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CN112341931A - A kind of water-based reflective thermal insulation coating and preparation method and use thereof - Google Patents

A kind of water-based reflective thermal insulation coating and preparation method and use thereof Download PDF

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CN112341931A
CN112341931A CN202011114637.5A CN202011114637A CN112341931A CN 112341931 A CN112341931 A CN 112341931A CN 202011114637 A CN202011114637 A CN 202011114637A CN 112341931 A CN112341931 A CN 112341931A
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water
thermal insulation
silver paste
insulation coating
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CN112341931B (en
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王涛
贾恒琼
祝和权
张恒
杜存山
魏曌
吴韶亮
王玮
李海燕
石振平
史懿
杜玮
伊钟毓
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China Academy of Railway Sciences Corp Ltd CARS
Railway Engineering Research Institute of CARS
Beijing Teletron Telecom Engineering Co Ltd
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Railway Engineering Research Institute of CARS
Beijing Teletron Telecom Engineering Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • C09D183/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D7/00Roof covering exclusively consisting of sealing masses applied in situ; Gravelling of flat roofs
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/005Additives being defined by their particle size in general
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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Abstract

The invention provides a water-based reflective heat-insulating coating and a preparation method and application thereof, wherein the water-based reflective heat-insulating coating comprises the following components in parts by weight: 30-45 parts of fluorosilicone emulsion, 20-35 parts of silicone-acrylic emulsion, 9-18 parts of filler, 15-25 parts of nano titanium dioxide, 0.2-3 parts of waterborne floating aluminum paste, 0.2-3 parts of waterborne non-floating aluminum paste, 0.9-4.5 parts of film-forming assistant and 0.1-0.8 part of bacteriostatic agent.

Description

一种水性反射隔热涂料及其制备方法和用途A kind of water-based reflective thermal insulation coating and preparation method and use thereof

技术领域technical field

本发明涉及涂料领域,具体涉及一种水性反射隔热涂料及其制备方法和用途。The invention relates to the field of coatings, in particular to a water-based reflective heat-insulating coating and a preparation method and application thereof.

背景技术Background technique

在夏天的炎炎烈日下,大气温度普遍在30℃以上,当水泥、混凝土、瓷砖、金属、保温砖、玻璃等建筑材料外表面经受长时间的太阳照射时,它们的温度可以达到40-50℃,而当彩钢板、防水材料等经受长时间的太阳照射时,其温度甚至可以达到60-70℃的烫人温度。上述这种情况给正常人类居住、材料存放、设备安全均造成了不利影响。Under the scorching sun in summer, the atmospheric temperature is generally above 30°C. When the outer surfaces of building materials such as cement, concrete, ceramic tiles, metal, thermal insulation bricks, and glass are exposed to the sun for a long time, their temperature can reach 40-50°C. , and when the color steel plate, waterproof material, etc. are exposed to the sun for a long time, the temperature can even reach the scalding temperature of 60-70 ℃. The above situation adversely affects normal human habitation, material storage, and equipment safety.

本领域已知,将反射隔热涂料用于建筑物表面可以有效地降低建筑物表面及内部的温度,并能缓解建筑物表面的温度变化,对建筑物有良好的保护作用。这主要是由于反射隔热涂料成膜后对太阳光的热射线具有高反射、同时又对高的远红外线具有高发射的特点,由此有效地隔绝太阳辐射,实现室内温度降低、节省制冷空调的电耗的效果。反射隔热涂料是建筑节能的新材料,现在已经应用于实际建筑节能工程。然而,现行反射型节能涂料大部分为丙烯酸涂料,随时间变化,丙烯酸涂料具有不耐沾污的缺点。一般而言,丙烯酸涂料的反射效果会在3年内降低50%,在部分空气污染严重的城市,其反射效果的下降速度更快,通常不到2年其反射效果就会降低50%。It is known in the art that using reflective heat-insulating paint on the surface of a building can effectively reduce the temperature on the surface and inside of the building, and can alleviate the temperature change on the surface of the building, and has a good protective effect on the building. This is mainly due to the high reflection of the heat rays of sunlight and the high emission of high far-infrared rays after the reflective thermal insulation coating is formed into a film, thereby effectively isolating solar radiation, reducing indoor temperature and saving refrigeration and air conditioning. effect of power consumption. Reflective thermal insulation coating is a new material for building energy saving, and it has now been applied to actual building energy saving projects. However, most of the current reflective energy-saving paints are acrylic paints, which have the disadvantage of not being stained with time. Generally speaking, the reflective effect of acrylic paint will decrease by 50% within 3 years. In some cities with severe air pollution, the reflective effect will decrease faster, and the reflective effect will usually decrease by 50% in less than 2 years.

目前,铁路设施建设与维护领域正在推行“节支降耗”战略,大量车站和房屋的节能是其内容之一。然而由于铁路旅客站房的建设规模一般较大,并且普遍采用超大金属屋面,另外人员又密集,因此,对屋内温度舒适与节能性要求较高。由此,本领域需要提供一种反射隔热涂料,该种反射隔热涂料的性能较现有反射隔热涂料有显著提高,特别适用于铁路站房屋面。At present, the strategy of “saving expenditure and reducing consumption” is being implemented in the field of railway facility construction and maintenance, and the energy saving of a large number of stations and houses is one of its contents. However, since the construction scale of railway passenger station buildings is generally large, oversized metal roofs are generally used, and people are densely populated, the requirements for indoor temperature comfort and energy saving are relatively high. Therefore, there is a need in the art to provide a reflective thermal insulation coating, the performance of which is significantly improved compared with the existing reflective thermal insulation coatings, and is especially suitable for railway station roofs.

发明内容SUMMARY OF THE INVENTION

针对以上问题,本发明的目的是提供一种水性反射隔热涂料及其制备方法和用途。本发明提供的涂料具有优异的附着性,特别适用于铁路站房屋面,能够降低屋内温度和提升站房防水效果且使用方便快捷,具有明显提高的耐久性和服役年限。In view of the above problems, the purpose of the present invention is to provide a water-based reflective heat-insulating paint and its preparation method and application. The coating provided by the invention has excellent adhesion, is especially suitable for railway station roofs, can reduce indoor temperature and improve the waterproof effect of station buildings, is convenient and quick to use, and has significantly improved durability and service life.

用于实现上述目的的技术方案如下。The technical solution for achieving the above purpose is as follows.

一方面,本发明提供一种水性反射隔热涂料,其中,以重量份数计,所述水性反射隔热涂料包含以下组分:氟硅乳液30-45份、硅丙乳液20-35份、填料9-18份、纳米二氧化钛15-25份、水性漂浮型铝银浆0.2-3份、水性非漂浮型铝银浆0.2-3份、成膜助剂0.9-4.5份、抑菌剂0.1-0.8份;In one aspect, the present invention provides a water-based reflective heat-insulating paint, wherein, in parts by weight, the water-based reflective heat-insulating paint comprises the following components: 30-45 parts of fluorosilicone emulsion, 20-35 parts of silicone-acrylic emulsion, 9-18 parts of filler, 15-25 parts of nano-titanium dioxide, 0.2-3 parts of water-based floating aluminum-silver paste, 0.2-3 parts of water-based non-floating aluminum-silver paste, 0.9-4.5 parts of film-forming aids, and 0.1- 0.8 servings;

优选地,以重量份数计,所述水性反射隔热涂料包含以下组分:氟硅乳液33-38份,硅丙乳液25-32份,填料13.5-16.5份,纳米二氧化钛15-18份,水性漂浮型铝银浆0.5-3份,水性非漂浮型铝银浆0.5-3份,成膜助剂1.5-3份,抑菌剂0.2-0.5份;Preferably, in parts by weight, the water-based reflective thermal insulation coating comprises the following components: 33-38 parts of fluorosilicone emulsion, 25-32 parts of silicone-acrylic emulsion, 13.5-16.5 parts of filler, 15-18 parts of nano-titanium dioxide, 0.5-3 parts of water-based floating aluminum-silver paste, 0.5-3 parts of water-based non-floating aluminum-silver paste, 1.5-3 parts of film-forming aids, and 0.2-0.5 parts of bacteriostatic agents;

更优选地,以重量份数计,所述水性反射隔热涂料包含以下组分:氟硅乳液38份,硅丙乳液25份,填料13.5份,纳米二氧化钛18份,水性漂浮型铝银浆1.5份,水性非漂浮型铝银浆1.5份,成膜助剂2.1份,抑菌剂0.4份;More preferably, in parts by weight, the water-based reflective heat-insulating coating comprises the following components: 38 parts of fluorosilicon emulsion, 25 parts of silicone-acrylic emulsion, 13.5 parts of filler, 18 parts of nano-titanium dioxide, and 1.5 parts of water-based floating aluminum-silver paste parts, 1.5 parts of water-based non-floating aluminum silver paste, 2.1 parts of film-forming aids, and 0.4 parts of bacteriostatic agents;

优选地,所述氟硅乳液为SD-5681氟硅乳液;Preferably, the fluorosilicone emulsion is SD-5681 fluorosilicone emulsion;

优选地,所述硅丙乳液为SD-528硅丙乳液;Preferably, the silicon-acrylic emulsion is SD-528 silicon-acrylic emulsion;

优选地,所述填料包含空心陶瓷微珠、相变微粒、纳米气凝胶微粉;进一步优选地,所述空心陶瓷微珠、相变微粒和纳米气凝胶微粉的重量比为1:1:1;还进一步优选地,所述空心陶瓷微珠的平均粒径为50μm;又进一步优选地,所述相变微粒为有机相变材料微胶囊,平均粒径为40μm,相变温度为35℃;再进一步优选地,所述纳米气凝胶微粉可以为KPore-G200纳米气凝胶微粉;Preferably, the filler comprises hollow ceramic microbeads, phase change microparticles, and nano aerogel micropowder; further preferably, the weight ratio of the hollow ceramic microbeads, phase change microparticles and nano aerogel micropowder is 1:1: 1; Still further preferably, the average particle size of the hollow ceramic microbeads is 50 μm; still further preferably, the phase change particles are organic phase change material microcapsules, the average particle size is 40 μm, and the phase change temperature is 35° C. ; Further preferably, the nano aerogel micropowder can be KPore-G200 nano aerogel micropowder;

优选地,所述纳米二氧化钛为金红石型钛白粉;Preferably, the nano titanium dioxide is rutile titanium dioxide;

优选地,所述水性漂浮型铝银浆的粒径为800目;Preferably, the particle size of the water-based floating aluminum-silver paste is 800 meshes;

优选地,所述水性非漂浮型铝银浆的粒径为800目;Preferably, the particle size of the water-based non-floating aluminum-silver paste is 800 meshes;

优选地,所述水性漂浮型铝银浆与所述水性非漂浮型铝银浆的重量比为1:1;Preferably, the weight ratio of the water-based floating aluminum-silver paste to the water-based non-floating aluminum-silver paste is 1:1;

优选地,所述成膜助剂包含分散剂、消泡剂和流变助剂;进一步优选地,所述分散剂、消泡剂和流变助剂的重量比为1:1:1;再进一步优选地,所述分散剂为

Figure BDA0002727341880000031
NC多聚磷酸钠盐分散剂;又进一步优选地,所述消泡剂为DH-202消泡剂;更进一步优选地,所述流变助剂为RHEOLATE299水性流变助剂;Preferably, the film-forming aid comprises a dispersant, a defoamer and a rheology aid; further preferably, the weight ratio of the dispersant, the defoamer and the rheology aid is 1:1:1; Further preferably, the dispersant is
Figure BDA0002727341880000031
NC polyphosphate sodium salt dispersant; further preferably, the defoamer is DH-202 defoamer; further preferably, the rheology aid is RHEOLATE299 aqueous rheology aid;

优选地,所述抑菌剂为DEUADD MB-11水性防腐剂;Preferably, the bacteriostatic agent is DEUADD MB-11 aqueous preservative;

在本发明的一些具体实施方案中,在本发明的水性反射隔热涂料中,氟硅乳液购自南通生达化工有限公司,工业级。硅丙乳液购自南通生达化工有限公司,工业级。空心陶瓷微珠购自上海汇精亚纳米新材料有限公司,平均粒径50μm。相变微粒购自湖北赛默新能源科技有限公司,型号为TH-ME35,平均粒径为40μm,相变温度为35℃。纳米气凝胶微粉购自苏州同玄新材料有限公司。纳米二氧化钛购自日本石原公司。水性漂浮型铝银浆和水性非漂浮型铝银浆购自苏州曼特博合金材料有限公司,两者的重量比为1:1。分散剂购自上海通洋化工有限公司,消泡剂购自上海鼎和化学科技有限公司,流变助剂购自上海凯茵化工有限公司,抑菌剂购自广州市金圣吉化工有限公司。In some specific embodiments of the present invention, in the water-based reflective thermal insulation coating of the present invention, the fluorosilicon emulsion is purchased from Nantong Shengda Chemical Co., Ltd., industrial grade. Silicone-acrylic emulsion was purchased from Nantong Shengda Chemical Co., Ltd., industrial grade. The hollow ceramic microspheres were purchased from Shanghai Huijing Sub-nano New Materials Co., Ltd., with an average particle size of 50 μm. The phase change particles were purchased from Hubei Thermo New Energy Technology Co., Ltd., the model is TH-ME35, the average particle size is 40 μm, and the phase change temperature is 35 °C. Nano aerogel powder was purchased from Suzhou Tongxuan New Materials Co., Ltd. Nano-titanium dioxide was purchased from Japan Ishihara Company. The water-based floating aluminum-silver paste and the water-based non-floating aluminum-silver paste were purchased from Suzhou Mantebo Alloy Materials Co., Ltd., and the weight ratio of the two was 1:1. The dispersant was purchased from Shanghai Tongyang Chemical Co., Ltd., the defoamer was purchased from Shanghai Dinghe Chemical Technology Co., Ltd., the rheological additive was purchased from Shanghai Kaiyin Chemical Co., Ltd., and the bacteriostatic agent was purchased from Guangzhou Jinshengji Chemical Co., Ltd.

另一方面,本发明还提供一种上述水性反射隔热涂料的制备方法,所述方法包括如下步骤:On the other hand, the present invention also provides a preparation method of the above-mentioned water-based reflective thermal insulation coating, the method comprising the following steps:

1)将预先称量的氟硅乳液,硅丙乳液,水性漂浮型铝银浆、水性非漂浮型铝银浆、成膜助剂、抑菌剂置于容器中,以1000-1200r/min的搅拌速率分散10-15分钟,得预混物;1) Place the pre-weighed fluorosilicone emulsion, silicone acrylic emulsion, water-based floating aluminum-silver paste, water-based non-floating aluminum-silver paste, film-forming aids, and bacteriostatic agents in a container, at a rate of 1000-1200 r/min. The stirring speed is dispersed for 10-15 minutes to obtain a premix;

2)在搅拌状态下,向步骤1)得到的预混物中加入填料和纳米二氧化钛,然后以1000-1500r/min的速率搅拌分散20-30分钟,研磨,即得。2) In a stirring state, add filler and nano-titanium dioxide to the premix obtained in step 1), then stir and disperse for 20-30 minutes at a rate of 1000-1500 r/min, and grind to obtain.

优选地,在步骤1)中,所述搅拌速率为1100-1200r/min,优选为1200r/min;Preferably, in step 1), the stirring rate is 1100-1200r/min, preferably 1200r/min;

优选地,在步骤1)中,分散时间为12-14分钟,优选为14分钟;Preferably, in step 1), the dispersion time is 12-14 minutes, preferably 14 minutes;

优选地,在步骤2)中,所述搅拌速率为1300-1450r/min,优选为1400r/min;Preferably, in step 2), the stirring rate is 1300-1450r/min, preferably 1400r/min;

优选地,在步骤2)中,分散时间为24-28分钟,优选为26分钟。Preferably, in step 2), the dispersion time is 24-28 minutes, preferably 26 minutes.

再一方面,本发明还提供一种隔热系统,其中,当应用于非金属基面时,所述隔热系统包含封闭层和反射隔热涂层;当应用于金属基面时,所述隔热系统包含防腐底漆层和反射隔热涂层;其中,所述反射隔热涂层是由上述水性反射隔热涂料经刮涂或喷涂形成。In yet another aspect, the present invention also provides a thermal insulation system, wherein, when applied to a non-metallic base surface, the thermal insulation system comprises a sealing layer and a reflective thermal insulation coating; when applied to a metal base surface, the thermal insulation system The thermal insulation system includes an anti-corrosion primer layer and a reflective thermal insulation coating; wherein, the reflective thermal insulation coating is formed from the above-mentioned water-based reflective thermal insulation coating by scraping or spraying.

优选地,所述封闭层由环氧类封闭底漆经刮涂或喷涂形成;根据本发明的具体实施方式,所述环氧类封闭底漆为水性环氧封闭底漆,购自廊坊三通化学工业有限公司。Preferably, the sealing layer is formed by scraping or spraying an epoxy-based sealing primer; according to a specific embodiment of the present invention, the epoxy-based sealing primer is a water-based epoxy sealing primer, purchased from Langfang Santong Chemical Industry Co., Ltd.

优选地,所述防腐底漆层为ZD800(W)水性环氧富锌底漆;根据本发明的具体实施方式,所述ZD800(W)水性环氧富锌底漆购自天津市双狮涂料有限公司。Preferably, the anti-corrosion primer layer is ZD800 (W) water-based epoxy zinc-rich primer; according to a specific embodiment of the present invention, the ZD800 (W) water-based epoxy zinc-rich primer is purchased from Tianjin Shuangshi Paint Ltd.

优选地,反射隔热涂层的刮涂或喷涂厚度为800-1500μm;更优选地为900-1300μm;进一步优选地为1000μm。Preferably, the blade or spray thickness of the reflective heat-insulating coating is 800-1500 μm; more preferably 900-1300 μm; further preferably 1000 μm.

又一方面,本发明还提供本发明所述的水性反射隔热涂料在建筑物表面、无砟轨道结构的表面的防护中的用途。In another aspect, the present invention also provides the use of the water-based reflective heat-insulating paint of the present invention in the protection of the building surface and the surface of the ballastless track structure.

再又一方面,本发明提供上述水性反射隔热涂料的施用方法,所述方法包括:In yet another aspect, the present invention provides an application method of the above-mentioned water-based reflective thermal insulation coating, the method comprising:

1)在待防护基面上刮涂或喷涂封闭层/防腐底漆层;1) Scratch or spray the sealing layer/anti-corrosion primer layer on the base surface to be protected;

2)将上述水性反射隔热涂料刮涂或喷涂于步骤1)的封闭层/防腐底漆层上。2) Scratch or spray the above water-based reflective heat-insulating paint on the sealing layer/anti-corrosion primer layer of step 1).

优选地,所述封闭层由环氧类封闭底漆经刮涂或喷涂形成;Preferably, the sealing layer is formed by scraping or spraying epoxy sealing primer;

优选地,所述防腐底漆层为ZD800(W)水性环氧富锌底漆。Preferably, the anti-corrosion primer layer is ZD800(W) water-based epoxy zinc-rich primer.

本发明提供的水性反射隔热涂料至少具有以下优点:The water-based reflective heat-insulating paint provided by the present invention has at least the following advantages:

1、本发明提供的水性反射隔热涂料具有反射阳光的作用,当在屋面上使用时,可减少由于阳光照射而产生的温升,降低屋内环境温度,对节能降耗具有显著促进作用。另外,本发明提供的水性反射隔热涂料具有优异的物理力学性能、附着性和紫外线辐射性能,长时间使用不会出现变色、龟裂和剥落等损害,能够起到高效防护作用。1. The water-based reflective heat-insulating paint provided by the present invention has the effect of reflecting sunlight. When used on the roof, it can reduce the temperature rise caused by sunlight, reduce the indoor ambient temperature, and significantly promote energy saving and consumption reduction. In addition, the water-based reflective heat-insulating paint provided by the present invention has excellent physical and mechanical properties, adhesion and ultraviolet radiation properties, and will not cause damage such as discoloration, cracking and peeling after long-term use, and can play an efficient protective role.

2、本发明提供的水性反射隔热涂料中采用了适当配比的氟硅乳液、硅丙乳液、填料、纳米二氧化钛、水性漂浮型铝银浆、水性非漂浮型铝银浆,其中氟硅乳液与硅丙乳液混合作为涂料的成膜物质,使其得到的涂膜既具有防污、防尘和耐候耐久的效果,同时涂膜固化后能够在表面形成疏水层,避免冻融伤损;水性非漂浮型铝银浆可使铝粉在由本发明的水性反射隔热涂料形成的反射隔热涂层的中部或底部位置成片,水性漂浮型铝银浆可使铝粉在所述反射隔热涂层的表面位置成片,由此形成了“双层铝膜”反射。同时,金红石型纳米二氧化钛也对太阳光具有良好的反射作用,多重作用下大幅提高了本发明的水性反射隔热涂料的太阳光反射率。此外,采用硅丙乳液与氟硅乳液共同成膜后,能够有效提升防污、防尘等效果,避免了随时间延长污染物粘附而造成的反射效果降低;硅丙乳液的加入对氟硅乳液的改性也可大幅提升所述反射隔热涂层对固态微粒(颗粒填料)和底漆(即封闭层/防腐底漆层)的附着力,同时可以提高所形成的隔热体系的整体性能。空心陶瓷微珠、相变微粒、纳米气凝胶微粉的组合使用可大幅降低涂层的导热系数,特别是相变微粒的添加,在超过相变温度点时能吸热量,保持所述反射隔热涂层体系温度处于设定温度以下,能有效控制极端高温天气的峰值温度,保证本发明的水性反射隔热涂料的节能效果。2. The water-based reflective heat-insulating paint provided by the present invention adopts appropriate proportions of fluorosilicon emulsion, silicone-acrylic emulsion, filler, nano-titanium dioxide, water-based floating aluminum-silver paste, and water-based non-floating aluminum-silver paste, among which the fluorosilicon emulsion It is mixed with silicone-acrylic emulsion as a film-forming substance of the coating, so that the obtained coating film has the effects of anti-fouling, dust-proof and weather resistance, and at the same time, after the coating film is cured, a hydrophobic layer can be formed on the surface to avoid freeze-thaw damage; water-based The non-floating aluminum-silver paste can make the aluminum powder form a sheet at the middle or bottom of the reflective heat-insulating coating formed by the water-based reflective heat-insulating coating of the present invention, and the water-based floating aluminum-silver paste can make the aluminum powder in the reflective heat-insulating coating of the present invention. The surface position of the coating is in flakes, thereby forming a "double aluminum film" reflection. At the same time, the rutile-type nano-titanium dioxide also has a good reflection effect on sunlight, which greatly improves the sunlight reflectivity of the water-based reflective heat-insulating paint of the present invention under multiple effects. In addition, the use of silicone-acrylic emulsion and fluorosilicone emulsion to form a film can effectively improve the anti-fouling, dust-proof and other effects, and avoid the reduction of reflection effect caused by the adhesion of pollutants over time; the addition of silicone-acrylic emulsion to fluorosilicone The modification of the emulsion can also greatly improve the adhesion of the reflective thermal insulation coating to solid particles (particle fillers) and primers (ie sealer/anti-corrosion primer layer), and at the same time can improve the overall thermal insulation system formed. performance. The combined use of hollow ceramic microbeads, phase change particles, and nano-aerogel micropowders can greatly reduce the thermal conductivity of the coating, especially the addition of phase change particles, which can absorb heat when the phase transition temperature is exceeded and maintain the reflection. The temperature of the thermal insulation coating system is below the set temperature, which can effectively control the peak temperature in extreme high temperature weather and ensure the energy saving effect of the water-based reflective thermal insulation coating of the present invention.

3、本发明提供的水性反射隔热涂料也可用于无砟轨道结构的表面防护,将其涂装于钢轨下混凝土轨道板表面或道床板表面时,由于所述水性反射隔热涂料可降低由阳光照射热量聚集而产生的昼夜温差,降低轨道板翘曲量,减少甚至消除板角离缝或道床板上拱等损害,能够很好地提升对平顺度要求严格的无砟轨道高速铁路的耐久性。3. The water-based reflective heat-insulating paint provided by the present invention can also be used for the surface protection of the ballastless track structure. When it is painted on the surface of the concrete track slab under the rail or the surface of the ballast slab, the water-based reflective heat-insulating paint can reduce the amount of heat generated by the water-based reflective heat-insulating paint. The temperature difference between day and night caused by the accumulation of sunlight and heat can reduce the warpage of the track slab, reduce or even eliminate the damage of the slab corner seam or the arch of the track slab. sex.

4、本发明提供的水性反射隔热涂料可通过喷涂、刷涂的方式涂覆于待防护基材表面,可采用多种设备进行施工,工作人员根据现场涂装实际情况能够更容易地选用适宜的施工设备。由此可见,本发明提供的水性反射隔热涂料更便于使用。4. The water-based reflective heat-insulating paint provided by the present invention can be applied to the surface of the substrate to be protected by spraying and brushing. Various equipment can be used for construction, and the staff can more easily select the appropriate one according to the actual situation of on-site painting. construction equipment. It can be seen that the water-based reflective heat-insulating paint provided by the present invention is more convenient to use.

5、本发明提供的隔热系统,使基材表面自下而上形成封闭层/防腐底漆层和反射隔热层,保证了反射隔热涂层体系的附着牢靠。5. The thermal insulation system provided by the present invention makes the surface of the substrate form a sealing layer/anti-corrosion primer layer and a reflective thermal insulation layer from bottom to top, which ensures the reliable adhesion of the reflective thermal insulation coating system.

附图说明Description of drawings

以下,结合附图来详细说明本发明的实施方案,其中:Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings, wherein:

图1为屋顶彩钢基面经涂覆本发明所述水性反射隔热涂料后的示意图。Fig. 1 is a schematic diagram of a roof color steel base surface after being coated with the water-based reflective heat-insulating paint of the present invention.

具体实施方式Detailed ways

以下参照具体的实施例来说明本发明。本领域技术人员能够理解,这些实施例仅用于说明本发明,其不以任何方式限制本发明的范围。The present invention will be described below with reference to specific examples. Those skilled in the art can understand that these examples are only for illustrating the present invention, and they do not limit the scope of the present invention in any way.

下述实施例中的实验方法,如无特殊说明,均为常规方法。下述实施例中所用的原料、试剂材料等,如无特殊说明,均为市售购买产品。The experimental methods in the following examples are conventional methods unless otherwise specified. The raw materials, reagent materials, etc. used in the following examples are all commercially available products unless otherwise specified.

在以下实施例中,所采用的氟硅乳液购自南通生达化工有限公司,工业级。硅丙乳液购自南通生达化工有限公司,工业级。空心陶瓷微珠购自上海汇精亚纳米新材料有限公司,平均粒径50μm。相变微粒购自湖北赛默新能源科技有限公司,型号为TH-ME35,平均粒径为40μm,相变温度为35℃。纳米气凝胶微粉购自苏州同玄新材料有限公司。纳米二氧化钛购自日本石原公司。水性漂浮型铝银浆和水性非漂浮型铝银浆购自苏州曼特博合金材料有限公司,两者的重量比为1:1。分散剂购自上海通洋化工有限公司,消泡剂购自上海鼎和化学科技有限公司,流变助剂购自上海凯茵化工有限公司,抑菌剂购自广州市金圣吉化工有限公司。In the following examples, the fluorosilicon emulsion used was purchased from Nantong Shengda Chemical Co., Ltd., industrial grade. Silicone-acrylic emulsion was purchased from Nantong Shengda Chemical Co., Ltd., industrial grade. The hollow ceramic microspheres were purchased from Shanghai Huijing Sub-nano New Materials Co., Ltd., with an average particle size of 50 μm. The phase change particles were purchased from Hubei Thermo New Energy Technology Co., Ltd., the model is TH-ME35, the average particle size is 40 μm, and the phase change temperature is 35 °C. Nano aerogel powder was purchased from Suzhou Tongxuan New Materials Co., Ltd. Nano-titanium dioxide was purchased from Japan Ishihara Company. The water-based floating aluminum-silver paste and the water-based non-floating aluminum-silver paste were purchased from Suzhou Mantebo Alloy Materials Co., Ltd., and the weight ratio of the two was 1:1. The dispersant was purchased from Shanghai Tongyang Chemical Co., Ltd., the defoamer was purchased from Shanghai Dinghe Chemical Technology Co., Ltd., the rheological additive was purchased from Shanghai Kaiyin Chemical Co., Ltd., and the bacteriostatic agent was purchased from Guangzhou Jinshengji Chemical Co., Ltd.

所采用的防腐底漆为ZD800(W)水性环氧富锌底漆,购自天津市双狮涂料有限公司。The anti-corrosion primer used was ZD800 (W) water-based epoxy zinc-rich primer, purchased from Tianjin Shuangshi Paint Co., Ltd.

实施例1水性反射隔热涂料 Example 1 Water-based reflective thermal insulation coating

在本实施例中,以重量份数计,所制备的水性反射隔热涂料由以下组分制成:氟硅乳液30份、硅丙乳液35份、空心陶瓷微珠3份、相变微粒3份、纳米气凝胶微粉3份、纳米二氧化钛20份、水性漂浮型铝银浆0.35份、水性非漂浮型铝银浆0.35份、分散剂1.5份、消泡剂1.5份、流变助剂1.5份、抑菌剂0.8份;In this example, in parts by weight, the prepared water-based reflective thermal insulation coating is made of the following components: 30 parts of fluorosilicone emulsion, 35 parts of silicone-acrylic emulsion, 3 parts of hollow ceramic microbeads, and 3 parts of phase change particles parts, 3 parts of nano aerogel powder, 20 parts of nano titanium dioxide, 0.35 parts of water-based floating aluminum silver paste, 0.35 parts of water-based non-floating aluminum silver paste, 1.5 parts of dispersant, 1.5 parts of defoamer, 1.5 parts of rheology additives part, 0.8 part of bacteriostatic agent;

其制备方法如下:Its preparation method is as follows:

将氟硅乳液,硅丙乳液,水性漂浮型铝银浆、水性非漂浮型铝银浆、成膜助剂、抑菌剂置于容器中,以1200r/min的搅拌速率分散14分钟,得预混物。边搅拌边向所述预混物中加入填料、纳米二氧化钛,再以1400r/min搅拌分散26分钟,研磨,即得。Put fluorosilicone emulsion, silicone acrylic emulsion, water-based floating aluminum silver paste, water-based non-floating aluminum silver paste, film-forming aids, and bacteriostatic agents in a container, and disperse at a stirring speed of 1200 r/min for 14 minutes to obtain a mixture. Add filler and nano-titanium dioxide to the premix while stirring, and then stir and disperse at 1400 r/min for 26 minutes, and grind to obtain.

实施例2至6和对比例1至5:水性反射隔热涂料 Examples 2 to 6 and Comparative Examples 1 to 5: Waterborne Reflective Thermal Insulation Coatings

实施例2至6与对比例1至5均按照实施例1中的制备方法制备,具体组分组成见表1。Examples 2 to 6 and Comparative Examples 1 to 5 were all prepared according to the preparation method in Example 1, and the specific component compositions are shown in Table 1.

表1:实施例1-6和对比例1-5制备的水性反射隔热涂料所包含的组分组成。Table 1: Component composition of the water-based reflective thermal insulation coatings prepared in Examples 1-6 and Comparative Examples 1-5.

Figure BDA0002727341880000071
Figure BDA0002727341880000071

实施例7:性能测试Example 7: Performance Test

1、测试样板的制备1. Preparation of test samples

为了更好地模拟实际应用条件,本实施例采用“防腐底漆层+反射隔热涂层”的隔热体系进行性能测试,测试样板为3mm喷砂钢板,防腐底漆为ZD800(W)水性环氧富锌底漆(天津市双狮涂料有限公司),根据不同的测试需求刮涂反射隔热涂层,进行性能测试,其中耐盐雾性能、太阳光反射能力测试的配套反射隔热涂层厚度为1.0mm。In order to better simulate the actual application conditions, in this example, the thermal insulation system of "anti-corrosion primer layer + reflective thermal insulation coating" is used for performance test, the test sample is 3mm sandblasted steel plate, and the anti-corrosion primer is ZD800(W) water-based Epoxy zinc-rich primer (Tianjin Shuangshi Coating Co., Ltd.), according to different test requirements, scrape the reflective thermal insulation coating for performance testing, among which the supporting reflective thermal insulation coating for salt spray resistance and sunlight reflection ability test The layer thickness is 1.0 mm.

制备反射隔热涂层测试样板的方法如下:The method for preparing the reflective thermal barrier coating test panel is as follows:

步骤1:将基面表面的浮尘、污物等清理干净,待表面干燥后喷涂防腐底漆;Step 1: Clean up the floating dust and dirt on the surface of the base surface, and spray the anti-corrosion primer after the surface is dry;

步骤2:喷涂防腐底漆24h后或者底漆实干后,再刷涂所述水性反射隔热涂料;Step 2: After spraying the anti-corrosion primer for 24 hours or after the primer is dry, brush the water-based reflective thermal insulation coating;

步骤3:刷涂水性反射隔热涂料24h后或者反射隔热涂料实干后,即得。Step 3: After brushing the water-based reflective heat-insulating paint for 24 hours or after the reflective heat-insulating paint is dry, it is obtained.

本实施例中,防腐底漆层的厚度为完全覆盖基面,所述水性反射隔热层干膜厚度为1300μm,本发明所述的具体涂层结构如图1所示。In this embodiment, the thickness of the anti-corrosion primer layer is to completely cover the base surface, the dry film thickness of the water-based reflective heat insulation layer is 1300 μm, and the specific coating structure of the present invention is shown in FIG. 1 .

将由实施例1至6及对比例1至5的水性反射隔热涂料制备的测试样板分别命名为样板1-6和对比样板1-5。The test panels prepared from the water-based reflective thermal insulation coatings of Examples 1 to 6 and Comparative Examples 1 to 5 were named as Samples 1-6 and Comparative Samples 1-5, respectively.

2、性能测试2. Performance test

对样板1-6和对比样板1-5的性能测试结果如表2所示。其中,The performance test results of samples 1-6 and comparative samples 1-5 are shown in Table 2. in,

适用期按TB/T1527-2011的规定进行测试;The applicable period shall be tested according to the provisions of TB/T1527-2011;

低温柔性(-40℃)按GB/T 6742-2007的规定进行测试;Low temperature flexibility (-40℃) is tested according to GB/T 6742-2007;

附着力按GB/T 5210-2006的规定进行测试;Adhesion is tested according to GB/T 5210-2006;

太阳光反射比、近红外反射比、半球发射率、污染后的太阳光反射比变化率、人工气候老化后太阳光反射比变化率、隔热温差按JG/T 235-2014的规定进行测试;Solar reflectance, near-infrared reflectance, hemispheric emissivity, change rate of solar reflectance after pollution, change rate of sunlight reflectance after artificial weathering, and thermal insulation temperature difference are tested according to the provisions of JG/T 235-2014;

耐人工加速老化按GB/T14522-2008的规定进行测试;The resistance to artificial accelerated aging shall be tested according to the provisions of GB/T14522-2008;

经测试,样板1-6和对比样板1-5适用期均大于90min,可满足操作要求。After testing, the pot life of samples 1-6 and comparative samples 1-5 is more than 90min, which can meet the operation requirements.

表2实施例1-6和对比例1-5的性能测试结果Table 2 Performance test results of Examples 1-6 and Comparative Examples 1-5

Figure BDA0002727341880000091
Figure BDA0002727341880000091

由上述内容可以看出,本发明提供的水性反射隔热涂料形成的反射隔热层具有良好的附着力、热反射和隔热性能,其耐人工加速老化可达3000h以上、太阳反射比超过90%,这些优异的性能很好地保证了本发明所述的反射隔热涂层的服役耐久性,能够有效防止构件温升/温差变形。It can be seen from the above content that the reflective thermal insulation layer formed by the water-based reflective thermal insulation coating provided by the present invention has good adhesion, heat reflection and thermal insulation performance, its resistance to artificial accelerated aging can reach more than 3000h, and the solar reflectance ratio exceeds 90. %, these excellent properties can well ensure the service durability of the reflective thermal insulation coating of the present invention, and can effectively prevent the temperature rise/temperature difference deformation of components.

表2表明,实施例1-6的各项性能都显著优于对比例1-5,尤其是耐人工加速老化、太阳反射比非常突出,可有效对待防护基面进行耐久性和结构稳定性的防护。Table 2 shows that the properties of Examples 1-6 are significantly better than those of Comparative Examples 1-5, especially the artificial accelerated aging resistance and the outstanding solar reflectance, which can effectively improve the durability and structural stability of the protective base surface. protection.

总之,以上对本发明具体实施方式的描述并不限制本发明,本领域技术人员可以根据本发明作出各种改变或变形,只要不脱离本发明的精神,均应属于本发明所附权利要求的范围。In a word, the above description of the specific embodiments of the present invention does not limit the present invention, and those skilled in the art can make various changes or modifications according to the present invention, as long as they do not depart from the spirit of the present invention, they should all belong to the scope of the appended claims of the present invention .

Claims (9)

1.一种水性反射隔热涂料,其中,以重量份数计,所述水性反射隔热涂料包含以下组分:氟硅乳液30-45份,硅丙乳液20-35份,填料9-18份、纳米二氧化钛15-25份、水性漂浮型铝银浆0.2-3份、水性非漂浮型铝银浆0.2-3份、成膜助剂0.9-4.5份、抑菌剂0.1-0.8份。1. A water-based reflective heat-insulating paint, wherein, in parts by weight, the water-based reflective heat-insulating paint comprises the following components: 30-45 parts of fluorosilicone emulsion, 20-35 parts of silicone-acrylic emulsion, 9-18 parts of filler parts, 15-25 parts of nano titanium dioxide, 0.2-3 parts of water-based floating aluminum-silver paste, 0.2-3 parts of water-based non-floating aluminum-silver paste, 0.9-4.5 parts of film-forming aids, and 0.1-0.8 parts of bacteriostatic agents. 2.根据权利要求1所述的水性反射隔热涂料,其中,以重量份数计,所述水性反射隔热涂料包含以下组分:氟硅乳液33-38份,硅丙乳液25-32份,填料13.5-16.5份,纳米二氧化钛15-18份,水性漂浮型铝银浆0.5-3份,水性非漂浮型铝银浆0.5-3份、成膜助剂1.5-3份、抑菌剂0.2-0.5份;2. The water-based reflective heat-insulating paint according to claim 1, wherein, in parts by weight, the water-based reflective heat-insulating paint comprises the following components: 33-38 parts of fluorosilicone emulsion, 25-32 parts of silicon-acrylic emulsion , 13.5-16.5 parts of filler, 15-18 parts of nano-titanium dioxide, 0.5-3 parts of water-based floating aluminum silver paste, 0.5-3 parts of water-based non-floating aluminum silver paste, 1.5-3 parts of film-forming aids, 0.2 parts of bacteriostatic agent - 0.5 servings; 优选地,以重量份数计,所述水性反射隔热涂料包含以下组分:氟硅乳液38份,硅丙乳液25份,填料13.5份,纳米二氧化钛18份,水性漂浮型铝银浆1.5份,水性非漂浮型铝银浆1.5份,成膜助剂2.1份,抑菌剂0.4份。Preferably, in parts by weight, the water-based reflective heat-insulating paint comprises the following components: 38 parts of fluorosilicon emulsion, 25 parts of silicone-acrylic emulsion, 13.5 parts of filler, 18 parts of nano-titanium dioxide, and 1.5 parts of water-based floating aluminum-silver paste , 1.5 parts of water-based non-floating aluminum silver paste, 2.1 parts of film-forming aids, and 0.4 parts of bacteriostatic agent. 3.根据权利要求1或2所述的水性反射隔热涂料,其中,所述氟硅乳液为SD-5681氟硅乳液;3. The water-based reflective thermal insulation coating according to claim 1 or 2, wherein the fluorosilicon emulsion is SD-5681 fluorosilicon emulsion; 优选地,所述硅丙乳液为SD-528硅丙乳液;Preferably, the silicon-acrylic emulsion is SD-528 silicon-acrylic emulsion; 优选地,所述填料包含空心陶瓷微珠、相变微粒、纳米气凝胶微粉;进一步优选地,所述空心陶瓷微珠、相变微粒和纳米气凝胶微粉的重量比为1∶1∶1;还进一步优选地,所述空心陶瓷微珠的平均粒径为50μm;又进一步优选地,所述相变微粒为有机相变材料微胶囊,平均粒径为40μm,相变温度为35℃;再进一步优选地,所述纳米气凝胶微粉可以为KPore-G200纳米气凝胶微粉;Preferably, the filler comprises hollow ceramic microbeads, phase change microparticles, and nano aerogel micropowder; further preferably, the weight ratio of the hollow ceramic microbeads, phase change microparticles and nano aerogel micropowder is 1:1: 1; Still further preferably, the average particle size of the hollow ceramic microbeads is 50 μm; still further preferably, the phase change particles are organic phase change material microcapsules, the average particle size is 40 μm, and the phase change temperature is 35° C. ; Further preferably, the nano aerogel micropowder can be KPore-G200 nano aerogel micropowder; 优选地,所述纳米二氧化钛为金红石型钛白粉;Preferably, the nano titanium dioxide is rutile titanium dioxide; 优选地,所述水性漂浮型铝银浆的粒径为800目;Preferably, the particle size of the water-based floating aluminum-silver paste is 800 meshes; 优选地,所述水性非漂浮型铝银浆的粒径为800目;Preferably, the particle size of the water-based non-floating aluminum-silver paste is 800 meshes; 优选地,所述水性漂浮型铝银浆与所述水性非漂浮型铝银浆的重量比为1∶1;Preferably, the weight ratio of the water-based floating aluminum-silver paste to the water-based non-floating aluminum-silver paste is 1:1; 优选地,所述成膜助剂包含分散剂、消泡剂和流变助剂;进一步优选地,所述分散剂、消泡剂和流变助剂的重量比为1∶1∶1;再进一步优选地,所述分散剂为
Figure FDA0002727341870000021
多聚磷酸钠盐分散剂;又进一步优选地,所述消泡剂为DH-202消泡剂;更进一步优选地,所述流变助剂为RHEOLATE299水性流变助剂;
Preferably, the film-forming aid comprises a dispersant, a defoamer and a rheology aid; further preferably, the weight ratio of the dispersant, the defoamer and the rheology aid is 1:1:1; Further preferably, the dispersant is
Figure FDA0002727341870000021
Sodium polyphosphate dispersant; further preferably, the defoamer is DH-202 defoamer; further preferably, the rheology aid is RHEOLATE299 aqueous rheology aid;
优选地,所述抑菌剂为DEUADD MB-11水性防腐剂。Preferably, the bacteriostatic agent is DEUADD MB-11 aqueous preservative.
4.权利要求1-3中任一项所述的水性反射隔热涂料的制备方法,所述方法包括如下步骤:4. the preparation method of the water-based reflective thermal insulation coating described in any one of claim 1-3, described method comprises the steps: 1)将预先称量的氟硅乳液,硅丙乳液,水性漂浮型铝银浆、水性非漂浮型铝银浆、成膜助剂、抑菌剂置于容器中,以1000-1200r/min的搅拌速率分散10-15分钟,得预混物;1) Place the pre-weighed fluorosilicone emulsion, silicone acrylic emulsion, water-based floating aluminum-silver paste, water-based non-floating aluminum-silver paste, film-forming aids, and bacteriostatic agents in a container, at a rate of 1000-1200 r/min. The stirring speed is dispersed for 10-15 minutes to obtain a premix; 2)在搅拌状态下,向步骤1)得到的预混物中加入填料和纳米二氧化钛,然后以1000-1500r/min的速率搅拌分散20-30分钟,研磨,即得。2) In a stirring state, add filler and nano-titanium dioxide to the premix obtained in step 1), then stir and disperse for 20-30 minutes at a rate of 1000-1500 r/min, and grind to obtain. 5.根据权利要求4所述的制备方法,其中,在步骤1)中,所述搅拌速率为1100-1200r/min;优选为1200r/min;5. The preparation method according to claim 4, wherein, in step 1), the stirring rate is 1100-1200r/min; preferably 1200r/min; 优选地,在步骤1)中,分散时间为12-14分钟,更优选为14分钟;Preferably, in step 1), the dispersion time is 12-14 minutes, more preferably 14 minutes; 优选地,在步骤2)中,所述搅拌速率为1300-1450r/min,更优选为1400r/min;Preferably, in step 2), the stirring rate is 1300-1450r/min, more preferably 1400r/min; 优选地,在步骤2)中,分散时间为24-28分钟,更优选为26分钟。Preferably, in step 2), the dispersion time is 24-28 minutes, more preferably 26 minutes. 6.一种隔热系统,其中,当应用于非金属基面时,所述隔热系统包含封闭层和反射隔热涂层;当应用于金属基面时,所述隔热系统包含防腐底漆层和反射隔热涂层,其中,所述反射隔热涂层由权利要求1-3中任一项所述的水性反射隔热涂料经刮涂或喷涂形成。6. A thermal insulation system, wherein, when applied to a non-metallic base, the thermal insulation system comprises a sealing layer and a reflective thermal insulation coating; when applied to a metallic base, the thermal insulation system comprises an anti-corrosion base A paint layer and a reflective thermal insulation coating, wherein the reflective thermal insulation coating is formed from the water-based reflective thermal insulation coating according to any one of claims 1 to 3 by scraping or spraying. 7.根据权利要求6所述的隔热系统,其中,所述封闭层由环氧类封闭底漆经刮涂或喷涂形成;7. The thermal insulation system according to claim 6, wherein the sealing layer is formed by blade coating or spraying of epoxy sealing primer; 优选地,所述防腐底漆层为ZD800(W)水性环氧富锌底漆;Preferably, the anti-corrosion primer layer is ZD800 (W) water-based epoxy zinc-rich primer; 优选地,反射隔热涂层的刮涂或喷涂厚度为800-1500μm;更优选地为900-1300μm;进一步优选为1000μm。Preferably, the blade or spray thickness of the reflective thermal insulation coating is 800-1500 μm; more preferably 900-1300 μm; further preferably 1000 μm. 8.权利要求1-3中任一项所述的水性反射隔热涂料或权利要求6-7所述的隔热系统在建筑物表面、无砟轨道结构的表面的防护中的用途。8. Use of the water-based reflective thermal insulation coating according to any one of claims 1 to 3 or the thermal insulation system of claims 6 to 7 in the protection of building surfaces and surfaces of ballastless track structures. 9.权利要求1-3中任一项所述的水性反射隔热涂料的施用方法,所述方法包括:9. The application method of the water-based reflective thermal insulation coating of any one of claims 1-3, the method comprising: 1)在待防护基面上刮涂或喷涂封闭层/防腐底漆层;1) Scratch or spray the sealing layer/anti-corrosion primer layer on the base surface to be protected; 2)将权利要求1-3中任一项所述的水性反射隔热涂料刮涂或喷涂于步骤1)的封闭层/防腐底漆层上;2) scraping or spraying the water-based reflective heat-insulating paint described in any one of claims 1-3 on the sealing layer/anti-corrosion primer layer of step 1); 优选地,所述封闭层由环氧类封闭底漆经刮涂或喷涂形成;Preferably, the sealing layer is formed by scraping or spraying epoxy sealing primer; 优选地,所述防腐底漆层为ZD800(W)水性环氧富锌底漆。Preferably, the anti-corrosion primer layer is ZD800(W) water-based epoxy zinc-rich primer.
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