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CN112501214A - Two-phase anaerobic treatment system and method for reinforcing wet garbage in villages and towns - Google Patents

Two-phase anaerobic treatment system and method for reinforcing wet garbage in villages and towns Download PDF

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Publication number
CN112501214A
CN112501214A CN202011333378.5A CN202011333378A CN112501214A CN 112501214 A CN112501214 A CN 112501214A CN 202011333378 A CN202011333378 A CN 202011333378A CN 112501214 A CN112501214 A CN 112501214A
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tank
garbage
treatment
liquid
wet garbage
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CN112501214B (en
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刘建伟
陈欣玥
臧娜娜
冯文韬
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Beijing University of Civil Engineering and Architecture
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Beijing University of Civil Engineering and Architecture
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    • C12P5/00Preparation of hydrocarbons or halogenated hydrocarbons
    • C12P5/02Preparation of hydrocarbons or halogenated hydrocarbons acyclic
    • C12P5/023Methane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C21/00Disintegrating plant with or without drying of the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
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Abstract

The invention discloses a system and a method for strengthening two-phase anaerobic treatment of wet garbage in villages and towns, which comprises wet garbage pretreatment, straw pretreatment and two-phase anaerobic fermentation treatment; the invention adopts directional sorting treatment to carry out the pretreatment of wet garbage, obtains high-purity organic garbage components, mixes the high-purity organic garbage components with the straws in a reasonable proportion, and carries out independent hydrolysis acid production reaction and independent methane production reaction, thereby having good treatment effect, good integration degree of a treatment system and greatly improving the resource utilization rate.

Description

Two-phase anaerobic treatment system and method for reinforcing wet garbage in villages and towns
Technical Field
The invention relates to the field of garbage treatment, in particular to a wet garbage reinforced two-phase anaerobic treatment system and a method.
Background
Along with the rapid development of rural economy, the living standard of residents is continuously improved, the production amount of domestic garbage in villages and towns is increased day by day, more than half of the domestic garbage is wet garbage consisting of organic components such as kitchen waste and the like, the wet garbage is high in water content, rich in organic matters and high in grease, easy to ferment, deteriorate and rot, long in standing time, easy to nourish pathogenic microorganisms and emit malodorous gas. The classification effect of wet garbage in villages and towns is poor, other components can be mixed in the wet garbage, and substances such as courtyard garbage, branches and leaves, grass and the like can be mixed in the wet garbage. If not properly handled, it can seriously affect environmental hygiene and human health. Meanwhile, the wet garbage is mainly characterized by containing other garbage components due to incomplete front-end classification, cellulose, hemicellulose and lignin substances such as vegetable stems, leaves, branches and leaves of trees and the like, and oil in the wet garbage. At present, the treatment is mainly carried out by landfilling, incineration, conventional composting and the like.
However, the above methods have the following disadvantages, respectively: the landfill technology is not suitable for treating wet garbage, can not realize the reclamation of the wet garbage, occupies a large amount of land, and leachate generated during the landfill pollutes soil and underground water to cause secondary environmental pollution. Although the incineration treatment has small occupied area and good volume reduction effect, wet garbage has high water content and low heat value, auxiliary fuel needs to be added, a large amount of waste gas and waste residue can be generated in the incineration process, and particularly toxic by-product-dioxin gas can be generated to cause secondary pollution. Conventional compost treatment needs a large field, the compost fermentation period is long, the efficiency is low, the quality of the unevenly fermented organic fertilizer is unstable, the finished organic fertilizer needs drying equipment, the energy consumption and the environmental pollution are increased, the problems of waste gas and odor pollution are caused in open type fermentation treatment, the treatment effect of leachate is poor, and secondary pollution is caused. Compared with the conventional solid waste treatment technologies such as landfill, composting and incineration and the like, the anaerobic fermentation is a technology which can effectively convert organic waste into methane so as to be used as gas fuel, and the biogas residues generated after the anaerobic fermentation can be further processed into high-quality fertilizers while generating clean energy, so that the method is a feasible new resource-based environment-friendly technology.
However, since the wet garbage contains cellulose, hemicellulose and lignin substances such as vegetable stems and leaves, branches and leaves of trees and the like, and possibly contains grease, the treatment effect is not high by adopting the conventional anaerobic fermentation technology, and the recycling effect is poor.
Disclosure of Invention
The purpose of the invention is as follows: one of the purposes of the invention is to provide a two-phase anaerobic treatment system for reinforcing wet garbage in villages and towns, which improves the treatment efficiency and the resource utilization effect of the system; the invention also aims to provide a two-phase anaerobic treatment method for reinforcing the wet garbage in villages and towns.
The technical scheme is as follows: the invention provides a reinforced two-phase anaerobic treatment method for wet garbage in villages and towns, which comprises wet garbage pretreatment, straw pretreatment and two-phase anaerobic fermentation treatment;
wherein the wet waste pretreatment comprises: manually sorting and removing interferents in the wet garbage, then carrying out solid-liquid separation treatment to obtain pre-dewatered garbage, screening the pre-dewatered garbage, then carrying out directional sorting treatment according to components contained in the garbage with different particle sizes, and removing metals, plastics, fibers and inorganic matters to obtain sorted organic garbage; crushing the organic garbage to obtain a crushed material, and then carrying out sorting treatment on stems and leaves and glass to obtain high-purity organic garbage with cellulose-containing substances and glass removed from the stems and leaves;
the straw pretreatment comprises the following steps: crushing the straws to obtain crushed substances with the size less than 5mm, blending the crushed substances to remove lignin substances, and then drying to obtain pretreated straws;
the two-phase anaerobic fermentation treatment comprises the following steps: mixing the pretreated straws with the organic garbage obtained by the wet garbage pretreatment, and adding a compound bacterial liquid to obtain a mixed material; sending the mixed material to a hydrolysis acidification area, and adding hydrolysis acidification bacteria to perform hydrolysis acidification reaction; and (3) feeding the hydrolytic acidification liquid formed by the hydrolytic acidification reaction into a methanogenic area, and adding methanogenic bacteria liquid to perform anaerobic fermentation reaction.
The treatment method also comprises sewage treatment, wherein the treated sewage is sewage subjected to oil-water separation treatment, biogas slurry subjected to centrifugal treatment and separation and sewage of each garbage treatment unit; the sewage is treated by adopting a coagulation air flotation-high load aeration tank-two-stage A/O-MBR process, the effluent is reused for a two-phase anaerobic fermentation system and a straw pretreatment system to adjust the humidity, one part of sludge flows back to a front-end first-stage denitrification tank, after the residual sludge is subjected to concentration treatment and deep dehydration, the generated clear liquid flows back to the first-stage denitrification tank, and the generated slag cake and sludge cake flow back to be hydrolyzed.
Wherein, the wet garbage pretreatment comprises the following steps:
(1) manually sorting and removing interferents in the wet garbage, wherein the interferents comprise plastic, glass, metal and other large substances;
(2) carrying out solid-liquid separation treatment on the residual wet garbage after manual sorting treatment to obtain pre-dehydrated garbage and oily wastewater; carrying out impurity separation on oily wastewater through a pipeline filter, then carrying out oil-water separation treatment, extracting oil, processing to prepare industrial oil, and feeding the wastewater into a sewage treatment system;
(3) performing primary screening treatment on the pre-dehydrated garbage obtained in the step (2) to obtain undersize products with the particle size smaller than 40mm and oversize products with the particle size larger than 40mm, performing magnetic separation treatment on the oversize products, separating metal garbage from the garbage under the action of magnetic force, performing air separation treatment on the residual garbage after magnetic separation, and performing air separation by utilizing the weight difference among the components to obtain medium materials containing organic components;
(4) performing secondary screening treatment on the primary screening undersize obtained in the step (3) to obtain undersize with the particle size smaller than 8mm and oversize with the particle size larger than 8mm, and collecting the undersize and then performing landfill treatment;
(5) and (3) crushing the medium material obtained in the step (2) and the secondary screening oversize material obtained in the step (3) to obtain a crushed material with the particle size of less than 20mm, and carrying out separation treatment on the crushed material by using stems and leaves and glass to obtain the residual organic garbage without the stems and leaves containing cellulose substances and glass.
Preferably, in the two-phase anaerobic fermentation treatment process, the composite bacterial liquid comprises trichoderma and bacillus. Adding composite bacteria consisting of trichoderma and bacillus in a bacterial quantity ratio of 1: 1, and concentrating the bacterial liquidDegree of 4.5X 108CFU/mL, the microbial community can degrade cellulose and lignin contained in the corn straws and the organic garbage, and the microbial community and acid-producing bacteria and methanogen have synergistic effect, so that the degradation rate of the organic garbage can be improved, the system stability is effectively improved, and the mixed material is sent to a hydrolysis acidification tank.
Preferably, the temperature of the hydrolysis acidification reaction is 35-38 ℃, and the pH value is 6.5-7.8; the temperature of the anaerobic fermentation reaction is 55-58 ℃, and the pH value is 7.0-7.5.
In the two-phase anaerobic fermentation treatment process, hydrolysis acidification reaction is carried out under the condition of medium temperature (35-38 ℃), and methanogenesis reaction is carried out under the condition of high temperature (55-58 ℃), wherein the medium temperature-high temperature system has the highest methane yield and VS removal rate, and the richness, diversity, uniformity and dominance degree of the bacterial community structure are also the best.
In the two-phase anaerobic fermentation treatment process, hydrolysis acidification reaction is carried out under the condition that the pH value is 6.5-7.8, methane production reaction is carried out under the condition that the pH value is 7.0-7.5, the hydrolysis acidification zone mainly carries out acetic acid and butyric acid type fermentation in the pH range, a more favorable substrate can be provided for the subsequent methane production process, wet garbage has higher hydrolysis and acidification rates, the VFA yield is 2 times of that of the garbage without pH adjustment, the methane production amount is sensitive to the pH value, and the methane production amount is the highest when the pH value is 7.
Preferably, in the straw pretreatment, KOH and Ca (OH) are adopted in the blending treatment2Performing combined pretreatment; the VS ratio of the mixture of the pretreated straws and the organic garbage is 1: 3-5.
KOH and Ca (OH)2The combined pretreatment can effectively remove lignin in the corn straws, destroy the wood fiber structure of the straws, increase the accessibility of the matrix, facilitate the hydrolysis of enzyme and improve the conversion rate of anaerobic fermentation.
The treated straw and the organic garbage are mixed according to the mixing ratio of 1: 3-5, the mixing ratio of the straw and the organic garbage can be adjusted to the optimal C/N ratio of 15-20 on the characteristic of raw materials, and the matching of acid production rate and methane production rate is adjusted on the fermentation dynamics, so that the fermentation process is more stable.
Preferably, part of digestion liquid of anaerobic fermentation reaction in the methanogenesis area directly flows back to the hydrolysis acidification area for fermentation, and the backflow part accounts for 20-30% of the total volume of the digestion liquid; and carrying out solid-liquid separation treatment on the residual digestive juice to separate biogas residues and biogas slurry, drying and granulating the crushed biogas residues, and carrying out sewage treatment on the biogas slurry.
The digestion solution which is not subjected to solid-liquid separation is recycled to the hydrolysis acidification tank to adjust the solid content, so that the discharge of the digestion solution can be reduced, the pH value of a hydrolysis acidification zone is in a range suitable for the survival of flora, the COD removal effect is better, and the methane content is higher when the recycling proportion is 20-30%.
In the prior art, due to incomplete classification, when wet garbage in villages and towns is treated by using a conventional process, only simple pre-sorting is carried out, sorted materials are rough, the sorting rate and the purity of the wet garbage are not high, and impurities with different components have great influence on the subsequent anaerobic fermentation treatment and the recycling effect of the wet garbage; courtyard organic wastes such as leaves are often mixed in the existing wet garbage of villages and towns, cellulose, hemicellulose, lignin and other refractory components in the wet garbage are lack of separation and treatment on cellulose components in the wet garbage, and the garbage often contains a large amount of cellulose, lignin and other substances for inhibiting anaerobic fermentation, so that the efficiency of a later-stage anaerobic fermentation process is adversely affected; the wet garbage in villages and towns usually has high water content and organic matter content, C, N is unbalanced, the wet garbage is extremely easy to hydrolyze rapidly in two-phase anaerobic fermentation, and a large amount of volatile fatty acid is accumulated, so that the system is over-acidified, and the activity of methanogenic bacteria is inhibited. The straw is added into the wet garbage, so that the alkaline buffer capacity of the fermentation system can be effectively improved, and the C/N ratio and the nutrient components of the system can be adjusted, so that the efficiency and the stability of the fermentation system are improved.
The invention adopts the directional sorting treatment technology to sort the garbage with different components in the wet garbage, separates the organic components capable of anaerobic fermentation, removes the substances difficult to biodegrade in the wet garbage, and utilizes cellulose in the sorted organic garbage to degrade the cellulose substances, thereby improving the anaerobic fermentation efficiency of the organic garbage and stabilizing the fermentation process; the straws are pretreated, wet garbage is reasonably mixed, the optimal C/N ratio is adjusted, and the anaerobic conversion efficiency of organic matters is improved; the anaerobic reaction process is decomposed into an independent hydrolysis acidogenesis stage and a methane production stage which are connected in series in a certain form, so that a complete anaerobic fermentation process is realized, the effects of hydrolysis acidification and methanation are optimized simultaneously, and the processing capacity of the system and the operation stability of the reactor are greatly improved.
The invention also provides a village and town wet garbage reinforced two-phase anaerobic treatment system, which comprises a wet garbage pretreatment system, a straw pretreatment system, a two-phase anaerobic fermentation system and a sewage treatment and reflux system;
the wet garbage pretreatment system comprises a sorting table, a pre-dehydration device, a water-oil separation device, a primary drum sieve, a magnetic separator, a winnowing machine, an electrostatic separation machine, a secondary drum sieve, a hammer impact crusher, a stem-leaf separation machine and a glass separation machine, wherein the primary drum sieve and the secondary drum sieve are respectively provided with an oversize material discharge port and an undersize material discharge port, the magnetic separator is provided with a magnetic material discharge port and a nonmagnetic material discharge port, and the winnowing machine is provided with a light material discharge port, a medium material discharge port and a primary heavy material discharge port. Furthermore, the wet garbage pretreatment system comprises a sorting table, a pre-dehydration device, a primary drum screen, a secondary drum screen, a hammer type impact crusher, a stem and leaf separator and a glass separator which are sequentially connected, wherein a screen underflow discharge port of the primary drum screen is connected with a feed port of the secondary drum screen, a screen overflow discharge port of the primary drum screen is connected with a feed port of a magnetic separator, a nonmagnetic material discharge port of the magnetic separator is connected with a feed port of a winnower, a medium material discharge port of the winnower and a screen overflow discharge port of the secondary drum screen are both connected with a feed port of the hammer type impact crusher, and a light material discharge port of the winnower is connected with a feed port of an electrostatic separator;
the straw pretreatment system comprises a double-roller crusher, a blending tank and a first dryer which are connected in sequence;
the two-phase anaerobic fermentation system comprises a hydrolysis acidification tank and a methane production tank which are communicated with each other, and the discharge ports of the first dryer and the glass separator are connected with the feed port of the hydrolysis acidification tank;
the sewage treatment and reflux system comprises a regulating tank, an air flotation tank, a high-load aeration tank, a two-stage nitrification-denitrification tank, a concentration tank, a secondary sedimentation tank and a biological coagulation reaction tank.
The hydrolysis acidification tank comprises a first controller, a mechanical stirring device, a pH sensor and a temperature sensor which are arranged in the tank, a neutralization liquid tank connected with the tank through a water pump, and a first liquid inlet system arranged at the top of the tank; the side wall of the tank body is provided with an acidizing fluid sampling port, the top of the tank body is provided with an exhaust port, and the bottom of the tank body is provided with a slag discharge port; the first controller is connected with the mechanical stirring device, the pH sensor, the temperature sensor and the neutralization liquid tank;
the methane production tank comprises a second controller, a mechanical stirring device, a pH sensor and a temperature sensor which are arranged in the tank, and a second liquid inlet system arranged at the top of the tank; the second controller is connected with the mechanical stirring device, the pH sensor and the temperature sensor; the side wall of the tank body is provided with a digestive juice sampling port and a discharge port, the discharge port of the methane production tank is respectively connected with a horizontal screw centrifuge and a return pipe communicated with the methane production tank through a pipeline with a flow dividing part, the bottom of the methane production tank is provided with a slag discharge port, the top of the methane production tank is provided with a methane gas outlet, and the methane gas outlet is sequentially connected with a desulfurization and dehydration device and a methane tank;
and a communicating pipeline is arranged between the exhaust port of the hydrolysis acidification tank and the methane production pipe, and the acidification discharge port of the hydrolysis acidification tank is connected with the methane production tank through a metering pump and a circulating pipe.
Further, the system also comprises a biogas residue crusher, a second dryer and a granulator which are connected in sequence; the horizontal screw centrifuge is provided with a biogas slurry outlet and a biogas residue outlet, the biogas slurry outlet is connected with the inlet of the adjusting tank, and the biogas residue outlet is connected with the inlet of the biogas residue crusher.
The pre-dehydration device is a variable-diameter spiral liquid removal machine, the 2 theta value of the spiral cone angle is 5-8 degrees, an infrared heating device is arranged in the device, and a pressure adjusting device is arranged at an outlet.
Preferably:
(1) the pressure adjusting device is arranged at the outlet of the pre-dehydration device or the machine head with a smaller outlet is arranged, and the pressure build-up of the flow field in the machine barrel is realized by improving the blocking effect at the outlet.
(2) In the pre-dewatering device, the spiral cone angle is enlarged to 5-8 degrees, and the solid-liquid separation efficiency can be improved by increasing the spiral inner diameter cone angle to reduce the cross section of the flow channel.
(3) The pre-dehydration device is internally provided with an infrared heating device, which is beneficial to oil recovery and organic food residue hydrolysis, and oily wastewater is separated through mechanical extrusion after heating, so that the water content of garbage is reduced, the treatment efficiency of subsequent links on wet garbage is improved, the continuous and stable degradation of the wet garbage is ensured, and the quality of fermentation products can be improved.
(4) The discharge port of the methane production tank is positioned on the side wall of the methane production tank, and a valve is arranged at the discharge port of the methane production tank. The valve is connected with the solid-liquid separation device and the communicated return pipe through pipelines with flow dividing parts, 25% of digestive juice is recycled for fermentation, 75% of digestive juice enters a horizontal screw centrifuge for solid-liquid separation, the digestive juice which is not subjected to solid-liquid separation is recycled into a hydrolysis acidification tank to adjust the solid content, the discharge of the digestive juice can be reduced, the pH value of a hydrolysis acidification zone is in a range suitable for the survival of flora, the COD removal effect is better, and the methane content is higher when the recycling proportion is 25%.
(5) In the two-phase anaerobic reactor, a temperature sensor in a hydrolysis acidification tank and a temperature sensor in a methane production tank are both connected with a temperature controller to synchronously detect the temperature of materials in the tanks, heat insulation layers are arranged on the outer surfaces of the hydrolysis acidification tank and the methane production tank, a circulating hot water pipe is arranged between the heat insulation layers and a device shell and connected with the temperature controller, and the temperature controller can independently control the temperature of circulating water in the two tanks, so that the optimal reaction temperature in the hydrolysis acidification tank is kept at 35-38 ℃, and the optimal reaction temperature in the methane production tank is kept at 55-58 ℃. The hydrolysis acidification reaction is carried out under the condition of medium temperature (35-38 ℃), the methane production reaction is carried out under the condition of high temperature (55-58 ℃), the methane yield and VS removal rate in the medium temperature-high temperature system are highest, and the richness, diversity, uniformity and dominance of the bacterial community structure are also optimal.
(6) A pH sensor is arranged in the hydrolysis acidification tank, a neutralization liquid tank is arranged on the right side of the tank body and is connected with the tank body through a water pump, and CaCO is filled in the neutralization liquid tank3Solution, mechanical stirring device, pThe H sensor and the neutralization liquid tank are connected with a controller and are used for synchronously detecting the pH value of materials in the tank, adjusting the pH value in real time and controlling the stirring of the materials, and the pH value is controlled to be 6.5-7.8; the methane production tank is internally provided with a mechanical stirring device 15 and a pH sensor which are connected with a controller and used for synchronously detecting the pH value of materials in the tank and controlling the stirring of the materials, wherein the pH value is controlled to be 7.0-7.5; when the two-phase anaerobic combined reactor is used for treating wet garbage in villages and towns, hydrolytic acidification reaction is carried out under the condition that the pH value is 6.5-7.8, methane production reaction is carried out under the condition that the pH value is 7.0-7.5, acetic acid and butyric acid type fermentation is mainly carried out in a hydrolytic acidification area in the pH range, a more favorable substrate can be provided for the subsequent methane production process, the wet garbage has higher hydrolytic and acidification rates, the VFA yield is 2 times of that of the wet garbage without pH adjustment, the methane production amount is sensitive to the pH value, and the methane production amount is highest when the pH value is 7.
Has the advantages that:
(1) the invention provides a reinforced two-phase anaerobic fermentation treatment system and method for village and town wet garbage.
(2) In view of the difficult biodegradability of cellulose, hemicellulose and lignin substances in the wet garbage, the cellulose, hemicellulose and lignin substances are difficult to degrade in the anaerobic fermentation process and can inhibit the anaerobic fermentation of other components; when wet garbage is sorted, cellulose-containing substances such as stems and leaves contained in the wet garbage are sorted out by a stem and leaf sorting machine, are ground properly by a machine, and are subjected to secondary fermentation or natural decomposition by a biological strain technology to form an organic fertilizer for utilization.
(3) The wet garbage has low C/N of about 10, and the straw has high C/N of about 40; according to the invention, by combining the actual conditions of villages and small towns, after the wet garbage and the corn straws are reasonably proportioned, the optimal C/N ratio can be adjusted to 15-20 on the characteristics of raw materials, so that microorganisms can obtain sufficient carbon sources and nitrogen sources, sufficient nutrient substances can be provided, the problem of insufficient nutrient components of single substances is solved, the multi-raw-material mixed fermentation has the advantages of diluting toxic compounds and enhancing the synergistic effect of microorganisms, the anaerobic conversion efficiency of organic matters is further improved, the raw materials can be obtained locally, and the transportation cost is saved.
(4) The anaerobic reaction process is decomposed into a hydrolysis acidogenesis stage and a methanogenesis stage, the two stages are separated, and two reactors are adopted, so that the mutual inhibition between microorganisms or the inhibition of metabolic products on the activity of the microorganisms in the reaction process is avoided, the fermentation efficiency is improved, and a proper growth environment is provided for acidogenic bacteria and methanogenic bacteria. The acid-producing phase and the methane-producing phase which are successfully operated are two independent processing units, can respectively optimize operation parameters, and are connected in series in a certain form, so that a complete anaerobic fermentation process is realized; because the operating parameters of the two units can be independently controlled, the effects of hydrolytic acidification and methanation can be simultaneously optimized, and the processing capacity of the system and the operating stability of the reactor are greatly improved.
(5) The reinforced two-phase anaerobic treatment system and method for the wet garbage in the villages and the towns have good treatment effect and good integration degree, and greatly improve the resource utilization rate.
Drawings
FIG. 1 is a schematic diagram of a two-phase anaerobic enhanced process for treating wet garbage in villages and towns according to the present invention;
FIG. 2 is a schematic view of a two-phase anaerobic enhanced village and town wet waste treatment system of the present invention;
FIG. 3 is a schematic diagram of a two-phase anaerobic fermentation reactor of the present invention.
Wherein, 1, a hydrolysis acidification tank; 2. a feed inlet; 3. a slag discharge port; 4. an acidified liquid sampling port; 5. a mechanical stirring device; 6. a temperature sensor; a pH sensor; 8. a first liquid inlet system; 9. acidifying the discharge hole; 10. a gas delivery pipe; 11. a methane generating tank; 12. a discharge port; 13. a slag discharge port; 14. a digestive juice sampling port; 15. a mechanical stirring device; 16. a temperature sensor; a pH sensor; 18. a second liquid inlet system; 19. an activated carbon adsorption desulfurization, condensation dehydration and molecular sieve pressure swing adsorption device; 20. a gas flow meter; 21. a methane outlet; 22. a metering pump; 23. a second controller; 24. a first controller; 25. a temperature controller; 26. a neutralization liquid tank; 27. a manual sorting table; 28. a variable diameter screw liquid remover; 29. a first-stage drum screen; 30. a secondary drum sieve; 31. a magnetic separator; 32. a winnowing machine; 33. an electrostatic classifier; 34. a hammer impact crusher; 35. a stem and leaf separator; 36. a glass sorter; 37. a double-roll crusher; 38. a blending tank; 39. a first dryer; 40. a two-phase anaerobic fermentation reactor; 41. a horizontal screw centrifuge; 42. a biogas residue crusher; 43. a second dryer; 44. and (4) a granulator.
Detailed Description
The present invention will be described in further detail with reference to examples.
Example 1:
as shown in fig. 1, a schematic diagram of a method for enhancing two-phase anaerobic fermentation of wet garbage in villages and towns according to the present invention includes: wet garbage pretreatment, corn straw pretreatment, two-phase anaerobic fermentation treatment, sewage treatment and reflux treatment.
The wet garbage pretreatment process comprises the steps of manually sorting out large interfering objects such as plastics, glass and metals from wet garbage, then carrying out pre-dehydration, screening the wet garbage with the pre-dehydrated moisture content of the wet garbage, sorting the components contained in the garbage with different particle sizes by adopting a directional sorting treatment technology, sorting out the metals, plastics, fibers and inorganic substances in the wet garbage through magnetic separation, air separation and electrostatic sorting, and carrying out corresponding treatment and recovery; the primarily sorted organic garbage falls into a crushing device, and the organic garbage is crushed into particles of 20 mm; opening a discharge port of the crushing device, enabling organic garbage particles to fall into a stem and leaf sorting machine to sort plant stems and leaves, and then falling into a glass sorting machine to sort glass, so as to obtain organic garbage with high purity.
Wherein, the wet garbage pretreatment specifically comprises the following steps:
s1, the wet garbage is firstly sent to a manual sorting table, large interfering objects such as plastics, glass, metal and the like in the wet garbage are manually and primarily sorted out, and the residual wet garbage is sent to a solid-liquid separation device through a conveyor belt.
S2, enabling the wet garbage to enter a pre-dehydration device, internally arranging an infrared heating device to heat the wet garbage, enabling the heating temperature to be 45-50 ℃, setting the radiation power to be 1kW, enabling the infrared heating wet garbage to be beneficial to oil recovery and organic food residue hydrolysis, extruding and separating oily wastewater from the heated wet garbage through a spiral machine, reducing the moisture content of the garbage, improving the sorting efficiency of a subsequent screening link on the wet garbage, improving the quality of a fermentation product, discharging the garbage with the moisture content of less than or equal to 75% from a solid discharging end, enabling the oily wastewater to flow out from a liquid outlet, carrying out impurity separation through a pipeline filter, conveying the oily wastewater to an oil-water separation device, processing the oily wastewater after oil extraction to prepare industrial oil, and enabling the wastewater to.
S3, the pre-dehydrated garbage enters a primary drum screen to screen the garbage, the screening aperture is 40mm, the rotating speed is 15-20 r/min, the garbage particles with the particle size larger than 40mm are used as oversize materials of the primary drum screen and are discharged from a discharge port to be sent to a magnetic separator, separating the metallic garbage from the garbage under the action of magnetic force of a magnetic separator, then feeding the metallic garbage into a winnowing machine, utilizing the weight difference among components of a primary screening oversize material, winnowing, crushing the sorted medium materials (including organic components, plant stems and leaves and glass) in a hammer type impact crusher, collecting the heavier materials in a heavy garbage collecting tank, wherein the main component is inorganic matter, the garbage can be buried, lighter materials (including plastics and fibers) are subjected to electrostatic separation to separate the plastics and the fibers, and garbage particles with the particle size of less than 40mm are collected by a collecting tank as undersize materials and then enter a secondary screening process.
And S4, feeding undersize products of the first-stage drum screen into a second-stage drum screen by a belt conveyor, wherein screen holes of the second-stage drum screen are 8mm, the rotating speed is 20-22 r/min, garbage particles with the particle size larger than 8mm are discharged from a discharge hole to be sent to a hammer type impact crusher for crushing as oversize products of the second-stage drum screen, and the garbage particles with the particle size smaller than 8mm are collected by a collecting tank and then can be buried.
S5, feeding the winnowed medium materials and oversize materials of a secondary drum screen into a hammer type impact crusher, feeding garbage into the crusher from an upper feeding port, crushing the garbage by high-speed impact of a hammer, crushing the garbage into particles with the particle size smaller than 20mm, arranging a screen plate on the lower portion of a rotor of the hammer type impact crusher, enabling the screen holes on the screen plate to be uniformly distributed, enabling the size of each screen hole to be 20mm, discharging the particles smaller than the size of each screen hole in the crushed materials through the screen plate, blocking the coarse particles larger than the size of each screen hole on the screen plate, continuously beating and grinding the particles by the hammer, finally discharging the particles out of the crusher through the screen plate, and conveying the particles to a stem and leaf.
S6, sorting the stems and leaves in the stem and leaf sorting machine according to the characteristic that the color depth of the garbage particles and the stems and leaves contained in the garbage particles is different from the contrast of the light sensation. The garbage in the hopper is conveyed into a channel by a vibration feeder to be arranged in a single row and sequentially falls at the speed of 3.5m/s, a photoelectric detection system optically detects garbage particles through light rays refracted by a background plate under the irradiation of a fluorescent lamp, a CCD sensor detects and analyzes the garbage particles, the color of detected stem leaves is compared with the contrast color of the background, when substances with the same color as that of the stem leaves are captured, optical signals of the stem leaves are immediately converted into electric signals, a judgment processing circuit analyzes and processes the signals, a high-speed electromagnetic valve is instructed to start a high-pressure air flow nozzle, the pressure is 0.4-0.6 MPa, high-speed jet air flow blows the stem leaves into a collecting tank, a lifter lifts the stem leaves into a secondary feeding hopper to perform secondary color sorting, and the residual garbage is conveyed to a glass sorting machine through a discharge port.
S7, enabling the garbage to enter a feeder from a feed hopper and convey forwards, enabling free falling bodies of the garbage to enter a glass chute of an optical sorting machine, recording and analyzing the falling garbage by a high-resolution camera, accurately blowing the glass to a glass collecting tank by a compressed air valve according to a set program, and conveying the residual organic garbage to a batching tank.
S8, placing stem and leaf substances sorted by a stem and leaf sorting machine and fiber substances sorted by static electricity in a fermentation tank, adding a compound microbial inoculum comprising fungi, actinomycetes, saccharomycetes and a bacterial compound beneficial bacterium group into the fermentation tank, controlling the temperature to be 15-17 ℃, the pH to be 6-8 and the humidity to be 55-65%, stacking for 24h, then starting to heat up, heating to 50-70 ℃ after 48h, uniformly distributing the bacteria by using a turnover planer in an untimely manner in the process, turnover planing for heat dissipation, successfully fermenting for 8-16 d, converting the treated fiber garbage into an organic fertilizer and a soil matrix which are easy to be absorbed by soil and plants, and further processing according to the requirements of different plants, wherein the produced fertilizer can be used in multiple fields of urban greening, nursery production, breeding and cultivation.
The corn stalk pretreatment is to crush the corn stalk into particles smaller than 5mm, mix 0.5% KOH and 2% Ca (OH)2Hermetically storing for 7 days at 38 ℃, mixing the treated corn straws and the organic garbage according to a mixing ratio of 1: 4, and adjusting the optimal C/N ratio to 15-20 on the characteristics of raw materials; adding composite bacteria composed of Trichoderma and Bacillus in a ratio of 1: 1, wherein the concentration of the bacteria liquid is 4.5 × 107CFU/mL。
The corn straw pretreatment specifically comprises the following steps:
s1, pretreating corn stalks, crushing the stalks into particles smaller than 5mm by using a double-roller crusher, conveying the crushed stalks to a blending tank for blending, and mixing 0.5% of KOH and 2% of Ca (OH)2Sealed storage at 38 ℃ for 7d, KOH and Ca (OH)2The combined pretreatment can effectively remove lignin in the corn straws, destroy the wood fiber structure of the corn straws, increase the accessibility of the matrix, facilitate the hydrolysis of enzyme and improve the anaerobic fermentation conversion rate.
S2, mixing the pretreated corn straws and the organic garbage according to a mixing ratio of 1: 4, adjusting the optimal C/N ratio to 15-20 on the characteristics of raw materials, adjusting the matching of acid production rate and methane production rate on the fermentation kinetics to stabilize the fermentation process, adding composite bacteria consisting of trichoderma and bacillus, wherein the bacteria quantity ratio is 1: 1, and the concentration of the bacteria liquid is 4.5 multiplied by 108CFU/mL, the microbial community can degrade cellulose and lignin contained in the corn straws and the organic garbage, and the microbial community and acid-producing bacteria and methanogen have synergistic effect, so that the degradation rate of the organic garbage can be improved, the system stability is effectively improved, and the mixed material is sent to a hydrolysis acidification tank.
The two-phase anaerobic fermentation treatment is to put the prepared materials into a hydrolysis acidification zone and feed the materials at a medium temperature (35-38℃)Performing hydrolysis acidification reaction, pumping hydrolysis acidification bacteria liquid into a first liquid inlet pipe through a water pump, spraying the hydrolysis acidification bacteria liquid to the surface of the organic material through a first atomizing nozzle, wherein the hydrolysis acidification liquid contains a large amount of acid-producing bacteria which are mixed bacteria of clostridium, acetic acid bacteria and rat spore bacteria, the bacteria amount ratio is 1: 1, and the concentration of the bacteria liquid is 5.5 multiplied by 108CFU/mL, the acidification period is 4d, the formed hydrolysis acidification liquid enters a methanogenesis area, anaerobic fermentation reaction is carried out at high temperature (55-58 ℃), methanogenesis bacteria liquid is pumped into a second liquid inlet pipe by a water pump and sprayed to the surface of a material by a second atomization nozzle, the methanogenesis bacteria liquid contains a large amount of methanogenesis microorganisms which are mixed bacteria of methanogenesis bacillus, methanothermobacter and methanosarcina, the bacteria amount ratio is 1: 1, and the concentration of the microorganism bacteria liquid is 5.5 multiplied by 108CFU/mL; in the anaerobic fermentation period of 10d, the generated biogas is sequentially subjected to activated carbon adsorption desulfurization, condensation dehydration and molecular sieve pressure swing adsorption to remove CO2And after impurities are mixed, the mixture is sent into a methane tank for storage, can be used for power generation or used as fuel for heat supply, 25 percent of digestion solution flows back to a hydrolysis acidification tank to adjust the solid content, 75 percent of digestion solution is sent into a horizontal screw centrifuge through a water outlet overflow pipe for solid-liquid separation, methane slag and methane liquid are separated, the methane slag is crushed by a methane slag crusher and then is dried and granulated, and the methane liquid is sent to a sewage collection box.
The two-phase anaerobic fermentation treatment specifically comprises the following steps:
s1, stirring the materials by a mechanical stirrer in a hydrolysis acidification tank at a speed of 50r/min for 20min/h, arranging a heat-insulating layer in the tank, arranging a circulating hot water layer between the heat-insulating layer and the shell of the device, keeping the temperature of the acidification process at 35-38 ℃ by a temperature controller, and arranging CaCO in the hydrolysis acidification tank3The neutralizing liquid tank of the solution is connected with the tank through a water pump, the pH in the tank is adjusted to be controlled to be 6.5-7.8, the hydrolysis acidification bacterial liquid is sprayed on the material through an atomizing nozzle, the hydrolysis acidification liquid contains a large amount of acid-producing bacteria which are mixed bacteria of clostridium, acetic acid bacteria and rat spore bacteria, the bacterial quantity ratio is 1: 1, and the concentration of the bacterial liquid is 5.5 multiplied by 108CFU/mL, acidification period 4 d.
S2, feeding the hydrolyzed and acidified solution into a methane-producing tank through a feeding pipe for digestion, and atomizing the methane-producing bacteria solutionThe spray head sprays the mixture onto the material, the methanogen liquid contains a large amount of methanogen which is a mixed bacterium of methanobacterium, methanothermobacter and methanosarcina, the ratio of the amount of the methanogen to the amount of the methanogen is 1: 1, and the concentration of the microbial liquid is 5.5 multiplied by 108A CFU/mL, wherein a stirrer is also arranged in the methane production tank, the rotating speed of the stirrer is 50r/min, the stirring time is controlled to be 20min/h, the pH value is controlled to be 7.0-7.5, a heat insulation layer is arranged in the tank, a circulating hot water layer is arranged between the heat insulation layer and the shell of the device, the temperature is controlled to be 55-58 ℃, and the digestion period is 10 d;
s3, refluxing 25% of digestion liquid in a methane production area to a hydrolysis acidification tank to adjust the solid content, relieving the VFA inhibition effect of an acidification phase, improving the methane production performance of the methane phase, feeding 75% of digestion liquid to a horizontal screw centrifuge for solid-liquid separation through a water outlet overflow pipe, separating biogas residue and biogas slurry, crushing the biogas residue through a biogas residue crusher, drying and granulating the biogas slurry, feeding the biogas slurry to a sewage collection tank, and removing CO from the biogas through activated carbon adsorption desulfurization, condensation dehydration and molecular sieve pressure swing adsorption in turn2And sending the impurities into a methane tank for storage.
The sewage treatment and reflux treatment are implemented by that the treated sewage is derived from sewage separated by an oil-water separator, biogas slurry separated by a horizontal screw centrifuge, percolate of each garbage treatment unit, daily drainage of each workshop, domestic sewage and the like, the sewage is treated by adopting a coagulation air flotation-high load aeration tank-two-stage A/O-MBR process, anaerobic biogas slurry is conveyed into a regulating tank, then the anaerobic biogas slurry is pumped into a subsequent air flotation treatment unit by a water pump, a certain amount of flocculating agent and coagulant are added into the sewage before the sewage enters the air flotation unit, so that the effect of removing suspended matters and grease can be achieved, colloid and partial phosphate are removed, the effluent of the air flotation unit is pumped into a high load aeration tank, most of organic matters are removed, then the effluent of the air flotation unit enters a secondary sedimentation tank for mud-water separation, the effluent of the secondary sedimentation tank automatically flows into a two-stage nitrification-denitrification tank to remove, and finally, performing sludge-water separation by a built-in MBR (membrane bioreactor) membrane assembly, reusing the effluent for a two-phase anaerobic system and a straw pretreatment system to adjust the humidity, refluxing a part of sludge to a front-end first-stage denitrification tank, discharging a part of sludge as residual sludge to a concentration tank, discharging sludge in an air flotation tank and a secondary sedimentation tank to the concentration tank, concentrating the sludge, then entering a biological coagulation reaction tank for deep dehydration, refluxing the generated clear liquid to the first-stage denitrification tank, and refluxing the generated slag cake and sludge cake to a hydrolysis system.
Example 2:
fig. 2 shows a reinforced two-phase anaerobic treatment system for wet garbage in villages and towns, which consists of a wet garbage pretreatment system, a corn straw pretreatment system, a reinforced two-phase anaerobic fermentation system and a sewage treatment and reflux system.
Wherein, wet rubbish pretreatment systems is used for sorting, screening, breakage, dehydration in advance to wet rubbish, and this system includes: the device comprises a discharge hopper, a manual sorting table 27, a pre-dewatering device, a water-oil separation device, a primary rotary screen 29, a magnetic separator 31, a winnowing machine 32, an electrostatic sorting machine 33, a secondary rotary screen 30, a hammer impact crusher 34, a stem-leaf sorting machine 35 and a glass sorting machine 36, wherein the primary rotary screen and the secondary rotary screen are respectively provided with an oversize material discharge port and an undersize material discharge port, the magnetic separator is provided with a magnetic material discharge port and a non-magnetic material discharge port, and the winnowing machine is provided with a light material discharge port, a medium material discharge port and a primary heavy material discharge port.
The device comprises a manual sorting table, a pre-dewatering device, a first-stage rotary screen, a second-stage rotary screen, a hammer type impact crusher, a stem and leaf sorting machine and a glass sorting machine which are sequentially connected, wherein a screen underflow discharge port of the first-stage rotary screen is connected with a feed port of the second-stage rotary screen, a screen overflow discharge port of the first-stage rotary screen is connected with a feed port of a magnetic separator, a nonmagnetic material discharge port of the magnetic separator is connected with a feed port of a winnowing machine, a medium material discharge port of the winnowing machine and a screen overflow discharge port of the second-stage rotary screen are both connected with a feed port of the hammer type impact crusher, and a light material discharge port of the winnowing machine is connected with a.
The manual sorting table 27 is composed of plate chain conveyors, the width of the frame is 1.3m, the moving speed of a belt is not more than 0.3m/s, a feeding hole and a discharging hole are formed in the manual sorting table, wet garbage enters the manual sorting table through the feeding hole, rubber, metal, glass and the like in the garbage are sorted out through manual sorting, the rest wet garbage is conveyed out through the discharging hole, a conveying belt is arranged on the lower portion of the discharging hole, and the conveying belt can convey the wet garbage to a solid-liquid separation device.
The pre-dehydration device is a variable diameter screw liquid removing machine 28 which mainly comprises a variable diameter screw, a motor, a filter cylinder and a machine head, wherein the device is provided with a feed inlet, a discharge outlet and a liquid outlet, an infrared heating device is arranged in the device, the heating temperature is 50 ℃, the radiation power is set to be 1kW, wet garbage is added into a hopper from the feed inlet, the motor drives the screw to rotate, materials are conveyed forwards under the combined action of the screw, the filter cylinder and the machine head, the extrusion liquid removal is realized, the rotating speed of the screw is 20rpm, the pre-dehydrated garbage is discharged from the discharge outlet and falls into a conveying belt to be conveyed to a No. 1 rotary screen, namely a first-stage rotary screen 29.
The barrel of No. 1 drum sieve is the slope and places, and the barrel is covered by dust-proof sealing cover, and the high-end feed inlet that is equipped with of slope cylinder, slope cylinder low side are equipped with oversize thing discharge gate, are equipped with the speed reducer in the section of thick bamboo, and it is rotatory with certain rotational speed to adjust the barrel, and the cylinder rotational speed is 15 ~ 20r/min, and slope cylinder lower part is equipped with undersize thing collecting vat, and the last sieve hole evenly distributed of slope cylinder stack shell, the sieve mesh diameter is 40mm, and cylinder inclination is 7 ~ 10, and wet rubbish is after the drum screening, and oversize thing is delivered to the magnet separator by the conveyer belt that sets up in oversize thing discharge gate lower part, and undersize thing is collected and is delivered to No. 2 drum sieve.
The magnetic separator 31 is a cylindrical magnetic separator and consists of a rotary multi-pole magnetic system and an external non-magnetic-conductive cylinder, a garbage feeding port is arranged at the upper part of the machine body, a metal collecting box is arranged at the lower left part, a garbage discharging port is arranged at the lower right part, and the discharging port is connected with a garbage collecting tank; when wet garbage passes through the cylindrical magnetic separator, under the combined action of magnetic force and mechanical force, metal is adsorbed on the belt and falls into the metal collection box, the wet garbage after the metal is removed enters the collection tank, a conveying belt is arranged below the collection tank, and the conveying belt is connected with the winnowing machine.
The winnowing machine 32 comprises a frame, a conveying belt rotatably connected to the upper end of the frame, a feeding hole positioned at the lower end of the conveying belt, an air suction pipeline positioned at the high end of the conveying belt, and a fan positioned on the air suction pipeline, wherein a heavy garbage collecting tank is arranged on the right side of the air blower, and a light garbage collecting tank is arranged on the right side of the heavy garbage collecting tank. Wet garbage is conveyed into a feeding hole through a conveying belt, heavier materials fall into a heavy garbage collecting tank, and the heavy garbage collecting tank can be buried as the main component of inorganic matters; the lighter material falls into a light garbage collection tank, such as plastic, fiber, etc. The air speed of the air blower is 1.6-2.1 m/s.
The drum body of the No. 2 drum screen is obliquely placed, the drum body is covered by a dustproof sealing cover, a feed inlet is formed in the high end of the inclined drum, an oversize material discharge port is formed in the low end of the inclined drum, a speed reducer is arranged in the drum, the drum body is adjusted to rotate at a certain rotating speed, an undersize material collecting tank is formed in the lower portion of the inclined drum, screen holes in the drum body of the inclined drum are uniformly distributed, the diameter of each screen hole is 8mm, the rotating speed of the drum is 20-22 r/min, and the inclination angle of the; after undersize of the No. 1 drum screen is screened by a drum, oversize and garbage winnowed from the winnowing machine enter a hammer type impact crusher together; the undersize is collected by an undersize collecting tank and can be landfilled.
The hammer impact crusher 34 is composed of a hammer, a rotating shaft, a disc, a bearing, an impact plate, a sieve plate and the like, wherein the hammer is movably hinged on a rotary table of a rotor, the rotating shaft and the rotary table are supported on rolling bearing seats at two sides of a shell, and a motor drives the rotor to rotate at a high speed in a crushing cavity. The material is in the feeder inlet machine from upper portion feed inlet, receive the high-speed impact of hammer and breakage, it is less than 20mm to break into the particle diameter with rubbish, hammer counterattack breaker is in the rotor lower part, be equipped with the sieve, sieve mesh evenly distributed on the sieve, sieve mesh size 20mm, the particle fraction that is less than sieve mesh size in the crushing material is discharged through the sieve, the coarse grain fraction that is greater than sieve mesh size keeps continuing to receive the strike and the grinding of hammer on the sieve, outside through the sieve discharge machine at last, send to glass-sorting machine by the conveyer belt.
The stem leaf sorting machine 35 is a photoelectric color sorting machine mainly composed of a CCD sensor, a high-speed magnetic valve, a nozzle, a discharging mechanism and the like, firstly, garbage in a hopper is sent into a channel by a vibration feeder to be arranged in a single row and fall at the speed of 3.5m/s in sequence, a photoelectric detection system optically detects garbage particles by light rays refracted by a background plate under the irradiation of a fluorescent lamp, the garbage particles are detected and analyzed by the CCD sensor, the color of detected stem leaves is compared with the contrast color of the background, when substances with the same color as the stem leaves are captured, optical signals are immediately converted into electric signals, then after the signals are analyzed and processed by a judgment processing circuit, pulsed compressed air sprayed out by the high-speed electromagnetic valve control nozzle blows the stem leaves away from a normal moving track, falls into a collecting tank and is lifted into a secondary feeding hopper by a lifter to perform secondary color sorting, and the residual garbage is conveyed to the glass sorting machine from a discharge port. The photoelectric color selector is provided with a material returning device such as a lifter, can automatically reselect stem leaves with low precision after primary color selection, equivalently two primary color selectors perform two-stage color selection simultaneously, can sort out plant stem leaves in wet garbage to the maximum extent, saves manpower, material resources and time, and is favorable for improving the color selection precision.
The glass sorting machine 36 adopts an optical sorting machine and comprises a feed hopper, a feeding machine, a glass chute, a high-resolution camera and a compressed air valve, the garbage enters the feeding machine from the feed hopper and is conveyed forwards, the free falling body of the garbage enters the glass chute of the optical sorting machine, the falling garbage is recorded and analyzed by the high-resolution camera, the compressed air valve accurately blows the glass to a glass collecting tank according to a set program, and the residual garbage is conveyed to a batching tank through a conveying belt.
Corn stalk pretreatment system for with corn stalk pretreatment, get rid of matters such as lignin, cellulose, hemicellulose that wherein contains, reach the optimum state with organic rubbish mixed anaerobic fermentation, this system includes: a double-roller crusher 37, a blending tank 38 and a first dryer 39. Two rollers are arranged inside the double-roller crusher, the surfaces of the two rollers are both in a sawtooth shape, the two rollers rotate to crush corn straws, the corn straws are crushed into particles with the particle diameter smaller than 5mm, the double-roller crusher is arranged on the lower portion of the rollers and is provided with a sieve plate, sieve holes on the sieve plate are uniformly distributed, the size of the sieve holes is 5mm, the particles smaller than the size of the sieve holes in the crushed corn straws are discharged through the sieve plate, the coarse particles larger than the size of the sieve holes are retained on the sieve plate to continue crushing, a feeding port is arranged above the double-roller crusher, a discharging port is arranged at the bottom of the double-roller crusher, and the crushed corn straws are sent to a blending tank. The blending tank is provided with a feeding hole, a discharging hole and a liquid inlet, a mechanical stirring device, a heating device and a temperature sensor are arranged inside the blending tank, corn straws enter the tank through the feeding hole, KOH enters the tank through the liquid inlet, the KOH is fully stirred through the stirring device, the temperature is controlled at 38 ℃, the blending tank is sealed for 7d, and the dried corn straws are sent to the hydrolysis acidification tank through the first dryer 39.
The reinforced two-phase anaerobic fermentation system is used for combining the pretreated corn straws and garbage for two-phase anaerobic fermentation, and comprises: a two-phase anaerobic fermentation reactor 40, a horizontal screw centrifuge 41, a biogas residue crusher 42, a second dryer 40, a granulator 44, a biogas storage tank and a sewage collection box.
As shown in figure 3, the two-phase anaerobic fermentation reactor is divided into a hydrolysis acidification tank 1 and a methanogenesis tank 11. The hydrolysis acidification tank 1 is provided with a feed inlet 2 and a discharge outlet 9, a mechanical stirring device 5, a pH sensor 7 and a neutralization liquid tank 26 are arranged on the right side of the tank body in the hydrolysis acidification tank, the neutralization liquid tank is connected with the tank body through a water pump, CaCO is filled in the neutralization liquid tank3The solution, mechanical stirring device 5, pH sensor 7, neutralization liquid tank 26 three connect first controller 24, be used for synchronous detection tank material pH value and real-time regulation and control material stirring, pH control is 6.5 ~ 7.8, hydrolysis acidification tank top installation first feed liquor system 8, including first feed liquor pipe and first atomizer, first atomizer evenly distributed is on first feed liquor pipe, first feed liquor pipe passes through the water pump and connects hydrolysis acidification liquid holding vessel, contain a large amount of acid-producing bacteria in the hydrolysis acidification liquid, such as clostridium, acetobacter, murray etc., acidification discharge gate 9 passes through measuring pump 22 and circulating pipe and is connected with methane production jar 11, be used for carrying the acidification liquid, there is gas delivery pipe 10 between hydrolysis acidification jar 1 and methane production jar 11, hydrolysis acidification jar lateral wall is equipped with acidification liquid sample connection 4, hydrolysis acidification jar bottom is equipped with row cinder notch 3, there is temperature sensor 6 in the hydrolysis acidification jar, the temperature sensor is connected with a temperature controller 25, the temperature of materials in the tank is synchronously detected, the outer surface of the hydrolysis acidification tank is provided with a heat-insulating layer, a circulating hot water pipe is arranged between the heat-insulating layer and the shell of the device, the circulating hot water pipe is connected with the temperature controller 25, and the temperature controller controls the temperature of circulating water, so that the optimal reaction temperature in the tank is kept at 35-38 ℃.
A mechanical stirring device 15 and a pH sensor 17 are arranged in a tank of a methane production tank 11, the two are connected with a second controller 23 and used for synchronously detecting the pH value of materials in the tank and controlling the stirring of the materials, the pH is controlled to be 7.0-7.5, a second liquid inlet system 18 is arranged at the top of the methane production tank and comprises a second liquid inlet pipe and a second atomizing spray head, the second atomizing spray head is uniformly distributed on the second liquid inlet pipe, the second liquid inlet pipe is connected with a methane production bacteria liquid storage tank through a water pump, a large amount of methane production microorganisms, such as methanobacterium, methanothermobacter, methanosarcina and the like, are inoculated in the methane production bacteria liquid, a digestive juice sampling port 14 is arranged on the side wall of the methane production tank, a residue discharge port 13 is arranged at the bottom of the methane production tank, a temperature sensor 16 is arranged in the methane production tank and is connected with a temperature controller 25, the temperature of the materials in the tank is synchronously detected, a heat preservation, a circulating hot water pipe is arranged between the heat preservation layer and the device shell, the circulating hot water pipe is connected with a temperature controller 25, the temperature controller controls the temperature of circulating water, the optimal reaction temperature in the tank is kept at 55-58 ℃, a valve is arranged at a discharge port 12 of the methane production tank, the valve is connected with a horizontal screw centrifuge and a return pipe communicated with the methane production tank 11 through a pipeline with a flow dividing part, 25% of digestive juice flows back to a hydrolysis acidification tank through the return pipe to adjust the solid content, 75% of digestive juice is sent to the horizontal screw centrifuge through a pipeline to be subjected to solid-liquid separation, a methane gas outlet 21 is arranged at the top of the methane production tank, the methane gas outlet 21 is communicated with an activated carbon adsorption desulfurization-condensation dehydration-molecular sieve pressure swing adsorption device 19 and a gas flowmeter 20, and the purified.
The biogas residues are crushed by a biogas residue crusher 42, dried and granulated, and the biogas residues are sequentially sent into the biogas residue crusher 42, a second dryer 43 and a granulator 44.
A horizontal screw centrifuge 41 mainly composed of a rotary drum, a screw conveyor, a differential mechanism, a transmission component and the like; the biogas residue crusher is provided with a feed inlet, a discharge outlet and a liquid outlet, the materials are extruded and dewatered in the machine, and the biogas residue after solid-liquid separation is discharged from the discharge outlet and sent to the biogas residue crusher.
The biogas residue crusher 42 mainly comprises a frame, a rotor, a transmission part and the like; the frame part is formed by welding a carbon steel plate and channel steel; the rotor part adopts double-layer blades for crushing, materials enter a crushing chamber from a feeding hole, and are continuously ground by the double-layer blades, so that the materials meet the granulation requirement. The transmission part adopts belt transmission, and the belt pulley and the belt are driven by the motor and are directly transmitted to the main shaft, so that the main shaft rotates at high speed to achieve the crushing effect; and feeding the crushed biogas residues into a second dryer.
A second dryer 43 mainly composed of a heat source, a rotary drum, an induced draft fan, etc.; the second dryer is provided with a feeding hole and a discharge valve, and after the biogas residues enter the second dryer from the feeding hole, the biogas residues are fully contacted with hot air under the turning of the shoveling plate, so that the drying heat transfer and mass transfer speeds are accelerated; discharging the dried biogas residues to a granulator through a discharge valve.
The granulator 44 is a disc granulator, the disc angle of the granulating disc adopts an integral circular arc structure, and the granulation rate can reach more than 94%; the bottom of the granulating pan is reinforced by a plurality of radiation steel plates, so that the granulating pan is firm, durable and not easy to deform; the granulation disc is provided with a discharge port, the fertilizer with the grain size of 3-5 mm is discharged from the discharge port, and the fertilizer is cooled and then metered and packaged to form the high-quality fertilizer, so that the fertilizer is convenient to store and use.
The sewage treatment and reflux system adopts a coagulation air flotation-high load aeration tank-two-stage A/O-MBR process to treat sewage from sewage separated by an oil-water separator, biogas slurry separated by a horizontal screw centrifuge, percolate of each garbage treatment unit, daily drainage of each workshop, domestic sewage and the like, and comprises a regulating tank, an air flotation tank, a high load aeration tank, a secondary sedimentation tank, a two-stage nitrification-denitrification tank, an MBR reaction tank, a concentration tank, a biological coagulation sedimentation reaction tank, a slag removal machine and the like. Conveying the sewage into a regulating tank, pumping the sewage into a subsequent air floatation treatment unit through a water pump, adding a certain amount of flocculant and coagulant into the sewage before the sewage enters the air floatation unit, removing suspended matters and grease, removing colloid and partial phosphate, pumping the effluent of the air floatation unit into a high-load aeration tank, removing most organic matters, then feeding the effluent into a secondary sedimentation tank for sludge-water separation, feeding the effluent of the secondary sedimentation tank into a two-stage nitrification-denitrification tank automatically to remove the residual organic matters and nitrogen pollutants in the sewage, finally performing sludge-water separation through a built-in MBR, returning the effluent to a two-phase anaerobic system and a straw pretreatment system for regulating humidity, returning a part of the sludge to a front-end primary denitrification tank, discharging a part of the sludge into a concentration tank as residual sludge, discharging the sludge in the air floatation tank and the secondary sedimentation tank into the concentration tank, and feeding the sludge into a biological coagulation reaction tank for deep dehydration after the sludge is concentrated, the generated clear liquid flows back to the first-stage denitrification tank for treatment, and the generated slag cake and sludge cake return to the anaerobic fermentation system.

Claims (10)

1.一种村镇湿垃圾强化两相厌氧处理方法,其特征在于:包括湿垃圾预处理、秸秆预处理、两相厌氧发酵处理;1. A method for strengthening two-phase anaerobic treatment of wet garbage in villages and towns, characterized in that: comprising wet garbage pretreatment, straw pretreatment, and two-phase anaerobic fermentation treatment; 所述湿垃圾预处理包括:人工分选去除湿垃圾中的干扰物,后进行固液分离处理得到预脱水垃圾,将预脱水垃圾进行筛分后,根据不同粒径大小的垃圾所含组分进行定向分选处理,去除金属、塑料、纤维、无机物得到分选后的有机垃圾;将有机垃圾进行破碎处理得到粉碎物料,后进行茎叶和玻璃分选处理,得到去除茎叶含纤维素类物质、玻璃的高纯度有机垃圾;The wet garbage pretreatment includes: manually sorting and removing the interfering substances in the wet garbage, then performing solid-liquid separation treatment to obtain pre-dewatering garbage, and after screening the pre-dewatering garbage, according to the components contained in the garbage with different particle sizes. Orientation sorting is carried out to remove metals, plastics, fibers and inorganic substances to obtain sorted organic waste; the organic waste is crushed to obtain pulverized materials, and then the stems and leaves and glass are sorted to obtain the removal of cellulose in stems and leaves. high-purity organic waste of similar substances and glass; 所述秸秆预处理包括:将秸秆进行破碎处理得到小于5mm的破碎物质,经破碎物质进行调配处理去除木质素类物质,后进行烘干处理得到预处理后的秸秆;The straw pretreatment includes: crushing the straw to obtain crushed material smaller than 5 mm, preparing the crushed material to remove lignin, and then drying to obtain the pretreated straw; 所述两相厌氧发酵处理包括:将预处理后的秸秆与经上述湿垃圾预处理得到的有机垃圾进行混合,并加入复合菌液得到混合物料;将混合物料送至水解酸化区,加入水解酸化菌进行水解酸化反应;水解酸化反应形成的水解酸化液进入产甲烷区,加入产甲烷菌液进行厌氧发酵反应。The two-phase anaerobic fermentation treatment includes: mixing the pretreated straw with the organic waste obtained by the pretreatment of the wet waste, and adding a compound bacterial liquid to obtain a mixed material; sending the mixed material to a hydrolysis and acidification zone, adding hydrolysis The acidifying bacteria carry out the hydrolysis and acidification reaction; the hydrolysis and acidification liquid formed by the hydrolysis and acidification reaction enters the methane-producing zone, and the methanogenic bacteria liquid is added to carry out the anaerobic fermentation reaction. 2.根据权利要求1所述的村镇湿垃圾强化两相厌氧处理方法,其特征在于:两相厌氧发酵处理过程中,复合菌液包括木霉和芽孢杆菌;水解酸化反应的温度为35℃~38℃,pH值为6.5~7.8;厌氧发酵反应的温度为55℃~58℃,pH值为7.0~7.5。2. The method for strengthening two-phase anaerobic treatment of wet garbage in villages and towns according to claim 1, is characterized in that: in the two-phase anaerobic fermentation treatment process, the compound bacterial liquid comprises Trichoderma and Bacillus; the temperature of hydrolysis and acidification reaction is 35 ℃ ℃~38℃, the pH value is 6.5~7.8; the temperature of the anaerobic fermentation reaction is 55℃~58℃, and the pH value is 7.0~7.5. 3.根据权利要求1所述的村镇湿垃圾强化两相厌氧处理方法,其特征在于:产甲烷区厌氧发酵反应的一部分消化液直接回流至水解酸化区用于发酵,回流部分占消化液总体积的20~30%;剩余消化液经固液分离处理,分离出沼渣和沼液,沼渣破碎处理后烘干造粒,沼液进行污水处理。3. The method for strengthening two-phase anaerobic treatment of wet garbage in villages and towns according to claim 1, is characterized in that: a part of the digested liquid of the anaerobic fermentation reaction in the methane-producing zone directly returns to the hydrolysis and acidification zone for fermentation, and the backflow part accounts for the digested liquid. 20-30% of the total volume; the remaining digested liquid is treated by solid-liquid separation to separate biogas residue and biogas slurry, the biogas residue is crushed and processed, dried and granulated, and the biogas slurry is treated for sewage. 4.根据权利要求1所述的村镇湿垃圾强化两相厌氧处理方法,其特征在于:秸秆预处理中,调配处理采用KOH和Ca(OH)2联合预处理;预处理后的秸秆与有机垃圾混合的VS比为1∶3~5。4. The method for strengthening two-phase anaerobic treatment of wet garbage in villages and towns according to claim 1, characterized in that: in the pretreatment of straws, KOH and Ca(OH) 2 combined pretreatment are used in the preparation treatment; the pretreated straws and organic The VS ratio of garbage mixing is 1:3-5. 5.根据权利要求1所述的村镇湿垃圾强化两相厌氧处理方法,其特征在于所述湿垃圾预处理包括如下步骤:5. The method for strengthening two-phase anaerobic treatment of wet garbage in villages and towns according to claim 1, wherein the wet garbage pretreatment comprises the following steps: (1)人工分选去除湿垃圾中的干扰物,干扰物包括塑料、玻璃、金属;(1) Manual sorting to remove interferences in wet garbage, including plastics, glass, and metals; (2)将人工分选处理后的剩余湿垃圾进行固液分离处理,得到预脱水垃圾和含油废水;含油废水通过管道过滤器进行杂质分离后进行油水分离处理,油脂提取后经加工制成工业油脂,废水进入污水处理系统;(2) Perform solid-liquid separation on the remaining wet waste after manual sorting to obtain pre-dewatered waste and oily waste water; oily waste water is subjected to oil-water separation treatment after separation of impurities through pipeline filters, and processed into industrial products after oil extraction Grease and waste water enter the sewage treatment system; (3)将步骤(2)得到的预脱水垃圾进行一级筛分处理,得到粒径小于40mm的筛下物和粒径大于40mm的筛上物,将筛上物进行磁选处理,在磁力作用下将垃圾中的金属类垃圾分选出来,磁选剩余垃圾进入风选处理,利用各组分之间的重量差异进行风选得到包含有机组分的中质物;(3) the pre-dewatering garbage obtained in step (2) is subjected to primary sieving treatment to obtain under-sieves with a particle size of less than 40 mm and an over-sieve with a particle size of greater than 40 mm, and the over-sieves are subjected to magnetic separation treatment. Under the action, the metal garbage in the garbage is sorted out, and the residual garbage in the magnetic separation is sent to the air separation treatment, and the weight difference between the components is used for air separation to obtain the medium substance containing organic components; (4)将步骤(3)得到的一级筛分筛下物进行二级筛分处理,得到粒径小于8mm的筛下物和粒径大于8mm的筛上物,将筛下物收集后进行填埋处理;(4) carrying out the secondary sieving treatment with the first-stage sieving undersize obtained in step (3) to obtain the undersize smaller than 8mm and the oversize larger than 8mm, and the undersize is collected and carried out landfill disposal; (5)将步骤(2)得到的中质物和步骤(3)得到的二级筛分筛上物进行破碎处理得到粒径小于20mm的粉碎物料,将粉碎物料进行茎叶和玻璃分选处理,得到去除茎叶含纤维素类物质、玻璃的剩余有机垃圾。(5) crushing the medium substance obtained in step (2) and the secondary screening oversize obtained in step (3) to obtain a crushed material with a particle size of less than 20 mm, and subjecting the crushed material to stem, leaf and glass sorting treatment , to obtain the remaining organic garbage containing cellulose substances and glass in stems and leaves. 6.根据权利要求1所述的村镇湿垃圾强化两相厌氧处理方法,其特征在于:还包括污水处理,处理的污水来自经油水分离处理后的污水、经离心处理分离后的沼液以及各个垃圾处理单元的污水;采用混凝气浮-高负荷曝气池-两级A/O-MBR工艺处理污水,出水回用于两相厌氧发酵系统和秸秆预处理系统调节湿度,污泥一部分回流至前端一级反硝化池,剩余污泥经浓缩处理、深度脱水后,所产生的清液回流至一级反硝化池,产生的渣饼及污泥饼回流进行水解处理。6. The method for strengthening two-phase anaerobic treatment of wet garbage in villages and towns according to claim 1, characterized in that: it further comprises sewage treatment, and the treated sewage comes from sewage after oil-water separation treatment, biogas slurry after centrifugal treatment and separation, and Sewage from each waste treatment unit; coagulation air flotation-high-load aeration tank-two-stage A/O-MBR process is used to treat sewage, and the effluent is reused for two-phase anaerobic fermentation system and straw pretreatment system to adjust humidity, sludge Part of it is returned to the front-end primary denitrification tank. After the excess sludge is concentrated and deeply dehydrated, the resulting clear liquid is returned to the primary denitrification tank, and the resulting slag cake and sludge cake are returned for hydrolysis treatment. 7.一种村镇湿垃圾强化两相厌氧处理系统,其特征在于:包括湿垃圾预处理系统、秸秆预处理系统、两相厌氧发酵系统、污水处理及回流系统;7. An enhanced two-phase anaerobic treatment system for wet garbage in villages and towns, characterized in that: it includes a wet garbage pretreatment system, a straw pretreatment system, a two-phase anaerobic fermentation system, and a sewage treatment and return system; 所述湿垃圾预处理系统包括依次连接的分拣台、预脱水装置、一级滚筒筛、二级滚筒筛、锤式反击破碎机、茎叶分选机、玻璃分选机,一级滚筒筛的筛下物出料口与二级滚筒筛的进料口相连,一级滚筒筛的筛上物出料口与磁选机的进料口相连,磁选机的非磁性物质出料口与风选机的进料口相连,风选机的中质物出料口、二级滚筒筛的筛上物出料口均与锤式反击破碎机的进料口相连,风选机的轻质物出料口与静电分选机的进料口相连;The wet garbage pretreatment system includes a sorting table, a pre-dehydration device, a first-stage drum screen, a second-stage drum screen, a hammer impact crusher, a stem and leaf sorting machine, a glass sorting machine, and a first-stage drum screen. The discharge port of the under sieve is connected to the feed port of the secondary trommel screen, the discharge port of the top sieve of the primary trommel screen is connected to the feed port of the magnetic separator, and the non-magnetic material discharge port of the magnetic separator is connected to the feed port of the magnetic separator. The feeding port of the air separator is connected, the medium material discharge port of the air separator and the upper screen discharge port of the secondary trommel screen are connected with the feeding port of the hammer impact crusher, and the light weight of the air separator is connected. The material discharge port is connected with the feed port of the electrostatic separator; 秸秆预处理系统包括依次连接的对辊式破碎机、调配罐、第一烘干机;The straw pretreatment system includes a pair of roller crushers, a mixing tank and a first dryer connected in sequence; 两相厌氧发酵系统包括相互连通的水解酸化罐和产甲烷罐,第一烘干机和玻璃分选机的出料口均与水解酸化罐的进料口相连;The two-phase anaerobic fermentation system includes a hydrolysis acidification tank and a methanogenic tank which are connected to each other, and the discharge ports of the first dryer and the glass sorting machine are all connected with the feed port of the hydrolysis acidification tank; 污水处理及回流系统包括调节池、气浮池、高负荷曝气池、两级硝化-反硝化池、浓缩池、二沉池、生物聚沉反应池。The sewage treatment and return system includes adjustment tank, air flotation tank, high-load aeration tank, two-stage nitrification-denitrification tank, concentration tank, secondary sedimentation tank, and biological coagulation reaction tank. 8.根据权利要求7所述的村镇湿垃圾强化两相厌氧处理系统,其特征在于:8. The village and town wet garbage strengthening two-phase anaerobic treatment system according to claim 7 is characterized in that: 水解酸化罐包括第一控制器,设于罐内的机械搅拌装置、pH传感器和温度传感器,通过水泵与罐体相连的中和液罐,设于罐顶部的第一进液系统;罐体侧壁设有酸化液取样口,顶部设有排气口,底部设有排渣口;第一控制器与机械搅拌装置、pH传感器、温度传感器、中和液罐相连;The hydrolysis and acidification tank includes a first controller, a mechanical stirring device, a pH sensor and a temperature sensor located in the tank, a neutralization liquid tank connected to the tank body through a water pump, and a first liquid inlet system located at the top of the tank; the side of the tank body The wall is provided with an acidizing liquid sampling port, the top is provided with an exhaust port, and the bottom is provided with a slag discharge port; the first controller is connected with a mechanical stirring device, a pH sensor, a temperature sensor, and a neutralization liquid tank; 产甲烷罐包括第二控制器,设于罐内的机械搅拌装置、pH传感器和温度传感器,设于罐顶部的第二进液系统;第二控制器与机械搅拌装置、pH传感器、温度传感器相连;罐体侧壁设有消化液取样口和出料口,产甲烷罐出料口通过带有分流部件的管路分别连接卧螺式离心机和连通产甲烷罐的回流管,底部设有排渣口,顶部设有沼气出气口,沼气出气口依次与脱硫脱水装置、沼气罐相连;The methanogenic tank includes a second controller, a mechanical stirring device, a pH sensor and a temperature sensor located in the tank, and a second liquid inlet system located at the top of the tank; the second controller is connected with the mechanical stirring device, the pH sensor and the temperature sensor ; The side wall of the tank is provided with a digestion liquid sampling port and a discharge port, and the discharge port of the methanogenic tank is respectively connected to the horizontal screw centrifuge and the return pipe connected to the methanogenic tank through a pipeline with a diversion component, and the bottom is provided with a discharge port. The slag port is provided with a biogas outlet at the top, and the biogas outlet is connected to the desulfurization and dehydration device and the biogas tank in sequence; 水解酸化罐的排气口与产甲烷管之间设有连通管道,水解酸化罐的酸化出料口通过计量泵和循环管与产甲烷罐相连。A communication pipeline is arranged between the exhaust port of the hydrolysis and acidification tank and the methane-producing pipe, and the acidification discharge port of the hydrolysis-acidification tank is connected with the methane-producing tank through a metering pump and a circulation pipe. 9.根据权利要求7所述的村镇湿垃圾强化两相厌氧处理系统,其特征在于:还包括依次相连的沼渣破碎机、第二烘干机、造粒机;9. The two-phase anaerobic treatment system for strengthening wet garbage in villages and towns according to claim 7, characterized in that: it further comprises a biogas residue crusher, a second dryer and a granulator which are connected in sequence; 卧螺式离心机设有沼液出口和沼渣出口,沼液出口与调节池入口相连,沼渣出口与沼渣破碎机入口相连。The decanter centrifuge is provided with a biogas liquid outlet and a biogas residue outlet, the biogas liquid outlet is connected with the inlet of the regulating tank, and the biogas residue outlet is connected with the inlet of the biogas residue crusher. 10.根据权利要求7所述的村镇湿垃圾强化两相厌氧处理系统,其特征在于:所述预脱水装置为变径螺旋脱液机,螺旋锥角2θ值为5~8°,装置内设有红外加热装置,出口处设有压力调节装置。10 . The enhanced two-phase anaerobic treatment system for wet waste in villages and towns according to claim 7 , wherein the pre-dehydration device is a variable-diameter screw deliquor, and the 2θ value of the spiral cone angle is 5 to 8°. 10 . Infrared heating device is provided, and pressure regulating device is provided at the outlet.
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