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CN112411212A - Production method of nylon super-high-elasticity fabric - Google Patents

Production method of nylon super-high-elasticity fabric Download PDF

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Publication number
CN112411212A
CN112411212A CN202011259883.XA CN202011259883A CN112411212A CN 112411212 A CN112411212 A CN 112411212A CN 202011259883 A CN202011259883 A CN 202011259883A CN 112411212 A CN112411212 A CN 112411212A
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China
Prior art keywords
nylon
gray cloth
nylon gray
dyeing
deodorizer
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Pending
Application number
CN202011259883.XA
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Chinese (zh)
Inventor
石峰
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Shanghai Taorui Textile Technology Co ltd
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Shanghai Taorui Textile Technology Co ltd
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Priority to CN202011259883.XA priority Critical patent/CN112411212A/en
Publication of CN112411212A publication Critical patent/CN112411212A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/24Polyamides; Polyurethanes
    • D06P3/241Polyamides; Polyurethanes using acid dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/02Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/41General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using basic dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/24Polyamides; Polyurethanes
    • D06P3/242Polyamides; Polyurethanes using basic dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a production method of a nylon super-high elastic fabric, which comprises the following preparation steps: s1: pretreatment: pretreating nylon gray cloth, performing closed degreasing on the nylon gray cloth by using a dry cleaner, removing silicone oil on the nylon gray cloth, soaking the nylon gray cloth in clear water at 45 ℃ for 30-45 minutes, and drying the degreased nylon gray cloth by using a dryer at 100-115 ℃; s2: shaping: adding 0.3-0.6% of softener and 3-5% of anti-yellowing auxiliary agent into the nylon gray cloth treated by the S1, and then adding elastic fiber into the nylon gray cloth. According to the invention, silicone oil is removed before embryo setting, so that dyeing of acidic materials can be effectively prevented from being seriously hindered during dyeing, thus dyeing patterns are formed, and the deodorant is added, has no toxic or side effect, and can effectively prevent fading through twice color fixing.

Description

Production method of nylon super-high-elasticity fabric
Technical Field
The invention relates to the field of nylon fabrics, in particular to a production method of a nylon ultrahigh-elasticity fabric.
Background
The spandex belongs to polyurethane fiber, and has a special supermolecular structure and high resilience and strength. In the spandex-containing fabric, although the proportion of spandex is small, the spandex-containing fabric has elasticity, no sense of compression, comfortable wear and free movement, is concerned by domestic and foreign markets and has high added value. The spandex-containing fabric is generally woven by using spandex filament as core yarn and using chinlon or other fibers (cotton, wool, silk, hemp, chemical fiber and the like) as skin yarns. The most common fabric in the market is a nylon coated spandex knitted fabric which can be used as swimwear, sportswear, tights, men and women underwear, socks and the like. The dyeing of the nylon-coated spandex knitted fabric generally adopts acid dye, the acid dye is fast in coloring, and the difference of the acid dye in the dyeing of the nylon and the spandex is large, so that the problem of uniform dyeing of products is easily caused. The amount of the silicone oil can reach more than 8 percent generally), and if the silicone oil is not removed before the embryo is fixed, the silicone oil can be crosslinked at the high-temperature embryo fixed time, and can be adsorbed on the nylon yarn, and the acidic material can be seriously hindered from being dyed during dyeing, so that the dyed flower is formed.
Disclosure of Invention
The invention aims to solve the defects in the prior art and provides a production method of a nylon super-high elastic fabric.
In order to achieve the purpose, the invention adopts the following technical scheme:
a production method of a nylon super high-elastic fabric comprises the following preparation steps:
s1: pretreatment: pretreating nylon gray cloth, performing closed degreasing on the nylon gray cloth by using a dry cleaner, removing silicone oil on the nylon gray cloth, soaking the nylon gray cloth in clear water at 45 ℃ for 30-45 minutes, and drying the degreased nylon gray cloth by using a dryer at 100-115 ℃;
s2: shaping: adding 0.3-0.6% of softening agent and 3-5% of anti-yellowing auxiliary agent to the nylon gray cloth treated by S1, then adding elastic fiber to the nylon gray cloth, then winding the nylon gray cloth on a porous roller capable of being vacuumized, and placing the nylon gray cloth in steaming for treatment, wherein the temperature is kept between 120 ℃ and 135 ℃;
s3: and (3) deodorization: installing the shaped nylon gray cloth on a shaping deodorizer, injecting the prepared deodorizer into a rolling groove of the shaping deodorizer, starting the shaping deodorizer to enable the nylon gray cloth to pass through the rolling groove at a speed of 5 minutes/meter and be soaked by the deodorizer, and soaking the nylon gray cloth for 30-45 minutes by using clean water at 45 ℃.
S4: dyeing: and (4) changing the clear water in which the nylon gray cloth is soaked in the S3 for multiple times, adding a dyeing auxiliary agent, adding an acid dye, adding a cationic dye, heating to 85-100 ℃, preserving the heat for 30-45 minutes, and then cooling.
S5: reinforcing: and (3) placing the dyed nylon gray cloth into clear water for cleaning until the water is clear, and fixing the color by using an anionic color fixing agent.
Preferably, the extractant for removing silicone oil in S1 is tetrachloroethylene.
Preferably, the softening agent in S2 is SOFTEX, and the anti-yellowing auxiliary agent is CF-2.
Preferably, the light dyeing color is formed by adding ammonium sulfate as a dyeing auxiliary agent.
Preferably, the color fixing agent in S5 is a nylon color fixing agent NL-47.
Preferably, the deodorizing liquid in S3 includes one or more of modified glucose polymer, methyl silicone oil emulsion, silicone oil emulsion and silicone elastomer emulsion.
Preferably, the cationic dye in S4 is used in an amount of 0.03-0.05%.
The invention has the beneficial effects that:
according to the invention, silicone oil is removed before embryo setting, so that the phenomenon that acid materials are seriously hindered from dyeing during dyeing can be effectively prevented, thus dyeing patterns are formed, and the deodorant is added, has no toxic or side effect, and can effectively prevent fading through twice color fixation.
Detailed Description
The technical solutions in the embodiments of the present invention will be described below clearly and completely in connection with the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
Example 1:
s1: pretreatment: pretreating nylon gray cloth, performing closed degreasing on the nylon gray cloth by using a dry cleaning machine, removing silicone oil on the nylon gray cloth, soaking the nylon gray cloth in clear water at 45 ℃ for 30-45 minutes, and drying the degreased nylon gray cloth by using a dryer at 100 ℃;
s2: shaping: adding 0.3% of softener and 3% of anti-yellowing auxiliary agent to the nylon gray cloth treated by S1, then adding elastic fiber to the nylon gray cloth, then winding the nylon gray cloth on a porous roller capable of being vacuumized, and placing the roller in steaming for treatment, wherein the temperature is kept at 120 ℃;
s3: and (3) deodorization: the shaped nylon gray cloth is arranged on a shaping deodorizer, the prepared deodorizer is injected into a rolling groove of the shaping deodorizer, the shaping deodorizer is started to enable the nylon gray cloth to pass through the rolling groove at the speed of 5 minutes/meter and be soaked by the deodorizer, and the nylon gray cloth is soaked in clear water at the temperature of 45 ℃ for 30 minutes.
S4: dyeing: and (4) changing the clear water in which the nylon gray cloth is soaked in the S3 for multiple times, adding a dyeing auxiliary agent, adding an acid dye, adding a cationic dye, heating to 85 ℃, keeping the temperature for 30 minutes, and then cooling.
S5: reinforcing: and (3) placing the dyed nylon gray cloth into clear water for cleaning until the water is clear, and fixing the color by using an anionic color fixing agent.
Example 2:
s1: pretreatment: pretreating nylon gray cloth, carrying out closed degreasing on the nylon gray cloth by using a dry cleaner, removing silicone oil on the nylon gray cloth, soaking the nylon gray cloth in clear water at 45 ℃ for 35 minutes, and drying the degreased nylon gray cloth by using a dryer at 104 ℃;
s2: shaping: adding 0.4% of softener and 3.5% of anti-yellowing auxiliary agent to the nylon gray cloth treated by S1, then adding elastic fiber to the nylon gray cloth, then winding the nylon gray cloth on a porous roller capable of being vacuumized, and placing the roller in steaming for treatment, wherein the temperature is kept at 125 ℃;
s3: and (3) deodorization: the shaped nylon gray cloth is installed on a shaping deodorizer, the prepared deodorizer is injected into a rolling groove of the shaping deodorizer, the shaping deodorizer is started to enable the nylon gray cloth to pass through the rolling groove at the speed of 5 minutes/meter and be soaked by the deodorizer, and then the nylon gray cloth is soaked in clean water at the temperature of 45 ℃ for 34 minutes.
S4: dyeing: and (4) changing the clear water in which the nylon gray cloth is soaked in the S3 for multiple times, adding a dyeing auxiliary agent, adding an acid dye, adding a cationic dye, heating to 89 ℃, keeping the temperature for 34 minutes, and then cooling.
S5: reinforcing: and (3) placing the dyed nylon gray cloth into clear water for cleaning until the water is clear, and fixing the color by using an anionic color fixing agent.
Example 3:
s1: pretreatment: pretreating nylon gray cloth, carrying out closed degreasing on the nylon gray cloth by using a dry washer, removing silicone oil on the nylon gray cloth, soaking the nylon gray cloth in clear water at 45 ℃ for 37 minutes, and drying the degreased nylon gray cloth by using a dryer at 107 ℃;
s2: shaping: adding 0.45% of softener and 4% of anti-yellowing auxiliary agent to the nylon gray cloth treated by S1, then adding elastic fiber to the nylon gray cloth, then winding the nylon gray cloth on a porous roller capable of being vacuumized, and placing the roller in steaming for treatment, wherein the temperature is kept at 127.5 ℃;
s3: and (3) deodorization: and (3) mounting the shaped nylon gray cloth on a shaping deodorizer, injecting the prepared deodorizer into a rolling groove of the shaping deodorizer, starting the shaping deodorizer to enable the nylon gray cloth to pass through the rolling groove at a speed of 5 minutes/meter and be soaked by the deodorizer, and soaking the nylon gray cloth for 37 minutes by using clean water at 45 ℃.
S4: dyeing: and (3) changing the clear water in which the nylon gray cloth is soaked in the S3 for multiple times, adding a dyeing auxiliary agent, adding an acid dye, adding a cationic dye, heating to 92 ℃, keeping the temperature for 37 minutes, and then cooling.
S5: reinforcing: and (3) placing the dyed nylon gray cloth into clear water for cleaning until the water is clear, and fixing the color by using an anionic color fixing agent.
Example 4:
s1: pretreatment: pretreating nylon gray cloth, performing closed degreasing on the nylon gray cloth by using a dry cleaner, removing silicone oil on the nylon gray cloth, soaking the nylon gray cloth in clear water at 45 ℃ for 40 minutes, and drying the degreased nylon gray cloth by using a dryer at 111 ℃;
s2: shaping: adding 0.55% of softener and 4.5% of anti-yellowing auxiliary agent to the nylon gray cloth treated by S1, then adding elastic fiber to the nylon gray cloth, then winding the nylon gray cloth on a porous roller capable of being vacuumized, and placing the roller in steaming for treatment, wherein the temperature is kept at 130 ℃;
s3: and (3) deodorization: the shaped nylon gray cloth is arranged on a shaping deodorizer, the prepared deodorizer is injected into a rolling groove of the shaping deodorizer, the shaping deodorizer is started to enable the nylon gray cloth to pass through the rolling groove at the speed of 5 minutes/meter and be soaked by the deodorizer, and the nylon gray cloth is soaked in clear water at the temperature of 45 ℃ for 40 minutes.
S4: dyeing: and (3) changing the clear water in which the nylon gray cloth is soaked in the S3 for multiple times, adding a dyeing auxiliary agent, adding an acid dye, adding a cationic dye, heating to 95 ℃, keeping the temperature for 40 minutes, and then cooling.
S5: reinforcing: and (3) placing the dyed nylon gray cloth into clear water for cleaning until the water is clear, and fixing the color by using an anionic color fixing agent.
Example 5:
s1: pretreatment: pretreating nylon gray cloth, performing closed degreasing on the nylon gray cloth by using a dry washer, removing silicone oil on the nylon gray cloth, soaking the nylon gray cloth in clear water at 45 ℃ for 45 minutes, and drying the degreased nylon gray cloth by using a dryer at 115 ℃;
s2: shaping: adding 0.6% of softener and 5% of anti-yellowing auxiliary agent to the nylon gray cloth treated by S1, then adding elastic fiber to the nylon gray cloth, then winding the nylon gray cloth on a porous roller capable of being vacuumized, and placing the roller in steaming for treatment, wherein the temperature is kept at 135 ℃;
s3: and (3) deodorization: the shaped nylon gray cloth is arranged on a shaping deodorizer, the prepared deodorizer is injected into a rolling groove of the shaping deodorizer, the shaping deodorizer is started to enable the nylon gray cloth to pass through the rolling groove at the speed of 5 minutes/meter and be soaked by the deodorizer, and the nylon gray cloth is soaked in clean water at the temperature of 45 ℃ for 45 minutes.
S4: dyeing: and (3) changing the clear water in which the nylon gray cloth is soaked in the S3 for multiple times, adding a dyeing auxiliary agent, adding an acid dye, adding a cationic dye, heating to 100 ℃, keeping the temperature for 45 minutes, and then cooling.
S5: reinforcing: and (3) placing the dyed nylon gray cloth into clear water for cleaning until the water is clear, and fixing the color by using an anionic color fixing agent.
Test example: 500 nylon fabrics are selected for testing, and the following table shows the statistical results after the test:
examples Low degree of color loss In degree of color loss High degree of color loss Number of formed dyeing flowers
Example 1 96 3 1 1
Example 2 97 2 1 0.5
Example 3 99 1 0 0
Example 4 98 1 1 1
Example 5 94 4 2 2
It can be seen that:
the degree of color loss of the example 1 is 4% and the rate of formed dyeing is 1%;
the degree of color loss of the example 2 is 3 percent, and the formed dyeing rate is 0.5 percent;
the degree of color loss of the example 3 is 1% and the formed dyeing rate is 0%;
the degree of color loss of the example 4 is 2% and the rate of formed dyeing is 1%;
the degree of discoloration in example 5 was 6% higher, resulting in a dyeing yield of 2%.
According to the embodiments 1, 2 and 3, the method has the advantages that the degree of color loss is low, the method is suitable for common use, the dyeing rate is low in the test process, and the effect of the method for removing the silicone oil is good.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and equivalent alternatives or modifications according to the technical solution and the inventive concept of the present invention should be covered by the scope of the present invention.

Claims (7)

1. The production method of the nylon super high-elastic fabric is characterized by comprising the following preparation steps:
s1: pretreatment: pretreating nylon gray cloth, performing closed degreasing on the nylon gray cloth by using a dry cleaner, removing silicone oil on the nylon gray cloth, soaking the nylon gray cloth in clear water at 45 ℃ for 30-45 minutes, and drying the degreased nylon gray cloth by using a dryer at 100-115 ℃;
s2: shaping: adding 0.3-0.6% of softener and 3-5% of anti-yellowing auxiliary agent to the nylon gray cloth treated by S1, then adding elastic fiber to the nylon gray cloth, then winding the nylon gray cloth on a porous roller capable of being vacuumized, and placing the nylon gray cloth in steaming for treatment, wherein the temperature is kept between 120 and 135 ℃;
s3: and (3) deodorization: installing the shaped nylon gray cloth on a shaping deodorizer, injecting the prepared deodorizer into a rolling groove of the shaping deodorizer, starting the shaping deodorizer to enable the nylon gray cloth to pass through the rolling groove at a speed of 5 minutes/meter and be soaked by the deodorizer, and soaking the nylon gray cloth in clean water at 45 ℃ for 30-45 minutes.
S4: dyeing: and (3) changing the clear water in which the nylon gray cloth is soaked in the S3 for multiple times, adding a dyeing auxiliary agent, adding an acid dye, adding a cationic dye, heating to 85-100 ℃, preserving the heat for 30-45 minutes, and then cooling.
S5: reinforcing: and (3) placing the dyed nylon gray cloth into clear water for cleaning until the water is clear, and then fixing the color by using an anionic color fixing agent.
2. The method for producing nylon ultra-high elastic fabric according to claim 1, wherein the extractant for removing silicone oil in S1 is tetrachloroethylene.
3. The method for producing nylon ultra-high elastic fabric according to claim 1, wherein the softening agent in S2 is SOFTEX, and the anti-yellowing auxiliary agent is CF-2.
4. The method for producing the nylon ultra-high elastic fabric according to the claim 1, characterized in that the dyeing assistant added for dyeing the light color is ammonium sulfate.
5. The method for producing nylon ultra-high elastic fabric according to claim 1, wherein the color fixing agent in S5 is nylon color fixing agent NL-47.
6. The method for producing nylon ultra-high elastic fabric according to claim 1, wherein the deodorizing liquid in S3 comprises one or more of modified glucose polymer, methyl silicone oil emulsion, silicone oil emulsion and silicone elastomer emulsion.
7. The method for producing nylon ultra-high elastic fabric according to claim 1, characterized in that the amount of the cationic dye in the S4 is 0.03-0.05%.
CN202011259883.XA 2020-11-12 2020-11-12 Production method of nylon super-high-elasticity fabric Pending CN112411212A (en)

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CN114921976A (en) * 2022-05-18 2022-08-19 浙江新舒纺织有限公司 Dyeing development process of nylon reactive dye

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114921976A (en) * 2022-05-18 2022-08-19 浙江新舒纺织有限公司 Dyeing development process of nylon reactive dye

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