[go: up one dir, main page]

CN112341166A - Ceramic hand mold coating suitable for nitrile rubber glove production and preparation method thereof - Google Patents

Ceramic hand mold coating suitable for nitrile rubber glove production and preparation method thereof Download PDF

Info

Publication number
CN112341166A
CN112341166A CN202011412127.6A CN202011412127A CN112341166A CN 112341166 A CN112341166 A CN 112341166A CN 202011412127 A CN202011412127 A CN 202011412127A CN 112341166 A CN112341166 A CN 112341166A
Authority
CN
China
Prior art keywords
parts
nitrile rubber
ceramic hand
coating suitable
hand mold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202011412127.6A
Other languages
Chinese (zh)
Other versions
CN112341166B (en
Inventor
耿宪兵
王丙志
刘新玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zibo Haoxiang Mould Technology Co ltd
Original Assignee
Zibo Haoxiang Mould Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zibo Haoxiang Mould Technology Co ltd filed Critical Zibo Haoxiang Mould Technology Co ltd
Priority to CN202011412127.6A priority Critical patent/CN112341166B/en
Publication of CN112341166A publication Critical patent/CN112341166A/en
Application granted granted Critical
Publication of CN112341166B publication Critical patent/CN112341166B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • C04B35/62209Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse using woody material, remaining in the ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62222Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining ceramic coatings
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5031Alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/87Ceramics
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206Magnesium oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3229Cerium oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3239Vanadium oxides, vanadates or oxide forming salts thereof, e.g. magnesium vanadate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3284Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3293Tin oxides, stannates or oxide forming salts thereof, e.g. indium tin oxide [ITO]
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3436Alkaline earth metal silicates, e.g. barium silicate
    • C04B2235/3454Calcium silicates, e.g. wollastonite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3804Borides
    • C04B2235/3813Refractory metal borides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3821Boron carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3852Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/3886Refractory metal nitrides, e.g. vanadium nitride, tungsten nitride
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/444Halide containing anions, e.g. bromide, iodate, chlorite
    • C04B2235/445Fluoride containing anions, e.g. fluosilicate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/447Phosphates or phosphites, e.g. orthophosphate or hypophosphite

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention belongs to the technical field of ceramic hand mold preparation, and particularly relates to a ceramic hand mold coating suitable for nitrile rubber glove production and a preparation method thereof. The feed is prepared from the following raw materials in parts by weight: 12-17 parts of feldspar, 10-15 parts of wollastonite, 22-27 parts of spodumene, 15-18 parts of magnesite, 28-33 parts of high-alumina bauxite, 5-10 parts of bentonite, 4.0-6.0 parts of boron carbide, 4.0-5.5 parts of titanium diboride, 5.0-8.5 parts of tin oxide, 6.5-8.0 parts of zinc oxide, 5.0-8.0 parts of cerium oxide, 0.3-0.5 part of sodium silicate and 0.3-0.5 part of sodium hydrogen phosphate. According to the ceramic hand mold coating suitable for producing the nitrile rubber gloves, the coating and the blank are sintered together, chemical reaction occurs between the components of the coating through sintering, the binding force with the blank is good, the process is simple, the prepared coating is compact, and the corrosion resistance and the thermal shock resistance are good.

Description

Ceramic hand mold coating suitable for nitrile rubber glove production and preparation method thereof
Technical Field
The invention belongs to the technical field of ceramic hand mold preparation, and particularly relates to a ceramic hand mold coating suitable for nitrile rubber glove production and a preparation method thereof.
Background
The butyronitrile gloves are mainly processed by butyronitrile rubber, and are indispensable protective articles for protecting hands and preventing cross infection in scientific research industries of medical treatment, medicine and health, hairdressing and beauty, food processing, chemical engineering biology and the like. The nitrile rubber does not contain protein, so that anaphylactic reaction can not be caused, and the nitrile rubber has the performances of static resistance, ageing resistance and oil resistance, is designed according to the hand shape of a human body, has higher flexibility, better tensile property and puncture resistance, higher tensile strength and better wear resistance, and is widely used.
The butyronitrile gloves are mainly prepared by the processes of dipping butyronitrile latex, molding, vulcanizing, surface treatment, dust-free cleaning and the like. In the preparation process, firstly, the used hand mold needs to be subjected to acid washing, alkali washing, rinsing and drying, then the hand mold is dipped in coagulant solution and latex raw materials, and demolding is carried out after vulcanization. The acid washing adopts acid solution such as nitric acid and the like, the alkali washing adopts alkaline solution such as aqueous solution of sodium hydroxide and the like, the rinsing adopts chlorine water, the chlorine washing time is about 20-30min, the temperature of the dipping coagulant solution is 60-70 ℃, the temperature of the dipping latex raw material is 20-30 ℃, the temperature of vulcanization is 120-130 ℃, and the temperature difference between the continuous steps is large.
Therefore, the hand mold for preparing the nitrile rubber gloves is required to have good acid and alkali corrosion resistance, oxidation resistance, higher thermal shock resistance stability when subjected to rapid cooling and rapid heating, uniform rubber hanging and good performance of easy demolding after vulcanization.
The traditional hand mold coating has the defects of poor acid resistance and alkali resistance and difficult cleaning, is not suitable for a ceramic hand mold used in the preparation process of nitrile rubber gloves, and in order to improve market competitiveness, the microcrystalline phase structure of the ceramic hand mold needs to be improved, the preparation process of a product needs to be further simplified, the energy consumption is reduced, and the online service life and the qualified rate need to be further improved.
Disclosure of Invention
The purpose of the invention is: providing a ceramic hand mold coating suitable for producing nitrile rubber gloves; the ceramic hand mold coating has acid and alkali resistance, oxidation resistance and thermal shock resistance stability; the invention also provides a preparation method thereof.
The ceramic hand mold coating suitable for producing nitrile rubber gloves is prepared from the following raw materials in parts by weight: 12-17 parts of feldspar, 10-15 parts of wollastonite, 22-27 parts of spodumene, 15-18 parts of magnesite, 28-33 parts of high-alumina bauxite, 5-10 parts of bentonite, 4.0-6.0 parts of boron carbide, 4.0-5.5 parts of titanium diboride, 5.0-8.5 parts of tin oxide, 6.5-8.0 parts of zinc oxide, 5.0-8.0 parts of cerium oxide, 0.3-0.5 part of sodium silicate and 0.3-0.5 part of sodium hydrogen phosphate.
Preferably, the ceramic hand mold coating suitable for producing nitrile rubber gloves is prepared from the following raw materials in parts by weight: 12-15 parts of feldspar, 10-12 parts of wollastonite, 22-25 parts of spodumene, 16-18 parts of magnesite, 28-30 parts of high-alumina bauxite, 5-8 parts of bentonite, 4.0-5.0 parts of boron carbide, 4.0-5.0 parts of titanium diboride, 7.0-8.5 parts of tin oxide, 7.0-8.0 parts of zinc oxide, 6.0-8.0 parts of cerium oxide, 0.3-0.5 part of sodium silicate and 0.3-0.5 part of sodium hydrogen phosphate.
Most preferably, the ceramic hand mold coating suitable for producing nitrile rubber gloves is prepared from the following raw materials in parts by weight: 15 parts of feldspar, 10 parts of wollastonite, 25 parts of spodumene, 18 parts of magnesite, 28 parts of high-alumina bauxite, 8 parts of bentonite, 5.0 parts of boron carbide, 5.0 parts of titanium diboride, 8.0 parts of tin oxide, 7.0 parts of zinc oxide, 6.5 parts of cerium oxide, 0.5 part of sodium silicate and 0.5 part of sodium hydrogen phosphate.
The ceramic hand mold coating suitable for producing nitrile rubber gloves, provided by the invention, is prepared by taking high-alumina bauxite and spodumene as main materials and adding magnesite, feldspar and wollastonite, so that the formation of a cordierite phase and a mullite phase is ensured, the corrosion resistance of the prepared coating is improved due to the matching of metal oxide and rare earth elements, and the oxidation resistance of the coating is improved due to the addition of boron carbide and titanium diboride while the corrosion resistance is further improved.
The invention relates to a preparation method of a ceramic hand mold coating suitable for producing nitrile rubber gloves, which comprises the following steps:
(1) performing wet ball milling on pulping raw materials, namely ball stone and water according to the proportion of 1:1.8-2.0:0.8-1.2 to prepare slurry;
(2) removing iron from the slurry, adding water, adjusting to a certain concentration, and sieving;
(3) the coating is sprayed on the surface of a ceramic hand mold blank, and then the ceramic hand mold blank is sintered in a kiln, and the ceramic hand mold coating suitable for producing nitrile rubber gloves is obtained after post-treatment.
Wherein:
the ball milling time in the step (1) is 40-45h, and when the ball milling is carried out until the proportion of the ball milling particles with the particle size less than 10 mu m is 75-80%, discharging slurry and milling.
And (3) adding water to adjust the Baume degree of the slurry to be 38-40 degrees in the step (2), and sieving the slurry with a 300-350-mesh sieve.
In the step (3), the temperature is raised from room temperature to 600-.
The ceramic hand die blank in the step (3) is prepared from the following raw materials in parts by weight: 30 parts of kaolin, 15 parts of kyanite, 10 parts of waste porcelain powder, 35 parts of calcined bauxite, 5 parts of potassium sodium sand, 12 parts of wollastonite, 20 parts of spodumene, 5 parts of bentonite, 5 parts of sawdust, 3 parts of aluminum fluoride, 0.4 part of vanadium pentoxide and 2 parts of titanium nitride.
And (3) performing surface micro-polishing treatment by using a ceramic ball grinding hand machine, and performing surface integral polishing by using a cloth wheel polishing machine.
Compared with the prior art, the invention has the following beneficial effects:
(1) the ceramic hand mold coating suitable for producing nitrile rubber gloves disclosed by the invention has good binding force with a ceramic hand mold blank, and the rare earth oxide is matched with tin oxide and zinc oxide, so that the coating is more compact and uniform, the corrosion resistance of the coating is improved, the corrosion resistance of the coating is further improved by adding boron carbide, and the oxidation resistance of the coating is improved by adding titanium diboride.
(2) The ceramic hand mold coating suitable for producing nitrile rubber gloves, disclosed by the invention, takes high-alumina bauxite, spodumene, feldspar, wollastonite and magnesite as main raw materials, so that the formation of a mullite phase and a cordierite phase is ensured, the coating has good chemical properties, and the addition of bentonite, sodium silicate and sodium hydrogen phosphate ensures that slurry has good fluidity.
(3) According to the preparation method of the ceramic hand mold coating suitable for producing the nitrile rubber gloves, the coating and the blank are sintered together, so that the energy consumption is reduced, chemical reaction is generated among all components of the coating through sintering, the bonding force with the blank is good, the process is simple, the cost is low, special equipment is not needed, the popularization and the use are easy to realize, the prepared coating is compact, and the corrosion resistance and the thermal shock resistance are good.
Detailed Description
The present invention is further described below with reference to examples.
The ceramic hand die blank disclosed by the invention comprises the following raw materials in parts by weight: 30 parts of kaolin, 15 parts of kyanite, 10 parts of waste porcelain powder, 35 parts of calcined bauxite, 5 parts of potassium sodium sand, 12 parts of wollastonite, 20 parts of spodumene, 5 parts of bentonite, 5 parts of sawdust, 3 parts of aluminum fluoride, 0.4 part of vanadium pentoxide and 2 parts of titanium nitride.
Example 1
The ceramic hand mold coating suitable for producing nitrile rubber gloves described in embodiment 1 is prepared from the following raw materials in parts by weight: 12 parts of feldspar, 10 parts of wollastonite, 22 parts of spodumene, 15 parts of magnesite, 33 parts of high-alumina bauxite, 5 parts of bentonite, 4.0 parts of boron carbide, 5.0 parts of titanium diboride, 5.0 parts of tin oxide, 6.5 parts of zinc oxide, 5.0 parts of cerium oxide, 0.3 part of sodium silicate and 0.3 part of sodium hydrogen phosphate.
The preparation method of the ceramic hand mold coating suitable for producing nitrile rubber gloves described in embodiment 1 comprises the following steps:
(1) performing wet ball milling on pulping raw materials, namely ball stone and water according to the proportion of 1:1.8:0.8 to prepare slurry;
(2) removing iron from the slurry, adding water, adjusting to a certain concentration, and sieving;
(3) the coating is sprayed on the surface of a ceramic hand mold blank, and then the ceramic hand mold blank is sintered in a kiln, and the ceramic hand mold coating suitable for producing nitrile rubber gloves is obtained after post-treatment.
Wherein:
the ball milling time in the step (1) is 45 hours, and when the ball milling is carried out until the proportion of less than 10 mu m is 75 percent, the slurry is discharged and milled.
Adding water to adjust the Baume degree of the slurry to be 38 degrees in the step (2), and sieving the slurry with a 300-mesh sieve.
And (3) firstly raising the temperature from room temperature to 600 ℃ at the temperature raising speed of 5 ℃/min, preserving the heat for 30min, then raising the temperature to 850 ℃ at the temperature raising speed of 2 ℃/min, preserving the heat for 30min, and finally raising the temperature to 1200 ℃ at the temperature raising speed of 2 ℃/min, preserving the heat for 20min and firing.
And (3) performing surface micro-polishing treatment by using a ceramic ball grinding hand machine, and performing surface integral polishing by using a cloth wheel polishing machine.
Example 2
The ceramic hand mold coating suitable for producing nitrile rubber gloves described in embodiment 2 is prepared from the following raw materials in parts by weight: 15 parts of feldspar, 11 parts of wollastonite, 24 parts of spodumene, 17 parts of magnesite, 28 parts of high-alumina bauxite, 7 parts of bentonite, 5.0 parts of boron carbide, 4.0 parts of titanium diboride, 7.0 parts of tin oxide, 7.0 parts of zinc oxide, 6.0 parts of cerium oxide, 0.4 part of sodium silicate and 0.4 part of sodium hydrogen phosphate.
The preparation method of the ceramic hand mold coating suitable for producing nitrile rubber gloves described in embodiment 2 comprises the following steps:
(1) performing wet ball milling on pulping raw materials, namely ball stone and water according to the proportion of 1:1.8:1.2 to prepare slurry;
(2) removing iron from the slurry, adding water, adjusting to a certain concentration, and sieving;
(3) the coating is sprayed on the surface of a ceramic hand mold blank, and then the ceramic hand mold blank is sintered in a kiln, and the ceramic hand mold coating suitable for producing nitrile rubber gloves is obtained after post-treatment.
Wherein:
and (2) performing ball milling for 43h in the step (1), and discharging slurry and milling when the ball milling is performed until the proportion of the ball milling particles smaller than 10 mu m is 80%.
Adding water to adjust the Baume degree of the slurry to 40 degrees in the step (2), and sieving the slurry with a 350-mesh sieve.
And (3) firstly raising the temperature from room temperature to 670 ℃ at the heating rate of 7 ℃/min, keeping the temperature for 35min, then raising the temperature to 900 ℃ at the heating rate of 3 ℃/min, keeping the temperature for 35min, and finally raising the temperature to 1250 ℃ at the heating rate of 2 ℃/min, keeping the temperature for 30min and firing.
And (3) performing surface micro-polishing treatment by using a ceramic ball grinding hand machine, and performing surface integral polishing by using a cloth wheel polishing machine.
Example 3
The ceramic hand mold coating suitable for producing nitrile rubber gloves described in this embodiment 3 is prepared from the following raw materials in parts by weight: 17 parts of feldspar, 13 parts of wollastonite, 25 parts of spodumene, 17 parts of magnesite, 28 parts of high-alumina bauxite, 8 parts of bentonite, 5.0 parts of boron carbide, 4.0 parts of titanium diboride, 8.5 parts of tin oxide, 8.0 parts of zinc oxide, 8.0 parts of cerium oxide, 0.5 part of sodium silicate and 0.5 part of sodium hydrogen phosphate.
The preparation method of the ceramic hand mold coating suitable for producing nitrile rubber gloves described in embodiment 3 comprises the following steps:
(1) performing wet ball milling on pulping raw materials, namely ball stone and water according to the proportion of 1:2.0:1.2 to prepare slurry;
(2) removing iron from the slurry, adding water, adjusting to a certain concentration, and sieving;
(3) the coating is sprayed on the surface of a ceramic hand mold blank, and then the ceramic hand mold blank is sintered in a kiln, and the ceramic hand mold coating suitable for producing nitrile rubber gloves is obtained after post-treatment.
Wherein:
the ball milling time in the step (1) is 40h, and when the ball milling is carried out until the proportion of less than 10 mu m is 80%, slurry is discharged and milled.
Adding water to adjust the Baume degree of the slurry to 40 degrees in the step (2), and sieving the slurry with a 350-mesh sieve.
And (3) firstly heating from room temperature to 630 ℃ at the heating rate of 5 ℃/min, keeping the temperature for 30min, then heating to 900 ℃ at the heating rate of 3 ℃/min, keeping the temperature for 35min, and finally heating to 1230 ℃ at the heating rate of 2 ℃/min, keeping the temperature for 25min, and firing.
And (3) performing surface micro-polishing treatment by using a ceramic ball grinding hand machine, and performing surface integral polishing by using a cloth wheel polishing machine.
Example 4
The ceramic hand mold coating suitable for producing nitrile rubber gloves described in this embodiment 4 is prepared from the following raw materials in parts by weight: 15 parts of feldspar, 10 parts of wollastonite, 25 parts of spodumene, 18 parts of magnesite, 28 parts of high-alumina bauxite, 8 parts of bentonite, 5.0 parts of boron carbide, 5.0 parts of titanium diboride, 8.0 parts of tin oxide, 7.0 parts of zinc oxide, 6.5 parts of cerium oxide, 0.5 part of sodium silicate and 0.5 part of sodium hydrogen phosphate.
The preparation method of the ceramic hand mold coating suitable for producing nitrile rubber gloves described in this embodiment 4 comprises the following steps:
(1) performing wet ball milling on pulping raw materials, namely ball stone and water according to the proportion of 1:1.8:1.0 to prepare slurry;
(2) removing iron from the slurry, adding water, adjusting to a certain concentration, and sieving;
(3) the coating is sprayed on the surface of a ceramic hand mold blank, and then the ceramic hand mold blank is sintered in a kiln, and the ceramic hand mold coating suitable for producing nitrile rubber gloves is obtained after post-treatment.
Wherein:
the ball milling time in the step (1) is 45 hours, and when the ball milling is carried out until the proportion of less than 10 mu m is 78%, slurry is discharged and milled.
And (3) adding water to adjust the Baume degree of the slurry to be 40 degrees in the step (2), and sieving the slurry with a 300-mesh sieve.
And (3) firstly raising the temperature from room temperature to 650 ℃ at the heating rate of 6 ℃/min, keeping the temperature for 30min, then raising the temperature to 950 ℃ at the heating rate of 3 ℃/min, keeping the temperature for 35min, and finally raising the temperature to 1250 ℃ at the heating rate of 1 ℃/min, keeping the temperature for 30min and firing.
And (3) performing surface micro-polishing treatment by using a ceramic ball grinding hand machine, and performing surface integral polishing by using a cloth wheel polishing machine.
Comparative example 1
The ceramic hand mold coating suitable for producing nitrile rubber gloves described in comparative example 1 is prepared from the following raw materials in parts by weight: 15 parts of feldspar, 10 parts of wollastonite, 25 parts of spodumene, 18 parts of magnesite, 28 parts of high-alumina bauxite, 8 parts of bentonite, 5.0 parts of boron carbide, 5.0 parts of titanium diboride, 8.0 parts of tin oxide, 7.0 parts of zinc oxide, 0.5 part of sodium silicate and 0.5 part of sodium hydrogen phosphate.
The preparation method described in this comparative example 1 is the same as in example 4.
Comparative example 2
The ceramic hand mold coating suitable for producing nitrile rubber gloves described in this embodiment 4 is prepared from the following raw materials in parts by weight: 15 parts of feldspar, 10 parts of wollastonite, 25 parts of spodumene, 18 parts of magnesite, 28 parts of high-alumina bauxite, 8 parts of bentonite, 5.0 parts of boron carbide, 5.0 parts of titanium diboride, 8.0 parts of tin oxide, 6.5 parts of cerium oxide, 0.5 part of sodium silicate and 0.5 part of sodium hydrogen phosphate.
The preparation method described in this comparative example 2 is the same as that of example 4.
Comparative example 3
The ceramic hand mold coating suitable for producing nitrile rubber gloves described in comparative example 3 is prepared from the following raw materials in parts by weight: 15 parts of feldspar, 10 parts of wollastonite, 25 parts of spodumene, 18 parts of magnesite, 28 parts of high-alumina bauxite, 8 parts of bentonite, 8.0 parts of tin oxide, 7.0 parts of zinc oxide, 6.5 parts of cerium oxide, 0.5 part of sodium silicate and 0.5 part of sodium hydrogen phosphate.
The preparation method described in this comparative example 3 is the same as that of example 4.
Comparative example 4
The ceramic hand mold coating suitable for producing nitrile rubber gloves described in comparative example 4 is prepared from the following raw materials in parts by weight: 15 parts of feldspar, 10 parts of wollastonite, 18 parts of spodumene, 18 parts of magnesite, 40 parts of high-alumina bauxite, 8 parts of bentonite, 5.0 parts of boron carbide, 5.0 parts of titanium diboride, 8.0 parts of tin oxide, 7.0 parts of zinc oxide, 6.5 parts of cerium oxide, 0.5 part of sodium silicate and 0.5 part of sodium hydrogen phosphate.
The preparation method described in this comparative example 4 is the same as that of example 4.
Comparative example 5
The ceramic hand mold coating suitable for producing nitrile rubber gloves described in comparative example 5 is prepared from the following raw materials in parts by weight: 43 parts of feldspar, 10 parts of wollastonite, 25 parts of spodumene, 18 parts of magnesite, 8 parts of bentonite, 5.0 parts of boron carbide, 5.0 parts of titanium diboride, 8.0 parts of tin oxide, 7.0 parts of zinc oxide, 6.5 parts of cerium oxide, 0.5 part of sodium silicate and 0.5 part of sodium hydrogen phosphate.
The preparation method described in this comparative example 5 is the same as that of example 4.
The ceramic hand mold coatings prepared in examples 1-4 and comparative examples 1-5, which were suitable for use in the production of nitrile rubber gloves, were subjected to performance testing, the results of which are shown in table 1 below:
the acid and alkali resistance test method comprises the following steps: slightly boiling for 1 hour in a sulfuric acid solution (10%) or sodium hydroxide solution (10%) medium, and determining the percentage of the mass of the sample after corrosion to the initial mass of the sample, namely the acid/alkali resistance of the ceramic hand mold.
The water absorption and the volume density are detected according to QB/T1642-2012, the acid and alkali resistance is detected according to GB/T4738-2015, and the thermal shock resistance is tested according to the GB/T3298-2008 thermal shock resistance test method for the domestic ceramic (the product is heated to 180 ℃, kept warm for 30min, put into water at 20 +/-2 ℃, subjected to heat exchange, and the heat exchange times are recorded).
TABLE 1 ceramic hand mold coating Performance test results
Figure BDA0002818766700000061
Figure BDA0002818766700000071

Claims (9)

1. The utility model provides a pottery hand former coating suitable for nitrile rubber gloves production which characterized in that: the feed is prepared from the following raw materials in parts by weight: 12-17 parts of feldspar, 10-15 parts of wollastonite, 22-27 parts of spodumene, 15-18 parts of magnesite, 28-33 parts of high-alumina bauxite, 5-10 parts of bentonite, 4.0-6.0 parts of boron carbide, 4.0-5.5 parts of titanium diboride, 5.0-8.5 parts of tin oxide, 6.5-8.0 parts of zinc oxide, 5.0-8.0 parts of cerium oxide, 0.3-0.5 part of sodium silicate and 0.3-0.5 part of sodium hydrogen phosphate.
2. The ceramic hand mold coating suitable for nitrile rubber glove production according to claim 1, wherein: the feed is prepared from the following raw materials in parts by weight: 12-15 parts of feldspar, 10-12 parts of wollastonite, 22-25 parts of spodumene, 16-18 parts of magnesite, 28-30 parts of high-alumina bauxite, 5-8 parts of bentonite, 4.0-5.0 parts of boron carbide, 4.0-5.0 parts of titanium diboride, 7.0-8.5 parts of tin oxide, 7.0-8.0 parts of zinc oxide, 6.0-8.0 parts of cerium oxide, 0.3-0.5 part of sodium silicate and 0.3-0.5 part of sodium hydrogen phosphate.
3. The ceramic hand mold coating suitable for nitrile rubber glove production according to claim 1, wherein: the feed is prepared from the following raw materials in parts by weight: 15 parts of feldspar, 10 parts of wollastonite, 25 parts of spodumene, 18 parts of magnesite, 28 parts of high-alumina bauxite, 8 parts of bentonite, 5.0 parts of boron carbide, 5.0 parts of titanium diboride, 8.0 parts of tin oxide, 7.0 parts of zinc oxide, 6.5 parts of cerium oxide, 0.5 part of sodium silicate and 0.5 part of sodium hydrogen phosphate.
4. A method for preparing a ceramic hand former coating suitable for nitrile rubber glove production according to claim 1, wherein the method comprises the following steps: the method comprises the following steps:
(1) performing wet ball milling on pulping raw materials, namely ball stone and water according to the proportion of 1:1.8-2.0:0.8-1.2 to prepare slurry;
(2) removing iron from the slurry, adding water, adjusting to a certain concentration, and sieving;
(3) the coating is sprayed on the surface of a ceramic hand mold blank, and then the ceramic hand mold blank is sintered in a kiln, and the ceramic hand mold coating suitable for producing nitrile rubber gloves is obtained after post-treatment.
5. The method for preparing a ceramic hand former coating suitable for nitrile rubber glove production according to claim 4, wherein: the ball milling time in the step (1) is 40-45h, and when the ball milling is carried out until the proportion of the ball milling particles with the particle size less than 10 mu m is 75-80%, discharging slurry and milling.
6. The method for preparing a ceramic hand former coating suitable for nitrile rubber glove production according to claim 4, wherein: and (3) adding water to adjust the Baume degree of the slurry to be 38-40 degrees in the step (2), and sieving the slurry with a 300-350-mesh sieve.
7. The method for preparing a ceramic hand former coating suitable for nitrile rubber glove production according to claim 4, wherein: in the step (3), the temperature is raised from room temperature to 600-.
8. The method for preparing a ceramic hand former coating suitable for nitrile rubber glove production according to claim 4, wherein: and (3) performing surface micro-polishing treatment by using a ceramic ball grinding hand machine, and performing surface integral polishing by using a cloth wheel polishing machine.
9. The method for preparing a ceramic hand former coating suitable for nitrile rubber glove production according to claim 4, wherein: the ceramic hand die blank in the step (3) is prepared from the following raw materials in parts by weight: 30 parts of kaolin, 15 parts of kyanite, 10 parts of waste porcelain powder, 35 parts of calcined bauxite, 5 parts of potassium sodium sand, 12 parts of wollastonite, 20 parts of spodumene, 5 parts of bentonite, 5 parts of sawdust, 3 parts of aluminum fluoride, 0.4 part of vanadium pentoxide and 2 parts of titanium nitride.
CN202011412127.6A 2020-12-04 2020-12-04 Ceramic hand mold coating suitable for nitrile rubber glove production and preparation method thereof Active CN112341166B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011412127.6A CN112341166B (en) 2020-12-04 2020-12-04 Ceramic hand mold coating suitable for nitrile rubber glove production and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011412127.6A CN112341166B (en) 2020-12-04 2020-12-04 Ceramic hand mold coating suitable for nitrile rubber glove production and preparation method thereof

Publications (2)

Publication Number Publication Date
CN112341166A true CN112341166A (en) 2021-02-09
CN112341166B CN112341166B (en) 2021-07-13

Family

ID=74427732

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011412127.6A Active CN112341166B (en) 2020-12-04 2020-12-04 Ceramic hand mold coating suitable for nitrile rubber glove production and preparation method thereof

Country Status (1)

Country Link
CN (1) CN112341166B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114633418A (en) * 2022-02-15 2022-06-17 深圳市可信华成通信科技有限公司 An energy-saving and environment-friendly glove production and manufacturing process
CN120117878A (en) * 2025-05-09 2025-06-10 德州昊祥模具科技有限公司 Preparation method of heat-conducting ceramic hand mold

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU317229A1 (en) * METHOD OF PROTECTION OF REFRACTORY FIELD OF METALLURGICAL UNITS
GB1106014A (en) * 1964-07-24 1968-03-13 Corning Glass Works Molding comminuted nonplastic inorganic material
US4781970A (en) * 1987-07-15 1988-11-01 International Business Machines Corporation Strengthening a ceramic by post sinter coating with a compressive surface layer
CN102276292A (en) * 2011-08-16 2011-12-14 淄博隆嘉工贸有限公司 Far-infrared ceramic hand shape die and preparation method thereof
CN104072205A (en) * 2014-07-11 2014-10-01 江苏拜富科技有限公司 Full polish ceramic product and preparation method thereof
CN105948503A (en) * 2016-04-29 2016-09-21 佛山市东鹏陶瓷有限公司 Wear-resistant transparent glaze and method for preparing glazed tile by utilizing same
CN106518166A (en) * 2016-09-22 2017-03-22 北京优材百慕航空器材有限公司 Carbon/carbon composite material anti-oxidation coating layer and heat treatment method
CN107721462A (en) * 2017-11-24 2018-02-23 淄博昊祥模具科技有限公司 The ceramic hand-mold coating and its production, application method used suitable for acrylonitrile butadiene glove
CN109133636A (en) * 2018-11-23 2019-01-04 禹州市华盛钧窑有限公司 A kind of pottery drinking utensils matt glaze
CN111925231A (en) * 2020-09-16 2020-11-13 佛山东鹏洁具股份有限公司 Glaze spraying process of robot glaze spraying circulation line and ceramic closestool prepared by glaze spraying process

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU317229A1 (en) * METHOD OF PROTECTION OF REFRACTORY FIELD OF METALLURGICAL UNITS
GB1106014A (en) * 1964-07-24 1968-03-13 Corning Glass Works Molding comminuted nonplastic inorganic material
US4781970A (en) * 1987-07-15 1988-11-01 International Business Machines Corporation Strengthening a ceramic by post sinter coating with a compressive surface layer
CN102276292A (en) * 2011-08-16 2011-12-14 淄博隆嘉工贸有限公司 Far-infrared ceramic hand shape die and preparation method thereof
CN104072205A (en) * 2014-07-11 2014-10-01 江苏拜富科技有限公司 Full polish ceramic product and preparation method thereof
CN105948503A (en) * 2016-04-29 2016-09-21 佛山市东鹏陶瓷有限公司 Wear-resistant transparent glaze and method for preparing glazed tile by utilizing same
CN106518166A (en) * 2016-09-22 2017-03-22 北京优材百慕航空器材有限公司 Carbon/carbon composite material anti-oxidation coating layer and heat treatment method
CN107721462A (en) * 2017-11-24 2018-02-23 淄博昊祥模具科技有限公司 The ceramic hand-mold coating and its production, application method used suitable for acrylonitrile butadiene glove
CN109133636A (en) * 2018-11-23 2019-01-04 禹州市华盛钧窑有限公司 A kind of pottery drinking utensils matt glaze
CN111925231A (en) * 2020-09-16 2020-11-13 佛山东鹏洁具股份有限公司 Glaze spraying process of robot glaze spraying circulation line and ceramic closestool prepared by glaze spraying process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114633418A (en) * 2022-02-15 2022-06-17 深圳市可信华成通信科技有限公司 An energy-saving and environment-friendly glove production and manufacturing process
CN120117878A (en) * 2025-05-09 2025-06-10 德州昊祥模具科技有限公司 Preparation method of heat-conducting ceramic hand mold

Also Published As

Publication number Publication date
CN112341166B (en) 2021-07-13

Similar Documents

Publication Publication Date Title
CN104229844A (en) Preparation method of superfine low-sodium alpha-alumina powder with high activity
CN104726734B (en) The preparation method of Aluminum Matrix Composites Strengthened by SiC
CN105130410B (en) A kind of preparation method of Fast back-projection algorithm CBN grinding tool vitrified bonds
CN105084877B (en) A kind of preparation method of microwave method Fast back-projection algorithm CBN grinding tool vitrified bonds
CN111484050B (en) A kind of preparation method of spherical α-phase nano-alumina
CN104149038B (en) Diamond wheel employing ceramic binding agent
CN101948325A (en) Synergistic toughening alumina ceramic and preparation method thereof
CN110642281A (en) Preparation method of alpha-phase superfine low-sodium alumina powder
CN112341166B (en) Ceramic hand mold coating suitable for nitrile rubber glove production and preparation method thereof
CN106145946A (en) A kind of method that liquid phase feed technology prepares vitrified bonded grinding wheel
CN112441823B (en) Ceramic hand mold suitable for producing nitrile rubber gloves and preparation method thereof
CN105503180A (en) Processing method of antibacterial ceramic knife
CN118026532A (en) Antibacterial ceramic glaze and preparation method thereof
CN109824340A (en) A kind of processing technology of abrasive media
CN103073275A (en) Abandoned sand-based mullite lightweight aggregate and preparation method thereof
CN114478041A (en) Preparation method of high-toughness alumina ceramic
CN104128897B (en) Method for preparing ceramic cBN abrasive disc through wet chemistry method forming and microwave sintering
CN110240483B (en) A method for preparing silicon carbide porous ceramics by using crystalline silicon waste mortar
CN108326294B (en) Pot, preparation method thereof and cooking utensil
CN107500776B (en) A kind of polycrystalline cubic boron nitride tool material and preparation method thereof
CN104961446A (en) Processing method for preparing boehmite for alpha-aluminum-oxide-based ceramic abrasive materials with sol gel technology
CN118894726A (en) A method for manufacturing a low-iron-content pollution-free silicon carbide boat support for photovoltaics and semiconductors
CN114346919B (en) Superfine-granularity diamond grinding wheel and processing technology thereof
CN103056785B (en) Method for preparing vitrified grinding wheels with metal matrixes for grinding stainless steel and titanium alloys
CN103922756B (en) Surface treatment process method for silicon carbide powder

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant