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CN112484574A - Ultrathin flexible film-pasting camouflage material and preparation method and application thereof - Google Patents

Ultrathin flexible film-pasting camouflage material and preparation method and application thereof Download PDF

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Publication number
CN112484574A
CN112484574A CN202011414811.8A CN202011414811A CN112484574A CN 112484574 A CN112484574 A CN 112484574A CN 202011414811 A CN202011414811 A CN 202011414811A CN 112484574 A CN112484574 A CN 112484574A
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Prior art keywords
film
camouflage material
ultra
flexible film
coating
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CN202011414811.8A
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Chinese (zh)
Inventor
曹粲
颜铄清
贺君
翟文正
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Central South University
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Central South University
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Priority to CN202011414811.8A priority Critical patent/CN112484574A/en
Publication of CN112484574A publication Critical patent/CN112484574A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H3/00Camouflage, i.e. means or methods for concealment or disguise
    • F41H3/02Flexible, e.g. fabric covers, e.g. screens, nets characterised by their material or structure
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/385Oxides, hydroxides or carbonates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/84Paper comprising more than one coating on both sides of the substrate
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04Physical treatment, e.g. heating, irradiating
    • D21H25/06Physical treatment, e.g. heating, irradiating of impregnated or coated paper

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

一种超薄柔性贴膜伪装材料及其制备方法与应用,该贴膜伪装材料由二维片状导电粉、有色颜料、功能助剂、高分子热塑性橡胶和有机溶剂配制成液体浆料后经涂布于塑料膜上热压而成。该贴膜伪装材料的制备方法包括以下步骤:(1)将热塑性橡胶颗粒与有色颜料、有机溶剂、功能助剂和片状导电粉混合均匀,得涂布浆料;(2)将涂布浆料涂布在含硅油的塑料膜上形成湿膜并烘干,得涂布膜;(3)将涂布膜进行热压硫化处理,得致密化薄膜;(4)将致密化薄膜进行背胶处理,即得超薄柔性贴膜。本发明柔性贴膜伪装材料生产成本低,质量轻,强度高,柔性好,颜色丰富,能同时模拟军事真目标对雷达波和可见光的信号特征,达到“以假乱真”的伪装效果。An ultra-thin flexible film camouflage material and a preparation method and application thereof. The film camouflage material is prepared into a liquid slurry from two-dimensional sheet-like conductive powder, colored pigments, functional additives, polymer thermoplastic rubber and organic solvent, and then coated Hot-pressed on plastic film. The preparation method of the film camouflage material includes the following steps: (1) uniformly mixing thermoplastic rubber particles with colored pigments, organic solvents, functional additives and sheet-like conductive powder to obtain a coating slurry; (2) mixing the coating slurry Coating on a plastic film containing silicone oil to form a wet film and drying to obtain a coating film; (3) subjecting the coating film to hot pressing vulcanization to obtain a densified film; (4) subjecting the densified film to back glue treatment , that is, the ultra-thin flexible film is obtained. The flexible film camouflage material of the invention has the advantages of low production cost, light weight, high strength, good flexibility and rich colors, and can simultaneously simulate the signal characteristics of real military targets to radar waves and visible light to achieve the camouflage effect of "fake the real".

Description

Ultrathin flexible film-pasting camouflage material and preparation method and application thereof
Technical Field
The invention relates to a film-pasting camouflage material, in particular to an ultrathin flexible film-pasting camouflage material and a preparation method and application thereof.
Background
The false target is made of light and cheap materials such as air cushions, foams, wood, plastics and the like to be prepared into a model of real weapon equipment and work, so that the effect of distinguishing true from false or showing false from false is achieved. The false camouflage target objects of military engineering comprise false roads, false workers, false trenches, false bridges, false cave depots, false places, false hangars, false runways, false armholes, wharves and the like. Because the corresponding military true targets and military facilities are mainly made of various metal materials and have strong reflection and echo signal characteristics on incident radar detection waves, the false targets are required to have consistent geometric dimensions and colors with the true targets and also need to have radar reflection characteristic signals for simulating the true targets, namely the surfaces of the false targets must have the function of reflecting electromagnetic waves; in addition, the fake target is required to be light in weight, convenient to transport, erect and withdraw, low in production cost and convenient to maintain. Although the existing metal film has strong reflection effect on electromagnetic waves and is thin in thickness, if the metal film is wrapped on the surface of a false target, the problems of low strength, easiness in damage, single color and the like are generated, and the multi-occasion requirements of modern war cannot be met.
Disclosure of Invention
The invention aims to solve the technical problem of overcoming the defects in the prior art and provide the ultrathin flexible film-pasting camouflage material which can simulate the signal characteristics of military real targets on radar waves and visible light, and has the advantages of low production cost, light weight, high strength, good flexibility, rich colors and wide application range.
The invention further aims to solve the technical problem of providing a preparation method of the ultrathin flexible film-pasting camouflage material.
The technical scheme for solving the technical problem is that the ultrathin flexible film camouflage material is prepared by preparing liquid slurry from two-dimensional flaky conductive powder, colored pigment, functional auxiliary agent, high-molecular thermoplastic rubber and organic solvent, coating the liquid slurry on a plastic film and carrying out hot pressing.
Further, the two-dimensional flaky conductive powder is one or more of micron-sized flaky nickel powder, micron-sized flaky aluminum powder, micron-sized flaky copper powder and micron-sized flaky graphite powder; the addition amount is 55-75% of the total mass of the raw materials, the flaky metal and graphite powder are oriented and arranged when the film is prepared, and the radar wave reflection signals are the same as those of the metal.
Further, the colored pigment is an inorganic pigment and is one or more of titanium dioxide, ferric oxide, carbon black, lead chrome yellow and iron blue, and the particle size of the pigment is larger than 1000 meshes; the addition amount is 5-15% of the total mass of the raw materials.
Further, the functional auxiliary agent is a solvent type auxiliary agent and is one or more of a wetting agent, a dispersing agent, a flatting agent, a vulcanizing agent, a defoaming agent, an antirust agent, a thickening agent and a toughening agent; the addition amount is 2-5% of the total mass of the raw materials.
Further, the high-molecular thermoplastic rubber is one or more of polyurethane rubber, nitrile rubber, ethylene propylene diene monomer, polyolefin rubber, polypropylene rubber and polyvinyl chloride rubber elastomer; the addition amount is 8-20% of the total mass of the raw materials.
Further, the organic solvent is one or more of toluene, xylene, n-butanol, cyclohexanone, toluene cyclohexanone, acetone and ethyl acetate; the addition amount is 15-30% of the total mass of the raw materials.
The invention further solves the technical problem by adopting the technical scheme that the preparation method of the ultrathin flexible film-pasting camouflage material comprises the following steps:
(1) preparing coating slurry: thermoplastic rubber particles, colored pigment, organic solvent and functional auxiliary agent
Uniformly mixing the powder with flaky conductive powder to obtain coating slurry;
(2) coating: coating the coating slurry obtained in the step (1) on a plastic film containing silicon oil to form a wet film and drying to obtain a coating film;
(3) hot-pressing and vulcanizing: carrying out hot-pressing vulcanization treatment on the coating film obtained in the step (2) to obtain a densified thin film;
(4) back gluing: and (4) carrying out gum treatment on the densified film obtained in the step (3) to obtain the ultrathin flexible film-pasting camouflage material. And then the ultrathin flexible film-pasting camouflage material is cut into ultrathin flexible film-pasting camouflage materials with different sizes according to the actual application requirements.
Further, in the step (2), the distance between the scrapers used for coating is 0-0.5 mm, the linear speed is 0.2-1.0 m/min, and the coating is uneven and easy to crack due to the fact that the linear speed is too high; the drying temperature is 50-90 ℃. Too high drying temperature can lead to diaphragm fracture, and too low can reduce work efficiency.
Further, in the step (2), the plastic film is a PET plastic film, and the PET film is used for conveniently uncovering the film.
Further, in the step (3), the working temperature of the roller during vulcanization hot pressing is 100-150 ℃, the proper temperature can soften and plasticize the resin, and the roller is stuck when the temperature is too high; the pressure between the steel belt and the roller is 5-15 MPa, and the steel belt can be damaged due to the fact that the pressure between the steel belt and the roller is too high; the linear velocity is 0.2 to 0.8 m/min. Too fast a speed will result in non-uniform thickness of the formed part.
The ultrathin flexible film camouflage material is applied to fake target simulation on radar wave reflection and visible light characteristic signals, and has a special effect of 'false and false'.
Compared with the prior art, the invention has the following beneficial effects:
(1) the ultrathin flexible film-pasting camouflage material has high conductivity, and can simulate strong reflection characteristic signals of a real target metal material to an incident radar; meanwhile, the appearance color of the film camouflage material can be adjusted according to the added pigment, so that military decoy targets have stronger fake camouflage effect.
(2) The film-pasting camouflage material has the advantages of high strength, light weight, adjustable size, flexibility, capability of meeting the requirements of various curved surfaces of the actual false target, folding during use, easiness in transportation, installation and withdrawal and stronger actual applicability.
(3) The preparation method can realize continuous batch preparation, has high production efficiency and low cost, and is very beneficial to industrial application.
Detailed Description
The present invention will be further described with reference to the following examples. It should be noted that the described embodiments illustrate only some of the embodiments of the invention, and should not be construed as limiting the scope of the claims. All other changes and modifications which can be made by one skilled in the art based on the embodiments of the present invention without inventive faculty are within the scope of the claims of the present application.
Examples
The raw material components and the mixture ratio of the embodiment are as follows: 0.5kg of polyurethane rubber particles, 1.0kg of cyclohexanone solvent, 100g of styrene-maleic anhydride copolymer, 20g of diphenyl polysiloxane, 0.35kg of inorganic pigment, 0.15kg of carbon black, 0.1kg of iron oxide red, 1.0kg of micron-sized flaky nickel powder and 2.0kg of micron-sized flaky aluminum powder.
The preparation method of the ultrathin flexible film camouflage material comprises the following steps:
(1) preparing coating slurry: pouring 0.5kg of polyurethane rubber particles and 1.0kg of cyclohexanone solvent into a 30L planetary stirrer, and stirring at the rotating speed of 200 r/min for 2h to ensure that the mixture is in a transparent state; after 100g of styrene-maleic anhydride copolymer and 20g of diphenyl polysiloxane are added, 0.35kg of lead chrome yellow, 0.15kg of carbon black and 0.1kg of iron oxide red which pass through a 6000-mesh screen mesh, 1.0kg of micron-sized flaky nickel powder and 2.0kg of micron-sized flaky aluminum powder are added into a planetary mixer for three times, and the mixture is continuously stirred for 6 hours at the rotating speed of 600r/min to obtain coating slurry;
(2) coating: adjusting the space between scrapers of the coating machine to be 0.05mm, rotating the coating machine at the linear speed of 0.5 m/min, pouring the coating slurry into a feeding port of the coating machine, uniformly coating the slurry on a PET plastic film, and drying the PET plastic film to form a film, wherein the drying temperature is 60 ℃ to obtain a coating film;
(3) hot-pressing and vulcanizing: adjusting the working temperature of a roller of a vulcanizing machine to be 100 ℃; the pressure between the steel belt and the roller is 5 MPa; the linear velocity was 0.2 m/min. Carrying out hot-pressing vulcanization treatment on the coating film obtained in the step (2) to achieve the purpose of dense orientation of the flaky conductive powder in the rubber to obtain a dense film;
(4) back gluing: and carrying out gum treatment on the obtained densified film, and shearing the densified film into ultrathin flexible film-pasting camouflage materials with different sizes according to the actual application requirements.
The performance parameters of the ultrathin flexible film-pasting camouflage material prepared by the embodiment are shown in the following table:
Figure DEST_PATH_IMAGE002

Claims (10)

1.一种超薄柔性贴膜伪装材料,其特征在于,由二维片状导电粉、有色颜料、功能助剂、高分子热塑性橡胶和有机溶剂配制成液体浆料后经涂布于塑料膜上热压而成。1. an ultra-thin flexible film camouflage material, it is characterized in that, after being mixed with liquid slurry by two-dimensional sheet-like conductive powder, colored pigments, functional additives, macromolecular thermoplastic rubber and organic solvent, it is coated on the plastic film Hot pressed. 2.根据权利要求1所述的超薄柔性贴膜伪装材料,其特征在于,所述二维片状导电粉为微米级片状镍粉、微米级片状铝粉、微米级片状铜粉、微米级片状石墨粉中的一种或几种;添加量为原料总质量的55~75%。2. The ultra-thin flexible film camouflage material according to claim 1, wherein the two-dimensional flake conductive powder is micron-level flake nickel powder, micron-level flake aluminum powder, micron-level flake copper powder, One or several kinds of micron-scale flake graphite powder; the addition amount is 55~75% of the total mass of raw materials. 3.根据权利要求1或2所述的超薄柔性贴膜伪装材料,其特征在于,所述有色颜料为钛白粉、氧化铁、炭黑、铅铬黄、铁蓝中的一种或几种,颜料粒径大于1000目;添加量为原料总质量的5~15%。3. The ultra-thin flexible film camouflage material according to claim 1 or 2, wherein the colored pigment is one or more of titanium dioxide, iron oxide, carbon black, lead chrome yellow, and iron blue, The particle size of the pigment is greater than 1000 mesh; the addition amount is 5~15% of the total mass of the raw material. 4.根据权利要求1~3之一所述的超薄柔性贴膜伪装材料,其特征在于,所述功能助剂为溶剂型助剂,为润湿剂、分散剂、流平剂、硫化剂、消泡剂、防锈剂、增稠剂、增韧剂中的一种或几种;添加量为原料总质量的2~5%。4. The ultra-thin flexible film camouflage material according to one of claims 1 to 3, wherein the functional auxiliary agent is a solvent-based auxiliary agent, which is a wetting agent, a dispersant, a leveling agent, a vulcanizing agent, One or more of defoamer, rust inhibitor, thickener and toughening agent; the addition amount is 2~5% of the total mass of raw materials. 5.根据权利要求1~4之一所述的超薄柔性贴膜伪装材料,其特征在于,所述高分子热塑性橡胶为聚氨酯橡胶、丁腈橡胶、三元乙丙橡胶、聚烯烃橡胶、聚丙乙烯橡胶和聚氯乙烯橡胶弹性体中的一种或几种;添加量为原料总质量的8~20%。5. The ultra-thin flexible film camouflage material according to one of claims 1 to 4, wherein the polymer thermoplastic rubber is polyurethane rubber, nitrile rubber, EPDM rubber, polyolefin rubber, polypropylene One or more of rubber and polyvinyl chloride rubber elastomers; the addition amount is 8~20% of the total mass of raw materials. 6.根据权利要求1~5之一所述的超薄柔性贴膜伪装材料,其特征在于,所述有机溶剂为甲苯、二甲苯、正丁醇、环已酮、甲苯环已酮、丙酮、醋酸乙酯中的一种或几种;添加量为原料总质量的15~30%。6. The ultra-thin flexible film camouflage material according to one of claims 1 to 5, wherein the organic solvent is toluene, xylene, n-butanol, cyclohexanone, toluene cyclohexanone, acetone, acetic acid One or more of ethyl esters; the addition amount is 15~30% of the total mass of the raw materials. 7.一种如权利要求1~7之一所述的超薄柔性贴膜伪装材料的制备方法,其特征在于,包括下列步骤:7. a preparation method of the ultra-thin flexible film camouflage material as described in one of claims 1~7, is characterized in that, comprises the following steps: (1)涂布浆料配制:将热塑性橡胶颗粒与有色颜料、有机溶剂、功能助剂(1) Preparation of coating slurry: mix thermoplastic rubber particles with colored pigments, organic solvents, and functional additives 和片状导电粉混合均匀,得涂布浆料;Mix evenly with flake conductive powder to obtain coating slurry; (2)涂布:将步骤(1)所得涂布浆料涂布在含硅油的塑料膜上形成湿膜并烘干,得涂布膜;(2) Coating: coating the coating slurry obtained in step (1) on a plastic film containing silicone oil to form a wet film and drying to obtain a coating film; (3)热压硫化:将步骤(2)所得涂布膜进行热压硫化处理,得致密化薄膜;(3) Hot-press vulcanization: the coating film obtained in step (2) is subjected to hot-press vulcanization to obtain a densified film; (4)背胶:将步骤(3)所得致密化薄膜进行背胶处理,即得超薄柔性贴膜伪装材料。(4) Self-adhesive: the densified film obtained in step (3) is subjected to self-adhesive treatment to obtain an ultra-thin flexible film camouflage material. 8.根据权利要求7所述的超薄柔性贴膜伪装材料的制备方法,其特征在于,步骤(2)中,所述涂布使用的刮刀间距为0~0.5mm,线速度为0.2~1.0 m/min,烘干温度为50~90℃;所述塑料膜为PET塑料膜。8 . The method for preparing an ultra-thin flexible film camouflage material according to claim 7 , wherein, in step (2), the distance between the blades used in the coating is 0 to 0.5 mm, and the line speed is 0.2 to 1.0 m. 9 . /min, and the drying temperature is 50-90° C.; the plastic film is a PET plastic film. 9.根据权利要求7或8所述的超薄柔性贴膜伪装材料的制备方法,其特征在于,步骤(3)中,所述硫化热压时滚筒的工作温度为100~150℃;钢带与滚筒间压力为5~15 MPa,线速度为0.2~0.8 m/min。9. The method for preparing an ultra-thin flexible film camouflage material according to claim 7 or 8, wherein in step (3), the working temperature of the roller during the vulcanization and hot pressing is 100-150°C; The pressure between the rollers is 5~15 MPa, and the line speed is 0.2~0.8 m/min. 10.一种如权利要求1~9之一所述的超薄柔性贴膜伪装材料作为假目标模拟对雷达波反射和可见光特征信号的伪装应用。10. The ultra-thin flexible film camouflage material according to one of claims 1 to 9 is used as a false target to simulate the camouflage application of radar wave reflection and visible light characteristic signal.
CN202011414811.8A 2020-12-07 2020-12-07 Ultrathin flexible film-pasting camouflage material and preparation method and application thereof Pending CN112484574A (en)

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CN205505865U (en) * 2016-04-06 2016-08-24 肖博元 Decoy is aerifyd in military use
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CN108641456A (en) * 2018-06-04 2018-10-12 丹阳市银海镍铬化工有限公司 Extra large land camouflage paint and preparation method thereof

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