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CN112586501B - Weeding composition containing cyhalofop-butyl and imazamox - Google Patents

Weeding composition containing cyhalofop-butyl and imazamox Download PDF

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CN112586501B
CN112586501B CN202011481633.0A CN202011481633A CN112586501B CN 112586501 B CN112586501 B CN 112586501B CN 202011481633 A CN202011481633 A CN 202011481633A CN 112586501 B CN112586501 B CN 112586501B
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butyl
imazamox
cyhalofop
weeds
herbicidal composition
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CN112586501A (en
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郭晓刚
廖意凤
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Anhui Xitian Biotechnology Co ltd
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Anhui Xitian Biotechnology Co ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04Aryloxy-acetic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/501,3-Diazoles; Hydrogenated 1,3-diazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides a weeding composition containing cyhalofop-butyl and imazamox, wherein the active ingredients comprise cyhalofop-butyl and imazamox, and the mass ratio of the cyhalofop-butyl to the imazamox is 1-30: 1-20. The weeding composition can be used for preventing and removing annual weeds in crop fields and has obvious synergistic effect.

Description

Weeding composition containing cyhalofop-butyl and imazamox
Technical Field
The invention belongs to the field of herbicides, and particularly relates to a weeding composition containing cyhalofop-butyl and imazamox and application thereof.
Background
Cyhalofop-butyl is aryloxy phenoxy propionic acid conduction type gramineae weed herbicide, is used for controlling weeds such as moleplant seed, barnyard grass and paspalum distichum in field stem and leaf treatment, is absorbed by stem and leaf and is conducted to a growing point, and the weed control effect is achieved.
The imazamox is an imidazolinone herbicide, and can well prevent and control a plurality of annual weeds in a field in a lasting way; after foliar treatment, sensitive weeds quickly yellow and growth stops, eventually leading to death or no longer being competitive. Can well prevent and kill off and control various gramineous and broadleaf weeds with lasting effect, such as: green bristlegrass, wild oat, barnyard grass, crab grass, wild millet, cyperus heterophyllus, cyperus rotundus, amaranth, polygonum, black nightshade, chenopodium album, purslane, cocklebur, shepherd's purse, piemarker, buckwheat tendril, dayflower and the like.
The chemical agent is easy to cause the drug resistance of weeds after being singly used for a long time, causes pollution to the environment, and the research and development of the synergistic composition which can improve the weeding effect and reduce the application dosage of active ingredients is the key point of the research and development of a plurality of pesticide companies in China. In the prior art, no report is provided about the compound use of cyhalofop-butyl and imazamox.
Disclosure of Invention
The weeding composition containing cyhalofop-butyl and imazamox and the application thereof have a remarkable synergistic effect. The specific technical scheme is as follows:
the active ingredients of the weeding composition comprise cyhalofop-butyl and imazamox, and the mass ratio of the cyhalofop-butyl to the imazamox is 1-30: 1-20. Preferably, the mass ratio of the cyhalofop-butyl to the imazamox is 5-30: 3-12. More preferably, the mass ratio of the cyhalofop-butyl to the imazamox is 15-30: 3-12.
The weeding composition comprises 1-75% of active ingredients in percentage by mass. Preferably, the mass percentage of the active ingredients is 20-60%.
The weeding composition is mixed with common auxiliary materials on pesticides to prepare any preparation suitable for agriculture. Preferably, the preparation is missible oil, water dispersible granules, wettable powder and granules.
The weeding composition is used for preventing and removing weeds in crop fields. Preferably, the crop is rice or soybean. Preferably the weeds are annual weeds.
Compared with the prior art, the invention has the following beneficial effects:
1. the combination of cyhalofop-butyl and imazamox has different combined effects. When the proportion of the cyhalofop-butyl to the imazamox is 0.5+0.8 and 0.5+1.2, the composition shows additive combined effect on the barnyard grass; the rest of the mixture ratio shows the technical effect of synergy. 2. The total control effect of the herbicide on the weeds in the paddy field is about 90 percent. Can effectively reduce the application dosage of active ingredients, slow down the generation of drug resistance of weeds and have obvious synergistic effect.
Detailed Description
The invention will be better understood from the following examples. However, those skilled in the art will readily appreciate that the description of the embodiments is illustrative only and should not be taken as limiting the invention as described in detail in the claims
Example 142% Cyhalofop-Citrobacter Water dispersible granule
30% of cyhalofop-butyl, 12% of imazamox, 7% of calcium lignosulfonate, 6% of NNO, 3% of urea, 4% of carboxymethyl cellulose and the balance of kaolin to 100%. The cyhalofop-butyl-imazamox water dispersible granule with the mass percentage of 42 percent is prepared according to a conventional method.
Example 227% Cyhalofop-Citrobacter Water dispersible granule
Cyhalofop-butyl 15%, imazamox 12%, sodium dodecyl benzene sulfonate 5%, nekal 2%, calcium lignosulfonate 3%, ammonium sulfate 3%, polyethylene glycol 4% and kaolin for 100%. The cyhalofop-butyl-imazamox water dispersible granule with the mass percentage of 27 percent is prepared according to a conventional method.
Example 322% Cyhalofop-butyl Methoxyfenapyr wettable powder
15% of cyhalofop-butyl, 7% of imazamox, 7% of nekal, 8% of sodium dodecyl benzene sulfonate, 5% of white carbon black and 100% of bentonite. The cyhalofop-butyl imazamox wettable powder with the mass percentage of 46 percent is prepared according to a conventional method.
Example 424% Cyhalofop-butyl Methoxyfenapyr wettable powder
15% of cyhalofop-butyl, 9% of imazamox, 8% of NNO, 4% of nekal, 4% of calcium lignosulfonate, 5% of white carbon black and the balance of kaolin to 100%. The cyhalofop-butyl imazamox wettable powder with the mass percentage of 24 percent is prepared according to a conventional method.
Example 5: indoor determination of cyhalofop-butyl and imazamox compounded pair barnyard grass
The tested weeds: barnyard grass is collected in non-cultivated land fields, and seeds are stored in a laboratory for later use.
Reagent to be tested: cyhalofop-butyl technical, imazamox technical; is commercially available.
The test method comprises the following steps: sowing 20-25 seeds of the grass family weeds, barnyard grass, in a square plastic plant cultivation flowerpot with the specification of 7 multiplied by 7cm, covering soil of 0.5cm after sowing, pressing, sprinkling water, and then putting into a greenhouse for cultivation according to a conventional method. And (3) spraying stems and leaves by using a spraying machine according to the experimental design dosage when 15 weeds are planted in the 1-2 leaf stage of the weeds and the weeds are planted in the 3-4 leaf stage of the weeds. The experiment was repeated 3 times. And (3) after the test material is treated, the test material is placed in a greenhouse to be managed according to a conventional method, the reaction condition of the tested weed to the medicament is observed and recorded, the fresh weight of the overground part of each treated weed is weighed 7 days after the treatment, and the fresh weight inhibition percentage is calculated.
And (3) evaluating the synergistic effect: and calculating the fresh weight inhibition rate (E) and the theoretical fresh weight inhibition rate (E0) of the weeds among different treatments of single-agent and binary compound. The combined action type of the binary compound herbicide was evaluated. When the E-E0 is more than 10 percent, the two herbicides have synergistic effect after being compounded; when E-E0 < -10%, the two herbicides have antagonism; values of E-E0 between-10% and 10% are additive effects.
The observed fresh weight inhibition ratio (E) ═ control fresh weight-treated fresh weight ÷ control fresh weight × 100%. Theoretical fresh weight inhibition ratio (E0) ═ X + Y-XY/100
And (3) analyzing a test result:
as is clear from Table 1, the control effect of cyhalofop-butyl and imazamox on barnyard grass is low when used alone, for example, the control effect of cyhalofop-butyl on barnyard grass is only 51.92% when 3g a.i./mu; the control effect on barnyard grass is only 47.05% when 1.2g of imazamox is a.i./mu; when the two are used in combination, the control effect on barnyard grass is obviously improved.
As can be seen from Table 3, the combination of cyhalofop-butyl and imazamox has different combined effects by comparing the actual inhibition rate and the theoretical inhibition rate of the two herbicides under different combination conditions. When the proportion of the cyhalofop-butyl to the imazamox is 0.5+0.8 and 0.5+1.2, the composition shows additive combined effect on the barnyard grass; the rest of the mixture ratio shows the technical effect of synergy.
Table 1 shows that the inhibition rate of cyhalofop-butyl and imazamox on the fresh weight of barnyard grass by compounding the cyhalofop-butyl and the imazamox in different proportions is%
Figure BDA0002838287590000051
Note: all the above values are actual measured values
Table 2 shows the theoretical fresh weight inhibition rate of cyhalofop-butyl and imazamox in different proportions for barnyard grass
Figure BDA0002838287590000052
Note: "-" indicates the absence of a combination of single agents
TABLE 3 Combined action value of cyhalofop-butyl and imazamox on barnyard grass in different proportions (E-E0)
Figure BDA0002838287590000053
Note: "-" indicates the absence of a combination of single agents
Example 6 measurement of drug efficacy of Cyhalofop-butyl and imazamox in combination on weeds in paddy fields
Test agents: examples 1-4 formulations of the present configurations
Test crop fields and weed species thereof: directly sowing rice in a field; and (3) field weeds: barnyard grass, crab grass, green bristlegrass herb and wild oat.
The application method comprises the following steps: 4 drug treatments were set, 1 blank control, repeated 3 times; the area per cell was 20m2, and the random arrangement was made. Spraying stem and leaf. And (5) investigating the weed fresh weight control effect 14d after the application.
And (3) analyzing a test result:
the dosage forms prepared in the examples 1-4 have the total control effect on the weeds in the paddy field of about 90 percent when the dosage of the active ingredients is 5g a.i./mu. Can effectively reduce the application dosage of active ingredients, slow down the generation of drug resistance of weeds and have obvious synergistic effect.
Table 4 herbicidal Effect of the compounded preparations on paddy field
Preparation Dosage g a.i./mu Total control effect%
Example 1 5 89.40
Example 2 5 93.85
Example 3 5 90.88
Example 4 5 91.05
CK - -
The foregoing is only a preferred embodiment of the present invention, and it will be apparent to those skilled in the art that modifications may be made without departing from the invention as claimed in the invention and these modifications are within the scope of the invention.

Claims (8)

1. The weeding composition of cyhalofop-butyl and imazamox is characterized in that the active ingredients consist of cyhalofop-butyl and imazamox, and the mass ratio of the cyhalofop-butyl to the imazamox is 15-30: 3-12.
2. A herbicidal composition according to claim 1, characterized in that the active ingredient is present in an amount of 1-75% by weight.
3. A herbicidal composition according to claim 2, characterized in that the active ingredient is present in an amount of 20-60% by weight.
4. The herbicidal composition as claimed in claim 2, wherein the herbicidal composition is mixed with the usual adjuvants for agricultural use to prepare any formulation suitable for agricultural use.
5. A herbicidal composition according to claim 4, wherein said formulation is selected from the group consisting of emulsifiable concentrate, water dispersible granules, wettable powder, and granules.
6. Use of the herbicidal composition according to any one of claims 1 to 5 for controlling weeds in crop fields.
7. Use of a herbicidal composition according to claim 6, wherein the crop is rice or soybean.
8. Use of a herbicidal composition according to claim 6, characterized in that the weeds are annual weeds.
CN202011481633.0A 2020-12-16 2020-12-16 Weeding composition containing cyhalofop-butyl and imazamox Active CN112586501B (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107736405A (en) * 2017-09-08 2018-02-27 江西中迅农化有限公司 Herbicidal composition for rice field based on the anti-imidazolinone herbicide rice varieties of non-transgenic

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107736405A (en) * 2017-09-08 2018-02-27 江西中迅农化有限公司 Herbicidal composition for rice field based on the anti-imidazolinone herbicide rice varieties of non-transgenic

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