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CN112456867A - Fireproof heat-insulation and decoration integrated board - Google Patents

Fireproof heat-insulation and decoration integrated board Download PDF

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Publication number
CN112456867A
CN112456867A CN202011382532.8A CN202011382532A CN112456867A CN 112456867 A CN112456867 A CN 112456867A CN 202011382532 A CN202011382532 A CN 202011382532A CN 112456867 A CN112456867 A CN 112456867A
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CN
China
Prior art keywords
mixed solution
parts
mixing
silane coupling
coupling agent
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Pending
Application number
CN202011382532.8A
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Chinese (zh)
Inventor
黄志强
焦洋
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Baorunda New Material Co Ltd
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Baorunda New Material Co Ltd
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Priority to CN202011382532.8A priority Critical patent/CN112456867A/en
Publication of CN112456867A publication Critical patent/CN112456867A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/30Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
    • C04B26/32Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/20Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in magnesium oxide, e.g. forsterite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063Preparing or treating the raw materials individually or as batches
    • C04B38/0635Compounding ingredients
    • C04B38/0645Burnable, meltable, sublimable materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Building Environments (AREA)

Abstract

The invention discloses a fireproof heat-insulation decorative integrated board, which comprises the following manufacturing steps of A, preparation of a first mixed solution, namely mixing modified inorganic waste residue powder, a silane coupling agent, acrylic polymer emulsion and polyether polyurethane to form the first mixed solution; B. preparing a second mixed solution, namely mixing the microporous ceramic particles, the silicon dioxide, the perlite, the silane coupling agent and the acrylic acid polymerization emulsion to form the second mixed solution; C. preparing a board, namely uniformly mixing the first mixed solution, the second mixed solution, the fibers and the methyl cellulose; D. and C, transferring the final mixed liquor in the step C into a die cavity, drying, curing and molding, and adding functional auxiliary agents such as microporous ceramic particles, silicon dioxide, perlite and the like to enable the molded plate body to integrate the functions of fire prevention, heat preservation and decoration.

Description

Fireproof heat-insulation and decoration integrated board
Technical Field
The invention relates to the technical field of building material preparation, in particular to a fireproof heat-insulation and decoration integrated plate.
Background
The soft porcelain is a novel energy-saving low-carbon decorative material, is a novel flexible surface decorative material, and is an ecological environment-friendly building material. The appearance of the soft porcelain is exactly like the porcelain, but the soft porcelain lacks the ice-cold, heavy and fragile texture of the traditional ceramic material, has the advantages of light weight, thin body, water and air permeability, natural color, various patterns and flexible decoration, greatly enriches and beautifies the living and working environments of people, and has wide popularization value.
For example, patent document 1 discloses a soft porcelain inorganic powder and a related preparation method, which are researches on basic materials, but the requirements on building material properties of final products are diversified, such as fire resistance, heat preservation, radiation protection and the like, and the material disclosed in patent document 1 cannot meet corresponding requirements, and for a decorative material with a multilayer structure appearing on the market, multi-level functional layers are integrated into a whole, but installation is troublesome, so that the research is further conducted on the development of the multiple properties of soft porcelain.
Patent document 1: a modified industrial inorganic powder and a composite material containing the same, which are disclosed in application publication numbers: CN 107311505A.
Disclosure of Invention
In order to solve at least one technical defect, the invention provides the following technical scheme:
the application document provides a fireproof heat-insulation decorative integrated board, which comprises the following manufacturing steps
A. Preparing a first mixed solution, namely mixing modified inorganic waste residue powder, a silane coupling agent, acrylic polymer emulsion and polyether polyurethane to form the first mixed solution;
B. preparing a second mixed solution, namely mixing the microporous ceramic particles, the silicon dioxide, the perlite, the silane coupling agent and the acrylic acid polymerization emulsion to form the second mixed solution;
C. preparing a board, namely uniformly mixing the first mixed solution, the second mixed solution, the fibers and the methyl cellulose;
D. and C, transferring the final mixed solution in the step C to a mold cavity, and drying, curing and molding.
The multi-performance development is carried out on the basis of patent document 1, and functional auxiliary agents such as microporous ceramic particles, silicon dioxide, perlite and the like are added to enable the formed plate body to integrate the functions of fire prevention, heat preservation and decoration.
The microporous structure of the ceramic particles is mainly utilized to improve the heat insulation performance, and the silicon dioxide-based perlite plays a role in fire resistance.
Further, the first mixed solution comprises the following components in percentage by mass: 100-110 parts of modified inorganic waste residue powder, 2-3 parts of silane coupling agent, 40-45 parts of acrylic polymer emulsion and 6-8 parts of polyether polyurethane.
Further, the silane coupling agent and the inorganic waste residue powder are mixed and then uniformly mixed and stirred with the acrylic polymer emulsion and the polyether polyurethane.
Further, by mass, 100-110 parts of modified inorganic waste residue powder, 5-7 parts of fiber and 5-6 parts of methyl cellulose.
Further, a silane coupling agent is mixed with water to form a modified liquid, and the modified liquid is sprayed on the silicon dioxide powder and the perlite particles.
Further, the second mixed solution comprises the following components in proportion by mass: 20-30 parts of microporous ceramic particles, 3-5 parts of silicon dioxide, 4-6 parts of perlite, 2-3 parts of silane coupling agent and 20-25 parts of acrylic acid polymerization emulsion.
Further, the modified inorganic waste residue powder is formed by mixing at least one of electroplating residue powder, red mud powder and urban construction waste soil with polyether polyurethane and acrylic polymer emulsion and then drying.
Further, mixing magnesium silicate powder with N, N-methylene bisacrylamide to prepare ceramic slurry, adding corn starch and a dispersing agent, performing ball milling, adding a catalyst and an initiator, mixing, performing injection molding to obtain a blank, demolding, sintering to obtain magnesium silicate porous ceramic, and crushing to obtain microporous ceramic particles.
Compared with the prior art, the invention has the beneficial effects that:
1. the integrated board improves the components, proportion and process, integrates fire prevention, heat preservation and decoration, and is more convenient to use.
Detailed Description
The present invention will be further described with reference to the following specific examples.
Preparing microporous ceramic particles: magnesium silicate powder, particle size 100-.
The dispersant is TH-904 aqueous dispersant.
The catalyst was TEMED in water at 5% concentration.
The initiator is ammonium persulfate aqueous solution with the concentration of 5 percent.
a. Mixing magnesium silicate powder with the premixed liquid to prepare ceramic slurry, mixing the magnesium silicate powder with the premixed liquid N, N-methylene bisacrylamide to prepare the ceramic slurry, wherein the solid content of the ceramic slurry is 55% by mass, the adding amount of the corn starch is 10% by mass, the adding amount of the dispersing agent is 5% by mass of the magnesium silicate powder, and then adding the catalyst and the initiator to mix to form the slurry.
b. Quickly mixing the ceramic slurry and injecting into a mould, demoulding, drying and sintering, wherein the temperature rise rate is 3-5 ℃/min below the sintering temperature of 600 ℃, the temperature rises to 1300 ℃ and 1320 ℃, the temperature is preserved for 1.5h, and then the mixture is crushed to 250 mu m to form microporous ceramic particles with the density of 2.1g/cm3The bending strength is 16 MPa.
Preparing modified zirconia and modified tungsten, mixing kh550 silane coupling agent with water or ethanol, spraying the mixture onto zirconia and tungsten powder, and uniformly stirring.
The grain diameter of zirconium oxide grain is 0.005mm, and the grain diameter of tungsten powder is 0.005 mm.
The modified inorganic waste residue powder is prepared by mixing and drying waste residues such as electroplating residue powder, red mud powder, urban construction waste soil and the like with polyether polyurethane and acrylic polymer emulsion respectively according to the reference of patent document CN107311505A, wherein the modified inorganic waste residue powder is prepared from 100 parts by mass of inorganic waste residue powder, 32 parts by mass of acrylic polymer emulsion and 19 parts by mass of polyether polyurethane.
Example 1
The fireproof heat-insulating decorative integrated board comprises the following manufacturing steps
A. Preparing a first mixed solution, namely preparing 100 parts of modified inorganic waste residue powder, 2 parts of silane coupling agent, 40 parts of acrylic polymer emulsion and 6 parts of polyether polyurethane, mixing the silane coupling agent and the inorganic waste residue powder, and then uniformly mixing and stirring the mixture with the acrylic polymer emulsion and the polyether polyurethane to form a first mixed solution;
B. preparing a second mixed solution, namely mixing 20 parts of microporous ceramic particles, 3 parts of silicon dioxide, 4 parts of perlite, 2 parts of a silane coupling agent and 20 parts of acrylic acid polymerization emulsion to form the second mixed solution;
C. preparing a board, namely uniformly mixing the first mixed solution, the second mixed solution, polyvinyl alcohol fibers and methyl cellulose;
D. and C, transferring the final mixed solution in the step C to a mold cavity, and drying, curing and molding.
Example 2
The fireproof heat-insulating decorative integrated board comprises the following manufacturing steps
A. Preparing a first mixed solution, namely preparing 102 parts of modified inorganic waste residue powder, 2 parts of silane coupling agent, 41 parts of acrylic polymer emulsion and 6.5 parts of polyether polyurethane, mixing the silane coupling agent and the inorganic waste residue powder, and then uniformly mixing and stirring the mixture with the acrylic polymer emulsion and the polyether polyurethane to form a first mixed solution;
B. preparing a second mixed solution, namely mixing 22 parts of microporous ceramic particles, 4 parts of silicon dioxide, 5 parts of perlite, 2 parts of a silane coupling agent and 22 parts of acrylic acid polymerization emulsion to form the second mixed solution;
C. preparing a board, namely uniformly mixing the first mixed solution, the second mixed solution, 5 parts of polyvinyl alcohol fiber and 6 parts of methyl cellulose;
D. and C, transferring the final mixed solution in the step C to a mold cavity, and drying, curing and molding.
Example 3
The fireproof heat-insulating decorative integrated board comprises the following manufacturing steps
A. Preparing a first mixed solution, namely preparing 105 parts of modified inorganic waste residue powder, 2 parts of silane coupling agent, 43 parts of acrylic polymer emulsion and 7 parts of polyether polyurethane, mixing the silane coupling agent and the inorganic waste residue powder, and then uniformly mixing and stirring the mixture with the acrylic polymer emulsion and the polyether polyurethane to form a first mixed solution;
B. preparing a second mixed solution, namely mixing 25 parts of microporous ceramic particles, 5 parts of silicon dioxide, 6 parts of perlite, 2 parts of a silane coupling agent and 24 parts of acrylic acid polymerization emulsion to form the second mixed solution;
C. preparing a board, namely uniformly mixing the first mixed solution, the second mixed solution, 6 parts of polyvinyl alcohol fiber and 5 parts of methyl cellulose;
D. and C, transferring the final mixed solution in the step C to a mold cavity, and drying, curing and molding.
Example 4
The fireproof heat-insulating decorative integrated board comprises the following manufacturing steps
A. Preparing a first mixed solution, namely preparing 108 parts of modified inorganic waste residue powder, 2.5 parts of silane coupling agent, 45 parts of acrylic polymer emulsion and 8 parts of polyether polyurethane, mixing the silane coupling agent and the inorganic waste residue powder, and then uniformly mixing and stirring the mixture with the acrylic polymer emulsion and the polyether polyurethane to form a first mixed solution;
B. preparing a second mixed solution, namely mixing 28 parts of microporous ceramic particles, 5 parts of silicon dioxide, 5 parts of perlite, 2 parts of a silane coupling agent and 25 parts of acrylic acid polymerization emulsion to form the second mixed solution;
C. preparing a board, namely uniformly mixing the first mixed solution, the second mixed solution, 7 parts of polyvinyl alcohol fiber and 6 parts of methyl cellulose;
D. and C, transferring the final mixed solution in the step C to a mold cavity, and drying, curing and molding.
The performance of the integrated plate prepared above was examined as follows
The heat conductivity of the integrated boards prepared in examples 1-4 was about 0.03W/mK, and the integrated boards were highly efficient heat insulating materials, and when the fire resistance was measured, the heat conductivity was found to be below 110 ℃, and the remaining boards were measured by GBT4085 standard, the dimensional change rate was less than 0.5, and the boards met the standard, and when the temperature was higher than 110 ℃, the surfaces thereof appeared sticky and had bubbles.
Meanwhile, due to the addition of the microporous ceramic particles and the like, the tensile strength, the breaking strength and the like of the integrated plate are higher than those of the original soft ceramic layer, and are improved by about 15%.
The above is only a preferred embodiment of the present invention, and the protection scope of the present invention is not limited to the above-mentioned embodiments, and all technical solutions belonging to the idea of the present invention belong to the protection scope of the present invention. It should be noted that modifications and embellishments within the scope of the invention may occur to those skilled in the art without departing from the principle of the invention, and are considered to be within the scope of the invention.

Claims (7)

1. Fire prevention type keeps warm and decorates intergral template, its characterized in that: comprises the following steps
A. Preparing a first mixed solution, namely mixing modified inorganic waste residue powder, a silane coupling agent, acrylic polymer emulsion and polyether polyurethane to form the first mixed solution;
B. preparing a second mixed solution, namely mixing the microporous ceramic particles, the silicon dioxide, the perlite, the silane coupling agent and the acrylic acid polymerization emulsion to form the second mixed solution;
C. preparing a board, namely uniformly mixing the first mixed solution, the second mixed solution, the fibers and the methyl cellulose;
D. and C, transferring the final mixed solution in the step C to a mold cavity, and drying, curing and molding.
2. The unitary plate of claim 1, wherein: the first mixed solution comprises the following components in percentage by mass: 100-110 parts of modified inorganic waste residue powder, 2-3 parts of silane coupling agent, 40-45 parts of acrylic polymer emulsion and 6-8 parts of polyether polyurethane.
3. The unitary plate of claim 2, wherein: firstly, mixing the silane coupling agent with the inorganic waste residue powder, and then uniformly mixing and stirring the mixture with the acrylic polymer emulsion and the polyether polyurethane.
4. The unitary plate of claim 1, wherein: the silane coupling agent is mixed with water to form a modified solution which is sprayed on the silicon dioxide powder and the perlite particles.
5. The unitary plate of claim 1, wherein: the second mixed solution comprises the following components in percentage by mass: 20-30 parts of microporous ceramic particles, 3-5 parts of silicon dioxide, 4-6 parts of perlite, 2-3 parts of silane coupling agent and 20-25 parts of acrylic acid polymerization emulsion.
6. The unitary plate of any one of claims 1-5, wherein: the modified inorganic waste residue powder is formed by mixing at least one of electroplating residue powder, red mud powder and urban construction waste soil with polyether polyurethane and acrylic polymer emulsion and then drying.
7. The unitary plate of any one of claims 1-5, wherein: mixing magnesium silicate powder with N, N-methylene bisacrylamide to prepare ceramic slurry, adding corn starch and a dispersing agent, performing ball milling, adding a catalyst and an initiator, mixing, performing injection molding to obtain a blank, demolding, sintering to form magnesium silicate porous ceramic, and crushing to obtain microporous ceramic particles.
CN202011382532.8A 2020-12-01 2020-12-01 Fireproof heat-insulation and decoration integrated board Pending CN112456867A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011382532.8A CN112456867A (en) 2020-12-01 2020-12-01 Fireproof heat-insulation and decoration integrated board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011382532.8A CN112456867A (en) 2020-12-01 2020-12-01 Fireproof heat-insulation and decoration integrated board

Publications (1)

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CN112456867A true CN112456867A (en) 2021-03-09

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101591177A (en) * 2009-06-19 2009-12-02 厦门大学 A kind of preparation method of magnesium silicate porous ceramics
CN104058630A (en) * 2014-04-24 2014-09-24 潍坊纳博欧化工科技有限公司 Novel heat insulating plate and manufacturing method thereof
CN105731880A (en) * 2014-12-10 2016-07-06 辽宁法库陶瓷工程技术研究中心 A novel polyphenyl granule-perlite organic composite thermal insulation material and a preparing method thereof
CN107311505A (en) * 2017-06-09 2017-11-03 广东福美软瓷有限公司 A kind of composite of modified industry inorganic powder and the inorganic powder containing modified industry
CN108191370A (en) * 2018-03-12 2018-06-22 合肥万之景门窗有限公司 A kind of heat insulating energy saving material and preparation method thereof
CN111393058A (en) * 2020-03-24 2020-07-10 莱恩斯新材料科技(唐山)有限公司 Energy-saving low-carbon soft porcelain decorative material and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101591177A (en) * 2009-06-19 2009-12-02 厦门大学 A kind of preparation method of magnesium silicate porous ceramics
CN104058630A (en) * 2014-04-24 2014-09-24 潍坊纳博欧化工科技有限公司 Novel heat insulating plate and manufacturing method thereof
CN105731880A (en) * 2014-12-10 2016-07-06 辽宁法库陶瓷工程技术研究中心 A novel polyphenyl granule-perlite organic composite thermal insulation material and a preparing method thereof
CN107311505A (en) * 2017-06-09 2017-11-03 广东福美软瓷有限公司 A kind of composite of modified industry inorganic powder and the inorganic powder containing modified industry
CN108191370A (en) * 2018-03-12 2018-06-22 合肥万之景门窗有限公司 A kind of heat insulating energy saving material and preparation method thereof
CN111393058A (en) * 2020-03-24 2020-07-10 莱恩斯新材料科技(唐山)有限公司 Energy-saving low-carbon soft porcelain decorative material and preparation method thereof

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Application publication date: 20210309

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