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CN112578302A - Echelon utilization power battery recombination method, system, equipment and storage medium - Google Patents

Echelon utilization power battery recombination method, system, equipment and storage medium Download PDF

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Publication number
CN112578302A
CN112578302A CN202011440103.1A CN202011440103A CN112578302A CN 112578302 A CN112578302 A CN 112578302A CN 202011440103 A CN202011440103 A CN 202011440103A CN 112578302 A CN112578302 A CN 112578302A
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power battery
internal resistance
rate
capacity
battery
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Inventor
范茂松
杨凯
耿萌萌
谭震
高飞
刘皓
赵光金
赖铱麟
张明杰
徐彬
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State Grid Corp of China SGCC
China Electric Power Research Institute Co Ltd CEPRI
Electric Power Research Institute of State Grid Henan Electric Power Co Ltd
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State Grid Corp of China SGCC
China Electric Power Research Institute Co Ltd CEPRI
Electric Power Research Institute of State Grid Henan Electric Power Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/396Acquisition or processing of data for testing or for monitoring individual cells or groups of cells within a battery
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/005Testing of electric installations on transport means
    • G01R31/006Testing of electric installations on transport means on road vehicles, e.g. automobiles or trucks
    • G01R31/007Testing of electric installations on transport means on road vehicles, e.g. automobiles or trucks using microprocessors or computers
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/3644Constructional arrangements
    • G01R31/3648Constructional arrangements comprising digital calculation means, e.g. for performing an algorithm
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/385Arrangements for measuring battery or accumulator variables
    • G01R31/387Determining ampere-hour charge capacity or SoC
    • G01R31/388Determining ampere-hour charge capacity or SoC involving voltage measurements
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/389Measuring internal impedance, internal conductance or related variables

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Abstract

A power battery recombination method, a system, equipment and a storage medium are used in a gradient manner to detect the capacity retention rate, the internal resistance increase rate or the open-circuit voltage of a power battery; selecting a power battery with capacity retention rate, internal resistance increasing rate or open-circuit voltage meeting a set threshold as a gradient utilization power battery; and recombining the echelon utilization power batteries according to the use conditions and the recombination standard. The invention can meet the application requirements under different scenes and can utilize the retired power battery to the maximum extent, thereby improving the economy of the echelon utilization of the power battery. The method adopted by the invention is easy to realize in engineering implementation and has higher application value.

Description

Echelon utilization power battery recombination method, system, equipment and storage medium
Technical Field
The invention belongs to the technical field of electric automobiles and energy storage, and particularly relates to a method, a system, equipment and a storage medium for recombining a power battery by echelon utilization.
Background
In recent years, the electric automobile industry in China is rapidly developed, and the quantity of electric automobiles in China exceeds 410 thousands by 6 months in 2020. At present, lithium ion power batteries are mainly used as power sources of electric automobiles, the performance of the power batteries is continuously degraded in the use process of the automobiles, the performance difference between the batteries is larger and larger, and the batteries need to be decommissioned from the automobiles when the batteries cannot meet the use requirements of the electric automobiles. Along with the rapid development of automobiles in China, the retirement amount of power batteries is also rapidly increased, the retirement amount of the power batteries exceeds 20GWH in 2020, and approaches 100GWH in 2025. Many of the retired power batteries still have high residual energy, and the batteries can be applied to occasions with low performance requirements through screening and recombination again, so that the gradient utilization of the power batteries is realized.
Compared with a new battery, the performance difference between batteries is obviously increased and the consistency is obviously reduced when the power battery is out of service, so that the power battery is usually required to be recombined before the utilization of the echelon to ensure better performance consistency in the utilization process of the echelon. The traditional method still sets a certain parameter threshold value aiming at parameters such as capacity, open-circuit voltage, internal resistance and the like of the battery according to a new battery method, and combines the batteries within a certain deviation range; however, the parameter difference between the retired power batteries is obviously increased compared with that of new batteries, the adoption of the traditional new battery recombination standard can cause that most of the retired power batteries are eliminated, and the echelon utilization rate is too low; meanwhile, the echelon utilization of the retired power battery has a plurality of potential application scenes, the use working condition under each scene is greatly different, the requirements on the performance difference between the echelon utilization batteries are different,
disclosure of Invention
The invention aims to provide a method, a system, equipment and a storage medium for recombining a power battery by using echelon utilization.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
a power battery recombination method for gradient utilization is used for detecting the capacity retention rate, the internal resistance increase rate and/or the open-circuit voltage of a power battery;
selecting a power battery with capacity retention rate, internal resistance increasing rate and/or open-circuit voltage meeting set threshold values as a gradient utilization power battery;
and recombining the echelon utilization power batteries according to the use conditions and the recombination standard.
A further improvement of the invention is that the capacity retention is calculated by the formula:
CR=Q/Qr*100% (1)
wherein CR is a capacity retention ratio, Q is a capacity after discharge, and Q isrIs rated capacity.
A further improvement of the invention is that the post-discharge capacity is obtained by: according to rated capacity QrAnd charging and discharging electricityAnd (3) voltage range, charging the echelon power battery to the upper limit voltage by constant current at the rate of 0.3-0.5C of rated capacity, standing for 120min, measuring open circuit internal resistance R, and then discharging the echelon power battery to the lower limit voltage by constant current at the rate of 0.3-0.5C to obtain the discharged capacity.
A further improvement of the present invention is that the internal resistance increase rate is calculated by the following formula:
RIR=(R-R0)/R0*100% (2)
wherein RIR is the increase rate of internal resistance, R is the open-circuit internal resistance0Is the initial resistance.
The invention is further improved in that the open-circuit internal resistance is obtained by the following process: and charging the battery to the upper limit voltage at a constant current of 0.3-0.5C multiplying power of the rated capacity, standing for 120min, and measuring the open-circuit internal resistance.
The invention is further improved in that the using conditions comprise the number of times of charge and discharge per year, the ambient temperature of the battery, the charge and discharge rate and the depth of each charge and discharge.
A further improvement of the invention is that the reconstitution standards include capacity retention, capacity range, OCV2Extremely poor, the increase rate of internal resistance and the internal resistance are extremely poor.
A power battery recombination system for gradient utilization comprises
The detection module is used for detecting the capacity retention rate, the internal resistance increasing rate and/or the open-circuit voltage of the power battery;
the selection module is used for selecting the power battery with the capacity retention rate, the internal resistance increasing rate and/or the open-circuit voltage meeting the set threshold value as the gradient utilization power battery;
and the recombination module is used for recombining the echelon utilization power battery according to the use condition and the recombination standard.
A computer device comprising a memory and a processor, the memory having stored thereon a computer program executable on the processor, the computer program when executed by the processor implementing the above-described echelon utilization power cell reorganization method.
A computer-readable storage medium, which stores a computer program that, when executed by a processor, causes the processor to perform the above-described echelon utilization power cell reorganization method.
Compared with the prior art, the invention has the following beneficial effects:
according to the invention, whether the echelon utilization value is obtained is judged according to the detection result of the echelon utilization power battery capacity retention ratio, the internal resistance increasing rate or the open-circuit voltage; for the battery without echelon utilization value, higher potential safety hazard exists, and echelon utilization is not carried out, so that the utilization rate of the retired power battery is improved on the basis of ensuring the safety and reliability of the echelon utilization battery; for the battery with the echelon utilization value, according to the use condition, the capacity retention rate, the capacity range difference, the open circuit voltage difference, the internal resistance increasing rate and the internal resistance range difference are taken as parameters to be recombined, and the residual value of the echelon utilization power battery is fully exerted. Therefore, the application requirements under different scenes can be met, and the retired power battery can be utilized to the maximum extent, so that the economy of the echelon utilization of the power battery is improved. The method adopted by the invention is easy to realize in engineering implementation and has higher application value.
Drawings
Fig. 1 is a flow chart of the power battery recombination by using the power batteries in a gradient manner.
Detailed Description
The present invention will be described in detail with reference to the accompanying drawings.
The invention discloses a recombination method for a echelon utilization power battery, which adopts different recombination standards according to different application working conditions, improves the utilization rate of a retired power battery on the basis of ensuring the safety and reliability of the echelon utilization battery, and sets different recombination standards according to the use conditions of the echelon utilization battery in different scenes, so that the application requirements in different scenes can be met, the retired power battery can be utilized to the maximum extent, and the economy of echelon utilization of the power battery is improved. The method has wide application prospect in the fields of electric vehicles, electrochemical energy storage, echelon utilization of power batteries and the like.
The invention relates to a power battery recombination method by gradient utilization, which is mainly used for a lithium ion power battery which is retired in large scale in the future, and comprises the following steps of firstly detecting the capacity retention rate, the internal resistance increasing rate and/or the open-circuit voltage of the power battery; selecting a power battery with capacity retention rate, internal resistance increasing rate and/or open-circuit voltage meeting set threshold values as a gradient utilization power battery; and recombining the echelon utilization power batteries according to the use conditions and the recombination standard.
Referring to fig. 1, the specific process is as follows:
(1) detecting open-circuit voltage before charging and discharging: before the battery is subjected to a charge-discharge capacity test, the open-circuit voltage OCV of the battery is tested and recorded1. And then judging whether the open-circuit voltage is in the range according to the charge-discharge voltage range on the specification of the model battery product, wherein the battery out of the range has higher potential safety hazard, and the battery recycling treatment is directly carried out without gradient utilization.
(2) Battery capacity, full-state open-circuit voltage and internal resistance detection: according to the rated capacity Q of the battery provided in the specification of the battery productrAnd charging and discharging voltage range, charging the battery to upper limit voltage at constant current of 0.3-0.5C rate of rated capacity at 25 + -5 deg.C, standing for 120min, and measuring open-circuit voltage OCV of the battery2And open circuit internal resistance R, then constant current discharging the battery to the lower limit voltage at the same multiplying power (0.3-0.5C multiplying power), and recording the current capacity Q of the battery. Calculating the capacity retention ratio CR and the internal resistance increase ratio RIR of the power battery used in the echelon, wherein the specific method comprises the following steps:
CR=Q/Qr*100% (1)
RIR=(R-R0)/R0*100% (2)
wherein R is0The internal resistance of the new battery, namely the initial resistance, is provided on the specification of the battery product of the model.
For the battery with the capacity retention rate CR lower than 50%, the residual capacity is too low, the echelon utilization value is small, and the battery is directly recycled without echelon utilization; for the battery with the internal resistance increasing rate RIR exceeding 200%, the safety risk in the use process is higher, and the battery is directly recycled without gradient utilization.
(3) Analysis of battery usage conditions during echelon utilization
Aiming at scenes and system configuration when the retired power battery is used in a gradient manner, the service conditions of the power battery used in the gradient manner are analyzed, and the service conditions mainly comprise the annual charging and discharging times, the ambient temperature of the battery, the charging and discharging multiplying power and the depth of each charging and discharging.
(4) Echelon utilization power battery recombination under different use conditions
Different recombination standards are adopted according to different using conditions during battery gradient utilization, and the specific recombination standards are shown in the following table 1:
TABLE 1 conditions of use and criteria for recombination
Figure BDA0002830162830000051
Figure BDA0002830162830000061
A power battery reorganization system for gradient utilization comprises:
the detection module is used for detecting the capacity retention rate, the internal resistance increasing rate and/or the open-circuit voltage of the power battery;
the selection module is used for selecting the power battery with the capacity retention rate, the internal resistance increasing rate and/or the open-circuit voltage meeting the set threshold value as the gradient utilization power battery;
and the recombination module is used for recombining the echelon utilization power battery according to the use condition and the recombination standard.
A computer device comprising a memory and a processor, the memory having stored thereon a computer program executable on the processor, the computer program when executed by the processor implementing the above-described echelon utilization power cell reorganization method.
A computer-readable storage medium, which stores a computer program that, when executed by a processor, causes the processor to perform the above-described echelon utilization power cell reorganization method.
According to the invention, the recombination method of the echelon utilization power battery under different use conditions is provided according to the detection results of the capacity, the open-circuit voltage and the internal resistance of the echelon utilization power battery and different use condition analysis, the echelon utilization of batteries with different performance differences is considered, the echelon utilization rate of the retired power battery is improved, and the technical economy of the echelon utilization of the power battery is improved. The method adopted by the invention is easy to realize in engineering implementation and has higher application value.
According to the invention, batteries without echelon utilization value and high potential safety hazard are eliminated by detecting the open-circuit voltage, the capacity and the internal resistance of the retired power battery, and different recombination methods are adopted by taking the capacity retention rate, the capacity range difference, the open-circuit voltage difference, the internal resistance increasing rate and the internal resistance range difference as parameters according to different use conditions during echelon utilization.
As will be appreciated by one skilled in the art, embodiments of the present invention may be provided as a method, system, or computer program product. Accordingly, the present invention may take the form of an entirely hardware embodiment, an entirely software embodiment or an embodiment combining software and hardware aspects. Furthermore, the present invention may take the form of a computer program product embodied on one or more computer-usable storage media (including, but not limited to, disk storage, CD-ROM, optical storage, and the like) having computer-usable program code embodied therein.
The present invention is described with reference to flowchart illustrations and/or block diagrams of methods, apparatus (systems), and computer program products according to embodiments of the invention. It will be understood that each flow and/or block of the flow diagrams and/or block diagrams, and combinations of flows and/or blocks in the flow diagrams and/or block diagrams, can be implemented by computer program instructions. These computer program instructions may be provided to a processor of a general purpose computer, special purpose computer, embedded processor, or other programmable data processing apparatus to produce a machine, such that the instructions, which execute via the processor of the computer or other programmable data processing apparatus, create means for implementing the functions specified in the flowchart flow or flows and/or block diagram block or blocks.
These computer program instructions may also be stored in a computer-readable memory that can direct a computer or other programmable data processing apparatus to function in a particular manner, such that the instructions stored in the computer-readable memory produce an article of manufacture including instruction means which implement the function specified in the flowchart flow or flows and/or block diagram block or blocks.
These computer program instructions may also be loaded onto a computer or other programmable data processing apparatus to cause a series of operational steps to be performed on the computer or other programmable apparatus to produce a computer implemented process such that the instructions which execute on the computer or other programmable apparatus provide steps for implementing the functions specified in the flowchart flow or flows and/or block diagram block or blocks.
Finally, it should be noted that: the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting the same, and although the present invention is described in detail with reference to the above embodiments, those of ordinary skill in the art should understand that: modifications and equivalents may be made to the embodiments of the invention without departing from the spirit and scope of the invention, which is to be covered by the claims.

Claims (10)

1.一种梯次利用动力电池重组方法,其特征在于,1. a kind of cascade utilization power battery reorganization method is characterized in that, 检测动力电池的容量保持率、内阻增加率和/或开路电压;Detect the capacity retention rate, internal resistance increase rate and/or open circuit voltage of the power battery; 选择容量保持率、内阻增加率和/或开路电压满足设置阈值的动力电池作为梯次利用动力电池;Select the power battery whose capacity retention rate, internal resistance increase rate and/or open circuit voltage meet the set threshold as the power battery for echelon utilization; 根据使用条件和重组标准对梯次利用动力电池进行重组。The cascade utilization power battery is recombined according to the usage conditions and recombination standards. 2.根据权利要求1所述的一种梯次利用动力电池重组方法,其特征在于,容量保持率通过下式计算:2. a kind of cascade utilization power battery reorganization method according to claim 1 is characterized in that, capacity retention rate is calculated by following formula: CR=Q/Qr*100% (1)CR=Q/Q r* 100% (1) 式中,CR为容量保持率,Q为放电后容量,Qr为额定容量。In the formula, CR is the capacity retention rate, Q is the capacity after discharge, and Q r is the rated capacity. 3.根据权利要求2所述的一种梯次利用动力电池重组方法,其特征在于,放电后容量通过以下过程得到:依据额定容量和充放电电压范围,以额定容量的0.3-0.5C倍率将梯次利用动力电池恒流充电至上限电压,静置后测量开路内阻,然后以0.3-0.5C倍率将梯次利用动力电池恒流放电至下限电压,得到放电后容量。3. A method for recombining power batteries for cascade utilization according to claim 2, wherein the capacity after discharge is obtained through the following process: according to the rated capacity and the charge-discharge voltage range, the cascade is divided into the cascade at a rate of 0.3-0.5C of the rated capacity. Charge the power battery to the upper limit voltage with constant current, measure the open-circuit internal resistance after standing, and then discharge the power battery with constant current to the lower limit voltage at a rate of 0.3-0.5C to obtain the post-discharge capacity. 4.根据权利要求1所述的一种梯次利用动力电池重组方法,其特征在于,内阻增加率通过下式计算:4. a kind of cascade utilization power battery reorganization method according to claim 1, is characterized in that, internal resistance increase rate is calculated by following formula: RIR=(R-R0)/R0*100% (2)RIR=(RR 0 )/R 0 * 100% (2) 式中,RIR为内阻增加率,R为开路内阻,R0为初始电阻。In the formula, RIR is the increase rate of internal resistance, R is the open circuit internal resistance, and R 0 is the initial resistance. 5.根据权利要求4所述的一种梯次利用动力电池重组方法,其特征在于,开路内阻通过以下过程得到:以额定容量的0.3-0.5C倍率将电池恒流充电至上限电压,静置后,测得开路内阻。5. A method for recombining power batteries for cascade utilization according to claim 4, wherein the open-circuit internal resistance is obtained by the following process: charging the battery with constant current to the upper limit voltage at a rate of 0.3-0.5C of the rated capacity, and leaving it at rest Then, measure the open circuit internal resistance. 6.根据权利要求1所述的一种梯次利用动力电池重组方法,其特征在于,使用条件包括每年的充放电次数、电池使用的环境温度、充放电倍率与每次充放电的深度。6 . The method for recombining a power battery for cascade utilization according to claim 1 , wherein the use conditions include the number of times of charge and discharge per year, the ambient temperature of the battery, the rate of charge and discharge, and the depth of each charge and discharge. 7 . 7.根据权利要求1所述的一种梯次利用动力电池重组方法,其特征在于,重组标准包括容量保持率、容量极差、OCV2极差、内阻增加率与内阻极差。7 . The method for recombining power batteries for cascade utilization according to claim 1 , wherein the recombination criteria include capacity retention rate, extremely poor capacity, extremely poor OCV 2 , increasing rate of internal resistance, and extremely poor internal resistance. 8 . 8.一种梯次利用动力电池重组系统,其特征在于,包括8. A power battery recombination system for cascade utilization is characterized in that, comprising 检测模块,用于检测动力电池的容量保持率、内阻增加率和/或开路电压;A detection module for detecting the capacity retention rate, internal resistance increase rate and/or open circuit voltage of the power battery; 选择模块,用于选择容量保持率、内阻增加率和/或开路电压满足设置阈值的动力电池作为梯次利用动力电池;The selection module is used to select the power battery whose capacity retention rate, internal resistance increase rate and/or open circuit voltage meet the set threshold as the power battery for cascade utilization; 重组模块,用于根据使用条件和重组标准对梯次利用动力电池进行重组。The recombination module is used to recombine the cascade utilization power battery according to the usage conditions and recombination standards. 9.一种计算机设备,其特征在于,所述计算机设备包括存储器和处理器,所述存储器上存储有能在所述处理器上运行的计算机程序,所述计算机程序被所述处理器执行时实现权利要求1-7中任意一项所述的梯次利用动力电池重组方法。9. A computer device, characterized in that the computer device comprises a memory and a processor, the memory stores a computer program that can run on the processor, and when the computer program is executed by the processor The method for recombining the power battery for cascade utilization described in any one of claims 1-7 is realized. 10.一种计算机可读存储介质,其特征在于,所述计算机可读存储介质存储有计算机程序,所述计算机程序当被处理器执行时使所述处理器执行权利要求1-7中任意一项所述的梯次利用动力电池重组方法。10. A computer-readable storage medium, characterized in that the computer-readable storage medium stores a computer program, the computer program, when executed by a processor, causes the processor to execute any one of claims 1-7 The step-by-step utilization power battery recombination method described in item.
CN202011440103.1A 2020-12-10 2020-12-10 Echelon utilization power battery recombination method, system, equipment and storage medium Pending CN112578302A (en)

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CN113759254A (en) * 2021-09-27 2021-12-07 中国联合网络通信集团有限公司 Battery recombination method, device, equipment and storage medium
CN113759254B (en) * 2021-09-27 2023-12-26 中国联合网络通信集团有限公司 Battery reorganization method, device, equipment and storage medium

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