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CN112551818B - High-salinity organic wastewater treatment system and treatment method - Google Patents

High-salinity organic wastewater treatment system and treatment method Download PDF

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CN112551818B
CN112551818B CN202011496416.9A CN202011496416A CN112551818B CN 112551818 B CN112551818 B CN 112551818B CN 202011496416 A CN202011496416 A CN 202011496416A CN 112551818 B CN112551818 B CN 112551818B
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CN112551818A (en
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陈顺权
戚广贤
王建明
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Guangzhou Institute of Advanced Technology of CAS
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/445Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by forward osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1268Membrane bioreactor systems

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  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
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Abstract

The invention provides a high-salinity organic wastewater treatment system which comprises a high-salinity wastewater inlet, a low-salinity wastewater inlet, a standard water discharge port, a forward osmosis device and an organic matter treatment device, wherein the forward osmosis device is divided into a first side area and a second side area, the first side area and the second side area are independent of each other and can only carry out mass transfer through a forward osmosis membrane, the high-salinity wastewater inlet is communicated with the first side area, a water outlet of the first side area is communicated with the organic matter treatment device, the low-salinity wastewater inlet is communicated with the organic matter treatment device, a water outlet of the organic matter treatment device is communicated with the second side area, and a water outlet of the second side area is communicated with the standard water discharge port. The high-salinity organic wastewater treatment system and the treatment method provided by the invention have lower treatment cost.

Description

一种高盐有机废水处理系统及处理方法A kind of high-salt organic wastewater treatment system and treatment method

技术领域technical field

本发明属于高盐废水处理技术领域,具体涉及一种高盐有机废水处理系统及处理方法。The invention belongs to the technical field of high-salt wastewater treatment, and in particular relates to a high-salt organic wastewater treatment system and a treatment method.

背景技术Background technique

高盐有机废水是目前难处理废水之一,具有盐分高、毒性高、难生化等特点。由于其中盐分浓度高,通常超过10%,常规的污水处理菌群无法在这么高盐浓度下存活并降解有机物污染物,而耐盐菌或嗜盐菌的菌落结构失衡,菌落单一,污染物降解能力差,所以,高盐有机废水生化处理困难,工业应用尚且较为困难。而采用高级氧化法,如臭氧氧化、电催化氧化,处理效率较低,成本高,而且无法彻底处理。芬顿氧化法处理高盐废水,由于废水有机物高,将产生大量铁泥,需要作危废处置,处置成本高。由于高级氧化法成本居高,又无法生化处理降解,在当前环保压力下,企业只能通过蒸发先结晶出盐分,再处理蒸出的废水。而蒸发结晶出的固体盐中含有大量有机物,需要作危废处置,费用高达数千元乃至万元每吨,该方法综合处置成本较高。High-salt organic wastewater is one of the most difficult wastewaters to treat. Due to the high salt concentration, usually more than 10%, conventional sewage treatment bacteria cannot survive and degrade organic pollutants at such a high salt concentration, while the colony structure of halophilic bacteria or halophilic bacteria is unbalanced, the colony is single, and the pollutants are degraded. The ability is poor, so the biochemical treatment of high-salt organic wastewater is difficult, and the industrial application is still relatively difficult. However, the use of advanced oxidation methods, such as ozone oxidation and electrocatalytic oxidation, has low treatment efficiency, high cost, and cannot be completely treated. The Fenton oxidation method is used to treat high-salt wastewater. Due to the high organic matter in the wastewater, a large amount of iron sludge will be generated, which needs to be disposed of as hazardous waste, and the disposal cost is high. Due to the high cost of advanced oxidation and the inability to biochemically treat and degrade, under the current environmental pressure, enterprises can only crystallize salt through evaporation, and then treat the evaporated wastewater. The solid salt produced by evaporation and crystallization contains a large amount of organic matter, which needs to be disposed of as hazardous waste, and the cost is as high as several thousand yuan or even ten thousand yuan per ton. The comprehensive disposal cost of this method is high.

发明专利一种高盐废水生化处理工艺(CN104150608A)公开了一种高盐废水生化处理工艺。主要包括以下步骤:1)获取耐盐菌并附着在反应器内填料上;2)配置不同模拟废水;3)驯化耐盐菌;将模拟废水和高盐废水按不同比例混合配制成多种驯化用废水,在反应器启动过程中,将耐盐菌按照驯化用废水中模拟废水含量由高到低的顺序依次经过多种驯化用废水驯化,缩短反应器启动时间;4)将驯化后的南阳郡直接对高盐废水进行处理。该专利中所要求的废水浓度为3-5%,不超过6%。采用该专利仍无法处理医药、农药、精细化工领域产生的高盐废水,因为这些高盐废水盐分多在10%以上。而且,驯化后的耐盐菌群与常规生化污水菌群有所差异,去除效率降低。The invention patent is a biochemical treatment process for high-salt wastewater (CN104150608A), which discloses a biochemical treatment process for high-salt wastewater. It mainly includes the following steps: 1) obtaining salt-tolerant bacteria and attaching to the packing in the reactor; 2) configuring different simulated wastewater; 3) domesticating the salt-tolerant bacteria; mixing simulated wastewater and high-salt wastewater in different proportions to prepare various domestication Using waste water, during the start-up process of the reactor, the salt-tolerant bacteria were domesticated through a variety of domestication waste water in the order of the simulated waste water content in the domestication waste water from high to low, so as to shorten the start-up time of the reactor; 4) The domesticated Nanyang The county directly treats the high-salt wastewater. The wastewater concentration required in this patent is 3-5%, not more than 6%. Using this patent, it is still impossible to treat the high-salt wastewater generated in the fields of medicine, pesticide and fine chemical industry, because the salinity of these high-salt wastewater is more than 10%. Moreover, the domesticated salt-tolerant bacteria were different from those of conventional biochemical sewage, and the removal efficiency was reduced.

在实际废水处理项目有,有部分企业对废水进行稀释后处理,但企业存在排水总量控制,生化处理后需要对废水进一步浓缩,多采用反渗透进行浓缩,浓缩成本高,需要巨额投资。In the actual wastewater treatment projects, some enterprises dilute the wastewater after treatment, but the enterprises have control of the total amount of drainage. After biochemical treatment, the wastewater needs to be further concentrated, and reverse osmosis is often used for concentration. The concentration cost is high and requires huge investment.

公开于该背景技术部分的信息仅仅旨在加深对本发明的总体背景技术的理解,而不应当被视为承认或以任何形式暗示该信息构成已为本领域技术人员所公知的现有技术。The information disclosed in this Background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person skilled in the art.

发明内容SUMMARY OF THE INVENTION

针对现有技术的不足,本发明提供一种处理成本较低的高盐有机废水处理系统及处理方法。In view of the deficiencies of the prior art, the present invention provides a high-salt organic wastewater treatment system and a treatment method with lower treatment cost.

本发明提供一种高盐有机废水处理系统,包括高盐废水入水口、低盐废水入水口、达标水排放口、正渗透装置和有机物处理装置,所述正渗透装置分为第一侧区域和第二侧区域,所述第一侧区域和第二侧区域相互独立,仅可通过正渗透膜进行传质,所述高盐废水入水口联通所述第一侧区域,所述第一侧区域出水口联通所述有机物处理装置,所述低盐废水入水口联通所述有机物处理装置,所述有机物处理装置的出水口联通所述第二侧区域,所述第二侧区域的出水口联通所述达标水排放口。The present invention provides a high-salt organic waste water treatment system, comprising a high-salt waste water inlet, a low-salt waste water inlet, a standard-compliant water discharge outlet, a forward osmosis device and an organic matter treatment device, wherein the forward osmosis device is divided into a first side area and a The second side area, the first side area and the second side area are independent of each other, and can only carry out mass transfer through the forward osmosis membrane, the high-salt wastewater inlet is connected to the first side area, and the first side area The water outlet is communicated with the organic matter treatment device, the low-salt wastewater inlet is communicated with the organic matter treatment device, the water outlet of the organic matter treatment device is communicated with the second side area, and the water outlet in the second side area is communicated with the water outlet. Describe the discharge outlet of up to standard water.

优选地,所述高盐有机废水处理系统还包括预处理装置、电催化装置和膜过滤装置,所述高盐废水入水口、预处理装置、电催化装置、膜过滤装置和第一侧区域沿水流方向依次联通,所述膜过滤装置柱式超滤、柱式微滤、浸没式超滤和浸没式微滤中的一种或几种。Preferably, the high-salt organic wastewater treatment system further comprises a pretreatment device, an electrocatalytic device and a membrane filtration device, and the high-salt wastewater inlet, pretreatment device, electrocatalytic device, membrane filtration device and the first side area are The water flow directions are connected in sequence, and the membrane filtration device is one or more of column ultrafiltration, column microfiltration, submerged ultrafiltration and submerged microfiltration.

优选地,所述第一侧区域中的盐浓度总是大于所述第二侧区域中的盐浓度,所述第一侧区域出水口流出的水的盐浓度小于所述高盐废水入水口的废水中的盐浓度,所述第一侧区域出水口流出的水中盐浓度小于3%。Preferably, the salt concentration in the first side area is always greater than the salt concentration in the second side area, and the salt concentration of the water flowing out of the water outlet of the first side area is less than that of the high-salt wastewater inlet. The salt concentration in the wastewater, the salt concentration in the water flowing out of the water outlet of the first side area is less than 3%.

优选地,所述有机物处理装置包括水解酸化池和膜生物反应器,所述低盐废水入水口联通所述水解酸化池,所述水解酸化池的出水口联通所述膜生物反应器,所述膜生物反应器的出水口联通所述第二侧区域。Preferably, the organic matter treatment device includes a hydrolysis and acidification tank and a membrane bioreactor, the low-salt wastewater inlet is connected to the hydrolysis and acidification tank, and the water outlet of the hydrolysis and acidification tank is connected to the membrane bioreactor. The water outlet of the membrane bioreactor communicates with the second side region.

优选地,所述膜生物反应器的回流口与所述水解酸化池联通。Preferably, the return port of the membrane bioreactor communicates with the hydrolysis and acidification tank.

优选地,所述水解酸化池内具有生物填料,所述膜生物反应器具有活性炭。Preferably, the hydrolysis and acidification tank has biological fillers, and the membrane bioreactor has activated carbon.

本发明提供一种高盐有机废水处理方法,包括如下步骤:The invention provides a method for treating high-salt organic wastewater, comprising the following steps:

先将低盐废水引入有机物处理装置中,所述有机物处理装置处理后的水通入正渗透装置的第二侧区域,First, the low-salt wastewater is introduced into the organic matter treatment device, and the water treated by the organic matter treatment device is passed into the second side area of the forward osmosis device,

将高盐废水引入正渗透装置的第一侧区域,所述第一侧区域和第二侧区域相互独立,仅可通过正渗透膜进行传质;The high-salt wastewater is introduced into the first side area of the forward osmosis device, the first side area and the second side area are independent of each other, and mass transfer can only be carried out through the forward osmosis membrane;

第二侧区域的水会通过正渗透膜流向第一侧,对第一侧中的高盐废水进行稀释,稀释后的废水流入有机物处理装置与引入的低盐废水混合处理,处理后再次通入正渗透装置的第二侧,实现循环处理,所述第二侧区域的水还会通过出水口排出。The water in the second side area will flow to the first side through the forward osmosis membrane to dilute the high-salt wastewater in the first side, and the diluted wastewater will flow into the organic matter treatment device to be mixed with the introduced low-salt wastewater, and then pass through again after treatment. The second side of the forward osmosis device realizes circulating treatment, and the water in the second side area will also be discharged through the water outlet.

优选地,所述高盐废水的盐浓度大于4%,所述低盐废水的盐浓度小于3%,所述低盐废水的进水量不少于高盐废水的进水量的10%。Preferably, the salt concentration of the high-salt wastewater is greater than 4%, the salt concentration of the low-salt wastewater is less than 3%, and the water intake of the low-salt wastewater is not less than 10% of the high-salt wastewater.

优选地,所述高盐废水的盐浓度大于6%,所述低盐废水的盐浓度小于2%。Preferably, the salt concentration of the high-salt wastewater is greater than 6%, and the salt concentration of the low-salt wastewater is less than 2%.

优选地,所述高盐废水引入正渗透装置之前还包括依次进行预处理、电催化和膜过滤的步骤;Preferably, before the high-salt wastewater is introduced into the forward osmosis device, it further comprises the steps of performing pretreatment, electrocatalysis and membrane filtration in sequence;

所述有机物处理装置包括水解酸化池和膜生物反应器,所述第一侧稀释后的废水先流入所述水解酸化池中,然后流入所述膜生物反应器中,膜生物反应器处理后的水流入所述第二侧区域,所述水解酸化池溶解氧控制在0.5mg/L以下,水停留时间为12-150h,所述膜生物反应器控制溶解氧为2-5mg/L,水停留时间为18-90h。The organic matter treatment device includes a hydrolysis and acidification tank and a membrane bioreactor. The diluted waste water from the first side first flows into the hydrolysis and acidification tank, and then flows into the membrane bioreactor. Water flows into the second side area, the dissolved oxygen in the hydrolysis and acidification tank is controlled below 0.5mg/L, the water residence time is 12-150h, the membrane bioreactor controls the dissolved oxygen at 2-5mg/L, and the water stays The time is 18-90h.

本发明提供的高盐有机废水处理系统及处理方法处理成本较低。The high-salt organic wastewater treatment system and the treatment method provided by the invention have lower treatment cost.

附图说明Description of drawings

通过附图中所示的本发明优选实施例更具体说明,本发明上述及其它目的、特征和优势将变得更加清晰。在全部附图中相同的附图标记指示相同的部分,且并未刻意按实际尺寸等比例缩放绘制附图,重点在于示出本的主旨。The above and other objects, features and advantages of the present invention will become more apparent from a more detailed description of the preferred embodiments of the present invention shown in the accompanying drawings. The same reference numerals refer to the same parts throughout the drawings, and the drawings have not been intentionally drawn to scale, the emphasis being placed on illustrating the subject matter of the present invention.

图1为本发明其中一个实施例提供的高盐有机废水处理系统结构示意图。FIG. 1 is a schematic structural diagram of a high-salt organic wastewater treatment system provided by one embodiment of the present invention.

图2为本发明另一个实施例提供的高盐有机废水处理系统结构示意图。FIG. 2 is a schematic structural diagram of a high-salt organic wastewater treatment system provided by another embodiment of the present invention.

图3为本发明实施例1提供的流程示意图。FIG. 3 is a schematic flowchart according to Embodiment 1 of the present invention.

具体实施方式Detailed ways

下面结合具体实施例对本发明技术方案作进一步的详细描述,以使本领域的技术人员可以更好的理解本发明并能予以实施,但所举实施例不作为对本发明的限定。The technical solutions of the present invention are further described in detail below with reference to specific embodiments, so that those skilled in the art can better understand the present invention and implement them, but the examples are not intended to limit the present invention.

参考图1-2,本发明实施例提供一种高盐有机废水处理系统,包括高盐废水入水口、低盐废水入水口、达标水排放口、正渗透装置4和有机物处理装置,正渗透装置4分为第一侧区域41和第二侧区域42,第一侧区域41和第二侧区域42相互独立,仅可通过正渗透膜进行传质,高盐废水入水口联通第一侧区域41,第一侧区域41出水口联通有机物处理装置,低盐废水入水口联通有机物处理装置,有机物处理装置的出水口联通第二侧区域42,第二侧区域42的出水口联通达标水排放口。1-2, an embodiment of the present invention provides a high-salt organic waste water treatment system, including a high-salt waste water inlet, a low-salt waste water inlet, a standard-compliant water discharge outlet, a forward osmosis device 4 and an organic matter treatment device, the forward osmosis device 4 is divided into a first side area 41 and a second side area 42, the first side area 41 and the second side area 42 are independent of each other, and can only be used for mass transfer through the forward osmosis membrane, and the high-salt wastewater inlet is connected to the first side area 41. The water outlet of the first side area 41 is connected to the organic matter treatment device, the low-salt waste water inlet is connected to the organic matter treatment device, the water outlet of the organic matter treatment device is connected to the second side area 42, and the water outlet of the second side area 42 is connected to the standard water discharge port.

本实施例提供的高盐有机废水处理系统通过正渗透装置4分为第一侧区域41和第二侧区域42,高盐废水进入第一次区域中,因为盐浓度较大,第二侧区域42中的水分会通过正渗透膜流向第一侧区域41,使得第一侧区域41的高盐废水得到稀释,稀释后的高盐废水进入有机物处理装置中,由于盐浓度较低,能够实现较好的污水处理效果。本实施例中低盐废水直接进入有机物处理装置中与高盐稀释后的废水一同进行处理,实现较高的处理效率,有机物处理装置处理的水流入第二侧区域42中,使得第二侧区域42的盐浓度能够持续保证比第一侧区域41进入的高盐废水的盐浓度低,进一步使得第二侧区域42的水能够不断进入第一侧区域41对高盐废水进行稀释。The high-salt organic wastewater treatment system provided in this embodiment is divided into a first side area 41 and a second side area 42 by the forward osmosis device 4, and the high-salt wastewater enters the first side area, because the salt concentration is high, the second side area The water in 42 will flow to the first side area 41 through the forward osmosis membrane, so that the high-salt wastewater in the first side area 41 is diluted, and the diluted high-salt wastewater enters the organic matter treatment device. Good sewage treatment effect. In this embodiment, the low-salt wastewater directly enters the organic matter treatment device and is treated together with the wastewater diluted with high salt to achieve higher treatment efficiency. The water treated by the organic matter treatment device flows into the second side area 42, so that the second side area The salt concentration of 42 can be continuously guaranteed to be lower than the salt concentration of the high-salt wastewater entering the first side area 41, further enabling the water in the second side area 42 to continuously enter the first side area 41 to dilute the high-salt wastewater.

本实施例中,将活污水等低盐度废水和高盐度废水分质分流处理,生活污水等低盐度废水处理后可持续为高盐度废水提供稀释用水,同时经稀释后的高盐废水的盐浓度较低,又能够实现与低盐废水一同经过有机物处理装置进行处理,可实现较好的水处理效果,极大的减少了水处理的成本。In this embodiment, low-salinity wastewater such as living sewage and high-salinity wastewater are separated and treated by quality, and after low-salinity wastewater such as domestic sewage is treated, dilution water can be continuously provided for high-salinity wastewater. The salt concentration of the wastewater is low, and it can be treated by the organic matter treatment device together with the low-salt wastewater, which can achieve a better water treatment effect and greatly reduce the cost of water treatment.

本实施例提供的高盐有机废水处理系统与稀释生化法相比,本发明专利利用原水浓度较高的特点,采用正渗透实现废水浓度只调整,正渗透只需提高循环流动,水分即可从低浓度一侧进入高浓度侧,实现了原水的低能耗稀释,经生化处理后有自动实现浓缩,无需反渗透所需的高压泵,能耗降低。Compared with the dilution biochemical method, the high-salt organic wastewater treatment system provided in this embodiment utilizes the feature of higher concentration of raw water, and adopts forward osmosis to realize only adjustment of the concentration of wastewater. The concentration side enters the high concentration side, which realizes the dilution of raw water with low energy consumption. After biochemical treatment, the concentration is automatically realized without the high-pressure pump required for reverse osmosis, and the energy consumption is reduced.

本实施例提供的高盐有机废水处理系统与现有的物化-化学处理工艺相比,本发明专利实现了高盐废水的生化处理,处理成本降低60%以上。Compared with the existing physicochemical-chemical treatment process, the high-salt organic wastewater treatment system provided in this embodiment realizes the biochemical treatment of high-salt wastewater, and the treatment cost is reduced by more than 60%.

本实施例提供的高盐有机废水处理系统与稀释法相比,本发明专利不增加外排水量,减少企业排污压力。Compared with the dilution method, the high-salt organic wastewater treatment system provided in this embodiment does not increase the external drainage volume and reduces the sewage discharge pressure of the enterprise.

本实施例通过正渗透系统实现了废水盐度自调节功能,高盐度废水转变成盐度较小的废水。从而可以采用常规的生化细菌进行处理,微生物菌落得到正常生长,系统更稳定,处理效果更好。In this embodiment, the self-adjustment function of the salinity of the wastewater is realized through the forward osmosis system, and the wastewater with high salinity is converted into wastewater with lower salinity. Therefore, conventional biochemical bacteria can be used for treatment, the microbial colonies can grow normally, the system is more stable, and the treatment effect is better.

参考图1-2,在优选实施例中,高盐有机废水处理系统还包括预处理装置1、电催化装置2和膜过滤装置3,高盐废水入水口、预处理装置1、电催化装置2、膜过滤装置3和第一侧区域41沿水流方向依次联通,膜过滤装置3柱式超滤、柱式微滤、浸没式超滤和浸没式微滤中的一种或几种。高盐废水首先在预处理装置1中通过絮凝沉淀或气浮等预处理去除悬浮物和油脂,然后进入电催化装置2中,在电催化中高盐废水中具有毒性的有机物将被降解成小分子,去除毒性,经过膜过滤装置3去除微小颗粒。进一步优选实施例中膜过滤装置3可以采用柱式超滤膜,也可采用浸没式超滤膜进行过滤。膜过滤装置3的水流入第一侧区域41中,被第二侧区域42的水进行稀释,盐浓度下降,进而实现有机物处理装置能够实现较好的处理,能够较好地去除原水的COD。1-2, in a preferred embodiment, the high-salt organic wastewater treatment system further includes a pretreatment device 1, an electrocatalytic device 2 and a membrane filtration device 3, a high-salt wastewater inlet, a pretreatment device 1, and an electrocatalytic device 2 , The membrane filtration device 3 and the first side area 41 are communicated in sequence along the water flow direction, and the membrane filtration device 3 is one or more of column ultrafiltration, column microfiltration, submerged ultrafiltration and submerged microfiltration. The high-salt wastewater first removes suspended solids and grease through pretreatment such as flocculation sedimentation or air flotation in the pretreatment device 1, and then enters the electrocatalytic device 2, where the toxic organic matter in the high-salt wastewater in electrocatalysis will be degraded into small molecules , remove toxicity, and remove tiny particles through membrane filtration device 3. In a further preferred embodiment, the membrane filtration device 3 can use a column-type ultrafiltration membrane or a submerged ultrafiltration membrane for filtration. The water of the membrane filtration device 3 flows into the first side area 41 and is diluted by the water of the second side area 42, and the salt concentration decreases, so that the organic matter treatment device can achieve better treatment and can better remove the COD of the raw water.

参考图1-2,在优选实施例中,第一侧区域41中的盐浓度总是大于第二侧区域42中的盐浓度,实现第二侧区域42中的水分能够通过正渗透膜流至第一侧区域41,对第一侧区域41中的高盐废水进行稀释。第一侧区域41出水口流出的水的盐浓度小于高盐废水入水口的废水中的盐浓度,第一侧区域41出水口流出的水中盐浓度小于3%,可较好的实现有机物处理装置能够实现较好的处理,避免盐浓度较高,影响菌群活性。1-2, in the preferred embodiment, the salt concentration in the first side region 41 is always greater than the salt concentration in the second side region 42, so that the moisture in the second side region 42 can flow through the forward osmosis membrane to The first side area 41 dilutes the high-salt wastewater in the first side area 41 . The salt concentration of the water flowing out of the water outlet of the first side area 41 is lower than that of the high-salt waste water inlet, and the salt concentration of the water flowing out of the water outlet of the first side area 41 is less than 3%, which can better realize the organic matter treatment device. It can achieve better treatment and avoid high salt concentration and affect the activity of bacterial flora.

参考图1-2,在优选实施例中,有机物处理装置包括水解酸化池5和膜生物反应器6,低盐废水入水口联通水解酸化池5,水解酸化池5的出水口联通膜生物反应器6,膜生物反应器6的出水口联通第二侧区域42。本实施例中,进入第一侧区域41的高盐废水经稀释后先进入水解酸化池5中进行处理,然后进入膜生物反应器6进行处理,经过水解酸化池5和膜生物反应器6处理能够实现较高的COD去除率。1-2, in a preferred embodiment, the organic matter treatment device includes a hydrolysis acidification tank 5 and a membrane bioreactor 6, the low-salt wastewater inlet is connected to the hydrolysis acidification tank 5, and the water outlet of the hydrolysis acidification tank 5 is connected to the membrane bioreactor. 6. The water outlet of the membrane bioreactor 6 communicates with the second side region 42 . In this embodiment, the high-salt waste water entering the first side area 41 is diluted and firstly enters the hydrolysis and acidification tank 5 for processing, and then enters the membrane bioreactor 6 for processing, and is processed by the hydrolysis and acidification tank 5 and the membrane bioreactor 6 High COD removal rate can be achieved.

参考图2,在优选实施例中,膜生物反应器6的回流口与水解酸化池5联通。本实施例中,膜生物反应器6的处理后的水还会回流至水解酸化池5中,进一步稀释水解酸化池5中的盐浓度,实现水解酸化池5具有较好的水处理效果。Referring to FIG. 2 , in a preferred embodiment, the return port of the membrane bioreactor 6 communicates with the hydrolysis and acidification tank 5 . In this embodiment, the treated water of the membrane bioreactor 6 will also return to the hydrolysis and acidification tank 5 to further dilute the salt concentration in the hydrolysis and acidification tank 5, so that the hydrolysis and acidification tank 5 has a better water treatment effect.

在优选实施例中,水解酸化池5内具有生物填料,膜生物反应器6具有活性炭。In a preferred embodiment, the hydrolysis acidification tank 5 has biological fillers, and the membrane bioreactor 6 has activated carbon.

在优选实施例中,在系统开始循环之前,往水解酸化池5、膜生物反应器6中加入一定量自来水与原废水混合,控制起始生化系统中盐度小于2%。In a preferred embodiment, before the system starts to circulate, a certain amount of tap water is added to the hydrolysis and acidification tank 5 and the membrane bioreactor 6 to mix with the original wastewater to control the salinity in the initial biochemical system to be less than 2%.

本发明实施例还提供一种高盐有机废水处理方法,包括如下步骤:The embodiment of the present invention also provides a high-salt organic wastewater treatment method, comprising the following steps:

先将低盐废水引入有机物处理装置中,有机物处理装置处理后的水通入正渗透装置4的第二侧区域42,First, the low-salt wastewater is introduced into the organic matter treatment device, and the water treated by the organic matter treatment device is passed into the second side area 42 of the forward osmosis device 4,

将高盐废水引入正渗透装置4的第一侧区域41,第一侧区域41和第二侧区域42相互独立,仅可通过正渗透膜进行传质;The high-salt wastewater is introduced into the first side area 41 of the forward osmosis device 4, and the first side area 41 and the second side area 42 are independent of each other, and can only carry out mass transfer through the forward osmosis membrane;

第二侧区域42的水会通过正渗透膜流向第一侧,对第一侧中的高盐废水进行稀释,稀释后的废水流入有机物处理装置与引入的低盐废水混合处理,处理后再次通入正渗透装置4的第二侧,实现循环处理,第二侧区域42的水还会通过出水口排出。The water in the second side area 42 will flow to the first side through the forward osmosis membrane to dilute the high-salt wastewater in the first side. The diluted wastewater flows into the organic matter treatment device and is mixed with the introduced low-salt wastewater. It enters the second side of the forward osmosis device 4 to realize the circulation treatment, and the water in the second side area 42 will also be discharged through the water outlet.

在优选实施例中,高盐废水的盐浓度大于4%,低盐废水的盐浓度小于3%,低盐废水的进水量不少于高盐废水的进水量的10%。一般医药农药精细化工行业生产企业情况,低盐废水水量不超过高盐废水的50%,一般可满足本实施例低盐废水的进水量不少于高盐废水的进水量的10%的要求。本实施例通过高盐废水和低盐废水分质收集,为高盐废水浓度自调节提供了条件。In a preferred embodiment, the salt concentration of the high-salt wastewater is greater than 4%, the salt concentration of the low-salt wastewater is less than 3%, and the influent amount of the low-salt wastewater is not less than 10% of the influent amount of the high-salt wastewater. In general pharmaceutical and pesticide fine chemical industry production enterprises, the amount of low-salt wastewater does not exceed 50% of that of high-salt wastewater, which generally meets the requirement that the inflow of low-salt wastewater in this embodiment is not less than 10% of that of high-salt wastewater. In this embodiment, the high-salt wastewater and the low-salt wastewater are collected by quality, which provides conditions for the self-adjustment of the concentration of the high-salt wastewater.

进一步在优选实施例中,高盐废水的盐浓度大于6%,低盐废水的盐浓度小于2%。更进一步优选实施例中,高盐废水的盐浓度大于10%,本实施例的高盐有机废水处理方法和处理系统特别适合高盐废水的处理,利用高盐废水盐浓度较高的特性,使得第二侧区域42的水分不断流入第一侧区域41对高盐废水进行稀释。Further in a preferred embodiment, the salt concentration of the high-salt wastewater is greater than 6%, and the salt concentration of the low-salt wastewater is less than 2%. In a further preferred embodiment, the salt concentration of the high-salt wastewater is greater than 10%. The high-salt organic wastewater treatment method and treatment system of this embodiment are particularly suitable for the treatment of high-salt wastewater, and the high-salt wastewater has a higher salt concentration. Moisture in the second side region 42 continuously flows into the first side region 41 to dilute the high-salt wastewater.

在优选实施例中,有机物处理装置包括水解酸化池5和膜生物反应器6,第一侧稀释后的废水先流入水解酸化池5中,然后流入膜生物反应器6(MBR)中,膜生物反应器6处理后的水流入第二侧区域42。In a preferred embodiment, the organic matter treatment device includes a hydrolysis and acidification tank 5 and a membrane bioreactor 6, and the diluted wastewater on the first side first flows into the hydrolysis and acidification tank 5, and then flows into the membrane bioreactor 6 (MBR), and the membrane bioreactor Reactor 6 treated water flows into second side zone 42 .

水解酸化池5采用生物填料作为生物载体,溶解氧控制在0.5mg/L以下,水停留时间为12-150h。The hydrolysis and acidification tank 5 uses biological fillers as biological carriers, the dissolved oxygen is controlled below 0.5mg/L, and the water retention time is 12-150h.

膜生物反应器6采用改性活性炭进行强化,膜生物反应器6内采用曝气盘进行增氧曝气,内悬挂填料,采用鼓风曝气手段控制溶解氧为2-5mg/L,好氧停留时间为18-90h。膜生物反应器6采用自吸泵抽吸出水,水经过膜生物反应器6的膜系统过滤进入正渗透装置4的第二侧区域42。The membrane bioreactor 6 is strengthened with modified activated carbon, and the aeration plate is used in the membrane bioreactor 6 for oxygen-enhancing aeration, and the packing is suspended inside. The residence time is 18-90h. The membrane bioreactor 6 uses a self-priming pump to suck the effluent water, and the water is filtered through the membrane system of the membrane bioreactor 6 and enters the second side area 42 of the forward osmosis device 4 .

在优选实施例中,高盐废水引入正渗透装置4之前还包括依次进行预处理、电催化和膜过滤的步骤;经过絮凝沉淀或气浮等预处理去除悬浮物和油脂,进入到电催化中进行降解。在电催化中废水中具有毒性的有机物将被降解成小分子,去除毒性,经过膜过滤去除微小颗粒。本实施例中,采用预处理装置1进行预处理,采用电催化装置2进行电催化,采用膜过滤装置3进行膜过滤。In a preferred embodiment, before the high-salt wastewater is introduced into the forward osmosis device 4, it also includes the steps of performing pretreatment, electrocatalysis and membrane filtration in sequence; after pretreatment such as flocculation sedimentation or air flotation, suspended solids and grease are removed, and then enter the electrocatalysis. degrade. In electrocatalysis, the toxic organic matter in the wastewater will be degraded into small molecules to remove the toxicity, and then the tiny particles will be removed by membrane filtration. In this embodiment, the pretreatment device 1 is used for pretreatment, the electrocatalysis device 2 is used for electrocatalysis, and the membrane filtration device 3 is used for membrane filtration.

在优选实施例中,由第二侧区域42排出的达标水可再次去除COD后排放。In a preferred embodiment, the up-to-standard water discharged from the second side region 42 can be discharged after removing the COD again.

本实施例提供的高盐有机废水的处理系统和方法适用于高盐废水的处理,可用于医药、农药、精细化工领域产生的高盐废水处理。The high-salt organic wastewater treatment system and method provided in this embodiment is suitable for the treatment of high-salt wastewater, and can be used for the treatment of high-salt wastewater generated in the fields of medicine, pesticide, and fine chemical industry.

为了对本发明的技术方案能有更进一步的了解和认识,现列举几个较佳实施例对其做进一步详细说明。In order to have a further understanding and understanding of the technical solutions of the present invention, several preferred embodiments are listed for further detailed description.

实施例1Example 1

广州市某外资医药企业,主要生产左旋肉碱等产品,产生盐浓度高达12%,COD为20000-30000mg/L的高盐废水,产生量为2-3m3/d。采用附图3工艺流程进行处理。原水100采用电催化200进行预处理,停留时间为2h,COD去除率为10%左右,经过浸没式超滤膜过滤300,膜过滤300出水进入正渗透系统400中,正渗透系统400采用二级逆流形式。经正渗透系统400后,第一侧区域401出水盐浓度为1.8%。第一侧区域401出水与低盐生活污水两者混合进入水解酸化池600,低盐生活污水500的水量为3m3/h,盐浓度在300mg/L以下,COD为200mg/L。水解酸化池600设计停留时间36h,采用悬挂帘式填料。水解酸化池600出水进入好氧MBR系统700,前端好氧采用接触氧化+活性污泥,接触氧化停留时间40h,活性污泥膜池停留时间8h,合计48h,MBR系统700设置回流,从MBR系统700回流至厌氧池前端回流比为100-150%。MBR系统700出水经过正渗透系统400浓缩,正渗透第二侧区域402出水直接排放。系统调试启动前,在水解酸化池和MBR池中加入自来水调节。系统自安装调试完成后,进出水水质情况如表1所示。A foreign-funded pharmaceutical company in Guangzhou mainly produces L-carnitine and other products, producing high-salt wastewater with a salt concentration of up to 12% and a COD of 20,000-30,000 mg/L, with an output of 2-3 m 3 /d. Adopt the technological process of accompanying drawing 3 to process. The raw water 100 is pretreated by electrocatalysis 200, the residence time is 2h, and the COD removal rate is about 10%. After 300 immersion ultrafiltration membrane filtration, the effluent of membrane filtration 300 enters the forward osmosis system 400, and the forward osmosis system 400 adopts the secondary Countercurrent form. After passing through the forward osmosis system 400, the effluent salt concentration of the first side region 401 is 1.8%. The effluent from the first side area 401 and the low - salt domestic sewage are mixed into the hydrolysis and acidification tank 600 . Hydrolysis and acidification tank 600 has a design residence time of 36h, and adopts hanging curtain packing. The effluent from the hydrolysis and acidification tank 600 enters the aerobic MBR system 700. The front-end aerobic use adopts contact oxidation + activated sludge, the contact oxidation residence time is 40h, and the activated sludge membrane tank residence time is 8h, totaling 48h. The reflux ratio of 700 to the front end of the anaerobic tank is 100-150%. The effluent of the MBR system 700 is concentrated through the forward osmosis system 400, and the effluent of the second side area 402 of the forward osmosis is directly discharged. Before the system is commissioned and started, tap water is added to the hydrolysis acidification tank and the MBR tank to adjust. After the installation and commissioning of the system is completed, the water quality of the incoming and outgoing water is shown in Table 1.

表1Table 1

Figure BDA0002841929830000081
Figure BDA0002841929830000081

满足广东省《水污染物排放限值》(DB4426-2001)排放标准中第二时段三级排放标准,处理后的废水外排。It meets the third-level discharge standard in the second period of the Guangdong Province "Water Pollutant Discharge Limits" (DB4426-2001) discharge standard, and the treated wastewater is discharged to the outside.

实施例2Example 2

实验室制作小型设备,参考图2,包括预处理装置1、电催化装置2、膜过滤装置3、正渗透装置4,、水解酸化池5、膜生物反应器6,膜生物反应器6包括好氧接触氧化池和好氧MBR池,其中水解酸化池体积为80L,好氧接触氧化池为30L,好氧MBR池为25L。采用蠕动泵作为进水泵,试验过程中水解酸化池溶解氧浓度控制在0.5mg/L以下,好氧池中溶解氧浓度控制为3-5mg/L,好氧池污泥培养时加入2%的粉末活性炭,提高好氧池的去除效果。采用江苏某医药中间体企业高盐废水,盐浓度约8%,为氯化钠硫酸钠混合盐,COD约15000-23000mg/L,采用电催化氧化进行预处理,预处理后经超滤膜进行过滤,超滤出水再正渗透装置内与膜生物反应器出水进行水分交换。正渗透装置第一侧区域的出水进入双级水解酸化池中,同时往水解酸化池中进生活污水(低盐废水)。观察稳定运行后水质变化。具体数据如表2所示。Small-scale equipment is produced in the laboratory, referring to Figure 2, including pretreatment device 1, electrocatalytic device 2, membrane filtration device 3, forward osmosis device 4, hydrolysis acidification tank 5, membrane bioreactor 6, membrane bioreactor 6 includes good Oxygen contact oxidation tank and aerobic MBR tank, the hydrolysis acidification tank volume is 80L, the aerobic contact oxidation tank is 30L, and the aerobic MBR tank is 25L. The peristaltic pump was used as the feed pump. During the test, the dissolved oxygen concentration in the hydrolysis and acidification tank was controlled below 0.5 mg/L, and the dissolved oxygen concentration in the aerobic tank was controlled at 3-5 mg/L. 2% of the dissolved oxygen in the aerobic tank was added during the culture of the aerobic tank. Powdered activated carbon to improve the removal effect of aerobic pools. High-salt wastewater from a pharmaceutical intermediate enterprise in Jiangsu, with a salt concentration of about 8%, is a mixed salt of sodium chloride and sodium sulfate, with a COD of about 15000-23000mg/L, which is pretreated by electrocatalytic oxidation, and then subjected to ultrafiltration membrane after pretreatment. Filtration, ultrafiltration effluent water is exchanged with membrane bioreactor effluent in the forward osmosis device. The effluent from the first side area of the forward osmosis device enters the two-stage hydrolysis and acidification tank, and simultaneously enters the domestic sewage (low-salt wastewater) into the hydrolysis and acidification tank. Observe the water quality changes after stable operation. The specific data are shown in Table 2.

表2Table 2

Figure BDA0002841929830000091
Figure BDA0002841929830000091

其中水解酸化停留时间为120h,好氧停留时间为82.5h。原水COD去除率达99%以上,去除效果良好。正渗透装置第二侧区域的出水可以采用臭氧氧化进一步降低COD。The hydrolysis and acidification residence time is 120h, and the aerobic residence time is 82.5h. The removal rate of COD in raw water is more than 99%, and the removal effect is good. The effluent of the second side area of the forward osmosis device can be further reduced by ozone oxidation to reduce COD.

实施例3Example 3

采用实施例2中的设备和原水,原水处理水量提高到5L/d,控制其他条件不变,生活污水进水仍为1L/d。则水解酸化池停留时间为76.8h,好氧停留时间为52.8h,进行培养试验。系统稳定后出水如表3所示。Using the equipment and raw water in Example 2, the treated water volume of the raw water is increased to 5L/d, and other conditions are kept unchanged, and the domestic sewage inflow is still 1L/d. Then, the residence time of the hydrolysis and acidification tank is 76.8h, and the aerobic residence time is 52.8h, and the culture test is carried out. After the system is stable, the effluent is shown in Table 3.

表3table 3

指标index COD(mg/L)COD(mg/L) 盐浓度(mg/L)Salt concentration (mg/L) 水量(L/d)Water volume (L/d) 原水raw water 15000-2300015000-23000 8000080000 55 电催化出水Electrocatalytic water effluent 13000-2020013000-20200 8000080000 55 第一侧区域出水Water outlet from the first side area 2700-42002700-4200 16700-1710016700-17100 24twenty four 生活污水domestic sewage 150-180150-180 200-220200-220 11 水解酸化出水Hydrolyzed acidified effluent 1220-18501220-1850 16000-1640016000-16400 2525 MBR出水MBR outlet 50-7350-73 16000-1640016000-16400 2525 第二侧区域出水Water outlet from the second side area 200-253200-253 约67000about 67000 66

废水中的COD去除率98.5%,去除效果良好。与实施例2相比,进水量增大以后,生化停留时间降低,去除率有所降低,但去除率仍十分理想。The removal rate of COD in wastewater was 98.5%, and the removal effect was good. Compared with Example 2, the biochemical residence time is reduced and the removal rate is reduced to some extent after the water inflow is increased, but the removal rate is still very ideal.

以上仅为本发明的优选实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书内容所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本发明的专利保护范围内。The above are only the preferred embodiments of the present invention, and are not intended to limit the scope of the patent of the present invention. Any equivalent structure or equivalent process transformation made by using the contents of the description of the present invention, or directly or indirectly applied in other related technical fields, are the same as The principles are included in the scope of patent protection of the present invention.

Claims (6)

1. A high-salt organic wastewater treatment system is characterized by comprising a high-salt wastewater inlet, a low-salt wastewater inlet, a standard water discharge port, a forward osmosis device and an organic matter treatment device, wherein the forward osmosis device is divided into a first side region and a second side region, the first side region and the second side region are independent of each other and can only transfer mass through the forward osmosis membrane, the high-salt wastewater inlet is communicated with the first side region, a first side region water outlet is communicated with the organic matter treatment device, the low-salt wastewater inlet is communicated with the organic matter treatment device, a water outlet of the organic matter treatment device is communicated with the second side region, and a water outlet of the second side region is communicated with the standard water discharge port; the salt concentration in the first side region is always greater than the salt concentration in the second side region;
the salt concentration of the high-salt wastewater is more than 6%, the salt concentration of the low-salt wastewater is less than 2%, and the water inflow of the low-salt wastewater is not less than 10% of that of the high-salt wastewater;
the organic matter treatment device comprises a hydrolysis acidification tank and a membrane bioreactor, wherein a low-salt wastewater inlet is communicated with the hydrolysis acidification tank, a water outlet of the hydrolysis acidification tank is communicated with the membrane bioreactor, and a water outlet of the membrane bioreactor is communicated with the second side area; and the reflux port of the membrane bioreactor is communicated with the hydrolysis acidification tank.
2. The high-salinity organic wastewater treatment system according to claim 1, further comprising a pretreatment device, an electro-catalytic device and a membrane filtration device, wherein the high-salinity wastewater inlet, the pretreatment device, the electro-catalytic device, the membrane filtration device and the first side region are sequentially communicated along the water flow direction, and the membrane filtration device comprises one or more of column type ultrafiltration, column type microfiltration, submerged type ultrafiltration and submerged type microfiltration.
3. The high salt organic wastewater treatment system of claim 1 wherein the salt concentration of the water exiting the first side zone outlet is less than the salt concentration of the wastewater exiting the high salt wastewater inlet and the salt concentration of the water exiting the first side zone outlet is less than 3%.
4. The high-salt organic wastewater treatment system of claim 1, wherein the hydrolysis acidification tank is provided with biological filler, and the membrane bioreactor is provided with activated carbon.
5. The method for treating the high-salinity organic wastewater is characterized by comprising the following steps of:
firstly, introducing the low-salt wastewater into an organic matter treatment device, introducing the water treated by the organic matter treatment device into a second side area of a forward osmosis device,
introducing high-salinity wastewater into a first side region of a forward osmosis device, wherein the first side region and a second side region are independent of each other and can only transfer mass through the forward osmosis membrane, and the salt concentration in the first side region is always larger than that in the second side region; the salt concentration of the high-salt wastewater is more than 6%, the salt concentration of the low-salt wastewater is less than 2%, and the water inflow of the low-salt wastewater is not less than 10% of that of the high-salt wastewater;
the water in the second side area flows to the first side through the forward osmosis membrane, the high-salinity wastewater in the first side is diluted, the diluted wastewater firstly flows into the hydrolysis acidification tank to be mixed with the introduced low-salinity wastewater and then flows into the membrane bioreactor, the water treated by the membrane bioreactor flows into the second side area, the backflow port of the membrane bioreactor is communicated with the hydrolysis acidification tank to realize circulation treatment, and the water in the second side area is discharged through the water outlet.
6. The method for treating high-salinity organic wastewater according to claim 5, characterized in that the method further comprises the steps of pretreatment, electrocatalysis and membrane filtration in sequence before the high-salinity wastewater is introduced into the forward osmosis device;
the dissolved oxygen of the hydrolysis acidification tank is controlled below 0.5mg/L, the water retention time is 12-150h, the dissolved oxygen of the membrane bioreactor is controlled to be 2-5mg/L, and the water retention time is 18-90 h.
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