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CN112612073B - A color filter capable of realizing ultra-wide color gamut and its structural parameter determination method - Google Patents

A color filter capable of realizing ultra-wide color gamut and its structural parameter determination method Download PDF

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CN112612073B
CN112612073B CN202011526417.3A CN202011526417A CN112612073B CN 112612073 B CN112612073 B CN 112612073B CN 202011526417 A CN202011526417 A CN 202011526417A CN 112612073 B CN112612073 B CN 112612073B
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silver film
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CN112612073A (en
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顾健
张钰
逯鑫淼
张辉朝
黄博
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Hangzhou Dianzi University
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Abstract

The invention discloses a color filter capable of realizing an ultra-wide color gamut and a method for determining structural parameters of the color filter. The range of colors and saturation that can be created by transmission or reflection of existing plasmonic filters is very limited. The invention includes a substrate layer and a silver film. The substrate layer is made of SiO 2 . A silver film overlies the base layer. A plurality of hollow microstructures are etched on the silver film. The hollow microstructure comprises a cross-shaped groove and four rectangular grooves. The four rectangular grooves are respectively connected with the four ends of the cross-shaped groove. Compared with the existing surface plasma filter, the color obtained by the invention can exceed the color space of sRGB, and a wider color gamut is obtained. Compared with the existing color filter based on surface plasmon resonance, the color filter has wider color gamut and higher saturation, and can provide richer colors and more vivid image quality.

Description

一种能实现超宽色域的颜色滤光片及其结构参数确定方法A color filter capable of realizing ultra-wide color gamut and its structural parameter determination method

技术领域technical field

本发明属于颜色滤光片器件建模仿真技术领域,具体涉及一种新的基于表面等离子体共振的,能获得超宽色域的颜色滤光片。The invention belongs to the technical field of modeling and simulation of color filter devices, in particular to a new color filter based on surface plasmon resonance and capable of obtaining an ultra-wide color gamut.

背景技术Background technique

滤光片是一种常用的光学设备,通常用于传输或反射特定波长的光,以显示所需的颜色。滤光片广泛应用于显示器、成像传感器、防伪技术、色彩装饰、彩色打印等领域。传统的滤光片使用传统的染料着色来吸收特定波长的光以显示特定的颜色。这种传统的化学染色滤光片不能承受高温或紫外线辐射,滤光片的性能会随着时间的推移而显著下降。为了解决传统滤光片存在的问题,近年来出现了基于结构色彩的滤光片。结构色是自然光与微纳结构相互作用而产生的,通常发生在干涉、衍射、散射等光学现象中。与化学染色形成的颜色相比,结构色具有不褪色、颜色稳定、环保等优点。结构颜色的这些优势使得研究者致力于基于导模共振、表面等离子体共振、Mie共振或Fabry Perot共振的滤光片的研究。A filter is a commonly used optical device that is typically used to transmit or reflect specific wavelengths of light to display a desired color. Filters are widely used in displays, imaging sensors, anti-counterfeiting technology, color decoration, color printing and other fields. Traditional filters use traditional dye tinting to absorb specific wavelengths of light to display a specific color. Such conventional chemically dyed filters cannot withstand high temperatures or UV radiation, and filter performance can degrade significantly over time. In order to solve the problems of traditional filters, filters based on structural color have appeared in recent years. Structural color is produced by the interaction between natural light and micro-nano structures, and usually occurs in optical phenomena such as interference, diffraction, and scattering. Compared with the color formed by chemical dyeing, structural color has the advantages of non-fading, color stability, and environmental protection. These advantages of structural color have led researchers to work on filters based on guided mode resonance, surface plasmon resonance, Mie resonance, or Fabry Perot resonance.

在实际应用中,高饱和的结构色彩和宽色域在显示和成像中起着至关重要的作用。在显示或成像中,饱和度越高,显示的颜色越生动,色域越宽,显示的颜色越多。然而,光通过现有的等离子体滤光片透射或反射所形成的色彩范围和饱和度是非常有限的。有限的色彩范围和饱和度会导致光的颜色在通过滤光片后,所产生的颜色太少达不到理想中的效果。这一缺陷会使成像后的图像质量过低,从而限制了等离子体滤光片的进一步应用。In practical applications, highly saturated structural colors and wide color gamut play a crucial role in display and imaging. In display or imaging, the higher the saturation, the more vivid the displayed colors, and the wider the color gamut, the more colors displayed. However, the color range and saturation formed by the transmission or reflection of light through existing plasmonic filters is very limited. The limited color range and saturation can cause the color of the light to pass through the filter to produce too few colors to achieve the desired effect. This defect can make the image quality after imaging too low, which limits the further application of plasmonic filters.

发明内容SUMMARY OF THE INVENTION

本发明的目的在于提供一种能实现超宽色域的颜色滤光片,以利用入射的白光来获得超宽的色域。The purpose of the present invention is to provide a color filter capable of realizing an ultra-wide color gamut, so as to utilize the incident white light to obtain an ultra-wide color gamut.

本发明一种能实现超宽色域的颜色滤光片,包括基底层和银膜。基底层的材质为SiO2。银膜覆盖在基底层上。银膜上蚀刻有多个镂空微结构。镂空微结构包括一个十字形槽和四个矩形槽组成。四个矩形槽与十字形槽的四个端部分别连接。The present invention is a color filter capable of realizing ultra-wide color gamut, comprising a base layer and a silver film. The material of the base layer is SiO 2 . A silver film covers the base layer. A plurality of hollow microstructures are etched on the silver film. The hollow microstructure consists of a cross-shaped groove and four rectangular grooves. The four rectangular slots are respectively connected with the four ends of the cross-shaped slot.

作为优选,通过调节矩形槽的长度D的大小来调节滤光片的透光波段范围。Preferably, the light transmission wavelength range of the filter can be adjusted by adjusting the length D of the rectangular groove.

作为优选,各镂空微结构呈矩阵状排列;相邻两个镂空微结构的中心点间距P的取值范围为150~300nm。Preferably, the hollowed-out microstructures are arranged in a matrix; the value range of the distance P between the center points of two adjacent hollowed-out microstructures is 150-300 nm.

作为优选,所述银膜的厚度H的取值范围为40~100nm。Preferably, the thickness H of the silver film ranges from 40 to 100 nm.

作为优选,所述矩形槽的长度D的取值范围为20~80nm;Preferably, the value range of the length D of the rectangular groove is 20-80 nm;

作为优选,镂空微结构关于十字形槽的中心点中心对称。Preferably, the hollow microstructure is centrosymmetric about the central point of the cross-shaped groove.

作为优选,所述矩形槽与十字形槽上对应端部的连接处为矩形槽的中间位置。Preferably, the connection between the rectangular groove and the corresponding end of the cross-shaped groove is the middle position of the rectangular groove.

作为优选,所述的矩形槽与十字形槽上的对应端部相互垂直。Preferably, the corresponding ends of the rectangular groove and the cross-shaped groove are perpendicular to each other.

作为优选,所述的十字形槽由相互垂直等分的的两条长条形槽组成。Preferably, the cross-shaped groove is composed of two elongated grooves that are equally divided perpendicularly to each other.

该能实现超宽色域的颜色滤光片及其结构参数确定方法,具体步骤如下:The color filter capable of realizing ultra-wide color gamut and the method for determining its structure parameters, the specific steps are as follows:

步骤一、确定透过滤光片的设计要求。设计要求包括目标可见光波段范围和最大透光率。Step 1: Determine the design requirements of the transparent filter. Design requirements include the target visible wavelength range and maximum light transmittance.

步骤二、根据目标可见光波段范围确定银膜厚度H和相邻镂空微结构中心距P的数值以及矩形槽长度D;Step 2: Determine the thickness H of the silver film, the value of the center distance P of the adjacent hollow microstructures, and the length D of the rectangular groove according to the target visible light band range;

目标可见光波段范围与绿色波段范围、蓝色波段范围、红色波段范围,分别进行比对如下:The target visible light band range and the green band range, blue band range, and red band range are compared as follows:

①.若目标可见光波段范围与绿色波段范围的重合程度最高,且最大透光率大于或等于 50%,则在40nm~80nm的范围内选定银膜厚度H;在150nm~210nm的范围内选定相邻镂空微结构中心距P。设定矩形槽长度D的取值范围为20nm~80nm。①. If the target visible light band has the highest degree of overlap with the green band, and the maximum transmittance is greater than or equal to 50%, select the silver film thickness H within the range of 40nm to 80nm; select the thickness H within the range of 150nm to 210nm. The center distance P of adjacent hollow microstructures is determined. The value range of the rectangular groove length D is set to be 20 nm to 80 nm.

②.若目标可见光波段范围与绿色波段范围的重合程度最高,且最大透光率小于50%,则在90nm~100nm的范围内选定银膜厚度H;在210nm~300nm的范围内选定相邻镂空微结构中心距P。设定矩形槽长度D的取值范围为20nm~80nm。②. If the target visible light band has the highest degree of overlap with the green band, and the maximum transmittance is less than 50%, select the silver film thickness H in the range of 90nm to 100nm; select the phase in the range of 210nm to 300nm. The center distance P of the adjacent hollow microstructures. The value range of the rectangular groove length D is set to be 20 nm to 80 nm.

③.若目标可见光波段范围与蓝色波段范围的重合程度最高,则在40nm~80nm的范围内选定银膜厚度H;在150nm~210nm的范围内选定相邻镂空微结构中心距P。设定矩形槽长度D的取值范围为50nm~80nm。③. If the target visible light band has the highest degree of overlap with the blue band, select the thickness H of the silver film within the range of 40nm-80nm; select the center distance P of the adjacent hollow microstructures within the range of 150nm-210nm. The value range of the rectangular groove length D is set to be 50 nm to 80 nm.

④.若目标可见光波段范围与红色波段范围的重合程度最高,则在40nm~80nm的范围内选定银膜厚度H;在150nm~210nm的范围内选定相邻镂空微结构中心距P。设定矩形槽长度D的取值范围为20nm~40nm。④. If the target visible light band has the highest degree of overlap with the red band, select the thickness H of the silver film in the range of 40nm-80nm; select the center distance P of the adjacent hollow microstructures in the range of 150nm-210nm. The value range of the rectangular groove length D is set to be 20 nm to 40 nm.

步骤三、在步骤二确定的矩形槽长度D的取值范围中,取最大值作为矩形槽长度D,并逐渐增小;每次减小后均对当前参数的滤光片通过时域有限差分方法模拟透射谱,直到模拟出的结果满足步骤一中确定的设计要求。Step 3. In the value range of the rectangular slot length D determined in Step 2, take the maximum value as the rectangular slot length D, and gradually increase it; after each reduction, the filter of the current parameter is passed through the time domain finite difference. The method simulates the transmission spectrum until the simulated result meets the design requirements determined in step one.

本发明的有益效果:Beneficial effects of the present invention:

本发明在二氧化硅衬底上镀一层银膜,并在银膜上蚀刻十字形槽和四个矩形槽组成的镂空微结构。在正常入射光下,纳米孔作为光栅耦合器提供光子-等离子体动量匹配,使表面等离子体共振发生在金属/介质界面。在这种情况下,等离子体通过孔径,并在通过金属薄膜后衰变为辐射光子。通过改变阵列的尺寸、形状、厚度和周期,可以调整允许的等离子体元耦合频率,从而决定透射光的颜色。与现有的表面等离子体滤光器相比,该滤光器获得的颜色可以超过sRGB的颜色空间,获得更宽的色域。与现有的基于表面等离子体共振的彩色滤波器相比,该滤波器具有更宽的色域和更高的饱和度,能够提供更丰富的色彩和更生动的图像质量。In the present invention, a layer of silver film is plated on a silicon dioxide substrate, and a hollow microstructure composed of a cross-shaped groove and four rectangular grooves is etched on the silver film. Under normal incident light, the nanohole acts as a grating coupler to provide photon-plasmon momentum matching, enabling surface plasmon resonance to occur at the metal/dielectric interface. In this case, the plasma passes through the aperture and decays into radiation photons after passing through the metal thin film. By changing the size, shape, thickness, and period of the array, the allowable coupling frequency of the plasmonic elements can be tuned, and thus the color of the transmitted light. Compared with the existing surface plasmon filter, the color obtained by the filter can exceed the color space of sRGB and obtain a wider color gamut. Compared with existing surface plasmon resonance-based color filters, the filter has a wider color gamut and higher saturation, enabling richer colors and more vivid image quality.

附图说明Description of drawings

图1a为本发明的结构原理图。FIG. 1a is a schematic structural diagram of the present invention.

图1b为本发明中单个镂空微结构的示意图;Figure 1b is a schematic diagram of a single hollow microstructure in the present invention;

图2a为本发明不同参数下透射蓝、绿、红光的透射谱图;Fig. 2a is the transmission spectrum diagram of transmission blue, green, red light under different parameters of the present invention;

图2b为本发明不同参数下透射蓝、绿、红光时在CIE1931色度图上的坐标图;Figure 2b is a coordinate diagram on the CIE1931 chromaticity diagram when blue, green and red light are transmitted under different parameters of the present invention;

图2c为本发明在保持P、H不变情况下调整D大小时的透射谱图;Fig. 2c is the transmission spectrum diagram of the present invention when the size of D is adjusted under the condition of keeping P and H unchanged;

图2d为本发明在保持P、H不变情况下调整D大小时在CIE1931色度图上的坐标图;2d is a coordinate diagram on the CIE1931 chromaticity diagram when the size of D is adjusted while keeping P and H unchanged in the present invention;

图3a为本发明在保持P、D不变情况下调整H大小时的透射谱图;Fig. 3a is the transmission spectrogram of the present invention when the size of H is adjusted under the condition of keeping P and D unchanged;

图3b-3h为本发明在保持P不变情况下调整D、H大小时在CIE1931色度图上的坐标图;3b-3h are the coordinate diagrams on the CIE1931 chromaticity diagram when the size of D and H are adjusted while keeping P unchanged in the present invention;

图4a为本发明在保持H、D不变情况下调整P大小时的透射谱图;Fig. 4a is the transmission spectrum when the present invention adjusts the size of P under the condition of keeping H and D unchanged;

图4b-4q为本发明在保持H不变情况下调整D、P大小时在CIE1931色度图上的坐标图。4b-4q are coordinate diagrams on the CIE1931 chromaticity diagram when the size of D and P are adjusted while keeping H unchanged in the present invention.

具体实施方式Detailed ways

以下结合附图对本发明作进一步说明。The present invention will be further described below with reference to the accompanying drawings.

如图1a和1b所示,一种能实现超宽色域的颜色滤光片,包括基底层1和银膜2。基底层1的材质为SiO2。银膜2覆盖在基底层1上。银膜2的厚度为H。银膜2上蚀刻有多个镂空微结构3。各镂空微结构3呈矩阵状排列;相邻两个镂空微结构3的中心点间距(即结构周期)为P。镂空微结构3包括一个十字形槽3-1和四个矩形槽3-2组成。镂空微结构 3关于十字形槽3-1的中心点中心对称。十字形槽3-1由垂直交叉的两个长条形槽组成。四个矩形槽3-2的中间位置与十字形槽3-1的四个端部分别连接。矩形槽3-2与自身连接的长条形槽相互垂直。十字形槽3-1和矩形槽3-2的槽宽均为W。矩形槽3-2的长度为D;十字形槽3-1中单个长条形槽的长度(即相对的两个矩形槽3-2的间距)为L。As shown in Figures 1a and 1b, a color filter capable of realizing an ultra-wide color gamut includes a base layer 1 and a silver film 2. The material of the base layer 1 is SiO 2 . The silver film 2 covers the base layer 1 . The thickness of the silver film 2 is H. A plurality of hollow microstructures 3 are etched on the silver film 2 . The hollowed-out microstructures 3 are arranged in a matrix; the distance between the center points of two adjacent hollowed-out microstructures 3 (ie, the structural period) is P. The hollow microstructure 3 includes a cross-shaped groove 3-1 and four rectangular grooves 3-2. The hollow microstructure 3 is center-symmetric about the center point of the cross-shaped groove 3-1. The cross-shaped groove 3-1 is composed of two elongated grooves intersecting vertically. The middle positions of the four rectangular grooves 3-2 are respectively connected with the four ends of the cross-shaped grooves 3-1. The rectangular slot 3-2 is perpendicular to the elongated slot connected to itself. The groove widths of the cross-shaped groove 3-1 and the rectangular groove 3-2 are both W. The length of the rectangular groove 3-2 is D; the length of a single elongated groove in the cross-shaped groove 3-1 (ie the distance between two opposite rectangular grooves 3-2) is L.

W=20nm;L=80nm;H=40~100nm;P=150~300nm;D=20~80nm。W=20nm; L=80nm; H=40~100nm; P=150~300nm; D=20~80nm.

通过调节矩形槽3-2长度D的大小能够调节滤光片的各波段光的透射率,从而实现滤光片对不同波段光的滤除。By adjusting the size of the length D of the rectangular groove 3-2, the transmittance of the light in each wavelength band of the filter can be adjusted, thereby realizing the filtering of the light in different wavelength bands by the filter.

该能实现超宽色域的颜色滤光片及其结构参数确定方法,具体步骤如下:The color filter capable of realizing ultra-wide color gamut and the method for determining its structure parameters, the specific steps are as follows:

步骤一、确定透过滤光片的设计要求。设计要求包括目标可见光波段范围和该波段光线的最大透光率。总的波段范围为380nm~780nm,包括可见光红、绿、蓝波段的范围和最大透光率,其中红色波段范围为640nm~780nm,绿色波段范围为500nm~550nm,蓝色波段范围为420nm~500nm,在可见光波段范围内,滤光片的最大透光率所对应的波长应在目标可见光波段范围内,最大透光率应大于10%,该最大透光率应该为该波段内的峰值,且该峰值为该波段内的唯一峰值。Step 1: Determine the design requirements of the transparent filter. Design requirements include the target visible light band range and the maximum transmittance of light in that band. The total wavelength range is 380nm~780nm, including the range of visible light red, green and blue bands and the maximum transmittance, of which the red band range is 640nm~780nm, the green band range is 500nm~550nm, and the blue band range is 420nm~500nm , in the visible light band range, the wavelength corresponding to the maximum light transmittance of the filter should be within the target visible light band range, the maximum light transmittance should be greater than 10%, the maximum light transmittance should be the peak value in this band, and This peak is the only peak within the band.

步骤二、根据目标可见光波段范围确定H和P的数值;Step 2: Determine the values of H and P according to the target visible light band range;

图3a和图4a分别仅为改变H的数值透射率的变化和仅改变P的数值透射率的变化,图3a结构参数为P=200nm,D=80nm,H从40nm增大至100nm,步长为10nm,图4a结构参数为H=80nm,D=80nm,P从150nm增大至300nm,步长为10nm。Figures 3a and 4a only change the numerical transmittance of H and only change the numerical transmittance of P, respectively. The structural parameters of Figure 3a are P=200nm, D=80nm, H increases from 40nm to 100nm, step size is 10 nm, the structural parameters of Fig. 4a are H=80 nm, D=80 nm, P increases from 150 nm to 300 nm, and the step size is 10 nm.

从两幅图可以看出,当银膜2厚度H增大时,最大透射率在减小,且共振波长往短波方向移动,透射率都在40%以上;当周期P增大时,最大透射率在减小,且共振波长往长波方向移动。It can be seen from the two figures that when the thickness H of the silver film 2 increases, the maximum transmittance decreases, and the resonance wavelength moves to the short-wave direction, and the transmittance is above 40%; when the period P increases, the maximum transmittance decreases. The rate is decreasing, and the resonant wavelength shifts toward the longer wavelength.

如果想要获取绿色波段(500nm~550nm)的光,从两个图中可以直观看出图中的波段范围基本都位于绿色波段,对透射率要求50%以上,银膜2厚度H可以设置为40nm~80nm,周期P可以设置为150nm~210nm;对透射率要求50%以下则可以将银膜2厚度H设置为 90nm~100nm,周期P可以设置为210nm~300nm;If you want to obtain light in the green band (500nm ~ 550nm), it can be intuitively seen from the two figures that the band ranges in the figures are basically in the green band, and the transmittance is required to be more than 50%. The thickness H of the silver film 2 can be set to 40nm~80nm, the period P can be set to 150nm~210nm; if the transmittance is less than 50%, the thickness H of the silver film 2 can be set to 90nm~100nm, and the period P can be set to 210nm~300nm;

如果想要获取蓝色波段(420nm~500nm)的光,由图2c可以知道随着矩形槽3-2长度 D的变化,峰值波长会逐渐从绿色波段左移至蓝色波段,且中心透射率会减小,D的长度减小至50nm之后蓝色波段的峰值会消失,由此我们应使得在D长度最长时即80nm时,滤光片的透射率尽可能的大,银膜2厚度H可以设置为40nm~80nm,周期P可以设置为 150nm~210nm,在透射率高的同时,峰值波长更偏向蓝色波段,使其在绿光波段范围时透射率超过50%,峰值波长左移至蓝色波段时透射率尽可能大;If you want to obtain light in the blue band (420nm-500nm), it can be known from Figure 2c that with the change of the length D of the rectangular groove 3-2, the peak wavelength will gradually shift from the green band to the blue band, and the central transmittance will decrease, and the peak of the blue band will disappear after the length of D is reduced to 50nm, so we should make the transmittance of the filter as large as possible when the length of D is 80nm, the thickness of the silver film 2 H can be set to 40nm~80nm, period P can be set to 150nm~210nm, while the transmittance is high, the peak wavelength is more inclined to the blue band, so that when the transmittance exceeds 50% in the green band range, the peak wavelength shifts to the left The transmittance should be as large as possible when reaching the blue band;

如果想要获取红色波段(640nm~780nm)的光,由图2c可以知道当矩形槽3-2长度D减小至20nm~40nm时,峰值波长正好就位于红色波段,而想要获取高透射率银膜2厚度H 设置为40nm~80nm,周期P可以设置为150nm~210nm。If you want to obtain light in the red band (640nm-780nm), it can be known from Figure 2c that when the length D of the rectangular groove 3-2 is reduced to 20nm-40nm, the peak wavelength is just in the red band, and you want to obtain high transmittance The thickness H of the silver film 2 is set to be 40 nm to 80 nm, and the period P can be set to be 150 nm to 210 nm.

步骤三、将矩形槽3-2长度D由80nm逐渐增小;每次减小5nm;每次减小后均对当前参数的滤光片通过时域有限差分(FDTD)方法模拟透射谱,直到模拟出的结果满足步骤一中确定的设计要求。Step 3: The length D of the rectangular groove 3-2 is gradually increased from 80 nm; each time is decreased by 5 nm; after each decrease, the transmission spectrum of the filter with the current parameters is simulated by the finite difference time domain (FDTD) method, until The simulated results meet the design requirements determined in step 1.

以下通过时域有限差分(FDTD)方法模拟本发明的纳米结构的透射谱,来验证不同参数的本发明的滤光波段的差异。In the following, the transmission spectrum of the nanostructure of the present invention is simulated by the finite difference time domain (FDTD) method to verify the difference of the filtering wavelength bands of the present invention with different parameters.

彩色滤光片的光谱和色度图Spectral and Chromaticity Diagrams for Color Filters

通过改变银膜2厚度H、结构周期P和四个矩形槽3-2D的大小,可以得到红、绿、蓝的三色透射谱;如图2a所示。为了直观地看到滤波后的显色效果,将仿真得到的谱数据绘制在CIE1931色度图上,如图2b所示。从这两幅图可以看出,我们设计的结构可以实现红、绿、蓝三色滤波。By changing the thickness H of the silver film 2, the structural period P and the size of the four rectangular grooves 3-2D, three-color transmission spectra of red, green and blue can be obtained; as shown in Fig. 2a. In order to visually see the color rendering effect after filtering, the spectral data obtained by simulation are drawn on the CIE1931 chromaticity diagram, as shown in Figure 2b. As can be seen from these two figures, the structure we designed can realize red, green, and blue three-color filtering.

具体来说,在图2a中,蓝色谱线对应的结构参数为H=70nm,D=64nm,P=130nm;绿色谱线对应的结构参数为H=70nm、D=80nm、P=200nm;红色谱线对应的结构参数为H=70nm,D=20nm,P=200nm。图2b中显示了红、绿、蓝色谱线对应的色坐标在 CIE1931色度图中。Specifically, in Figure 2a, the structural parameters corresponding to the blue spectral line are H=70nm, D=64nm, P=130nm; the structural parameters corresponding to the green spectral line are H=70nm, D=80nm, P=200nm; red The structural parameters corresponding to the spectral lines are H=70nm, D=20nm, P=200nm. Figure 2b shows the color coordinates corresponding to the red, green and blue spectral lines in the CIE1931 chromaticity diagram.

当确定银膜2的厚度H和结构周期P(确定为P=200nm和H=80nm)时,仅减小矩形槽3-2长度D,峰值波长将蓝移且透射率将减小,第二个峰值波长将出现在红色波段中。如图2c所示,随着矩形槽3-2长度D的减小,第二峰值波长的透射率将向蓝色波段偏移。它表明,仅将矩形槽3-2长度D从80nm减小到20nm(步长为10nm),就可以获得相对较大的颜色范围。在CIE1931色度图上绘制了将矩形槽3-2长度D从80nm减小到20nm 之后获得的透射光谱相对应的颜色,如图2(d)所示。绘制CIE1931色度图后,可以看出,通过将矩形槽3-2长度D从80nm减小到20nm,图2(d)中的黑点分布在一个较宽的范围内,可以获得宽范围的色域。When the thickness H and the structural period P of the silver film 2 are determined (determined as P=200nm and H=80nm), only the length D of the rectangular groove 3-2 is reduced, the peak wavelength will be blue-shifted and the transmittance will be reduced, the second The peak wavelengths will appear in the red band. As shown in Fig. 2c, as the length D of the rectangular groove 3-2 decreases, the transmittance of the second peak wavelength will shift to the blue band. It shows that a relatively large range of colors can be obtained simply by reducing the length D of the rectangular grooves 3-2 from 80 nm to 20 nm in 10 nm steps. The corresponding colors of the transmission spectrum obtained after reducing the length D of the rectangular groove 3-2 from 80 nm to 20 nm were plotted on the CIE1931 chromaticity diagram, as shown in Fig. 2(d). After drawing the CIE1931 chromaticity diagram, it can be seen that by reducing the length D of the rectangular groove 3-2 from 80 nm to 20 nm, the black dots in Fig. 2(d) are distributed in a wide range, and a wide range of color gamut.

模拟银膜2厚度H和矩形槽3-2长度D对滤光片特性的影响The influence of the thickness H of the simulated silver film 2 and the length D of the rectangular groove 3-2 on the filter characteristics

首先,我们在改变矩形槽3-2长度D的基础上,研究了改变银膜2厚度对滤光片特性的影响。将周期固定在200nm,矩形槽3-2长度D固定在80nm。当银膜2厚度从40nm增加到100nm时(步长为10nm),可以得到图3a所示的透射谱。当银膜2厚度从40nm增加到100nm时,透射率降低,透射峰发生蓝移。半波全宽也在减小。由于将矩形槽3-2长度D从80nm减小到20nm可以得到很宽的色域范围,所以当银膜2厚度选择一个值时,将矩形槽3-2长度D从80nm减小到20nm。所以每改变银膜2的厚度,都将矩形槽3-2长度D从80nm减小到20nm,步长值为5nm。图中的红色三角形是标准的红、绿、蓝颜色空间(sRGB)。然后计算得到的透射谱,得到色度图上的坐标,并在CIE1931色度图上标记颜色变化,如图3b-h所示。图3b中表现了P=200nm,H=20nm,D从80nm减小到20nm时透射光波段的变化情况;图3c中表现了P=200nm,H=30nm,D从80nm减小到20nm时透射光波段的变化情况;图3d中表现了P=200nm,H=40nm,D从80nm减小到20nm时透射光波段的变化情况;图3e中表现了P=200nm,H=50nm,D从80nm减小到20nm时透射光波段的变化情况;图3f中表现了P=200nm,H=60nm,D从80nm减小到20nm时透射光波段的变化情况;图3g中表现了P=200nm,H=70nm,D从80nm减小到20nm时透射光波段的变化情况;图3h中表现了P=200nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况;First, on the basis of changing the length D of the rectangular groove 3-2, we studied the effect of changing the thickness of the silver film 2 on the filter characteristics. The period was fixed at 200 nm, and the length D of the rectangular groove 3-2 was fixed at 80 nm. When the thickness of the silver film 2 is increased from 40 nm to 100 nm (the step size is 10 nm), the transmission spectrum shown in Fig. 3a can be obtained. When the thickness of the silver film 2 increases from 40 nm to 100 nm, the transmittance decreases and the transmission peak is blue-shifted. The full width at half-wave is also decreasing. Since a wide color gamut can be obtained by reducing the length D of the rectangular groove 3-2 from 80 nm to 20 nm, when a value is selected for the thickness of the silver film 2, the length D of the rectangular groove 3-2 is reduced from 80 nm to 20 nm. Therefore, each time the thickness of the silver film 2 is changed, the length D of the rectangular groove 3-2 is reduced from 80 nm to 20 nm, and the step size is 5 nm. The red triangle in the figure is the standard red, green, and blue color space (sRGB). The resulting transmission spectrum was then calculated to obtain the coordinates on the chromaticity diagram, and the color changes were marked on the CIE1931 chromaticity diagram, as shown in Fig. 3b–h. Figure 3b shows the change of the transmitted light band when P=200nm, H=20nm, and D decreases from 80nm to 20nm; Figure 3c shows the transmission when P=200nm, H=30nm, and D decreases from 80nm to 20nm The change of the optical band; Figure 3d shows the change of the transmitted light band when P=200nm, H=40nm, D decreases from 80nm to 20nm; Figure 3e shows P=200nm, H=50nm, D from 80nm The change of the transmitted light band when it is reduced to 20nm; Fig. 3f shows the change of the transmitted light band when P=200nm, H=60nm, and D decreases from 80nm to 20nm; Fig. 3g shows the change of the transmitted light band when P=200nm, H =70nm, the change of the transmitted light band when D decreases from 80nm to 20nm; Figure 3h shows the change of the transmitted light band when P=200nm, H=80nm, and D decreases from 80nm to 20nm;

当银膜2厚度为60nm时,滤光片产生的红光比银膜2厚度为70nm或80nm时产生的红光更靠近色度图的中心,导致饱和度较低,如图3d-(f)所示。当银膜2厚度为90nm或 100nm时,滤光片产生的色域会向左上方偏移,滤光片生成的蓝色光和红色光比银膜2厚度是70nm和80nm时生成的蓝色光和红色光更接近色度图的中心,同样导致较低的饱和度,如图3(e)-(h)所示。当银膜2厚度为70nm或80nm时,滤色器产生的颜色范围可以更好地匹配sRGB颜色空间的范围,从而获得更宽的色域。低饱和度会导致更少的颜色和更窄的色域。比较上述七幅图,可以得出结论,当银膜2的厚度是70或80nm,可以获得更好的色域范围,除了矩形槽3-2长度D,银膜2的厚度也是影响色域的一个因素。When the thickness of silver film 2 is 60nm, the red light generated by the filter is closer to the center of the chromaticity diagram than the red light generated when the thickness of silver film 2 is 70nm or 80nm, resulting in lower saturation, as shown in Figure 3d-(f ) shown. When the thickness of the silver film 2 is 90nm or 100nm, the color gamut generated by the filter will shift to the upper left, and the blue light and red light generated by the filter are higher than the blue and red light generated when the thickness of the silver film 2 is 70nm and 80nm. Red light is closer to the center of the chromaticity diagram, again resulting in lower saturation, as shown in Fig. 3(e)-(h). When the thickness of the silver film 2 is 70nm or 80nm, the color range produced by the color filter can better match the range of the sRGB color space, thereby obtaining a wider color gamut. Low saturation results in fewer colors and a narrower gamut. Comparing the above seven figures, it can be concluded that when the thickness of the silver film 2 is 70 or 80 nm, a better color gamut range can be obtained. Except for the length D of the rectangular groove 3-2, the thickness of the silver film 2 also affects the color gamut. a factor.

模拟结构周期P和矩形槽3-2长度D对滤光片特性的影响Simulation of the influence of the structural period P and the length D of the rectangular groove 3-2 on the filter characteristics

在此部分中,在改变矩形槽3-2长度D的基础上,探讨了滤光片周期对显色效果的影响。图4(a)显示了当厚度不变时,滤光片周期从150nm增加到300nm时的透射光谱。银膜2的厚度为80nm,矩形槽3-2长度D为80nm。从图中可以清楚地看出,周期越小,透射率越大,半波全宽越大。随着周期的增加,峰值波长将出现红移。每当周期的大小改变时,都将矩形槽3-2长度D从80nm减小到20nm,步长为5nm。然后计算获得的透射光谱,在CIE1931色度图上绘制坐标,如图4b-q所示。图4b中表现了P=150nm,H=80nm,D 从80nm减小到20nm时透射光波段的变化情况;图4c中表现了P=160nm,H=80nm,D从 80nm减小到20nm时透射光波段的变化情况;4d中表现了P=170nm,H=80nm,D从80nm 减小到20nm时透射光波段的变化情况;图4e中表现了P=180nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况;图4f中表现了P=190nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况;图4g中表现了P=200nm,H=80nm,D从80nm减小到 20nm时透射光波段的变化情况;图4h中表现了P=210nm,H=80nm,D从80nm减小到20nm 时透射光波段的变化情况;图4i中表现了P=220nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况;图4j中表现了P=230nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况;图4k中表现了P=240nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况;图4l中表现了P=250nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况;图4m中表现了P=260nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况;图4n中表现了P=270nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况;图4o中表现了P=280nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况;图4p中表现了P=290nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况;图4q中表现了P=300nm,H=80nm,D从80nm减小到20nm时透射光波段的变化情况。In this part, on the basis of changing the length D of the rectangular groove 3-2, the influence of the filter period on the color rendering effect is discussed. Figure 4(a) shows the transmission spectrum when the filter period is increased from 150 nm to 300 nm when the thickness is constant. The thickness of the silver film 2 is 80 nm, and the length D of the rectangular groove 3-2 is 80 nm. It can be clearly seen from the figure that the smaller the period, the larger the transmittance and the larger the full width at half-wave. As the period increases, there will be a red shift in the peak wavelength. The length D of the rectangular grooves 3-2 was reduced from 80 nm to 20 nm in steps of 5 nm each time the size of the period was changed. The obtained transmission spectra were then calculated and the coordinates were plotted on the CIE1931 chromaticity diagram, as shown in Fig. 4b–q. Figure 4b shows the change of the transmitted light band when P=150nm, H=80nm, and D decreases from 80nm to 20nm; Figure 4c shows the transmission when P=160nm, H=80nm, and D decreases from 80nm to 20nm The change of the optical band; 4d shows the change of the transmitted light band when P=170nm, H=80nm, D decreases from 80nm to 20nm; Figure 4e shows the P=180nm, H=80nm, D decreases from 80nm The change of the transmitted light band when it is as small as 20 nm; Figure 4f shows the change of the transmitted light band when P=190nm, H=80nm, and D decreases from 80nm to 20nm; Figure 4g shows P=200nm, H= 80nm, the change of the transmitted light band when D decreases from 80nm to 20nm; Fig. 4h shows the change of the transmitted light band when P=210nm, H=80nm, and D decreases from 80nm to 20nm; Fig. 4i shows the change of the transmitted light band The change of the transmitted light band when P=220nm, H=80nm, D decreases from 80nm to 20nm; Figure 4j shows the change of the transmitted light band when P=230nm, H=80nm, D decreases from 80nm to 20nm ; Figure 4k shows the change of the transmitted light band when P=240nm, H=80nm, and D decreases from 80nm to 20nm; Figure 4l shows when P=250nm, H=80nm, and D decreases from 80nm to 20nm Changes in the transmitted light band; Figure 4m shows the change in the transmitted light band when P=260nm, H=80nm, and D decreases from 80nm to 20nm; Figure 4n shows P=270nm, H=80nm, D from The change of the transmitted light band when 80nm is reduced to 20nm; Fig. 4o shows the change of the transmitted light band when P=280nm, H=80nm, and D is reduced from 80nm to 20nm; The change of the transmitted light band when H=80nm, D decreases from 80nm to 20nm; Figure 4q shows the change of the transmitted light band when P=300nm, H=80nm, and D decreases from 80nm to 20nm.

从图4b-4q这十六张图中可以看出,彩色滤光片获得的蓝光和红光的饱和度不会随着周期的增加而发生很大变化,而绿光的变化则更为明显。当周期大小在150nm-240nm或280nm-300nm这两个范围内时,可以清楚地看到滤光片获得的绿光在sRGB的色彩空间内,并且低于当周期在250nm至270nm范围内时滤波器产生的绿光的饱和度,如图4(b)-(k) 和图4(o)-(q)。当周期大小在250nm-270nm范围内时,可以获得高饱和度的绿光,并且总体颜色可以超过sRGB色彩空间的范围,从而导致更宽的色域,如图4(l)-(n)所示。比较上面的十七幅图,可以得出结论,当滤光器的周期在250nm-270nm范围内时,获得的色彩范围超过sRGB色彩空间,可以获得更宽的色域和更高的饱和度。除了矩形槽3-2 长度D和银膜2的厚度,周期的大小是影响色域的另一个主要因素。As can be seen from the sixteen figures in Figures 4b-4q, the saturation of blue and red light obtained by the color filter does not change much with the increase of the period, while the change of green light is more pronounced. When the period size is in the range of 150nm-240nm or 280nm-300nm, it can be clearly seen that the green light obtained by the filter is in the color space of sRGB and is lower than when the period is in the range of 250nm to 270nm. The saturation of the green light generated by the detector is shown in Fig. 4(b)-(k) and Fig. 4(o)-(q). When the period size is in the range of 250nm-270nm, highly saturated green light can be obtained, and the overall color can exceed the range of the sRGB color space, resulting in a wider color gamut, as shown in Fig. 4(l)-(n) Show. Comparing the seventeen figures above, it can be concluded that when the period of the filter is in the range of 250nm-270nm, the obtained color range exceeds the sRGB color space, and a wider color gamut and higher saturation can be obtained. Besides the length D of the rectangular groove 3-2 and the thickness of the silver film 2, the size of the period is another major factor affecting the color gamut.

Claims (10)

1. A color filter capable of realizing ultra-wide color gamut comprises a substrate layer (1) and a silver film (2); the method is characterized in that: the silver film (2) is covered on the substrate layer (1); a plurality of hollow microstructures (3) are etched on the silver film (2); the hollow microstructure (3) comprises a cross-shaped groove (3-1) and four rectangular grooves (3-2); the four rectangular grooves (3-2) are respectively connected with the four ends of the cross-shaped groove (3-1).
2. A color filter enabling an ultra-wide color gamut as recited in claim 1, wherein: the light transmission waveband range of the filter is adjusted by adjusting the length D of the rectangular groove (3-2).
3. A color filter enabling an ultra-wide color gamut according to claim 1, wherein: each hollow-out microstructure (3) is arranged in a matrix shape; the value range of the central point distance P between two adjacent hollow microstructures (3) is 150-300 nm.
4. A color filter enabling an ultra-wide color gamut as recited in claim 1, wherein: the thickness H of the silver film (2) ranges from 40nm to 100 nm.
5. A color filter enabling an ultra-wide color gamut as recited in claim 1, wherein: the length D of the rectangular groove (3-2) ranges from 20nm to 80 nm.
6. A color filter enabling an ultra-wide color gamut as recited in claim 1, wherein: the hollow-out microstructures (3) are centrosymmetric about the central point of the cross-shaped groove (3-1).
7. A color filter enabling an ultra-wide color gamut according to claim 1, wherein: the connecting part of the corresponding end parts of the rectangular groove (3-2) and the cross-shaped groove (3-1) is the middle position of the rectangular groove (3-2).
8. A color filter enabling an ultra-wide color gamut as recited in claim 1, wherein: the rectangular groove (3-2) is perpendicular to the corresponding end part of the cross-shaped groove (3-1).
9. A color filter enabling an ultra-wide color gamut as recited in claim 1, wherein: the cross-shaped groove (3-1) is composed of two strip-shaped grooves which are vertically and equally divided.
10. A method of determining configuration parameters of a color filter enabling an ultra-wide color gamut as claimed in claim 3, characterized in that: step one, determining the design requirement of a transmission filter; the design requirements include a target visible band range and maximum transmittance;
secondly, determining the thickness H of the silver film, the numerical value of the center distance P of adjacent hollow microstructures and the length D of the rectangular groove according to the target visible light wave band range;
the target visible light wave band range is compared with the green wave band range, the blue wave band range and the red wave band range respectively as follows:
if the superposition degree of the target visible light wave band range and the green wave band range is the highest, and the maximum light transmittance is greater than or equal to 50%, selecting the thickness H of the silver film (2) in the range of 40 nm-80 nm; selecting the center distance P of the adjacent hollow microstructures (3) in the range of 150 nm-210 nm; setting the value range of the length D of the rectangular groove to be 20-80 nm;
if the coincidence degree of the target visible light wave band range and the green wave band range is highest and the maximum light transmittance is less than 50%, selecting the thickness H of the silver film (2) in the range of 90-100 nm; selecting the center distance P of the adjacent hollow microstructures (3) in the range of 210 nm-300 nm; setting the value range of the length D of the rectangular groove to be 20-80 nm;
selecting the thickness H of the silver film (2) in the range of 40 nm-80 nm if the overlapping degree of the target visible light wave band range and the blue wave band range is the highest; selecting the center distance P of the adjacent hollow microstructures (3) in the range of 150 nm-210 nm; setting the value range of the length D of the rectangular groove to be 50-80 nm;
selecting the thickness H of the silver film (2) in the range of 40nm to 80nm if the coincidence degree of the target visible light wave band range and the red wave band range is the highest; selecting the center distance P of the adjacent hollow microstructures (3) in the range of 150 nm-210 nm; setting the value range of the length D of the rectangular groove to be 20-40 nm;
step three, in the value range of the rectangular groove length D determined in the step two, taking the maximum value as the rectangular groove length D, and gradually increasing the maximum value; and (3) simulating a transmission spectrum for the optical filter with the current parameters by a finite difference time domain method after each reduction until the simulated result meets the design requirement determined in the step one.
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