CN112646420A - Environment-friendly water-based ink for green printing of rigid substrate signboard - Google Patents
Environment-friendly water-based ink for green printing of rigid substrate signboard Download PDFInfo
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- CN112646420A CN112646420A CN201911177257.3A CN201911177257A CN112646420A CN 112646420 A CN112646420 A CN 112646420A CN 201911177257 A CN201911177257 A CN 201911177257A CN 112646420 A CN112646420 A CN 112646420A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 238000007639 printing Methods 0.000 title claims abstract description 18
- 239000000758 substrate Substances 0.000 title claims abstract description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000002904 solvent Substances 0.000 claims abstract description 25
- 239000008367 deionised water Substances 0.000 claims abstract description 21
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 21
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- 230000000694 effects Effects 0.000 claims abstract description 10
- 229920000412 polyarylene Polymers 0.000 claims abstract description 10
- -1 sulfide sulfone Chemical class 0.000 claims abstract description 10
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 9
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000661 sodium alginate Substances 0.000 claims abstract description 9
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 9
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 9
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 24
- 239000002923 metal particle Substances 0.000 claims description 20
- 229940071575 silver citrate Drugs 0.000 claims description 15
- QUTYHQJYVDNJJA-UHFFFAOYSA-K trisilver;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Ag+].[Ag+].[Ag+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QUTYHQJYVDNJJA-UHFFFAOYSA-K 0.000 claims description 15
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 12
- 239000001509 sodium citrate Substances 0.000 claims description 12
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical group [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 4
- 239000000908 ammonium hydroxide Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 230000002572 peristaltic effect Effects 0.000 claims description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 4
- 238000000967 suction filtration Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 2
- 239000000976 ink Substances 0.000 description 65
- 239000000975 dye Substances 0.000 description 14
- 239000000049 pigment Substances 0.000 description 14
- 238000005516 engineering process Methods 0.000 description 7
- 238000007641 inkjet printing Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 3
- 239000008365 aqueous carrier Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002952 polymeric resin Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 238000004904 shortening Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses environment-friendly water-based ink for green printing of rigid substrate signboard, which is characterized by comprising the following components in parts by weight: 2-6 parts of polyarylene sulfide sulfone resin, 10-15 parts of conductive solvent, 0.2-2 parts of solvent surface activity, 0.09-0.15 part of sodium alginate, 5-10 parts of glycerol, 5-5.5 parts of triethylene glycol, 3.2-3.6 parts of pH regulator, 0.3-0.5 part of surfactant, 1-1.5 parts of triethylene glycol monobutyl ether, 2-5 parts of dye and 70-80 parts of deionized water.
Description
Technical Field
The invention relates to the technical field of signboard printing ink, in particular to environment-friendly water-based ink for green printing of a rigid substrate signboard.
Background
Ink jet printing is the combined imaging of minute droplets of ink ejected onto a medium. The size of the ink droplets can be as small as only a few tens of microns. Inkjet printing technology is diverse, and printing technology is generally divided from two perspectives: 1. the printing on a medium according to ink drops is divided into a list/demand type and a continuous type, and the continuous type ink jet is not adopted by most printers at present because of high cost and complex maintenance; 2. the division into ink droplet generation methods is more, such as thermal jet/bubble type, piezoelectric type, acoustic wave type, electrostatic type, and the like, and the thermal jet/bubble type and the piezoelectric type are both successful. The principle of the thermal bubble jet technology is that a plurality of jet holes are formed in an ink jet head, an electric pulse is applied to a selected thermistor, the thermistor heats ink at a speed of 1000 ℃/millisecond, an ink film with a thickness of about 0.1mm is heated to about 340 ℃, bubbles are generated and burst, and then ink droplets are ejected from the jet holes.
Piezoelectric ink jet technology utilizes the principle of direct voltage conversion to create a mechanical force and "pushes" or "pushes" ink out of an ink channel in a mechanical action to eject ink droplets onto a medium to form an image. Advantages of the piezoelectric ink jet technology: the ink jet head works at normal temperature, so that the service life of the nozzle is greatly prolonged (thousands of hours can be reached), ink is jetted under pressure rather than heat, the size of ink drops can be selected, the shape is more regular, the diameter of the ink drops is small, the resolution ratio is high, wider ink types can be selected, and dye type and pigment type inks can be used, so that the application range mainly outdoors is realized, and compared with a thermal bubble type ink jet technology, the whole ink consumption is less.
There are many different types of ink for inkjet printing, and the ink is obtained by uniformly dispersing a colorant in a solvent system, and the ink is classified into water-based ink and solvent-based ink according to the solvent. The water-based ink is prepared by taking water as a main solvent, accounts for 60-70% of the total amount of the ink, and does not contain or hardly contain a volatile organic solvent, so that the water-based ink is more environment-friendly and has less influence on human health compared with a solvent-based ink taking the volatile organic solvent as a main solvent.
Colorants used in inks for inkjet printing are mainly of two types, a dye (water-soluble dye) and a pigment (insoluble pigment and disperse dye). Although the light and water fastness of the dye is inferior to that of the pigment, the dye is relatively stable because the dye is completely dissolved in the ink medium. Pigment is superior to dye in light resistance and water fastness and is not easily affected by weather, but because pigment is not dissolved but dispersed in ink medium, pigment ink is generally stabilized by coating pigment particles with polymer such as resin, and a stable film is formed after ink is sprayed onto medium and is adhered to medium. With the continuous development and progress of the technology, the pigment ink has long-term development in the aspects of granularity, stability, color reduction and the like, the problems of instability of the aqueous pigment ink and easy blockage of a spray head for a long time are solved, and the market is gradually expanded due to the inherent advantages of strong light stability and the like.
At present, an electric original is installed on a rigid bottom signboard according to requirements, how to spray ink with good toughness and convenient processing on the signboard and ensure the conductivity of the ink are needed to be solved.
Disclosure of Invention
The invention aims to provide environment-friendly water-based ink with conductivity and corrosion resistance for green printing of rigid base signboard.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows: an environment-friendly water-based ink for green printing of rigid-substrate signboard comprises the following components in parts by weight:
2-6 parts of polyarylene sulfide sulfone resin, 10-15 parts of conductive solvent, 0.2-2 parts of solvent surface activity, 0.09-0.15 part of sodium alginate, 5-10 parts of glycerol, 5-5.5 parts of triethylene glycol, 3.2-3.6 parts of pH regulator, 0.3-0.5 part of surfactant, 1-1.5 parts of triethylene glycol monobutyl ether, 2-5 parts of dye and 70-80 parts of deionized water;
preferably, the PH regulator is ammonium hydroxide, and the addition process is as follows: adding polyarylene sulfide sulfone resin, nano metal particles, a dispersing agent, solvent surface activity, sodium alginate, glycerol, triethylene glycol, a pH regulator, a surfactant and triethylene glycol monobutyl ether into deionized water according to parts by weight, stirring for 10-30min, adding a dye, continuously stirring for 1-1.5h, and repeatedly filtering to obtain the ink.
Preferably, the surfactant is one or a combination compound of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate and sodium polyacrylate.
Preferably, the conductive solvent comprises 3-5 parts of nano metal particles and 5-10 parts of a dispersing agent according to parts by weight.
Preferably, the nano metal particles are silver citrate metal particles, and the preparation steps are as follows:
dissolving a proper amount of sodium citrate in 100ml of deionized water at normal temperature, dissolving 6g of silver nitrate in 80ml of deionized water, slowly dropwise adding a silver nitrate aqueous solution into the sodium citrate aqueous solution at the speed of 20r/min by using a peristaltic pump, accelerating stirring for 30min when a white precipitate appears, performing suction filtration, deionized water washing twice and ethanol washing once, drying in an oven for 6h, and drying to obtain the silver citrate metal particles.
Preferably, the molar ratio of silver nitrate to sodium citrate is 3: 1.
compared with the prior art, the invention has the advantages that:
according to the invention, the polyarylene sulfide sulfone resin, the solvent surfactant and the conductive solvent are added into the dye, so that the stability of the ink can be improved, the surface tension of the ink is reduced, and the printing work of the ink is facilitated, so that the service life of a machine-printed ink-jet head is prolonged, the ink can have conductive performance by adding the silver citrate into the ink, the stability is high, and the mounting of an electrical element on a signboard is facilitated.
Detailed Description
Example one
The invention provides environment-friendly water-based ink for green printing of rigid substrate signboard, which comprises the following components in parts by weight:
2 parts of polyarylene sulfide sulfone resin, 10 parts of conductive solvent, 0.2 part of surfactant, 0.09 part of sodium alginate, 5 parts of glycerol, 5 parts of triethylene glycol, 3.2 parts of pH regulator, 0.3 part of surfactant, 1 part of triethylene glycol monobutyl ether, 2 parts of dye and 70 parts of deionized water;
the pH regulator is ammonium hydroxide, and the adding process is as follows: adding polyarylene sulfide sulfone resin, nano metal particles, a dispersing agent, solvent surface activity, sodium alginate, glycerol 5, triethylene glycol, a pH regulator, a surfactant and triethylene glycol monobutyl ether into deionized water according to parts by weight, stirring for 10-30min, adding a dye, continuously stirring for 1-1.5h, repeatedly filtering to obtain ink, and adding the pH regulator into the ink to ensure the solubility and dispersibility of the polymer resin in an aqueous carrier.
The surfactant is one or a combination compound of sodium dodecyl sulfate, sodium dodecyl sulfonate, sodium dodecyl benzene sulfonate and sodium polyacrylate, and is used for improving the grinding effect of the pigment color paste, shortening the time, reducing the diameter of pigment particles, improving the stability of the color paste and ink and reducing the surface tension of the ink.
The conductive solvent comprises 3 parts of nano metal particles and 5 parts of a dispersing agent according to the weight part.
The nano metal particles are silver citrate metal particles, and the preparation steps are as follows:
at normal temperature, dissolving a proper amount of sodium citrate in 100ml of deionized water, dissolving 6g of silver nitrate in 80ml of deionized water, and slowly dripping the silver nitrate aqueous solution into the sodium citrate aqueous solution at the speed of 20r/min by using a peristaltic pump, wherein the molar ratio of the silver nitrate to the sodium citrate is 3: 1, until white precipitation appears, stirring is accelerated for 30min, suction filtration, deionized water washing twice and ethanol washing once are carried out, the mixture is placed in a drying oven for drying for 6h, silver citrate metal particles are obtained after drying, the decomposition temperature of the silver citrate is low, the silver citrate has excellent stability performance at room temperature, preparation and storage are simple, the ink can have conductivity by adding the silver citrate into the ink, the stability is high, and an electric element is convenient to mount on a signboard.
Example two
The invention provides environment-friendly water-based ink for green printing of rigid substrate signboard, which comprises the following components in parts by weight:
6 parts of polyarylene sulfide sulfone resin, 15 parts of conductive solvent, 2 parts of solvent surface activity, 0.15 part of sodium alginate, 10 parts of glycerol, 5.5 parts of triethylene glycol, 3.6 parts of pH regulator, 0.5 part of surfactant, 1.5 parts of triethylene glycol monobutyl ether, 5 parts of dye and 80 parts of deionized water;
the pH regulator is ammonium hydroxide, and the adding process is as follows: adding polyarylene sulfide sulfone resin, nano metal particles, a dispersing agent, solvent surface activity, sodium alginate, glycerol, triethylene glycol, a pH regulator, a surfactant and triethylene glycol monobutyl ether into deionized water according to parts by weight, stirring for 10-30min, adding a dye, continuously stirring for 1-1.5h, repeatedly filtering to obtain ink, and adding the pH regulator into the ink to ensure the solubility and dispersibility of the polymer resin in an aqueous carrier.
The surfactant is one or a combination compound of sodium dodecyl sulfate, sodium dodecyl sulfonate, sodium dodecyl benzene sulfonate and sodium polyacrylate, and is used for improving the grinding effect of the pigment color paste, shortening the time, reducing the diameter of pigment particles, improving the stability of the color paste and ink and reducing the surface tension of the ink.
The conductive solvent comprises 5 parts of nano metal particles and 10 parts of a dispersing agent according to the weight part.
The nano metal particles are silver citrate metal particles, and the preparation steps are as follows:
at normal temperature, dissolving a proper amount of sodium citrate in 100ml of deionized water, dissolving 6g of silver nitrate in 80ml of deionized water, and slowly dripping the silver nitrate aqueous solution into the sodium citrate aqueous solution at the speed of 20r/min by using a peristaltic pump, wherein the molar ratio of the silver nitrate to the sodium citrate is 3: 1, until white precipitation appears, stirring is accelerated for 30min, suction filtration, deionized water washing twice and ethanol washing once are carried out, the mixture is placed in a drying oven to be dried for 6h, silver citrate metal particles are obtained after drying, the decomposition temperature of the silver citrate is low, the silver citrate has excellent stability performance at room temperature, preparation and storage are simple, the ink can have conductivity by adding the silver citrate into the ink, the stability is high, and an electric element is convenient to mount on a signboard.
Claims (6)
1. The environment-friendly water-based ink for green printing of the rigid substrate signboard is characterized by comprising the following components in parts by weight:
2-6 parts of polyarylene sulfide sulfone resin, 10-15 parts of conductive solvent, 0.2-2 parts of solvent surface activity, 0.09-0.15 part of sodium alginate, 5-10 parts of glycerol, 5-5.5 parts of triethylene glycol, 3.2-3.6 parts of pH regulator, 0.3-0.5 part of surfactant, 1-1.5 parts of triethylene glycol monobutyl ether, 2-5 parts of dye and 70-80 parts of deionized water.
2. The environmentally friendly water-based ink for green printing of rigid substrate signs of claim 1, wherein: the pH regulator is ammonium hydroxide, and the adding process is as follows: adding polyarylene sulfide sulfone resin, nano metal particles, a dispersing agent, solvent surface activity, sodium alginate, glycerol, triethylene glycol, a pH regulator, a surfactant and triethylene glycol monobutyl ether into deionized water according to parts by weight, stirring for 10-30min, adding a dye, continuously stirring for 1-1.5h, and repeatedly filtering to obtain the ink.
3. The environmentally friendly water-based ink for green printing of rigid substrate signs of claim 1, wherein: the surfactant is one or a combination compound of sodium dodecyl sulfate, sodium dodecyl sulfonate, sodium dodecyl benzene sulfonate and sodium polyacrylate.
4. The environmentally friendly water-based ink for green printing of rigid substrate signs of claim 1, wherein: the conductive solvent comprises 3-5 parts of nano metal particles and 5-10 parts of a dispersing agent according to parts by weight.
5. The environmentally friendly water-based ink for green printing of rigid substrate signs according to claim 4, wherein the nano metal particles are silver citrate metal particles, and the preparation steps are as follows:
at normal temperature, a proper amount of sodium citrate is dissolved in 100ml of deionized water, 6g of silver nitrate is dissolved in 80ml of deionized water, a peristaltic pump is used for slowly dripping the silver nitrate aqueous solution into the sodium citrate aqueous solution at the speed of 20r/min, when white precipitates appear, stirring is accelerated for 30min, suction filtration, deionized water washing twice and ethanol washing once are carried out, the mixture is placed into an oven for drying for 6h, and silver citrate metal particles are obtained after drying.
6. The environmentally friendly water-based ink for green printing of rigid substrate signs of claim 5, wherein: the molar ratio of the silver nitrate to the sodium citrate is 3: 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911177257.3A CN112646420A (en) | 2019-11-26 | 2019-11-26 | Environment-friendly water-based ink for green printing of rigid substrate signboard |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911177257.3A CN112646420A (en) | 2019-11-26 | 2019-11-26 | Environment-friendly water-based ink for green printing of rigid substrate signboard |
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| Publication Number | Publication Date |
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| CN112646420A true CN112646420A (en) | 2021-04-13 |
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| CN201911177257.3A Withdrawn CN112646420A (en) | 2019-11-26 | 2019-11-26 | Environment-friendly water-based ink for green printing of rigid substrate signboard |
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| CN (1) | CN112646420A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0433971A (en) * | 1990-05-30 | 1992-02-05 | Toto Kasei Kk | Coating composition composed of polyarylene sulfide resin |
| JP2001287353A (en) * | 2000-04-05 | 2001-10-16 | Fuji Xerox Co Ltd | Ink jet recording method and ink jet recording ink |
| CN1974688A (en) * | 2006-12-12 | 2007-06-06 | 中国乐凯胶片集团公司 | Water-base pigment ink |
| CN103102732A (en) * | 2012-12-12 | 2013-05-15 | 张家港威迪森化学有限公司 | Inkjet printing ink |
| CN106867311A (en) * | 2015-12-10 | 2017-06-20 | 青岛华南盛源果业有限公司 | A kind of pad-ink |
| CN108610743A (en) * | 2018-04-18 | 2018-10-02 | 长沙新材料产业研究院有限公司 | A kind of conductive ink composition and preparation method thereof |
-
2019
- 2019-11-26 CN CN201911177257.3A patent/CN112646420A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0433971A (en) * | 1990-05-30 | 1992-02-05 | Toto Kasei Kk | Coating composition composed of polyarylene sulfide resin |
| JP2001287353A (en) * | 2000-04-05 | 2001-10-16 | Fuji Xerox Co Ltd | Ink jet recording method and ink jet recording ink |
| CN1974688A (en) * | 2006-12-12 | 2007-06-06 | 中国乐凯胶片集团公司 | Water-base pigment ink |
| CN103102732A (en) * | 2012-12-12 | 2013-05-15 | 张家港威迪森化学有限公司 | Inkjet printing ink |
| CN106867311A (en) * | 2015-12-10 | 2017-06-20 | 青岛华南盛源果业有限公司 | A kind of pad-ink |
| CN108610743A (en) * | 2018-04-18 | 2018-10-02 | 长沙新材料产业研究院有限公司 | A kind of conductive ink composition and preparation method thereof |
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Application publication date: 20210413 |