CN112646669A - Washing and protecting integrated laundry detergent containing biological protease - Google Patents
Washing and protecting integrated laundry detergent containing biological protease Download PDFInfo
- Publication number
- CN112646669A CN112646669A CN202110096991.8A CN202110096991A CN112646669A CN 112646669 A CN112646669 A CN 112646669A CN 202110096991 A CN202110096991 A CN 202110096991A CN 112646669 A CN112646669 A CN 112646669A
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- China
- Prior art keywords
- parts
- laundry detergent
- surfactant
- washing
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003599 detergent Substances 0.000 title claims abstract description 94
- 239000004365 Protease Substances 0.000 title claims abstract description 70
- 108091005804 Peptidases Proteins 0.000 title claims abstract description 68
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 title claims abstract description 68
- 238000005406 washing Methods 0.000 title claims abstract description 43
- 230000002633 protecting effect Effects 0.000 title claims abstract description 30
- 235000011347 Moringa oleifera Nutrition 0.000 claims abstract description 55
- 239000004094 surface-active agent Substances 0.000 claims abstract description 48
- 239000002888 zwitterionic surfactant Substances 0.000 claims abstract description 48
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 43
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 43
- 241001076416 Dendrobium tosaense Species 0.000 claims abstract description 38
- 102000004190 Enzymes Human genes 0.000 claims abstract description 38
- 108090000790 Enzymes Proteins 0.000 claims abstract description 38
- 229940088598 enzyme Drugs 0.000 claims abstract description 38
- 108010059892 Cellulase Proteins 0.000 claims abstract description 36
- 229940106157 cellulase Drugs 0.000 claims abstract description 36
- 239000004382 Amylase Substances 0.000 claims abstract description 34
- 102000013142 Amylases Human genes 0.000 claims abstract description 34
- 108010065511 Amylases Proteins 0.000 claims abstract description 34
- 102000004882 Lipase Human genes 0.000 claims abstract description 34
- 239000004367 Lipase Substances 0.000 claims abstract description 34
- 108090001060 Lipase Proteins 0.000 claims abstract description 34
- 235000019418 amylase Nutrition 0.000 claims abstract description 34
- 235000019421 lipase Nutrition 0.000 claims abstract description 34
- 230000002335 preservative effect Effects 0.000 claims abstract description 32
- 239000003381 stabilizer Substances 0.000 claims abstract description 32
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 31
- 239000003899 bactericide agent Substances 0.000 claims abstract description 31
- 239000003755 preservative agent Substances 0.000 claims abstract description 31
- 239000002562 thickening agent Substances 0.000 claims abstract description 31
- 239000003021 water soluble solvent Substances 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000008367 deionised water Substances 0.000 claims abstract description 22
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 22
- 241000220215 Moringa Species 0.000 claims abstract 7
- 238000002156 mixing Methods 0.000 claims description 75
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 74
- 235000019419 proteases Nutrition 0.000 claims description 65
- -1 alkyl glycoside Chemical class 0.000 claims description 57
- 235000001014 amino acid Nutrition 0.000 claims description 45
- 150000001413 amino acids Chemical class 0.000 claims description 45
- 239000000686 essence Substances 0.000 claims description 40
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 38
- 239000011734 sodium Substances 0.000 claims description 34
- 229910052708 sodium Inorganic materials 0.000 claims description 34
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 31
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- 238000000605 extraction Methods 0.000 claims description 27
- 238000002360 preparation method Methods 0.000 claims description 26
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 22
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 22
- 239000011259 mixed solution Substances 0.000 claims description 20
- 239000011780 sodium chloride Substances 0.000 claims description 19
- 238000001816 cooling Methods 0.000 claims description 18
- 238000000926 separation method Methods 0.000 claims description 18
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 14
- 239000000194 fatty acid Substances 0.000 claims description 14
- 229930195729 fatty acid Natural products 0.000 claims description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 11
- UYTOHYBIBPDOKX-ZDUSSCGKSA-N (2s)-2-(dodecanoylamino)propanoic acid Chemical compound CCCCCCCCCCCC(=O)N[C@@H](C)C(O)=O UYTOHYBIBPDOKX-ZDUSSCGKSA-N 0.000 claims description 10
- VUWCWMOCWKCZTA-UHFFFAOYSA-N 1,2-thiazol-4-one Chemical class O=C1CSN=C1 VUWCWMOCWKCZTA-UHFFFAOYSA-N 0.000 claims description 10
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 10
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 10
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 claims description 10
- 229920002907 Guar gum Polymers 0.000 claims description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 10
- 229960005443 chloroxylenol Drugs 0.000 claims description 10
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 10
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 10
- 229930182478 glucoside Natural products 0.000 claims description 10
- 239000000665 guar gum Substances 0.000 claims description 10
- 235000010417 guar gum Nutrition 0.000 claims description 10
- 229960002154 guar gum Drugs 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- ARIWANIATODDMH-UHFFFAOYSA-N rac-1-monolauroylglycerol Chemical compound CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims description 10
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 10
- 229940075582 sorbic acid Drugs 0.000 claims description 10
- 235000010199 sorbic acid Nutrition 0.000 claims description 10
- 239000004334 sorbic acid Substances 0.000 claims description 10
- 229940104261 taurate Drugs 0.000 claims description 10
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 9
- 229920002125 Sokalan® Polymers 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 9
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 9
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 9
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 9
- 235000019864 coconut oil Nutrition 0.000 claims description 9
- 239000003240 coconut oil Substances 0.000 claims description 9
- 150000004665 fatty acids Chemical class 0.000 claims description 9
- 229930182470 glycoside Natural products 0.000 claims description 9
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims description 9
- 229920000570 polyether Polymers 0.000 claims description 9
- 229920005862 polyol Polymers 0.000 claims description 9
- 150000003077 polyols Chemical class 0.000 claims description 9
- 108700004121 sarkosyl Proteins 0.000 claims description 9
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 9
- 229940079781 sodium cocoyl glutamate Drugs 0.000 claims description 9
- 229940065859 sodium cocoyl glycinate Drugs 0.000 claims description 9
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 9
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims description 9
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 9
- 235000011152 sodium sulphate Nutrition 0.000 claims description 9
- IKGKWKGYFJBGQJ-UHFFFAOYSA-M sodium;2-(dodecanoylamino)acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCC([O-])=O IKGKWKGYFJBGQJ-UHFFFAOYSA-M 0.000 claims description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 8
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims description 8
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 229940079988 potassium cocoyl glycinate Drugs 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- 239000004368 Modified starch Substances 0.000 claims description 3
- 229920000881 Modified starch Polymers 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- 235000019426 modified starch Nutrition 0.000 claims description 3
- 229940083542 sodium Drugs 0.000 claims description 3
- TUBPSFQENHCYBW-HVDRVSQOSA-N (2s)-2-aminopentanedioic acid;2-[bis(2-hydroxyethyl)amino]ethanol Chemical compound OC(=O)[C@@H](N)CCC(O)=O.OCCN(CCO)CCO TUBPSFQENHCYBW-HVDRVSQOSA-N 0.000 claims description 2
- 229940031728 cocamidopropylamine oxide Drugs 0.000 claims description 2
- 229940048912 triethanolamine cocoyl glutamate Drugs 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- 238000005202 decontamination Methods 0.000 abstract description 12
- 230000003588 decontaminative effect Effects 0.000 abstract description 12
- 230000000474 nursing effect Effects 0.000 abstract description 6
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract description 2
- 244000179886 Moringa oleifera Species 0.000 description 48
- 239000004744 fabric Substances 0.000 description 25
- 230000000694 effects Effects 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 16
- 239000008280 blood Substances 0.000 description 11
- 210000004369 blood Anatomy 0.000 description 11
- 238000002791 soaking Methods 0.000 description 10
- 235000018102 proteins Nutrition 0.000 description 9
- 102000004169 proteins and genes Human genes 0.000 description 9
- 108090000623 proteins and genes Proteins 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000010298 pulverizing process Methods 0.000 description 6
- 229920002472 Starch Polymers 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 235000013336 milk Nutrition 0.000 description 4
- 239000008267 milk Substances 0.000 description 4
- 210000004080 milk Anatomy 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 241001388119 Anisotremus surinamensis Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 210000002374 sebum Anatomy 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- WFJFGMLKAISFOZ-UHFFFAOYSA-N 1-amino-3-iminourea Chemical compound NN=C(O)N=N WFJFGMLKAISFOZ-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 244000062250 Kaempferia rotunda Species 0.000 description 1
- 235000013422 Kaempferia rotunda Nutrition 0.000 description 1
- 108010053229 Lysyl endopeptidase Proteins 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000005227 alkyl sulfonate group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001516 effect on protein Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 210000001724 microfibril Anatomy 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000001139 pH measurement Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/40—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using enzymes
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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Abstract
The invention belongs to the technical field of laundry detergents, and particularly relates to a washing and protecting integrated laundry detergent containing biological protease, which comprises the following components in parts by weight: 1-30 parts of nonionic surfactant, 1-30 parts of anionic surfactant, 0-30 parts of zwitterionic surfactant, 0.6-8 parts of biological protease, 0.6-8 parts of lipase, 0.6-8 parts of amylase, 0.6-8 parts of cellulase, 0-20 parts of water-soluble solvent, 0.01-0.03 part of dendrobium officinale extract, 0.1-0.3 part of moringa seed extract, 0-1.0 part of preservative, 0-0.5 part of essence, 0.1-20 parts of enzyme stabilizer, 0-5 parts of bactericide, 0-1 part of thickening agent and a proper amount of deionized water. According to the invention, through compounding of different types of surfactants with various biological enzymes and the like, the synergistic effect is achieved, so that the laundry detergent has high-efficiency decontamination capability and a nursing effect, and the washing and nursing effects are achieved.
Description
Technical Field
The invention belongs to the technical field of laundry detergents, and particularly relates to a washing and protecting integrated laundry detergent containing biological protease.
Background
With the continuous development of modern society, household detergents are gradually developed into the current laundry detergent from soap and washing powder, and the laundry detergent is gradually accepted by domestic consumers due to the advantages of convenient use, quick dissolution, good low-temperature washing, mild clothes and skin and the like, so that various types of laundry detergent products appear in the market at present. Although many laundry detergents are available on the market with various functions, there is still a large space for optimization. The conventional products are more and more on the market, so that the liquid laundry detergent can not be used for thoroughly removing some stubborn stains, such as blood stains, protein, starch and oil stains. On the other hand, the fabric does not have a high-efficiency care effect, and after the fabric is washed for multiple times, the appearance and color of the fabric gradually become poor, gray and dark. How to improve the cleaning, nursing effect and cost performance of the laundry detergent is one of the necessary topics for the current daily necessities industry to explore.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a washing and protecting integrated laundry detergent containing biological protease.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
a washing and protecting integrated laundry detergent containing biological protease comprises the following components in parts by weight: 1-30 parts of nonionic surfactant, 1-30 parts of anionic surfactant, 0-30 parts of zwitterionic surfactant, 0.6-8 parts of biological protease, 0.6-8 parts of lipase, 0.6-8 parts of amylase, 0.6-8 parts of cellulase, 0-20 parts of water-soluble solvent, 0.01-0.03 part of dendrobium officinale extract, 0.1-0.3 part of moringa seed extract, 0-1.0 part of preservative, 0-0.5 part of essence, 0.1-20 parts of enzyme stabilizer, 0-5 parts of bactericide, 0-1 part of thickening agent and a proper amount of deionized water.
The biological protease, lipase, amylase, cellulase and protease are added, and have extremely strong decontamination capability, and the biological protease is an enzyme capable of hydrolyzing protein into soluble amino acid and is mainly used for protein dirt such as blood, milk, cocoa, coffee and the like; the lipase can hydrolyze macromolecular fat in the oil stains into small molecular substances, so that the small molecular substances are easy to fall off from clothes and mainly aim at the oily stains; the amylase can hydrolyze starch into small molecular substances, and is mainly used for treating starch stains such as potatoes, noodles and the like; the cellulase can decompose and remove the microfibril in the cotton fiber of the clothes when the clothes are washed, and mainly aims at the clothes. After the clothes are washed for many times, micro-hair and small pompon appear on the surface of the clothes, and after the clothes are treated by cellulase, the micro-hair and the pompon on the surface of the clothes can be removed by the cellulase, so that the surface of the clothes becomes flat and smooth. Meanwhile, the fabric has whitening effect, so that the color of the colored clothes becomes more bright, and the clothes recover the original color.
Among the three different types of surfactants, the amino acid surfactant contains an amide group and a carboxyl group, so that the strong interface adsorption capacity of the laundry detergent on clothes can be increased, the adsorption capacity of protein stains on the clothes can be reduced, and the protein stains in the clothes can be efficiently removed. The non-amino acid anionic surfactant has excellent emulsifying performance and good effect of removing granular dirt. The nonionic surfactant has good functions of foaming, foam stabilization, penetration decontamination, hard water resistance and the like, and can enhance the cleaning effect on clothes. The amphoteric surfactant has mild performance, small irritation and good compatibility with anionic surfactants and nonionic surfactants, and can improve the softness, smoothness, conditioning property and antistatic property of clothes. The laundry detergent uses three types of surfactants with different types, so that the irritation of the laundry detergent can be effectively reduced, the dirt-removing capacity of the laundry detergent is improved, the softening and nursing effect of the laundry detergent is improved, and the effect of washing and nursing is achieved.
Preferably, the preparation of the dendrobium officinale extract in the laundry detergent comprises the following steps: crushing dried dendrobium officinale, leaching twice with 70-90% ethanol with the weight of 4-6 times of that of the dendrobium officinale at the temperature of 80-90 ℃ and the pH of =8 for 3-5 h, mixing the extractive solutions, and concentrating under reduced pressure to obtain the dendrobium officinale extract.
The laundry detergent is preferably prepared by the steps of:
(1) extracting moringa seeds for 45-240 min at an extraction pressure of 12-30 MPa and an extraction temperature of 35-60 ℃ for CO2Performing supercritical CO2 extraction under the condition that the gas flow is 6-50 Kg/h to obtain an extract;
(2) separating the extract under the conditions that the separation pressure is 3-7 MPa and the separation temperature is 30-60 ℃ to obtain moringa seed extract;
wherein the extraction entrainer is selected from ethanol with the volume percentage of 85-95%, and the dosage of the extraction entrainer is 1-15% of the total weight of the moringa seeds.
The laundry detergent preferably comprises 2-4 wt.% (1-3 wt.%), 1-3 wt.% (2-4 wt.%) of the biological protease, the amylase, the lipase and the cellulase.
In the laundry detergent, the enzyme stabilizer is preferably one or more selected from sodium chloride, glycerin, alkyl glycoside, and polyether polyol. The enzyme stabilizer can greatly increase the stability of the biological enzyme, keep the activity of the biological enzyme in the laundry detergent and further prolong the storage period of the laundry detergent.
Preferably, the weight ratio of the anionic surfactant to the nonionic surfactant to the zwitterionic surfactant is (10-30) to (3-7) to (2-5).
In the above laundry detergent, preferably, the anionic surfactant comprises an amino acid surfactant and a non-amino acid surfactant, and the amino acid surfactant is selected from one or more of sodium lauroyl sarcosinate, sodium lauroyl alanine, sodium cocoyl glutamate, potassium cocoyl glycinate, sodium cocoyl methyl taurate, sodium cocoyl glycinate, triethanolamine cocoyl glutamate and supramolecular amino acid;
the non-amino acid surfactant is one or more than two of sodium dodecyl benzene sulfonate, fatty acid salt, sodium fatty acid, fatty alcohol-polyoxyethylene ether sodium sulfate and secondary alkyl sodium sulfonate.
In the above laundry detergent, preferably, the nonionic surfactant is one or more selected from coconut oil fatty acid diethanolamide, fatty alcohol polyoxyethylene ether, condensation product of fatty acid methyl ester and ethylene oxide, fatty alcohol polyoxyethylene ether, alkyl glucoside and alkyl dimethyl amine oxide;
the zwitterionic surfactant is selected from one or more of dodecyl betaine, cocamidopropyl betaine, alkyl dimethyl amine oxide, dodecyl dimethyl amine ethyl lactone and cocamidopropyl amine oxide.
In the laundry detergent, preferably, the thickener is one or more selected from sodium chloride, modified starch, polyacrylic acid polymer, carboxymethyl cellulose and guar gum; the bactericide is selected from one or two of carbazone and chloroxylenol, has a good sterilization effect on most negative bacteria, fungi and mould fungi, and can reduce the breeding of bacteria on clothes; the preservative is selected from one or more than two of isothiazolinone derivatives, nano silver, sorbic acid and monoglycerol laurate, so that the preservative property of the laundry detergent can be effectively improved, and the laundry detergent is prevented from being rotten and mildewed; the essence is selected from one or more than two of kason, ether, alcohol and saturated hydrocarbon essences, and can increase the fragrance of the washing liquid containing the biological protease for washing and protecting; the water-soluble solvent is one or more than two of ethanol, ethylene glycol, isopropanol, ethylene glycol butyl ether, ethylene glycol propyl ether, propylene glycol butyl ether, diethyl ether and diethylene glycol butyl ether.
Based on one general inventive concept, another object of the present invention is to provide a method for preparing the above-mentioned bio-protease-containing laundry detergent, comprising the steps of:
s1, placing a nonionic surfactant, an anionic surfactant, 2/3 zwitterionic surfactant, dendrobium officinale extractum, moringa seed extract, a water-soluble solvent and deionized water into a container, heating to 52-68 ℃, and stirring until the components are dissolved and uniformly dispersed;
s2, cooling to 40-50 ℃, and then sequentially adding a preservative, essence, an enzyme stabilizer, 1/3 zwitterionic surfactant, a bactericide and a thickening agent under the stirring condition to obtain a uniform mixed solution;
and S3, cooling to 25-35 ℃, sequentially adding the biological protease, the lipase, the amylase and the cellulase into the mixed solution, and uniformly stirring to obtain the washing and protecting integrated laundry detergent containing the biological protease.
Compared with the prior art, the laundry detergent disclosed by the invention contains three different types of surface active agents, the three types of surface active agents have good compatibility, the adsorption capacity of the laundry detergent on clothes can be increased, the adhesive force between stains and the clothes is weakened, and the laundry detergent has high-efficiency decontamination capacity. In addition, the three surface activities enable the laundry detergent to have the characteristics of mild performance, small irritation, softness and the like, and the care effect of the laundry detergent is improved. Biological protease, lipase, amylase, cellulase and biological enzyme in the protease IV are added, so that different stain removal effects are achieved for different types of stains. Biological protease mainly removes protein dirt; the dendrobium officinale extract and moringa seed extract prepared by a specific process have unexpected technical effects for solving the technical problems by technical personnel in the field; lipases are mainly directed against oily stains; amylase mainly removes starch stains; the cellulase can remove micro-hair and pompon on the surface of the clothes, so that the surface of the clothes is smooth, and simultaneously, the cellulase has whitening effect, so that the color of the clothes becomes brighter, and the clothes can recover the natural color. Through the compounding of different types of surfactants, various biological enzymes and other components, the synergistic effect is achieved, so that the laundry detergent has high-efficiency decontamination capability, the nursing effect of clothes is improved, and the washing and protecting effects are achieved. The laundry detergent disclosed by the invention is simple in production process, easy to prepare and produce in batches, and can be widely applied to the industry of daily necessities.
Detailed Description
The present invention will be further described with reference to specific embodiments for making the objects, technical solutions and advantages of the present invention more apparent, but the present invention is not limited to these examples. It should be noted that, without conflict, any combination between the embodiments or technical features described below may form a new embodiment. In the invention, all parts and percentages are mass units, and the adopted equipment, raw materials and the like can be purchased from the market or are commonly used in the field. The methods in the following examples are conventional in the art unless otherwise specified.
Example 1
A washing and protecting integrated laundry detergent containing biological protease comprises the following components in parts by weight: 3.6 parts of nonionic surfactant, 6.2 parts of anionic surfactant, 12 parts of zwitterionic surfactant, 1.5 parts of biological protease, 2.1 parts of lipase, 3.5 parts of amylase, 4.2 parts of cellulase, 12 parts of water-soluble solvent, 0.02 part of dendrobium officinale extract, 0.2 part of moringa seed extract, 0.6 part of preservative, 0.2 part of essence, 10.8 parts of enzyme stabilizer, 3.2 parts of bactericide, 0-1 part of thickener and a proper amount of deionized water.
The preparation method of the dendrobium officinale extractum comprises the following steps: pulverizing dried herba Dendrobii, soaking in 5 times of 80% ethanol at 85 deg.C and pH =8 for two times, respectively soaking for 4h, mixing extractive solutions, and concentrating under reduced pressure to obtain herba Dendrobii extract.
The preparation method of the moringa seed extract comprises the following steps:
(1) extracting Moringa seed with CO at extraction pressure of 21MPa and extraction temperature of 45 deg.C for 128min2Supercritical CO is carried out under the condition that the gas flow is 28Kg/h2Extracting to obtain an extract;
(2) separating the extract under the conditions of separation pressure of 5MPa and separation temperature of 45 ℃ to obtain moringa seed extract;
wherein the extraction entrainer is selected from ethanol with the volume percentage of 90 percent, and the dosage is 8.2 percent of the total weight of the moringa seeds.
The weight ratio of the biological protease to the amylase to the lipase to the cellulase is 3: 2: 3.
The enzyme stabilizer consists of sodium chloride, alkyl glycoside and polyether polyol in the weight ratio of 1 to 4 to 2.
The weight ratio of the anionic surfactant, the nonionic surfactant and the zwitterionic surfactant is equal to 20: 10: 3.
The anionic surfactant comprises an amino acid surfactant and a non-amino acid surfactant, wherein the amino acid surfactant is formed by mixing sodium lauroyl sarcosinate, sodium lauroyl alanine, sodium cocoyl glutamate, sodium cocoyl methyl taurate and sodium cocoyl glycinate in any proportion;
the non-amino acid surfactant is prepared by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and secondary alkyl sodium sulfonate in any proportion.
The nonionic surfactant is prepared by mixing coconut oil fatty acid diethanolamide, fatty alcohol-polyoxyethylene ether, alkyl glucoside and alkyl dimethyl amine oxide in any proportion.
The zwitterionic surfactant is formed by mixing dodecyl betaine, cocamidopropyl betaine and alkyl dimethyl amine oxide in any proportion.
The thickening agent is formed by mixing sodium chloride, polyacrylic acid polymer, carboxymethyl cellulose and guar gum in any proportion; the bactericide is formed by mixing the cason and the chloroxylenol in any proportion; the preservative is formed by mixing isothiazolinone derivatives, nano silver, sorbic acid and monoglycerol laurate in any proportion; the essence consists of alcohol and saturated hydrocarbon essences which are conventional in the field; the water-soluble solvent is formed by mixing ethanol, ethylene glycol, propylene glycol butyl ether and diethylene glycol butyl ether in any proportion.
The preparation method of the laundry detergent comprises the following steps:
s1, placing a nonionic surfactant, an anionic surfactant, 2/3 zwitterionic surfactant, dendrobium officinale extractum, moringa seed extract, a water-soluble solvent and deionized water into a container, heating to 52-68 ℃, and stirring until the components are dissolved and uniformly dispersed;
s2, cooling to 46.2 ℃, and then sequentially adding a preservative, essence, an enzyme stabilizer, 1/3 zwitterionic surfactant, a bactericide and a thickening agent under stirring to obtain a uniform mixed solution;
and S3, cooling to 32 ℃, sequentially adding the biological protease, the lipase, the amylase and the cellulase into the mixed solution, and uniformly stirring to obtain the washing and protecting integrated laundry detergent containing the biological protease.
Example 2
A washing and protecting integrated laundry detergent containing biological protease comprises the following components in parts by weight: 28 parts of nonionic surfactant, 30 parts of anionic surfactant, 25 parts of zwitterionic surfactant, 6.5 parts of biological protease, 4.2 parts of lipase, 6.5 parts of amylase, 3.8 parts of cellulase, 20 parts of water-soluble solvent, 0.02 part of dendrobium officinale extract, 0.3 part of moringa seed extract, 1.0 part of preservative, 0.3 part of essence, 20 parts of enzyme stabilizer, 5 parts of bactericide, 1 part of thickener and a proper amount of deionized water.
The preparation method of the dendrobium officinale extractum comprises the following steps: crushing dried dendrobium officinale, leaching twice with 90% ethanol with the weight of 6 times of that of the dendrobium officinale at 90 ℃ and under the condition that the pH is =8 for 5 hours respectively, then combining the extracting solutions, and concentrating under reduced pressure to obtain the dendrobium officinale extract.
The preparation method of the moringa seed extract comprises the following steps:
(1) extracting Moringa seed with CO at 60 deg.C under 30MPa for 240min2Supercritical CO is carried out under the condition that the gas flow is 50Kg/h2Extracting to obtain an extract;
(2) separating the extract under the conditions that the separation pressure is 7MPa and the separation temperature is 60 ℃ to obtain moringa seed extract;
wherein the extraction entrainer is selected from 95% ethanol by volume, and the dosage of the extraction entrainer is 15% of the total weight of the moringa seeds.
The weight ratio of the biological protease to the amylase to the lipase to the cellulase is 4: 1: 3: 2.
The enzyme stabilizer is prepared by mixing sodium chloride, glycerol and alkyl glycoside in any proportion.
The weight ratio of the anionic surfactant, the nonionic surfactant and the zwitterionic surfactant is equal to 30: 6: 5.
The anionic surfactant comprises an amino acid surfactant and a non-amino acid surfactant, wherein the amino acid surfactant is prepared by mixing sodium lauroyl sarcosinate, sodium lauroyl alanine, sodium cocoyl glutamate, potassium cocoyl glycinate and sodium cocoyl methyl taurate in any proportion.
The non-amino acid surfactant is prepared by mixing sodium dodecyl benzene sulfonate, sodium fatty acid, sodium fatty alcohol-polyoxyethylene ether sulfate and sodium secondary alkyl sulfonate in any proportion.
The nonionic surfactant is prepared by mixing coconut oil fatty acid diethanolamide, condensation products of fatty acid methyl ester and ethylene oxide, fatty alcohol-polyoxyethylene ether, alkyl glucoside and alkyl dimethyl amine oxide in any proportion.
The zwitterionic surfactant is prepared by mixing dodecyl betaine, cocamidopropyl betaine, alkyl dimethyl amine oxide and dodecyl dimethyl amine ethyl lactone in any proportion.
The thickening agent is formed by mixing polyacrylic acid polymers, carboxymethyl cellulose and guar gum in any proportion; the bactericide is formed by mixing the cason and the chloroxylenol in any proportion; the preservative is formed by mixing isothiazolinone derivatives, nano silver, sorbic acid and monoglycerol laurate in any proportion; the essence is formed by mixing the kaempferia and saturated hydrocarbon essence in any proportion; the water-soluble solvent is formed by mixing ethanol, ethylene glycol, isopropanol, ethylene glycol propyl ether, propylene glycol butyl ether and diethylene glycol butyl ether in any proportion.
The preparation method of the laundry detergent comprises the following steps:
s1, placing a nonionic surfactant, an anionic surfactant, 2/3 zwitterionic surfactant, dendrobium officinale extractum, moringa seed extract, a water-soluble solvent and deionized water into a container, heating to 68 ℃, and stirring until the components are dissolved and uniformly dispersed;
s2, cooling to 50 ℃, and then sequentially adding a preservative, essence, an enzyme stabilizer, 1/3 zwitterionic surfactant, a bactericide and a thickening agent under stirring to obtain a uniform mixed solution;
and S3, cooling to 35 ℃, sequentially adding the biological protease, the lipase, the amylase and the cellulase into the mixed solution, and uniformly stirring to obtain the washing and protecting integrated laundry detergent containing the biological protease.
Example 3
A washing and protecting integrated laundry detergent containing biological protease comprises the following components in parts by weight: 3 parts of nonionic surfactant, 2 parts of anionic surfactant, 3 parts of zwitterionic surfactant, 0.8 part of biological protease, 1.2 parts of lipase, 0.8 part of amylase, 0.8 part of cellulase, 10 parts of water-soluble solvent, 0.01 part of dendrobium officinale extract, 0.1 part of moringa seed extract, 0.1 part of preservative, 0.1 part of essence, 1.2 parts of enzyme stabilizer, 1 part of bactericide, 0.1 part of thickener and a proper amount of deionized water.
The preparation method of the dendrobium officinale extractum comprises the following steps: pulverizing dried herba Dendrobii, extracting with 72% ethanol 4 times the weight of herba Dendrobii twice at 80 deg.C and pH =8 for 3 hr, respectively, mixing extractive solutions, and concentrating under reduced pressure to obtain herba Dendrobii extract.
The preparation method of the moringa seed extract comprises the following steps:
(1) extracting Moringa seed with CO at 35 deg.C under 12MPa for 45min2Supercritical CO is carried out under the condition that the gas flow is 6Kg/h2Extracting to obtain an extract;
(2) separating the extract under the conditions of separation pressure of 3MPa and separation temperature of 30 ℃ to obtain moringa seed extract;
wherein the extraction entrainer is selected from 85% ethanol by volume percentage, and the dosage is 1% of the total weight of the moringa seeds.
The weight ratio of the biological protease to the amylase to the lipase to the cellulase is 2: 3: 1: 4.
The enzyme stabilizer is prepared by mixing sodium chloride, glycerol and polyether polyol in any proportion.
The weight ratio of the anionic surfactant, the nonionic surfactant and the zwitterionic surfactant is equal to 10: 6: 3.
The anionic surfactant comprises an amino acid surfactant and a non-amino acid surfactant, wherein the amino acid surfactant is formed by mixing sodium lauroyl alanine, potassium cocoyl glycinate, sodium cocoyl methyl taurate and sodium cocoyl glycinate in any proportion;
the non-amino acid surfactant is prepared by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and secondary alkyl sodium sulfonate in any proportion.
The nonionic surfactant is formed by mixing fatty alcohol-polyoxyethylene ether, condensation products of fatty acid methyl ester and ethylene oxide, alkyl glucoside and alkyl dimethyl amine oxide in any proportion;
the zwitterionic surfactant is formed by mixing cocoamidopropyl betaine, alkyl dimethyl amine oxide, dodecyl dimethyl amine ethyl lactone and cocoamidopropyl amine oxide in any proportion.
The thickening agent is formed by mixing sodium chloride, modified starch and guar gum in any proportion; the bactericide is formed by mixing the cason and the chloroxylenol in any proportion; the preservative is formed by mixing isothiazolinone derivatives, nano silver, sorbic acid and monoglycerol laurate in any proportion; the essence is formed by mixing the kasong and the alcohol essence in any proportion; the water-soluble solvent is formed by mixing ethanol, ethylene glycol, isopropanol, ethylene glycol butyl ether, ethylene glycol propyl ether, propylene glycol butyl ether, diethyl ether and diethylene glycol butyl ether in any proportion.
The preparation method of the laundry detergent comprises the following steps:
s1, placing a nonionic surfactant, an anionic surfactant, 2/3 zwitterionic surfactant, dendrobium officinale extractum, moringa seed extract, a water-soluble solvent and deionized water into a container, heating to 52 ℃, and stirring until the components are dissolved and uniformly dispersed;
s2, cooling to 40 ℃, and then sequentially adding a preservative, essence, an enzyme stabilizer, 1/3 zwitterionic surfactant, a bactericide and a thickening agent under stirring to obtain a uniform mixed solution;
and S3, cooling to 25 ℃, sequentially adding the biological protease, the lipase, the amylase and the cellulase into the mixed solution, and uniformly stirring to obtain the washing and protecting integrated laundry detergent containing the biological protease.
Comparative example 1
A washing and protecting integrated laundry detergent containing biological protease comprises the following components in parts by weight: 3.6 parts of nonionic surfactant, 6.2 parts of anionic surfactant, 12 parts of zwitterionic surfactant, 1.5 parts of biological protease, 2.1 parts of lipase, 3.5 parts of amylase, 4.2 parts of cellulase, 12 parts of water-soluble solvent, 0.2 part of moringa seed extract, 0.6 part of preservative, 0.2 part of essence, 10.8 parts of enzyme stabilizer, 3.2 parts of bactericide, 0-1 part of thickening agent and a proper amount of deionized water.
The preparation method of the moringa seed extract comprises the following steps:
(1) extracting Moringa seed with CO at extraction pressure of 21MPa and extraction temperature of 45 deg.C for 128min2Supercritical CO is carried out under the condition that the gas flow is 28Kg/h2Extracting to obtain an extract;
(2) separating the extract under the conditions of separation pressure of 5MPa and separation temperature of 45 ℃ to obtain moringa seed extract;
wherein the extraction entrainer is selected from ethanol with the volume percentage of 90 percent, and the dosage is 8.2 percent of the total weight of the moringa seeds.
The weight ratio of the biological protease to the amylase to the lipase to the cellulase is 3: 2: 3.
The enzyme stabilizer consists of sodium chloride, alkyl glycoside and polyether polyol in the weight ratio of 1 to 4 to 2.
The weight ratio of the anionic surfactant, the nonionic surfactant and the zwitterionic surfactant is equal to 20: 10: 3.
The anionic surfactant comprises an amino acid surfactant and a non-amino acid surfactant, wherein the amino acid surfactant is formed by mixing sodium lauroyl sarcosinate, sodium lauroyl alanine, sodium cocoyl glutamate, sodium cocoyl methyl taurate and sodium cocoyl glycinate in any proportion;
the non-amino acid surfactant is prepared by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and secondary alkyl sodium sulfonate in any proportion.
The nonionic surfactant is prepared by mixing coconut oil fatty acid diethanolamide, fatty alcohol-polyoxyethylene ether, alkyl glucoside and alkyl dimethyl amine oxide in any proportion.
The zwitterionic surfactant is formed by mixing dodecyl betaine, cocamidopropyl betaine and alkyl dimethyl amine oxide in any proportion.
The thickening agent is formed by mixing sodium chloride, polyacrylic acid polymer, carboxymethyl cellulose and guar gum in any proportion; the bactericide is formed by mixing the cason and the chloroxylenol in any proportion; the preservative is formed by mixing isothiazolinone derivatives, nano silver, sorbic acid and monoglycerol laurate in any proportion; the essence consists of alcohol and saturated hydrocarbon essences which are conventional in the field; the water-soluble solvent is formed by mixing ethanol, ethylene glycol, propylene glycol butyl ether and diethylene glycol butyl ether in any proportion.
The preparation method of the laundry detergent comprises the following steps:
s1, placing a nonionic surfactant, an anionic surfactant, 2/3 zwitterionic surfactant, moringa seed extract, a water-soluble solvent and deionized water into a container, heating to 52-68 ℃, and stirring until the components are dissolved and dispersed uniformly;
s2, cooling to 46.2 ℃, and then sequentially adding a preservative, essence, an enzyme stabilizer, 1/3 zwitterionic surfactant, a bactericide and a thickening agent under stirring to obtain a uniform mixed solution;
and S3, cooling to 32 ℃, sequentially adding the biological protease, the lipase, the amylase and the cellulase into the mixed solution, and uniformly stirring to obtain the washing and protecting integrated laundry detergent containing the biological protease.
Comparative example 2
A washing and protecting integrated laundry detergent containing biological protease comprises the following components in parts by weight: 3.6 parts of nonionic surfactant, 6.2 parts of anionic surfactant, 12 parts of zwitterionic surfactant, 1.5 parts of biological protease, 2.1 parts of lipase, 3.5 parts of amylase, 4.2 parts of cellulase, 12 parts of water-soluble solvent, 0.02 part of dendrobium officinale extract, 0.6 part of preservative, 0.2 part of essence, 10.8 parts of enzyme stabilizer, 3.2 parts of bactericide, 0-1 part of thickener and a proper amount of deionized water.
The preparation method of the dendrobium officinale extractum comprises the following steps: pulverizing dried herba Dendrobii, soaking in 5 times of 80% ethanol at 85 deg.C and pH =8 for two times, respectively soaking for 4h, mixing extractive solutions, and concentrating under reduced pressure to obtain herba Dendrobii extract.
The weight ratio of the biological protease to the amylase to the lipase to the cellulase is 3: 2: 3.
The enzyme stabilizer consists of sodium chloride, alkyl glycoside and polyether polyol in the weight ratio of 1 to 4 to 2.
The weight ratio of the anionic surfactant, the nonionic surfactant and the zwitterionic surfactant is equal to 20: 10: 3.
The anionic surfactant comprises an amino acid surfactant and a non-amino acid surfactant, wherein the amino acid surfactant is formed by mixing sodium lauroyl sarcosinate, sodium lauroyl alanine, sodium cocoyl glutamate, sodium cocoyl methyl taurate and sodium cocoyl glycinate in any proportion;
the non-amino acid surfactant is prepared by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and secondary alkyl sodium sulfonate in any proportion.
The nonionic surfactant is prepared by mixing coconut oil fatty acid diethanolamide, fatty alcohol-polyoxyethylene ether, alkyl glucoside and alkyl dimethyl amine oxide in any proportion.
The zwitterionic surfactant is formed by mixing dodecyl betaine, cocamidopropyl betaine and alkyl dimethyl amine oxide in any proportion.
The thickening agent is formed by mixing sodium chloride, polyacrylic acid polymer, carboxymethyl cellulose and guar gum in any proportion; the bactericide is formed by mixing the cason and the chloroxylenol in any proportion; the preservative is formed by mixing isothiazolinone derivatives, nano silver, sorbic acid and monoglycerol laurate in any proportion; the essence consists of alcohol and saturated hydrocarbon essences which are conventional in the field; the water-soluble solvent is formed by mixing ethanol, ethylene glycol, propylene glycol butyl ether and diethylene glycol butyl ether in any proportion.
The preparation method of the laundry detergent comprises the following steps:
s1, placing a nonionic surfactant, an anionic surfactant, 2/3 zwitterionic surfactant, dendrobium officinale extractum, a water-soluble solvent and deionized water into a container, heating to 52-68 ℃, and stirring until the mixture is dissolved and dispersed uniformly;
s2, cooling to 46.2 ℃, and then sequentially adding a preservative, essence, an enzyme stabilizer, 1/3 zwitterionic surfactant, a bactericide and a thickening agent under stirring to obtain a uniform mixed solution;
and S3, cooling to 32 ℃, sequentially adding the biological protease, the lipase, the amylase and the cellulase into the mixed solution, and uniformly stirring to obtain the washing and protecting integrated laundry detergent containing the biological protease.
Comparative example 3
A washing and protecting integrated laundry detergent containing biological protease comprises the following components in parts by weight: 3.6 parts of nonionic surfactant, 6.2 parts of anionic surfactant, 12 parts of zwitterionic surfactant, 1.5 parts of biological protease, 12 parts of water-soluble solvent, 0.02 part of dendrobium officinale extract, 0.2 part of moringa seed extract, 0.6 part of preservative, 0.2 part of essence, 10.8 parts of enzyme stabilizer, 3.2 parts of bactericide, 0-1 part of thickening agent and a proper amount of deionized water.
The preparation method of the dendrobium officinale extractum comprises the following steps: pulverizing dried herba Dendrobii, soaking in 5 times of 80% ethanol at 85 deg.C and pH =8 for two times, respectively soaking for 4h, mixing extractive solutions, and concentrating under reduced pressure to obtain herba Dendrobii extract.
The preparation method of the moringa seed extract comprises the following steps:
(1) extracting Moringa seed with CO at extraction pressure of 21MPa and extraction temperature of 45 deg.C for 128min2Supercritical CO is carried out under the condition that the gas flow is 28Kg/h2Extracting to obtain an extract;
(2) separating the extract under the conditions of separation pressure of 5MPa and separation temperature of 45 ℃ to obtain moringa seed extract;
wherein the extraction entrainer is selected from ethanol with the volume percentage of 90 percent, and the dosage is 8.2 percent of the total weight of the moringa seeds.
The weight ratio of the biological protease to the amylase to the lipase to the cellulase is 3: 2: 3.
The enzyme stabilizer consists of sodium chloride, alkyl glycoside and polyether polyol in the weight ratio of 1 to 4 to 2.
The weight ratio of the anionic surfactant, the nonionic surfactant and the zwitterionic surfactant is equal to 20: 10: 3.
The anionic surfactant comprises an amino acid surfactant and a non-amino acid surfactant, wherein the amino acid surfactant is formed by mixing sodium lauroyl sarcosinate, sodium lauroyl alanine, sodium cocoyl glutamate, sodium cocoyl methyl taurate and sodium cocoyl glycinate in any proportion;
the non-amino acid surfactant is prepared by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and secondary alkyl sodium sulfonate in any proportion.
The nonionic surfactant is prepared by mixing coconut oil fatty acid diethanolamide, fatty alcohol-polyoxyethylene ether, alkyl glucoside and alkyl dimethyl amine oxide in any proportion.
The zwitterionic surfactant is formed by mixing dodecyl betaine, cocamidopropyl betaine and alkyl dimethyl amine oxide in any proportion.
The thickening agent is formed by mixing sodium chloride, polyacrylic acid polymer, carboxymethyl cellulose and guar gum in any proportion; the bactericide is formed by mixing the cason and the chloroxylenol in any proportion; the preservative is formed by mixing isothiazolinone derivatives, nano silver, sorbic acid and monoglycerol laurate in any proportion; the essence consists of alcohol and saturated hydrocarbon essences which are conventional in the field; the water-soluble solvent is formed by mixing ethanol, ethylene glycol, propylene glycol butyl ether and diethylene glycol butyl ether in any proportion.
The preparation method of the laundry detergent comprises the following steps:
s1, placing a nonionic surfactant, an anionic surfactant, 2/3 zwitterionic surfactant, dendrobium officinale extractum, moringa seed extract, a water-soluble solvent and deionized water into a container, heating to 52-68 ℃, and stirring until the components are dissolved and uniformly dispersed;
s2, cooling to 46.2 ℃, and then sequentially adding a preservative, essence, an enzyme stabilizer, 1/3 zwitterionic surfactant, a bactericide and a thickening agent under stirring to obtain a uniform mixed solution;
and S3, cooling to 32 ℃, adding the biological protease into the mixed solution, and uniformly stirring to obtain the washing and protecting integrated laundry detergent containing the biological protease.
Comparative example 4
A washing and protecting integrated laundry detergent containing biological protease comprises the following components in parts by weight: 3.6 parts of nonionic surfactant, 6.2 parts of anionic surfactant, 1.5 parts of biological protease, 2.1 parts of lipase, 3.5 parts of amylase, 4.2 parts of cellulase, 12 parts of water-soluble solvent, 0.02 part of dendrobium officinale extract, 0.2 part of moringa seed extract, 0.6 part of preservative, 0.2 part of essence, 10.8 parts of enzyme stabilizer, 3.2 parts of bactericide, 0-1 part of thickener and a proper amount of deionized water.
The preparation method of the dendrobium officinale extractum comprises the following steps: pulverizing dried herba Dendrobii, soaking in 5 times of 80% ethanol at 85 deg.C and pH =8 for two times, respectively soaking for 4h, mixing extractive solutions, and concentrating under reduced pressure to obtain herba Dendrobii extract.
The preparation method of the moringa seed extract comprises the following steps:
(1) extracting Moringa seed with CO at extraction pressure of 21MPa and extraction temperature of 45 deg.C for 128min2Supercritical CO is carried out under the condition that the gas flow is 28Kg/h2Extracting to obtain an extract;
(2) separating the extract under the conditions of separation pressure of 5MPa and separation temperature of 45 ℃ to obtain moringa seed extract;
wherein the extraction entrainer is selected from ethanol with the volume percentage of 90 percent, and the dosage is 8.2 percent of the total weight of the moringa seeds.
The weight ratio of the biological protease to the amylase to the lipase to the cellulase is 3: 2: 3.
The enzyme stabilizer consists of sodium chloride, alkyl glycoside and polyether polyol in the weight ratio of 1 to 4 to 2.
The weight ratio of the anionic surfactant, the nonionic surfactant and the zwitterionic surfactant is equal to 20: 10: 3.
The anionic surfactant comprises an amino acid surfactant and a non-amino acid surfactant, wherein the amino acid surfactant is formed by mixing sodium lauroyl sarcosinate, sodium lauroyl alanine, sodium cocoyl glutamate, sodium cocoyl methyl taurate and sodium cocoyl glycinate in any proportion;
the non-amino acid surfactant is prepared by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and secondary alkyl sodium sulfonate in any proportion.
The nonionic surfactant is prepared by mixing coconut oil fatty acid diethanolamide, fatty alcohol-polyoxyethylene ether, alkyl glucoside and alkyl dimethyl amine oxide in any proportion.
The thickening agent is formed by mixing sodium chloride, polyacrylic acid polymer, carboxymethyl cellulose and guar gum in any proportion; the bactericide is formed by mixing the cason and the chloroxylenol in any proportion; the preservative is formed by mixing isothiazolinone derivatives, nano silver, sorbic acid and monoglycerol laurate in any proportion; the essence consists of alcohol and saturated hydrocarbon essences which are conventional in the field; the water-soluble solvent is formed by mixing ethanol, ethylene glycol, propylene glycol butyl ether and diethylene glycol butyl ether in any proportion.
The preparation method of the laundry detergent comprises the following steps:
s1, placing a nonionic surfactant, an anionic surfactant, 2/3 zwitterionic surfactant, dendrobium officinale extractum, moringa seed extract, a water-soluble solvent and deionized water into a container, heating to 52-68 ℃, and stirring until the components are dissolved and uniformly dispersed;
s2, cooling to 46.2 ℃, and then sequentially adding a preservative, essence, an enzyme stabilizer, 1/3 zwitterionic surfactant, a bactericide and a thickening agent under stirring to obtain a uniform mixed solution;
and S3, cooling to 32 ℃, sequentially adding the biological protease, the lipase, the amylase and the cellulase into the mixed solution, and uniformly stirring to obtain the washing and protecting integrated laundry detergent containing the biological protease.
Comparative example 5
A washing and protecting integrated laundry detergent containing biological protease comprises the following components in parts by weight: 3.6 parts of nonionic surfactant, 6.2 parts of anionic surfactant, 12 parts of zwitterionic surfactant, 1.5 parts of biological protease, 2.1 parts of lipase, 3.5 parts of amylase, 4.2 parts of cellulase, 12 parts of water-soluble solvent, 0.02 part of dendrobium officinale extract, 0.2 part of moringa seed extract, 0.6 part of preservative, 0.2 part of essence, 10.8 parts of enzyme stabilizer, 3.2 parts of bactericide, 0-1 part of thickener and a proper amount of deionized water.
The preparation method of the dendrobium officinale extractum comprises the following steps: pulverizing dried herba Dendrobii, soaking in 5 times of 80% ethanol at 85 deg.C and pH =8 for two times, respectively soaking for 4h, mixing extractive solutions, and concentrating under reduced pressure to obtain herba Dendrobii extract.
The preparation method of the moringa seed extract comprises the following steps:
(1) extracting Moringa seed with CO at extraction pressure of 21MPa and extraction temperature of 45 deg.C for 128min2Supercritical CO is carried out under the condition that the gas flow is 28Kg/h2Extracting to obtain an extract;
(2) separating the extract under the conditions of separation pressure of 5MPa and separation temperature of 45 ℃ to obtain moringa seed extract;
wherein the extraction entrainer is selected from ethanol with the volume percentage of 90 percent, and the dosage is 8.2 percent of the total weight of the moringa seeds.
The weight ratio of the biological protease to the amylase to the lipase to the cellulase is 3: 2: 3.
The enzyme stabilizer consists of sodium chloride, alkyl glycoside and polyether polyol in the weight ratio of 1 to 4 to 2.
The weight ratio of the anionic surfactant, the nonionic surfactant and the zwitterionic surfactant is equal to 20: 10: 3.
The anionic surfactant comprises an amino acid surfactant and a non-amino acid surfactant, wherein the amino acid surfactant is formed by mixing sodium lauroyl sarcosinate, sodium lauroyl alanine, sodium cocoyl glutamate, sodium cocoyl methyl taurate and sodium cocoyl glycinate in any proportion;
the non-amino acid surfactant is prepared by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and secondary alkyl sodium sulfonate in any proportion.
The nonionic surfactant is prepared by mixing coconut oil fatty acid diethanolamide, fatty alcohol-polyoxyethylene ether, alkyl glucoside and alkyl dimethyl amine oxide in any proportion.
The zwitterionic surfactant is formed by mixing dodecyl betaine, cocamidopropyl betaine and alkyl dimethyl amine oxide in any proportion.
The thickening agent is formed by mixing sodium chloride, polyacrylic acid polymer, carboxymethyl cellulose and guar gum in any proportion; the bactericide is formed by mixing the cason and the chloroxylenol in any proportion; the preservative is formed by mixing isothiazolinone derivatives, nano silver, sorbic acid and monoglycerol laurate in any proportion; the essence consists of alcohol and saturated hydrocarbon essences which are conventional in the field; the water-soluble solvent is formed by mixing ethanol, ethylene glycol, propylene glycol butyl ether and diethylene glycol butyl ether in any proportion.
The preparation method of the laundry detergent comprises the following steps:
s1, placing a nonionic surfactant, an anionic surfactant, a zwitterionic surfactant, dendrobium officinale extractum, moringa oleifera seed extract, a water-soluble solvent and deionized water into a container, heating to 40-50 ℃, and stirring until the components are dissolved and uniformly dispersed;
s2, sequentially adding a preservative, essence, an enzyme stabilizer, a bactericide and a thickening agent under the stirring condition to obtain a uniform mixed solution;
and S3, sequentially adding the biological protease, the lipase, the amylase and the cellulase into the mixed solution, and uniformly stirring to obtain the laundry detergent.
Test example 1
(1) pH value test
The pH measurements of examples 1 to 3 and comparative examples 1 to 5 were directly performed at 25 ℃ and room temperature using a Mettler Toledo Fivego pH meter.
(2) Detergency test
a. According to the requirements of GB-T13174-2008 'determination of detergency and circulating washing performance of a detergent for clothing', three dirty cloths such as carbon black dirty cloth, protein dirty cloth and sebum dirty cloth are selected as experimental objects, a standard laundry detergent is used as a reference laundry detergent, and the obtained decontamination ratio is as follows: carbon black greasy dirt cloth: 1.4, protein stain cloth: 5.0, sebum stain cloth: 1.8. the total value of the decontamination ratio (carbon black soiled cloth, protein soiled cloth and sebum soiled cloth) is equal to 8.2.
b. A certain amount of the laundry detergents of examples 1 to 3 and comparative examples 1 to 5 are respectively prepared into 0.2% aqueous solution, the hardness is 250ppm (calculated by calcium carbonate), the washing temperature is 30 ℃, the stirring speed of a vertical decontamination machine is 120rpm, the water washing time is 20min, and the decontamination capability of the laundry detergents is tested.
(3) Compliance testing
Taking a plurality of commercially available white full-cotton square towels of 30 multiplied by 30cm, and washing the square towels at normal temperature by using the laundry detergents of the examples 1-3 and the comparative examples 1-5 respectively; after washing, the soft degree and the smooth degree are evaluated after drying. The softness ratings were as follows: 1 point (very hard), 2 points (hard), 3 points (not soft and not hard), 4 points (softer) and 5 points (very soft). Smooth degree of hand: 1 point (dry and astringent), 2 points (drier and astringent), 3 points (moderate), 4 points (smoother) and 5 points (very smooth).
The test results are shown in table 1 below:
TABLE 1 pH, stain removal, compliance tests for examples 1-3 and comparative examples 1-5
Test example 2
The laundry detergents of the embodiments 1 to 3 and the comparative examples 1 to 5 of the present invention and the standard laundry detergents specified in the industry standard (the standard laundry detergents are composed of, by mass, 4% of AEO-9, 2% of AES, 8% of dodecylbenzene sulfonic acid, 0.5% of triethanolamine, 0.5% of anhydrous sodium citrate, a proper amount of sodium hydroxide, and the balance of deionized water) are tested by a standard dirty cloth test and a self-made dirty cloth (containing milk stains, blood stains, and oil stains), and the comparative detergency test effect is shown in the following table 2.
TABLE 2 contrast effect tested with self-made soiled cloths
| Laundry detergent | Milk stain removing effect | Blood stain removing effect | Oil stain removing effect | Remarks for note |
| Standard of merit | Is difficult to be removed completelyLeaving traces of milk stain | Difficult to remove and leave obvious blood marks | Difficult to remove and leave oily spots | Obvious stain trace of cloth sample |
| Example 1 | Removed in 45 seconds without residual traces | Instantly removing the blood stain without residue | Removed in 45 seconds without residual traces | The cloth sample is clean as new |
| Example 2 | Removed in 45 seconds without residual traces | Instantly removing the blood stain without residue | Removed in 45 seconds without residual traces | The cloth sample is clean as new |
| Example 3 | Removed in 45 seconds without residual traces | Instantly removing the blood stain without residue | Removed in 45 seconds without residual traces | The cloth sample is clean as new |
| Comparative example 1 | Removed in 1 minute with almost no residual traces | Quick removal and almost no residual trace | Removed in 1 minute with almost no residual traces | The cloth sample is clean as new |
| Comparative example 2 | Removed in 1 minute with almost no residual traces | Quick removal and almost no residual trace | Removed in 1 minute with almost no residual traces | The cloth sample is clean as new |
| Comparative example 3 | Removed in 50 seconds with almost no residual traces | Quick removal, no residual blood stain | Removed in 50 seconds with almost no residual traces | The cloth sample is clean as new |
| Comparative example 4 | Removing for 50 s without residual traces | Quick removal, no residual blood stain | Removed in 50 seconds with almost no residual traces | The cloth sample is clean as new |
| Comparative example 5 | Removing for 50 s without residual traces | Quick removal, no residual blood stain | Removed in 50 seconds with almost no residual traces | The cloth sample is clean as new |
As can be seen from tables 1 and 2, the laundry detergent disclosed by the invention is prepared by fully utilizing the synergistic effect of the components through a specific process, has a good stain removal effect, does not leave any stain residual trace, and has strong hard water resistance. The laundry detergent disclosed by the invention not only has an efficient decontamination and cleaning effect, but also has a washing and protecting two-in-one effect. By adding biological protease, lipase and amylase, the decontamination capability of the laundry detergent is greatly improved, and the laundry detergent has a high-efficiency decontamination effect on protein, starch and fat stains.
The laundry detergent disclosed by the invention is mild in property, free of stimulation and soft in hand feeling, does not leave alkaline residues after washing, does not cause symptoms such as skin allergy, does not damage fabrics, is easy to dissolve in water, and is convenient to use, control in dosage, store and use; has strong functionality and multiple functions of softening, sterilizing, protecting color and the like. The surfactant used in the laundry detergent disclosed by the invention has a good foam stabilizing effect, the detergency effect is far better than that of common laundry detergent products on the market, the foam is less, and no alkaline residue can be achieved by rinsing twice.
The above embodiments are merely preferred embodiments of the present invention, and any simple modification, modification and substitution changes made to the above embodiments according to the technical spirit of the present invention are within the scope of the technical solution of the present invention.
Claims (10)
1. The washing and protecting one-in-one laundry detergent containing the biological protease is characterized by comprising the following components in parts by weight: 1-30 parts of nonionic surfactant, 1-30 parts of anionic surfactant, 0-30 parts of zwitterionic surfactant, 0.6-8 parts of biological protease, 0.6-8 parts of lipase, 0.6-8 parts of amylase, 0.6-8 parts of cellulase, 0-20 parts of water-soluble solvent, 0.01-0.03 part of dendrobium officinale extract, 0.1-0.3 part of moringa seed extract, 0-1.0 part of preservative, 0-0.5 part of essence, 0.1-20 parts of enzyme stabilizer, 0-5 parts of bactericide, 0-1 part of thickening agent and a proper amount of deionized water.
2. The washing and protecting integrated laundry detergent containing biological protease as claimed in claim 1, wherein the preparation of the dendrobium officinale extract comprises the following steps: crushing dried dendrobium officinale, leaching twice with 70-90% ethanol with the weight of 4-6 times of that of the dendrobium officinale at the temperature of 80-90 ℃ and the pH of =8 for 3-5 h, mixing the extractive solutions, and concentrating under reduced pressure to obtain the dendrobium officinale extract.
3. The biological protease-containing washing and care one-time laundry detergent as claimed in claim 1, wherein the preparation of the moringa seed extract comprises the following steps:
(1) extracting moringa seeds for 45-240 min at an extraction pressure of 12-30 MPa and an extraction temperature of 35-60 ℃ for CO2Supercritical CO is carried out under the condition that the gas flow is 6-50 Kg/h2Extracting to obtain an extract;
(2) separating the extract under the conditions that the separation pressure is 3-7 MPa and the separation temperature is 30-60 ℃ to obtain moringa seed extract;
wherein the extraction entrainer is selected from ethanol with the volume percentage of 85-95%, and the dosage of the extraction entrainer is 1-15% of the total weight of the moringa seeds.
4. The washing and protecting one-in-one laundry detergent containing the biological protease is characterized in that the weight ratio of the biological protease to the amylase to the lipase to the cellulase is (2-4) to (1-3) to (2-4).
5. The liquid laundry detergent of claim 1, wherein the enzyme stabilizer is selected from one or more of sodium chloride, glycerol, alkyl glycoside, and polyether polyol.
6. The liquid laundry detergent of claim 1, wherein the weight ratio of the anionic surfactant to the nonionic surfactant to the zwitterionic surfactant is (10-30) to (3-7) to (2-5).
7. The bio-protease containing laundry detergent according to claim 1, wherein the anionic surfactant comprises amino acid surfactants and non-amino acid surfactants, and the amino acid surfactants are selected from one or more of sodium lauroyl sarcosinate, sodium lauroyl alanine, sodium cocoyl glutamate, potassium cocoyl glycinate, sodium cocoyl methyl taurate, sodium cocoyl glycinate, triethanolamine cocoyl glutamate, and supramolecular amino acids;
the non-amino acid surfactant is one or more than two of sodium dodecyl benzene sulfonate, fatty acid salt, sodium fatty acid, fatty alcohol-polyoxyethylene ether sodium sulfate and secondary alkyl sodium sulfonate.
8. The washing-care one-time laundry detergent containing biological protease as claimed in claim 1, characterized in that the non-ionic surfactant is selected from one or more of coconut oil fatty acid diethanolamide, fatty alcohol polyoxyethylene ether, condensation compound of fatty acid methyl ester and ethylene oxide, fatty alcohol polyoxyethylene ether, alkyl glucoside and alkyl dimethyl amine oxide;
the zwitterionic surfactant is selected from one or more of dodecyl betaine, cocamidopropyl betaine, alkyl dimethyl amine oxide, dodecyl dimethyl amine ethyl lactone and cocamidopropyl amine oxide.
9. The washing and care one-time laundry detergent containing biological protease as claimed in claim 1, characterized in that the thickener is selected from one or more of sodium chloride, modified starch, polyacrylic acid polymer, carboxymethyl cellulose, guar gum; the bactericide is selected from one or two of cason and chloroxylenol; the preservative is selected from one or more than two of isothiazolinone derivatives, nano silver, sorbic acid and monoglycerol laurate; the essence is selected from one or more of cason, ethers, alcohols and saturated hydrocarbon essences; the water-soluble solvent is one or more than two of ethanol, ethylene glycol, isopropanol, ethylene glycol butyl ether, ethylene glycol propyl ether, propylene glycol butyl ether, diethyl ether and diethylene glycol butyl ether.
10. The washing and care integrated laundry detergent containing the biological protease as claimed in claim 1, characterized in that the preparation method of the laundry detergent comprises the following steps:
s1, placing a nonionic surfactant, an anionic surfactant, 2/3 zwitterionic surfactant, dendrobium officinale extractum, moringa seed extract, a water-soluble solvent and deionized water into a container, heating to 52-68 ℃, and stirring until the components are dissolved and uniformly dispersed;
s2, cooling to 40-50 ℃, and then sequentially adding a preservative, essence, an enzyme stabilizer, 1/3 zwitterionic surfactant, a bactericide and a thickening agent under the stirring condition to obtain a uniform mixed solution;
and S3, cooling to 25-35 ℃, sequentially adding the biological protease, the lipase, the amylase and the cellulase into the mixed solution, and uniformly stirring to obtain the washing and protecting integrated laundry detergent containing the biological protease.
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| CN114774213B (en) * | 2021-05-26 | 2023-10-31 | 浙江施维康生物医学材料有限公司 | Detergent for textiles and preparation method thereof |
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| CN113637533A (en) * | 2021-09-01 | 2021-11-12 | 宁波芮颂生物科技有限公司 | Preparation method of plant-type anti-allergic and antistatic laundry detergent |
| CN115216371A (en) * | 2022-05-20 | 2022-10-21 | 广州摩亚方舟贸易有限公司 | Multifunctional laundry detergent and preparation method thereof |
| CN114921293A (en) * | 2022-06-13 | 2022-08-19 | 西安优露清科技股份有限公司 | Abrasive cleaner for immediately removing clothes stains and preparation method thereof |
| CN115678688A (en) * | 2022-09-23 | 2023-02-03 | 深圳乙奇生物科技有限公司 | Special laundry detergent for sportswear and preparation method thereof |
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