fabrics, green and environment-friendly textiles which are popular with people and have the health-care and medicinal effects can be developed.
The coptis chinensis is a famous Chinese herbal medicine, the main effective component berberine of the coptis chinensis belongs to quaternary ammonium alkaloids, and is also used as a main pigment source of dye, the potential value of the coptis chinensis dye in the aspect of dyeing is fully developed, the natural dye coptis chinensis is applied to dyeing of cotton products, the added value of the cotton products is improved, meanwhile, the full naturalization of the cotton products can be realized, the requirements of people in the new century on the cotton products are met, and the coptis chinensis is also a good way for developing 'ecological cotton textiles' and 'full green cotton textiles'. The dyeing effect of the coptis chinensis dye on cotton fabrics is improved through modification treatment on the cotton fabrics, and the environment-friendly natural dye of the coptis chinensis can be widely applied to dyeing of textiles, so that healthier, environment-friendly and green textiles can be obtained.
The coptis chinensis dye has dyeing property and antibacterial property, and is very worthy of development. As the only natural cationic dye, the coptis has better dyeing effect on protein fibers, for example, the coptis extract has good dyeing effect on wool fabrics and silk fabrics, and obtains brighter yellow, but has lower dye-uptake on cellulose fibers such as cotton. The cotton fabric is soft in hand feeling, comfortable to wear and low in price, is the fabric which is most popular and used by people, but because the affinity of the cotton fiber and the golden thread dye is not enough, the golden thread has poor dyeing effect on the cotton fabric, the dye-uptake is low, the color is not bright, and the color fastness is not high. In order to improve these defects, a dyeing method of silk peptide modified cotton fabric using coptis chinensis dye is needed, which modifies cotton plants to improve the dyeing performance of coptis chinensis.
Disclosure of Invention
In view of the above problems, the invention provides a method for dyeing silk peptide modified cotton fabric by using a coptidis dye, which comprises the following steps:
in order to achieve the purpose, the invention adopts the following technical scheme: a method for dyeing silk peptide modified cotton fabric by using coptis dye comprises the following raw materials: oxidant, silk peptide solution and cotton fabric, the operation steps include:
(1) preparing raw cloth: the preparation of the raw cloth comprises raw cloth inspection, cloth turning (batching, boxing and printing) and head sewing, wherein the purpose of the raw cloth inspection is to inspect the quality of the grey cloth, and the problem can be solved in time when the problem is discovered. The inspection content comprises two items of physical indexes and appearance defects;
(2) singeing: the singeing aims at burning off the fluff on the cloth cover, so that the cloth cover is smooth and beautiful, and uneven dyeing and printing defects caused by the fluff during dyeing and printing are prevented;
(3) desizing: oxidizing the cotton fabric by using an oxidant to enable the silk peptide to be smoothly attached to the surface of the cotton fabric, so as to realize the silk peptide modification of the cotton fabric; selecting an oxidant with concentration which does not seriously affect the physical and mechanical properties of the cotton fabric to treat the cotton fabric, and then reacting the cotton fabric with silk peptide solutions with different concentrations; obtaining the influence of the concentration of the oxidant and the concentration of the silk peptide solution on the weight gain rate of the cotton cloth by using an orthogonal contrast test;
(4) dyeing: and (3) carrying out silk peptide solution treatment with different concentrations on cotton cloth oxidized by the same oxidant concentration, respectively carrying out coptis dyeing, and providing a heat source by using a high-temperature cylinder to research the influence of the dyeing temperature and the silk peptide solution concentration on the dye uptake and the color fastness respectively.
Preferably, the oxidant and the silk peptide solution are respectively provided with three different concentration specifications.
Preferably, the oxidizing agent is used in combination with enzymatic desizing and alkaline desizing.
Preferably, the cotton fabric after the step (3) is bleached, and any one of a sodium nitrilate method, a hydrogen peroxide method and a sodium chlorite method can be selected.
Preferably, in the step (4), the temperature of the high-temperature cylinder needs to be slowly increased, the highest temperature cannot exceed 130 ℃, and the temperature is reduced to below 85 ℃.
The invention has the following beneficial effects: the dyeing method of the silk peptide modified cotton fabric by utilizing the coptis chinensis dye adopts silk peptide to pretreat the cotton fabric, sodium periodate is firstly used to oxidize the cotton fabric, and then the oxidized cotton fabric is reacted with the silk peptide solution, so that a large number of active groups such as amino groups, hydroxyl groups and the like are deposited and fixed on the cotton fiber, the dyeability of the natural dye is improved, meanwhile, the excellent performances of silk are endowed to the cotton fabric, such as improvement of the hygroscopicity, hand feeling, suspension style and the like, and the prepared natural dye dyed cotton fabric has elegant and natural tone, unique style and good market prospect.
Detailed Description
The following examples may assist those skilled in the art in a more complete understanding of the present invention, but are not intended to limit the invention in any way.
Example 1:
a method for dyeing silk peptide modified cotton fabric by using coptis dye comprises the following raw materials: oxidizing agent, silk peptide solution and cotton fabric.
The method comprises the following steps:
(1) preparing raw cloth: the preparation of the raw cloth comprises raw cloth inspection, cloth turning (batching, boxing and printing) and head sewing, wherein the purpose of the raw cloth inspection is to inspect the quality of the grey cloth, and the problem can be solved in time when the problem is discovered. The inspection content comprises two items of physical indexes and appearance defects;
(2) singeing: the singeing aims at burning off the fluff on the cloth cover, so that the cloth cover is smooth and beautiful, and uneven dyeing and printing defects caused by the fluff during dyeing and printing are prevented;
(3) desizing: firstly, sodium periodate is used for carrying out oxidation treatment on the cotton fabric, so that silk peptide can be smoothly attached to the surface of the cotton fabric, and the silk peptide modification of the cotton fabric is realized; the effect of silk peptide modification is influenced by the concentration of an oxidant and the concentration of silk peptide, and when a single condition is changed, the weight gain rate of cotton cloth is higher along with the increase of the concentration of the oxidant; the rate of weight gain increases with increasing silk peptide concentration; however, too large a concentration of the oxidizing agent will seriously affect the mechanical properties of the fabric, so that the concentration of the oxidizing agent should not exceed 2 g/L.
(4) Dyeing: after the silk peptide modified cotton fabric is dyed by the coptis dye liquor, the dye uptake is obviously improved compared with the untreated cotton fabric, and the color is more yellow and bright. The silk peptide concentration and the dyeing temperature influence the dye uptake of the fabric to coptis chinensis, and when a single condition is changed, the dye uptake gradually rises along with the increase of the silk peptide concentration; the dye uptake rate gradually decreased with increasing treatment temperature. After the cotton fabric is subjected to silk peptide modification treatment, the soaping color fastness of the dyed fabric is improved to a certain extent compared with that of untreated cotton fabric. But the colorfastness to washing is still lower and still needs to be further enhanced.
Wherein, the oxidant and the silk peptide solution are respectively provided with three different concentration specifications; the oxidant is used in combination with enzyme desizing and alkali desizing; bleaching the cotton fabric after the step (3), wherein any one of a sodium nitrilate method, a hydrogen peroxide method and a sodium chlorite method can be selected; and (4) slowly raising the temperature of the high-temperature cylinder in the step (4), wherein the highest temperature cannot exceed 130 ℃, and the temperature is reduced to below 85 ℃.
The golden thread dye has good dyeing effect on silk fabrics, the scheme adopts silk peptide to pretreat cotton fabrics, sodium periodate is firstly used for oxidizing cotton fabrics, and then oxidized cotton fabrics react with silk peptide solution, so that a large amount of active groups such as amino, hydroxyl and the like are deposited and fixed on cotton fibers, the dyeability of natural dyes is improved, meanwhile, the excellent performances of silk, such as improvement of hygroscopicity, hand feeling, suspension style and the like, are given to the cotton fabrics, and the prepared natural dye dyed cotton fabrics have elegant and natural tone, unique style and good market prospect.
The technical solutions provided by the embodiments of the present invention are described in detail above, and the principles and embodiments of the present invention are explained herein by using specific examples, and the descriptions of the embodiments are only used to help understanding the principles of the embodiments of the present invention; meanwhile, for a person skilled in the art, according to the embodiments of the present invention, there may be variations in the specific implementation manners and application ranges, and in summary, the content of the present description should not be construed as a limitation to the present invention.
Claims (5)
1. A method for dyeing silk peptide modified cotton fabric by using coptis dye comprises the following raw materials: oxidant, silk peptide solution and cotton fabric, characterized by, the operation step includes:
(1) preparing raw cloth: the preparation of the raw cloth comprises raw cloth inspection, cloth turning (batching, boxing and printing) and head sewing, wherein the purpose of the raw cloth inspection is to inspect the quality of the grey cloth, and the problem can be solved in time when the problem is discovered. The inspection content comprises two items of physical indexes and appearance defects;
(2) singeing: the singeing aims at burning off the fluff on the cloth cover, so that the cloth cover is smooth and beautiful, and uneven dyeing and printing defects caused by the fluff during dyeing and printing are prevented;
(3) desizing: oxidizing the cotton fabric by using an oxidant to enable the silk peptide to be smoothly attached to the surface of the cotton fabric, so as to realize the silk peptide modification of the cotton fabric; selecting an oxidant with concentration which does not seriously affect the physical and mechanical properties of the cotton fabric to treat the cotton fabric, and then reacting the cotton fabric with silk peptide solutions with different concentrations; obtaining the influence of the concentration of the oxidant and the concentration of the silk peptide solution on the weight gain rate of the cotton cloth by using an orthogonal contrast test;
(4) dyeing: and (3) carrying out silk peptide solution treatment with different concentrations on cotton cloth oxidized by the same oxidant concentration, respectively carrying out coptis dyeing, and providing a heat source by using a high-temperature cylinder to research the influence of the dyeing temperature and the silk peptide solution concentration on the dye uptake and the color fastness respectively.
2. The method for dyeing the silk peptide modified cotton fabric by using the coptidis dye according to claim 1, wherein the method comprises the following steps: the oxidant and the silk peptide solution are respectively provided with three different concentration specifications.
3. The method for dyeing the silk peptide modified cotton fabric by using the coptidis dye according to claim 1, wherein the method comprises the following steps: the oxidant is used in combination with enzyme desizing and alkali desizing.
4. The method for dyeing the silk peptide modified cotton fabric by using the coptidis dye according to claim 1, wherein the method comprises the following steps: and (3) bleaching the cotton fabric after the step (3), wherein any one of a sodium nitrilate method, a hydrogen peroxide method and a sodium chlorite method can be selected.
5. The method for dyeing the silk peptide modified cotton fabric by using the coptidis dye according to claim 1, wherein the method comprises the following steps: and (4) slowly raising the temperature of the high-temperature cylinder in the step (4), wherein the highest temperature cannot exceed 130 ℃, and the temperature is reduced to below 85 ℃.
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Cited By (1)
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CN113863029A (en) * | 2021-09-29 | 2021-12-31 | 江苏迈思德超净科技有限公司 | Method for dyeing cotton fabric by coptis chinensis |
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CN102561058A (en) * | 2012-02-16 | 2012-07-11 | 武汉纺织大学 | Method for improving dyeing property of cotton fabric natural dye by using silk peptide |
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CN109235090A (en) * | 2018-09-13 | 2019-01-18 | 佛山市三水南方天泽印染有限公司 | A kind of pure cotton twill stained clot-h dyeing and printing process |
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2020
- 2020-12-29 CN CN202011586511.8A patent/CN112726229A/en active Pending
Patent Citations (3)
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CN102561058A (en) * | 2012-02-16 | 2012-07-11 | 武汉纺织大学 | Method for improving dyeing property of cotton fabric natural dye by using silk peptide |
CN106758208A (en) * | 2016-11-25 | 2017-05-31 | 江苏爱西施科技服务咨询股份有限公司 | A kind of bafta preparation method of SP finishing agent |
CN109235090A (en) * | 2018-09-13 | 2019-01-18 | 佛山市三水南方天泽印染有限公司 | A kind of pure cotton twill stained clot-h dyeing and printing process |
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Title |
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