CN112342448A - Oxide-based metal ceramic material - Google Patents
Oxide-based metal ceramic material Download PDFInfo
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- CN112342448A CN112342448A CN202011169504.8A CN202011169504A CN112342448A CN 112342448 A CN112342448 A CN 112342448A CN 202011169504 A CN202011169504 A CN 202011169504A CN 112342448 A CN112342448 A CN 112342448A
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- CN
- China
- Prior art keywords
- oxide
- boride
- cermet material
- mass
- tungsten
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910010293 ceramic material Inorganic materials 0.000 title abstract description 18
- 229910052751 metal Inorganic materials 0.000 title abstract description 6
- 239000002184 metal Substances 0.000 title abstract description 6
- 239000011195 cermet Substances 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 23
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 16
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 16
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 13
- 239000010941 cobalt Substances 0.000 claims abstract description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 13
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 13
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 13
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 13
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 13
- 239000010937 tungsten Substances 0.000 claims abstract description 13
- OFEAOSSMQHGXMM-UHFFFAOYSA-N 12007-10-2 Chemical compound [W].[W]=[B] OFEAOSSMQHGXMM-UHFFFAOYSA-N 0.000 claims description 3
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052582 BN Inorganic materials 0.000 claims description 3
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 3
- 229910052691 Erbium Inorganic materials 0.000 claims description 3
- 229910052693 Europium Inorganic materials 0.000 claims description 3
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 3
- 229910052689 Holmium Inorganic materials 0.000 claims description 3
- 229910052765 Lutetium Inorganic materials 0.000 claims description 3
- 229910052779 Neodymium Inorganic materials 0.000 claims description 3
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 3
- 229910052773 Promethium Inorganic materials 0.000 claims description 3
- 229910052772 Samarium Inorganic materials 0.000 claims description 3
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 3
- 229910052771 Terbium Inorganic materials 0.000 claims description 3
- 229910052775 Thulium Inorganic materials 0.000 claims description 3
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 3
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- LRTTZMZPZHBOPO-UHFFFAOYSA-N [B].[B].[Hf] Chemical compound [B].[B].[Hf] LRTTZMZPZHBOPO-UHFFFAOYSA-N 0.000 claims description 3
- LGLOITKZTDVGOE-UHFFFAOYSA-N boranylidynemolybdenum Chemical compound [Mo]#B LGLOITKZTDVGOE-UHFFFAOYSA-N 0.000 claims description 3
- VDZMENNHPJNJPP-UHFFFAOYSA-N boranylidyneniobium Chemical compound [Nb]#B VDZMENNHPJNJPP-UHFFFAOYSA-N 0.000 claims description 3
- XTDAIYZKROTZLD-UHFFFAOYSA-N boranylidynetantalum Chemical compound [Ta]#B XTDAIYZKROTZLD-UHFFFAOYSA-N 0.000 claims description 3
- AUVPWTYQZMLSKY-UHFFFAOYSA-N boron;vanadium Chemical compound [V]#B AUVPWTYQZMLSKY-UHFFFAOYSA-N 0.000 claims description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 3
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 3
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 3
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims description 3
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 3
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims description 3
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 3
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 3
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 claims description 3
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims description 3
- 229910052706 scandium Inorganic materials 0.000 claims description 3
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 3
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 claims description 3
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 3
- FRNOGLGSGLTDKL-UHFFFAOYSA-N thulium atom Chemical compound [Tm] FRNOGLGSGLTDKL-UHFFFAOYSA-N 0.000 claims description 3
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/005—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides comprising a particular metallic binder
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Ceramic Products (AREA)
Abstract
The invention discloses an oxide-based cermet material, which comprises the following components in parts by mass: 3-10% of aluminum oxide, 1-3% of magnesium oxide, 1-3% of rare earth, 0.5-0.8% of tungsten, 0.5-0.8% of cobalt and the balance of silicon carbide. When the oxide-based metal ceramic material is used, the components such as aluminum oxide, magnesium oxide, rare earth, tungsten, cobalt, silicon carbide and the like are added into the ceramic material, so that the properties of high temperature resistance, wear resistance, hardness and the like of the ceramic material can be greatly improved, and the use requirements of special industries are met.
Description
Technical Field
The invention relates to an oxide-based cermet material.
Background
The existing ceramic material has general strength, wear resistance and high temperature resistance, and can not meet the use requirements of special industries.
Disclosure of Invention
The present invention addresses the above-mentioned deficiencies of the prior art by providing an oxide-based cermet material.
The technical scheme adopted by the invention for solving the technical problems is as follows: an oxide-based metal ceramic material is constructed, and the ceramic material comprises the following components in parts by mass: 3-10% of aluminum oxide, 1-3% of magnesium oxide, 1-3% of rare earth, 0.5-0.8% of tungsten, 0.5-0.8% of cobalt and the balance of silicon carbide.
In the oxide-based cermet material of the present invention, the cermet material further comprises, by mass: one or more of titanium boride, tantalum boride, vanadium boride, chromium boride, zirconium boride, tungsten boride, molybdenum boride, niobium boride and hafnium boride, and the mass ratio is 0.5-1%.
In the oxide-based cermet material of the present invention, the cermet material further comprises, by mass: one or more of titanium nitride, boron nitride, silicon nitride and tantalum nitride, and the mass ratio is 0.5-1%.
In the oxide-based cermet material according to the present invention, the rare earth is one or more of lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu), scandium (Sc), and yttrium (Y).
In the oxide-based cermet material, the cermet material comprises the following components in parts by mass: 6% of aluminum oxide, 2% of magnesium oxide, 2% of rare earth, 0.6% of tungsten, 0.6% of cobalt and 88.8% of silicon carbide.
In the oxide-based cermet material, the cermet material comprises the following components in parts by mass: 9% of aluminum oxide, 2.5% of magnesium oxide, 2.5% of rare earth, 0.7% of tungsten, 0.7% of cobalt and 84.6% of silicon carbide.
The oxide-based cermet material has the following beneficial effects: when the oxide-based metal ceramic material is used, the components such as aluminum oxide, magnesium oxide, rare earth, tungsten, cobalt, silicon carbide and the like are added into the ceramic material, so that the properties of high temperature resistance, wear resistance, hardness and the like of the ceramic material can be greatly improved, and the use requirements of special industries are met.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, embodiments of the present invention are described in further detail below.
In a first embodiment of the oxide-based cermet material of the present invention, the cermet material comprises the following components by mass: 3-10% of aluminum oxide, 1-3% of magnesium oxide, 1-3% of rare earth, 0.5-0.8% of tungsten, 0.5-0.8% of cobalt and the balance of silicon carbide.
When the oxide-based metal ceramic material is used, the components such as aluminum oxide, magnesium oxide, rare earth, tungsten, cobalt, silicon carbide and the like are added into the ceramic material, so that the properties of high temperature resistance, wear resistance, hardness and the like of the ceramic material can be greatly improved, and the use requirements of special industries are met.
Further, the ceramic material also comprises the following components in percentage by mass: one or more of titanium boride, tantalum boride, vanadium boride, chromium boride, zirconium boride, tungsten boride, molybdenum boride, niobium boride and hafnium boride, and the mass ratio is 0.5-1%.
Further, the ceramic material also comprises the following components in percentage by mass: one or more of titanium nitride, boron nitride, silicon nitride and tantalum nitride, and the mass ratio is 0.5-1%.
Specifically, the rare earth is one or more of lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu), scandium (Sc) and yttrium (Y).
In one embodiment, the ceramic material comprises the following components in parts by mass: 6% of aluminum oxide, 2% of magnesium oxide, 2% of rare earth, 0.6% of tungsten, 0.6% of cobalt and 88.8% of silicon carbide.
In another embodiment, the ceramic material comprises the following components in percentage by mass: 9% of aluminum oxide, 2.5% of magnesium oxide, 2.5% of rare earth, 0.7% of tungsten, 0.7% of cobalt and 84.6% of silicon carbide.
The above description is only an embodiment of the present invention, and not intended to limit the scope of the present invention, and all modifications of equivalent structures and equivalent processes, which are made by the present specification, or directly or indirectly applied to other related technical fields, are included in the scope of the present invention.
Claims (6)
1. The oxide-based cermet material is characterized by comprising the following components in parts by mass: 3-10% of aluminum oxide, 1-3% of magnesium oxide, 1-3% of rare earth, 0.5-0.8% of tungsten, 0.5-0.8% of cobalt and the balance of silicon carbide.
2. The oxide-based cermet material according to claim 1, further comprising, in mass proportions: one or more of titanium boride, tantalum boride, vanadium boride, chromium boride, zirconium boride, tungsten boride, molybdenum boride, niobium boride and hafnium boride, and the mass ratio is 0.5-1%.
3. The oxide-based cermet material according to claim 1, further comprising, in mass proportions: one or more of titanium nitride, boron nitride, silicon nitride and tantalum nitride, and the mass ratio is 0.5-1%.
4. The oxide-based cermet material according to claim 1, wherein the rare earth is one or more of lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu), scandium (Sc) and yttrium (Y).
5. The oxide-based cermet material according to claim 1, wherein the cermet material comprises the following components in parts by mass: 6% of aluminum oxide, 2% of magnesium oxide, 2% of rare earth, 0.6% of tungsten, 0.6% of cobalt and 88.8% of silicon carbide.
6. The oxide-based cermet material according to claim 1, wherein the cermet material comprises the following components in parts by mass: 9% of aluminum oxide, 2.5% of magnesium oxide, 2.5% of rare earth, 0.7% of tungsten, 0.7% of cobalt and 84.6% of silicon carbide.
Priority Applications (1)
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CN202011169504.8A CN112342448A (en) | 2020-10-28 | 2020-10-28 | Oxide-based metal ceramic material |
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CN202011169504.8A CN112342448A (en) | 2020-10-28 | 2020-10-28 | Oxide-based metal ceramic material |
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CN202011169504.8A Pending CN112342448A (en) | 2020-10-28 | 2020-10-28 | Oxide-based metal ceramic material |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5236875A (en) * | 1989-10-26 | 1993-08-17 | Western Mining Corporation Ltd. | Dense sic ceramic products |
JPH10237579A (en) * | 1997-02-21 | 1998-09-08 | Sumitomo Metal Ind Ltd | Low thermal expansion and high heat conduction heat dissipation material and method of manufacturing the same |
CN102056863A (en) * | 2008-06-06 | 2011-05-11 | 陶氏环球技术公司 | Metal-infiltrated titanium-silicon-carbide and titanium-aluminum-carbide bodies |
CN106498255A (en) * | 2016-09-21 | 2017-03-15 | 芜湖扬展新材料科技服务有限公司 | A kind of hard composite material and preparation method thereof |
CN108642316A (en) * | 2018-05-22 | 2018-10-12 | 新沂市中诺新材料科技有限公司 | A kind of Al-Mg/SiC composite materials |
CN108998712A (en) * | 2018-07-18 | 2018-12-14 | 上海电机学院 | A kind of solvable bridge plug composite material and preparation method |
CN109852862A (en) * | 2019-01-11 | 2019-06-07 | 广东技术师范学院 | A kind of high rigidity composite hard alloy and the preparation method and application thereof |
-
2020
- 2020-10-28 CN CN202011169504.8A patent/CN112342448A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5236875A (en) * | 1989-10-26 | 1993-08-17 | Western Mining Corporation Ltd. | Dense sic ceramic products |
JPH10237579A (en) * | 1997-02-21 | 1998-09-08 | Sumitomo Metal Ind Ltd | Low thermal expansion and high heat conduction heat dissipation material and method of manufacturing the same |
CN102056863A (en) * | 2008-06-06 | 2011-05-11 | 陶氏环球技术公司 | Metal-infiltrated titanium-silicon-carbide and titanium-aluminum-carbide bodies |
CN106498255A (en) * | 2016-09-21 | 2017-03-15 | 芜湖扬展新材料科技服务有限公司 | A kind of hard composite material and preparation method thereof |
CN108642316A (en) * | 2018-05-22 | 2018-10-12 | 新沂市中诺新材料科技有限公司 | A kind of Al-Mg/SiC composite materials |
CN108998712A (en) * | 2018-07-18 | 2018-12-14 | 上海电机学院 | A kind of solvable bridge plug composite material and preparation method |
CN109852862A (en) * | 2019-01-11 | 2019-06-07 | 广东技术师范学院 | A kind of high rigidity composite hard alloy and the preparation method and application thereof |
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Application publication date: 20210209 |