CN112626698B - Healthy screen cloth - Google Patents
Healthy screen cloth Download PDFInfo
- Publication number
- CN112626698B CN112626698B CN202011315930.8A CN202011315930A CN112626698B CN 112626698 B CN112626698 B CN 112626698B CN 202011315930 A CN202011315930 A CN 202011315930A CN 112626698 B CN112626698 B CN 112626698B
- Authority
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- China
- Prior art keywords
- healthy
- layer
- nco
- dimensional porous
- surface layer
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- 239000004744 fabric Substances 0.000 title claims abstract description 62
- 239000010410 layer Substances 0.000 claims abstract description 103
- 239000000835 fiber Substances 0.000 claims abstract description 46
- 229920000728 polyester Polymers 0.000 claims abstract description 44
- 239000002344 surface layer Substances 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 31
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920000433 Lyocell Polymers 0.000 claims abstract description 13
- 239000011787 zinc oxide Substances 0.000 claims abstract description 12
- 239000010977 jade Substances 0.000 claims abstract description 9
- 229920001778 nylon Polymers 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 8
- 239000002135 nanosheet Substances 0.000 claims description 44
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 21
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 18
- 239000002585 base Substances 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- RJZNFXWQRHAVBP-UHFFFAOYSA-I aluminum;magnesium;pentahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Al+3] RJZNFXWQRHAVBP-UHFFFAOYSA-I 0.000 claims description 14
- 229910021389 graphene Inorganic materials 0.000 claims description 13
- 239000002244 precipitate Substances 0.000 claims description 12
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 11
- 239000000347 magnesium hydroxide Substances 0.000 claims description 11
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 11
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 8
- 238000000149 argon plasma sintering Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000005245 sintering Methods 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 238000009837 dry grinding Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000007909 melt granulation Methods 0.000 claims description 5
- 238000002074 melt spinning Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 2
- 230000006870 function Effects 0.000 abstract description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 3
- 239000011707 mineral Substances 0.000 abstract description 3
- 150000001450 anions Chemical class 0.000 abstract description 2
- 230000005540 biological transmission Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 19
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000009941 weaving Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 10
- 239000000395 magnesium oxide Substances 0.000 description 9
- 239000005020 polyethylene terephthalate Substances 0.000 description 9
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 238000009987 spinning Methods 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 229920002302 Nylon 6,6 Polymers 0.000 description 4
- 210000004027 cell Anatomy 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 238000007645 offset printing Methods 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 210000002268 wool Anatomy 0.000 description 4
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- 229920002334 Spandex Polymers 0.000 description 3
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- 241000194017 Streptococcus Species 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000009940 knitting Methods 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000004759 spandex Substances 0.000 description 3
- 239000002759 woven fabric Substances 0.000 description 3
- WRDNCFQZLUCIRH-UHFFFAOYSA-N 4-(7-azabicyclo[2.2.1]hepta-1,3,5-triene-7-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1C2=CC=C1C=C2 WRDNCFQZLUCIRH-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 2
- 239000005750 Copper hydroxide Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 241000208181 Pelargonium Species 0.000 description 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 2
- 230000000840 anti-viral effect Effects 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229910001956 copper hydroxide Inorganic materials 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000005543 nano-size silicon particle Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 206010003399 Arthropod bite Diseases 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- 208000006877 Insect Bites and Stings Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000008104 plant cellulose Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- -1 polytetramethylene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000917 skin toxin Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/10—Open-work fabrics
- D04B21/12—Open-work fabrics characterised by thread material
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The utility model relates to a healthy mesh cloth, which comprises a surface layer, a connecting layer and a base layer, wherein the surface layer is connected with the base layer through the connecting layer; the thickness ratio of the surface layer, the connecting layer and the base layer is 4:1: 4-6: 1:6, preferably 5:1: 5; the surface layer is made of healthy polyester fiber and lyocell fiber; the number ratio of the healthy polyester fibers to the lyocell fibers is 19: 1-29: 1; the connecting layer is made of nylon fibers, and the bottom layer is made of healthy polyester fibers. This application introduces zinc oxide whisker and jade powder structure in healthy material, utilizes to have similar mineral substance structure to promote its anion and functions such as far infrared transmission.
Description
Technical Field
The utility model relates to the technical field of mesh fabric production, in particular to a healthy mesh fabric.
Background
Chinese patent application No. 2019113960007 relates to a high-strength mesh cloth and a preparation method thereof, wherein the high-strength mesh cloth is prepared by high-strength composite monofilaments through a weaving process; the high-strength composite monofilament comprises an inner layer and an outer layer, wherein the outer layer is coated on the periphery of the inner layer; the ratio of the cross-sectional areas of the inner layer and the outer layer is 10: (6.5-8.5); the inner layer comprises the following raw materials in parts by weight: 90-95 parts of polyhexamethylene adipamide, 5-10 parts of poly-p-phenylene terephthalamide, 2-3 parts of boron nitride nanosheets, 4-5.5 parts of nano silicon dioxide, 5-7 parts of a lubricant and 3-5 parts of a dispersant; the outer layer comprises the following raw materials in parts by weight: 15-20 parts of polyhexamethylene adipamide, 80-88 parts of poly-p-phenylene terephthalamide and 3-4 parts of reduced graphene oxide. The high-strength mesh cloth has the advantages of high tearing strength (in the warp direction), high tensile strength (in the warp direction), high strength, excellent mechanical property and long service life; the comprehensive service performance is good, and the market application prospect is wide.
Chinese patent application No. 201711234928.6 relates to a mixed-color weaving process for double-jacquard woven fabrics, which is integrally woven by a double-needle bar double-jacquard warp knitting machine, the double-needle bar double-jacquard warp knitting machine comprises a front needle bar, a rear needle bar and guide bars, the guide bars comprise ground guide bars GB1, GB2, GB5, GB6 and jacquard weave bars JB1 and JB2, one ground guide bar of each guide bar is made of nylon low stretch yarn or cation low stretch yarn or one jacquard weave bar is made of polyester low stretch yarn, the other guide bars are respectively made of polyester low stretch yarn, nylon semi-bright yarn and cation low stretch yarn, and the grey cloth is tightly woven into a whole by doubling the polyester low stretch yarn and the nylon semi-bright yarn and the polyester low stretch yarn and the cation low stretch yarn, so that the front side and the back side of the grey cloth are tightly woven without gaps, the mixed-color jacquard woven double-jacquard woven fabrics with better mixed-color effect are more excellent, and the problem of the color of the double-jacquard woven fabrics is solved, Uneven through holes, exposed threads in the holes, low physical property, lower supporting force and the like, and greatly improves the product quality.
Chinese patent application No. 201810049198.0 relates to the technical field of textile production, and provides a sandwich mesh cloth for composite plates, which can be compounded with plates, is high temperature resistant, effectively enhances the strength, impact resistance and shear stress resistance of the plates, and consists of a surface layer, a bottom layer and a supporting yarn connected between the surface layer and the bottom layer; the surface layer, the bottom layer and the supporting yarns are woven into three-dimensional sandwich mesh cloth in a warp knitting mode; the surface layer is woven by heat-resistant spandex fibers and carbon fibers into a mutually parallel structure; the bottom layer is woven into a mutually parallel structure by heat-resistant spandex fibers and polyester fibers; the supporting yarn is heat-resistant spandex fiber woven monofilament. 1
Chinese patent application No. 201711468671.0 relates to a ventilative three-dimensional vamp structure, including screen cloth basic unit, screen cloth surface course and be located the three-dimensional offset printing layer and the junctional complex between screen cloth basic unit and the screen cloth surface course, three-dimensional offset printing layer is by down and last oily gloss oil layer, aqueous three-dimensional gold oil layer, foaming look thick liquid layer and the dot printing layer of being in proper order, three-dimensional offset printing layer covers partial screen cloth basic unit, the screen cloth surface course passes through the junctional complex respectively with screen cloth basic unit and three-dimensional offset printing layer hot pressing connection. The utility model also discloses a manufacturing process of the breathable three-dimensional vamp structure. By adopting the technical scheme of the utility model, the integrated vamp without sewing is realized, the three-dimensional decorative feeling is very strong on the non-outermost layer of the vamp, and the whole vamp has the function of shaping and supporting, so that the vamp has good stiffness and attractiveness, the printed patterns can be directly observed through the mesh fabric surface layer, and all the layers of the vamp are combined and fastened, and are firm and durable.
Chinese patent application No. 201710706459.7 relates to a sandwich screen cloth is spun to dacron colour, the sandwich layer including surface course, bottom, support surface course and bottom, surface course, sandwich layer or bottom weave by crisscross yarn and form, surface course and bottom on be equipped with the mesh, the yarn of colored fibre intensive mixing constitution of yarn by corresponding colour. The sandwich mesh fabric is woven by adopting the yarns on the surface layer, the sandwich layer and the bottom layer, and the yarns are formed by fully mixing the colored fibers. The coloring fiber is produced by adding proper coloring agent during polymerization or spinning during the production process of corresponding polyester filament fiber, and the coloring agent is uniformly dispersed in the fiber after spinning formation. The process belongs to physical change and has the advantages of continuous coloring and spinning, uniform coloring, good color fastness, high dye uptake, short production period, low cost and less pollution. The screen cloth has the advantages of no pollution, uniform coloring, no fading, short production period, low cost and little pollution.
Chinese patent application No. 2019113998409 relates to a high wear-resistant mesh cloth and a preparation method thereof, wherein the high wear-resistant mesh cloth is prepared by weaving high wear-resistant composite monofilaments; the high-wear-resistance composite monofilament comprises an inner layer and an outer layer, wherein the outer layer is coated on the periphery of the inner layer; the ratio of the cross-sectional areas of the inner layer and the outer layer is 10: (7.5-9); the inner layer comprises the following raw materials in parts by weight: 90-95 parts of polyhexamethylene adipamide, 5-8 parts of pelargonium adipamide, 4-6 parts of carboxylated carbon nanotubes and the outer layer of the material comprising the following raw materials in parts by weight: 13-16 parts of polyhexamethylene adipamide, 80-85 parts of pelargonium adipamide, 6-8 parts of polytetramethylene adipamide, 2-3 parts of graphene, 3-4.5 parts of nano silicon dioxide, 3-5 parts of a lubricant and 4-6 parts of a dispersant. The high-wear-resistance mesh cloth has excellent wear resistance; the (warp direction) tearing strength is large, the (warp direction) tensile strength is large, and the (warp direction) tensile strength is high in strength, good in mechanical property and long in service life.
Chinese patent application No. 201710329490.3 relates to a weaving method of double-jacquard mesh cloth, which comprises the following steps: defining the basic organization of a guide bar, and then weaving the double jacquard mesh cloth: the guide bar yarn laying is characterized in that a ground guide bar GB1 is matched with a jacquard pattern guide JB1 to work on a front needle bed, and the jacquard pattern effect on the front face of the grey cloth is formed by weaving; the ground guide bar GB6 and the jacquard guide bar JB2 are jointly knitted to form base fabric of the grey cloth, and the jacquard guide bar JB2 is knitted to form a V point jacquard effect on the front surface of the grey cloth; the front and back connecting lines of the grey cloth are woven by the ground guide bar GB5, and under the weaving action of the ground guide bar GB5, the front and back sides of the grey cloth are integrally woven and connected into a whole to form the double-jacquard mesh cloth. When the weaving method is adopted for weaving, the front side and the back side of the grey cloth are tightly woven and connected into a whole without gaps, so that the problems of foaming and wrinkling, uneven through holes, thread exposure in the holes, lower physical property, lower supporting force and the like are effectively solved, and the weaving production quality is greatly improved.
Chinese patent application No. 201710016771.3 relates to a manufacturing method of double-colored three-layer screen cloth that discolours, including following step threading, step such as weaving and dyeing and finishing, through specific threading and yarn pad motion mode, can form bellied wave sand grip or staggered arrangement's lug on the surface course of three-layer screen cloth, have comparatively bright third dimension, simultaneously middle level colour can be revealed through the recess between the sand grip or the recess between the lug, because the barrier effect of sand grip or lug, the colour of three-layer screen cloth can be along with the different and production changes of observer's visual angle, realize the colour change effect, and do not influence the gas permeability and the weight of screen cloth, the gas permeability is better and cost and weight are lower relatively.
Chinese patent application number 201621094328.5 relates to a screen cloth of mosquito-proof insect bite, be in including basic gauze and setting the mosquito-proof worm gauze of basic gauze upper surface, the shape of mosquito-proof worm gauze is the wave, mosquito-proof worm gauze has the crisscross crest and the trough that set up of a plurality of intervals, the trough and the basic gauze of mosquito-proof worm gauze are made through the silk thread or are fixed through the hot viscose glue bonding, distance H between the crest of mosquito-proof worm gauze and the basic gauze is not less than 6mm, distance L between two adjacent crests of mosquito-proof worm gauze is 8mm ~ 12 mm. The mosquito-repellent incense has the advantages of simple structure, convenience in use, good ventilation performance, better effect of preventing mosquito bites, lighter weight, no toxicity, no smell, long-term use, simple manufacturing process, low cost and convenience in popularization and application.
Chinese patent application number 201520773663.7 relates to an anti ultraviolet three-layer screen cloth, including the screen cloth body, the screen cloth body includes upper strata, lower floor and the intermediate level that supports upper and lower floor, its characterized in that, the intermediate level includes globular elasticity interval silk bundle, U type silk bundle and V type silk bundle, globular elasticity interval silk bundle is connected with the lower floor, alternate between U type silk bundle and upper strata and globular elasticity interval silk bundle, alternate between V type silk bundle and upper and lower floor and globular elasticity interval silk bundle, the three-layer screen cloth of the utility model has the advantage of resisting radiation, antibiotic deodorization and comfortable and easy to wear.
Chinese patent application No. 201220505325.1 relates to a transparent three-layer mesh, which relates to a mesh. The jacquard and wool fabric comprises a surface plain cloth layer, a jacquard and wool high layer and a bottom plain cloth layer, wherein the surface plain cloth layer is arranged on the upper surface layer of a transparent three-layer mesh fabric, the jacquard and wool high layer is arranged between the surface plain cloth layer and the bottom plain cloth layer, the bottom plain cloth layer is arranged on the lower surface layer of the transparent three-layer mesh fabric, the surface plain cloth layer and the bottom plain cloth layer are made of polyester transparent yarns, and the jacquard and wool high layer is made of polyester; the utility model is made of transparent silk, has high transparency and beautiful appearance, and is suitable for shoes, clothes and bags, and also suitable for decorative cloth.
Disclosure of Invention
The utility model aims to overcome the defects of the prior art and provide a healthy mesh.
The purpose of the utility model is realized by the following technical scheme:
a healthy mesh fabric comprises a surface layer, a connecting layer and a base layer, wherein the surface layer and the base layer are connected through the connecting layer.
The thickness ratio of the surface layer, the connecting layer and the base layer is 4:1: 4-6: 1:6, preferably 5:1: 5.
The surface layer is made of healthy polyester fiber and lyocell fiber;
the ratio of the healthy polyester fibers to the lyocell fibers is 19: 1-29: 1.
The connecting layer is made of nylon fibers.
The bottom layer is made of healthy polyester fiber.
The preparation method of the healthy polyester fiber comprises the following steps: dispersing two-dimensional porous NCO nanosheets in a sodium hydroxide solution, then adding a magnesium chloride solution for microwave ultrasonic mixing, and then reacting for 30-50 minutes at a reaction temperature of 33-38 ℃ to obtain a two-dimensional porous NCO nanosheet adsorbed magnesium hydroxide precipitate; then continuously adding an aluminum chloride solution, continuously generating a precipitate, and filtering and drying to obtain an aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheet; carrying out dry grinding on aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheets, jade powder, zinc oxide whiskers and graphene oxide, and putting the ground mixture into a laser sintering chamber for rapid sintering to obtain a healthy material; then, carrying out melt granulation on the healthy material, the polyvinyl alcohol, the PBT particles and the regenerated PET slices to obtain healthy master batches; and then carrying out melt spinning on the healthy master batch and the PET chips to obtain the healthy polyester fiber.
The mass ratio of the two-dimensional porous NCO nanosheet to the magnesium chloride is 4: 1-6: 1.
The mass ratio of the two-dimensional porous NCO nanosheet to the aluminum chloride is 4: 1-6: 1.
The mass fraction of the aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheet in the healthy material is 20-30%.
The mass fraction of the graphene oxide in the healthy material is 20-30%.
The mass fraction of the zinc oxide whisker in the healthy material is 20-30%.
The mass fraction of the healthy material in the healthy master batch is 10-20%.
The mass fraction of the polyethanol in the healthy master batch is 1-3%.
The mass fraction of the PBT particles in the healthy master batch is 30-50%.
The mass fraction of the healthy master batch in the healthy polyester fiber is 10-20%.
Firstly, reacting magnesium chloride with hydroxyl in sodium hydroxide to obtain magnesium hydroxide precipitate, wherein the magnesium hydroxide precipitate is absorbed in porous gaps of a two-dimensional porous NCO nanosheet; the porous characteristic of the two-dimensional porous NCO nanosheet is utilized to attach the magnesium hydroxide in the pores of the two-dimensional porous NCO nanosheet, so that an antibacterial function is achieved. Then copper hydroxide is absorbed on the surface of the magnesium hydroxide-two-dimensional porous NCO nanosheet to generate copper hydroxide, the magnesium hydroxide is quickly calcined at high temperature to generate magnesium oxide, the magnesium oxide is absorbed in porous gaps of the two-dimensional porous NCO nanosheet to form an antibacterial effect, and then the magnesium oxide and the polyethanol are ground to improve the compatibility with polyester, so that the dispersing effect of spinning is better than that of spinning when the magnesium oxide is directly added, and the spinnability of spinning is facilitated.
The adsorption effect of the magnesium oxide particles on microorganisms can also cause cell membrane damage so as to achieve the antibacterial effect; meanwhile, the nanometer magnesia particles can generate superoxide anion free radicals due to contact with water, and the superoxide anion free radicals have strong oxidizing property, so that the peptide bond structure of the cell membrane wall of bacteria can be destroyed, the bacteria can be killed quickly, and the antiviral and antibacterial functions are obtained. Viruses are present in cells where they replicate and multiply, and when cells are destroyed, they lose their viable mother and are therefore not present. Therefore, has good antiviral and bactericidal functions.
The jade micropowder after laser sintering has the functions of promoting skin metabolism, eliminating skin toxin, resisting radiation, repairing skin damaged cells and enhancing cell activity when acting on skin.
Graphene oxide itself also has a good antibacterial effect.
Compared with the prior art, the utility model has the following positive effects:
the lyocell fiber is derived from plant cellulose, has various excellent performances of natural fiber and synthetic fiber, is green fiber, is prepared from inexhaustible cellulose in nature, has no chemical reaction in the production process, uses nontoxic solvent, and accords with the concept of health and environmental protection.
This application introduces zinc oxide whisker and jade powder structure in healthy material, utilizes to have similar mineral substance structure to promote its anion and functions such as far infrared transmission.
Detailed Description
The following provides specific embodiments of a healthy web of the present invention.
Example 1
A healthy mesh fabric comprises a surface layer, a connecting layer and a base layer, wherein the surface layer and the base layer are connected through the connecting layer.
The thickness ratio of the surface layer, the connecting layer and the base layer is 4:1: 4.
The surface layer is made of healthy polyester fiber and lyocell fiber;
the number ratio of the healthy polyester fiber to the lyocell fiber is 19: 1.
The connecting layer is made of nylon fibers.
The bottom layer is made of healthy polyester fiber.
The preparation method of the healthy polyester fiber comprises the following steps: dispersing two-dimensional porous NCO nanosheets in a sodium hydroxide solution, then adding a magnesium chloride solution for microwave ultrasonic mixing, and then reacting for 30-50 minutes at a reaction temperature of 33-38 ℃ to obtain a two-dimensional porous NCO nanosheet adsorbed magnesium hydroxide precipitate; then continuously adding an aluminum chloride solution, continuously generating a precipitate, and filtering and drying to obtain an aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheet; carrying out dry grinding on aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheets, jade powder, zinc oxide whiskers and graphene oxide, and putting the ground mixture into a laser sintering chamber for rapid sintering to obtain a healthy material; then, carrying out melt granulation on the healthy material, the polyvinyl alcohol, the PBT particles and the regenerated PET slices to obtain healthy master batches; and then carrying out melt spinning on the healthy master batch and the PET slices to obtain the healthy polyester fiber.
A two-dimensional porous NCO nanosheet and a two-dimensional porous nickel cobaltate sheet are prepared by growing an NCO precursor on a graphene oxide nanosheet in situ and calcining at a proper temperature (400-600 ℃), and the two-dimensional porous NCO nanosheet with good crystallinity and uniform morphology can be obtained, and specifically, the two-dimensional porous NCO nanosheet can also be referred to as a Holey two-dimensional transformation metal oxide nano sheets for expression energy storage Nat, 2017,8, 15139.
The laser sintering process comprises the following steps: under the anaerobic condition, the temperature is increased to 240 ℃ at the heating rate of 35 ℃/min, the temperature is kept for 2 hours, then the temperature is increased to 450 ℃ at the heating rate of 15 ℃/min under the anaerobic atmosphere, and the temperature is kept for 4 hours; according to the preparation method, aluminum hydroxide and magnesium hydroxide are generated into corresponding aluminum oxide and magnesium oxide in a laser rapid sintering mode, and the aluminum oxide and the magnesium hydroxide are adsorbed in gaps of the two-dimensional porous NCO nanosheets, so that the dispersibility of the aluminum oxide and the magnesium oxide in the two-dimensional porous NCO nanosheets is improved, and the antibacterial effect and the sustained-release effect of the aluminum oxide and the magnesium oxide are improved; for zinc oxide whisker and jade powder structures, the functions of negative ions, far infrared emission and the like are improved by utilizing similar mineral structure.
The mass ratio of the two-dimensional porous NCO nanosheet to the magnesium chloride is 4: 1.
The mass ratio of the two-dimensional porous NCO nanosheet to the aluminum chloride is 4: 1.
The mass fraction of the aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheet in the healthy material is 20%.
The mass fraction of the graphene oxide in the healthy material is 20%.
The mass fraction of the zinc oxide whiskers in the healthy material is 20%.
The mass fraction of the healthy material in the healthy master batch is 10 percent.
The mass fraction of the polyethanol in the healthy master batch is 1 percent.
The mass fraction of the PBT particles in the healthy master batch is 30 percent.
The mass fraction of the healthy master batch in the healthy polyester fiber is 10 percent.
The healthy polyester fiber has the antibacterial performance that the antibacterial rate of escherichia coli is 98%, the antibacterial rate of staphylococcus aureus is 98%, and the antibacterial rate of streptococcus albus is 98%.
Example 2
A healthy mesh fabric comprises a surface layer, a connecting layer and a base layer, wherein the surface layer and the base layer are connected through the connecting layer.
The thickness ratio of the surface layer, the connecting layer and the base layer is 6:1: 6.
The surface layer is made of healthy polyester fiber and lyocell fiber;
the number ratio of the healthy polyester fiber to the lyocell fiber is 29: 1.
The connecting layer is made of nylon fibers.
The bottom layer is made of healthy polyester fiber.
The preparation method of the healthy polyester fiber comprises the following steps: dispersing two-dimensional porous NCO nanosheets in a sodium hydroxide solution, then adding a magnesium chloride solution for microwave ultrasonic mixing, and then reacting for 30-50 minutes at a reaction temperature of 33-38 ℃ to obtain a two-dimensional porous NCO nanosheet adsorbed magnesium hydroxide precipitate; then continuously adding an aluminum chloride solution, continuously generating a precipitate, and filtering and drying to obtain an aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheet; carrying out dry grinding on aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheets, jade powder, zinc oxide whiskers and graphene oxide, and after grinding, putting the mixture into a laser sintering chamber for rapid sintering to obtain a healthy material; then, carrying out melt granulation on the healthy material, the polyvinyl alcohol, the PBT particles and the regenerated PET slices to obtain healthy master batches; and then carrying out melt spinning on the healthy master batch and the PET slices to obtain the healthy polyester fiber.
The mass ratio of the two-dimensional porous NCO nanosheet to the magnesium chloride is 6: 1.
The mass ratio of the two-dimensional porous NCO nanosheet to the aluminum chloride is 6: 1.
The mass fraction of the aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheet in the healthy material is 30%.
The mass fraction of the graphene oxide in the healthy material is 30%.
The mass fraction of the zinc oxide whiskers in the healthy material is 30%.
The mass fraction of the healthy material in the healthy master batch is 20%.
The mass fraction of the polyethanol in the healthy master batch is 3 percent.
The mass fraction of the PBT particles in the healthy master batch is 50 percent.
The mass fraction of the healthy master batch in the healthy polyester fiber is 20 percent.
The healthy polyester fiber has the antibacterial performance that the antibacterial rate of escherichia coli is 98.5%, the antibacterial rate of staphylococcus aureus is 98.5%, and the antibacterial rate of streptococcus albus is 98.5%.
Example 3
A healthy mesh fabric comprises a surface layer, a connecting layer and a base layer, wherein the surface layer and the base layer are connected through the connecting layer.
The thickness ratio of the surface layer, the connecting layer and the base layer is 5:1: 5.
The surface layer is made of healthy polyester fiber and lyocell fiber;
the number ratio of the healthy polyester fiber to the lyocell fiber is 24: 1.
The connecting layer is made of nylon fibers.
The bottom layer is made of healthy polyester fiber.
The preparation method of the healthy polyester fiber comprises the following steps: dispersing two-dimensional porous NCO nanosheets in a sodium hydroxide solution, then adding a magnesium chloride solution for microwave ultrasonic mixing, and then reacting for 30-50 minutes at a reaction temperature of 33-38 ℃ to obtain a two-dimensional porous NCO nanosheet adsorbed magnesium hydroxide precipitate; then continuously adding an aluminum chloride solution, continuously generating a precipitate, and filtering and drying to obtain an aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheet; carrying out dry grinding on aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheets, jade powder, zinc oxide whiskers and graphene oxide, and putting the ground mixture into a laser sintering chamber for rapid sintering to obtain a healthy material; then, carrying out melt granulation on the healthy material, the polyvinyl alcohol, the PBT particles and the regenerated PET slices to obtain healthy master batches; and then carrying out melt spinning on the healthy master batch and the PET chips to obtain the healthy polyester fiber.
The mass ratio of the two-dimensional porous NCO nanosheet to the magnesium chloride is 5: 1.
The mass ratio of the two-dimensional porous NCO nanosheet to the aluminum chloride is 5: 1.
The mass fraction of the aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheet in the healthy material is 25%.
The mass fraction of the graphene oxide in the healthy material is 25%.
The mass fraction of the zinc oxide whiskers in the healthy material is 25%.
The mass fraction of the healthy material in the healthy master batch is 15%.
The mass fraction of the polyethanol in the healthy master batch is 2 percent.
The mass fraction of the PBT particles in the healthy master batch is 40 percent.
The mass fraction of the healthy master batch in the healthy polyester fiber is 15%.
The healthy polyester fiber has the antibacterial performance that the antibacterial rate of escherichia coli is 97.5%, the antibacterial rate of staphylococcus aureus is 97.5%, and the antibacterial rate of streptococcus albus is 97.5%.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications and decorations can be made without departing from the concept of the present invention, and these modifications and decorations should also be regarded as being within the protection scope of the present invention.
Claims (6)
1. A healthy mesh is characterized by comprising a surface layer, a connecting layer and a base layer, wherein the surface layer is connected with the base layer through the connecting layer;
the surface layer is made of healthy polyester fiber and lyocell fiber;
the preparation method of the healthy polyester fiber comprises the following steps: dispersing two-dimensional porous NCO nanosheets in a sodium hydroxide solution, then adding a magnesium chloride solution for microwave ultrasonic mixing, and then reacting for 30-50 minutes at a reaction temperature of 33-38 ℃ to obtain a two-dimensional porous NCO nanosheet-adsorbed magnesium hydroxide precipitate; then continuously adding an aluminum chloride solution, continuously generating a precipitate, and filtering and drying to obtain an aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheet; carrying out dry grinding on aluminum hydroxide-magnesium hydroxide-two-dimensional porous NCO nanosheets, jade powder, zinc oxide whiskers and graphene oxide, and after grinding, putting the mixture into a laser sintering chamber for rapid sintering to obtain a healthy material; then, carrying out melt granulation on the healthy material, the polyvinyl alcohol, the PBT particles and the regenerated PET slices to obtain healthy master batches; and then carrying out melt spinning on the healthy master batch and the PET slices to obtain the healthy polyester fiber.
2. The healthy web according to claim 1, wherein the thickness ratio of the surface layer, the connecting layer and the base layer is 4:1:4 to 6:1: 6.
3. The healthy web of claim 1, wherein the surface layer, the interconnecting layer, and the base layer have a thickness ratio of 5:1: 5.
4. The healthy mesh fabric according to claim 1, wherein the number ratio of the healthy polyester fibers to the lyocell fibers is 19:1 to 29: 1.
5. The healthy web of claim 1, wherein the material of the connecting layer is nylon fibers,
6. the healthy web of claim 1, wherein the material of the bottom layer is healthy polyester fibers.
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