CN112517223A - Enrichment method of low-quality copper-zinc bulk concentrate - Google Patents
Enrichment method of low-quality copper-zinc bulk concentrate Download PDFInfo
- Publication number
- CN112517223A CN112517223A CN202011164877.6A CN202011164877A CN112517223A CN 112517223 A CN112517223 A CN 112517223A CN 202011164877 A CN202011164877 A CN 202011164877A CN 112517223 A CN112517223 A CN 112517223A
- Authority
- CN
- China
- Prior art keywords
- copper
- zinc
- concentrate
- ton
- low
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012141 concentrate Substances 0.000 title claims abstract description 101
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 title claims abstract description 75
- 238000000034 method Methods 0.000 title claims abstract description 36
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000010949 copper Substances 0.000 claims abstract description 45
- 229910052802 copper Inorganic materials 0.000 claims abstract description 43
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 37
- 239000011701 zinc Substances 0.000 claims abstract description 37
- 238000005188 flotation Methods 0.000 claims abstract description 20
- 230000005484 gravity Effects 0.000 claims abstract description 15
- 238000004140 cleaning Methods 0.000 claims abstract description 4
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 16
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 15
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 11
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 11
- 239000004571 lime Substances 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 8
- 229940001584 sodium metabisulfite Drugs 0.000 claims description 8
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- TUZCOAQWCRRVIP-UHFFFAOYSA-N butoxymethanedithioic acid Chemical compound CCCCOC(S)=S TUZCOAQWCRRVIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 5
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 5
- 230000008719 thickening Effects 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims 2
- DSCFFEYYQKSRSV-UHFFFAOYSA-N 1L-O1-methyl-muco-inositol Natural products COC1C(O)C(O)C(O)C(O)C1O DSCFFEYYQKSRSV-UHFFFAOYSA-N 0.000 claims 1
- VJXUJFAZXQOXMJ-UHFFFAOYSA-N D-1-O-Methyl-muco-inositol Natural products CC12C(OC)(C)OC(C)(C)C2CC(=O)C(C23OC2C(=O)O2)(C)C1CCC3(C)C2C=1C=COC=1 VJXUJFAZXQOXMJ-UHFFFAOYSA-N 0.000 claims 1
- DSCFFEYYQKSRSV-KLJZZCKASA-N D-pinitol Chemical compound CO[C@@H]1[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@H]1O DSCFFEYYQKSRSV-KLJZZCKASA-N 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- 238000000926 separation method Methods 0.000 abstract description 24
- 239000012535 impurity Substances 0.000 abstract description 12
- 238000011084 recovery Methods 0.000 abstract description 11
- 239000011593 sulfur Substances 0.000 abstract description 8
- 229910052717 sulfur Inorganic materials 0.000 abstract description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 7
- 239000002253 acid Substances 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 150000002739 metals Chemical class 0.000 abstract description 3
- 239000008262 pumice Substances 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 3
- 230000005764 inhibitory process Effects 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 6
- 229910001656 zinc mineral Inorganic materials 0.000 description 5
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- 239000010665 pine oil Substances 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 229910001779 copper mineral Inorganic materials 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 229910052683 pyrite Inorganic materials 0.000 description 2
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 2
- 239000011028 pyrite Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B7/00—Combinations of wet processes or apparatus with other processes or apparatus, e.g. for dressing ores or garbage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B5/00—Washing granular, powdered or lumpy materials; Wet separating
- B03B5/02—Washing granular, powdered or lumpy materials; Wet separating using shaken, pulsated or stirred beds as the principal means of separation
- B03B5/04—Washing granular, powdered or lumpy materials; Wet separating using shaken, pulsated or stirred beds as the principal means of separation on shaking tables
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/018—Mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
An enrichment method of low-quality copper-zinc bulk concentrates comprises the steps of table reselection, tailing reselection, cleaning and flotation and copper-zinc separation. Impurity metals with large specific gravity and gangue components with small specific gravity are removed by gravity separation, so that the problem that the copper-zinc concentrate cannot be effectively enriched to influence separation in the traditional process is solved; the impurities removed by gravity separation are subjected to acid washing and then subjected to low-concentration strong inhibition flotation, so that the recovery rate of copper and zinc is ensured, the recovery rate of ore dressing is improved, the problem that sulfur is difficult to inhibit in the traditional process is solved, meanwhile, the phenomenon that pumice floats upwards easily due to the traditional flotation enrichment method is avoided, the separation efficiency is improved after copper and zinc concentrate is enriched, qualified copper concentrate and zinc concentrate are obtained after copper and zinc separation, and the problems that the copper concentrate produced by the traditional process is poor in quality and high in impurity content and cannot be sold are solved.
Description
Technical Field
The invention relates to the technical field of mineral flotation separation processes, in particular to a method for enriching low-quality copper-zinc bulk concentrates.
Background
The low-quality copper-zinc concentrate has the following characteristics: 1) the low-grade copper-zinc concentrate is a flotation product, and 80% of the surface of the mineral is hydrophobic; 2) carbonate-containing pumice minerals; 3) the metal impurities in the low-quality copper-zinc concentrate mainly comprise sulfur, lead and the like, wherein the floatability of the pyrite is better. The traditional enrichment and separation process of the low-quality copper-zinc concentrate mainly comprises copper-zinc bulk flotation-copper-zinc separation, and for the low-quality copper-zinc concentrate, pyrite and gangue cannot be effectively inhibited by adopting the traditional flotation process, so that the concentrates after copper-zinc separation have high mutual content and low recovery rate, and qualified copper concentrates cannot be obtained.
Disclosure of Invention
The invention aims to provide an enrichment method of low-quality copper-zinc bulk concentrates, which utilizes the specific gravity and floatability difference between impurities in copper-zinc bulk concentrates and copper-zinc minerals to separate impurities such as lead-sulfur gangue and the like so as to achieve the purpose of separating and enriching the copper-zinc minerals.
In order to achieve the purpose, the invention discloses an enrichment method of low-quality copper-zinc bulk concentrate, which is characterized by comprising the following steps of: adding water into low-quality copper-zinc concentrate, stirring to adjust the concentration of the ore pulp to be 15%, then entering a shaking table for reselection, wherein the stroke of the shaking table is 6-8mm, the frequency of flushing the shaking table is 420-490 times/min, middlings of the shaking table are used as copper-zinc rough concentrate I, and concentrate and tailings of the shaking table are combined to be used as reselected tailings; step 2: adding 10% dilute sulfuric acid of 1000-; and step 3: and (2) combining the copper-zinc rough concentrate I obtained in the step (1) and the copper-zinc rough concentrate II obtained in the step (2), adding 500 g/t of activated carbon and 1000 g/t of sodium sulfide for regrinding, then adding 3000 g/t of sodium metabisulfite for copper-zinc separation, carrying out two-time concentration on copper to obtain copper concentrate, adding 2000 g/t of lime, 20 g/t of copper sulfate, 20 g/t of butyl xanthate and 10 g/t of pine oil into the separated tailings, and carrying out one-time rough concentration and two-time concentration to obtain zinc concentrate.
In the technical scheme of the enrichment method of the low-quality copper-zinc bulk concentrate, the further preferable technical scheme is characterized in that:
1. the stroke of the shaking table in the step 1 is 7mm, and the stroke frequency of the shaking table is 450 times/min;
2. 1500 g/ton of 10% dilute sulfuric acid is added in the step 2;
3. 700 g/ton of sodium sulfide and 1500 g/ton of lime are added in the step 2;
4. 700 g/ton of sodium sulfide is added in the step 3, and 2500 g/ton of sodium metabisulfite is added.
Compared with the prior art, the method has the advantages that firstly, impurity metals with large specific gravity and gangue components with small specific gravity are removed from the low-quality copper-zinc concentrate through gravity separation, so that the problem that the separation is influenced because the copper-zinc concentrate cannot be effectively enriched in the traditional process is solved; the impurities removed by gravity separation are subjected to acid washing and then subjected to low-concentration strong inhibition flotation, so that the problem that sulfur is difficult to inhibit in the traditional process is solved, the phenomenon that the pumice is easy to float due to a traditional flotation enrichment method is avoided, the separation efficiency of copper-zinc concentrate is improved after the copper-zinc concentrate is enriched, the qualified copper concentrate and zinc concentrate are obtained after the copper-zinc separation, and the problems that the copper concentrate produced by the traditional process is poor in quality and high in impurity content and cannot be sold are solved.
Detailed Description
The following will clearly and completely describe the technical solutions in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Embodiment 1, a method for enriching a low-quality copper-zinc bulk concentrate, comprising the following steps, step 1: adding water into low-quality copper-zinc concentrate, stirring to adjust the concentration of the ore pulp to be 15%, then entering a shaking table for reselection, wherein the stroke of the shaking table is 6-8mm, the frequency of flushing the shaking table is 420-490 times/min, middlings of the shaking table are used as copper-zinc rough concentrate I, and concentrate and tailings of the shaking table are combined to be used as reselected tailings; step 2: adding 10% dilute sulfuric acid of 1000-; and step 3: and (2) combining the copper-zinc rough concentrate I obtained in the step (1) and the copper-zinc rough concentrate II obtained in the step (2), adding 500 g/t of activated carbon and 1000 g/t of sodium sulfide for regrinding, then adding 3000 g/t of sodium metabisulfite for copper-zinc separation, carrying out two-time concentration on copper to obtain copper concentrate, adding 2000 g/t of lime, 20 g/t of copper sulfate, 20 g/t of butyl xanthate and 10 g/t of pine oil into the separated tailings, and carrying out one-time rough concentration and two-time concentration to obtain zinc concentrate. The low-quality copper-zinc concentrate is prepared by firstly removing impurity metals with large specific gravity and gangue components with small specific gravity by gravity separation, recovering copper-zinc minerals by flotation after acid washing of tailings removed by gravity separation, and carrying out copper-zinc separation after regrinding on the copper-zinc concentrate. The unit of "g/ton of raw ore" refers to the number of grams of medicament added to each ton of low-quality copper-zinc bulk concentrate; the whole process flow in the step 1-3 is a closed-circuit flotation circulation flow.
Example 2, according to the method for enriching a low-quality copper-zinc bulk concentrate described in example 1, the stroke of the table in step 1 is 7mm, and the frequency of the table stroke is 450 times/min.
Example 3 in a method for enriching a low quality copper zinc bulk concentrate according to example 1 or 2, 1500 g/ton of 10% dilute sulphuric acid is added in step 2.
Example 4. in a method for the beneficiation of low quality copper zinc bulk concentrate according to example 1, 2 or 3, 700 g/ton of sodium sulfide and 1500 g/ton of lime are added in step 2.
Example 5. in the method for concentrating a low quality copper zinc bulk concentrate according to any one of examples 1 to 4, 700 g/ton of sodium sulfide is added in step 3, and 2500 g/ton of sodium metabisulfite is added.
Embodiment 6, a method for enriching low-quality copper-zinc bulk concentrates comprises the following steps of 1, adding water into low-quality copper-zinc concentrates, stirring and adjusting the concentration of ore pulp to 15%, and then performing '1 table concentrator reselection', wherein the stroke of a table concentrator is 8mm, and the frequency of impact of the table concentrator is 420 times/min; step 2, combining the table concentrator concentrate and table concentrator tailings, and then carrying out 2-acid pickling thickening operation, after cleaning with 1000 g/ton 10% dilute sulfuric acid and thickening to 50% of the concentration, adding water to adjust the concentration of the ore pulp to 15%, then adding 500 g/ton sodium sulfide and 1000 g/ton lime, and obtaining copper-zinc rough concentrate and tailings through 3-copper-zinc flotation and 4-copper-zinc mixed concentrate; and 3, adding 500 g/ton of activated carbon and 500 g/ton of sodium sulfide before grinding, adding 2000 g/ton of sodium metabisulfite after grinding for copper-zinc separation, performing 6-9 closed-loop flotation circulation operation on copper concentrate, adding 2000 g/ton of flotation underflow, 20 g/ton of copper sulfate, 20 g/ton of butyl xanthate and 10 g/ton of pine oil, and performing 10-14 closed-loop flotation circulation flow to obtain zinc concentrate.
The detection shows that the copper grade in the low-quality copper-zinc concentrate described in the embodiment 6 is 7.45% and the zinc grade is 22.43%; the copper concentrate obtained by the method has 22.43 percent of copper grade, 0.67 percent of lead grade, 3.21 percent of zinc grade and 75.34 percent of copper recovery rate; the zinc grade of the zinc concentrate is 47.45 percent, the copper grade is 1.13 percent, and the zinc recovery rate is 84.54 percent.
In comparative example 1, the traditional copper-zinc mixed flotation-copper-zinc separation process is adopted, lime is added into the same low-quality copper-zinc concentrate to make the pH value of the ore pulp be 12, and then copper-zinc mixed concentration is carried out. After regrinding, the copper-zinc ore concentrate pulp is added with 500 g/ton of sodium sulfide, 1000 g/ton of liquid sulfur dioxide, and then the copper and zinc minerals are separated to obtain copper ore concentrate and zinc ore concentrate.
According to detection, the copper grade in the low-quality copper-zinc concentrate in the comparative example 1 is 7.45 percent, and the zinc grade is 22.43 percent; the copper concentrate obtained by the process method of the comparative example 1 has 11.24 percent of copper grade, 7.32 percent of lead grade, 12.23 percent of zinc grade, 38.45 percent of sulfur grade and 77.34 percent of copper recovery rate; the zinc grade of the zinc concentrate is 35.34 percent, the copper grade is 2.34 percent, the sulfur grade is 35.45 percent, and the zinc recovery rate is 77.45 percent. Compared with the embodiment 1, the copper concentrate has higher impurity content and lower zinc concentrate grade, and the copper and zinc concentrate grade does not meet the requirements of qualified products.
Embodiment 7, a method for enriching low-quality copper-zinc bulk concentrates includes the following steps that 1, after water is added into low-quality copper-zinc concentrates and the concentration of ore pulp is adjusted to 15%, operation of '1 table concentrator reselection' is carried out, the stroke of a table concentrator is 6mm, and the frequency of impact of the table concentrator is 490 times/minute; step 2, combining the table concentrator and table concentrator tailings, then carrying out 2-acid pickling thickening operation, after cleaning with 2000 g/ton of 10% dilute sulfuric acid and thickening to 60%, adding water to adjust the concentration of the ore pulp to 15%, then adding 1000 g/ton of sodium sulfide and 1000 g/ton of lime plus 2000 g/ton, and obtaining copper-zinc rough concentrate and tailings through 3-copper-zinc flotation and 4-copper-zinc mixed concentrate; and 3, adding 500 g/ton of activated carbon and 1000 g/ton of sodium sulfide before grinding, adding 3000 g/ton of sodium metabisulfite after grinding for copper-zinc separation, performing 6-9 closed-loop flotation circulation operation on copper concentrate, adding 2000 g/ton of flotation underflow, 20 g/ton of copper sulfate, 20 g/ton of butyl xanthate and 10 g/ton of pine oil, and performing 10-14 closed-loop flotation circulation flow to obtain zinc concentrate.
The detection shows that the copper grade in the low-quality copper-zinc concentrate described in the embodiment 7 is 11.23% and the zinc grade is 27.34%; the copper concentrate obtained by the method has the copper grade of 24.34 percent, the lead grade of 0.45 percent, the zinc grade of 2.12 percent and the copper recovery rate of 78.43 percent; the zinc grade of the zinc concentrate is 48.56 percent, the copper grade is 0.87 percent, and the zinc recovery rate is 83.67 percent.
In comparative example 2, the conventional copper-zinc mixed flotation-copper-zinc separation process is adopted, and the lime is added into the same low-quality copper-zinc concentrate to make the pH value of the ore pulp be 12, and then the copper-zinc mixed concentration is carried out. The copper-zinc ore concentrate pulp is reground, 800 g of sodium sulfide per ton of raw ore is added, 1500 g of liquid sulfur dioxide per ton of raw ore is added, and then copper and zinc minerals are separated to obtain copper ore concentrate and zinc ore concentrate.
According to detection, the copper grade in the low-quality copper-zinc concentrate in the comparative example 2 is 11.23 percent, and the zinc grade is 27.34 percent; the copper concentrate obtained by the process method of the comparative example 2 has 13.23% of copper grade, 8.23% of lead grade, 14.23% of zinc grade, 36.32% of sulfur grade and 73.54% of copper recovery rate; the zinc grade of the zinc concentrate is 38.32 percent, the copper grade is 3.12 percent, the sulfur grade is 35.32 percent, and the zinc recovery rate is 80.45 percent. Compared with the embodiment 2, the copper concentrate has higher impurity content and lower zinc concentrate grade, and the copper and zinc concentrate grade does not meet the requirements of qualified products.
The above description is only for the preferred embodiments of the present invention, but the protection scope of the present invention is not limited thereto, and any person skilled in the art can substitute or change the technical solution of the present invention and the inventive concept thereof within the scope of the present invention.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011164877.6A CN112517223B (en) | 2020-10-27 | 2020-10-27 | A kind of enrichment method of low-quality copper-zinc mixed concentrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011164877.6A CN112517223B (en) | 2020-10-27 | 2020-10-27 | A kind of enrichment method of low-quality copper-zinc mixed concentrate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112517223A true CN112517223A (en) | 2021-03-19 |
| CN112517223B CN112517223B (en) | 2022-11-08 |
Family
ID=74978982
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011164877.6A Active CN112517223B (en) | 2020-10-27 | 2020-10-27 | A kind of enrichment method of low-quality copper-zinc mixed concentrate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112517223B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112934479A (en) * | 2021-04-22 | 2021-06-11 | 江西理工大学 | Combined inhibitor and micro-fine particle copper-zinc bulk concentrate flotation separation method |
Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1127170B (en) * | 1955-08-04 | 1962-04-05 | Minnesota Mining & Mfg | Use of perhalocarboxylic acids as an additive to aqueous solutions for the surface treatment of metal objects |
| CN101293221A (en) * | 2008-06-16 | 2008-10-29 | 李美平 | Inhibition reelection and separation method for bulk concentrate floatation of plumbum-zincium, plumbum-zincium-copper or plumbum-copper |
| CN101428250A (en) * | 2008-12-08 | 2009-05-13 | 杭州建铜集团有限公司 | Copper-zinc separation beneficiation method |
| CN101451185A (en) * | 2007-11-28 | 2009-06-10 | 灵宝市金源矿业有限责任公司 | Comprehensive recovery method for ferro-sulphur ore containing copper, zinc and iron multi-metal |
| CN101745458A (en) * | 2008-12-16 | 2010-06-23 | 北京有色金属研究总院 | Separation process for low-grade Cu-Pb-Zn complex multi-metal sulphide ore |
| CN102205264A (en) * | 2010-12-23 | 2011-10-05 | 紫金矿业集团股份有限公司 | Beneficiation method for increasing gold recovery rate of copper-zinc sulfide ore |
| CN102225368A (en) * | 2011-04-02 | 2011-10-26 | 吐鲁番雪银金属矿业股份有限公司 | Flotation separation method for refractory sulfide ore and high-sulfur copper-zinc ore |
| CN102441497A (en) * | 2011-10-24 | 2012-05-09 | 山东黄金矿业(莱州)有限公司精炼厂 | Direct cyanidation and comprehensive recovery production method of high-lead zinc copper gold concentrate |
| CN102513214A (en) * | 2011-12-09 | 2012-06-27 | 紫金矿业集团股份有限公司 | Process for separating copper from waste micro/fine-particle zinc tailing |
| AU2013200446A1 (en) * | 2006-08-03 | 2013-02-14 | Halliburton Energy Services, Inc | A composition and method for making a proppant |
| CN103447155A (en) * | 2013-08-23 | 2013-12-18 | 西北矿冶研究院 | Ore dressing method for blue chalcocite and pyrite and collecting agent used in ore dressing method |
| CN104741210A (en) * | 2013-12-25 | 2015-07-01 | 北京有色金属研究总院 | Mineral processing technology for treating copper sulfide ore containing easy-floating gangue |
| CN105057072A (en) * | 2015-09-02 | 2015-11-18 | 云南华联锌铟股份有限公司 | Comprehensive recovery technology of multi-metal low-grade ore and ore-bearing waste rock resources thereof |
| CN107413513A (en) * | 2017-06-07 | 2017-12-01 | 中南大学 | The method for floating of copper sulfide zinc ore |
| CN110743900A (en) * | 2019-10-29 | 2020-02-04 | 攀钢集团攀枝花钢铁研究院有限公司 | Novel method for recovering carbon, copper and silver in zinc kiln slag |
| CN111530622A (en) * | 2020-05-08 | 2020-08-14 | 江西理工大学 | Method for removing impurities from high-grade sulfur concentrate |
-
2020
- 2020-10-27 CN CN202011164877.6A patent/CN112517223B/en active Active
Patent Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1127170B (en) * | 1955-08-04 | 1962-04-05 | Minnesota Mining & Mfg | Use of perhalocarboxylic acids as an additive to aqueous solutions for the surface treatment of metal objects |
| AU2013200446A1 (en) * | 2006-08-03 | 2013-02-14 | Halliburton Energy Services, Inc | A composition and method for making a proppant |
| CN101451185A (en) * | 2007-11-28 | 2009-06-10 | 灵宝市金源矿业有限责任公司 | Comprehensive recovery method for ferro-sulphur ore containing copper, zinc and iron multi-metal |
| CN101293221A (en) * | 2008-06-16 | 2008-10-29 | 李美平 | Inhibition reelection and separation method for bulk concentrate floatation of plumbum-zincium, plumbum-zincium-copper or plumbum-copper |
| CN101428250A (en) * | 2008-12-08 | 2009-05-13 | 杭州建铜集团有限公司 | Copper-zinc separation beneficiation method |
| CN101745458A (en) * | 2008-12-16 | 2010-06-23 | 北京有色金属研究总院 | Separation process for low-grade Cu-Pb-Zn complex multi-metal sulphide ore |
| CN102205264A (en) * | 2010-12-23 | 2011-10-05 | 紫金矿业集团股份有限公司 | Beneficiation method for increasing gold recovery rate of copper-zinc sulfide ore |
| CN102225368A (en) * | 2011-04-02 | 2011-10-26 | 吐鲁番雪银金属矿业股份有限公司 | Flotation separation method for refractory sulfide ore and high-sulfur copper-zinc ore |
| CN102441497A (en) * | 2011-10-24 | 2012-05-09 | 山东黄金矿业(莱州)有限公司精炼厂 | Direct cyanidation and comprehensive recovery production method of high-lead zinc copper gold concentrate |
| CN102513214A (en) * | 2011-12-09 | 2012-06-27 | 紫金矿业集团股份有限公司 | Process for separating copper from waste micro/fine-particle zinc tailing |
| CN103447155A (en) * | 2013-08-23 | 2013-12-18 | 西北矿冶研究院 | Ore dressing method for blue chalcocite and pyrite and collecting agent used in ore dressing method |
| CN104741210A (en) * | 2013-12-25 | 2015-07-01 | 北京有色金属研究总院 | Mineral processing technology for treating copper sulfide ore containing easy-floating gangue |
| CN105057072A (en) * | 2015-09-02 | 2015-11-18 | 云南华联锌铟股份有限公司 | Comprehensive recovery technology of multi-metal low-grade ore and ore-bearing waste rock resources thereof |
| CN107413513A (en) * | 2017-06-07 | 2017-12-01 | 中南大学 | The method for floating of copper sulfide zinc ore |
| CN110743900A (en) * | 2019-10-29 | 2020-02-04 | 攀钢集团攀枝花钢铁研究院有限公司 | Novel method for recovering carbon, copper and silver in zinc kiln slag |
| CN111530622A (en) * | 2020-05-08 | 2020-08-14 | 江西理工大学 | Method for removing impurities from high-grade sulfur concentrate |
Non-Patent Citations (2)
| Title |
|---|
| 张文瀚等: "某高硫铜锌多金属矿综合回收试验研究", 《矿业工程》 * |
| 苏成德等: "《选矿操作技术解疑》", 31 August 1999, 河北科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112934479A (en) * | 2021-04-22 | 2021-06-11 | 江西理工大学 | Combined inhibitor and micro-fine particle copper-zinc bulk concentrate flotation separation method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN112517223B (en) | 2022-11-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107029870B (en) | Method for comprehensively recovering lead, zinc, tin and fluorite from tailings | |
| CN101234363A (en) | A method of producing high-grade sulfur concentrate with low-grade pyrite ore | |
| CN110170381B (en) | Beneficiation method for recovering cassiterite from tin-copper paragenic ore | |
| CN101786049A (en) | Flotation method of lead-zinic-sulphide ore with high oxygenation efficiency | |
| CN106622634A (en) | Beneficiation method for copper-cobalt ore | |
| CN102430480A (en) | Regrinding, recleaning and recleaning separation process for coarse clean coal | |
| CN113333153B (en) | Ore dressing method for fine-grained chalcopyrite in plateau area | |
| CN103990547A (en) | A complex refractory zinc oxide ore beneficiation process | |
| CN111167596A (en) | Method for comprehensively recovering rare earth minerals and fluorite in bastnaesite treatment process | |
| CN110653075B (en) | A kind of copper mineral flotation method in seawater medium | |
| CN107971124B (en) | Copper-molybdenum separation method for mud-containing sulfur-containing low-grade copper-molybdenum ore | |
| CN102527497B (en) | Beneficiation method for separating zinc sulfide ores from sulphur in wet-method zinc smelting slag | |
| CN112844818B (en) | Beneficiation separation method for copper-zinc sulfide ore | |
| CN112517223A (en) | Enrichment method of low-quality copper-zinc bulk concentrate | |
| CN104190528A (en) | Method for recycling ultra-fine fraction titanic iron ore and production method for titanium concentrate | |
| CN112619880A (en) | Separation method of limonite and barite ores | |
| CN110038718B (en) | Process for efficiently separating micro-fine tungsten ore by using centrifugal machine and flotation | |
| CN112619881A (en) | Copper-lead-zinc-sulfur bulk concentrate sorting method | |
| CN113333170B (en) | Method for improving main grade of zinc concentrate after copper-zinc separation | |
| CN112619878A (en) | Comprehensive recovery process for iron symbiotic nonferrous metal copper, lead and zinc | |
| CN113333180B (en) | Flotation method for ore containing altered rock | |
| CN113351360A (en) | Beneficiation method for high-sulfur magnetite ore of low-grade copper | |
| CN110538724A (en) | Beneficiation method for high-mud complex fluorite ore | |
| CN115445778B (en) | A two-stage short-process flotation process for high-calcium mica-type fluorite | |
| CN110538718A (en) | Tin rough concentrate concentration process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |